Chemrcad emetics , y Ny, te a geld Sere da Ads | NS the edad of ste calbis ai We chornis wy bo | whe, oma chemi tal, secces ds conven heh Xo auollav, 6 ! st Consrder the Rito? ny teachion I A+B—eKR WW =o a vateoA yeachyon \| | -Ygon aS PLE GWE © etn 43 ow G aakln +Yp. = 4 SN | & Nez Moles eA reacted mole. s Nz Volume of Pad. ue }} = Hae Sce.=2- -2- = fers paar) =a = fep-- fCc) | Yaak Peg). | Kes reackon, Constand_ fa ae a RA PIR —sSC —m = KG Cg f oR -ra> kK Ca poR an kG {oe * Who Kil Poet CoS. Ce page ae By fee . eé Arrhenous equati— kor frawengfacfon Bu), he E= Attivatu—Energy. Jeti 2b Ro gas cusdant. a = Temp. Ale. thee Lomb fet pro pills a “PelpV SUD) aliens Jo os ee ete ate £0 NG) ab Ms evxe ALD) tet Ree Bheis pre Soli edly ep Who H .BUy2 ara MsR Bs & | cate E Types ef Reactions +. Ay y | ~ 4) Nomogeneous ebeléS, ably Belt teus SS Qe Hp —OHe tran“ foes = Fe nile — Zncnde Sec | 3 Bw (YL LI lol ely) ad 2) Helrgeneous . PE sty) ae AM, Sb) 2 AGW oy (gas ~ Solid) _ Qqcd Brpl ie og ee, c | eartion mages. a ey aist Swe Se D 4 Epa 8 | e o | Ei Sy Zins’ Z ri ws | DP AS, eASy eal de AS = DS - 44 ur] + por) e ated] i + ASKS Hale op AB(E%) + AVC) (isle eat __b ae dels pg) he gp BA fo ok caSe I , GMs Je oye SPE saabsy oly Boe Wet i Spal Te Atl= DHp BHR + Sty | A Heyg = Se -Eniang || || BHp2 Ses st I e. TG | Bigs & SURAT ieé | mee: | a a Hh Ex> Caltalate He Keak of Cracking +f propane. fo ethylene waa methane ‘at yoo? | C3Hy —> GH 4 HY given the follorsig. data. | ie ° Co by cHey CoH Nene (296 F999 - 24 B20 Cal/g-me) @ Ay) 20-4 We Yo Saln> se hh hHm e { AAT aH, Pare Z Zn at, diy = (124496 ~1790) — C24 222) = 19 42 ot e ot = 1042? + ((20-4q-4)—4i] (492-2— 917.99) bd = 19525 CHS su ae —— |Kell Kr= ciliate af reschon cottent: tachi xfficte oe af +b“ -CydD sex maole Cacdion Pr ‘f 2 Kee xe “9. Keg igs Xe Xe-XD oF ae uf Xe Xe =, ts 5 ay 8ah Kee Ky er Pe ae | 1] ay Ee eo | | Ke Eyer : | jee ae Abr OH 2 JospT | any RY) | Q '@ t : on oy | Ke ky (or), ike @r | RT? Le a | Ke” Kee \ky yD. fo Ai f Woe SEAT yr Vet eee . RV a ied A ae ' : e ey Gd 6) = tl) obs» 28° Homi = - teach Femi en Chemicoh EQuililpring . Like RG ee ae —N ce ert = eee r Awe BN yc ——te) SS Se RY a nz i % SADA pact ta) Sub bt IAT TT Al ot nas| fG (Goud al ow gli oles | Inne Bly BG We Sh a tthn= rn 6B -AaTI4T—) abt T pol, LS apt. woe s.6. fu | ONes JyAaT SS Tose 74 : oi wd) BH, = Sdarclarel baad of wollen a deepal | AM = Standard hah a} ven ion ak Te 20g | | = ea R= way Ss | Bw ie K . e ~ x IS sAali AN Clip, QP R Br who 3 . ete ee PI? | BATT SH Rp zreane: pats thrg. ee 7 | P > e > He > AH = np oNey Smo Hec| £ e CRQ = ° : | SRO Zn abe, —Zvinhy BeAr ec ° OW = 93294 cal /owt, wu Glo tA a Chet Hho ——— = eee e| Culcon fou > 2G a BM dies = Tho goo | cHy coc 490, 52 Cer +iHt0 Aes | of Ho + 4 02 ——» 20 supa —64pre ° | 2Wfo +219 > CUs Coo Hy gin BHc = 20544 } Cee +2 —> 2. loo BE aHe= 226700 eo He + hor — > Hro At) = 8314, | Gtr oh + 4 OL —S Ch e+ Heo | Ss 3d0 | : 3 | Qg. BH, = Ae ace AIT ee 293 | Bul Saag + Aa (qs) +bP Ce ate ae) ® oe SGe0= DUpy—T PS.00 0 NS op aets Senge Cali BE ATQ We 3 es SEY os eee = — fae se aT + ate nant aT bri hs cn Soo 2b yp — | | x koa Ra kp =~ ay | | K = fa ky Pe e Ka ky pn | + v3 Kyo se oh tym, | Syn Qnty > Wo 4a jtsids \ ° oO | eam - 02, 40.47) 3(098) = QAr-aa f Bload doa? : ee Sige ace oe tks Sia Ag 7 ve Vag Sues V-AB | ° f—> Fae Kp= ky B odin 2 glo ese FR | | 5 \eh ee SS ey LE) ne So. | oo2 ty : T12- Ho Wo pre's) Us Gs Pe oe wht As Lys L .~13- I i We tmet of rind = Jy om verted A Tent) = Ba | | Coq 4B ee EH ZO y Melo @ wy os eas ° 2 Jaw of) 0 W-$4) Ry 4 SP GA es see ul bath i949 1S ° Ibe —orttmfr 1.22 fo =Total wel oh Come = 325 _2f, 24e e : wet Tapped | Co SEU te to= Vaeh-ef. | bay Si 2s 3h- adn eg «emai | ca Barth —Ude a7 Galt @ | y fists Kiy_(raeo) Sere c | i+ 1 ee “Cy nF een © | i oer Sy (Boa) = “hose y eee So= pig ate + Bicone \ — Or —sS 0¢ e e =a Herne 6 Wiese acs, Moe > DYen ice Ture a BHR = i 7 oe To “we. aif ib ast Te 8Snxiod F2 = 673 2 . a ae 7102 WOT 0 42x00 T™ ofa ay | Qe Spee | | ees po Bboy act’, ~— ay - l|_( eee “SR | o- I Re eer oe AB? C3 oT { = == | Lak » & | e bia I+ Sa (aie WD Jz -2t 0% (3) Muy 2 T eH | 220480 4 4 W3(244)Iq 4d — tend! (193), BIS KI Cony) | = PCega) e | 16102 -\563H — T0243) | WA. ae SA mas or | BGqp 2.16930 - } -S ‘ = || 2eqee = J 4-4 Coys) + Sue (242) + 2 293) ®— ' ee ; = BG J patint. 8b pt set p z AG = -12oB0 ee lt TYG) a4) = 12. 471en si (4). 744 a cane 4 grpsenta® (74). 2-875 (744) + ser 27g | = 96.57 fe)| alee pte bye. taf, 1 ef ey rode swt, So ae fi) 1. 4 di On g-bh tid fish Soz f Li] ws- “eth oes ee ee ee eee. | r fi eerie uate (Sena LS-LS, 1.o- Lhe es 5. ey) a. aes dees TAY (Shh zi - | e- Z me, 917 ~ \uot pt dh pr cA” Ales yr ~ bans fs Sn ee I es SSE RT 2318 =p2), il 7 mecca aia E C2 lsc 4 6, CH; Cosy Age 4 the By tim teh bHe Be dew DWe= Sige Awe — R eo — 326. oo (Las. 1¢e) ae WESC Calf oprer AUT. = as want Sa AvP e e Ww Cb, 217 — Nb pee) ~C_60.220) Steg 2ae 7 fae a Hail ?” Sheet -t- aa i. Coicelata- the hack of peunben fe th. folreviiy at es € nual oy t BHO ———e Glo. ¢ CM yD ;* tab + Cab 9 jn 5 AUS wig th basis BU dade cute YN Hoe Calorie Gig le 1 i, 7 y f i (als wos) 715080 ~ 63514 -2s5Be0 FI yar 4 on Cabeluaa HL bent uf reaction shsiny the hawt of combus tio Mathie foo the Prawieg* . Cols ort, peew) s,(tHy cont +A2d, a “ éatly cf CHy Coot H20 (ey Ox atl ee a 6 ‘ 20g Cpa lyme) = 69317 6 @): Glue 4G » at veo the reactio n may be faleus us : GN +50 —»4NO* EH2 Ory, cok the valraber use data dren fable aed take inte ae { Cfie heat enth Tear X ¥ A Na PP i ay be Gon © aol Co dal pressure f jo thm, ammo So esciatiel te exteal of Yah: Coktakibe kp , Ky, wel Fe fer aes et HOM QNHy sacs Ne + 3He &s) A gas mucture of pe md {Oe wil 75), is mised ft with the sdochivme tie He for fhe fom reaction: pee 6 Coe pjllh oe cHyot +Heo Kez Ge Kk =2-0x10 @ = ¢HsoH ie The wwersion fo eg is effected 14 The presence of : geo adi pressure. Asowung The bebavir |» Cattle The pochonal conversion 0 cd hence Phe Comp af Ue ¢ wmbxdavess Co + Zriez- 24 i) A Streum <( 44s of composition So 2fe, Ges 9h 7 riak oot unl Hom NaF]. cater & Contact absor be discharged as cqalibriam at S00 C . The eym fractional conversion at this temp 13 e-4il and specitic hat dale are + a pbk SO. ZUG Tr q.sly oT + PSU KOT a 6-2 S% : 6 elt + 23-55 PKIO 0-6 RF KID T - ab Os 66 v.gtoe nto? T- 0-9234)2 T* : -6_ te, 2 Sy eo tee Kio TK eebob AOI T* T iw cp in Cal fymol le The Standend het of fermekow alte: ~ pvgee cal {g-veol. cad [y-me) wn wo 3 -yuaso a Cadtutal the heed that must be removed inorgler We Seve { is aut excrete yoo &YShag -e- -2A2 - 2 Pe catculnt Ko kp Ky ak patente and Ps boo ahem for the foteoiig reactions $Me EM2 > NHs ven Ae fenowing clades e4e) AG = Stoo Cal) g-mol Lion 24.5 = as Ue Nis Fo adn, hos los 7 Ie 2 og Saale’ 089 ie d Ayes mirdave censist of Aan B with the padg~ na mR = 3). Was ful de th. teacher Where the follocrny Yeactiens occurs: A+B = C+D Nac 2é lep = 6 Cob euleute The composfion at CFD. Qa, A witture -f 7-9 gr Ethanel ancl 10 gn AcebiCacid was maivdamed oct Constawt Lemme a4 equilib rieva th wag formal Mat the ache «cic js eA + YO pssume Ha miztare is chad Solu: Chelate, ———* i (4) Equilibewm Constant thr The composition at equilibrium Whey 12 4m p Eilanos and Pal gan acekie acid and eo am of Etylacetal | enol feof qm Water. under the Some nopve Ginclihiens. | CeNseH + CHpCoeH —- CMs Cocos gdeo Mu YE bo Fr r QA. cdealate te Epullriun Gnstant fr te jeroury ~ betditn af 320% - | Coy + Heo = C2Hook x | f given the. fellowing veecatten lala < \3) atl, = = 10466 Cal /g-mel.NG. r toll Hee S 4) 78, 67.26 as. (Ng-rolr) AS] cp (al yet) Ele: Gs 3-598 po-evgas TH 64-910 pt Hee Kp = 684 ro-cetg T—34ayt Te Cathy CP oe 2-464 0-024 TH Goebx ie Tt Qs. given So, AG = vA Cogent) AH = - Hat e ? S (CMfpoml -e) & So 4 O2 Glade 06, the fontotsing information for th. = = W0 jola ligne of a tb Or — > Sox ' 0 ~38,52¢ 735 Alf gr-mol. = ~b TUS A SILKS Tr FSU AD OTS : <6 E077 e235 pKio 7 o-bep AIO T % = Cia 4H 3102x005 a at T~ 6-923 xo °F and Ik 744k. @ ~)Qe Cala + tile 0 — 5 Cacole+Coe yy) . Ally = Em nike peal Kop ns 2 ee i He niger S4iq -.C- 238700) —[- Le ~1Seov) aH = peeve Gl /o-wot. — 279 Fr Calf. gam Qe Cells olf, £ Ovys > CH, CoH, Hedy ® ; i a AH, = > a Ae © Zneade rR e = -326 70 ~C- 20rtyo.~svslz) AHa, = -S00u3 Cl /g-rel. Gu 4NHs -S02 NO 4+ 6 H20,, bing (AYG-mi) oie 2S de ~577493 * ° a aG - 34.16 ° 20690 Sub es- fj +4) CP Gal G-mel Ie) ~2. So Wa, Py 797K 10 ee 10Sx0 he ag: Op 3 NS + 0-2 76x10 r ~ nis le ale No #y tgs: 4 O> L4asxlo Tames oF x10 2 xe° ° é BW, = WidSWee — ene She ip E6(-5:7798) + 4 (2iSFo)] ~L= Hove’) == 26549 Cl /g-mek,_ 29 - ni Ab 2-416 ACs L10o 216348 = 7 + 2324 NOTE Qe R- ay Fes cep 6g +. Ape. = 217699 +7: 7lSe0) ~ (2 a Cs00" + LbeS 18" C500)? a en Cal /g-mal. _ AQ = Trelis - Ba TIT b Ab ree act! e . | AGiy, = [-Su6s5 06) +4 C2069) ~L- sa z0Cu] = 7224 146 Calf gmat « = eas =O (248) rer? eahdemaier i i bh ~ 2-416) C242) X00 - ro WSK eg)? 2046-298 C, + (= 216348) Veet R487 10 =oT geka lt yTed: sot fp oe Tt i AG, = UlSee) FC n216348) ~ 14 Uias be Sve) — bens xi? OD CS0)" \ Cinos x1e)(560) * \ sooe —Zib6ZYb —24 206 pr Jo2v — 2fu-e a bprbe Cad /g-— ey iS loawle ef Nity enWy Se Wea tthe @ i ye) 300 18) Pag mek . \ oe Votal weles ah equlibvian = = oa) y e4/t gant So gte (erie) NN) 5, geVeo wy =b6ia® an i" Vo veathen Kes Fp =FyC82) = Fy (su) Thy = 2-8e wid 6ey = is ¥ feps-ec-ef-th J e (6 th thy (of) — fou © 8@ => f, oor {2 o 2d. st 4\ wvesiew | vecchons ——_ 4 de Converse Rr tratdions one * Ss) ~ fQe Soy eo bg - a Soy 10-45 1 be ° On aSsy Me aq OQ bil, RHR e BH 16 , +h Or 0% : SoAge — AICO Adz) (o.aw) é beg mde af feuh Tachad 12Co-4y) ste-ggr wd rarTaene wash y=S vee SD, grodech = 1O-qze mrol SO ovk = 12-4 SL = lobe ~ 9166 = US oH 2 bla Zinc -Enj OU prise Clo gzz) — U—degboClo 4s { tose 4 p 1Is 184 a Dif = 7 e8b ye Ct E 7 £ -¢t ates [ (Sataldt sf apy seg bace TH iasce I jdt : ¢ 109 ¢ PSEA Pe 8 Bhi s Onley + SEE Thy by 4-4) (OA EYP) +126 Bw 5e gay Alig = 242% x08 Gl =e6 \ Te a f Zorerad T= J 6oNg 4p HOKE THIS 24x70 i to To | / By af cead. 334 380 3 8 = (rps nepny + OME Cnn) CEA Ot 43) a Q~ arudyt — 272-410 4-25 6742) ts — io, 648 Gal- => ; ® yt ee e ak f — a | v we ciseAbe RT le B¥eo =_1-9370773) lan 3 2 IS 1X10 (03) egy" 8 KEK S-4XIB” = Eplo-gody | Pexib T= Shy, viet 2-407 ale ~Ot: Bs Az Suelo Bet mal Set fi fs the mete A veaectige enuf fae 4044 * a) 4 A+@ xm=c+D _ fw Foscs A4c = 2€ eo fh ba hb o 4 ot eqn. A ge tak B taf a fr fr D fy iS 2 fa Teint = 4 Mol G wi 7 yP nso * ee =i . a, Ke=ky. ee 8) CAD) _ \ GCFsy ¢ Kp al6 = aBs er Cou)! be (i 225 sz P22 de ep ae gee VAs CLL Jp ft eae, heme yp Seeasee sae les mele to i Be Bang 2 so Bo f-0-& oy fo 3 fe o-6—0.Y ork a D o-€ ob cs E 2n0y Or8 fo no leo — > Mr: CLS OH 4 CMs of= Mglrn & tHro 46 b0 Bs iP Thitially the mixture contains: CMe = zt = 69S mete x CAycoeH = 106g = ofl] nwte- . eqm CMa wok Foy = 01214 mele. pe oe Moles rrecdrol = 0-695 ~ of2/7 > 0-09 79 mole OH Cel gle = eo l2lE mole Hoo = OFZ (Sseten JO Xin) (SRE, (Kes WC Nengeroy) ~16~ role. o-e474Forte. Seconsl tate Leb x be the moles ef Mohol reackeol at °9rae & At eg: Alone! > Yao fom O86 )-x Acid te» Et x = otts—x Bote tay = 0.04SS 4X | Alo = X#0r6 ; wg my X= 0-072. Ky = 2 Lm wn ¢ sheald be last bai aL8S Oe a 0 2 nt eguy: ei Heot= 0-2 6/— 0-032 = 2-494 mole (3-4. §™) EUs Coo Hx a (3S= 0:42» 0-06 mole (3-294) Cs vote up = 0 2 VSS 0-072 =o TE Me) (l0-S45a) ay Hro 2 Orbe 0072 = o- 692 mol (12-4 gn). nla Qur— a AG, = 6746 =CYSlo 402-49) = 32-3). cal Jn AG = 60/7? +2 a) IS THs. a yeep i Rye 107 960 + espa so seseEaeanit 1) IT Be tigi yd Gq A GiS Bgag eft ee ocp dT AS, = BSop [ose —_ ogi = 30314 { ¢- - po TS RATS 4 fe TAT a bd C320) BenQ 4 ISH 5-/ P17 aH-Tas| 2-10,4 e—CS9)C —jo: “Be qe =BT In Ieee PG = Hee 26-06 j CRT 13a 7) j- Be 2-2/0), | AS AG, = ~~ F8s7e = C=71 40) = 16 730 St woh. = 23-3 Kas bepR Fe iby MEME) SA YNZ bbs [23-514 Opie tk xp-1or)Jxi63 =12- way xis dca Cnonbe GS ig xo-4 +5 }eis f STP pee 3G CT + BH — aT IT b Abr Pees I ner? x AG. Fe Fm 22, F3S ANS a 23/ oh Te beapyio Bigg eee —> BS IR ca a ooAG, = —-22)- 72S — 130g T 6-23 KIO ET ep ork eee xi + 4-038 T aan AG—-=- 6612 : - 9 ts -AG 660 ay | la koe ae SOO eH ely | me 1 TAG A-980 je BS-) — i wt zs Czy) ~25 ai. wy CrB ete Ue presence of itn The behavior Jounal conversion cletely uve’.g// le Sal aa SF dors Calceulake yo feak of reackion for Lhe Alluring oe Lech 25°C. and Leake CAG) + H/20 (2) ~» CoCGH), 6) + GHacgs ~usiig Lhe Fellousing AHp dabes- GaGa: ale =-'500 cal /g.mol. H20 (0): * ate = - 68,517 col /g mol Ca (OH), ale = ~ 235200 cal. /gmol. Caleulale Lhe freak of reachon ering Lhe heals of combushion and Peak of formation dala fey bre. following 3 GMs OH cay # Cy cg) —> CH3CCIH » M20 we given: ‘ = d alle for GHoOW = - 326,700 calfgmel af 26% ane fr Ch COOH 2° ~ 208, 240 colfgmel. ab ost hp for GIO ~~ 66 220. cal/ymel. as ag Ar Chcool =. NE 400 Cal / gine! [ste Go hl yy = 68,312 Cal-Lgmel- * a Lf . ; Caleulale A&G and al? fr the ammonia oxrdakion reachin at cox Kv Ihe reachon AN 50, >» {N04 EMO, use lake » dables ancl dake ints account phe variation of the Lemp peret ure— 5215243 calacs see = See ti ib W0%. ad « ketal pressure of fo abv, Cuuprone & £F F Associaked Lo Lhe extenk of 98% -( Caleulase Kos, Ay onl Ke Br the yeachion > My az Ne 4 3H Ans. Kp= 991x104 abnt, ky 2990 , Kes 22.66 Set GAS ) 4A gas anyvxkure of 25 mol % CO, and 757 ~ wrth the stochomelc ty Br the CO, + 3H, 1s mixed Pllovinny reach ous te Ch0H 4 KC kz 262 x68 CO-4 2th = Ls Chow Kz 2.60 x10" S The conversion £0. ¢ eau!” 1s eHecked i Lhe presence of a nes ak 00 abn pressure Assuning the beaver to remar ideal, cahelbe Lhe frachonal conversiin br each reachan ancl Henie the wrposithin of bhe egzerI? mx kure th Ans. Fursk reaction fee og yp Second fs 6.965 ( ie. Be veachon Gly - AO Gg) ae & Me OW 1g) 4q° = 1625 cal. pnp ancl 2H = —fotoo Glfoul. al the -, 3) operating Lemp. of 48% The Frouly prodachin yale rs juey" Bb he. 550 kg of GHsoH from a feed wabainag Zoroles AO per rele of GM4. Assuming Mal Le feed eulers and Lhe prducks have ak the reathin Zemperakure carl thak egivhbrivm i adtaned ak « pressure. of 2akm., estimate the frachanaf conversion aviel Fow rch Teak isdo be removed ? = othe f: oft sae es ie. ~ S9- d A skechomekere mixture of Wr end Hy 1s do be brought 2 egwhbrum «hk 600 alin preesure. Fer fhe reachin Nig at” FK Nhe eqwitbriua rucdynaim= olale chon f “ Eskimake the freckénal conversion to avanoini aennneg 1 vdeol fen wizbare 2. pun ~rheat gas PELE Ane. fo 058 (chal), fe» 0°89 (n00- shal) @ Challe the egutbriiun conrbank and epulbtitn conveysjin, 08 Le elowig seathim: Ge 9 +#-Ge Gh Gg) » te ak « Lemperebue of tel If the reachon taker piece of Lain. Pressure . below :- Dake on 4G", aH? ancl @ ore given 46 by |aml | at” be/el | @ ke fol. K e” -| a2 ba6 : | sceneries RAP po Cony j 6824 52-3 lo-ouzy 12 sy Ha | o ° Leste 64 x65 Be ‘esMa east MH tay? Me, ( Por the ammonta synthesis veackron the eqwhbrum vensersfon do ammonra os large ab Book, bul decreases rapidly with theveasing T. For a feed mixkure of Hy ancl Ny in stochrometite proporkrons cco Delerone the role frackion of ainmenia in Lhe egubbnia prebare ab L haw cued poo tb) AL jwhal demperature does the eguibhtiun mole frach or © bear Sor a pressure of of amnroiua gA + se—c I} se 20 \s | ; : | 4 a = 2 =2$ = § Limi bing « | s | i - | a reacted) 76 i Givasions a (er =) Cx Or —» or I ae Ss 3 | 5 sors so / 10 a Comversinw. =Bo ae veld . . ee'yy rt 7 abyay oo) yterd—= Satu: - a+ 6 —5c4D LS Asis PE) Goll 2B oy | n free De Bye Sek I ae Sg atc SPs vler sous YP Ie Asly gol Gs ed x Ahs> Mee see 248, $ IN bi Ngling eb oul, Psp San aD Fe ONY Gael pb ae pe Ns salts) Shp lal atcha ye Go ||G@toeH — << CHs Hote | a yore oe 1 Heo fo. |} Ce¥roMy —_s» Coto H | | Yiek 4 Leo Fo Yield city = ee of 2g Ket a ee | g Go é Rode, ofrenction — 21) a5r lucy afi Ub ICES de) Na ve. — S08 avs SQ -- e at aeBe sa Se f : 2 iL wih Sl bed bE) age ly UL eb | zp 9S) Bed YUEN Oe dee So | At) aud Eu” Nimi My Ji ol SLi 75° dag | aAxbRacc+d) Wea Nes eB oe 4 TD | a b © a | sl : | Y & Molemlor\y: ee lala ty | RA HIS ELD overall | | ph methanjsu 1s Ark — 5 cH & stp IT. : | ~Ate—s Dp Step hhy HUD BF St NS GALA) pe D , Holeeulftity. x SY E Sx 48 S44) 351) a : \ oF Mo le-ealelily = tare 2, b } -Soub\ 2 pow’ —> dee poeti Stoithiewedlry . | Reathion order: pA ale | ah+bB ieee : "= ee e ypworey orpty order of reattion —n=3 44 ¢ with wes peet Jen_2\ 5G With verpetl te Bs 2 = lementy y_reatfion Anon elemendtvy reaction. e ai +5, 8 —> “4 Cc Yak oe Steichomeley Woult LOX ue ye Bey por lps Elementvy | elmer PUD) Ye ee A) | | | ary. Kk c «OK @ ee . ; Yai ‘AIA 4s PIN by Wow joe CV ef) boa) eae, CPvenk e ee CS SS C.t Go. 2A4+6 sR 7 “he kG Ce AYE pee ee oe ae =(/— )h-fe S| KRG i58- ie rds Coby sty WG eZ gous |. JHU) Fer ee en | 1D Tadegrel methacl) |g) didferential mettuiel . Th hegral wees Dp First ordw yeackion sie tc i at ne Poa Dieste roles | ® me ae a 1h G \ lass = Be a 5 P08 2hy Me) wb CMM 27/3 > a) & Sane sy _ ite at & t | dt 4 aoe fly 19 —ites eat "ee be SS wo too | ‘ - | | | oH «Kt tees Ca Kt @ a im tae |™ ES ee at | aires & x a a 3 - noe} bie st —_____ order ca Seca + \aeero oe \ \ 0 ke | \ ( a £ e a ; fob oN ev Ley es an aaa Wah Wh Aa ost) teed Get ois Gee () pe) | sb Ee eae Aa\| 5 Nz, oN oe ee te oo) ng | || poe Gt pi app pte lass aioe i a ~ Cry oil) Sit 22 || I oe .| Fics. ie reathiom- Fi Om Uke 10.92 | {| eager = kt 2nd ordu-n | | | gH —> KR * || | | | = = =K& Ind order. . a eS Ce WAX DBM gs Cw pie Raa Ce eee ce. é se ~s | Ds ese = Se = eg GH) ; Hah, WA oh — aris er les) = (Gro- fa) Ce = CRo~ (Car-Ga) = CoCo 4 Ca ae ae at Inst > = See aa ake cep y x oe Tithe =k to) \ei avn. KW YD Oo JH cg — a Seas a eee Tae a =Kt GAO i. -4 R 2-3 = Kol aA +bB —>R . Geb log —__Fzhee Gld ao" 1a — X92 Gren sio. é fie : C= Go — de eu ¢ dt ; e — “ee of Ge tes Sy — = Le Ft (Xa) (E= te) aie : X x X a tery oh Fy esate) tS Ae [ dra =| ke d+ SKGheli =e) Cool SEF bea) ((-va (Nx) Eby Li xa OMe ng) << poet aa dL a IC t-xa)(ava) (=x) __CN-XA) \ A= ere . ,c oe ae a} Xs 1 Ss Xp Sie dra el Bs ee ee eto M—Xa ——— =n | xa _ Xan | fc nf ie s oe bE Ef bl ——, Ktaot +b fen © tnxa)}—+—_la HoBe |= Gut Eb HOE | ket tte) UU-XA' ni~ 19 ) Sr tees Gg opt. |e j eas Bsa i = wae oe ee ; > _ valle ioe Le Cui ef ENE 20 ral) 2S Bp ee clr oo bit LO ve, a su fed ee = 3 ane WO=Xa) = Kh. (=!) e Sw the aa aes E yw Hew) | Ae ar & ee aA+bh se a het — she -p Ke A Me Sao le = \sCoo—-F ER 0) +\ Art bs ox 0 = Coty = Uta @ GG~ 66- e oe Sys Gorka, rare 2 j == aot mn oe ee ee Hof — Le fim oe yr ae & ee ee Des byt Nase a aa esa 2 we — PD eds 307 Abra nigh? We BE ee o\s.a) —puNiess jp fer Es) se Sit oo al Sheed bog er Wn Can KSer 9 SERFS cys bg Bi! Ba Bis |- dtm 2 | edt 5 — E@-Gil= Ike ieee ea} tS tas Go—Kt niet tn ‘> a oo | Hal tee | 1 2 te EE nat litle cee elie = Ge ee s zk : ee Z ik L Plc phn ld, wos ey Bap Bids haat ee 24 tS ep et ce ee ee ee a S £ iA+SR SD t = | ae | toh ASR IS | | | PER “U1 S255 aad Goby LG adie | a Xaseves ¥ LU Er FS yee EN a ieee ee Oi Play ve) FEN 2 Ue : Os VE25 oFe u Ve. 244-8 —>R— Naa Kale Empirical Qvts Cqualin nth. ordeu. ) ae e7 si jae y ot POIPT Vs =Fy oh dla ort e te = ee ae ee Ca —fto cet f ) ohn ke eas : va | ioe tke 4-0 AD a Ln a fe Het paar Pee Gall ey A838 VA GAA oa cre ee es Ye kh Aad Per HP lng sk Cp Pw bam ee “ge Wac{ Ade Hime.oO? Os a Fig Ps Sy gp gg < pp pep a L bets ~h] oF } $4) lo Wo hati @ ln tng SSA eh Es ae bia ps DI ytell no 2 Or 28 py, Qn aes | Wil WES 5. 2—) 3 w 194 | C ee z ov eo 0 tm 09 @ n Oss0 . Abs a ie Ca ORF Kn es are ec ee Sey a Pigg vp& eg | Arts tos of total pressune dal at (on tland_voluuae = - Se. — = Vrs O= OOan te ee ae —_ E84 go egal Gh bias fe Os Pe ell Bite Eastal Seeev Ny ot adh oe CA: G Ge sles eh t a > ze pip pe FA oN) se Ne a ea t — aS _ hte .A7t- ete fmadur si Atetord—preg Fee lore hr : 5 CovsSdent valiant a ay + g —>c oe ge Wig ttle en Mg ee ees 2 ORT a 2 a ajcle | st-ovdesn is A 2. et Sy op [eee = jp df Fa a 28 _dfa = Pa_ = erat Ree Be f Z — at as ALA) bees Pdi — oo Sh te ee sail ge ee wi es = © PA pal order sntanaf Jprtal pretere ae Ls Gol amy|} Hho Nog 5 Na0y el fire tine Des 2h ee P ss | fe fy the pao weis forshordes « oa Tri Nally, only Now: mn Be eae = fa-Te F-=TNo+ 2(T— Te) ey = 2T-Th at: ad &\. La ad) 1 Kk Grn at sk (arm) ¥ 3D oe Kdt 21-Th ie Ty 1 = Ln (2th) =~ e+ SS % ~ = Ly Ci-Te) = —K4 i149 “Ho — ’ eS 2 he ao 4st evcbr Th zs a do Fe stape = K ae 20-Ty : qe cag eeBegs 54 the Freavtion lt Setond order» & TS a — sss Ic CA dt ae ata aon os Ls bee <7 8 i ages ee (2T_-T) Pas dt RT Sees eee, Soe sl {2E-Iy)* JRO Ee pred oe 24 oe J ie ie —— Te) Ko RT a toes 27-To“p, fre | t “2D/ y | Z4 | 4344 ten ue A> 3k Gz Pao fe Chto) Beet By=a2 Tals 100 mn Hey (Spee beset ernst 2s 32 fee Te ae Ro 3 I- To) fre ete-39 22RD) din 2 dT oe re => -f H+ i. LUn-T) fax fs 310-3 : lo TT ye — In To = ee oe Ty rae z | thn 21 eee — | 3% ~J ae mh So“)oe | Las os Sgt eG : = sans pressure morease OY TT- To. pete) 2 oss tl Pure A= fay = Th = # an_inert with 2 ourecley Col mert) > ez oF To f--—> £44 DP a a= Poo %, (1) Se ee He Pepa ea ee Py = FCAT) 4 (2-1) ge 4 VAs + dt a epost Aab 2 pla Pe) \ a dPoee ete Bil ae ee [st ovders 5 — fost ak fa ae ae ee ae (Cle BT) a = ty Die = AT-- 81 | fee oe PE ick oh lee - (ST. eles eek ” Ante DBVee- ST se HoT a= Ad Tees 614 eC =o-0 1 9-088 pe S34077 fp fp 9 (2 i see ee 6 | ie Scared : ogg ah a eae 6 - | a goles | g | [e Ls pes 2 saat ed) sees — ce aber = yR +cC I = ES Sa ie Se ee Is oa Bee ee oe | Gp al Ceol {| Ky | E Re a Cs a Ge + G09 ) 6 —Fatecep ee mee — kh.7 ¥- AS@ Ss _ boa ~as bt | -¥R = a = NG aCe e Spo Weegee g ~hrt fame a> Cae & — C rf —kit cf = K.Goee ia (fh a ¥ =et d& E S ae ts eee | pa wu | ee ferct—_tet @\| e-e Boe sae, Areever site: faction in ser ——e Ke—= fR G09 dx eh = kiln —G_w ——@ | Fit (Ke-1q) + pe = Kino fe dt ac |] Cer-Kt + 5 tg ie > B Go— 2. $6 | Fo-y At ket =; Ek: fo & DelaCpe Ca a eels Gy mg Ne K Kt egy . okt a — Cro tafe nel y ICa-ky e shou Auk = Goli-e [il g Kray ky [Ne / Et iS me eae 2 ke 4 ZA G=4f1-e fi | €7 © ee < ~ket shew Mt Cah, ie = ie a \ 4 Ki a> ke te =ht yb ot LEG - Ee eG Cs=Gwfi-e @° st pe Ki \ bi ket [; =o fi — | =oy ° Tempurtire dependence oh coke Snstant T. Tempra. Dohvodw— Enthy y_ =ERT _k= Ko e Greaney faster. EsBX } os Bed pr bob eee ll 9 4 ened tw les BY WAL IAS al yt 2 J 2d ges ey) on aS Git Ho Ge Chor Go— GER “A= ba ke lg cb lati logos Go~C) atA- =kirtya — IcrC Moro) | "AQs Dotell po Ke ped cd oh eee” Ga S a ; eal |- = = (Ke 2)G- 5 (Whe Go) x (we . AotGo-He _ Got (do 2 che Che ~ , Be Gwe Con (Ete —— eSTye ee ~ 4a = Cee H ae Lea) ene | o| | ~ = 2 by Cis i tee ki Cat Jone as. - bk, a ~a an ae Cl+ =). Ca~Ge) ok ee | Zlerlede) dt Ca—he CAo cA g Le Tce, Ge) 2 isi Clg) 2) o——— | | Oe en tlie | | fA Ae = (ke) + er k+l) eee “Gon Ge ; as = A-Re os | a aa3 | Liat le ae a a ds ve | ha ee OW pe ee he (ae y 7 rslet ood aes ta 60 eek tad s_e Ge a) ty ly Phd pcp fe Prue, e \ th See 7 ee 3 me Xhe ) ie ae : Ol aia ey = sbeee| 6) fy Chae sand \ phe| | | obs, ap ‘ae Complete aay sis pie Of CK tsa) 2 gn CfA) wea d\n Ca Nn able Woy 35), Wy G9) = | Ue LZ pel ae le LP preSyp dds 1) Complete anady sis. | 3) Partial analy ois :— | Pe oie pe y a) Medboel iSolation b) initial rade Synahe a Hethod.. | c) least d) Excess tn ta4) -Yn =k (aL 4 hie Di eupé ra K p ise pes Ge mo cae c — ah JX pe dP he by Ca ae. i Wind Ginpiele anelysy Cy, pM) ot Lew \@ ye Gh a) GH) as Ay) cytes) é aed) ae Bile co Ske Was AAS; alo ak fetes ood mrae8R = 1c Gog" Prd analysis. stay ee Parte asa is) | Rachel, av aly sigs. : Re S ple) up ae bd ew polly Kak Ce 7G. iis ==) ran Lf 5 pl Bpht | @BC - | -3- |) Method ef iSolation ek ae ye FO dw \ | Sevting with only trenchant A, lng aide Ay) the @ntd ration f R XS b eeoiene: apa the! |} above egy: C1) he comed = | ee eee me Ti ky Ca mp) = pt dn G eth: ki etd a pet «. I | iit ideas 2 In Ie, Int | Similarly , SAarding Width pure R ond S-- end ending, befor Ale Cone AB Le lo mes appre Unde. | of rae | | = =k (ACs 4 A The Cone. 7 RD tne of s | S dG a eee re [eee ase | *, Ay. | [we stack Ba agatha Wy? ce => fy In Gy “eB \ dee. a UE) } SS eae e ZA tb eg a i) Sn by ; * ——— | Yap se eo I ey e x See a) FS is hye PDan dak In Gy ie @ Series of Ca. Versus 1 Yons \g made or l@ AwWerent ford cmoposi tons ( dillerent Cao’, ancl each (awd 3 evteapalated do We Ved Ma Condidver| to Qud Vel hte aeenchiin- Race okey o4 nacdion TAs i ren A nthyt Ape gy e a hak ta eee Gyy e Vn =t ro) we | ont l om Std me po (ew) Wy peeps sey Lo ley Pe« =ki(a C { —1bo Cae Bo 53 o.| o-} 2-¥ o-U 02 7-5. 0-4 O25 a4 Oy mF bof (+B) =k | Jesu aie cae ~ Sef dete x -ta = te @ tp a. =k Ce oly r x 2522 Ye &) Ceo” P B \ Set 1 Cay= Ceo { Stk 2 (Cao+ Bo Fer Set f Gaz ay ||C ae) SN eas a = i | =m aK Ga pe ixbs 29s iin ier x ey" oe - l=lay 2 ev) ee | =taj2 wh ees ly In| ) ae ene wl Gua | , | =") \at Set lots nee ——> \ Gao) a ge | Zz Sg ae patk@ Puul) 2s Kk uy fae WW [to Media Toth Squade, as es oe et \wle 4 ala Ga) al 9) Qs +A, xt +O, XX LY. ye x, ee Jub 2 mtd sfc Bred || | Oo wy CoD Us jessMeta ol ayes — ee - 28 = kG Ce ——o ee Keupiny in a ged OxXte45 oft We Componentes other (han athe, ~ Se one fo be examined gat @|—4%--G >>: 3% z ae ale Ca In A 1% 4 GD & Me eo a 0. - i = Ces -F\- | j i Pabst ae jane Ss ORL aA ai Baken Reactoy> (Guhenk pase) | Nodes 2h—rk eLbre | Hirai Constavk _Wolume qa ek pie 4\ | Cas Go Ci. Xa) 3& __ ta, pee 2 SN | | - dhe —Godxp | | e | Noviakle_Volwwt wit Cas Cai X8) ve Exe expat Geers cee £ expansivldy 54H Sola VER KAZ aa c ica Che aXA Se tel Uskate JED > waa | "tha Xn dx (1 +faxn)! de 4. pr tiring) + ~(ba-» ene [ C'# kn tn )* | ate. tap (tate Ye — hg 5 “Sn (aka)? e a = & ss ) (inka xa)” (14 Saka)? ¢ : one ca, PUES | 3Xa. | - (IF tAKaye \e Sa —_ Rapausivils | 2A —> TR eh Se, SON e le2 | Z Lt | Te gaia ae ape A—»4R tne Mal = 3 SA —>38 Daa ou | 5 jJA— 49 420/ iner}. @ ihe (ey Jet ie, “ae : | | our et Cle gh 42k 5 spe oe EAE a & Ee P\ Pus Hiss obey pp eT ated 9 C18) of | Feed eenate on deurease — pe7 ite le Pertert Clainge iy valine = V=Ve rlvo/, Vp s value ak aay +- No le [Ads Ge Ge tay C70)(nm Livin ie ae -Ya-s oe 2k - dh= Go dXp \+pxXa Go dyp =o K Vaha Xa f axe = at dy > ata xa ee ™ \ | ae ee a [1+ fo Kel ke i j @ | Xn] ae t Ae In (14Cn Yay fn = lek ne : wy vo fujm ie eee fol Sdbes yr alka Fea Xan | oe 2 4 dol 1~ #0) a |_tyama__* Chaaay Ska = edt nA, —basff= xa} =kt hone he PEN | Pncirdens nage Mabeidl , XA math Valent.= 95 a i oie JA __» RA rwoemsiiensy 4 AWG —sK bo 24 ode bt tma2 a, dun = dXp OAs ber fa Ge TA Le teak a fda Lom, du s-F lard aig fa uw : ith 4 ie dt = OR da kno de Sl Pa ae ee (pet Tahu =k woteet ee eee ees ==k (mot si iG de k (aot nace Xp pooled: va) = kot i. [ty fa) —» Sabo fiche) =F tee y fa ta (1a) ot SUPE Ya = Fey | | U-~Xa i ae Int or AM- Oy es Cheng tn ve leenne | Vo d= omy LAR. 2az(‘=2) OF 2 -o-Y4 = (are a Sie, - be[1- oot) -K(Y) \ J =D K = 02g we _—_— L —fab Re Pwr lA) BV oe b> 4 ie Soe vo ° v P= tat C2 143 Je & t-6-"' . 66 I iY Senile Ly -4 | ale fi s |= IX Ca) = K = 0-4) wed oS ASR. Zero arden. ee Lem ovdenr dt {l Go- (a ~ ict cae ee e/a ' fa> fro -2,(1 TT) fata = &(1-Th) Pir Pe a Les-"] RE K Ms75 ic | ee) yarinble vidamnt + | Sevy ~ or div -35>: ConStunt —voluer 2 chai | roa QA —aR+25 | Bo eet 5 g a oe | = A eer | | Ses | }/ e- fro SCT} daze Bat | Pees To | Pes 3N0-211 | Tle 2) Te 4 T]o = ty Fas it) = 2.0u) = on I ea eee od Nae > Ce eee eT a \ a Ler | Be a | SS Gni~— C= Got~ va) Ea > Aro C1 xa} = epee eo? Ch 1 “t) | fae oe Viertalole 5s AV Me - ete * + th A clears = S$ 2 TAG ey =p t :sry oof Hade Arabisis of omplele i! A real tion Tar fab om 4 4 uth et rie hae z \ vas eB "Method 4 isglabge hed Syrares ‘ ake. 4 dees} “ f de rate ¥ ree e wD) An As siy ef comple ‘ e Mh KG) = Re aie ait ° . Me « (-19) a lee m3 -ta al Sy ae : x f{cak ‘ J ¢ ae i 2 eee : as pe pat ote |: oo CA 4 Ayes SS. Gv je Pei Vase ee g boy (fa}= bg k+ 5 oA aa 6st rere ttetoen bes rae log k 705 GyoN Temperedure ligunalind ay ree Gngfont ~é i Ka - Arrhentas “a kK =k, ee & zeyl E Inks Inke = >) slepes- ree Rajat Gntent Take ® 2 Es activaton, energy - } Pre BAe Pap ee PS s A » fees jez RC OMT in ae tea ; CSc a e qo Qs/ shee? D : ou aar ip) ee ot EZR. meee ees | * a Een i ha ee hoe gc Sei, es ne zy oY 43 ee e ear: ; eopat Z3y © = -tin] mp E ‘ Hi or ai oh ANi UBD Aw yobs Goth 5), E \y (-¥9) Lett 2\e2e “Taffyen tial Hebe dls «f- Daly staf lala Hes 2 WP pty dy Pe) oi cad 1) Gaplele avitysid 4) Partial analysis 2 — | *7 a) Mellvel Igolation b) intliad vat C) Least Sqanane d) | Excess Hethad z Sloiie Hi { Sif 0.00 0) “h] O60 0 69 { 5 ~—Va= k Ca Cot, Lot 73 camplele aulyiy Fide CK one » aly Gta) = Marr t \y Ca| = oO ey ae Bee -1A 2 K Ri “Abide ye pes ae + ~ SS XY pea ae c oe a ¥* i ae eS eet a « > ON fe ed aN ale veg) ee | - = Z aay le Zea) ar ” dd A ie | at oe sie pred Gimp ete ity Ch GM ot Mee eA gi a a SLED) te GN ys ¢ Es HS Nb gaslbeas: oie LANNY SAN 3 Arb. —3 C49 Ges ZK haa : Pa dod aradysis. 3s) (350 By Aik te yt bid a) Tectia. analy sigs. q 2s pHs . pM ue Je bd j NK ~ \| ol Fi | uae) 2 Kyln — Kr CQ Cy i @ Hicltiaet ok (6 cf CK ph iPeZlhec € a) ttethod of isoloction aA Lela (rape dik, ceo Ca ee Myce ea pas Tian Veber Ge Gat 4 A be wes ay yre Ciable . 0 Ev en a C4 Gs 4, fh Gone af BR D> Gus of gS. v \ AGA a ar Kt G In(—Ya) et ae | ue Siaed So y/ Ceane : Inc dees co dt wie), : tre Wnt me) Dy bite (GP UeCip tee kc ‘ i) hee We Wye p vealed A, ending he Cary befor Siu tiny Wh om | : fh ; [the Gnetrates af R&S becomes appreciable, thel above egy Uy) becomes a ee ~ ABS i en ai fies Samoa bey SNer ting Wi yur & ork S md tdi, aay o25- | Jib) Hetheel +f initia Here a Series of CA Vevsis Lo vans [dierent fad aempotitiens ( different Cro’) ) ancl AAW (un VS ey Wo palate Va Whe Se Niel cond Nara oe i fp Qnd Vy tb ale rection wi ak TAL of veo Von | —Vho)\ run | 7 ' tun 4] we obdawn Cho 0 0 0 0 DUN —Vike Adelie EE Sessler \qc ata) wy A]. = 3 - * ee (aa gy rh Pd po yor Ck ow ) AW ep e US Ape piles 3 Gs Me 93 nH ( ~ Yaz an (A | a fetes Loa lee Co see lve aa In oy \s made PexPay a+) Ty Oe on eS 0:4 0 2 11 Oy of Qs (416) ~1Ae k, a Ke 4y fen = In -YA for Sof net pe Vy Wik uw aed = K lp Cg 4 Seid Gy = (ey 4 Bed 2 (Now Wo For Sel 1 Caps Cay Ca aie = Syrah |aN Mein ( ow) ) Gy eyel) 7 = Ke aj (ete ee valhiraye eh a Oo el Jtdo ye é osad (eo) He thad ad exces Kee Ae =a fh pdG ok Ge CR pee sts dt 4 Keeping MD Overd CxCeKs alt Whe Components oder 0 ie ope, dhe ont 40 be examined zeeVe = Z- | . ee Pey- The fontorring date gives Kinedics fer te How reachim: at aed Oc: 4 Se Or ei ac de ia? st {Gee 4 oe ; e | © o-0014 o-0017 lve 145 | 8 (€) 00044 oot 1-00 BS | @ e-eole 0-005 Y leoo 31-5 GC) ov0ll @o00lt - 0. ais rete law for the venther ond whet whet is the is he Value of the ade constont . : E o Sold DO en Cen eae dt ae é « ¢ bas x! =k [o-v019) Co mn boo) 35 410" = kCo-o0sy)® Coot)? Cio) ——_ @) es gtd' = K Co -c0lt” Co-cnm)F .Ct-c0d® ——f} BiseeiBY SIE Goel) “Caeariret et) 4 + + a cividiy O/@ ¢-(Q) She wey 2a ys bah = pet | 4 O/1@ $ s(ey® = we-! | Atel Goa KG! Cour dt x find mM Subst oe oUn ae 1S xs lobe g? = t. alne ee Genet Ce) | oe oe aS 7 oval ed ey = Bs | 4 —Gonidnat — Yak ly eg is Cad Cp ote Gujlend =¥A = je-Co nae ae ous je Boge Gets BO Sie =e ein a “VA tes al Ee eae ae s ee Pl ee ee ee a Gee ES Scr 6 ok ate ee SS 5 — : ter f é Ss! (3) A—— Cony bonne pa ae RG fs ais eu oi a x el % Py ATs wlGe o 3 0555 Ca el Ge Oh on gl OR 0. fo os yo «8 a paige ae sey eae Da pele Pie ye = || cpe 63 O2~ a => k&tb =¥. eane G Cee Ne g \ ( RY ) oo (Ss aa fA es cay a fon @IO——e GiB ai Ts Gd tw Gre = mIn(Zy) xt{té- Art —> R. CA. vA sin 2 _o4¥—_of Oo oe — eTS— Ce Be _ pom OAO aoe —p ine - sie: 3S b-F a of {la A) nfily+ p ne 2 —_{i) Al ane oa mm) Alain S64) open e as oe Cg—— (i) ie oe, AF foo AOD. ge UsesA AES * 5 es K TE Oven gels ea Q Big SO oe 9. ie Cue Cit ‘ a x &)Peis —— rk —op - oS eg ner — a os NO = ee \w SS e ae ee Se os a ae a ee eee foe = Beto TE a — de Uwe oS ion Jake Le as 5 a = a et = = Suse S 6. a oe 3 ax Snenh = = = = = fa ! (a = : oe EN er anne — al = : oR Axe ) Se ee Bem = i. oo B : mew ee “ae oh 0-037 (6204277) oSCur | ed Y+ ia The sedersible decomposition of.a rage A fyin Soliton is Ghalyred by a matrat B. y TL. me hulf— ampletion ef th batch nackion tas delervinl by Vary te intel GuteDrabe— a Aad B. From Abe vesutt estimate . (4) The oer af reaction iy respect to A (b) he le ordey a reaChon With vespecd fo go 1 (OO thy yah | Gri dant. . \| ” 4 7 Bait emit! Pen beg o-cel "2-0 peo o-oob (feo Zep 2-004 4-8 2-0 O-0e4 as | A | Selon wa 4% Se atef) dt * ww | fst e (4 oR yy b * - , yo) Be @ us? C feo Be a ee ays om Ws \ \ 2 wf :B ane Ea 6 ~ <8 bi Gilt, Gy te akla-i)teye n ‘ i-4 4, y GG) — (cay ) = ke-1) cal t* pay wy | : FL, Slit, ikea is KCa-\) Ce t* | a \- 1 eee peal (ne ei of Meat? a | ge q Wy ny 5 (mes (as # tu) Oka) 7 cB) Spon Bae rsssn of spate frm O30 dh aie hose a5) 5 = => asl a ob. The reaction 11 184 orden wilh respect be Avand jt order with retpect fe B \, Ie ae de aS ieG@ ad Ga, Ye : Gh oe =k Ce ot lle < Ken oP In 2 fy 2 * aR RE ke kG me B oo) . e Heh lb pe cle Abt deol A bia! 7 if =a° ARH siable volume Bodeh Reacher (Gulet = x gA—eik &. é D Cons hank lune fos ek : r ” ysee Pea panne ae te AG. 2 me) eee sey #, AaB bas Cxpmsive'y poash pw she St axa ae anpte | "thy Bn os ( tt taxa)? = Pee Sie s= (11 (axa) x bn-%eg) } aka [ Cree | Fi se wane na 2 Go, (EMMI D eto) =, fm nlaye ft pdfs | (Ma Xap : ® cd. tae) el = by betta heres fake)? { dy 2a Gas {ie (+ fn) jo i Crt AK nye ' ta Cxpansivily- 2A = 2k ® ho Sa 1SA—=ay4R fas wok =5 5A 58 da IA — 4 F Soe eee he fA te 2 of tess ued do OA ta. Verund werrate ot deca cate [Ported Charge la usta poe vt tinea tay tb: Nea Valance ook d= 9 ~(v2 Ne (Ar baxa) | \\o - Tash eyer pele fosoe Tae tay Cerny » Bi.ea —lane 2k Srvor bur pXe ce Ae hl . kp Xe ( ax Ji thee Vax a e Mba [isdaxn | at ke ea2. = peed = Pare oi oh =f bg 1-40 ltée d : (“bk Sey ee OR EE, sees by ii tig ee 3 first ardler (heme Wauaple pet nentsfond order peacon 2A. 4A +e ~ . -Yas Fw aba ay dee 4 an (iw) ducry @odd-Lob dee -Cite)- ty bu sek eet in e safe | ba Inu)- Fk (not A ynty noe Xp ft ‘ ae xa)) = Fa le Rar dy (as dp (lyin) p Sql (t-xa) = k ley (| kA See RA fa ta (tt Xa) of Orlel Xa ny thy | \ 2 COAKgg Boe ts 2nd. or Au. oN O82 ca Chang te valnaws {= 3 eiy ah». ta-(22) a2 2-0 aV)- sah ee ~ fi Gy akc = A [ie e2 aikils) -04 dl - TS eledgi) BS eT bt iN“wo i = A—s) x Zev ordayy- | i * k Qe erdin ‘ | Gee Wud | fo BIL NAT IA) ei Vie il «i la tho - 4,018 te) +i (1-7). “BN 3 i" tool i ism Gy ve Gs RT KG) 2 yp ser)Boe Consdad! ° Vokine Ioeeiatekecicn \| ao Pe | , Woks {| A” wm By | (2 a 4 fre fe - ae (1%) dat) Bal Paes Te Pre sMy— 21] Te = 1 ete <0y Fa = 30) = 20-44) a Ae ed ee ee Oe K (3) ore A. Ss FE | CAs (ee a) Gre Vi] peed 0-4) ) Vortabole ( 5h) ¢ dle 40 tn AC xa) =k Foe Vt : Bere oy ee ea Bl ie olds Lee) | 7 ahee Kinckies of homoge yercdlnny yw Anse auction? | Rog Wmyprtint aspect of design ond anglais af chisel reader is th stndy Athy yah, oh! shansical rractions Astley Place + each omtadieg wit by corvied och becides ho Abermall cued | Blamitath i! wrsapecok al | Ta chiwical reachlon lenarnteying 1 TL Kindcs ghadg Will bes concentratid gin the shevtlopmesd -t cnevarcad vate squakion. in wh form i ov Wa Er Gote oh Sesign. i winwldi ih Chemical Eva. faction kinekles! Aw Mae Se ematleste Air Ta lelthlp MRERTE awowds Sor trample C401 1S) Cog | aba ta bivsting ranclawk, 15 the sreactamt| thah ib pees tat Co jer 120 ym Sc Jeo Moles is toad lata Brorchrouey ic \ aE Sony Co ig the Himiding reattawk e ¢ sion ve the Reaction of the Led ov Sima makevial wm the Ceeds tud.\e conver Led into pedacke 4ee C +02 — > S02 e Hbtes 10 7770 moles S moles . C which rected LF is The Conversion = = S05 © feed jam Yield + isthe weight Cass. ov moles) of tinal product divided by the weight (wags. or moles) a} wilinl vercdadt either Rech or Onsumed ex consibey Mme teacRery + CzKs on CHg cho +He me a ea Hy te Heo = @ led @} = motes af Gite ott be fed 40 the veatdor which a dodal of CX). mole react. to-give Cy) moles aidthey deand (Z)-mptes af ethylene. thems — —Tatal conversion = 1 Sield =f aldehyde = AIG ay: yx. ; yield of ethelyne = P/P. ov Bk. Rote. reaction mage eect Ap @ Te lecthe rote, of decrensing of the conc...of | awg “yen cdaich or Wc valttof increasing. af Ake Conc. | ade anay ro duck: of Mae vee Mom —- considey He ‘yeaclloy, ofA, b%® —y»,eC + ae wee rab. of change of A == C2Dpa A226 as tae. — of change af % = Se i ave i tre. of of ee ae \ Nese af change of D = SOA dNea _y dhe _ td Ma Bee ae Se ae _ wales ef A which afPOr by ection Catan) Cami Hoey y aCa) feat a Nas GU > ee- 4 =o Rae —conctonr volume is Se é -¥ dla — ap 4 Nae" 5 2 Holeculavtd: Te ig ARE Mambo ef molectlam rea cline, aw AE Vall cdeeruninine, SAP (the slowest step jy ee any | i For txample, 2848 —> C+D ———overallh__ | A +8... c+ —__ stip A +4€ —»D__¢#p Can) “ Hatecutnily of Sath vencdion Reacti wm ordev- : = Consider Nine Serorwy ate af eB SECEAD Cas) oN gBea. i ean The. rats cenversion Sf CA) pec unit vatume of mixture 7 $y io a—-f Sagan save —dNa 2 KG. ar ne Cp x: reaction onder with respect to (A) f->—feaction erokr with respect te (B) n= aX+fh + overall reaction order Ka—Reathion onstaut. Elementary ancl Nonelementary reactions , e Elementury reactions : Reactons in which the ial epurtion corresponds to the a Sdoichiomerrig, equation For example. RB eo eee mek & Ss elementary. Beh 2A SC | ; f & = =k G& -Clementary. 4 ArB—wl , s oh 2 KG Ce chmewiry Non elemenhary reations s Reactions Wn-which there ig wo Coftespemdence betwety stoichiomedry. awd ie Ga ee ee a Bee ce: => ANB Rt Ca) 26Ves : dtl LBal” Ni hl leet tia » kee + Werd/Ce] ds Sinale_onh Marple Reactions When jo single Stoichiometric Cyuaion and single vale equation ave chosen to represent the progress e] the veaction .we have a single TeAchion, Sx A+2B —+f wtp Ey Cg Whin more than one stoichiomedric equation is used to represeak the ovserved changes , then more than ¢ KiaelicOxpression 5 neeeled te feller the Chats composidion o'f at tle reaition camponwts, and We Mave nuitiple reactions. : 1 Ee Pea Chow. sa S-eries A= pR—>S- f dle y, Reaction in paralle/ Amzek Sis} CV aes ee Mixed Reaction py B —>R——2_-Hixeal- as Rr B SS ot ALS inseries for ARs in paralhl for B | Represe Reaction Rat consider he reaction me A ige Kea le Rate equation | () fer La pressing a tAlee We May. use. asiy. “case equivalent tothe ac os Such aS. pardiol is Dae ee 53pressunces og kK BR he pope ale) boas) | ald» shu fii pid. ea) St 2 Bie II Zep ype bs ply fe42- 2 Ege ols 1 (Q.- Elementary eepos.riaChions ade often_represeaded by an eg uations Shoising both the molecularly aud th cati_constant . ius i Brg 2A 52k. Go ee See Sa tn et eG reaching tate —.— Coa ZS peo lth Bpybr odes abla) ZalS- 5550) ahs) QUMy 25a 3 HA 8 Ki Uvot proper J — f= THD Ev Gs necessary to specly the componarck | veactivk bo which ae rate Constant Is _reffe Ex- consider the rete senate reaction Bp ees s 272 : kK, aD 2 2 = Ey, -BCd wn ae rly 2 ks Cp : if : 8 La ey Folletoigg the cent. of one of the component: 2—by following Abe change in Some. phy sied—proper lies suchas electrical concluctivity. sinh ge ty forewing tle total pressure in a wonsdant volun e ees Be aS 9 tis en pits Ba in Constend vessar veaclic Cens® aoe ve * Meted ee ae a yt Tatenyal method - X Aa lp) “- SAlerentiod method x Aco, EW) A a WGiteytl Rake egutedion Poseeagiale Reaski se West ovder ApWord reaction o “Une feachion — Aaa gtoduct is _aumwole lay | ae Reiword ceaction has a Guctavk— Volume. ee gee Rik so Sue ata fay ROUSE wenger at at [ x ae i are ORE frat In Ae akt }wn Seem ef Xp o Ss rea ea teeta See oe Tot es This the time neigh bev he Come ofthe reaclant 0-diop to—one—half. ofits atijmal vadve.___ Bre Weis She eldih Bad Sele i Bay = UChr) FALE Bo 5d 2 econth (ac Sa ‘The taclion A+B es 1s -bimole euded = ugp ¢ nd Reorder reactan with a vat epuaton expresiel by —we= an pera Cees From — hess — balance: C= (po-— Cop p— ca) i Cay “6? Bop fotca : 28 "90 y oe ae tka Cons)_ (ara) +ny | Sanity) wy , = Vine ShS SS is it we oR SAowd oe 6 Cone = a Pa ee = Sno (Car) es NS SA CERO SRCaSA0). Sao ree ad sole Py (Cas Calas) ——— ee A - Cae CBo Xs Ce, Coo} t \ L c Nae eae a feo. Cart Cas ooo s -K Cao Ci=%y) (M=xa) di, (die lear Clea ya) @a [5 Contnns i i 4 g ACH Xa)+6C1-Xa) Ht (i-34) (M-¥R) I-A MAXA ()~ ¥0)(M-xa) = a Xe anlar In (rt=Xa) ] me He Got (MD. Ih (NO) _ ea, E CM=0 ei bere ie aersi ple 5 = Che) + [acces =K&,(H-t | bcanzicgo. ahtee—s RK ee tet, Css tig bens pif de We EGY Let Dome Che bare i pe sy eed est = pe% BN Gae sds hee bape eae hig nln en Ong The Juattan is of 20 ordi’ saluna tar pti af. ceachen | e —is-“ndepenslond—af Ha Coro be afte ey oe I gue es " Se ete At | _H Oo . Cag a bag —__— Se ee ae geeld iY ee ce aie ye (ENO OL Ee ose eee | a4g+D—> prduct Mad Feast t — Ae = Kate ty Au See oS 4 Bo ol eS as (Goes) Gor)__-* 60 G00) gen bao) 8 (Sea es \ Ni Sbe See Po eG) a iota ei = ee fe 3 Ee wa Mea Te =As Ca Lg | 2tao — Ceo) CCe0 Ca) f + : “ _2lao — ho) CCb0-G) |, ‘see = (Lee —Gee) eb cm; oe WS xe AO HL of th OF der lise i EEG aoe Aten Fo find th value of » atreil 2 exo solulir— should re mols ciel Hho esived. ee that “| whith minimita i variable Ks [ies VY = tne Naa as Ms i eed pees ~~ te Sap = a | ity ele, eco oe elie) a as @-nk vi Se eae1 ipo yee ye ri) L229 OF 0 Shp =G-n) 5, Nn kay, Por ND Cori teS0 inetemtes crth jntdtaed jnhielh Come a Agen ds. en Peta a et ae Gazac\n Cay fenet os On ol Gp ap e <> ohn \ at Con pa eae or = (ae); g Gude (Ca, Coy), ae. WE elem) In {S600 ees era Tee Spe age Ea: elle! Liz L eiP Y , ee. (FEV oy Ne 3 The ae (fe time af a Oa order veattion Q— f No wim. Wha percent of A_Yemens Tagter the: aI l- storder: reachion : tne _ 2-643. Ke Ge 2 00693 x. x, “Qi Cos Ix6 A 0+9643) (Ix6e) Be Ae tail ck Fe eet 1S h eat Af. remiing On The showering dake were eb Veinad oR hee de ef bydrotyn e 4 th eucrpst. tn 0-088 mote tik Hel aqatous. Meplubion ai ast +/min, 4.62 5460 Gave MEd 2aNF Saad ae 965 $05 Wo Tt 52-8 ee what is dle ord of the reaction wi th respect sucrose nd Le re Of the rele eonstant Ko soluban . Sag pose the riachion is, a order. 1 f -Kt ss n B Shy) e \w ss = 1K a c ' R B ai het tlinin § ae. K CEI ) wank 106965 aczexio3 50-6 0: B03 Br x16 93018 on S620 3 eg o-S4/ 367 xi? 294-3 0-323 373 x10 shy onl 292x167 fa Bk ia early Gunsteak ap the reaction in Porter Sy Besta xte® Vmin (ovelage valde) @ Kye WR we “Ae os aba oh de te Ro aee He HE to Hat ak 506 C ete ae detoupesition f 135 min. Ben gthad inirtcal PERE Qs has oohath- like of ef HTais o-} atm ond 19-5 min when Ale pressure '5 L atm: a shew that Ue reaction is second order bp wheal ea value 1 the. rate constant fom ae e eo) o« DOGG, ve an Nee see 4) + a eC a 2 in onbfser Soukow > Ql —> He td a) Assume Ale rewCion js Seeond onder uP We Lae? 2h) de» tee ole ( ene Sante j pics 2} Ran iG) 35 o-\ 0 00\G602, ® \s-5 vo 2: 015603 \ \ ~ tee kee? KE From Ran ® Ke Ve pte ee G8” (35 woetsios) t = 0-074) vow & \ “Ok. se Tye OE potty melt VBS (015605) Renee since Abe vale of KOS constant fn ra $48: Tums» then Abe Asiarenp tion Av de reachiory Ih 34 order is rl t 2 idRok eet ere a6 oot 7 e « oh. (5) fo =Kh a Sioelzs ao See et bnife = 2 O19 si Se web (STS) = 0 001218 bar Se. & K* pr” 908 e;._ 80906 ° yi 2 o aq4~ (aa dt, oe Jar- «dy 0.079) ——— By Ke mel sec y G-o2enic? molec bk 2 As = 1.313 15° ~Se 21.313 x10 Cwr7sec- a a G4 Oye Q4e The reaction between propionaldehyde. amet hydrocyanis has been Studked at 25 - Tn acer kane apucons | solydebn ga abe cenent tons yardous times were as Hellas z Bo UM 4 > pole We sth BF (Sigucd Mae v “ wy fob 00930" D026 065 ay & chy cre £1 mel bs 5 : eGa 00566 po ge 0406 = mehee P0224 je.200 wi i eer of I tin vl of He Consdante K ‘ A Dolton | aS _— HEN + Hye CHa SR wee iM : A+t8® — >R i a pw be Assume the reaction is seund order eS eieen! ct > nbd a lp de am alow Sy ea ane Ut, Kod ei aes Ned Kee et! In (Be 8) EA ew fo- Ao Hg WSs) Ro ~ Bo RA pbs Oy 2 oh ope Y aoe ide (o-0s95) ind Ao te 2-49) Hered <2:le “7: 7 F782 S3 - ) gg Pied Be ocSbb— O°0Y82 (3.79) ¢ 0566 = O0bSF 28-533 C e M4Few Pan SS ea om Q "a.065 E (0-051 LA ee Let i eg | ee ; in [Sa eh ate me * eges ; kel ee ty rac he 5353 Loop -ootsy 070VG8.C0:/002..2. teint @ 1 ' 2065760065) Ke | = 063 Blt | anp-0- 065? e DS fice 206St (2:0 706. dj ea6s Oe hy Garop | ebz8e mal Min oedee ote) oa ae nee og Oda Im Sg aay ergs bine / he vabae of je ip nearly Gasdane e => phe reactor ts Second order Me” 0-109 — Qh at is Kz o 6) AE. (ong vel]. Mat he gen ee auld 2 Am, Bu Bs ep) o. As gee Be fe pe Be ¥ . : CN poe cry he C8 38) oe ee i (re-Bo) Ss dls JY Ae 2A co Fr sO fer ok esi ae s Ac = ol0F e Fy oF Bor 0066 shpe= 0-028 <= Figes Pi $i . KCe-Be) =9:0238 : en Ka 2088 206] ee Ht igop (eAaaE ee om Fig h > Aen ole en ‘3 Boe 0-066 mo! jut [BB] = et ie L(gn- 09) ie i so ier ae aod. (yo- oe BES Bs aoe 20028 = k(Ar-60) onae ats = oe K (Ao- ae efsg0 6b kanés) # Cras eQs: The paction eta Oe, € Os WeO+CH,CH is of second orders and K yy ec. fs 34.1 Lfmel-, ein, aqueous solition is o-eeH mol (UL Incnibipethane al jn Neo. How long will ik take for ao'f of to react ? ances bnel o ® Mee nitrertlane, cs HEM, Mee ee nd 2 order Selebeie "Bo C+R Kee ag, (, B BC) Aaz o-voy, od , WF 3t | Kaine] = Ab (i-X,) = o-o04 lino 4) =" +000 e905 —0- 0036 = 0-001 Bz Bo Mexe = V a yee / m % 00004 (0-005) e oo aq t= calls coke | = 1024-5 e S00y,0005,. 2004 (2:00!) de > t= 26-3 min. ae ae A silation of AH winged withan equal voli of Slaton ay Vs Sentaining He Same rawabers of weles, tine Ma reactive A+B 6 occurs At An end of 4 he Hos 75 /. veattes How much of A will be Left vnvearteol, of Hhs.end +} 2 the mh is (a) first orderin A ond zero bide i” Bs e ie eS, in both A ancl Bs and (el: ‘ere othe pet A oir ZA Tes a7 Bee ogee Nlaee ies _solubor 201 glen ins a ey ae wt Gud “w AtB—>e - fhe wee! 2 KA aL oraer racton a7 Xt _ Are fo : Y Afléc tele — Xare Te 4 eng 210.452 0775 ob aK hee : wy o-aseer => Ka aoe We N «4 ou Satter <2 be Be cht nS 2625-~ fi B alos! 4 6.25h TeasFipsk eoreiar im oth A, ‘ ’ = a a kae » genes = VE Box Ae eee Kt= Bo Ao KAgt = Be- ot = \ at fis bem 2 [0 FTO Ae but Bs bm qraoes =p Bd de KAI) = 4-18 Ue o> KK Ae=3 i ‘ “ter Bhn Ao t = 4-! Re ay =, Boo !42 Pivot, = 14-27. Ao ce) erp Bren BC both. 3A A+B—-c¢ i= ek ar Ale Pa let S. RAGE : kof Ae* Ae p the © Aecery aloe 78 # O72 peoes, =e 0 K so-gs After a he = 2 2682) = 0 #52) Ab et lS Ae Ae Len nSe-05 The matiriel finshud befor vs ahr, dad pa oo) (SF £03 eh 1s ‘Dus pile Bday A gob AoA sist j-ie Kt pew Ae leotht>. tals hyn (BO min) Whin JA=oel. Qt Mydrogen peroxide rencks with Kniosutt att ts conemttian in slightly acd@ solukton ois {ovows 17 20, «25,025 2h» 2haG + 54 One The reaction rate is independent of dle hy concentYabon Mike pH range 4 te 6.7 date were obtdmed ak 25% and puss- concanrtattens : [moa\~ 0-036 mol &'; [s.o3 pees ig 36 43 » $2 10.3 6-18 416 3-13 ta Whok is the oder of ta, reaction © (oe) Ww hak ig Ree Kate constant e Solutrg te Had, B a Assume the maction 1% a= + -2 + 25205 + 2H —> RH20 + 8,0 R 8 second order f ‘ ‘ 1c Be et Cae |= Note bere A is the lime tings ractands: Bz Bo — (reacted) ee ‘ ok B =Be - LAe-A —® : = 0.03045 mel At talon SF Bx 01036 \ Lenszou~ velesh 2 O30RF 5 Day aed Be € (nia) pcenot C') Brot 1h) K 6 Kies tien) 16 09103 iy sor OROES es are: out 36 Sosa ena ae + ee 43 ooo Hib 0-0 2188 Se 2-00 S13 e 02718 \e-596 wg By 0036 (103 J Foy Run Noki) amit 0 en Soe ane k= Daan (caso §@ O42. aad K eC ae aby, oe ; sods! old 2 Kai06!2 Lit /mol-min average valine), * &sion of Mikes tant temperate (he veaction to We compres onal Ao the Wikial OF wing resalks are Ve vw is oind t Yoo Lime weak tes Wg) 13 Voversedy pcoperh te on Varying the Comp: He foto 4) 50. @ ianiad ce are CV A TAG) = Bud a) 944 vie B60, 348 tu, (8) 1530 a PPedace the order of fle renter. @) The Junction pate constant (a nel» ch) The activa energy ee life since ae half a tle bites presuee. f Ae EEE Second werden CacHan:, # wy At ene A eK eqa wall e244." eae p. Pa). a aqan fe oa #60 21820 02 eer : eS leap Cand 2th). ee ener Vo gceae 4 | AQ ata BOF) al from ee ee a { wore SE Da ght? WeBq qi lego “Sl 1930. ewgxd" — g.qui0" $ (082.14 3-3 xe 4 ee ie es 6 a @= 62 (-8) From Fig. Slope = ———_ (5-10) x16 * 4 = -3o,ov0 (si 13 lout Me slopes —Fa & De x 0 Exe 2 (slope) 2-8-3119 000) = Bhaxid Swol.i i wt) rake equator Jon wyeaichion ue dhe expressed “fev hale vyhe Derwe Be 4 L ordevrs De a such a PMC On. = 152 Bs solubon af Me - a sikh -dfA eKdt AY pitdk e-kdt in ar=-§ a 1 VX When t= *n2 3 fo Wy ex) * _(ayt=-4 8 due a fake ye = ik ue eV 2 3K bn A, C ve { ay (47-%) eel K eR ee = -y@4 appwximuts\ 5% ~ vohune are remvel is . (& Lion of Maotl. Cabintale Abe ® sing Cupretebentae ater 27 4546, ve 2 oH 39-9) er aT al Fi Firse-order reattidn mp In Stayt > pe tee = AL @ 8 R= Ro (Ao-A) O bh, leh ‘ lage mets oe ae EF a, ae we : / e jst! be RLY, fA gee . R-mVv. ———@® [pk ; > onstant * Ph | from@® A= RorM-R on bt | fio 2 s ke “Ror Qe oo t t At t= 00 Ee Rs RorAon 3t-1m At t=o A => R= Rothonf => R= Bo = 25-19 77 oes extrapotathgn bs < % PorRo= 39.1 os 26.79m => Kos 39-1 —25-79m = 13-3) 7 freG@> flsherhy “Ry Az 39:1 =Ve ——(8> |, 13-3) m 0 Te Ea e 4 Web +*65) 334 1242 2745 4546 a) FE NS eB i‘ e e SUC BRN Sage ag gee gy sie ee Sea EARNS SIRES aa Kx L168 l2us Liq L234 = Ke veexid'! 67 e27% 5th W 37 Lg - bt (age 2000 oy, Bobprye sina laro Tine/see 4 Is(rate eauation ~ Ig) The —tomplex.reachng System is tat jn which mors tla. one—rachon..akesplace—and His vill give saan desired. anol ustelesired products. In 0 5 : Coly =: Calduie- eiesirey Hy 29, 2 G2 pep ——wolesire | dG At Som © me woneee ln as mibtpicyl ot 24 kee @SG 4 Fe kr Gane an =-Yatar = KiG eke os tne = alton he Baton) ah ee _ IS a aiCe : So : | Haring a Sevies wf vans with vary Yee tly situ e Onc. — allows us to find kb) 3B ke é dy intyratare facter — @ fo pt err be LE Ge, 6G oni (e-tey ae Eh C0 ons k2-Ky fat bod seee | Geet Cg ee ies moe aN + HF ak we eo So Rok a Teg 5 & BsCer HIRI kei (Ho Fie hub e | }. : i SS = Gro= Grlerls = ae RQ 7, Fae Wire ase lar @. ete — e-=Cao-& Le ez-ky fee hit hes oe ae eit it) e; Gf a ee tbe \\ ler much wigan then bea Comcay [ime”''\\ Eee are ree zs Kyt Heb —Ca=taobf- €@ + | =f fe ee Keak ki-ky dite ECO) 0 ere ice) | ace Ca) ' (-kle Eye | ek, .. Ge yg Ss, ee Ae ee Cele) 4 > tad mapAe =F ttt rid | Ce = Gol (lee e So ee i Kr-Ic, 2 eS Lo Re pues fe fig AN Se Iea= ky Subs t= tux . In CeeAe) Se = fez~Ic, te Ki trax _ kar tei) "er y) ee RE I 2 E Sok ae Kick SPee , ’ Ge ee 2 Ku twy ake brovy “¢ ey __= Ay 2 leaky Ce€ 2 ie Lemp Hoe (ey = Cae CEE Ke 2-K) .a Qt GA bqud 4 tindilli by first order Kinetic aud im a batch reactor s0% of A is anverted iMG win « How much. longer would ik take to Yeach 75%. conversion « Gz. Repeat Ahe previous Suid for Second -oydey | Kinetic. Ato min cle eat Yun shows: 75h of igi ? venet tis converted to. Product by ot riage oA ae Twa. i ot Quy Tino, honogeus tsntherwal asl poy eiiaad 204 of) monomer Aisappears iw 34 mesa doe wstial woncinan Content Valow of 0.04 and alse for og mol /Iit * who isthe ati. of clisappeva mae Ae | + After 2 min, in_abatch reactoy reactant Core=\msi/it) 1380! _camerted after 18min. éonuersion is go's. | Find arate equation. to represent thas reaction. | é GYSe ee z af M7. the vera _ovder ol Une ivreversible — 8 —2 Ho 4 2NO > Nay 2He9— from Dhue folowing — constant volume data uSime> } ieaineton wmoudl of hydrogen oma nitvic_oxide. ‘Veaction Total qreceute (wmilg) [400 240 280 320 360 Ee Haig life, ¢ see) | 265 186-5 Iny_ 64 C N@q:—Tets Sek “Mad th the, decomposition of ar 4o e Ly—wndl Ha’ — at-508 Chas aif life of 135. mia. jswhere bbe invkia pressure of HT isos aby ound | VBeS. Min, Where the pressure ts A abmo. (@— shou Mat Abs proves that Ma reaction is send order ee > What js the value of Ms. rah. ee In He Litw/mol see. \ Qgs— Derive We integrated vote. equation. he tT aveaction of + order+ Derive. the. expression forthe 1 life of such__reaction.___f ek ae A Gle z a eh The Bet oder rarer siWle liquid. ree c\loo ki ° 4 hae R C Croee-S mol /lid ancl _Cepzo) Inke place in a batch water » Axier minutes, ;' Gmversiwn of A iS 33.3% While equ. Savers is 66%. Find th rat equation fer this rexclion. arn Methyl apelate s nin sd toy appretandela | of ‘mel Alek Hel ot25 ¢ Samples —of equal volume are \ removed. ab “at intervals and oo ee Do c{ Nac — Gltulte the. first order—vak.cons4ant—| ~ from th. foltets ines — dade I _32q.1247 97s _ysygs og EY 26.34 27.B-—24.70 31.31 3 q- #1-.-—} Tine Ct) Mol-Com®). ~ Qus— Hydngen. peroxich reacd swith thin sulfate Lom. in slightly acidic solulion as fe = @ He Or, 4+ 25203 2H?» 2Hz0» S40, the venttion rat /s melepenolert for th —hyding are jon Gort. in Be mange of pH.Cu tp 6) + The folior: ju. _ date were obtained at 250._anal__pH_S._ltni. Gutenbratign-s ¢ [He 02 | = 0.036 mol/lit, [520§*) 20.0204 mol Jit —— : ea : 61)Time Smin) 46 36 43. S2_ t | S205" XH wtolefiil e103 — 5.13. M16 F155 | a Whale is— tle ordue—o fll. reaction be Whot 15 the rade Constant, ee The kinelics 41 tne Liat Ss an a: is Sinai by dilraehion of tke acid produced. .A Sample, his withdrawn and tilvatal with alkali The vedues frequired ak various Imes ale p— 3 Time tmn.) 7-0 27 60 ee Poh. chaly pO. NBD BG BF a) prove this veachon is first order | by Calculate th hatf — life» a The folowing data were obtained on the sate kde ifs feachen 17h Suerese in ogg melfhd uel aqueous Solutcon at 36°C A—>R time (min) ¢ 962 54.6 93-19 1429. 27ba Sucrose 1965 B43 Flo 54-1 pent ‘ What isthe order of th reaction with vespedt| fo Sucre and th value of the vate constant KC{Mi Ah vesegall ee ty iwZ Me reacion between propionaldehyde —and aa lnyavecyanie acid has been staohed at 25 2 pn a cert apueouS -scljbtan- at 25% the Conte avet | & prvi 48-73 9.3399 1532 14.8 | oe HN fal Hits 0.084% — 210906 0+t8S-__as0F06. 0x0 635 Voit CUsHpCHo ¢ 20566 MOYF2 010406 01029 _o.0224. a, eectFe eg ea ae . MAVEN sheet =2- Seiten @ a: A= praduct———___________+.~ 25 e- Ths tema on Je mado ears ahh Udy) = KE = Shes ze oh mdn CoS) = SK => Kz 0.1396 ly (10-95) = Coe 1386) C4) mb 210 mine 2 Finer donges oie ne g Zz ar or lhe fe _ Sy jes Sis 24S = 0, 20t) (OFS pk_+= 10 vin = , Cas C0 ios) mes KCI) o> K=o.| Cro— cng abe g pe fee —tans)hanl Let yigae iF z Ne Se eei te IS 2 tik gf %i pe Geo tne aeetk ie aS (ou) oat t @: zo oo at Y=. Ph pian Ge eerie ie an aes @u:_t since oe onus is tndependedon Hh istind { wonomer_Cont.__24 the veachion— eS Geen bee Assume —184-ovden ——= la =Xa) = tore : 609 ¥ 154 piiat = 60% 9.20) tnd point jes EB O12 oh —the!_reachion is not. _Ist order reaction Assume dnd-orolen of th form 2A» produch—. - Soke =e A See t NNR ape Seale oe eee Sa Ip An Gt tra dst_pgut ——_k =-a25____ Sgn Lud own Ke z0S obj the. rea ction _13__Setond ander. eal C4)+ CH —Wo}- —— wt Moe 27% = es ote =) cer)” Gr) a ghee oe a a es Ke fw) i We dyeeele pias ed” } eae creed ee O25 We eS | 209-265. c.g S579 4 #? ee 249-4136 $298 Sante RN 230. 1s. G63. Ue WS _4. 44) 32e_ toy SF h = gue a 360 269. ey | aa is MWY / : ~ \), \ t f @ \\F py Lap \ Ni WBa Ser tee e |. _-»3 len: 2 a= 3. oe oh The esetion 1s af thin oreler: —- Gi. HT pee v For: 2nd orgin reaction _t “s oe 0 | feat a ‘RT Ma ms, ton eee Re Ay t ty Ma ond since. [Ap bo =.0-1¥ IBS = 1418-5 © eons tarit oe KF = Constant, > The verction-(S Seconcl-orger2 SOK 7H Ft xs Ut ori Leeh: SE: 26 ts eRe casita + Coe5 oe Sheet -2- fi 5 $5 86 Fh SE 3 $2 S$ 4 Wir Qe Vegeos = Kila ete + Ake Rot Say —Ca) f = Mee bi). ee Sao = (take) [la FS pias tke Kr hes Kelno—Gre) Rod a dl 5 aye ge Pe he er dea ee eee Ao- re __ af 2 «fox Xiy-=-0-333 Sh =CRe ee} oat 333) 06535 for Xpe = 01664 — Gre = Cav (s—Xae) 205 Cl~ 0-662) = 0.1665 J | SOS = o/665 5 Biss oc aegnae kitke oy “Kr = aS ky = i o-333- 6 1665 Weer. ry ah 8 Derk) C8) eine HAG OF —Olbes eae ey it aeee 9) ky 0-05 FS Ka 0224s! )4 ips se AFB a1 Bd fk 4 BB 5 et fora My | ne, pace J | pivsd order reaction o> InAs eet 2 aa | tw ele e 2 => Ke. —- LY ne le 2 - + R= Ror FMe-~G]-—_(©) Mi-e-N2V_ aS Fee a wk. See oe Vy uae WA ote a | ¢ : | ov =» G=m\ 1 (3, = = fa ‘e Ss onstanit t Az Kor Gio-Cx ==) | CAo Cae kw IN Bere e Cenc Ggm © € € oO At tote ERS Gp ten => RCs Ges 39) [PL bao! Geka > Ga Goro A (ealey ses yon by extrapolation =~ eb Gor Ceo = 39-1 Go = 25.74 ae > Nos 34-/ mt 25.9 = 13.3104 Lede Ca = Ror ho (2 = B= 7g.pm Uy ba 13:3(_m sos a ic | Bis 39-1 — mv, Se oe lee ea GO oe neo) ae 334 a-nfhyh. __.23yse Sy sb Jon? t65y- 8a a $174 kas! 1g regs 4a Lesy <4 ae) Sa ID ae 2 sae ed > ibe Hoe eG ea ie Oe Go 20-076 — mel Ltip- | eh Pn 2B a prone st Ll paige, { ody ABO pet ( Gon Co) SB 4 ae ee ee ee | £ - i 4 fin Mel) » ci ls | orcl03—oupfoq-— (B63 005/32 0-024 Los. wows. 0.0273 1.241 o003/$ —-mottg ——2 (6Foun plot de obdtuin ik -SIeaiyhd aes ot Ah action 62nd order. Pe pen opsgg = Ki 2h, tg) Shope pe OSS Ke lease) eee Ka 0.6 5 Lit fel. mid. ~ File Hes del te Put— Cen = & Gola Ca se 4 fost order be oe bt : = as — G2 he +leo- Ce e | Sinte——-at ——t29. Mao =? Thd\ 1 is plesenk —iny tially ——Gho=o— ae eee Gale 3G ot Ga Cond |G y= Cow Yoo 2 @ {St Noszott = 02614 Veveots H + vA I Cp Ce gon ite Visag fom | t : |, Se eee lee eb ae Co- Const. Voaott at 200 Nuaow = 24-7 As amt Cap -G. 2f-7 om zy-% g aoe es ee tt \ qo tet ks EES OS bobe Ue reaction ts 1st orden, cena fe oh fa ‘ rene: oe : Sa 149A min, a ns ee Ot ———_Pisiema-the Beathon—B— fit salon i ag ee ae Why = Be st ee 4 1 beset dati yp ott 2-148 S344. ~ from Al plat. The dale. vepresud a Sheaight Aine - —_— sth freachoe tt freetardtace —Slope=—ic = 3-66. A Sg ae a ee eda —6.0.566 SFG on Ba FG 0: 0iph ong tac ea es ag a 083 g0M08 en gp eae 6.0fog—a-0086 00653 ; soured| —By-exleprlation Goa eno Cera anotsg — Fic plot the Slope = 9.0263 ae Cia ~S:lepes 60266 (He~ Gp) ————— 6-026 72k (ol? _on.ggsp) = —-Ks O28. SM Lh foe th pe rey | i ' fe@u [sheet w 4 0 15 2 2 Me 4 in CA Ae eeSlope= og 26h 6 B Ww jt jd te time /min 76“20h BE bss dowel Sara 7 a Soe tasnt} Bu nS 8PFAIY og In QE ne “Tah ar i, o0l6 —Ih tana * n=\> /\ Be - EON y OAL Vy ar i (a - 42 @ @a = CAao+t Coe — VA = EGE Ka (Got. Go-@) =*\'a- ees fe EE see [le Bee Ne eae va =(Ktk2) Ga - KelMo +o) 4 6 _f Ger Ki me 7 ie = (Ku) -¥ (enot Wo) . g Ge, Caertpo= At Cael mae. rege het oe KA Ne ne - iy Ge 5 Sfpee a (Ker Q 1% ae + Bo Po, Pod oma vie tal: oi Boa Che, Che -\ in - spe) Ge. = wie By week (Ue bae re ide ALTE te (@-%e) 9SY gt Re oN ou = i oe gE Hy ee eG I i aouau zAe Wy 2 ge oe f, i NEA eles oof up nf s WHS wr dos @ a Dead t PT 5 eee wr wt ey is oD ie ee eee ae 44 bs Cin tee un) 2 Bes = She je7A- MITES i Apia ae sili a A Oo ee ot CAE. s In Saas 2 (Keka) £ Chee o0UTH al trae e Gp — “Ae $F casind te ep vn oe “Vy Go Be f Sroka ; Cana we Og elees a! ‘ OB: 36 2 1453 1.336 2-32 65 o11b \-84 06 (eo eet 2.504 oat \bo onde yt tu f Ge ens dow, Oe a bye Yas epee fre es aa “wa tA je (2h yk Ki bs XAe es a 6 e es ae ae a @ 5 bud ( i )“Ye Ky ta - Fats Care Gare o—C% = ic, (taor@o~Cz) - kxCo we -—Y¥R = He Cos va g@lkitk) -re F key Ueno elas ~ og CK + SY) me Mt as Ae Sasato-@e eels K See aS \ e K tebe tat SS) (ie kK, (Ke) Cas ailing) es : K(X!) Ge-G:) ag a eS Ie fe ere Cat he ; v } = = aN {aCe enone) L Coaster w/\y ) wip, f= K Ded a (Zo)oe 4 mee aA, 5's OMS . D5: 2) fee lop i ee —Rrs ‘ APB ee = 88 «kK wiq@aricels at kK 2 ie 2A — = 2k -26 1 km -K2& Ky oe L eae é 5 Ja a kts Re aes r28 se Ka ON eae nt ceca ca " ata ky Ga Cy mek Kt pote a de 7 & HZ = aR a GG i : Sea civll * ¢ spe 38 Cgy "sh aes ) oe mine Ss CUv ve ws 7 Load “| Mm Kae — Ct tae“) X0 @ eka j OOGR Eee 4 In AU XA So1S ~e a mee Qu: For |) Wwe aches KK eo (a as Ii 5 beg Find Al anak Gatentia tion of R ance whenett jy Yea chad. viho hadrogen to Para hydrogene On, = Can be tepwsented — by -t= kk C¥e-Yp,, + ce. ye athe Yaka of the Pe tas i Yeachon ot FY > -146 © Whore 1s Gnstaut equal to Cr Bley “tu =o diel place 8 minntes 4» Gnversion of A is 33.3/. v Find the rate equilibria — Gaversion equator fraction aversion Eig) s x” AEs aioe 4) aK = Die wld igh yb, a Cy The {ust Corder reversible quid reaclien A = g mol /lit in a batch eather. After while Ms integvation fake equalior ty fe “Devwe ee orde> reversible reaction In terms ef fo as wf see SS) & Spee ee be oe es.” soje o> x (@& For a Gastaut—velume reaction of the fore 7 ni-~mB Containing inidialy A at para U pressure B Boat a partial pressure [2, andl MOP Ae / Pacial pressure. [ey jner}s at Pertiod pressure PTy + Show that at tied city dime (V7 when te detal pregure (Ww) fh N R Abe fartinl pressure ef A will be Roz Miho +n ( fev + ro) @ m™—y Ber Ta Me Constautvolume reactions th eeries A+B —s csp. The rates are Pirst order with respect to cach henclawt . Tf the mitial reaction mixture aalains Po md Bo -f A and B respeclively but ne Cudunde Dion Shee ote. the da conlento of A [lak dime 4 is Gao ( Gao — 0) é SS Me — Gee exp [- kit CGro-Gar) J Frame this antwer for dhe utimat. Oneendre tar of A fer the Gases Gord Go and also for Cao cx Cap Qg. — Derwe te factional Aife time ti as a function of initial Qneentate— fer nth orele Feaclion - e |te Et ACR at Ce nay 3 te at \b6 - Ais 8 te Ki eis = Sna Cae = Rita Kise. de Su Wig i CR ak OR vw Cee k Cpe > WwW =K K tmx Jt = t Ke =e ae Sek oe aSiKiCpe ny 1 Pde ‘7 eu Cae dt & consty -K CayJdt - const, Bc -Kt fot oe Lax Ho € ok tao CAs SxERES(6) Ke Cee ck J “kK Golte CK) ee ] =i Ca Le Ltr] Us ier tp a0 eS ci () Sp» some = Be KK 2 x i “ts | aa) Is Cp | abi iA a dt 4 constant i } | =D Snsteo) | vo Hoy, oa ' | as | | 2:34 Ge ||PES e Ll | ~Y4 =Ki Ca — Ka CB R= ha +S B ~My = 6 CG * B-“a) - Kaa = Ki Cnet po) - Sp Cita) =Yp = CC t-Cae) 6 kee eau 0 Bo) - Ca CK + a) ic oaes ikil= S@e = See Cay +g o-Cee cot Ro we = Garo = See (Kt) Kel ! = = ) Ge = inlir 2) Se ~Ya= ty CHL) [ Ge 6, ra nee ra} Bee 8 CeeeGR i eetauss ( i a f CEN coor G) [ e=S ] Boeho =pe We Ce -¥)pea Coe = ay aN Be % for fist ceversible veactivn A= =K { Ik, (M+) t M+ Xe Kye aertee given ws (Ke aaa : Gia : Gio X ple} = 01S (1 0 664) 2 0-(865 = How Ges o-S— 0/5 = 0.3335 eee eg obs Ce 00 8 1 Ge aah Fa Kae Ki (ori) if fei Xme ly 285% x let Co) obde 2-999 O° b6F bunt Ky = 00576 K Ky =1-0043 -) vain Sey Wee 02 bien! -_ 6-ate \@ Qo = | eae A See ® | ‘ | Aca 4X4 c | arora Ae at = Ca —t2 CB CA= Sno (l-%n) 9» B2Bo t Horn. =‘ nolht Xn) | Ge oe = K; GuI-Xq) — Ka Cae CME IH) e ata = Kil i-Kq) — Ka CM 4X9) | (ee Kin = ee Cho(H+Xae) | Ke Cae Cag (t= Xae) =, (Lokae Ge oint foes mM axa - mE IOTE ) (MX Jt Ay Mi) - es Hex aa) ) | Hob MMM Me) — He Cikec) HA) é Hakae / WM = Mx Xe aXe) — Hy (MM Kae 430 -KAXRe) Boas Wx Kae | SNe Gc AM the a) Wi Kee pat (Xne Ka) OM et) at ek eh inte) 4 Q UXe = Kha yh me -In Uxre~*n} Saas = Ane- ha MAXae ° f,a VALS tee fhe Fee PIe werk. i as Ta = Tae Ter Teot at me B. -e A Pes Oe ER. * Fea TR, CE -) + PLe 4 Pao = Fou a x(2) +P Lo Wo -T, )n | & -Te. “re ) >: eve Rhetis (Bee. n( Tes PEe any wom = eet wow He BL Les, | in Ta Meacl | /@ =e da maar fens Cys ek ta =I 6A Cg =~ 52 aie =k Ca = o- Xa Can % ae B= Bo~ Xalne SON St B =e +h - Cre where Fe Sneha, aA = ( CEE) & PCa =| AFLAG t+ BCn =1 AF +CaCh 6) =1 hols cfle 4 | ca , B=-A i | ineg J = nCreGa)] =F kt Tash ts | Che “Ae | (ESE AE CEE) 2 ea | Sao Fay | in CACFHM) cine | aCe ra) ie | Ca (Bo =e We "Bo) : | Ge (FAG) €%,~Gpe) Kit cA = She 'e F@| Se| SS re le Ge) Et SEQ. See le 2 | 2 oA Bo 5 ;: ~C Gho-CWe Kit oF - be e Poo ere cA Ao ~Ctpe~Cee) Ki [aes ae Bees Sic SA CAs: Alo | ~ boa Che) Kiet | Fee et < e| * & ca = £A0 Lebo Cae) | Ta Cea Cg ple t Bee eons. | eq = [AoC ene ee) Cae- QI) Kit | eran oS @) kK —>o i = Cp < when 2 po a -—— Oo | “ab Ge Coe 2) _ She) | (aye 5 EEN) Coo Rie ese bee l oe de ) =e I = Bok ca= face ® ee(1+ Es) fi Eau Nariatale volume lpatthn reactor the a show thet for second order reacts tauation applied . bale li-xa) 4 Ut Ea)Xa jg, Cac +. 1 xa maka “tat Ao dxa (XK Va = Soe K Che Ce = 1 Tea OE EAA ANA ea I pe aes * ee The Aydrolysis ef 1 - chiora~ 1. methyl eyeto decane f Rid| Bo'h clhanel has been studied ok 25°C - The Hae nieneent WaliglGt Whe mmete hy Libraling the y latid formed after mensured mer vals oR lime witty ia Solulion of Haotl the data owe as follows: t/hr oo Lo 3.0 5.0 40 12 < 9 V/Cw* 0035 05295 OHS 05S 1.505 25 2049 (ay, What is the onder of the reaction £ 1h) Whek is the Value 4 Na ratte Gustant ? (Wht brachton, of We tH chloro—t wwetly| Gyelode tine will be lett vonkey dro! ted ol tex a ka ® Ester 4 W260 —s Acid. nic Ester ¢H20 — = fcid 4 file td Ce = Coster Cacid = Ca 4. the reaction is 45t- order » In be kt v GMa= Gy > & = \b => leastout Cay = 9035 7 p45; foes At t= Cho + Wired = 2-197 1) V3, oo * Re aal = PIM Gig = 2197 -0:035 m = 2.162 9 %. = Gp, = 2-lbem == formecd | From, mass. balan. Cror Geo = are = G | Gs G@eG-G= 2N7M-MY, —_@ New. Subst, (2.3@ nO pve - ® \ a19F 5 a olyeek ne Ibe on i eee = Kt te 2-14 Fm — BM | Ia HER ONS Set | 27 Vy 4 ploltiny In eg Vs. & yives ustiaight {me ef Spe = 02+ ie the reaction As first order 246% T= Ve 127 | tt Cb> the sape Wa ertey he © bn = =kt 0 t kt olay x6 esi!" Se £ oraee Py sae of ester remain nhydroly zed after B hes : ‘ Kok Qj: Fv the veuctions in series A —yR—,5,, ’ “derive the yoations ying Cy ond Gas a function of time fn the ase that Kizka ck » Also find hh max. Conc» of Rand Whey Fh is renchedl. Ak da ste a =k SRS kG dete a dt Bese -kt NOL op Seat oR Ge Cp =o & _ 7 R lo 3~ (96- oO ~ G t =Ft +k2 okG@e ae et —Kt Ff C &=fKGE ¢ HH + cont. = SK Gay ol? + Gonst = K Gant 4 Const at t=o0 Ce=0 of @nsd oo ~ < 4 aoa Ft * € Ca = Gao kt > &R = tho kt e | hes + Pa ie Ue = ho ~ ioe -Rokt é y y = Kt =Ke rioWlarc - lar ekee 4 7 | GO Ul retina a lak Ra Ce en © ~ -Ht ht GeGkTe dh strek{e Ke Jeo -Ft Pee (kL) y tS AL : | Ik ay > as Ges = = fe 0367 Cho Tas The wiblal met -f the veadlton » { E me mt Br O, +'% S03 ws Br 4 3 50, was found to be given hy K[ Bro Jl sog‘Joat] Give one of He Termedyngmitelly posiille rat. |aiy | for how veverse Yeaction. Le lits a Ty:= 729 ~ 1) iy fra [sel Hn dt si eit lias tet thavene vole qa is E88) elas) Ise) toi} ov fhe ned vale 4 ss eel) aH = k,[8r9;J)9 JA") ie Ler)ly" info yar neh L Me ee tel tonite tom rset") | fe [Br 0s) Eso} fH") and from te geveral Ratlion eqn. ky _ (ee. 11 ieaitsa This means the a=) pal Cz0 zat The passitle form of the reverse Yeathion yeile! is. | | | Jd | at The ayneous reaction Aa» Res proceads as frtows 5 Time [min ° a6 cs to ho oe Ca] et At olds o- M53 0-426 011025 we'7gs Oo -OugY iM) IGP NEA, Cape. Sess so aol Chit. Find the we ey mactior— yor this Veacdivny 2 (esBe Tb euay 2 CR 7 gk eb el gene Bile 55 ml hyp Spot pe pt Dey uy AF SVEN pF J a Ves wd) A pul pie | oes wd Sid & rsd Poin 25k, oe esl d Pew bik te redcton 5 rwersible Girst~ order. AA Gre = erouad mol/l? Dodi WG ve | et Ge = Se + Ro eee | PEG = he Gey Ge = 0-173 + 0m o-cugy = e124 wef Ih Bee Gee (Keister) { HAC Weg Gy lg He fui Afar “a= sf ° os 1823 ae | 1\| 36 o4s3 0-322 | 65 ©1216 1 o-8) too 0.1025 O42 | \60 Oo 14S 14g | Nm Noe vee ee Grea dy dt gD ee Mot | Skye = #.00925 (\hegespes a(link) okivk. iy yVig eat Cas Cae ET Fa Ce ott eae 7 Ge e4y wp ge 6-34 010? 4 hr. 25154 soti ~~ o 2a2- sheet ‘D/ Reactor detign. } 22), Fhe aes first order sat.. constant . forthe i disepperince off (7 in The gas.remetion 1 i I 2A--R \ Hy son holding the pressure constank » the Volume of Wee veaction mixture » starXing ith | Boy, Ay ceereasey by 20 fo. Awd. wine ne zf | Gel Fmd the Rivet order veto constant for he Ate ow pearance a A inthe gas reaction A) re Ry Shy Me Vo tame of the, reaction mixtare, Starting | l with pure, Ala mereases by Bol, in G& win The 4o lel presswee woithiy the system stays cons tant | ak 4-2 gh y ond the tome is 25 € , wrt oa A “éx0 = order hereageasony gas reacho A rR Proceeds iw ao Contlerk veluwe leomlos) no'le inerks, amd Nhe. presswre vites Sem 140 4% ulm by a Bin ah the same veathion | Jatess place Im a Constonk — pressure loakieh rea thor | } lat 1s the fractonad Valagechunse in & min “fe The ud is ot 2 atin ond consist of Hol. tert Vy Ly e4a Peat: | ) shat t Db a Reacher legit Z Zz ‘| The voll soi hide a} op te reaction le The fillowing Kinekic dato. have Leen olotarinad her] | eis veaction of 104g °K \ ous Quay) 284 205 14 “on 400 »}Heo Ire “Xo (Cana th) soo toe 4s 354 Sep 182 J swidiod Pe elb otto 2019 o-AS 0:J03.. e025) oh reaction Casa Bee Bind Ye Rate equabe— nitric exide swith: hydrog eae is 2No 42Ha —>Nar2Hzole | wattial rete dader Gor the following, rection Hep Gaia 2HBr | aha ware Sppamiger | | ‘ | t it an eee le be (Cog), mole Miter e225 0:9 GIS OMT FER eH OB] O4SS | = t Wleeg), ete fut artes 0:4 onG67S os tH GIS! oS west Reais ape toq #4 web 482 bbs Beg L2b Me eas ~~\ Sagal The ges veaction 2A—>R +25 is appromimatiy Setond orcke wit. respect tu A» wher per Ais Mtroduted at 1 atm into « @nstent—Volume bateh reactor, The pressure mses 4of in 3 muff For nm onstoi Pressure batel reactor fd (4) tha tree Required for | He same conversion. ancl hy the firctonal j, Mevease hat ipslbban gb tak. Ha Ra, QA Rh Fer erdor homagenrods gas veackion with ft stoichiometry As rR prceeds in a eons dent ewe bomb, Tel Whn tro and WHS wher | bat Tf the Same reachiny cam feel comprsttan,| init pressure proceeds tw oo cas tort — pressure Seh—up , find Vio ak tet if Ved ot dey. — eH Mol The “first order homogeneous gasenut de cangesition A —> 2:5 R js cattiedd out in an isothermal Yokch reathor at 2 atm with 2ol. ierts present, and the, velome “Awereses by Gof, Sn 20 ww yTr a tongtank —voluune veattor, find Ike Vine vequired for. The pressure. to reek p ater if fle inpral pressure is S adm . gate cs Which consist ft I nerts