Vidyamandir Classes

Class Test-2 Organic Halides Chemistry

CH3

Cu aq
1.(a) Identify (A), (B), (C). A 1.(b) CCl 4 
NaOH (excess) B


I
HF
1.(c) CCl 4 
SbF6 C  D

2. ZnCl2 Na/ether 1. Br2 /127C

+ HCHO + A B C
 2. KOH/EtOH
HCl

Br
Mg CH3CHO 1. HBr
3. (B) (C) (D)
ether H2O 2. Mg/ether
(A) 3. H2O
How will you obtain D from A in NOT more than 3 steps ?

Alc. KOH
3 BH / THF
4. C4 H9 Br  A  
 B 

C
H2 O2 / OH
aq. KOH
A  D D resist oxidation.

1. EtMgBr
2 4 3 H SO 170C  O
5. C8 H16 O 

 B  C   Et 2 CO
2. H3 O
1. 2 mol of A
2 4 H SO 170C  [O]
6. CH 3COCl 
2. H O / HI
 B  C  D  C13H10O   CO 2 [B reacts with Na metal].
2

31. CH Cl / AlCl
3 A  KCN 1. MeMgBr (1mol) NaOH
7. Benzene   B 
 C 
I
PQ
2. NBS  2. H3 O 2

1. NaNO2  A  CuCl

2  C  phCH Cl NBS 1. aq. KOH
8. C6H 7 N 
2. HCl  5C 
 B 
Na / ether
 D 
2. [O]
E
CCl4

Cl  500C  Aq. NaOH 1. Na

9. 2
CH3 CH  CH  A 
B C
2. MeBr

1. OsO4
D
2. NaHSO4

10. 2H SO
4 B 1. BH3 / THF
 C6 H14O  A 
2. H2O2 / OH
C [C is an isomer of A]
170C

O3
D +E
D can be obtained by hydration of propyne in presence of H+ and Hg2+ ions.

VMC/Chemistry 3 Organic Halides/Class Test