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Engineering Analysis with Boundary Elements 77 (2017) 36–48

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Engineering Analysis with Boundary Elements


journal homepage: www.elsevier.com/locate/enganabound

Optimizing the sacrificial anode cathodic protection of the rail canal MARK
structure in seawater using the boundary element method

Yong-Sang Kima, Jeongguk Kimb, Dooho Choic, Jae-Yong Limd, Jung-Gu Kima,
a
School of Advanced Materials Science and Engineering, Sungkyunkwan University, 300 Chunchun-Dong, Jangan-Gu, Suwon 16419, Republic of Korea
b
New Transportation Systems Research Center, Korea Railroad Research Institute, 176 Chelodo Bangmulgwan-ro, Uiwang, Gyeonggi 16105, Republic of
Korea
c
Department of Advanced Materials Engineering, Dong Eui University, 176 Eomgwangno, Busan 47340, Republic of Korea
d
School of Mechanical Engineering, Daegu University, 201 Daegudaero, Gyeongsan, Gyeongbuk 38453, Republic of Korea

A R T I C L E I N F O A BS T RAC T

Keywords: This paper deals with the cathodic protection design for axle/wheel and rail of ‘rail-canal system’ in the ocean.
Cathodic protection The cathodic protection design was carried out using the boundary element method and was verified by the
Corrosion physical miniature tests. The optimum cathodic protection designs were determined based on the cathodic
Rail canal system potential distribution and anode lifetime provided by the simulation. The unprotected physical miniature
Boundary element method
experienced widespread corrosion, whereas the protected miniature was covered with calcareous deposit,
Physical miniature test
indicating that the surface was fully protected from corrosion. This study demonstrated that the boundary
element can be applicable to the cathodic protection design of rail-canal structure.

1. Introduction and DNV RPB041. However, important SACP design factors such as
the selection, location and number of anodes are determined by the
A ship canal is that provide a shortcut for transport ships to avoid corrosion engineer due to complex conditions and uncertainties [5].
lengthy detours. With the recent increase in demand for ship canals Thus, studies on SACP design for various offshore structures are
desire to reduce the cost of cargo transport, there are plans to extend required to ensure the adequate design of SACP.
both the existing ship canal in Panama, and build additional ship The boundary element method (BEM) is an element method that
canals in Nicaragua, Colombia [1,2]. However, conventional canal only requires meshing of the boundary on the modeling structure, so it
waterways are enormously expensive to construct and have long lock can more effectively mesh and calculate the boundary elements
gate operation times. Also, overland routes are interrupted by canal compared to other element methods [5]. Due to this advantage, BEM
construction, resulting in environmental problems and restrictions in has been widely utilized for the cathodic protection design of enormous
national land use. To address these drawbacks in waterway canals, the structures such as ships, offshore structures and underground pipeline
Korea Railroad Research Institute (KRRI) has proposed a ‘rail-canal systems [5–9]. Various studies [10–12] have showed that the use of
system’, in which a large vessel is transported not along waterways but BEM results in excellent cathodic protection system designs.
on land, so as to replace conventional waterway canals [3]. The rail- Simulations of galvanic corrosion related to the SACP using the BEM
canal system process is illustrated in Fig. 1. However, the corrosion method were in good agreement with the experiment results [13,14].
problems caused by a marine environment should be addressed to In this study, the SACP of rail canal structure parts (wheel/axle and rail)
provide safe and long-term operations for rail-canal systems. in a seawater environment was simulated using BEM. It was difficult to
Sacrificial anode cathodic protection (SACP) is a widely used anti- apply an organic coating to these parts due to the continuous friction and
corrosion method for offshore structures. The mechanism is that stress. Thus, a huge current is needed for impressed current cathodic
galvanic current flows from a sacrificial anode such as magnesium protection (ICCP) without the organic coating, and this may cause an
(Mg), zinc (Zn) and aluminum (Al) to the protected structure when the electrical accident. Therefore, SACP is applied for the cathodic protection
anode and protected structure are electrically connected in a conduct- method of rail canal structures. The optimum selection, location and size of
ing environment [4]. In general, the design of SACP follows the the sacrificial anodes were determined, and the optimized cathodic
international cathodic protection criteria, including NACE RP0176 protection design was investigated using physical miniature tests.


Corresponding author.
E-mail address: kimjg@skku.edu (J.-G. Kim).

http://dx.doi.org/10.1016/j.enganabound.2017.01.003
Received 30 June 2016; Received in revised form 5 December 2016; Accepted 4 January 2017
Available online 21 January 2017
0955-7997/ © 2017 Elsevier Ltd. All rights reserved.
Y.-S. Kim et al. Engineering Analysis with Boundary Elements 77 (2017) 36–48

Fig. 1. Schematic of rail-canal system.

to avoid computational errors. Three-dimensional models of wheel/


axle and rail structures with detailed dimensions are shown in Fig. 3(a)
and (b), respectively. Also, the cathodic protection system information
was used to provide the size, location and form for simulating the
cathodic protection process. The size of the anode and the anode
location were changed during the process of cathodic protection design,
and the form of the anode was rectangular to simplify the computation
process. After modeling the structure, the designed structure model
was imported into the BEASY software.
Setting the boundary conditions is an essential step in modeling
corrosion and cathodic protection systems with BEASY. The model
structure and surrounding environment (seawater) are enclosed within
a rectangular box that was approximately 30 times bigger than the
modeling structures. In order to avoid current flow from the object, the
vector sum of the current was zero. The conductivity of the environ-
ment was fixed to 3.75 S/m. The relationship between the current and
potential of the cathode and anode gives the polarization state; there-
Fig. 2. Boundary conditions for the cathodic protection computation. fore, the cathode and anode electrochemical properties were deter-
mined according to the input polarization data.

2. BEM simulation 3. Experiments

Adey and Niku [15] have provided the mathematical formulation 3.1. Materials
for a uniform, isotropic electrolyte domain Ω as shown in Fig. 2. Some
simplifying assumptions were made to assist in the computation The axle/wheel and rail materials were based on carbon steel. The
including: (i) the solution must be uniform and electro-neutral, (ii) axle had a nominal composition (wt%) of 0.45% C, 0.30% Si, 0.75%
there is no concentration gradient in the electrolyte solution, and (iii) Mn, 0.010% P, and 0.001% S, while the wheel had a nominal
the boundary of the container was electrically insulating, so there was composition of 0.64% C, 0.25% Si, 0.73% Mn, 0.015% P, 0.003% S,
no flow current leakage from the container. Following these assump- and 0.025% Cu. The rail had a nominal composition of 0.85% C, 0.5%
tions, the potential obeys the Laplace equation: Si, 0.64% Mn, 0.003% P, and 0.003% S. Zn and Al sacrificial anodes
∇2 Φ = 0 (1) were used in this study. The Zn anode had a nominal composition of
0.050% Al, 0.04% Cu, 0.02% Pd, and 0.001% Mg. The Al anode had a
The Laplace equation is solved using the following boundary
nominal composition of 0.05% Fe, 0.05% Si, 0.01% Cu, 3.5% Zn, 0.03%
conditions:
In, and 1.0% Mg. Synthetic seawater from ASTM D-1141 was used, and
Φ = Φ0, on Γ1, (2) its chemical composition is listed in Table 1.
I = I0, on Γ2, (3)
3.2. Potentiodynamic tests
Ia = fa (Φa ), on Γ3a, (4)
The polarization data for the cathode and sacrificial anode materials
Ic = fc (Φc ), on Γ3c, (5)
were needed to carry out the simulation. The cell used for carrying out
Γ is the entire surface of the electrolyte domain which includes Γ1, Γ2 , potentiodynamic tests was a conventional three-electrode cell. A
Γ3a and Γ3c . Φ is the potential, and I is the current density across the purified carbon rod was used as the counter electrode, and a saturated
boundary. Φ0 and I0 are given constant values of potential and current calomel electrode (SCE) was used as the reference electrode. The
density, respectively. fa (Φa ) and fc (Φc ) are functions that indicate the working electrodes for axle/wheel, rail and sacrificial anodes (Al, Zn)
relationship between the potential and current density of the anode and were rectangular cubes of 1×1×0.3 cm, and these were mounted in
cathode, respectively. epoxy resin with an exposed area of 1 cm2. Before the tests, the working
Wheel/axle and rail models were created in the Rhinoceros 3D electrode was abraded with wet SiC paper (initially 220, 400, 600 and
drawing software based on the real shape and dimensions of the 800 grades), washed with distilled water, degreased with acetone,
structures. The dimension data include the length, height, width, washed with ethanol, and finally dried in nitrogen gas.
diameters and so on. The inner parts of structure were not modeled Potentiodynamic tests were carried out using a Bio-Logic VSP-300

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Y.-S. Kim et al. Engineering Analysis with Boundary Elements 77 (2017) 36–48

Fig. 3. 3D models of the (a) axle/wheel and (b) rail structures with detailed dimension.

potentiostat. The potential range was from −300 mV vs. open-circuit


Table 1 potential to 0 mVSCE at a scan rate 0.166 mV/s. All polarization tests
Chemical composition of synthetic seawater. were repeated a minimum of three times to confirm the accuracy of the
obtained data.
Component Concentration (g/L).

NaCl 24.53
MgCl2 5.20 3.3. Physical miniature test
Na2SO4 4.09
CaCl2 1.16 Physical miniature tests were carried out to verify the cathodic
KCl 0.695
protection design. The miniature size was 1/10 of that used in the
NaHCO3 0.201
KBr 0.101 numerical model of axle/wheel and rail structures. The axle/wheel was
H3BO3 0.027 connected by silver paste to ensure a good electrical connection. Fig. 4
SrCl2 0.025 shows the physical miniature model used in this study. The sacrificial
NaF 0.003 anode was rectangular, and the size was 1/10 of the numerical model.

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Y.-S. Kim et al. Engineering Analysis with Boundary Elements 77 (2017) 36–48

Fig. 4. Physical miniature of axle/wheel and rail structures.

In order to evaluate the cathodic protection, one miniature had an −770 mVSCE according to the cathodic protection criteria. In addition,
installed sacrificial anode, while the other miniature did not. The the sacrificial anode life was 25 years, in accordance with the general
physical miniatures with sacrificial anodes were placed in a tank service life of the rail structure. The axle/wheels and rails structures are
containing 20 L synthetic seawater for 45 days. During the immersion not combined during the design of the cathodic protection system
period, images were recorded using a digital camera. After 45 days of because the axle/wheels and rails are not fixed to a specific location
immersion, the weight loss of each miniature model was measured to during operation. This means that the effect of the combined axle/
confirm the cathodic protection design. Before the weight loss mea- wheels and rails continuously changes, and the design of such a
surements, the corrosion products on the unprotected physical minia- cathodic protection would be complex and have certain limitations.
ture were removed and cleaned for 10 min in a cleaning solution Thus, the cathodic protection design for this system was separately
containing 500 ml HCl, 3.5 g hexamethylenetetramine (C6H12N4) and carried out, and the combined structures were simulated. Then, the
enough distilled water to make 1000 ml. The specimens were then cathodic protection design was verified by miniature physical tests.
rinsed in distilled water and weighed to 10−4 g for the weight-loss
measurements. Also, the calcareous deposit on the protected physical
miniature was removed using a 3% acetic acid solution and was cleaned 4.1. Cathodic protection design of axle/wheel
using the same process mentioned above.
Because the wheel is more noble than the axle, a simulation must be
conducted without a sacrificial anode to determine where the sacrificial
4. Results and discussion anode should be installed. Fig. 7 shows (a) the potential distribution
and (b) the current distribution of the axle/wheel without a sacrificial
A flow chart for the design process for a systematic cathodic anode. An anodic reaction (corrosion) at the connection point between
protection system is shown in Fig. 5. The polarization data of each the axle and wheel would be expected because of the galvanic effect
structure and the sacrificial anode materials are shown in Fig. 6. caused by the potential difference between the wheel (cathode) and
Although the axle/wheel structure has a wet-dry cycle during the axle (anode) [16–18]. Thus, the sacrificial anode should be installed at
operation, the structure is washed off after operation to minimize the axle and at the connection regions.
corrosion by the concentrated salts during wet-dry cycles. Thus, only Before the simulation with a sacrificial anode, an adequate sacri-
the immersion condition was considered in this study. Both sacrificial ficial anode was identified. The axel/wheel structures are subjected to
anodes have a lower corrosion potential than the rail structure (axle, high stress during operation. The Zn anode was not appropriate as a
wheel and rail) materials. Therefore, these anodes seem to be appro- sacrificial anode for the axle/wheel because the heavy Zn anode cannot
priate for use as sacrificial anodes. For the purpose of the simulation, properly balance the rotating part. Therefore, the light Al anode was
the linear region (Tafel region) in the anodic and cathodic parts of the selected in SACP for the axle/wheel structure. Also, to minimize the
polarization data was selected and inputted into the material database influence of the anode weight on the axle/wheel structure, the Al anode
in the software. The cathodic protection potential was determined to be size was fixed to dimensions of 5×3×1 cm, and SACP was determined

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Y.-S. Kim et al. Engineering Analysis with Boundary Elements 77 (2017) 36–48

Fig. 5. Flow chart of cathodic protection design in this study.

as a function of the number of anodes. seawater might be half of the service life. Therefore, the adjusted
Fig. 8 shows the potential distribution of the axle/wheel as a sacrificial anode lifetime for the axle/wheel was determined to be 12.5
function of Al anode number. A potential below −770 mVSCE was years. Table 2 lists the calculated sacrificial anode life in each case. To
considered to be an appropriate cathodic protection potential accord- calculate the lifetime of sacrificial anodes (t, day), the following
ing to the international standard. When 1 and 4 Al anodes were equation (Faraday’s law) was used [4]:
installed, the potential did not satisfy the cathodic protection criterion,
i.e., above −770 mVSCE on the axle/wheel. In contrast, the protection mnF
t=
potential was satisfied in cases where 6, 8 and 12 anodes were installed. Ia (6)
However, both cathodic potential and the lifetime of the sacrificial
where F is Faraday’s constant (96500 C/mol), n is the number of
anode should be considered in the design of SACP. The required
equivalents exchanged, a is the atomic weight (a / n=9 at Al), I is the
sacrificial anode life is 25 years, which is the service life of the rail
current measured from the simulation results associated with a 90%
structure. Actually, the average immersion time of the axle/wheel in
effectiveness of Al [19], and m is the weight (mg) of the sacrificial

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Y.-S. Kim et al. Engineering Analysis with Boundary Elements 77 (2017) 36–48

side of the rail.


In order to select an appropriate sacrificial anode, the potential
distribution of a 3 m rail section with a Al or Zn anode was simulated as
shown in Fig. 10. Fig. 10(a) shows the potential distribution of the rail
with an Al anode, and Fig. 10(b) indicates the unprotected region with
an Al anode, which was above the −770 mVSCE region. The Al anode
could not provide sufficient protection; therefore, the Al anode was not
an appropriate sacrificial anode for the rail. On the other hand, the Zn
anode decreased the potential of all 3 m rail regions in the range of
−784 and −1051 mVSCE. Thus, the Zn anode could be applied to the rail
structure.
After selecting the sacrificial anode, cathodic protection simulations
were carried out as a function of anode size. Also, the distance between
the anodes was fixed to 6 m to minimize the external influence of other
structures.
Fig. 11 indicates the potential distribution of a 12 m rail as a
function of Zn anode size: (a) 5×3×1 cm, (b) 6×4×2 cm, and (c)
Fig. 6. Polarization curves of axle/wheel, rail structures and sacrificial anodes. 12×5×2 cm. As shown in Fig. 11(a), the small anode does not satisfy
the cathodic protection criterion, whereas the cathodic potential was
satisfied with the other two cases. The designed anode life (25 years)
was also satisfied, and the anode life was calculated using Faraday’s
anode (36 g of Al). According to these results, the anode life for service
law. In the anode life calculation, a / n=32.7, the weights were 106.5,
was satisfied in cases where 6, 8 and 12 anodes were installed.
342.2 and 865.2 g, and a 90% effectiveness of Zn [19] was used in the
In summary, the average potential (cathodic potential criteria) and
calculation. Table 3 lists the calculated anode life. As shown in Fig. 12,
service life of the anode are important considerations in cathodic
the average potential, Fig. 12(a), and life of the anode, Fig. 12(b), were
protection design. As shown in Fig. 9, the average potential, Fig. 9(a),
satisfied only with the 12×5×2 cm (865.2 g) anode. Thus, considering
and lifetime of the anode, Fig. 9(b), were satisfied for systems with 6
the potential and anode life, only the 12×5×2 cm (865.2 g) anode
anodes, which also minimized the number of anodes from an econom-
provided the appropriate cathodic protection design for the rail.
ics perspective. Thus, the optimized SACP design of the axle/wheel is
the 6 anodes installed in pairs at symmetric locations along the axle.
4.3. Simulation of combined structures (axle/wheel and rail)

4.2. Cathodic protection design of rail After the cathodic protection design of each structure (axle/wheel
and rail), the potential distributions of combined structures, which are
The rail has no galvanic effect; therefore, there is no need to applied during the cathodic protection design, were investigated as
simulate the cathodic protection step. To avoid contact between the shown in Fig. 13. The sacrificial anode installed in the middle part of
wheel and anode installed on the rail, the anodes were located at the the rail did not satisfy the cathodic protection potential (−770 mVSCE).

Fig. 7. Simulation results of axle/wheel without sacrificial anode: (a) potential and (b) current distribution.

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Y.-S. Kim et al. Engineering Analysis with Boundary Elements 77 (2017) 36–48

Fig. 8. Potential distribution of axle/wheel SACP as a function of Al anode number: (a) 1, (b) 4, (c) 6, (d) 8, (e) 12 anodes.

The protection current is not sufficiently supplied to the far region of


Table 2 the rail structure from the sacrificial anode because of the axle/wheel
Lifetime of sacrificial anode (Al) for the each cathodic protection design of axle/wheel
structure.
structures near the sacrificial anode on the rail. However, the dis-
satisfaction value of the cathodic potential is small (about 10 mVSCE),
Number of Al anode Total current from anode ( μ A) Calculated anode life and the axle/wheels and rails are not always combined in specific
(year) regions as mentioned above. Therefore, the influence of the combined
1 132728 7.9
condition does not have a significant effect on the cathodic protection.
4 96876 10.8 In addition, the combined effect would be less than that observed in
6 79488 13.3 actual conditions because the contact resistance between the axle/
8 64584 16.3 wheels and rails increases due to the formation of scale on the surface
12 56304 18.7
of the structure used for cathodic protection.

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Y.-S. Kim et al. Engineering Analysis with Boundary Elements 77 (2017) 36–48

Fig. 9. Determination of cathodic protection design of axle/wheel as a function of the (a) average potential and (b) anode life.

4.4. Physical miniature test showed uniform corrosion because there is no galvanic corrosion. The
connection region between the axle and wheel was preferentially
Physical miniature tests were carried out to verify the cathodic corroded in the case of the unprotected axle/wheel structure after a
protection design of the axle/wheel and rail. In previous studies [5,8], 2-d immersion test. This result is similar to the simulation result in
the differences between computational and experimental results were Fig. 7, which shows a higher current density in the connection region.
attributed to geometric simplifications and a lack of material interac- This means that the computational simulation result was highly
tions during polarization. The relationships between corrosion and correlated with the miniature physical test at the galvanic corrosion
cathodic protection observed in computational and experimental part. Meanwhile, white scale precipitated on the whole surface in the
results are compared by means of the miniature physical tests. protected physical miniature test. Generally, the cathodic current
Although the combined effect is small, the combined situation is the during cathodic protection increases the dissolved oxygen reduction
worst case in the simulation result. Thus, miniature physical tests were reaction (7), which generates hydroxyl ions on the polarized surface.
conducted in combined structures. Fig. 14 shows the physical minia- This increases the surface pH and increases the carbonate ion
ture results for axle/wheel and rail after 2 days of immersion in concentration (8), resulting in the precipitation of inorganic layers
synthetic seawater. The results of physical miniature test for the rail such as calcium carbonate and magnesium hydroxide. These mixed

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Y.-S. Kim et al. Engineering Analysis with Boundary Elements 77 (2017) 36–48

Fig. 10. Potential distribution of 3 m rail installed (a) one Al anode and (b) unprotected region, above −770 mVSCE, (c) one Zn anode.

Fig. 11. Potential distribution of 12 m rail as a function of Zn anode size; (a) 5×3×1 cm, (b) 6×4×2 cm and (c) 12×5×2 cm.

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Y.-S. Kim et al. Engineering Analysis with Boundary Elements 77 (2017) 36–48

Table 3 Mg2++2OH−→Mg(OH)2 (s) (9)


Lifetime of sacrificial anode (Zn) for the each cathodic protection design of rail structure.

Weight of Zn anode Total current from anode Calculated anode life (year) Ca2++CO32−→CaCO3 (s) (10)
(g) ( μ A)
The calcareous deposit decreases the active surface reaction, which
106.5 211544 6.3 decreases the anode dissolution and the rate of reaction (7). Thus, the
342.2 243936 11.3 calcareous deposit has a beneficial effect on cathodic protection,
865.2 272313 25.8 indicating that cathodic protection occurred on the structure [21].
Fig. 15 shows the physical miniature test results for (a) unprotected
and (b) protected system after 45 days immersion in synthetic sea-
water. A thick corrosion product was formed on the unprotected
deposits are generally called calcareous deposits [20]. physical miniature specimen, whereas calcareous deposits precipitated
on the surface of the protected miniature physical specimen. As
O2+2H2O+4e−→4OH− (7)
mentioned above, this indicates that the protected structure had
sufficient protection potential (negative potential) regardless of the
HCO3−+OH−→H2O+CO32− (8) connection between the axle/wheel and rail structures, as suggested in

Fig. 12. Determination of cathodic protection design of rail as a function of the (a) average potential and (b) anode life.

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Y.-S. Kim et al. Engineering Analysis with Boundary Elements 77 (2017) 36–48

Fig. 13. Potential distribution of combined structures (axle/wheel and rails), which are equipped with cathodic protection.

Fig. 14. Photograph of unprotected and protected physical miniatures after immersion in synthetic seawater for 2 days.

the computational results. After removing the corrosion product and the boundary element method. The design was verified using physical
calcareous deposit, corrosion rates were determined by the weight loss miniature tests. In the axle/wheel cases, the Al anode and the number
method. The corrosion rates of the physical miniature specimens with of anodes were design factors for minimum load influence. Considering
and without cathodic protection are listed in Table 4. The corrosion the cathodic potential criterion and anode life, the case where 6 anodes
rate was calculated based on the following equation [4]: were installed was the optimum design for the axle/wheel structure. In
the rail case, the optimum cathodic protection design for the rail was a
87600W
μ m /yr = 12×5×2 cm (865.2 g) Zn anode installed at 6 m intervals based on
DAT (11)
potential and anode life. The influence which degrades the corrosion
where W is the weight loss in grams, D is the density of the low carbon protection and the life of anodes at the certain location of the structure,
steel (7.85 g/cm3), A is the exposed area in cm2 (axle/wheel: 239 cm2, due to the increase of the protection area, was indicated in the
rail: 76 cm2), and T is the time in hours (1080 h). Weight loss occurred simulation of the combined structure (axle/wheel and rail). Although
on the unprotected structure, while weight loss was not measured in the axle/wheel and rail were not fixed to a specific location, satisfactory
the protected structure. The corrosion rates for unprotected axle/wheel the cathodic protection could be achieved. The cathodic protection
and rail structures were 148 and 177 μ m/yr, respectively. This means design from the simulation was verified by physical miniature tests.
that the corrosion only occurred in the unprotected structure. This The unprotected physical miniature specimen was corroded and
indicates that the cathodic protection design was adequately applied, showed corrosion products on the surface, whereas the protected
and the simulation results well reflected the actual state. miniature physical specimen formed calcareous deposits on the surface
without weight loss. Thus, the simulated cathodic protection design
results showed trends similar to those of the experiments, and these
5. Conclusion results can be applied to the cathodic protection design of an actual rail
canal system.
In the present work, the cathodic protection design of axles, wheels
and rails used in rail canal systems in seawater was carried out using

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Y.-S. Kim et al. Engineering Analysis with Boundary Elements 77 (2017) 36–48

Fig. 15. Physical miniature models of axle/wheel and rail, (a) unprotected and (b) protected, after 45 days immersion in synthetic seawater.

Acknowledgments
Table 4
Corrosion rates of axle/wheel and rail physical miniature by weight loss method. 1. This research was supported by a Grant from R & D Program of the
Physical miniature Initial Weight after Initial weight Corrosion rate
Korea Railroad Research Institute, Republic of Korea.
weight immersion −weight after 2. This research was supported by a Global Ph.D. Fellowship Program
(g) (g) immersion ( μ m/yr) through the National Research Foundation of Korea (NRF) funded
(g) by the Ministry of Education (2015H1A2A1033362).
Axle/ Protected 611.1 611.1 0 –
w- Unprotected 608.2 2.9 148.4 References
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