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    This document contains 3 homework problems for a physical chemistry class. Students are asked to (1) calculate the normalization constant for a particle in a 1D box wavefunction, (2) find the expectation values and standard deviation for the first excited state of a particle in a 1D box, and (3) calculate the energy levels and transition wavelength for an electron in the π-network of n-hexatriene using a particle in a box model. The homework is due on April 27th at 5:00pm and should be submitted to teaching assistant Shen Boyue in room H231.

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    HW01 1082 PCI_7D

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    This document contains 3 homework problems for a physical chemistry class. Students are asked to (1) calculate the normalization constant for a particle in a 1D box wavefunction, (2) find the expectation values and standard deviation for the first excited state of a particle in a 1D box, and (3) calculate the energy levels and transition wavelength for an electron in the π-network of n-hexatriene using a particle in a box model. The homework is due on April 27th at 5:00pm and should be submitted to teaching assistant Shen Boyue in room H231.

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    © All Rights Reserved
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    12 views1 page

    HW01 1082 Pci - 7D

    Uploaded by

    張湧浩
    This document contains 3 homework problems for a physical chemistry class. Students are asked to (1) calculate the normalization constant for a particle in a 1D box wavefunction, (2) find the expectation values and standard deviation for the first excited state of a particle in a 1D box, and (3) calculate the energy levels and transition wavelength for an electron in the π-network of n-hexatriene using a particle in a box model. The homework is due on April 27th at 5:00pm and should be submitted to teaching assistant Shen Boyue in room H231.

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    © All Rights Reserved
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    Physical Chemistry I, (10802) | Homework ONE|

    FOCUS 7 Quantum theory 7D


    Hand your homework paper to 物化一 T.A. 沈伯叡 (H231)
    Due: April 27 (Mon.), by 17:00 pm

    𝑥 𝑥
    1. The function ψ(𝑥) = 𝐶 (1 − ) is an acceptable wave function for the particle in the one
    𝐿 𝐿

    dimensional infinite depth box of length L. Calculate the normalization constant C.


    2. The normalized wavefunction for particle in the one dimensional box at first excited state, n = 2
    2 2𝜋𝑥
    is , ψ(𝑥) = √ sin ( ). Find the expectation values x and x 2 . What is the standard
    𝐿 𝐿

    deviation of position, 𝜎𝑥 ?
    3. Using the particle in the box model, calculate the energy levels of the π-network in n-hexatriene,
    C6H8, To calculate the box length, assume that the molecule is linear and use the values 135 and
    154 pm for C=C and C–C bonds. What is the wavelength of light required to induce an electron
    transition from the HOME state to the excited LUMO state?

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