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4/29/2020 Standard conditions for temperature and pressure - Wikipedia

Standard conditions for temperature and


pressure
Standard conditions for temperature and pressure are standard sets of conditions for
experimental measurements to be established to allow comparisons to be made between different
sets of data. The most used standards are those of the International Union of Pure and Applied
Chemistry (IUPAC) and the National Institute of Standards and Technology (NIST), although these
are not universally accepted standards. Other organizations have established a variety of alternative
definitions for their standard reference conditions.

In chemistry, IUPAC changed the definition of standard temperature and pressure (STP) in
1982:[1]

Until 1982, STP was defined as a temperature of 273.15 K (0 °C, 32 °F) and an absolute
pressure of exactly 1 atm (101.325 kPa).
Since 1982, STP is defined as a temperature of 273.15 K (0 °C, 32 °F) and an absolute pressure
of exactly 105 Pa (100 kPa, 1 bar).

STP should not be confused with the standard state commonly used in thermodynamic evaluations of
the Gibbs energy of a reaction.

NIST uses a temperature of 20 °C (293.15 K, 68 °F) and an absolute pressure of 1 atm (14.696 psi,
101.325 kPa). This standard is also called normal temperature and pressure (abbreviated as
NTP).

The International Standard Metric Conditions for natural gas and similar fluids are 288.15 K
(15.00 °C; 59.00 °F) and 101.325 kPa.[2]

In industry and commerce, standard conditions for temperature and pressure are often necessary to
define the standard reference conditions to express the volumes of gases and liquids and related
quantities such as the rate of volumetric flow (the volumes of gases vary significantly with
temperature and pressure): standard cubic meters per second (sm3/s), and normal cubic meters per
second (nm3/s).

However, many technical publications (books, journals, advertisements for equipment and
machinery) simply state "standard conditions" without specifying them; often substituting the term
with older "normal conditions", or "NC". In special cases this can lead to confusion and errors. Good
practice always incorporates the reference conditions of temperature and pressure. If not stated,
some room environment conditions are supposed, close to 1 atm pressure, 293 К (20 °C), and 0%
humidity.

Contents
Definitions
Past uses
Current use
International Standard Atmosphere
Standard laboratory conditions

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Molar volume of a gas


See also
Notes
References
External links

Definitions

Past uses

Before 1918, many professionals and scientists using the metric system of units defined the standard
reference conditions of temperature and pressure for expressing gas volumes as being 15 °C
(288.15 K; 59.00 °F) and 101.325 kPa (1.00 atm; 760 Torr). During those same years, the most
commonly used standard reference conditions for people using the imperial or U.S. customary
systems was 60 °F (15.56 °C; 288.71 K) and 14.696 psi (1 atm) because it was almost universally used
by the oil and gas industries worldwide. The above definitions are no longer the most commonly used
in either system of units.[3]

Current use

Many different definitions of standard reference conditions are currently being used by organizations
all over the world. The table below lists a few of them, but there are more. Some of these
organizations used other standards in the past. For example, IUPAC has, since 1982, defined
standard reference conditions as being 0 °C and 100 kPa (1 bar), in contrast to its old standard of 0 °C
and 101.325 kPa (1 atm).[4] The new value is the mean atmospheric pressure at an altitude of about
112 metres, which closer to the worldwide median altitude of human habitation (194 m).

Natural gas companies in Europe, Australia, and South America have adopted 15 °C (59 °F) and
101.325 kPa (14.696 psi) as their standard gas volume reference conditions, used as the base values
for defining the standard cubic meter.[5][6][7] Also, the International Organization for Standardization
(ISO), the United States Environmental Protection Agency (EPA) and National Institute of Standards
and Technology (NIST) each have more than one definition of standard reference conditions in their
various standards and regulations.

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Standard reference conditions in current use

Temperature Pressure Relative


Humidity Publishing or establishing entity
°C °F kPa mmHg psi inHg (%)

0 32 100.000 750.06 14.5038 29.530 IUPAC (STP) since 1982[1]

NIST,[8] ISO 10780,[9] formerly IUPAC


0 32 101.325 760.00 14.6959 29.921
(STP) until 1982[1]

ICAO's ISA,[10] ISO 13443,[2] EEA,[11]


15 59 101.325 760.00 14.6959 29.921 0[2][10]
EGIA (SI Definition)[12]

EPA,[13] NIST.[14] This is also called NTP,


20 68 101.325 760.00 14.6959 29.921
Normal Temperature and Pressure.[15]
American Association of Physicists in
22 72 101.325 760.00 14.6959 29.921 20–80
Medicine[16]
25 77 100.000 750.06 14.5038 29.530 IUPAC (SATP)

25 77 101.325 760.00 14.6959 29.921 EPA[17]

20 68 100.000 750.06 14.5038 29.530 0 CAGI[18]

15 59 100.000 750.06 14.5038 29.530 SPE[19]

20 68 101.3 760 14.69 29.9 50 ISO 5011[20]


20 68 101.33 760.0 14.696 29.92 0 GOST 2939-63

16 60 101.33 760.0 14.696 29.92 SPE,[19] U.S. OSHA,[21] SCAQMD[22]

16 60 101.6 762 14.73 30.0 EGIA (Imperial System Definition)[12]

16 60 101 760 14.7 30 U.S. DOT (SCF)[23]

15 59 99.99 750.0 14.503 29.53 78 U.S. Army Standard Metro[24][a]

15 59 101.33 760.0 14.696 29.92 60 ISO 2314,[25] ISO 3977-2[26]

AMCA,[27][b] air density = 0.075 lbm/ft3.


This AMCA standard applies only to air;
21 70 101.3 760 14.70 29.92 0
Compressed Gas Association [CGA]
applies to industrial gas use in USA[28]

15 59 101.3 760 14.70 29.92 Federal Aviation Administration (FAA)[29]

20 68 101.325 760.00 14.6959 29.921 0 EN 14511-1:2013[30]

ISO 2533:1975[31] ISO 13443:2005[32],


15 59 101.325 760.00 14.6959 29.921 0
ISO 7504:2015[33]

0 32 101.325 760.00 14.6959 29.921 0 DIN 1343:1990[34]

Note: This table needs careful checking. For example the American Association of Physicists in
Medicine paper quotes a temperature of 22°C. It does not quote a Fahrenheit equivalent. The correct
Fahrenheit equivalent is 71.6°F, not 72°F as stated in the table.

Abbreviations:

EGIA: Electricity and Gas Inspection Act (of Canada)


SATP: Standard Ambient Temperature and Pressure
SCF: Standard Cubic Foot

International Standard Atmosphere


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In aeronautics and fluid dynamics the "International Standard Atmosphere" (ISA) is a specification of
pressure, temperature, density, and speed of sound at each altitude. The International Standard
Atmosphere is representative of atmospheric conditions at mid latitudes. In the USA this information
is specified the U.S. Standard Atmosphere which is identical to the "International Standard
Atmosphere" at all altitudes up to 65,000 feet above sea level.

Standard laboratory conditions


Because many definitions of standard temperature and pressure differ in temperature significantly
from standard laboratory temperatures (e.g. 0 °C vs. ~25 °C), reference is often made to "standard
laboratory conditions" (a term deliberately chosen to be different from the term "standard conditions
for temperature and pressure", despite its semantic near identity when interpreted literally).
However, what is a "standard" laboratory temperature and pressure is inevitably geography-bound,
given that different parts of the world differ in climate, altitude and the degree of use of heat/cooling
in the workplace. For example, schools in New South Wales, Australia use 25 °C at 100 kPa for
standard laboratory conditions.[35] ASTM International has published Standard ASTM E41-
Terminology Relating to Conditioning and hundreds of special conditions for particular materials and
test methods. Other standards organizations also have specialized standard test conditions.

Molar volume of a gas


It is equally as important to indicate the applicable reference conditions of temperature and pressure
when stating the molar volume of a gas[36] as it is when expressing a gas volume or volumetric flow
rate. Stating the molar volume of a gas without indicating the reference conditions of temperature
and pressure has very little meaning and can cause confusion.

The molar volume of gases around STP and at atmospheric pressure can be calculated with an
accuracy that is usually sufficient by using the ideal gas law. The molar volume of any ideal gas may
be calculated at various standard reference conditions as shown below:

Vm = 8.3145 × 273.15 / 101.325 = 22.414 dm3/mol at 0 °C and 101.325 kPa


Vm = 8.3145 × 273.15 / 100.000 = 22.711 dm3/mol at 0 °C and 100 kPa
Vm = 8.3145 × 298.15 / 101.325 = 24.466 dm3/mol at 25 °C and 101.325 kPa
Vm = 8.3145 × 298.15 / 100.000 = 24.790 dm3/mol at 25 °C and 100 kPa
Vm = 10.7316 × 519.67 / 14.696 = 379.48 ft3/lbmol at 60 °F and 14.696 psi (or about
0.8366 ft3/gram mole)
Vm = 10.7316 × 519.67 / 14.730 = 378.61 ft3/lbmol at 60 °F and 14.73 psi

Technical literature can be confusing because many authors fail to explain whether they are using the
ideal gas constant R, or the specific gas constant Rs. The relationship between the two constants is Rs
= R / m, where m is the molecular mass of the gas.

The US Standard Atmosphere (USSA) uses 8.31432 m3·Pa/(mol·K) as the value of R. However, the
USSA,1976 does recognize that this value is not consistent with the values of the Avogadro constant
and the Boltzmann constant.[37]

See also
Environmental chamber
ISO 1 – standard reference temperature for geometric product specifications
Standard state
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Standard sea level


Reference atmospheric model
Room temperature

Notes
a. The pressure is specified as 750 mmHg. However, the mmHg is temperature-dependent, since
mercury expands as temperature goes up. Here the values for the 0–20 °C range are given.
b. The standard is given as 29.92 inHg at an unspecified temperature. This most likely corresponds
to a standard pressure of 101.325 kPa, converted into ~29.921 inHg at 32 °F (0 °C).

References
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External links
"Standard conditions for gases" (http://goldbook.iupac.org/S05910.html) from the IUPAC Gold
Book.
"Standard pressure" (http://goldbook.iupac.org/S05921.html) from the IUPAC Gold Book.
"STP" (http://goldbook.iupac.org/S06036.html) from the IUPAC Gold Book.
"Standard state" (http://goldbook.iupac.org/S05925.html) from the IUPAC Gold Book.
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