1) Express the titer of a 0.

05000 M KMnO4 solution in

mg Fe2O3/mL KMnO4. The molar mass of Fe2O3 is
159.69 g/mol. (3 points)

2) A sample of USP-grade citric acid (H3C6H5O7, three

titratable protons) is analyzed by titrating with
0.1087 M NaOH. If a 0.2678-g sample requires
38.31 mL for titration, what is the percent purity of
the preparation? The molar mass of citric acid is
192.13 g/mol. (3 points)
Find the pH during the titration of
20.00 mL of 0.1000 M triethylamine,
(CH3CH2)3N (Kb = 5.200 x 10–4), with
0.1000 M HCl solution after the
following additions of titrant:

1) 15.00 mL (3 points)
2) 20.00 mL (3 points)
Oxalic acid (Ka1 = 5.60 x 10–2; Ka2 = 5.40 x 10–5)
is the simplest diprotic carboxylic acid. Its
commercial uses include bleaching straw and
leather and removing rust and ink stains. For
a 0.150 M H2C2O4 solution, calculate the
following:

1) pH (2 points);
2) [H2C2O4] (2 points); and
3) [C2O42–] (2 points).
A 1.200 g sample of an impure mixture of Na2CO3
(105.9889 g/mol) and NaHCO3 (84.007 g/mol) containing
only inert impurities is dissolved and titrated cold with
0.5000 M HCl. With phenolphthalein as indicator, the
solution turns colorless after addition of 15.00 mL of the
acid. Methyl orange is then added, and 22.00 mL more of
the acid is required to change the color of this indicator.
What is the percentage of Na2CO3 and of NaHCO3 in the
sample? (6 points)
Calculate pCl for the titration of 100.0 mL of
0.1000 M KCl with 0.1000 M AgNO₃ after
the addition of the following volumes of
reagent:

(a) 20.00 mL (2 points);

(b) 100.00 mL (2 points); and
(c) 110.00 mL (2 points).

Ksp of AgCl = 1.82 x 10–10