SKEMA JAWAPAN MODUL ANALISIS BERTOPIK KIMIA TINGKATAN 5 KOLEKSI SOALAN PERCUBAAN KIMIA SPM 2016 Disusun seikhlas hati: G4 Mohd Fazdli Bin Mohd Nor SMK Pesisiran Perdana, Tangkak, Johor dd MWS"pzeynby19s Skema Jawapan Modul Analisis Bertopik ‘Soolan Percuboan SPM Negeri 2016 [Terengganu 2016, No 4] 47 @ ‘Change of volume of gas released per time taken al ©) Mg + 2HCl — MgC + He 1 2 © ‘Size of reactant / Total surface area il (d) | (| Experiment! 50 = 10.em? min 10.167 cm? s* 3 Experiment i 50 = 16.667 cm? min* // 0.278 cm? s* 3 1. Correct value for both experiment 1 2. Correct unit for both value 1 2 (i) | 1. Size of magnesium in Experiment Ilis smaller than Experiment I // Total surface area of magnesium in Experiment Il is greater than Experiment | 1 2. Frequency of collision between magnesium atoms and hydrogen ions, H’ in Experiment Il is higher than Experiment |. i 3. Frequency of effective collision between magnesium atoms and hydrogen ions, H” in Experiment Il is higher than Experiment | 1 © The mass of magnesium in both experiments are the same 1 TOTAL 10 IMRSM 2016, No 5] Mark No Mark Scheme [Sab | Tora 5(a) | Hydrogen 1 1 (b) | PI. Axis with label and unit 1 P2. Uniform scale smooth curve and size > ¥ of graph paper 1 P3. All points transferred corretly 1 3 (© @ | PI. Show tangent on the graph 1 2. Rate of reaction = 0.183 em's" + 0.05 with correct unit, 1 (i) | 45,00em* 77 0.214 em's™ 1 3 210s ©©Mohd Fazdli Bin Mohd Nor, SMK Pesisiran Perdana, Tonghak SPM 2016, Kimia 4541 Ases ‘Skema Jawapan Modul Analisis Bertopik ‘Soolan Percuboan SPM Negeri 2016 (OW | Temperature!” Catalyst 7 Use [correct volume] of [correct molarity higher than 0.1 mol dm®] of hydrochloric acid {to obtain the same number of mole] 1 1 (e.g. 25 om’ of 2.0 mol dm? of HCI) (i) [Factor : Temperature] PI. Kinetic energy of particles is higher in K 1 P2. Frequency of collision between hydrogen ion and. ‘magnesium atom is higher in K 1 3. Frequency of effective collision between hydrogen ion and magnesium atom is higher in K 1 Max 2 Or [Factor : Catalyst] 1. Catalyst/copper({1) sulphate provide alternative path with lower activation energy P2. More colliding particles achieve the lower activation energy 3. Frequency of effective collision between hydrogen ion and magnesium atom is higher in K Or [Factor : concentration] 1. The number of particles per unit volume is higher in K P2. Frequency of collision between hydrogen ion and magnesium atom is higher in K 3. Frequency of effective collision between hydrogen ion and magnesium atom is higher in K (iil) | The number of mole of hydrochloric acid/ Hydrogen ion/H in Mis half than in L/ [0.025 mol Total 1 (©Mohd Fazdii Bin Mohd Nor, SMK Pesisiran Perdana, Tonghak SPM 2016, Kimia 4541 A‘Skema Jawapan Modul Analisis Bertopik ‘Soolan Percuboan SPM Negeri 2016 Carbon Compound [Pahang 2016, No 6] Question Answer Sub- | Mark Number Mark 6 | @) Carbon dioxide 1 I (b) | @ Hydroxyl group //-OH 1 1 Gi) H HH tt od 1 ~—T HH OH 1-Propanol(n-propanol) ivi He—eme oa HH OH 2-Propanol (isopropanol) “accept without name (© @ Oxidation 1 1 Gil) K2Cr07 7KMnOs *accept 1 1 name (@) | @_ Propene 1 1 (i) 1. Functional diagram 1 2. label 1 2 Pate gs propere Propene soaked into miner © Ethanol and butanoie acid TA 2 TOTAL ul (©Mohd Fazdii Bin Mohd Nor, SMK Pesisiran Perdana, Tonghak SPM 2016, Kimia 4541 A dd WS pzeyn6y104 ‘Skema Jawapan Modul Analisis Bertopik ‘Soolan Percuboan SPM Negeri 2016 [Negeri Sembilan 2016, No 6] Question Mark scheme Sub Mark Total mark 6(a) Able 10 the meaning of carbon compounds Sample Answer ‘Compound that contains carbon as its constituent element 6(b) ‘Able to name of Substance X, ¥ and Z based on TUPAC nomenclanure Answer X: Propane Y: — Propan-I-ol Z: — Propene 6(e) Able fo dravw the structural formula for isomer of Substance ¥ (propan-I-ol) Answer od) Able fo draw a labelled diagram apparatus set-up for dehydration alcohol Answer Glass wool soaked with Y/propanol Heat 1, Functional diagram 2. Correct label: Propanol, Heat, Porcelain chip and water 6(e(i) Able to State the observations for both test tube Sample Answer Z change brown colour of bromine water to colourless and Xu colour of bromine water ow ‘Able to explain the observation Sample Answer 1. Zs unsaturated hydrocarbon and X is saturated hydrocarbon 2, Z undergoes addition reaction with bromine / bromination and X does not react with bromine water Total 10 (©Mohd Fazdii Bin Mohd Nor, SMK Pesisiran Perdana, Tonghak SPM 2016, Kimia 4541 A[Perlis 2016, No 4] a ‘Skema Jawapan Modul Analisis Bertopik ‘Soolan Percuboan SPM Negeri 2016 Question “Answer Mark Number 4 [@@ | Chk. : OH 1 i) _ | Hydroxyl 7 -OF 1 MG] Butene I di) H oH H H Pode H-C=C-C-C-H 1 | | HOH (© _ | Potassium dichromate (VI) solution/7 T Potassium mangganate (VII) solution Gi)_| Orange to green i Purple to clourless 1 (2G) | Butyl propanoate r (i) | GHCOOH + GHOH —6:H.COOC.H + H.0 1 © Number of mole of butene = 11.2/56 0.2 mol 1 1.0 mole of butene burt to produce 4.0 mole of carbon dioxide 0.2 mole of butene burnt to produce 0.8 mole of carbon dioxide 1 Number of carbon dioxide molecules = 0.8 mol x 6.02 x 10 = 4816x 10” molecules 1 Total | 11 [Pulau Pinang 2016, No 5] Question Mark Scheme Sub | Total Mark | Mark s@) Fermentation 1 1 Penapaian &) Ethene // Frena 1 © Method-1 * Observation -1 Sample answer: | Ethene gas is passed through bromine water. i Gas etena diatir melalui air bromin. 2.Brown solution turns colourless 1 3 Larutan perang menjadi tidak berwarna © | @ | Ethanoic acid i Asid eranoik T I (©Mohd Fazdii Bin Mohd Nor, SMK Pesisiran Perdana, Tonghak SPM 2016, Kimia 4541 A6 ‘Skema Jawapan Modul Analisis Bertopik ‘Soolan Percuboan SPM Negeri 2016 H 1 1 oO ey H—c—c \ | ‘O—H H (d) (i) | Label war in and water out in the diagram correctly. 1 1 (i | Ethyl ethanoate // etil eranoar_r: ester T 1 (ii_| Formula of product and reactant ) * Balance equation I * Answer 1 |2 CH:COOH + C3HOH > CH:COOC3Hs + H30 (iy) | To make perfume // food flavouring 1 1 ‘Membuat minyak wangi /perisa makanan Total | it IMRSM 2016, No 2(4)] (@ @) | Fermentation 1 Alcohol 1 C:H;OH ——>C2Hs + 120 1 Porcelain chips! pumice stone// aluminium oxide! 1 concentrated sulphuric acid aformula [SBP 2016, No 5] Question Answer Mark 3] (a) @) | [Able to state the meaning of isomer correctly Sample answer: Isomers are compounds with the same molecular formula but 1 different structural formula (©Mohd Fazdii Bin Mohd Nor, SMK Pesisiran Perdana, Tonghak SPM 2016, Kimia 4541 Are ‘Skema Jawapan Modul Analisis Bertopik ‘Soolan Percuboan SPM Negeri 2016 Gi)_| [Able io state the name of the compounds by using IUPAC nomenclature correctly Answer: P: Butan-I-ol 1 Q: Butan-2-ol 1 (iii) | [Able 10 drarw the structural formula for another isomer of the carbon compound correctly} Answer: (6) @ | [Able to write a balance chemical equation for the reaction involve correctly] Answer: CiHoOH + 602 4CO2 + SH2O 1, Correct chemical formula for reactants and products 1 2. Balance chemical equation 1 (il) [able to describe briefly a confirmatory test for the gas released correctly] Sample answer: 1, Flow the gas into lime water 1 2. Lime water turns chalky//cloudy 1 ©) [able to calculate the empirical formula of compound R correctly Answer: Element ce H Mass, % 85.7 143 Number of mole 85.7/12 143/1 =7.14 z Ratio 1 i Empirical formula of R = CHz Total) 11 (©Mohd Fazdii Bin Mohd Nor, SMK Pesisiran Perdana, Tonghak SPM 2016, Kimia 4541 A8 ‘Skema Jawapan Modul Analisis Bertopik ‘Soolan Percuboan SPM Negeri 2016 [JUS Pahang 2016, No 6] ‘Question _[ Answer Sub mark | marks 6(a) (CiH2a:1OHL 1 (b) ‘Compound Q : Propene //Propena Compound R : Propanoie acid //Asid propanoik Compound S : Ethyl propanoate // etl propanoat 3 oO 1. Functional apparatus 2. Label eB Porcelain chip Glass wool ‘Soaked in os een Compan Heat water (| @ | Acidified Potassium mangganate (VIT) /KMn0, 77 T 7 Acidified Potassium dichromate (VI) / K2Cr:07 T. Correct formulae of reactants and products i (ii) | 2. Balance equation 1 2 CsHOH +2[0] + CHsCOOH + 20 ©] @__ | Carboxylate //- COO - i i T 1 i. / H H—cC—c—c 4 pot Note HOH eee ae I ot HOH TOTAL iL [Kedah 2016, No 5] 3 (a)_| 2-methylbut-1,3-diene / 2-metilbut-1,3-diena 1 1 (b) |G) Polymerization/ pempolimeran 1 1 ‘i 4 OF oH 1 | c | 7 He) 1 1 (©_1@ [A athanoie acid/any suitable asid I Mona Foz Bin Mohd Ner, SMK Pessiran Perdare,Tongkak ‘SPM 2016, Kimia 4541 Ae dd WS pzeyn6y10on ‘Skema Jawapan Modul Analisis Bertopik ‘Soolan Percuboan SPM Negeri 2016 Avid etanoik) apa-apa asid yang sesuai T 2 B: ammonia solution//any suitable alkali Ammonia / apa-ape alkali yang sesuat (i)_| T-Reaction of bacteria inthe air produce an acid, I 2.Presence of H’ ion neutralize the negative charge of latex. 1 2 particles 1-Tindak balas bakteria dalam udara menghasilkan statu asid 2kehadiran ion H meneutralkan cas negatif pada zarah getah @/® TL i 7 (i) Vulcanised rubber is - harder = high resistant to heat = not easily oxidized. Getah tervulkan 2 = lebih kuat = mempunyai daya ketahanan terhadap haba = tidak mudah dioksidakan. (Any two) 2 2 ii) Vulcanised rubber Total mn [Terengganu 2016, No 6] 6] @ | @ | Copper 1 (i) | The concentration / number of copper ion decrease 1 (ij. | The oxidation number of magnesium change from 0 to +2 7 The oxidation number of copper change from +2 to 0. 1 {Change in oxidation number] d 2 (vy) | Mg + CuSO, — MgSO.+ Cu 7 (W) | No reaction. 7 Copper is less electropositive than magnesium. 1 2 (b) | (i) | Presence of oxygen and water. 1 (©Mohd Fazdii Bin Mohd Nor, SMK Pesisiran Perdana, Tonghak SPM 2016, Kimia 4541 A10 ‘Skema Jawapan Modul Analisis Bertopik ‘Soolan Percuboan SPM Negeri 2016 qi) Water droplet Iron 1. Label for iron, water and oxygen 1 2. lonization of iron in the water droplet (at anode) i 3. Flow of electron in the iron to the edge of water droplet 1] 3 TOTAL 4 [Perlis 2016, No 5) Question ‘Answer Mark Number 3 [(@)___ | Acidified Potassium manganate(VI) (by) 47 ©), reduction (a)G) | Colourless solution tun brown Gi) (2 > b + 26 (ii)_| Todide ion release electron @ ‘To allow the flow of ion from both electrolytes 0 Functional diagram of simple cell Label Total 10 [Kedah 2016, No 6] 6 1@ Allows the flow of ions T T Membenarkan ion-ion mengalir. © [O [46 043 1 T +6 kepada +3 Reduction I T Penurunan © [@_[Fe"re" Fe 1 1 ‘Add a fow drops of sodium hydroxide solution into the solution at carbon electrode X 1 Brown precipitate form. 1 Tambahkan beberapa titis larutan natrium hidroksida ke dalam larutan pada elektrod karbon X. 1 Mendakanperangterbentuk 1 2 Note: Accept any suitable reagents and correct observation respectively. @/0 |P.QSHR I 1 = Copper 1 (©Mohd Fazdii Bin Mohd Nor, SMK Pesisiran Perdana, Tonghak SPM 2016, Kimia 4541 ArT ‘Skemna Jamapan Modul Analisis Bertopk ‘Solan Percuboon SPM Negeri 2016 = Oxidizing agent = Kuprum - Agen pengoksidaan 1 Sulphuric acid Asia sulfur —=_ Flat-bottomed flask Kelalang berdasar rata Zine Zink Funetional diagram Correct label Gambarajah berfungsi Label yang betul TOTAL, i [Pulau Pinang 2016, No 6] Question Mark Scheme Sub’ Total 6(a) Reaction that involves oxidation and reduction occur simultaneously. Tindak balas yang melibatkan pengoksidaan dan penurunan berlaku serentak, @) @ Electrode P / elekirod P: Chet 20> 2CT Electrode Q / elektrodQ: 21° I+ 2€ (i) Char > 2CF +h © Show the arrow direction of electron transfer from electrode Q to P in Diagram 6 Tunjukkan arah anak panah pemindahan elektron dari elektrod Q ke P dalam Rajah 6 @ Electrode P / elektrod P: Pale yellow solution tums colourless Larutan kuning pudar menjadi tidak herwarna, Electrode Q / elektrodQ: Colourless solution turns to brown. Larutan tidak berwarna berubah menjadi erang. (©Mohd Fazdii Bin Mohd Nor, SMK Pesisiran Perdana, Tonghak SPM 2016, Kimia 4541 Ane ‘Skema Jawapan Modul Analisis Bertopik ‘Soolan Percuboan SPM Negeri 2016 © Potassium iodide solution / Larutan Kalium iodide T 1 iodide ion /ion iodide Oo ‘Add several drops of starch solution, T 2 The solution turns dark blue. ! Titis beberapa tik larutan kanji Larutan bertukar menjadi biru ta. @ Bromine water! Air bromin T 7 Total | 11 [SBP 2016, No 6] Question Answer Mark 6] (a) |i) (Able 10 state the negative terminal correctly) Gil) | [Able to state the rote of bromine water correctly] Answer: Oxidising agent 1 (ii) | [Able to explain why bromine water act as oxidising agent correctly] Sample answer: 1, Bromine undergoes reduction 2. Oxidation number of bromine decreased from 0 to -1 1 1/Bromine atom receive electron to form bromide ion (b) | [Able to draw the arrow to show the direction of electron flow correctly] Sample answer: carbon arton x thon) suighate solution ron feta) slot Dilute sulphur aca ‘sid sulrk car ©) | [able t0 describe briefly a chemical test to identify cation present correctly} Sample answer: 1, Add NaOH solution // ammonia aqueous in excess// add potassium hexacyanoferrate({I1)//potassium thiocyanate solution 1 2. Brown precipitate which cannot dissolve in excess NaQH/ NH3(aq)// Dark blue precipitate// Blood red coloration 1 (©Mohd Fazdii Bin Mohd Nor, SMK Pesisiran Perdana, Tonghak SPM 2016, Kimia 4541 A13 ‘Skema Jawapan Modul Analisis Bertopik ‘Soolan Percuboan SPM Negeri 2016 d) e) [able to write the overall ionic equation correctly] Answer: 2Fe + Bro 2Fe + 2Br 1 + Correct formula reactants and products + Balanced equation 1 [Able to draw a labelled diagram for the apparatus set-up to show the electron’ transfer at a distance correctly] Sample answer; Carbon idified potassium manganate(VID) solution Sodium iodide solution Dilute sulphuric acid + Functional diagram + Correct label Total | 11 [MRSM 2016, No 6] (a) ] +5 1 (ii) | Ps / Phosphorus 1 Oxidation number of phosphorus increases from 0 to #5 T 3 Blue 1 PI, Copper(Il) ion is reduced // gain / receive electron to form copper atom 1 P2. The concentration of copper(II) ion decreases 1 (iii) | PI. Mg/ Al Zn/ [any metal more electropositive than copper] 1 P2.Mg + Cu Mg” + Cu 1 5 ttohd Fazeli Bin Mohd Nor, SME Pesisiran Perdana, Tengkak ‘SPM 2016, Kimia 4541 A dd WS pzeyn6y1014 ‘Skema Jawapan Modul Analisis Bertopik ‘Soolan Percuboan SPM Negeri 2016 (based on the named metal G) (© @ | PI. Znis (more electropositive) /above iron in Electrochemical Series/ the anode // Zn has higher tendency to release electron P2. Zn is corrodedi/ sacrificed/ ionised/ oxidised// loss electron 1 (i) [Zn ——> Zn ¥ 2e T ; Total i ‘Chemical For Consumer [Perlis 2016, No 1] ‘Question ‘Answer Mark Number 1 [(@G@)_| Psychotherapeutic 1 (ii) | To treat infections caused by bacteria or fungi, 1 Gii)___[ Paracetamol 1 (b)()_| Potassium palmitate 1 (ii)___| P: soluble in grease/oil 1 Q: soluble in water. 1 (OG) _| Ethyl butanoat - flavouring agent // Sunset Yellow — colouring H1Ascobic acid ~ Antioxidant 141 (i)__| Aspartame 1 Total| 9 (©Mohd Fazdii Bin Mohd Nor, SMK Pesisiran Perdana, Tonghak SPM 2016, Kimia 4541 A