1 xe ‘it of EXERCISE-I (Conceptual Questions)| 1. azbac,an=y~90" 9x90" represents XTi tetragonal system {orthorhombic sustern {3} monoclinic sysiem (A) triclinic system z. must unsymmetrical crystal syst is — (1) Cubic 2) Hexagonal (3) Triclinic (4) Orthorhombie 3. — Bravais lattices are of 7 {1) 10 types (2)8 types (3) 7 types {4} 14 types ‘4, The crystal system of a compound with unit cell dimensions a = 0.387, 387 and c=0.504 am and a=P =90° and y=120° is : (1) Cubic (2) Hexagonal (3) Orthorhombie (4) Rhombohedric 5,—“In a simple cubic cell, each point om a corner is shared by (1)2 unit cells 2) L unit call (3) 8 unit cells (4)4 unit cals 6 Ina face centred cubic cell, an atom at the face contributes to the unit cell (1)1 part (2)1/2 part 3)1/4 part (4) 1/8 port XK ina body centred cubic cell, an atom at the body centre is shared by (2) 1 unit cell (2)2 unit cell 3) 3unit cals 44) 4 unit cells Which of the following type of cubic lattice has maximum number of atoms per unit cell ? (1) Simple cubic (2) Body centred cubic (G) Face centred cubic (4) Allhave same The number of atoms present in 2 unit cell of a monoatomic element of a simple cubic lattice, body: centred cubie and face centred cubic respectively are (1)8, 9and 14 (i, 2and4 (3)4, 5 and 6 (4)2, 3and 5 Chemistry Cr RC a 10. | Which one of the following is a primitive unit cell? (1) Simple cubic (2) bee: —~BHtce (4) bee and fec both _ Ina body centred eubic unit cell, a metal atorn at 7 the centre of the cell is surrounded by how many other metal atoms as (216 (3)12 A compound is formed by elements A and B. This crystallises in the cubic structure when atoms A are. at the comers of the cube and atoms B are at the centre of the body. The simplest formula of the compound is ()AB IAB, BAB A compound formed by elements A and has cubic structure in which A atoms are at the comers of ‘the cube and B atoms are at the face centres. The formula of the compound will be (AB, (2)AB @)AB, AB, Sodium metal crysallises in bec lattice with the cell ‘edge a = 42.29 A. What is the radius of sodium atom ? 11) 1.86 A BSA aa (4) AB, 1. ~~ (2) 1.90 12a we An element has bee structure having unit cells 12.08 x10, The number of atoms in these cells is, (1) 12.08 = 10% (2) 24.16 x10" (3) 48.38 102 (4) 12.08 x 10# 16. Ametal hasbec structure and the edge length of its unit cell is 3.04 A. The volume of the unit cell in com? will be (0) 1.6 x 10 em? (2)2.81 x10 cm* (3)6.02 x10 cm? (4) 6.6 X10 em? ‘An element having bee geometry has atomic mass, 50. Caleulate the density of the unit cel, ifits edge iength is 290 pm (1) 6.81 g cur® (2)3.403 cm* 18) 13.62 g am (4) 123g an 18 A metal (atomic mass = 50} has a body centred cubic crystal structure. The density of metal is 5.96 g cm, Find the volume of the unit cel. (1) 13.9 10% em? (2)27.8 x 10 cm* (3) 6.95 x 10% cm (4) 55.6 x 10 cm? FeoPre-Medical 19. DP An element crystalises in bee structure. The edge length of its unit cell is 288 pm. If the density of the crystal is 7.2 g crn’, what is the atomic mass of the element? (518 (3) 25.9 (2)103.6 (4) 207.2 ‘An element, density 6.8 g cm? occurs in bee structure with cell edge 290 pm. Calculate the number of atoms present in 200 g ofthe element (1)2.4x 102 (12x 102 (1.2 10" (2.4.x 108 ‘An element A crystallises in fee structure, 200 g of this element has 4.12 x 10% atoms. The density of Ais 7.2 cm Calculate the edge length of the unit call (1) 26.97 x10%em (2) 299.9 pm Q)5 x 10cm (4) 2.99 om Density of Li atom is 0.53 qem-3, The edge length of Li is 3.5 A. Find out the number of Li atoms in an unit cell. (N, = 6,023 x 1023), (M= 6.94. mol) a2 8 4 a6 23. /The coordination number of hexagonal closest 24, / packedthcp) structure is (12 210s ‘ae The ABAB close packing and ABC ABC close packing are respectively called as. (1) hexagonal close packingthcp) and cubic close packing {ecp) {2} cep and hep (3) body centred cubic (bec) packing and hexagonal close packing (hep) (4) hep and bee The space occupied in bee arrangement is (1) 74% (2) 70% (3) 68% (4) 60.4% 26/1 The vacant space in bee unit cell is (1) 32% (2) 10% (3) 23% (A) 46% 27. 28. ‘The space occupied by spheres of equal size in three dimensions in both hep and ccp arrangement is (1) 74% (2) 70% (4) 52.4% ‘The empty space in the hep and ecp is about (1) 26% (2) 30% 3) 35% 4) 40%, Which one of the following isnot a close packing ? (hep — (ecp (BY bee (A) Fe (3) 60.4%, 30, Close packing is maximum inthe crystal late of 31. By 41) Simple cubic. (2) Face centred (3) Body centred (4) Simple cubic and body centred Which of the following has hep structure ? (WAL Mg Cu NN All noble gases crystals in the cep structure except (1) Helium, (2) Neon 8) Argon {4} Krypton Ifthe coordination number of an element in its crystal lattice is 8, then packing is (I) fec (2) hep (3) bee (4) None of the above 34 35, 37. 38. 39. 41. A tetrahedral void in a crystal implies that (1) shape of the void is tetrahedral (2) molecules forming the vold are tetrahedral in shape (@) the void is surrounded tetrahedrally by four spheres (A) the void is surrounded by six spheres Ina closest packed lattice, the number of octahedral sites as compared to tetrahedral ones will be (1) Equal (2) Halt (3) Double (4) One fourth, ‘The coordination number of a cation occupying ‘an octahedral hole is (4 26 3)8 (4) 12 ‘The size of an octahedra! void formed in a closest packed lattice as compared to tetrahedral void is (1) Equal (2) Smaller (3) Larger (4) Not definite ‘The coordination number of a cation occupying a tetrahedral hole is (ya 26 as (a) 12 Number of tetrahedral voids per atom in a crystal lattice is ad (B2 (3)4 as ‘A compound contains P and Q elements. Atoms: Q are in cep arrangement while P occupy all tetrahedral sites. Formula of compound is (PQ (2)PQ, — B)P,Q_ (4) P,Q. If ‘2! is the number of atoms in the unit cell that represents the closest packing sequence ABCABC-, the number of tetrahedral vids in the uit cel is equal io (DZ (222 (32/2 (ayz/a —_—. Im erro nae oensonontee| sxomenuemesttsits MM versa \Sesotsae NcmoBeMe NcoaL 4S aac (mTorr mer oucrnounsvcna seme eee 49. 51. 52. ‘The limiting radius ratio for tetrahedral shape is (1) 0 to 0.155 (2}.0.155 to 0.225 (3)0.225%00.414 —(4)0.414 to 0.732 For an octahedral arrangement the lowest radius ratio limit is {10.155 (2)0.732 (3)0.414 (4) 0.225, If the radius ratio is in the range of 0.414 - 0.732 then the co-ordination number will be we (a4 G6 as In NaCl erystal r°/1° ratio is (04 (290.98 1.0 4} 0.52 ‘Which one of the following statements is incorrect about rock salt type ? (It has foc arrangement of Na* {2}Nar and Cl ions have a co-ordination number of 6:6 {3} unit cell of NaCl consists of four NaCl units (4) Ail halides of alkali metals have rock-salt type structure In sodium chloride, Cl-ions form cep arrangement. Which site does Na* ions will occupy in this structure ? . (1) Cubic (2) Tetragonal (3) Octahedral (4) Trigonal bipyramidal “The positions of Ct ions in NaCl structure are (1) Comers of the cube (2) Centres of faces of the cube £8)Comears as well as centros ofthe faeus ofthe cube (4) Edge centres of the eube The number of NaClunits present in a unit cell of NaClare Mt 4 The tetrahedral voids formed by cep arrangement of Ct-ions in rock sat structure are (1) Occupied by Na* ions (2) Occupied by Cr tons (3) Occupied by either Na’ or Ch ions (4) Vacant The structure of MgO is similar to NaCl. The co-ordination number of Mg is (2 (6 4 as ‘The co-ordination number of Cs* and Cl ions in CsCl structure is (4:4 Q)6:6 (2 as 38:8 (4)4:8 55. 37. 61. 64. Chemistry A unit cell of CsCl consists of (Q) ene CsCi unit (2} two CsClunits (3) four CsC1 units (4) eight CsCl units The NaCl structure can be converted into CsCl structure (1) by opplication of high pressure {2} by heating to 760K {Gi both by heat and pressure (4) the conversion is not possible TiCh has stmeture similar to CCI. The en-ordination umber of TI*is ae (26 3108 ‘The co-ordination number of Zn? and $* ions in, the zinc blende (ZnS) type structure is (4:4 (2)6:6 3)8:8 4:8 “The co-ordination number of calcium fluoride (CaF) type structure is (1-2 (24:4 84:8 8-4 ‘The number of formula units in an unit cell of fluorite is 2 24 36 as 4: 4 Co-ordination is found in (2S 2)CuCl 3) Aal- 4) Al Antifluorite structure is derived from fluorite structure by (1) Heating fluorite crystal lattice. (2) Subjecting fluorite structure to high pressure. Ghlnterchanging the positions of positive and negative ions inthe lattice, {4) All of the above A binary solid (A"B) hasa zinc blend structure with, B-ions constituting the latice and A* ions occupying 2586 tetrahedral holes. The formula of solid is. (AB 2)AB (BAB, (4) AB, The radius of Na‘ is 95 pm and that of CF ion is 181 pm, Hence the co-ordination number of Nat wall be 4a 6 (3)8 (4) 12 ‘The ionic radii of Rbt and Tare 1.46 and 2.16 A respectively. The most probable type of structure exhibited by itis (1) CsCl type (2) NaCl type @) 208 type. (4) CaP, type A binary solid (ABY) has a rock sak structure if the cege lenath is 400 pm and radius of cation (A°)is 75 pm, the radius of anion (Bis (1) 100 pa (2) 125 pm (3) 250 pr (4) 325 pmPre-Medical 65. A solid XY has a bee structure. If the 66. 67. 69. 70. n. fance of closest approach between the two atoms is 173 pin, the edge length of the cell is (1} 200 pm 2 4 pm (3) 142.2 pm (4) 2 pm If the distance between Na’ and Cr ions in NaCl crystal is ‘a! pm, what is the length of the cell edge? () 2a pm (2) a/2 pm (3} 4a pm (@)a/4 pm Potessium fluoride has NaChtype structure. What is the distance between K* and F* ions if it's cell edge ‘a! om? (1) 2acm (2)a/2 em (8) 4a.cm (4) a/4.cm KF has NaCl structure. Whatis the distance between K+and Fin KF if density is 2.48 g cm *? (1) 268.8 pm 2)537.5 pm (155.310 cm — 4) 5.375 em In a NaCl type crystal distance between Na and CT ion is 2.814 A and the density of solid is 2.167 q em then find out the value of Avogadro constant. (2) 6.05 x 10" (2}3.02 x 102 (3) 12.10 x 10% (4) 9.6 x10 The density of crystalline sodium chloride is 5.85 g cm? What Is the edge length of the unit cal, (1)4.06 «10cm. (2) 1.32 x 10-em 8)7.8x 10% (419.6 x10" ‘unit cell of sodium chloride has four formula units, ‘The edge length of unit cell is 0.6 nm. What is the density of sodium chloride ? (1) 7.60 g em? (2) 1.80 g cms (3) 9.609 cm (4) 6.38 gear EXERCISE-I (Conceptual Questions) IMPERFECTIONS IN SOutbS Ba 72, Atzero kelvin, most of the ionic crystals posses (1) Frenkel defect (2) Schoithy detect {3} Metal excess defect (4) No defect 73. Asa result of Schottky defect (2) theve isto effect on the density (2) density of the crystal increases (3} density of the crystal decreases (4) any of the above three can happen 74. Schottky as well as frenkel defects are observed in the erystal of (NaCl (2}AgBr (3) AgC]_—_ (4) MgCl, 75. Which one of the following is correct ? {1} Schottky defect lowers the density (2) Frenket defect increases the dielectric constant of the crystals (3) Stoichiometric defects make the crystals good. electrical conductors (4) All the three 76. Frenkel defect is generally observed in . (AgBr (2)Aql —{3)ZnS_— (4) ABof these. 77, Frenkel defect is found in erystals in which the radios ratio is (tow 13 15 (4) slightly less than unity 78. F-centres in an ionic crystal are (I) lattice sites containing electrons (2) interstitiat sites containing electrons (3) altice sites that are vacant (4) interstitial sites containing cations 79. The correct statement regarding F-centre is (1) Electrons are held in the lattice site of crystals {2} P-centre imparts colour to the crystal (3) Conductivity of the crystal increases due to Fecentre (4) Allthe three above ESET Sa Ii Boxonemmamoenecwcusa som sonar seietrsS E gs EXERCISE-II (Previous Year Questions) CCsBr erystalises in a body centred cubic lattice, The Unit cell length is 436.6 pm. Given that the atomic mass of Cs=133 and that of Br=80 amu and Avogedro number being 6.023 x 1025 mot! the density of CsBr is 2) 42.5 g em? 8) 8.25 g cm? (2) 0.425 g cms 44) 4.25 g cm? 5 ‘The Ca® and F* are located in CaF, crystal, respectively at face centred cubic lattice points and in (1) Tetrahedral voids (2) Half of tetrahedral voids (3) Octahedral voids (4) half of octahedral voids * ° - NaClis doped with 10~ mol% SrCl,, the concen- ‘ration of cation vacancies is ~ [rm -Concentration of vacancies. = 1G] (1) 6.02 x 105 molt (3) 6.02 x10” mot? (2) 6.02 x10" mot? (4) 6.02 x10 mol ‘The fraction of total volume occupied by the atoms present in a simple cube is ~ 5 mg Ose Ope mF 5 Percentage of free space in a boxy centred cubic units: (1) 32% (3) 28% JF a stands for the edge length of the cubic sys- tems: simple cubic, body centred cubic and face centred cubic, then the ratio of radi ofthe spheres in these system will be respectively, (2) 34% (4) 30% 1 1 oientets gh? 1 Bla: Baa) gatbaine 7. Chemistry Oe vee) Which of the following statement is not correct? (1) Motecutar solids are generally volatile (2) The numbers of carbon atoms in an unit cell of diamond is 8 (3) The number of Bravais lattices in which a cys: tal can be categorized is 14 (4) The iraction of the total volume occupied by the atoms in a primitive cells 0.48 ithium metal crystallises in a body centred cubic crystal. If the length of the side of the unit cell of lithium is 361 pm, the atomic radius ofthe lithium will be (1) 300.5 pm. (3) 151.8 pm Copper crystallises in a face-centred cubic lattice ‘with a unit celllength of 361 pen. What is the radius of copper atom in pm ? (1) 108 (3) 157 2} 240.8 pm @) 75.5 pm (2) 128 (4) 181 10. AB crystallizes in a body centred cubic lattice with edge length ‘a! equal to 387 pm. The distance ‘between two oppesitively charged ions in the lattice is= (1) 300 pm (3) 250 pm (2) 335 pm (4) 200 pm 1. In a trigonal crystal, which statement is incorrect (1) All the axial length and axial angle are equal (2) All the three axial lengths are equal (3) All the three axial angles are equal (4) Two axial angles are same and one is different 12, - A solid compound XY has NaCl structure. If the radius of the cation is 100 pm the radtus of the anion (Y°} will be = (1) 165.7 pm (2) 275.1 pm 3) 322.5 pm 4) 241.5 pm13. Schotthy defect is- (1) vacancy of ions (2 Delacolization of tons (3) Interstitial vacancy of ions (4) vacancy of only cation 14, The number of octehedtal void(s) peratom present in a cubie-close-packed structure is: a2 4 1 3 15. A metal crystallizes with a face-centered cubic lattice. The edge of the tmit cell is 408 pm. The diameter of the metal atom is: (2) 204 pm (4) 408 pm (1) 144 pm (3) 288 pm 16, Structure of a mixed oxide is cubic close-packed (cep). The cubic unit cell of mixed oxide is composed of oxide ions. One fourth of the tetrahedral voids: are occupied by divalent metal A and the octahedral voids are occupied by a monovalent metal B. The formula of the oxide is = (0) A,B.0, (8) ABO, (2) AB,Oy (4) A,BO, 17. InBCCstuctute, contribution of comer and central atom is = 1 ll ol =o wy ass it 1 Bs5 bs 18. Which of the following statements about the interstitial compounds is incorrect ? (1) They have higher melting points than the pure metal (2) They retain metalic conductivity (@) They are chemically reactive (4) They are such harder than the pure metal Eau 19. The number of carbon atoms per unit cell of diamond unit cell is - aa (4 8 ae 20, A metal has a fcc lattice. The edge length of the unit cell is 404 pm, The density of the metal is 2.72g cm™, The molar mass of the metal is :- {1} 20g mort (2) 40g mort (3) 30g mot! (4) 27q mot" 21. Ina solid, atom M occupy cep lattice and 1/3" of tetrahedral voids are occupied by atom N. Find formula of solid formed by M and N = MN, @MN, () MN, 8) MN, 22. Ifaisthe length of the side of a cube, the distance beiween the body centered atom and one corner atom in the cube will be 2 4 qQ) Bz ie) zr 23. Inany compound, atom B occupies in HCP packing and Ais 1/3rd of tetrahedral voids, Then emperical formula of compound is = (2) BA, (9) B, «BA, (3) AB 24. Agiven metal crystallizes out with a cubic structure having edge length of 361 pm. if there are four ‘metal atoms in one unit cell, what is the radius of one atom? (1) 127 pm (2) 80 pm (3) 108 pm (4) 40 pm 25, The vacant space in bee lattice unit cell is = (1) 23% (3) 26% {2} 32% (4) 4896 frm eco ¢ nano COMMS WCOUE sa ARCHESIT 2 cern pie inmsateneNe WHA SOW SUCRODIECSENS Chemistry 26. The correct statement regarding defects in] 30. The ionic radii of A+ and B- jons are caystaline solids is = 0.98 x 10-20m and 1.81 x 10% m, The coordination number of each ion in AB is = (1) Frenkel defect isa dislocation defect ay 6 2) 4 318 (4) 2 (2) Frenkel defect is found in halides of alkaline 31. _incaicium fluoride, having the fluorite structure, the metals ie i ut cium i 24) (8) Schottky defects have no effect on the density eon ane mbes for caium ion (Cal) and ot eoslin sls Henin (2)4 and 8 (4) Frenkel defects decrease the density of enstaline = (@)4 and 2 (4,6 and 6 solids 27. Defects in NaC & AgC| crystals are respectively (1) Schoithy, Frenkel (2) Frenkel, Schotthy (3) Both Schottky (4) Both Frenkel 1 32. Inacrysaline sold, X atoms occupy hep and th of tetrahedral voids are occupied by Y atoms. Then ‘empirical formula of crystalline solid is (W XY XY, BXY aX 33. A metal crystallizes in bec lattice having a radius 4A, Then what will be edge length of its unit cell? 8 What will be value of Try: +f in CsCl crystal hhaving edge length ‘a 16 oS Ons @ wi oon a RA 2) 163A 16 Its density is a aA (4) 16v2A 530 kg m3 and its atomic mass is 6.94 g mol Caleulate the edge length of a unit cel of Lithium metal. (Nq = 6.02 x 10% mol} (1) 154 pm 2) 352 pm 8) 527 pm (4) 264 pm (Previous Year Questions) Cea ee ee eee 34(Analytical Questions) 1. What is the % of vohime occupied by atom in bee (1) 58% (2) 68% (3) 78% (4) 88% 2. — Which of the following exists as covalent crystals in the solid state 7 (2) fodine (2) Stlicen. (3) Sulphur (4) Phosphorus, 3. Coordination number in hep is = 6 28 (3) 12 (4) 18 4. The lattice structure of group | elements is () fee (2) bee (3) hep (4) cop 5. Elements Na and Mg are Crystalizes in bee and fee respectively, then number of atoms of Na and Mg per unit cell are respectively = 24 (29,14 (3) 14,9 (a) 4.2 ee 3 ec a) Ina face centred cubic lattice, atom A occupies the comer positions only and atom B occupies the face centre positions. If one atom of B is missing from ‘one of the face centred points. the formula of the compound is = (1) AgBs (3) AB (2) ABs, (4) ABy An alloy of copper, silver and gold is found to have copper constituting the fec lattice, If siver atoms occupy the edge centres and gold is presentat body centre, the alloy has a formula (1) Cu,Ag,Au (2) Cu,Ag,fsu (3) CuAg Au (4) CuAgAu Expermentally it was found that a metal oxide has formula Mygg. Metal M. is present as M°* and M** in its oxide, Fraction of the metal which exists as M®* would be = () 7.01% 8) 6.05% (2) 4.08% (4) 5.08% ANSWER KEY {Peco 6 MURCEN HEA RS WOE ADSL DARCNE PSSi | | 2 | i : i Assertion Metals are generally good conductors of electricity. Reason =~ Electrical conductivity of metals is due to schottky defect. Ma (1B Bc ‘4D Assertion: Graphite isan example of tetragonal comystal system. Reason:- For a tetragonal system a=bzc, a=P=90", y= 120% (Da 2B gc iD Assertion « BCC & HCP has same packing efficiency Reason :- Both have same number of atoms per unit Cell and same arrangement, Wa (2B ac 4D EXERCISE-IV (Assertion & Reason) tee) Assertion :~ The number of tetrahedral void is double the number of octahedral voids, Reason :~ The size of the tetrahedral void is half of that of the octahedral void. yA QB 3) C @)D Assertion :- In CsCl crystal. the Co-ordination number of Cs* ions is 6. Reason :~ Ci ion in CsCl, adopt body centred cubic arrangement Ma OB ac (4)D Assertion = Na,O adopts structure similar to that of CaF, but positions of positive and negative fons are reversed. Reason = The structure of Na,0 Is also called antifvorte structure. Aa (QB BC @D Baa