Chemistry EXERCISE-I (Conceptual Questions)| Build Up Your Understanding Strong electrolyte are those which : (1) dissolve readily in water (2) conduct electricity {3) dissociate into ions even at high concentration {4) dissociate into ions at high dition 2, — Molten sodium chloride conducts electricity due to (2) free ions (3) free molecules (@) free atoms of Na and Cl 8. Electrolytic conduction is due to the movement of : (1) molecules (2) atoms (3} ions (electrons 4, — Which of the following solutions of KCI has the lowest value of equivalent conductance ? aim (2}0.1M (3).01M (4).001M 5. Inthe equation A = sp. cond. xV, IF Vis the volume nema Legale Becaerhe en Viora Ta 7 sohtion will be = wiicee, (2) 100 c.c. (3) 1000 cc. (4) 10,000 c.c. 6. If the specific resistance of a solution of concentration C g equivalent litre’ is R, then its equivalent conductance is: 1008 aS a0 1000 Re ® To00R 7. The specific conductances in ohm cm of four electrolytes P, Q, R and S are given in brackets P 5.0 x10 Q 17.0 x10) R(L0 x10" $09.2 x10) ‘The one that offers highest resistance to the passage of electric current is (yP (2s )R Q 8. The specific conductance of a salt of 0.01 M concentration is 1.061 x 10 § cm. Molar ‘conductance of the same solution will be : (1) 1.061 «104 (3) 10.61 (2) 1.061 4) 106.1 10. 1. 12, 13. 14, Which of the following solutions of NaC] will have. the highest specific condutance ? ()0.001N (2)0.1N (3)0.01N (4) 1.0N The value of molar conductivity of HCl is greater than that of NaC] at a particular temperature because (1) Melecular mass of HClis less than that of NaCl (2) Velocity of H* fons fs more than that of Na* ions. . (3) HCl is strongly acidie (4) lonisation of HCl s larger than that of NaCl Which statement is not correct =~ (2) Conductance of an electrolytic solution increases, with dilution: (2)Conductance of an electrolytic solution decreases with dilution (3) Specific conductance of an electrolytic solution decreases with dilution (4) Equivalent conductance of an electrolytic solution increases with dilution. “The resistance of 0.01 N solution of an electrolyte was found to be 210 ohm at 298 K using a conductivity cell of cell constant 0.66 em”. The equivalent conductance of solution is:= (1) 314.28 mho em” eq (2) 3.14 mho om? eg! (3) 314.28 mho cm? eq” (4) 3.14 mho™ em? eq" Electrolytic conduction differs from metallic conduction from the fact that in the former (1) The resistant increases with increasing temperature (2) The resistance decreases with increasing temperature (3) The resistance remains constant with increasing, temperature (4) The resistance is independent of the length of the conductor ‘The specific conductance of a 0.01 M solution of KClis 0.0014 ohm" em-tat 25°C. tts equivalent conductance (cm? ohm equiv) is :~ (a) 140 Qa @) 14 (4) 0.14 141Pre-Medical 18. Which one of the following is wrong :— (1) Specific conductance increases on dilution (2) Specific conductance decreases on dilution {3} Equivalent conductance increases on dilution (4) Molar conductance increases on dilution " ae AA infinite dltion, the equivalent conductances of CH,COONa, HCl and CH,COOH are 91, 426 and 391 mho cm¥ eq" respectively at 25 °C. The eq, 16. conductance of NaCl at infinile diuiion wil. be (1) 126 {2} 209 (3.391 (4) 908 17. The equivalent conductivity of 0.1 N CH,COOH at 25 “Cis 80 and at infinite dilution itis 400, The degree of dissociation of CH,COOH is : a. (20.2 O01 05 18. The limiting molar conductivities A” for NaCl, KBr and KC! are 126, 152 and 150 § cm? mol respectively. The A? for NaBr is (1) 278 S cm? mol (2) 176 S cm? mol* {3)128.S.cm® mot? (4) 302 S cm? mol? For HC solation at 25°C, equivalent conductance at infinite dilation, #s 425 ohm em? equiv"). The specific conductance of @ solution of HCl is 3.825 ohm’t cm". If the apparent degree of dissociation is 90% the normality of the solution is- (1) 0.90 N (3) 10 N 19, 10N (4) 12. 20. The molar conductivities 1%, and fy atinfinite dilution in water at 25°C are 91.0 and 426.2 S cm?/mol respectively. To calculate A%y., the additional value required is + 1) Ake 2 rio 8) ns 8) aor 21. The molar conductance at infinite dihition of AgNO,, AgCl and NaCl are 116.5, 121.6 and 110.3 respectively. The molar conductance of NaNO, is: ita (2) 105.2 8) 130.6 (4) 150.2 22. The conductivity ofa saturated solution of BaSO, is 3.06 x10 ohm" emtand ils moler conductance is 1.63 ohnr' cnr? mol". The K,, of BaSO, will be (4 x10" {2)2.5 x10” (3)2.5 «108 4) 410% 142 23. In the galvanic cell Cu | Cu?* (1M) || Ag* (1M) | Ag the electrons will travel in the external circuit : (2) from Ag to Cu (2) from Cu to Ag electrons do r The passage of electricity in the Daniell cell when. Zn and Cu electrodes are connected is : (1) from Cu to Zn in the cell {2} from Cu to Zn out side the cell (3) from Zn to Cu outside the cell (4) in any direction in the cell 25. The equation representing the process by which standard reduction potential of zinc can be definedis, (1) Zn® (5) + Ze" ——> Zn (2)Zn lg) ——> Zn* (@) + 2° (3) 2n® @) + 2° ——>2n (4) Zn (aq) + 2" ——> Zn (s) 26. A standard hydrogen electrode has zero electrode potential because : (1) Hydrogen is easiest to oxidize (2) This electrode potential is assumed to be zero (3) Hydrogen atom has only one electron (4) Hydrogen is the lightest element Which isnot trie for a standard hydrogen electrode ? (1) The hydrogen ion concentration is 1M (2) Temperature is 25°C (3) Pressure of hydrogen is 1 bar {@) It contains a metallic conductor which does not adsorb hydrogen, E° for the half cell Zee | Zn is-0.76 em. of the cell Zn | Zn® (1M) || 2H+ (1M) | H, (1 atm) is : )-0.76V (240.76 @)-0.38V (4) +0.38V 27. 28. 29. The chemical reaction, 2AgCils) + H fa) —> 2H fa) + 2Ag(s) taking place in a galvanic cell is represented by the notation, (1) PUsi[H,(g).Tbar |IMKClaq)|AgCis)/Agts). (2) Piis)|H,(g) 1bar[2MHCllag)lIM Agiea)/Agts) (3) Ptis}{H, (a). ‘oar |IMHCi(aq)|AgCi(s)[Aals) (4) PUsH, (a). Tae|I MHClaq)/Aals}AaCis). Le| 31. 32, 34. A cell represented above should have em. (1) Positive (2) Negative (8) Zero (4) Cannot be predicted Given electrode potentials Fe + -——> Fe; 1+ 20 ar; E* cal fr the cell reaction 2Fe* + Or > OFet + is (1) (2 0.771 - 0.536) = 1.006 volts (2)(0.771 - 0.5 x0.536) = 0.503 volts (8) 0.771 - 0.536 = 0,235 valts, (4) 0.536 - 0.771 = -0.235 volts Which of the following is not an anodic reaction~ (1) Ag” + Age (2) Cu -» Cu?* + 267 (8) Fe2* > Fe? + (4) 40H” > 2H:0 + Op + de” Which of the following statements is correct :- (2) Oxidation occur at anode in both galvanic and electrolytic cell (2)Reduction occurs at anode in both galvanic and electrolytic cell (3) Reduetion occur at anode in electrolytic cell ‘where as oxidation occur at cathode in galvanic call (4)Oxidation oceurat anode in electrobyticcall where as reduction occur at anode in agalvanic cell Other things being equal, the life of a Daniell cell may be increased by (1) Keeping low temperature (@)Using large copper electrode (8) Decreasing concentration of copper ions (4) Using large zinc electrodes E EE 1.771 volts 1.536 volts 35. 36. Zn can not displace following ions from their aqueous solution : (Agr (2) Cu @)Fe* (@) Nat The standard reduction potentials at 25°C for the following half reactions are given against each : Zn* (aq) + 26°F Znis), 0.762 Cr fag) + 3e° = Cris}, -0.740 2Ht + 2e" S Hyg), 0.00 Fe + 2e & Fe®,0.77 Which isthe strongest reducing agent ? zn (2) Cr BH (4) Fe (aq) 37. 38. 39. a. 42, Chemistry Red hot carbon will emove oxygen from the oxide XO and YO but not from ZO. Y will remove oxygen from XO. Use ths evidence to deduce the order of activity of the three metals X, Y and Z putting the most active firs. ayxyz (2vx (3) YXZ (4) ZXY Adding pousdered Pb and Fe toa solution containing 1.0 M in each of Pb*? and Fe*? ions would result into the formation of :— (2) More of Fe and Pb? ions (2) More of Fe*? and Pb® ions (3) More of Pb and Fe“? ions (4) More of Fe and Pb Ifa spoon of copper metals placed ina solution of ferrous sulphate : (1) Cu-will precipitate out {2)iron will precipitate (8) Cuand Fe will precipitate {) No rection will take place Which one will liberate Br, from KBr ? (HI @1, 8d, (4)$0, Using the standard electrode potential vals given ‘below, decide which of the statements, I, Ill and Ware correct. Choose the right answer from (1), (2), @)and (4, Fe +2e Pe; 9 E*=-0.44V Cur + 2e Cu; B= 40.34V Agi+e Ags EP= 40.80 1. Copper can displace iron from FeSO, solution, IL Iron can displace copper from CuSO, schition. Il. Siker can displace copper from CuSO, solution. IV. Iron can displace silver from AgNO, solution. (1) and (2) and tt @) land IV (and Iv ‘The standard electrode potential value of the elements A, Band C are 0.68, ~2.50 and 0.50V respectively, The order of their reducing power s ()A>B>c QA>C>B G)C>B>A (@B>C>a 14343. The oxidation potential of Zn, Cu, Ag, H, and Ni | 49. 47. 144 are 0.76, -0.34, -0.80, 0, 0.55 volt respectively Which of the following reaction will provide ‘maximum voltage ? (1}Zn + Cu® — Cu + Zn®* (2) Zn + 2Ag' —> 2Ag + Zn? (3) H, + Co 3 2H + Cu (4) H, + Ne —> 24 + Ni ‘The following facts are available 2K + Yao BY +X 2W- + 2+ NO reaction 20 + Xy-» K+ Z Which of the following statements is correct Evy > By iy, > Bm Err, 2) Ev < Bry < Pca < Br, 8) Erm

Bem > Bary 4) Ew, > Brig < Bre < Pere The standard reduction potential at 25 °C of Lit / Li, Ba / Ba, Na* / Na and Mg? / Mg are -3.05, -2.73, -2.71 and -2.37 volt respectively. Which one of the following is the strongest oxidising agent? (1) Nav (2) Lx (3) Ba" (4) Ma A gas X at 1 atm. is bubbled through a solution containing a mixture of 1M Y- and 1M Z: at 25 °C. If the reduction potential of 2>Y>X then: {1)¥ wall oxidise X and not 2 (2) ¥ will oxidise Z and not X (3) ¥ will oxidise both X and Z (4) Y wil reduce both X and Z The standard electrade potential of Zn, Ag and Cu are -0.76, 0.80 and 0.34 volt respectively, then (1) Ag can oxidise Zn and Cu (2) Ag can reduce Zn** and Cut (3) Zn can reduce Ag’ and Cut (4) Cu can oxidise Zn and Ag Each of the three metals x, yand z were put in tum {nto aqueous solution of the other two. x + salt of y {or2) = y (or 2) + salt of x Which one of the following observation is incorrect? (1) y + salt of x = no action observed hy + salt of z=2+ sat of y (B)z + salt of x=x + salt of z (4) z + salt of y = no action observed (3}0.118V (4)0.059.V elements are A=-0.250V, B--0140V C=-0126V, D=-0402V ‘The element that displaces A from its compounds aqueous sokstion is — ae ac @)D (4) None of the above 50. The following four colourless salt solutions are placed in separate test tubes and a strip of Cu is placed in each solution which finally tums blue (1) Zn(NO.),, (3) KNO, (2) MgiNO3)p (4) AgNO, 51, Which of the followingdisplacement doesnot occur (I) Zn + 2H* > Zn?* + Het (2) Fe + 2Ag* + Fe’* + Ag d (8) Cu + Fe?* 5 Cu? + Feb (4) Zn + Po?* 5 Zn?* + Pot 52. EWN#*/N} =-0.25 volt, E*(Au* / Au) = 1.50 volt. ‘The emf of the voltaic cell. Ni/Ni**(1.0M) | | Au* (0M) | Au is: {1) 1.25 volt (2) -1.75 volt (3) 1.75 volt (4) 4.0 volt 53. The emf of the cell in which the following reaction Znls) + Ni** (a = 0.1) <= Zn (a = 1.0) + Niés) occurs, is found to be 0.5105 V at 298 K. The standard e.m.f. of the cells {)~0.5105V (3) 0.4810 V 54, The emf of the cell (2)0.5400V (4) 0.5696 V TVTI (0.0001 M) | 1 Cu?*(0.01M)/Cuis 0.83 V ‘The emf of this cell will be increased by ~ (1) Increasing the concentration of Cu* ions (2) Decreasing the concentration of TI* (3) Increasing the concentration of both @){1) & (2) both ‘The potential of hydrogen electrode (P,,, = Latms; C,* = 0.1 M) at 25°C will be - ()0.00V (2)-0.059V 55. may A standard reduction electrode potentials of four :56. Which of the following represents the potential of 57. 59. 61. silver wire dipped into 0.1 M AgNO, solution at 25°C? ES, (2) €",, + 0.059) (3)E, ~ 0.059) (4) E,, - 0.059) “The potential of @ hydrogen electrode at pH = 1 is (1) 0.059 volt {2} 0.00 volt (3) -0.059 volt (4) 0.59 volt }. Consider the reaction Cha) + 2Br (eq) —> 2Ct faq) + Br, ‘The emf of the cell when [Cty = (Br, = Br] = 0.01 M and Cy, gas at 1 atm pressure willbe (E*for the above reaction is = 0.29 vat) (1) 0.54 volt (2) 0.35 volt (3) 0.24 volt (4) 10.29 volt The standard emf for the cell reaction Zn + Cu —> Zn® + Cu is 1.10 volt at 25 °C. The emf for the cell reaction when 0.1 M Cu®* and 0.1 M Zn® solution are used at 25°C is: (1) 1,10 volt (3)-1.10 volt (2) 0.110 volt (4) -0.110 volt E°for F, + 20°» 2F is2.8V, E*for 4F, +e" Fis ? (28V @)1L4v Q)-28V @)-14V A Gof the call reaction AgCls) +4H{g) -> Agls) + H* +Cl is -21.52 KJ AG* of 2AgCis) +H fa) > 2Agls) +2H* +2Cr is : (1) 21.52 KJ (2)-10.76 Ks (3) 43.04 KJ (4) 43.04 Ks How much will the potential of Zn / Zn® change if the solution of Zn?* is diluted 10 times (1) increase by 0.03 V (2) decreases by 0.03 V @) increases by 0.059 V (4) decreases by 0.059 V How much will the potential ofa hyelrogen electrode change when its solution initially at pH = 0 is neutralised to pH = 7? (1) increases by 0.059 V (2) decreases by 0.059 V (2) increases by 0.41 V (@) decreases by 0.41 V Chemistry |. Which of the following will increase the voltage of the cell with following cell reaction Sry + 2Ag",, > Sn“¥,, + 2Ag, (1) Increase in the size of sitver rod (2) Increase in the concentration of Sn‘* ions (3) Increase in the concentration of Ag” ions (4) Decrease in the concentration of Ag” ions E® for the reaction Fe + Zn® -» Zn + Fe is ~0.35V. The given cell reaction is : (1) feasible (2) not feasible (3) in equilibrium (4) cant say anything Fore reaction- Als) + 2B" > A? + 286s) K, has been found to be 10%. The E°, is: (0.354 (2)0.708V (3) 0.0098 V @)136V |. The standard electrode potential (E)) for OCF/Cl- and Cl / % Cl, respectively are 0.94 V and =1.36V. The E° value of OCI/ % Cl, will be : (1)-2.20V (2)-0.42V (0.52 (4)1.04V |. The standard reduction potentials of Cu?*/Cu and (Cu*t/Cur are 0.337 and 0,153 V respectively, The standard electrode potential of Cur/Cu half cel is : () 0.184 (2) 0.827 V (3)0.521V (4) 0.490V ). The hydrogen electrode is dipped in a solution of pH = 3at 25°C. The potential of the cell would be : (1)0.177 ()-0.177V (3) 0.087 V (4) 0.059, ‘What is the potential of the cell containing two hydrogen electrodes as represented below Pt; Hg) | H*(10)M || 110.001 M) | Hig). Pt ; (1)- 0.295 V (2)-0.0591V (3) 0.295 V (4) 0.0591 V Consider the cell Cu/Cu"*! |Ag*/Ag. If the concentration of Cu? and Ag” ions becomes ten times the emf of the cell — (1) Becomes 10 times (2) Remains same (3) Increase by 0.0295 V (4) Decrease by 0.0295 V 145Pre-Medical 72. The emf of the cell Ni/Ni**(1.0 M) || Aus (0.1M)/Au IE*for Ni7/Ni = -0.25 V, E°for Au*/Au= 1.50V] is given as:- (1.25 (2)-1.75V GhL75V (1.73 73. 74. 75. 76. 77. 78. 148 ‘When an electric current is passed through acidified water, 112 ml. of hydrogen gas at STP collects at the cathode in 965 seconds. The current passed, in ampere is (1) 10 205 B01 20 Two electrolytic cells one containing acidified ferrous chloride and another acidified feric chloride are connectedin series. The ratio of iron deposited at cathodes inthe two cals when electricity is passed through the cals will be + (3:1 2st A current of 9.65 amp. flowing for 10 minute deposits 3.0 g of a metal. The equivalent wt. of the metal is : (1) 10 (4) 96.5, ‘The seme amount of electricity was passed through two separate electrolytic cells containing soutions of nickel nitrate [Ni(NO,)Jand chromium nitrate (CHINO) respectively. If 0.3 g of nickel was deposited in the first cal, the amount of chromium Bist 3:2 (2)30 (3)50 deposited is (at, wt, of Ni= 59, at. wi. of Cr = 52) (01g (20.17 g 03g (40.69 How many coulombs of electricity are required for the oxidation of 1 mole of H,0 to O, ? (1) 9.65 x10°C (2) 4.825 x105¢ (3) 1.93 x10°C ‘When a quantity of electricity equal to that required to liberate 2.24 L of hydrogen at STP from 0.1 M aqueous H,SO, is passed (At. mass of Cu = 63.5) then the mass of copper that will be deposited at cathode in electrolysis of 0.2 M solution of copper (4) 1.93 x10°C sulphate will be {1)1.59g (23.189 (36.354 (412.704 79. 81. 83. 85. 86. 87. 10800 C of electricity through the electrolyte deposited 2.97 g of metal with atomic mass 106.4 g mot. The charge on the metal cation is M4 Qs B42 Wat (On passing electricity through dil. H,SO, solution the amount of substance librated at the cathode and anode are in the ratio (1:8 (3) 16:1 During electrolysis of fused calcium hydride, the hydrogen is produced at : (1) Cathode (2) Anode (3) Hydrogen is not liberated at all (4) H, produced reacts with oxygen to form water (28:1 41:16 A silver cup is plated with silver by passing 965 ampere current for one second, the mass of ‘Ag deposited is --(At. wt. of Ag = 107.87) (1) 9.89 ¢. (2) 107.87 g. (3) 1.0787 g (4) 100.2 g. When electricity is passed through a solution of AlCl, 13.5 g. Al are deposited. The number of Faradays must be ~ () 5.0 (2) 1.0 B15 A solution of sodium sulphate in wateriselectrolysed using inert electrodes, The product at the cathode (4) 3.0 and anode are respectively (1) H,, SO, (2)0,, Hy {3}, Na (4) Hy, Op One Faraday of electricity will liberate one mol atomic mass of the metal from the solution of (1) Aurc chloride (2) Siver nitrate (@)Caleium chloride (4) Copper sulphate When 96500 coulombs of electricity are passed through barium chloride solution, the amount of barium deposited will be :- (1)0.5 mol, (21.0 mol. (3)1.5 mol. (4)2.0 mot Aactory produces 40kgofcalciumin twohoursby 3Fet? will be : (0.330 (2)1.653V 1.212 (01n1V x A hypothetical electrochemical cell is shown Aiarsm! 1BiyMyB ‘The emf mearured is +0.20 V The cell reaction is : () At +B—> A+ Br (Q)At+e—+A,Br+e—oB (3) The cel reaction cannot be predicted A+ BeAr +B 3. The charge required for the reduction of 1 mol of MnOy- to MnO» is: (ir (2)3F Q)5F a) 7F ‘The products formed when an aqueous solution of [NaBris electrolyzed in a cell having inert electrodes are (1) Na and Bry (2) Na and O, {(3)H,, Brzand NaOH (4) Hy and O, ‘The equilibrium constant of the reaction : Culs) + 2Agr(aq.) —> Cur%aq) + 2Ag(s) E? = 0.46 Vat 298 Kis (1) 2.0 x10 (2) 4.0 x 1010 (3)4.0 x 1015 (4) 2.4 x 1010 - 6. Ontthe basis ofthe following E°values, the strongest oxidizing agent is - IFe(CN)J* + [Fe(CNP +e7,E* = - 0.35V Fe + Fe + et; E=-0.77V () Fe* 2) ec (8) [Fe(CN) J (4) Fe? 148 auLEN AIPMT/NEET & AIIMS (2006-2016) 7. Kohlrausch’s law states that at = (2) Infinite dilution, each ion makes definite contribution to conductance of an electrolyte whatever be the nature of the other ion of the electrolyte. (2) Infinite dilution, each ion makes definite contribution to equivalent conductance of an electrolyte whatever be the nature of the other ion of the electrolyte. (3) Finite dilution, each ion makes definite contribution to equivalent conductance of an electrolyte whatever be the nature of the other ion of the electrolyte. (4) Infinite dilution, each ion makes definite contribution to equivalent conductance of an clectroiyte depending on the nature of the other fon of electrolyte. 8. Given: (Cu + 20° > Cu, E = 0.337 V (i) Cu” + e° > Cu’, E? = 0.153 V lectrode potential, E°for the reaction, Ca‘ + &°>Cu, willbe: (1) 0.38 V {2) 0.52 V {3) 0.90 V {4} 0.30 V 9. The equivalent conductance of x solution of a ‘weak monobasic acid is 8.0 mhos cm” andat infinite ditution is 400 mhos cm®, The dissociation constant of this acid is : (1) 1.25 x 104 (2) 1.25 x10 8) 1.25 x10¢ (4) 6.25 x 10% 10. Al,0, istreduced by electrolysis at low potential and high current. If 4.0 x10" amperes of current is passed through molten Al,Oy for 6 hours, what ‘mass of aluminium is produced ? (Assume 100% current efficiency, At. mass of Al = 27g mo) (1) 1.3 «108g (2) 9.0 x10°g (8.1 x 10g (4) 2.4 x10° g 11. An increase in equivalent conductance of a strong electrolyte with dilution is mainly due to:- (1) Increase in number of ions (2) Increase in ionic mobility of ions (8) 100% jonisation of electrolyte at normal dition 44) Increase in both i.e. number of ions and ionic mobility of ions12. 13. iM Consider the following relations for emf of a electrochemical cell: (2) emf of cell =(Oxidation potential of anode) ~ (Reduction potential of cathode) {b) emf of cell = (Oxidation potential of anode) + (Reduction potential of cathode) (0. emf of cell = Reductional potential of anode} + (Reduction potential of cathode) (d) emf of cell = (Oxidation potentiat of anode) - (Oxidation potential of cathode) Which of the above relations are comect : Options {2} (a) and () (2) (@ and (4) 43) ) and (@) (A) (9 and (a) Which of the following expressions correctly represents the equivalent conductance at infinite dilution of AL{SO,}y. Given that A°,>. and ‘A’op are the equivalent conductances at infinite dition of the respective fons :- Ake Aap) (A°p + Ap x6 1 1 ° ° 3) youn + Bt @) 2A% 9. #3A Gy For the reduction of silver ions with copper metals, the standard cell potential was found to be +0.46V at 25°C, The value of standard Gibbs energy. AG? wall be (F = 96500 C mol) (1) -98.0 kd {2} -89.0 kd (3) -89.0 5 () -44.5 kd 15, 16. Limiting molar conductance of H* and CH,COO- ions are 344 and 40 respectively. Molar conductance of 0.008 M CH,COOH is 48. What will be the value of K, for CH,COOH = (Q) 14x 10% (312 x10° (3) 1.4 «10* (110% E value for the cell reaction Cu | Cu® (0.001 M) 11 Cu?(0.1 M) | Cuis = a) Zion RT RT 3} +p inl0.01) (4) - In(0.1) 17, Standard electrode potential of three metals X, Y and Z are -1.2 V, +0.5 V and -3.0 V respectively. The reducing power of these metals will be = WY>Z>X Q)¥>X>Z B)Z>X>¥ @X>Y>Z 19. 20. Chemistry “The electrode potentials for Cul yg + > Cia and Ci yg + > Cig are 40.15 Vand +0.50 V respectively. The value of Bea jg, will be = (1) 0.500 V (2) 0.325 V @) 0.650V (4) 0.150V Standard electred potential for Sn+/Sn couple is +0.15 V and that for the Cr°*/Cr couples is 0.74 V. These two couples in their standard state are connected to make a cell. The cell potential will be = () +119 V (3) 40.18 V (2) +0.89 V @) +183 V If the Ea fora given reaction hasa negative vale, ‘then which of the following gives the correct relationship for the values of AG? and Ky, ? (1) AG? > 0; K,,> 1 (2) AG" < 0; Ky, > 1 (3) AG*< 0; Ky <1 (4) AG? > 0; Key < 1 21. A solution contains Fe’, Fe’ and I" ions. This solution wes treated with fodine at 36°C. E® for Fe* / Fe® is +0.77 V and E* for 1/2 = 0.536 V. The favourable redox reaction is (1) Fe? wall be oxidised to Fe™* (2) Ip will be reduced to Fr (2) There will be no redox reaction (4) F will be oxidised t0 1, 22. Limiting molar conductivity of NH,OH fe Aner (1) Ariotior)+ Ansgar Arita (2) Ansara} Asn Anevscy 13) Anspaigoy+ Amiac= Arto) (A) Arasor-+ Amiact— Amino} SSF tts23. Molar conductivities (A2.) at infinite dilution of NaCl, HCl and CH;COONa are 126.4, 425.9 and 91.0 cm? mot" respectively. A°, for CH;COOH will be = (2) 290.8 $ om? moti (3) 425.5 § cm? mot? (2) 390.5 S cm? mol * (4) 180.5 S$ cm? mort For 2n* | Zn E° = ~0.76V then EMF of this cell 2n/2n*41M) || 2H*(1M) ( H,(1 atm) wall be = ()-0.76V (2) 0.76 ¥ (3) 0.38 V (4) -0.38 V 25. 27. ‘At 25°C molar conductance of 0.1 molar aqueous solution of ammonium hydroxide is 9.54 ohm” em? mol" and at infinite dilution its molar conductance is 238 ohm”! cm? molt, The degree of ionisation of ammonium hydroxide at the same concentration and temperature is :- @) 40,800 % (2) 2,080 % @) 20.800 % (4) 4.008 % A hydrogen gas electrode is made by dipping platinum wie in a solution of HCl of pH = 10 and by passing hydrogen gas around the platinum wire at one atm pressure, The oxidation potential of electrode would be ? (@) 118V (3) 0.59V (20.059 V (4) 0.118 V A button cell used in watches function as following Zag) + Ag,O(s) + HZO(0) = 2Agls) + Zn**(aq) + 20H aq) I half cell potentials are Zn?(aq) + 2e° — Znls); E* = -0.76 V ‘Ag,Ols) + H,O(0) + 2e" > 2Agls) + 20H lag): E=0.34V ‘The cell potential will be : @i34v 42) 110 V @) 042 (4) 0.84 V 28. 150 Electrode potential of hydrogen electrode is 18 mV then {H’] is - (0) 0.2 1 2 (5 e 35. The pressure of Hy required to make the potential 29. When 0.1 mol MnO}- is oxidised the quantity of electricity required to completely oxidise MnO” to MnO; is = (1) 96500 C (2) 2 x 96500 C (8) 9650 C (4) 96.50. C 30. The weight of silver (at wt. = 108) displaced by a quantity of electricity which displaces 5600 mL. of Op at STP will be 54g (2) 1089 @) 54.05 (4) 108.0 g Re ae 31. Amount of charge is required to convert 17 gm 1,0, into O, = a) iF (2) 2F BF (4) None of these 32. device that converts energy of combustion of fuels» like hydrogen and methane, directly into electrical energy is known as := (1) Bectroltic cell G) NiCd cell (2) Dynamo (4) Fuel Cell 33. For the cell reaction ‘Mg +2Ag" (0.0001M) > Mg** (0.01M)+2Ag Bi, =3.177 V then what will be value of Ey for the above reaction ? M25 (230 32 38 If electrode potential of 0.01 M Cut*/ Cu is 0.32 V then what wil be its B®, — (1) 0.18 V (2) 0.28 V (3) 0.74V (4) 0.38 V ‘of Hyelectrode zero in pure water at 298 K is - (1) 104 atm (2) 10-2 atm (3) 10-10 atm (4) 10+ atm The molar conductivity of a 0.5 mol/dm? solution of AgNO, with electrolytic conductivity of 5.76 x 103 S am at 298 Kis (1) 0.086 $ cm?/mol (2) 28.8 S cm?/mol (3) 2.88 S cm?/mol (4) 11.52 $ em*/mol i E37. During the electrolysis of molten sodium chloride, the time required to produce 0.10 mol of chlorine gas using a current of 3 amperes is (1) 220 minutes (2) 330 minutes (3) 55 minutes (4) 110 minutes 38. Ifthe E%y fora given reaction has anegative value, which of the following gives the correct relationships for the values of AG? and Ke, ? () AG?< 0; Ke> 1 @)aGr< 0; Ky <1 (8) AG"> 0; Ky< 1 @)AG*>0; Kq>1 Chemistry 39. The number of electrons delivered at the cathode during electrolysis by a current of 1 ampere in {60 seconds is (charge on electron = 1.60 x10" CQ (1) 3,75 « 10% (2) 7.48 x 10% (3)6 x108 (4) 6 «10% 40. How many faraday charge is required for KMnO/Mn® ()3F Q2F )SF IF RO kdPre-Medical EXERCISE-II! (Analytical Questions) 1, 152 ‘Specific conductance of 0.1 M Nitric acid is 6.3 x10 ohn cm. The molar conductance of the solution is (1) 630 obi? em? mot (2) 315 chert em? mot* (3) 100 chm cm? mot* (4) 6.300 ohn cm? mot* (8) 63.0 ohne! em? molt The highest electrical conducitivity of the following aqueous solution is of (1) 0.1 M fluoroacetic acid (2)0.1 M diflucroacetic acid (3) 0.1 M acetic acid (4)0.1 M chloroacetic acid Resistance of a conductivity cel filed with a sohition of an electrolyte of concentration 0.1 M is 100 @. The conductivity of this solution is 1.29 S mr, Resistance of the same cell when filled with 0.02 M of the same solution is 520 Q. The molar conductivity of 0.02 M solution of the electrolyte will be. (1) 124 «10-4 § m? mot (2) 1240 x 10-4 S m? mob (3) 1.24 x 10-4 § m2 mot! (4) 12.4 x104§ m2 mobi Resistance of 0.2 M solution of an electrolyte is 50 2. The specific conductance of the solution is 1.4 ‘Sim. The resistance of 0.5 M solution of the same electrolyte is 280 £2, The molar conductivity of 0.5 M solution of the electrolyte in $ mf mor! is () 5 x 105 (2) 5 x 102 85 x104 (4) 5 x108 Resistance of 0.2 M solution of an electrolyte is 50.2. The specific conductance of the solution is 1.3$ mt Thresistance of the 0.4M solution of the same electrolyte is 260 Q, its molar conductivity is (1) 6250 Sm? mob? (2) 6.25 x 10-4 § m? mokt (3) 625 x 10-4 $ m? mot (4) 62.5 $ mé mob! The. equivalent “conductance ‘of NaCl at * concentration Cand af infinite dilution are Acand Auge respectively. The correct relationship between Acand 2, is given as {where the constant B is postive) 1) 2g= he BYE 8) ie = + BC Bde = hat BWC ac =2.- BIC 10. nu. 12, Bay CC eae at Blecrolte | KCT_[RNO, | ACT [NaOAe [Nac AY (Sem*mot [1499 | 145.0 [426.21 910 [1265 Calculate Ajig,, using appropriate molar conductances of the electrolytes listed above at infinite dilution in H,O at 25°C (390.7 (2)2175 @)5172 552.7 ‘Which of the following statements is TRUE for the electrochemical Daniel cell (2) Electrons flow from copper electrode to zine electrode, (2) Current flows from zinc electrode to copper electrode. (3) Cations move toward copper electrode. (4) Cations move toward zinc electrode. Aluminium displaces hydrogen from dilute HCL whereas silver does not, the E.M.F. of a cell prepared by combining AV/AI'? and Ag/Agr is 2.46V. The reduction potential of silver electrode is +0.80V. The reduction potential of aluminium, electrode is ()-3.26V (+166V 8)-1.66V (4) 3.26V ‘Standard reduction electrode potentials of three metals A, B and C are respectively + 0.5 V, ~3.0 Vand ~1.2V. The reducing powers of these metals are ()C>B>A QA>C>B BB>C>A @A>B>C Consider the following E° values Ebsyga = + 0.77V Egos, =- O14 Under standard conditions the potential for the re- action ‘Sn{s) + 2Fe** (aq) —> 2Fe*faq) + Sn(aq) is MoV (2)1.40V @168V (4)0.63 For the redox reaction : Zns) + Cu {0.1M) > Zn® (1M) + Cus) taking place in a cell, E'qq is 1.10 volt. En, for the cell will be (20s (1) 1.07 volt (2} 0.82 volt (3) 2.14 volt (4) 1.80 volt13, 14. 15. 16. a7. 18. Ina cell that utilises the reaction 2n(9) + 2H'(eq,) == Zn*(aq) + H,{q) addition of H,S0O, to cathode compartment, will (2) increase the E,,, and shift equiibrium tothe right (2) lower the E.,, and shift equilibrium to the right (@) lower the E, and shift equilibrium to the left (@)increase the E,,, and shift equlbrium to the let ‘The e.mi, of a Daniell cell at 298 K is E, 2n|ZnSO,1 1CuSO,1Cu (0.01M) (1.0) ‘When the concentration of ZnSO, is 1.0 M and that of CuSO, is 0.01 M, the e.m.f. changed to E,, What is the relationship between E, and Ey (NE, > Ey (2) E, < E, @E,=E GE, = 028, The reduction potential of hydrogen half-cell will be negative if (1) pH,) = 2 atm [H"] = LOM (2) piH,) = 2 atm and (EI'] = 2.0 M (3) pH.) = 1 atm and [H") = 2.0M (2) ptt) = 1 atm and [H"} = 1.0 M For a cell reaction involving two-electron change, the standard e.m-¥. of the cell is found to be 0.295 V at 25°C. The equilibrium constant of the reaction at 25°C will be a) 10 (2) 1 x 10" @) 1x10” (4) 29.5 x 108 For a spontaneous reaction the AG, equilibrium constant (Khand E®,, will be respectively (ve, < 1, -ve (2) ~ve, >1, ve B)-we, >1, He (4) awe, >1, -ve (On the basis of the information available from the 4 2 reaction Al + 0, > 3 ALO,, AG = -827 KJ mot" of O,, the minimum em. required to carry out an electrolysis of Al,O, is = (F = 96500 C mot’) @234V 8) 642V (2)4.28V (a) 8.56 V 19. 21. 22. 23. 24. Chemistry Given below are the half -cell reactions :- Mn? + 2e-> Mn; E" = -1.18V 2(Mn** +e > Mn), E'= 41.51 V ‘The E* for 3Mn?—+ Mn + 2Mn3* wall be : (1) -0.33 Vs the reaction wall not occur (2) -0.33 V; the reaction will occur (8) -2.69 V, the reaction will not occur (4) 2.69 V; the reaction will occur Given the data at 25°C, AgtboAglee, — E°=0.152V Ag Agr +e, E=-0,800V What is the value of log Ksp for Ag! ? (2 30387 0.059 v} (1) -8.12 (2) +8.612 (3) 37.88 (4) -16.13 ‘The metal that cannot be oblained by electrolysis of {an aqueous solution of its salts is: (A) Cu (2) Cr (3) Ag a) Ca When during electrolysis of a solution of AgNO, 9650 coulombs of charge pass through the eleciroplating bath, the mess of silver deposited on the cathode will be : () 2164 (3) 1.08 g Aluminiuin oxide may be electrotysed at 100°C to furnish aluminium metal (At. Mass = 27 amu; 1 Faraday = 96500 Coulombs).The cathode reaction is Abs + 3 —> AB To prepare 5.12 kg of aluminium metal by this method would require. (1)8.49 x 10°C of electric charge (2)5.49 x 10! Cof electric charge (3) 5.49 x 10? C of electric charge (4) 1.83 x 10" Cof electric charge (2) 108 g (4) 10.8 g Accurrent of i ampere was passed fort sec. through three cells P, Q and R connected in a series, These contain respectively silver nitrate, mercuric nitrate and mercurous nitrate. At the cathode of the eal P, 0.216 g of Ag was deposited, The weights of mercury deposited in the cathode of Q and R respectively are : (at. wt. of Hg = 200.59) (1) 0.4012 and 0.8024 g (2)0.4012 and 0.2006 g 8) 0.2006 and 0.4012 g (4) 0.1003 and 0.2006 g 153Pre-Medical 25. A galvanic cell is set up from a zine bar weighing | 28. An electric current is passed through silver 100 gand 1.0 kitre of 1.0 M CuSO, solution, How. voltameter connected to a water voitameter. The Jong would the cell run if itis assumed to deliver a cathode of the silver voltameter weighed 0.108 g. steady current of 1.0 amp. (Atomic mass of more at the end of the electrolysis. The volume 2n = 65) of oxygen evolved at STP is a) 1.1 he (2) 46 hr. a) 56 cm’ (2) 550 cm* (3)53.6 he (4) 24.00 hr. 8) 5.6 om? (@) 11.2 cm (5) 22.4 om’ 26. The electrochemical equivalent of silver is 0.0011180 g. When an electric current of | 29. 4.5 g of aluminium (at. mass 27 amu) is deposited 0.5 ampere is passed through an aqueous siver at cathode from AI solution by a certain quantity nitrate solution for 200 sec., the ammount of sier of electric charge. The volume of hydrogen deposited is : produced at STP from H* ions in solution by the (2) 1.1180 g (2}0.11180 q same quantity of electric charge will be - (3) 5.590 g (4)0.5590 g ()44.8L ()1L2L 27. A current of 9.65 amp. is passed through an 224 MeL aqueous solution of NaCl using suitable electrodes | 39, The thermodynamic efficiency of cell is given by - for 1000 s. Given that 1 faraday equals 96500 ‘coulombs the amount of NaQH (mot wt. 40.00} ay at HE formed on electrolysis is : AG AG 20g 28.09 EE 34.09 10g Sr (AiZero EXERCISE-III (Analytical Questions) ANSWER KEY [ans 2a letaban? olan” alee taal See Seales sleet | |Chemistry EXERCISE-IV (Assertion & Reason) Bete etd Directions for Assertion & Reason questions (A) _Ifboth Assertion & Reason are True & the Reason isa correct explanation of the Assertion. I i ae oe ae 3 1. Assertion Electrolysis of molten cakium hydride | 8. Assertion =~ The molar conductance of weak produces hydrogen gas at anode. electrolytes is low as compared to that of strong Reason = Hydrogen in calcium hide fs present electrolytes at moderate concentrations. as HT ion, Reason :~ Weak electrolytes at moderate Ma (QB @c @D concentration dissociation to a much greater extent 2. Assertion = Conductance of 0.1 M NH,OH aor oo we an solution is fess than that of 0.001M NH,OH solution. 9. Assertion :~ Gahanised iron does nol rust. Reason + Dilution increases the degree of Reason :~ Zinc has a more negative electrode ionisation of NH,OH potential then iron MA 2B @C Dd wa 2B Bc Dd 3. Assertion = Salt bridge is used generally in the | 10. Assertion = Increase in the concentration of electrochemical cals copper half cell in Daniel cell increases the emf Reason ~The ions ofthe electrolyte used in the of the cal salt bridge should have nearly same transport Reason :~ According to the nernst equation number. cut Qa aB ac aD emf of cell = e+ og, a in 4, Assertion =~ The electrode potential of SHE is WA OB 8 @D zer0. Reason :~SHE isa standard reference electrode. Ma QB gc (@)D 11. Assertion ~ Sodium ions are discharged at the Hg electrode during electrolysis in preference to HE fons. 5. Assertion = Copper sulphate sohllon cannotbe Reason ~The nalure of electrode also affect the stored in iron-vessal. order of discharge of cations Reason ;- Copper atoms are oxidised by iron ions. AA QB gc @D MA BB BCP N12, Assertion : The cll constant ofa cell depends 6. Assertion =~ Absolute value of E‘, of an onthe natu ofthe material of the de orente electrode cannot be determined. upon the nature of the electrolyte and the Reason :~ Neither oxidation nor reduction can concentration of the solution. take place clone. wa QB Bc Dd MA @B @C @D 13. Assertion = At the end of electrolysis using 7. Assertion :~ A dry cell became dead after long platinum electrodes, an aqueous solution of eopper time even if it has not been used. sulphate turns colourless ‘Reason ;~ The NH C\slowiy and gradually corrads Reason :- Copper in CuSO, is converted to the zinc container. CuOH), daring the electrolysis. ga @B @c @D MA @B Bc aD 155Pre-Medical Le 18. Assertion = 14. Assertion :~ In olectrolysis, the quantity of electricity needed for depositing 1 mole of silver is different from that required for 1 mole of copper. Reason :~ The atomic weight of siver and copper are different. (A AB BC Md 15. Assertion ;~ pH of solution increases during electrolysis of aqueous solution of NaCl. Reason :~ Electrolysis is non-spontaneous process, Qa QB @)D 16. Assertion :- A reactions is spontaneous if Ey= te Reason s- For E,, = 4ve. AG is always -ve MA @B BC wD 17. Assertion + Cu is stronger reducing agent than H,, Reason :- E° of Cu'2/Cu is negative (A 2B gc ac (a) D EXERCISE-IV (Assertion & Reason) 19. ‘or cell reaction; at 298 K Zny + Cu’%(1M) = Zn‘(1M} + Culs) Ey, =0 Reason :- At standard condition ; cell potential js always zero. Qa (2B aC Assertion : Li forms ethynide with acetylene. Reason: £),,,=+43.04V wa QB 3)C aD Assertion = Molar conductivity of a solution increases on dilution, Reason = Decrease in conductivity is overcome. by increase in volume, Ma 2B (4) D gc @D ANSWER KEY