be Lunamsmrtatotenanu infra piperidine; eicthyronine j gacthylonine, dibenzylaminetiay dibutylamine oy inorganic ation TnundiTucton Toto uasiiton une J.tsle1 Ammonium salts of dithiocarbanic acids sau satungadhtona A. Nepentaethylene annoniun-N' -pontamethylenc dithiocarbamate (¥32 S-piperid-1-yl M, N-penta methylene F githiocarbamate) s i Ch 6-5 > domnanrsaiila vurcacit P vay Bayor Vuleafor PIPC voy Vulnax 952 Accelerator vay De Pont: Necyclohexylethyl ammonium -Nt-cyclohexylethy1 dithiocarbamate Janwmamia Vutkacit 774 vor Bayer saat ~ a ea eee eo cae eee susguMi A unsiiutuenthe Massaujatawasty Sree aad eee oe 3 anunn onath dia sastiihifotonedtuogina antunaddlunsosunnay (oixing Sy whotetator don”. sill) ae scorch witntoy wiotilanviialoigengiinarae core molu 2 ieee bi Lond wet ate f 4 24 Satay vavorgmygilgstuas scorch (Gann dafuartadarsadluagoaun erie te Hita wu dt oy “ Kcunossedaiunsitiudy Aanutavasdinis scorch sa-duinnrsuduaantiiu52 nisin 5 jauatieraeat i ‘ fart anon dowd. dondistbarnediauasaliinn 8 Sa rtoataadhvtvararsoc tnt A len wweionosnn a sfyualaida Taser’ jauaadats uonoant 4 way edonfludonttasanininat anv yhowivin ¥ fadoadnarweni av scorch romans Saree sean (former) astra aquastuarsncanacordaTauty davirtnanns3 aanannt eenaunstuuunitth hunts en 3 self voleaniain (dipping) sruetngavbs 1k Antetanviuaean vatunrsvhin rien! iB aanoaivertta iibninwts ane Suga donate Tnorarenarsaca wee AlaninitatsTom avin arvuaat oudnunatuitdonte Wena ania cunastinsataate ‘Bavoantst sauaatlnn entitle aslit peaky cure fia enatnestulatonsei idumnany 145°8 dium notanoarnsis x sautstatetninvoetete aactuon ad silent sion’ unecranrsontren ei dat anna mstisws raginganagHyos (self wl mages ood voleanizins solati suture estas dy compound) , ansacaoitdanlite 4 sash cure V7 (fast ovring) , devsdonucdurs (repair stock) > pandontlaaiansyu (dipped goods) > ahansonue Clatex compound fabric proofing) ansunuimen aot idee autautantotatomsnie asiloignasthucinwnna ower snuff nae avilevanagns catetun ¥ ry Sndvradgntannlsvon 4 Aqunfttatinarnsenrorées seus geil aedarotnomnasntt: 53 3et,1-2 Sodium salt of dithiocarbamic acid wt de sb sac sstunguilly Sado tateun fA) Sodium-N-cyclohexyldithiocarbamate EB 4 part ael 5 Ee ie tebabile NC - 57a My domanismia Vulkacit WL at Baeyer 9) Sod iun-N-dibutyldithiocarbamate fF janine nil owrsarsniia Vuloafor SDEC’ 994 Vulnax Pennac SDED gay Pennwalt aasidaa y Yea 4, ae “ dau astunguiltthu nfovostanetariton acténrnaw Runstamtusdananeadutauiinitatstamsviiie vavvilosanrdacssunart ferawlamurdrligislaluriers gougiislunstanridannsonriagstia Hast (umlunasifu 125d uisriav'la peaky cure) [2 au tt tua a 7 Tooninan ssagaibintdtan'lalslomriaurina (Zine dithio- ; Garbanate) aduravinw daaelunandaittudarinran datum sianrlud Be ee eeepc tLe tenes Geaviun TdvitenilalsTonrsuuilvutunos ddenvontda ualinovtvasalmin aasenutney Tatdnitalstonranian donsacmulalugidaazawlinita tee . 7 Hatt Mais amMAnsazamasadtuis asledrsazaieyu umlseduénwluanas ST EE‘unataan cdoveanergnaedivsasitinh faunas initia via wpsrsacardluidescuiteson Late stanviincamesenaioe ; snavtatauuvda distor saitrauntotuguarsas eadlunnattunmed |, chao Belele3 Zine salt of dithiocarbamic acid ongaraalsetmdestatotomntan ihusacsasiintateto- mnsvrunniicrsigige neste natrenrailgeunnsen sronrsooasaerennitiaun a. Binc-Nedimethyl dithiocarbamate (ZDMC) cH s osteitis N-C-8 Zn so , 3 cH. dhaunafamanrsmiio Vulkacit L vad Bayer Methasan #99 Monsanto Vuleafor 2DMG tot Vulnax te Zinowladiothy2 dithiccarbanate(z0c W40 ZDEC) ft S cot, EEE 225 -¢eN S ’ : oH Onis hanidamsorvimia Vulkacit LDA waa Bayer Bthasan 04 Monsanto . Vuleafor ZDECtaY Vulnax vo \y3 be | Cully mavrvdamanisaiie Vulkacit LDB aaa Bayer Vuleafor ZDBC va Vulnax 2DBC + Yaa Henley Vuleacure 2B a9 Alco Chen 4, Zine-N-ethyl phenyl dithiocarbamate 8 Ong fhamadamsnrvsera Velkacit Pextra N YOY Bayer Vuleafor 226 a4 Vulnax tas a, Bine-N-pentamethylene dithiocarbanate s s eee mH on N-¢-san**s7-c-N~ ?> cH 4, 1 2 | oH Cit, ca, MovriamanrsAiia Vulkacit ZP 909 Bayer Vuloafor ZDPC Wat Vulnex dratatstomaiia 2% oure sravwanduluiteytatolamsurn *iaesatungeransatstauerautnr” (Tadlinestdunsnelanhorsoons tier) ovsihin cure thi sitar sondsnetabe ron 4 dun'weduta56 Sadumrstdtmhorsosnariuar gribmrwsstums cure 8 ditinmarduaraianntdinds asi ne-Nlpentamothylene dithiocarbamate, ZinorNndityy, dithio carbamate, ginc-l-diethyl dithiocarbamate, Zinc-N- ethylphenyl dithiocarbamate, gine-N-dimethyl dithiocarbanate unvilsladuarauiset nitanariaraavlagnnas Hasomueundin santana ansiita 4 soso sitar susihin | astanefivans cure Tht donorsowitatorr innit cure a arunsy woaguina downs care tundesicorncitarinsionotine sitidadintstemaniin aronsoaenTuniigengiini Ywautaunntaninta w 7 x 415-125°8 Tuseoer aad uni ignagiganrnonscinms reversion dul Satuoananatoee BIEN) ATG cure vau 125 a malidvalsenanean Tetramethyl thiurandisuaphice cc wfo dibenzothiazyl disulphide yo 2emercapto densinidasote'd ; suns tatun sbaa stoma sani cure L aun uals naudiuannes nasties om nia sevtiane scorch t nestor futons ruta “chiienistoutontatstem ono wloanadsenevosdtiawavtd “ (R+O-G-87) Bn Nao Sodium alkylxanthate Zine alkylxanthate59 arstee * i fa saaiinuducmeihusintsait cure Sayan c5anrndadtesitanos > dy datyfetetontant tuners sden.a’, dithio carbanic acid (didn dulnaytunasiinteluvnaun unaraletu asiuthaasasavuvasons Tutor ioadudiiors! daub iteallalstanasuriia whim mtalalugndiasautins dasha uae iomuduc an allio sana inudtuemda vanrs doa vnases nara Tucioudueanuaedaee ae edad at ea a 7 asuem amity cure Usanviteeletau? 9 nad samantdasiiuasnrsit prada doce tant ‘ beter I Ulovarniacsadtin’ cure amin dathugengiitums cure nasaee’ vox 80-110 tiatwla plateau curve unis cure, wthuminasld eroont nna: eqitinai eu duforfnnotototonniincan UniinasAss 908 fs stn unootiont twin sais iunanihvhSen@naann atunresrimin A 3e143. Thiuram, accelerators ganntuta s s R" -C-S. Ngee X= 1h RUGR",RIM = alkyl group msvaion Lssusaladalindaan sacndeutalncnrsoan nd letstonauaiwa faunraaotit 8 s s eRfi-G~s7 Nat > RW -G-8-5-0-n oxidise : e Tetraalkylthiuram disulphide! 60 dawlogwartutudalatat sfavlavnnraitogussladatamentgase ud », f aan wy TWitiderlenilun ‘asthenljazoranalait et ec RNHC-8-8-CoNRG#KCN <-> RpWl-CoS-C-NR, +KONS Vetraalkyl thiurammonosulphide Hromnavasiaisangitogusn ‘leun fl. Tetramethyl thiurammonosulphide (THT) cH 8 8 oH, " x ’ N-C-S=C-NL cH,” cH, 3 dovasmisnvia Vulkacit thiuran MS 10% Bayer Mono~thiurad 1 Honsanto Vuleafor THIN voy Vulnax Yetramethyl thiuramdisulphide (THT, THTD) er a W-G-S-S+C=NC ony ott, domansmie vurkactt thiuram vat Bayer hiured 09 Monsanto Vuleafor THTD | fay Vulnax 4. @etraethyl thiurandisulphide (TEP, THLD) He 8 Cast [ee N-C€+S-S-C-N CoS Cos: .6 Jowranremiia Ethyl thiured 101 Monsanto Bthyl thiurea vad Pennwalt Ethyl tuads 94_-RYT. Vanderbilt Ye Dimethyl diphenyl thiurandi sulphide 7 cH. ‘N= -S-5-C-N wa Gonnsmrsmriia Vulkacit J a9 Bayer Robac J. 001 Robinson Brother Ltd. % Dipentanethylene thiuramtetrasulphide (DPTS) {oly Cha 8 8 CHC cH, N-€-8-+S-S-8-C-N ct, 5 ¢ \ ’ cHy-cHy cH,-CH,, damnamiimiia Pre a4 Henley Accelerator 4P Ua9 Anchor Chemical Co., Ltd. et wig ot tow da. prea Tutnnuiaisie 5 a TTD uae THEN Lihutpiilow daaniiga Mwavlegumladatin iu TTD ia TEM qatdacn anon eu wanted = vit Ye gy tt 05 phr ahlunriedy 2.0-2.5 phr wa nrsldySaoduifalthatsa un Snnaihiivta ovislogustedalindine 3 phx Tan'lnaslan'wedtindanse eas Sa cure oivladuid my cure Wwidun "Phiuram vulcanization on an eeeta ata ae Anigarerstannsil dnwsdu (2.02.5 phy) Aylaildatmeduagilacuanarsau Aeenaranoly undia 4 ua did “paiuram vuleanization" (singe Vuormsduadtahamiondne iadadbinstanaludeheintucr aie waisillagaat z s Perea i2. ae 4 : fu unnsldoweduas Sinanwasl avtfon'lwi Low-sulphur cure Wo EV-cure (BV fon91 Efficient vulcanizing systen ywia62 Pee eee cee vit diredomnslussdiantuons eroeshink) séuuiil dared saremad jiu wae compression a wo eee u esti ginanton wa ces . cot Ma uadsuudurr mm namumaursty, srumarnamsnwse (Abrasion resistance) waznrsuanduilaszinniaingaliia (flex cracking) (0704 1. psi fLogusutuia ss aera eee ate eee zene “Vausainctnetasaae simian ag se arduersssasaa wlly muaunvaialsguans H184e scorch vino tatstomsin cians eure $1077 ed arudingtagusuarerinas T™TD cit cure caailgn dou THTM wae TETD soxavanemnts uae DPR aegetungatagusn ovititogenantatass dunsotimntidtnervit vd Janrtidladtandaadaoiwneorentaon ios annvilegusn cure hhuitatstomanean arias, wibinarluntunrseadosdn vinttuta Ctitattatonnan fae noxaetont fon cure 4 “a ‘VuradardA) druarsitlogusudanrsa cure Tavlitavrndeanadsouniu che visrelogusn cure (Fanoders vita Sinn apo cure Tnatartifonrnrdson dudaslupl 9.8 i Le » Jmaagdussla — cL 5 mraaelvanau War cure gil s.8 arstdupiarain cure th ciatatindituin63 Frc sangutoyusua ur sost tatu eure ante Taunasdiiacsauraia ercapto~ iazole disulphide ‘Ghia sdstaaaminno 2-n swctucdnodhsedahins amu cure shasta waar dibenzol penainsdazone Lf antennae sanga ogy cure thiu dwnild basic accelerator yiuaspbony guanidine,0-tolyl biguansaine wo butyraldehyde arsine dua vdatiinssguloan strata sangutataTom suru ua gvivorttasosmstiaaarty sostihian O-tolyl biguanidine Wt ieerinomnr Auunankstagussordtitihaiar sstians wnetaiintanta vadrutunad a logusaisZaluntaia aalilsragoreci so Ueusitions an cure tras (delayed actionniraitinas cure diysinedtua Fatal 369 sukphonanide — sulphoneside + thiuran Torque cure time Pri 3.9 mnsidtegusnnseqadeihentunuae dij delayed action6h : « pee te teeter ae mrldlogusunse mt arsangnlir tuniihoa neigana Tooter swt qmusduias CV eysten) ‘Tunas cure wnoriélegusafianatoy 9 unas htn dag ‘ Aa ¢ at oritilotstansunwainiti scorch time HUH ‘Vunstal THaH Vaitiatogusn (dimethyl diphenyLthiuran) aetananrsWilt scorch tine snanranst TTD matigrmmcdi aastilsgumnae hassoantnogane visting wala nosiasatashinva anni fun cure ‘uns tas5e135° 8 (ust onion 4 d Javiitinrsqaviuty (over eure) ‘tae (anshudinnst eure Tns/ldlogus vie low sulphur uarganigiluays cure senses) anata lsgusmide sausluortadtategusavanesnia vreinfanotan selina somonuna wig hysteresis ah dnansiiait ad sausouiiau 1 compression seta 778 at snonatitapiouotn stoi duvas Tuas adtunratiftagitnn usaraoarnsd talaga ira usduisTiunraaniod vession sett taenmvtoumn chinaturda (seat) heat build up mn de annarmsursitii comp! chumw Lit mp a phutednion ht THTD 3 phoyhued 0.25 par vio GHTD 1,5 phr, HBT 1.5 phr Wagn? 0 1.5 phr Matorsufioaa un aeliwnananininaussaaaan nastinraedumrnriina (dararustild 265 phe) vaelnr Tage sasha srunsitdtunanieitssta 4 dona widens sta sais dagunanatiun andi ora a Verngunstltatuoe aunty uniénsaa savy ingaarienh attvewans uaedumanagnd runs haw65, y.4 yalsoilda (triazole accelerators davsannlsaytausenouard 2-aercaptobenzothiazole wazayitus Bee gout Aaussaitotiin ehvaniign gnamaucilas 2-nercaptobenzothiauore fa pr 8 Ye - st St Ne sfnfon 2-mercaptobenzothiazole aansaistounaniamtacn rar alaie sanavaidu msuawledatya uavo’ntedie mitagaugiuasanadiga ujiten 2508 v8 +5 ae OF po 7 SH + HS 450 wen a vown/ns.ua mM dibensothiazyl disulphide », BER ra bea eB nrsvdondaaan®ledtactheSosdreyin avisa7a aamraaratealana sont tot 2-mercaptobenzothiazole bat ByY vag tT WW Neocl Ala aalidFernaui By et 8, U8 2 ¢ = S7Nat + NaOCl + {80> { 6-8-S~C a Wy? Sy w + NaCl + Na,80, + 130 sromrsaosiarsatungitsartaa ‘Loun 4, 2ercaptobenzothiazole (MBI) 8 gennaceit ee © - sit ne feminism vuleafor NBT wy Vulnax Thionax vey Monsanto Vulkacit Mercapto aaa Bayer66 pibenzothiazyl disulphide (BTS) 3 ' - ot rama a e -8-8- of 1) / ay 2 domanrsm Vuleafor HBTS a4 Vulnex Thiofide 91 Monsanto Vulkecit DN | tat Bayer iagole (Z4BE) 3, Zine salt of 2-mercaptobenzoth: a yes gasmseeit x o-8 ne damanrsm Vuleafor MBP 994 Vulnax Bantex #04 Monsante VYulkacit 7M way Bayer pasta anuasaiala dasa ours sngatentaaite atone Wreaan fastitoovtsarnneannn ue? runanfiatoguss sosagngitaans cure tgif we, ‘og +d elinwiediaiarennnn Sacto] Tuga 4 fyiltdtntetomey aatdtsartsanti i aaiiutonn 4 waa onsiiaaetnnninonfits anv iva 4 vin Tsgum AntsTom anu camnason warns tan gat aalaiaursitiat Funguaosdnadac sana sagalunens Gham dalits Tungulsortiariinmy scorch time vosursaet Tusa Twa AVAIL : mers > 2MBT MBE 4 ei Thu uses ail scorch time ovni{noe tan ad : . raat s allstar isa dnwina cure “Layjn gulunusi9sa 13 960" oana atin gianm delay 4 4, gotniosdn Nain. annadion Ghuass Tadtarniasdariny é etson Aunastanrtied yibilsartdanne ans cure nts MBP way KBTS dua aetinn sindlunsuaaarns Sathdadaclu | nwlsglvesensn Aiadost worsen Samm sumadiens Soussnealtsor Tua prvng ibaa sn udu sonletstonnanuamine ogc unnnanseqilanati soorch time dustin dunatdsonits basic sestenaton Tosh ntti avlvangadnuacnrat 31ua7 cure ihnrnbetiitinantin 9 tdodn nvavabansed woe at Wananuas waaay Aca tee. w 4 synergetic waraiaiy) auindluguit 3.10 synergism (¢" fanaa via th - havs08+Dpa08 MOTS 1 phe eet PG 4 phr é Cure Timo = f 7 ; : ail 3.10 udaanistiin synergion FEW MBTS My DPC canphretinn vers 0.5 phray DPG 0.5 Pe ‘Wmamasege( 907 Yuma cure arwnmnunanssiis wwelupigann roasts mers 1 phe vio Dro 1 par codn cvinmimositsnstioni damortunsttse Trung) paote accelerator iat saettioratatiin vin pps vo Dora hexamethylene tetramine lay butyraldehyde aniline (unt6a - vametogusucinseg gavlsavidaasriuenghiwos flat cane antatalstonsin ‘a scoreh tine finns unaefaaein dunn uaahtininn ata tant tastomsiniomesagtineaontentstersp%, basic acecla ogg mstitsortsagsuast ne siularened asleostan nae Sonia aglatunatuns avons MED ovocstaefine aasld MBE Uas i gauduaelt scorch tine nisuadoumnded nusoan tet (uBT mn scorheh, \Go, MBPS an seorch dn) wae stil pPG qaucrtiiuwosuasilaedan iu safunrsisinlgsdesinusos npr, HBTS Way DPC seit ms cure vs re time Anarunasnas Tastmnsan nin aansatdan scorch time Uae ne 4 @dunsitensiias cure Tooarnratsow dirt enstnsotinintid dani wavdae ciihaNd basic accel dy Deo Wo Butyraldenyde andhine (wa) sant vor Nase ou ‘ Wianonstas st rears hexanethyLene tetraminewiy % dounrstatsgusottetatst aman cainns vital univ PG via BA orafiaadtvdannatatsartdaiy basic accelerator daa anuserteentsnsitunostdssoantenacanstehe ne atid x auntumanottatajaaer atu os tontaen wnat gu carey castaaadennninatieny 9 m6 2) “iad uoransegurrntonne acid (miua satis duidoantadiwundsuaan venenid nandvaedin Coviuant 17 49) 3 acid (asia 22 #2) taba ee ae ws fincsaloorTaaiisam aiudstaonst ins ‘tan snoadii dm 2uB? dal scorch time senna HBT Whe HBTS fy zune ane} ‘waters seen wan uae cure (yan07 NBS as dovtinstan Suan salunae ayersjo5 Sulphenenide 2ecelerators wt unin ei aac sanguin landsenovaradauinihilsortauaedawiciivesihn gas fh 4 Wwoosdlchevtana thiazole Marea tundwnsacaaa 2 Ihe ne Tanijadnraondladtndaaziiunas 2-mercaptobenzothiazole 9, Ufiiivrsei7112-meroaptobenzothiazole MU N-chloroamine 8. PR ASS ye cost scien’ 3 (CY TensnZ + we Nn? Rk Ne SR shovasvosiaesstungrtishuntaa awa 1, Benaothiesyl-2-diethylsulphenanide d 4 Cries 2 alls i gannaat CT 7 WS Cally damensm Vurkacit a2 Ud Bayer 2. Necyclohexy1-2-benzothiazyl sulphenamide (CBS) cy 8s - . dasa ( Y o-s-nn-<) — gamaamiyar 96° ne ae :70 damamany Vulkacit CZ: yoy Bayer Santo cure vat Monsanto 7 Vuleafor CBS aay Vulnax N,N-dieyclohexyl-2-benzothiazy1 sulphenamide 3 i: ae a wy 8s y greet fT e-S-N Q Lan? ‘ <> domnansen Vulkecit DZ vox Bayer Vuleafor DOBS ¥@y Vulnax 4, N-tert-butyl-2-benzothiazyl sulphenamide (TBBs) aman yen Monsanto damanism Santo cure NS tay Delac NS vat Uniroyal Chen Akrochen BBTS Wai Akron Chem 2+(Norpholinothio)-benzothiazole visit #un7 N-Oxydiethylene-2-benzothiazyl sulphenamide gamons wn a damamsm vutkacst oz Hot Bayer Santo cure MOR gq Monsanto VWuleafor MBS — 99q_Valnaxnm 6. NyN-Diicopropyl-2-benzothiazyl sulphenamide doswacsit of gnvaantuna 55-60" damanism DIBS aq American Cyanamid Co. DIPAC Yay Pennwalt Chomical Co. ata tea . is Sofuvluarihudat sain favianrssanadad MBE AULud R Nn? ~R n” SR fay td te f dodhualuaclutarsat delayed action wo scoreh time s19a7wntsarlda dodninsrerfotatuitadlagunrroutesunadeon ‘Ii KBR WAetMoomN reneviortoviacumdrconniadtinia detayed action galiaunnittaen do itor Auvvatindunn quifitt dedayed action viv Uiadihmtumania Wore non Autuditucatndomsdoartudacautretdumansegitiniarss vnerutody Tageigads dehuastintarurmnormnsteshntatucdassos delayed action Bogdinuaitnareis war Suavostuduuala 2 ansto te base strength 2, steric effect strength ayasiiu ‘Unlavannaaaanira tno dgnana lt 1B sratod.d.or. 1500 100 HAF 50 Bavaontse fi nsnavanin 2Santoflex 0D 145, Paraflux 10 Tt . noyedi 4,75 yo dailunton o.0045 Twa ae Vebdhetunigardstulu CT Se-s-r if UX ye vk, darosilu | Nooney Scoreh | Relative cure ral ze Py (ys-P yg" B54) 3 . i I | Bag = L1AA( wi) finr Mooney gaduarnarehga 10 sae : Tyg = La(inii) jim Mooney gatuanamehgn 35 mnie saan sadanarsactiniada aun arocihinr mn duudganrsuandavorasiivena Mp? fastinllulaginda wily scorch time srihuias cure rate didi Setaudl cure tine thay hidnme73 2, Steric hindrance auilufil steric hindrance winaeitili yore sore avin vasiidasaiatuns eure gviwllaane waves ee d [ esic ef foot dorovintwudnymunaasi 3.1 oo Pros gositl A unrsunaasiiaait srstod.th.ans 1500 100 HAF-black 50 Bataonten 40 nsnaiicin 2.0 Paraflux 10.0 Santoflex Ob 145 anaed 1475 asia 0.0045 THa 0-8-R vignssostehntanutl OL 7 Papages pi, voreedy | Honey scorch [Relative cure rate | (49) (55-2 49) | 3.7 27.6 3.6 5 42 29.7 46 6.2 3204 4.9 cH on, 3.9 46.5 10.6 cH, My7 nastadatsedaihituncindunritn scorch tind duawraimiitn cure tine Ransarnunetugdagatrernery dnnrvakaartadatirttungs eweitush alts da ms cure Witnn iow sulphur curevia EV system dadawetn comp act mh, Hysteresis 91 wax aging dou tioaanaalualudly delayed action wilwnag cure ‘Tuy duwsiilaaial mina ta tavaainn unlansneinms cure wanildarnian latdetuviamauty mens gently cure Vai aufansayanrtusTaday; savito Soha luddanadravradr 4 menradhiluornas unaiIalovrsowarre 4 shotnasrarin gafunashortuadathiatmetidouaaetarwa nae cu Fauna une'lawina delayed actiontay Wa Tetetomionandslepine aeniluiiy cure ative rng ara aimee primary amines (guCBS, TABS dau secondary amine (Ju MBS, DIN aaa “e ev ao. ea ee Was DOBS audawAadian falhuns fustinn sean atta on? iauloat aan ansdanadauoadeshntuatavnnsinns idounesdasdounsdta siaadad 4 peer aa “ alae tna Adseaonveagtaarnnfiuvasosihngouasiuiis uneriawinnadrndtuaeardty danasaa ean o. . fa od Ujiierars is asdddvaazaiburtvaduia 8 HAO nt /S\4 s. 4 coserrn 29h { Se-s-s-0 (1° So-soe Z oy A, n@ LA MBTS MBI Sulfoy y 4 weedy pee teeta dat the « MBTS qe uaa rigitlaazardludanasoawiaoi nas masdarsAOWNIA 4 an unit Fudaromauralfigorse 998M wins Ginnasusannidauasshn asta 6 ad Sw dup ait Wat Hons vivant iu sa 2!5 CRS CBS + 0,25% HBTS Ls ap tg i 720, 160-200 a 80 aan, (ai) 1 udnwaves METS nanislalasidavos CBS 7 niu Iu ato a? soslotstwnnuoanenitr 22.5 «2 4 90°a(2) ey «8 Bate Beye nasrausavadatualunaerfanrstatasdddta adanidusnsiiel aasudas Ap) 3.120 100 sealed vial 65 ° 10 30 50 70 90 yaar (ait) ae 4 “ : vet qui set2 wdasiny TBBS AumiuerDe 25-30°¢ ea aduiis 90 4 (2) ss76 dyes tu enayeaantiihe fw nasidatvtundawiaaaln seoreh gneiu uasdasae stuns J aradroanla faudastugd 3.13 a 6 > 8 8 2 85 on 97 103 109 i B kscay , lh udawiages MBBS assay 9 Nooney scorch Tworsssswinid ‘ anstidudailualanastuens Sailr land nuflsal ae a asada usnavittaaa aman ausaduieasiafanounnanos 4 Ydasluns pasvruhidlaentadans etiam & nsemolunratin nysnse) esronoataontatae sae gaunautvaraasi urtyavoy uaaudewa ost (maxcing nit) fig wt fiat a ae t fanarraraiTivia duthdsaas iam master bateh Sant igengig ao ey Tete gaveany a7 wnaruigcagtig avfuiuaenttis scorch timeduaata ‘lwsiM aihalua N-diethyl-2-benzotbiazyl sutphenanidethivoseiim ¥ sana unasladraaadadurtsndn 1 Adhanaadya ra item tad srisad Bo ds da tnalilnsa snsittonstvnan (recdaim rubber) Wootters (aera (carbon black) winuilunt ’ We Jot7 aastianuasainla dedinbuhas shin sogtgnn uaetidiuaan Banal sonia Ww fet cure Way aging fin aysly Mat cure asildmneuraeam » ygorTdanaete _—~— Sulphenamide + Thiazole + base Torque A cue Tine > 3 4 4 F gull 3.14 tdnaiianralit delayed action voataihii'tan He I: wien fasttsortda Le : Sather delayed actionana sathduinnein sit furnace beck ihutasiavia uisrenntdleartvaaertfli score av umsnsemt Uehnladaild basic accelerator (vituassquastanalanmin oats TR InlsTonasuatumvalegusauturassquaclumadnyy babic ‘accelerator sn ; on rtaatovtanshathna te waantdrann an 3 phr, iotwiter J Usedutinangagn dounsetonh udu ore fenoeruiusuonan nsnlaiivanas Lf kananns ecoren tin anc aucatduriercdatcint nvsldnsalosuinr wa x a Awhusedavteosda funseerdunnatariedhn usdainnitlertners buiading tack gh Leena nine (fatique resistance) (A2aIAIH da astddaurtanandtaguntadetinaenttntwedinsaran nto aetinrsitt compression setinv, aging dos wwraihl dnredtuaedatuatunaitos osnatiteahe. 78 aavormstilogusnianegs Tnvilatwedinidnaramiounfolailiy arvana Toqussawactadeshnluntitucfoasty sean stuoonsniiaoraas Tagua dathnlantatinLintwdarheitaaasinesaumafs 4 ht ovascoud onaduaw dy Suds cavanatvosmsildnardana dothntudlstatanass sauna tava, onitillasd uawoasdatve uncuidionstiatctalatdntwedinion anedoihuat wWararinnr wad 36146 aariantludnredrsiasaitilunrs matdougniaeriudanrer nn danoom sand wacl anaes anvil thnsarfauinenaertidasrantiasosmstaactiney abiorye ta magqniacthidac tana amanda stieltuaratatasaatudradar rad 4 Wwhuns wititidhemnsiantudtinom san Foateiladalianracnetia. sosatoatunsttfioun aravanihiity, secondary aliphatic amines, thiocarbanilide yaya yalsenauiit havindadldns wauuantan tours Aldehyde amine accelerators dnstacsvtngilt tuauannrsduonadnn au éradac zs inalltn 3.1.6.1 Butyraddehyde aniline 3et6s2 Hexemethylene tetramine 3a4s6-3Crotonaldehyde ammonia 3.1.6.4 Anhydroformaldchydo-p-toluidine 3y1,6,1Butyraldehyde aniline condensate (BA) 4 gaswrsioil — Ol,CH,CHOH = N7” owranasan Vuleafor BA gag Vulnax Accelerator 832 vol Harwick Chen. as 808 accelerator ay Du Pont Beutene gaa Uniroyal Chem. tedonrv milder anes ay : a CHCHACH CHO + H cy > ar conch = NX> + HAO 4 butyraldehyde uasoildunayjaiay entrees as eonumesins 0.9hat.02 agarsly th cnidy wa Janadaa azarditusnainri 5.9 lorem ioamatesanenats Ylugaororst moatiiy mundi ‘4 ist eet BA ihdasdacasiess wtiions scorch siaiasduens7 Tarra Warns (retarder) nanny seoreh la wnaeti aiphenylnitrosanine ae + wfonsadu 9 han and BA vennasiostiinns scoreh Tnnladasdaesabatega won wsqunranouratnobl tdoaaan Ba hunascwasss sates as ‘lavia BA Sauluansinn tsar angaonans vitvond iT ugalag nails BA dwisa cure jativtmadossi Yor cavtuoraviiou dwiunis cure IW afasdautnnorseifasedouins BA aitinnaduiias7 o onauttlnona vats ta fsheorsodtusosdlgagigs ts ast nasvhayumos BA aegnasegilt Unhidatantiaaniaranmmnsagsiite (edu 20¢, TID), tsorlda, dathntan Weldtoarsnda (avBaaziy whosndivty BA shonsegulsartva, deanna wiLavaneaioonann aevevtwarsatlagdag ewan naavrsaaas BA sii sasaantsnogios ( aitsn) arationaetane tdi nse ta vant BA wens vanradtutun Mast cthinost Banaa maldiu 0.5 phr e foanastimnsilonutnanutanr naraEEE 0. snassmudyit cure Taunastd aa ‘Wnadviinnas reversion traf = 1g BA agen a Donadatornigs Tugalaga cavasovtituonaiudy sada vraande anetinn uaedawwaw dha Jbdiantarnrerasooud Ge scoreh stil) uaumnelumandtulennnssssain’ cosa 8A idea todu wgssd Ahinanslumatsiinnrvtaosnaatididan Iupndunssantranatineg duiaiuawns 3.1,6.2 Hexamethylone tetramine chet sinc ianniitiomuniisan adit vostiaditan 4 WH, + GHCHO -—= (CH,)gh, + 61,0 3 gevinaiil tnd 1920 thers raed undagiiilstrdyuas Tagihil outa savadn tadarrmaasequbusauindiitinide 8 nastdarmuasdain tench voi Lanai ae tetramine) (UWAIsAI154 ay ot de dana Wa scorch wn quer sibttugdanuae tans reversion law indy Vdarida aadoguns aint ienstuiinduns Swntidanihdaana thionsinasat mnadén aclicradactalsecomtatstomaninn Tegusn Wetsortsa wats (dar uniddu caasithe dhidasta satdivhaonseg Gwradaiiawes aha st ae a ae * ac at ; fusanrsatiamban casing autdusaniaay81 Tuaginonsnat cusses astacinta estou Tag cure enstapian rn gant nse dagen cure shutters £ Tia aman suite saudtathe dtumaivassn dusoscin paoisdavionmnd und crow sauaonasoauame marrsamastdas anita. ‘ iesatvnasasoon dane uatuenciumos dasnteni 3610663 Grotonaldenyde ammonia Sudan sastina ran Saunas Loensoumatentad : dasersinistaein wivdlaranlaaniflunrsnan wae eoraifudonta sas sata dagyn73007 udae iwdvlatnsarsudes Nis 1 da ifr gs vs ‘{alstananiin ‘Lagam uiosunuta uaedathentan od a onaldohyde ammoniaeynnnintiluiansegi : aonsnciy tito Bavrnaa Tua ania ss satariatlanatdn Satuttlonscrot: A twiudrsan sacwerit : Eee eautta attra trot etl ‘unatls crotonaldehyde aruihnasiiBenoontuncitalytanaitingn wens tutus uihuaosti Aaeluo sadam ouabain jausrnaedin novos cure anuilug sna una o ¢ “ cans staan ins Gaus cure BI ¢ Addasdasestnilavrtmon plateau cure ns ons crotonaldehyde annonia anaciaantaintiiesén wiolew ‘atdormatsamaae cvsignore peepiniar3 coaeeetinsss pt : Jonriufluarard savin, snatdanrtdunsasuhuen atta ‘diiadnfimiona watdaaa crotonaldehyde ammonia spittin dione pe ¥ ae wa tama sathdonna Ldn aiid 4 tat wad asia! inauean eta ht Saati tniein snotiahiowne vWondinan fansite ‘grotonaléchyde eomonia — davlugaeldauanssssrtuaceracod i, nta2 3.1.6.4 Anhydroforneldehyde-p-toluidine | Uharsdarsadiinnrae sydd Uluorsiinaanas cure 4 « i eee ele ace tle cu rarin 9 Tadltinas reversion drsdasaitveniversidsliian tad oe TE ec reer da eee ae ate A aauntusrananrsilsgd citoras wore iani lust sant Towl vey ae74 Tails Ie ae a : woe’ a tdneaudu cansiilu (nexamethylene tetramine) vasuansiouidal duly damit satdiudiuaasdasaitiar mt sagatdy Grasuevla “Legusa Taovairs e ‘oe a ae d ay, ws LnlaTamsuriain unonrw'snmwi satin dtaga 9 tHowianaluans¢M7 cure dy. Hal idyoouiy Sereda forever ' dist sadiiniion sel wlagaauarnay] dns ol FuIewAAyN Ulolgdrastai sadwdseunnsonay 4-6 Banoan'lsinwuihinasl dunnsca toatl at Sea acd tae grata ee Ai avstantiuddawlyyatituasasdmisolela unorardisautd via tisaenas cure iitann Udoanamsiantludaastdcoannu wigan Bones snatdeasdarsasia’ su aowmmnnmnausada Tuga aharnclaldaasit ts dug iu Lalotomsuwaa Togusn tsortda fo putyratdenyde anitine dun mnsitdinstcsisinfaettten snd savannedy Weannrunonasiiet tiursannn Aaattibmoslduodoanduan dasisatsheldiuenssssde idhildihoramiganasdoriinnnouiens 3.167 drstinsamaitd (Guanidine accelerators) arian raogaiftoun diphenyl guanidine, di-o-tolyl guanidine ay o-tolyl biguanide 3414741 Diphenyl guanidine (DPG) grant <> mi NH & - al83 domnamrmn DP 0d Harvick Chen DPG #04 Monsanto Vuleafor ppg 7X Vulnax Vulkacit D ad Bayer Gm +08, Onn, 8 “4 PO >a S €Y- 7 4etp2e2 divontolyl guanidine (DONG) Fiat c NK gasmaveil nH cH, fomanism vulkecit DoT 904 Bayer VYulcafor DOTG ay Vulnax Dor ax American Cyanamid Co. 3.1.7.3 g-tolyl biguanide qramaacail 6 domrannsm Vvurkacit 1000 od Bayer oo AH nas danmasdatia arama sang ndaiunthdrsdaisah cure ty dasinrwt Talus 4 tg eta scorch (ausvinlavidsavina pPG > DOTG > O-tolyl biguanideBh Abidurnasise dmueran tmmenod cure, WM ‘tt over cure mu ung ‘wistiduaeittags plaguncligdionacidu onsets cure uaa enti hd satdinaedlansnse qufwnntaatannemanney eaumontsartda tiluaw wit wd ay Twdduttanegulogusa LntsTomsinesa uisretiatoatit cure (Frog arididailuvtundatiiasoma quand weudaani dofiduasladannsequtad Tunquoasdaiifutos Unsdvinmvardnsiiasauveriidamady a diay, va a t forwiansequgann PG we o-totyt biguenide edn arcsitetunsepd Asoaldaaemuaavianas scorch Iaiie unaild o-tolyl biguanide wn jracoreh amin Tuts pra, pore Malad 7 unaetachiiaeryd s oot eee terete . Jedmnseiamtuelagan awluenvitiaruaninmunans saa Tugdauacarrs ATULAYa, heat build up M1, aging ftv uncial deatiucthuaa sau acladnnaafamtudindtdormtsoula es waeduda its avanti qunos ihithmostBasoantseudtiaThaastasalals iHareseHituos cure thal avortdvantivlvacdt vaults Dsnawosoriastins PG Uae Dony ogee eects. Avardluslan du o-tolyl biguanide axaiilavos gant aarnduadd whet aaster baten, srsihadatifuthta sadtuasithitimalavcanas ui DOTG way o-tolyl viguanide aelidoouny PG, DoLG finger ve a yt doa de oe sda Auaivinuaneiasl Muswiddadvanns Un o-tolyl biguanide arasldta usieliasaraadluuninaanvininy Sauna utiea oT snadauidy Tedld o-tolyl biguanide 3-4 % waenraedinliumdatins an’ 2 ’ . we dw abenensartunstaumar) asada cure “Lau shgangiivass 2 fv 8 vif ead ain ge iy e Familie dutharsdaerangaiatttviatsuenmmnssasua sean Ane uaw |85 2 Saver Mn saunyaniluduarm USAT AIWTaMAM (eynereion) 2 darrar nn sTuags ran aluoo sd san BWANA ANT EAOA TH e177 wNaontihawaMAMAgAsLA UasarauNs Panes dn sitac satin ghana itituasnnriadat a. dasdacsailcdunna lan enhydrofornaldehyde-p-toluiding, putyraldehyde aniline, hexemethylone tetramine, DPG,DOrG ifun a. dasdussihtiunsa aun Lsortua dathurtan ogusn Uelteto- qiviuununcieduion dum asdausailunseil thdtiowtanan odioniounrin sujidortunas Taorhalors Tas dae samagins : sats ©) - svasraudta 100 Baoontan 5 i ent oudanta 6 nandvioin 1 i“ ahedts 25. : ansitnus 0.5 ian's press cure d athe toate on ‘ 4° sos 3.1 Wieutfounran s2¢oann satmednlaadwoaa iA i i cana joptimun cure! saroey |PaS : Tugdait (ni) Cks/en®) | 00,2 Butyraldohyde aniline] 25 acorchy | 200 100 : vec 25 safe 200 % Dore 20 safe 205 103 vee 30 scorehy | 160 60 hers 30-35 safe 160 6086 4 ‘ ansraft. 3. (a0). aan optimum cure T.8. Tuga tea (nil) satety | gfomd) | 5°08 esse _ kg/en! 2MBT 30 scorchy | ,160 60 cps 25 safe 220 115 mrp 8 scorehy | 210 103 ETD 10 fairy safd 207 100 urn 10 fairy safd 107 103 +200 2 very scorchy203 25 ae , eee te wid 4 * (awae soc winis cure 1125 9 dmdasMaaaU cure M1 sats hort 4 4 igor Ma 3.2 WAAL IATHAININ scorch ilalddrsaae A 1 Tals azo. srasssutii — 100 das cduuitadugns a. unit HAP Aeaoontia 5 arson fuertnon nsevieia 3 | amruedit 3 inant 187 ete ecorch time(uni) | dasa — gaz a. | gas 8 NjNeDiisopropylbensothiazole (DIBS) 63 ar 2,6-Dimethylorphol inebenzothiazole-2- sulfenamide (Santocure 26) 60+ | 27 NeOxydiethylene benzothiagole-2-svifenamide| (NoBS special) bor | 24 Blend of 90% NOBS special with 10% MB? (OBS # 1) bor | 20 Netert-butyl-2-benzothiazolesul fenamide (wens) sor | 23 2eBensothiazyl-NN-diethylthic carbamy? sulfide (Bthylac) 26 15 NeCyclohexyl-2-benzothiazole sulfenamide | (cBs) 60+ | 20 Benzothiazyl disulfide (HBTS) 3 2 | 2lerceptobenzothiazole (H2T) 12 9 Tetrencthylthiuran sonosuifide (aH a | 1 | Tetracthylthiuran disulfide (TETD) 18 9 Zine dibutyl dithiocarbamate (ZDBC) 5 4 Zine dimethyldithio carbamate (Methyl 2iram) 6 4 Butyraldehyde aniline condensation product (fice. 808) 19 5 Dipheny1 guanidine (DPG) | 76 10 | Tetramethy thiurea disulfide (HTD) * 68a aarataga gu ananartlandduarsdasalanithidarn suns cure ay ay Goaahaudanatlt Xanthate ) Dithiccarbamate > Thiuran > Thiazole Sulfenamide > Guanidine (unlaenbatudaiintad sida sada ualldtituny sauaaa) 4 4 4 a aoe ie ‘ ‘ Mash 3.3 Wun srits ws aUMtiNBAITTAI TT armani sBanaan ida uasosndttedunariens sadennsiarssitld antuvtonsegat oatlfiien ak a’ "ude sais ad704 d ws ada! o ! ars 3.3 Wdasdvenavaadscoliiiinanis cure woxdIsNILTN t ° 1 os elo ad ad Sinaosaradarsa | Siaeoe | __sarminngnas _| dase ars vente arscure| Iynoontsin| asad vaosn nivqly, 4 | cure that beet : cure (a70u Ammonium Peaky nasars | Vari | MBP, Litharge J dithiocarbamat, 2De -2-Mercapte benzimidant ATI (Retarder) Sodiun salt of[Peoky | sawas | Wushu | MBT + 2-Mercapt dithiocarbamate ape benzimidaty IMBT: “avant Zinc salt of |Peaky nan ‘luvtialu | Amine -MBIS dithiocarbanat: Awmoniua | “DMD dithio- -2-Mercapt] carbamate | benzimidat “ayant89 “ ad «| itinnos arquaaynrs ays satit graven esd a onsemll ° _ aaa cure {Sxnaantsa fnsnavanin} ORM, 4 | cure gray td a9” Ars canine Peary | aaams | usa] peo Lwers o-tolyl |-2aMercapto~ viguanide foonzimidazole, Bay asain aithio carbamate Plateau | aay aims | Basic ace.J dasa awn. wan Guanidine Thiuram Dithiom carbamate “Ada fSuphonamide | Plateau | qoaais | f09n1s | Polyfunc~ uot tional, amine, Dithio- carbamate Phiuren aanmasrea Ua LAI nasnsegallvariadion sanfianucs inne | da [ sth sautrouiton anavin araaetillenmradiionaati etniuanadaisaiieu 1 wove ivdmnea nits Ldunasts BTS dathnarstatss scoroh onan Bios cure iat onatdgnsda saaisduasadaunsequita umnadaarai90 Upaciadu cine oure Giaw un seorch tine ndvdungthl dan, pristow 65) laninisunaanin cure time une scorch time ao unalastigns SHR cv” 100 Benaontdn 5 : asnd vinta 2 vers 1 ahaedit 3 dasiatsaidia O61 phr “gqq SMR din constant viscosity wt a de “a ae Arsdasatdiuiitdiia DPG, DOTG,THTD ,THTM Wau ZDEC HANTS MAADUINA ead Anemaansyat 3.4 card 5.4 titvavowa sd unasenunrstd mens / Puede anaiousavdin Ov tphr |Noonoy, scorch (anit) | cure time (anit) : (ii 120 4) (90 % Tugda, 1508) te re 7 te Wid 3367 20.1 DPG 25.0 1202 bDoTG 28.9 13.9 TTD 24.9 967 TM 34.0 11409 2DEO 3205 | 12.02 samamancorvetinitan aati Faas di “Laguss petststomainwre sausnat tes Tnwiia 3 vanilartacnatnse qurites out phry cure tine fl 150°a avant 50 J sasyaavtin waa f d <2, qiindy scorch time 120. uaastinitan THIN Way 2DEC setiluiti d : fs Pt 7 fr yoneaviign ‘luniaan cure time tagluitit scorch tine ulamilusnatin 5 arin Synergion ~ Aunvinge gussfisnmosda it Janta somaiay 2 ilsecanita . 4 ‘ ‘ anansequasdat sal cure th Tam stinsanssh cure (31001 a wisartiva uavdadnlae aawlagusswa elalstan suauwaciun 019 a aan ‘2 4 dulinys cure aetSrgoainananiagusnatat stam mrs rn : w onansequitaatiarsifassi care thon ti Vsyussnsalsarta g ‘ replat tau dearnitactarnilaccinanadasdnssachuasastdetn 44 fprnsase puns 30077 Synengion dahunra dias ii dain satus fgnitouncan tsar tind ii chi MBPS uae DEG hun cd : baa pil 3.15 udnseamasnraidseinay DPC 0.5 phr iy HBTS 0.5 phr EE ident Seni th Wimiuuiy MBPS 1 phr way DPG 7 phr “—~ MBES 0.5 + ~- MBES 4 ine DPG 1 Modulus cure ting cd gil 3.15 way Synergism e171 NBTS uae DPG92 annginanvactintadncain” mats ppc naudy uBTS ae | Tugildsornuaednsims cure fav MBTS wiaDPG tisvamnsiaor (6) EB ms : WsTIANTAMAAMOL Dogadkin et al AUNATWATMUAAUS AION apes eee eect 7 Pesiereeyeed ansitlidasmaisy 2 a) fo MBTS Way DPG wduiuasganndyArL Ty Mibes 4 “ uaz DPG thin q doa wonaneeld ans wawily DPE umy dasifauiaitly synergion dey tye * ge eee eee ears : iuinitadnto nee diy mar Zaaelilupdeiganvinastoarsiaisa cia 9 (7° oxydiethyl ence phenad uavdnguiisiia N-oxyaicthylenethiocarbany1-N (ons) ay MBP Gyavlwannw 7 fy THTD iy MBT un scorch tine vay OT0S fy NB? avdanaa (8)93 sandasorsiy Gottlob, K, Gumniztg., 30(1916) pp. 303, 326, 33(1918), pe 876 i Bueckeny Jods and Sullivan, 4.B., EBlastomerics, Aug, (1981), pe She Nounton, W.J.Se, editor, “The Applied Science of Rubber", Edward Arnold (Publisher) Ltd., (1961), p. 356,365. Studebaker, M.L. and Beatly, J.R., Science and Technology of Rubber, Eirich, F.R, Editor, Academie Press, (1978), pe 392. MR Technology vol, 12 part 3, (1981), p. 68. Dogadkin, Bete, Fel'dshtein, H.S., and Belyaeva, E,li. J. of Polymer Science, 93, (1961), pe 22522314 Skinner, P.D., and Watson, keA., Rubber Age, 99(11), 1967), Pe 766 Moore, X.C,, Blastomerics, June (1978), p..36.96 dastatsanantatstamsuii Yoguin Vaartsa aedailuvtun undodatiny a ned nsiiuiidl duo ws annie ‘wilasadiiaanin avaeladauddt di agusn Tasty aanunet (antioxidant) win phenylene diamine fran N-Ni tron} sodiphenylanine teivsedvtnmnut ( pavitrosediphenylamine | « “4%, . y. ad dudnsitidhhymatioons sehdvtionstdivottanetsrnet un Besos anvarnsauviaaton insrwaettcfinge pula aouaafios W-Nitros 4 sodtphonyanine foutatdastumns eooreh Tunas sextitnsineyty 4 Gathaawtiari seoren vaaniomnat Ba 8 Nitrosodiphonylanine aati so. nanan dood aundrtuel uganda tw aatitvarsinios gaunt N-Nitrosodipienylamine 1M75 scorch Tal balances ora 4 makidatuainadiions 7 lndavtaunsait set 990. udasnaaaadtasiniaaa Mooney scorch’ BOI cure furinnansdiinitn (2) gaa grads 100 HAP black 50.0 Benaontde, 5.0 asaalagin 3.0 Paraflux 3.0 Pan 145 ated 265 aasdauss 0.5 nana 10 (iI-Nitrosodiphenylamine) 8 ansiuaaits a \ OC sees nf97 ES ETT RE TTT tea. NW |-(eyelohexyl thio)-phthalimide 0 ° : o = 4 ey {asm Rix - a4 gaan Clk & xe domamisar Santogard PVI to’ Monsanto (pvr = Breyuleanization Inhibitor) oraaetit Mooney scorch time i 135" nama R . Ganga iim mooney gain (nity to ranaarnmarga) Wdarsvaa Addaane - 7 126 : jant-c(CHl,) 5 14.0 767 3.2 | aun <> 42.9 15.9 3.0 ay at, 12.0 24.3 903 | “ i ac 16.0 2it.2 8.2 chs cH diester) 16.7 26.8 1004 HN 8H 8 cH cH | 7 | aanmsradananiaetinitadacaun dananvaciburenct aa Twos he a BME wn tet scorch hidmisesny 2-10 wnt thiltuhudlinvosensdae r4e78StS atti aa ee Dee egies Mier ce diamine m0 voldalwYhdoarneniaow Asvasldudrannsd sting HeAlanw vst pvr asluorailaawlwsr scorch shawunaasns cure ami crosslink density idhunnitunn lO gausnvtuguil 4.3 98 (ua cure time asi) dudadtuguin 42 4 4 -2 3 | ee 3 cure time 4 : : - git 2 wastonasormstd PVT cerhftwun ©) 4 node : (1) Ghunsiif sutphenanide (2) Uhrail sutphonamide tay dithiocarbanate (3) viwnaibl surphenanide + dithiocarbamate + PVI anstiin PVT aalusratFou 4 avBaseoe2a1ms scorch ‘IwRheometer units tua x < warenrasaduminiuoutaandumnnaa Pe HB fienava ish 99 vaan (unity A a Pt eee a vit 4.3 navasnarmimiatves PVE ag cure rate aaynsssaNta curve 1 ait BVT curve 2. PVE 0.10 phr curve 3+ PVE 0625 phr ourve 4 PVT 0450 phr curve 5 PVE 1,00 phr aavdy Santogard PVE eatin hadionrntugatninssnhewsro0i so we onylenediamine ynnvxa7d AA pe eag tered ae Sprott onarndltnaiblgnfcdunsed ai finer actos uns Sante it as 4.1.34 Phthalic anhydride 0 4 eS gonnaceit nye °100 Fonanism Esen od Naugatuck Chemicals Retarder PA {109 Honsante Retarder AK 001 Akron Chems Retarder PD 901 Anerican Cyanamid Auth, Bengoic acid oe gone danamisin Retarder BA 04 Akron Chea Retarder BA 0% Monsanto Chemicals + Salicylic acid 4 Gn dooce, LT coo dowansni Retarder TSA 18% Monsanto Chi Retarder W 804 Du Pont Retarder SAX WY Akron Chens nak dunsnciondedtanintaosin 4 fo 0.2005 phe aii gepet2aqweams scorch sviiilaglanitusene ex nsoama tants anni satis nnsownonteenbth7e Tnarane search anwar inner aetthion ails saavtwdins ua: evdatanvtutua parva a asnuuntdén vonsnveflin estas vin 2-6 phr x vii natinsnunitéin bad phr Wt asihcentvian aetna scoreh oy tuuenaratibernn staan phe vin wgastudo sass aeuanmacinitagne a ahi hncennstrunmisesen datdansr| x (ean tumntdvsoaindadusosun ennesbtiosnsionint waelddasdawnanane nna eure wrasrandintiisautaian vansraiisvi slitanddvnstte (shusoauit dracula 4a Sudiuns anvnvontidaounsesin a wate da uuaw ung bit thudranna it tenientidasinas cure