Dr .

Sh a r a d Ko t h a r i P iyu s h Ma h es h w a r i B r ij es h Jin da l
(SK SIR) (PMS SIR) (BJ SIR)

CLASS : XI INORGANIC CHEMISTRY DPP. NO.-6

Q.1 Aqueous solutions of two compounds M1–O–H and M2–O–H are prepared in two different beakers.
If, the electronegativity of M1 = 3.4, M2 = 1.2, O = 3.5 and H = 2.1, then the nature of the two solutions
will be respectively:
(A) acidic, basic (B) acidic, acidic
(C) basic, acidic (D) basic, basic

Q.2 Choose the correct order for the given property.

(A) HOBr > HBrO3 : Acidic strength
(B) Br > Cl : E.A. order
(C) La < Y : Ionisation energy order
(D) NH3 < PH3 : Proton affinity order

Q.3 Consider the following statements in respect of Lanthanoids:

(i) The basic strength of hydroxides of lanthanoids increases from La(OH)3 to Lu(OH)3.
(ii) The lanthanoid ions Lu3+, Yb2+ and Ce4+ are diamagnetic.
Which of the statement(s) given above is / are correct?
(A) (i) only (B) (ii) only
(C) Both (i) and (ii) (D) Neither (i) nor (ii)

Q.4 Select the incorrect option according to the given properties:

(A) Te > O [order of electron affinity]
(B) In < Sr [order of ionisation potential]
(C) LiH < H2 < CH4 [order of electronegativity of hydrogen]
(D) F¯ < Cl¯ [order of ionisation potential]

Q.5 In the compound M–O–H, the M–O bond will be broken if

(A) (E.N) of M & O <  (E.N.) of O & H
(B)  (E.N) of M & O =  (E.N.) of O & H
(C)  (E.N) of M & O >  (E.N.) of O & H
(D) Can not be predicted according  (E.N.) data

Q.6 Which among the following factors is most important in making fluorine, the strongest oxidising agent?
(A) Bond dissociation energy (B) Ionization energy
(C) Hydration enthalpy (D) Electron affinity

Q.7 Which of the following option is correct regarding Li+ and Be2+?
(A) Size of Li+ > Be2+
(B) Hydration energy of Li+ and Be+2 are equal
(C) Li+ and Be2+ having same molar conductivity in aqueous solution
(D) Size of Li+ < Be2+

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Q.8 According to Born-Haber's cycle, the enthalpy of formation of ionic compounds can be determined.
The formation of NaCl involves following steps:
(I) Na(S)  S  Na(g) (II) Na(g)  I  Na+(g) + e–
Energy of sub lim ation Ionisation potential

 D  2Cl (g)

(III) Cl2(g) Bond (IV) Cl(g) + e–   E  Cl– (g)
dissociati on energy Electron  affinity

(V) Cl–(g) + Na+(g)  U  NaCl (S)

Lattice energy
The enthalpyof formation of NaCl will be
D D
(A) Hf = S + I– –E–U (B) Hf = S + I+ –E–U
2 2
E E
(C) Hf = –S – I–D+ +U (D) Hf = –S – I–D – –U
2 2

Q.9 Which of the following statement is not correct:

(A) Ionic mobility of Na+(aq) is greater than Mg2+(aq)
(B) The E.A. of 'O' atom is more than 'Cl' atom
(C) Second I.P. of 'B' atom is greater than that of 'C' atom
(D) I.E. of O¯ is less than that of 'O' atom.

Q.10 Which one of the following arrangements does not truly represent the property indicated against it?
(A) Br2 < Cl2 < F2 : Oxidising power
(B) Br < Cl < F : Electronegativity
(C) Br < F < Cl : Electronaffinity
(D) Br2 < Cl2 < F2 : Bond energy

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