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Thermal and water vapor resistance of the elastic and conventional cotton
fabrics

Article  in  Textile Research Journal · September 2012


DOI: 10.1177/0040517512445337

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Original article
Textile Research Journal
82(14) 1498–1506

Thermal and water vapor resistance ! The Author(s) 2012


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of the elastic and conventional cotton DOI: 10.1177/0040517512445337
trj.sagepub.com
fabrics

Dunja Šajn Gorjanc, Krste Dimitrovski and Mateja Bizjak

Abstract
The research focuses on the influence of elastane (Spandex) incorporation in the weft direction of cotton fabrics, and the
structural properties (fabric density, type of weave) on the thermal and water vapor resistance level.
For that purpose, woven fabrics, in plain and twill weave with two different densities (17 and 20 yarns/cm) in the weft
direction, were made from 100% cotton (conventional) and from a mixture cotton/elastane in the ratio 93.8%/6.2%
(elastic fabric) intended for men’s shirts for the summer season.
Thermal and water vapor resistance were determined with two novel methods, which were compared with the well-
known Permetest method. The thermal resistance was calculated according to the thermal conductivity method which
was established by the faculty research laboratory and with the Permetest, while the water vapor resistance was
measured with the water cup method (developed by Professor D. Jaksic) and with the Permetest.
The research results indicate that cotton fabrics in twill weave with elastane in the weft direction have higher thermal and
water vapor resistance compared to conventional cotton fabrics. The reason lies in the higher yarn density of fabrics
with elastane in the weft direction in twill weave (from 24 to 29–31 yarns/cm in the warp direction) compared to the
plain weave (from 24 to 28 yarns/cm in the warp direction).

Keywords
Thermal resistance, water vapor resistance, elastic fabrics, conventional fabrics

comfort in relation to fiber fineness,2 while others dealt


Introduction
with the thermal comfort properties of knitted fabrics
The garments intended for the summer season (e.g. and thermal properties of knitted fabrics made from
shirts, blouses) are often made from natural fibers cotton and regenerated bamboo cellulosic fibers.3,6–8
(cotton and flax). Cotton and flax garments are Many researches have investigated the moisture trans-
strong, comfortable and cool and they allow the body mission properties of different fabrics.9–12 Moreover,
to breathe. Therefore, they are widely used in the numerous methods for the determination of the heat
manufacture of shirts and blouses for the summer and water vapor transmission have been introduced in
season. the literature.4,13,14
The clothing comfort, especially the sense of cool-
ness, has become very important for the wearer. The
clothing comfort depends mainly on the thermal and
water vapor transfer properties of the fabric.1
In the literature of the last few years, a wide number University of Ljubljana, Faculty of Natural Sciences and Engineering,
of papers dealing with the thermal and water vapor or Slovenia
moisture transmission have been written. Some
Corresponding author:
researches studied the impact of structural variations Dunja Šajn Gorjanc, University of Ljubljana, Faculty of Natural Sciences
in hollow yarn on the heat and water vapor transmis- and Engineering, Snežniška 5, Ljubljana 1000, Slovenia
sion.1 Some authors wrote about thermophysiological Email: dunja.sajn@ntf.uni-lj.si

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Gorjanc et al. 1499

Based upon the abovementioned facts, the influence The negative temperature gradient is a vector with
of incorporation of elastane in the weft direction of direction to the region with lower temperature.
cotton fabrics and the influence of structural properties The law of heat conduction, also known as Fourier’s
(i.e. fabric density, type of weave) on the thermal and law, states that the time of heat transfer, q, through a
water vapor resistance level were analyzed. material is proportional to the negative temperature
For the purpose of this research, woven fabrics in gradient and to the area at right angles, to the gradient
plain and twill weave with two different densities in the through which the heat is flowing, and can be calcu-
weft direction were made from 100% cotton (conven- lated with equation (1).
tional and non-elastic) and from a mixture of cotton/
elastane yarns (elastic fabric) intended for men’s shirts q ¼ gradT ð1Þ
for the summer season.
In the research, two novel methods for the determin- The heat conduction of a fabric presents the transfer
ation of the thermal and water vapor resistance were of the heat from a body to the environment through a
used and compared with the well-known Permetest fabric with the thickness, d, and the cross-sectional
method.13 The first method was the thermal conductiv- area, A, and is calculated with equation (2).
ity method – a comparative method, to calculate the
thermal resistance, whereas the second method was M T
H¼ ¼A ð2Þ
the water cup method14 to calculate the water vapor t d
resistance. The water cup method was developed by
Professor D. Jaksic,14 while the thermal conductivity where Mt is the rate of the heat flow (J/s),  is the
method was established by the faculty research thermal conductivity (W/mK), A is the total cross-sec-
laboratory. tional area of a fabric (m2), T is temperature differ-
The aim of the research was to find out how strong ence (K) and d is the fabric thickness (m).
the correlation between the results of thermal resistance The heat conduction is also expressed as the tem-
obtained with the thermal conductivity method and perature difference and thermal resistance, R, and fol-
with the Permetest is, and the results of the water lows equation (3).
vapor resistance obtained with the water cup
method14 and with the Permetest.13 M T
¼ ð3Þ
t R

Thermal conductivity, , is the property of fabric


Thermal resistance that indicates its ability to conduct heat.
Heat transfer can occur by radiation (R), convection The rate of the heat flow is proportional to the tem-
(C), conduction (K), evaporation (E), and respiration perature difference, T, and the cross-sectional area, A,
(Eres). Heat transfer by radiation occurs constantly while it is inversely proportional with the fabric thick-
between a body and the environment where the body ness, d. The intensity of the heat conduction depends on
dwells, i.e. in both directions, depending on differences the thermal conductivity, , of a material. Higher ther-
in the body skin temperature and the temperature of mal conductivity means higher heat conduction cross
other surfaces. the fabric.5–8
The heat transfer by convection is caused by the air With equations (2) and (3), the thermal resistance, R,
flow around the body or by the movement of liquid is expressed with equation (4).
drops if the body is in the water. Conduction means
the rate of the temperature exchange between two sub- d
R¼ ð4Þ
stances, while evaporation is the changing of liquid 
water into vapor, requiring a large amount of energy.5,6
With the research the heat transfer by conduction The thermal resistance, R, means the resistance of
was evaluated. The quotient between the heat conduc- fabric with the thickness, d, to the thermal conduction,
tion (H), and cross-sectional area (A), presents the , from the region with higher temperature to the
density of the heat conduction (q), which is the vector region with lower temperature, and is expressed in
with the definite direction to the region with lower tem- m2K/W.5–8
perature. The density of the heat conduction, q, is pro-
portional to the quotient, T d , which presents the Water vapor resistance
difference in the temperature regarding the fabric thick-
ness in the heat conduction direction. The quotient T
d is Perspiration is the process of losing body heat due to
the negative temperature gradient –grad T. the moisture evaporation from the skin to the

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1500 Textile Research Journal 82(14)

environment. In this case, the perspiration is trans- The thermal resistance is calculated with the thermal
ported as vapor through the air gaps between the conductivity method (established by the faculty
yarns in the fabric.9 research laboratory) and with the Permetest,13 while
Fabrics present the media between the human body, the water vapor permeability is measured with water
skin and environment. If water vapor permeability is cup method14 and with the Permetest.13
high, the water vapor transport is higher through the The significance of the variations was determined
textile material to the environment. The latter is of with ANOVA using SigmaPlot9 software. The signifi-
extreme importance in a hot environment where a cance of the parameters (the influence of yarn density
cloth must allow the water vapor transfer from the increase in the weft direction from 17 to 20 yarns/cm,
skin into the environment. the elastane incorporation in the weft direction, the
The water vapor transport, called diffusion, runs type of weave – plain or twill) was examined with
from the region of high concentration to the region of p-values. If the p-value of a parameter was higher
low concentration until the concentrations
dm level out.10 than 0.05 (p  0.05), the parameter was not significant
The rate of the transport dt of the diffusing sub- for the observing variable – thermal or water vapor
stance across the area, A, and concentration gradient, resistance.16
c
d, is given with the Fick’s Equation (5). The correlation analysis is used to compare the rela-
tion between the resulting values of the thermal resist-
dm c ance and water vapor resistance obtained with the
¼ DA , ð5Þ
dt d presented methods. The correlation coefficients present
the strength of the association between two variables –
where D is called the diffusion coefficient (m2/s). the results obtained with the two methods. The coeffi-
The Fick’s law describes the water vapor transfer cient of determination (R2), was used to measure the
and could also be presented as equation (6). strength of the linear association between variables.
The value of the coefficient of determination ranges
W between -1 and 1. The positive value of coefficient of
U¼ ð6Þ
tA determination means that the values obtained with two
methods are proportionally linear. If the coefficient of
where U is the water vapor transfer, g/m2h, A is the determination, R2, is +1, this presents the maximum
area of the sample, m2, W is the weight change, g, positive correlation; if it is + 0.8, this means a strong
and t is time, h. positive correlation; and if the correlation coefficient is
The water vapor diffusion resistance is the reciprocal zero, this means zero correlation.16
quantity of water vapor permeability and is also given
with the Ficḱs law.9,10
Thermal conductivity method (comparative method)
c The thermal conductivity method was established by the
Rt ¼ , ð7Þ
m faculty research laboratory and is used in common to
evaluate the thermal conductivity properties. Measuring
where Rt is the total water vapor diffusion resistance, the thermal conductivity is based on the transport of the
g/m, c is the water vapor concentration difference heat flow from a warmer to cooler region, from the
through the fabric, g/m2, m is the rate of diffusion of bottom of the apparatus to the top. The massive frame
the mass of water vapor per unit area through the of the apparatus has the insulating plate with block 1.
sample.10–12 On block 1, the thick copper plate is placed, with the
temperature T ¼ 60  C which has the weight of 706 g.
On that plate, the glass plate with known thermal con-
Methods
ductivity is put, then a thin copper plate (m ¼ 353 g),
The research is focused on thermal and water resistance after that a sample is placed and finally, a cooler
of conventional (100% cotton) and elastic cotton fab- copper plate with T2 ¼ 20 C is added, and a block 2
rics with 6.2% of elastane in the weft direction, which with the weight 2150 g (Figure 1). Between the blocks,
are made on the Picanol OMNI looms with the warp there is a sample with an area of 100 cm2 and a reference
density 24 yarns/cm. The fabrics are lightweight, glass sample with known thermal conductivity, and an
intended for the summer season, in plain and twill area which also amounts to 100 cm2. Both blocks and
weave with different densities in weft direction, 17 three measuring plates are connected with Ni/Cr/Ni
and 20 yarn/cm (Table 1). Thermal and water vapor thermoelements, with diameter 0.5 mm, to the tempera-
resistance are determined with the three different meth- ture measuring instrument, ALMENO 2590. The whole
ods, where two of them present novel methods. system is isolated with thin grains of cork.

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Gorjanc et al. 1501

Table 1. Basic properties of analyzed fabrics

Density, g (yarn/cm) Fineness, Tt (tex)


Fabric Thickness, Type of
mark Composition Warp Weft Warp Weft Mass, M (g/m2) d (mm) weave

1 Cotton – OE yarn 24 17 20.3 20.5 86.8 0.174 plain


2 Cotton – OE yarn 24 20 19.6 20.5 94.0 0.169 plain
3 Cotton/elastane 28 17 19.4 21.6 101.8 0.209 plain
OE yarn/core-spun yarn
4 Cotton/elastane 28 21 19.4 21.6 107.2 0.197 plain
OE yarn/core-spun yarn
5 Cotton – OE yarn 24 17 20.3 21.0 86.0 0.224 twill
6 Cotton – OE yarn 24 20 19.7 20.7 93.0 0.253 twill
7 Cotton/elastane 31 17 19.4 21.7 106.6 0.331 twill
OE yarn/core-spun yarn
8 Cotton/elastane 29 21 19.7 21.6 111.0 0.347 twill
OE yarn/core-spun yarn

the temperature of the middle thin copper plate and


T4 the temperature of the warmer thin copper plate.
With equation (4), the thermal resistance
R (m2K/W) is calculated.

Water vapor diffusion resistance method (water cup


method with PES monofilament fabric)
The water cup method with the PES monofilament
fabric14 is similar to the water vapor diffusion measur-
ing method according to the standard ASTM E96-00.17
The sample with the area A ¼ 50 cm2 is set onto the
round shaped cup, which is covered with the PES
monofilament fabric (Figure 2). The five round cups
Figure 1. The principle of measuring thermal conductivity which are covered with the PES monofilament fabric
(using comparative method). are filled with distilled water with levels, L, of 12 mm,
13.5 mm, 15 mm, 17.5 mm and 20 mm under the cov-
ered PES monofilament. The sample is placed under
The measuring instrument, ALMENO 2590 has four the cover with PES monofilament fabric (Figure 2).
available measuring places to measure temperatures T2, The other five round cups with the PES monofilament
T3 and T4. With equation (8), the thermal conductivity fabric are without the sample, however, with the same
x is calculated. levels of distilled water.
Thermal conductivity is inversely proportional to Before measuring the water vapor permeability, the
the temperature differences between the blocks (equa- weight of a sample is controlled. Afterwards, the
tion (8)). sample with the area A ¼ 50 cm2 is put onto the water
cups with different water levels and after one hour, the
weight of a sample is controlled again (Wo). The mea-
dx ðT4  T3 Þ
x ¼ n   , ð8Þ suring is repeated after 20 hours (W1). The water vapor
dn ðT3  T2 Þ
transfer is calculated using equation (6).
The quantity of water vapor (W-mass) which trans-
where x is the thermal conductivity of a sample, n is fers from the cup in a unit of time (t ¼ 20 h) is irre-
the thermal conductivity of the glass plate versely proportional to the height of the air layer, L (i.e.
(n ¼ 1.0319 W/mK), dx the sample thiskness, dn the the distance from the water level to the PES monofila-
thickness of the reference glass plate (dn ¼ 4 mm), T2 ment fabric; L ¼ 12 mm, 13.5 mm, 15 mm, 17.5 mm and
the temperature of the cooler thick copper plate, T3 20 mm), if the height of the air layer is lower than

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1502 Textile Research Journal 82(14)

Figure 2. The principle of measuring of water vapor permeability with the water cup method.14

Figure 3. Graphical method to determine the water vapor resistance, R (1/U); the values of height of the air layer, L (mm), are set on
the x-axis, while the water vapor resistance values, R (1/U), are figured on the y-axis.

20 mm. The water vapor transfer is expressed as the for the measurements without a sample (section on
height of the air layer. The measurements were taken the y-axis which is marked a0).14
with different heights of the air layer for the results to
The water vapor resistance, R, is calculated from the
be presented in a graph (Figure 3) with the height of the
graph (Figure 3) and is presented as the difference
air layer, L (mm), on the x-axis and the water vapor
between the two heights of the air layer, L, with equa-
resistance, R (1/U), on the y-axis. The obtained graph
tion (12) and is expressed in millimeters (mm).
presents two straight lines with the sections on the
y-axis, i.e. a0 and b0, one straight line shows the results
for the measurements with a sample (section on the 1=U2  1=U1
R ¼ L1  L2 ¼ , ð12Þ
y-axis which is marked b0) and another straight line a1

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Gorjanc et al. 1503

Table 2. Thermal resistance values obtained with the thermal conductivity method – comparative method
and Permetest

Thermal resistance, Rct (m2K/W)

Thermal conductivity method


– comparative method Permetest

Fabric Coefficient of Coefficient of


mark Average variation, CV (%) Average variation, CV (%)

1 0.00251 1.80 0.0086 2.79


2 0.00254 1.34 0.0098 2.30
3 0.00243 1.67 0.0092 1.85
4 0.00277 1.98 0.0099 2.22
5 0.00301 2.01 0.0116 2.50
6 0.00307 2.15 0.0118 2.64
7 0.00305 2.18 0.0132 2.27
8 0.00339 2.23 0.0133 2.88

where L1 is the height of the air layer in the cup without The section of the straight line on the y-axis for the
a sample, L2 is the height of the air layer in the cup with measurements of the water vapor transfer without a
a sample, a1 is the straight line coefficient which is cal- sample, a0, is expressed with the same equation (15).14
culated directly from the experimental straight line.
A more specific method is the analytical method
where the straight line coefficient, a1, is calculated
Results and discussion
with equation (13). Thermal resistance
P P 1  Thermal resistance is calculated from heat permeability
P  Li  (equation (4)), which is measured with two different
L  U1i  N
Ui

methods, i.e. the thermal conductivity method (com-


a1 ¼ P 2 ð13Þ
P Li parative method) and the Permetest.13 The results of
L2i  N the thermal resistance obtained with both methods
are given in Table 2. The correlation between the two
The water vapor resistance, R, which is obtained values of thermal resistance obtained with the thermal
with the analytical method (equation (14)) is the quo- conductivity method – comparative method and the
tient between the difference between the section of the Permetest – is shown in Figure 4.
straight line on the y-axis for the measurements with a An increase in the fabric density and weight
sample (b0) and the section of the straight line on the y- increases the thermal resistance due to the incorpor-
axis for the measurements without a sample (a0), and ation of elastane in the yarn. The incorporation of elas-
the straight line coefficient (a1). All the mentioned par- tane in the yarn (in the weft direction) causes an
ameters (a0, b0 and a1) are calculated with equations increase of the yarn density in the warp direction,
(13) and (15). Both straight lines have the same straight with fabrics 1–4 in plain weave, from 24 to 28 yarns/cm,
line coefficient, a1, which means that they are parallel. while the fabrics 5–8 in twill weave have a higher dens-
ity increase in the warp direction, i.e. from 24 to
b0  a0 29–31 yarns/cm (Table 1).
R¼ ð14Þ According to Table 2, by increasing the density in
a1
the weft direction from 17 yarns/cm to 20 yarns/cm, the
The section of the straight line on the y-axis for the rise in the thermal resistance is very low and is statis-
measurements of the water vapor transfer with a tically insignificant (p ¼ 0.118). The significance of the
sample, b0, is expressed with equation (15). thermal resistance increase level was calculated by com-
paring fabrics 1, 3, 5, 7 with 17 yarns/cm and 2, 4, 6, 8
P P with 20 yarns/cm. Means that the weft density increase
1
Ui  a1  Li by 3 yarns/cm has statistically insignificant influence on
b0 ¼ ð15Þ
N the thermal resistance increase. Based upon the results

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1504 Textile Research Journal 82(14)

Figure 4. Relationship between thermal resistance, Rct, obtained with Permetest and with thermal conductivity
method – comparative method, R2 ¼ 0.8726.

Table 3. Water vapor diffusion resistance values obtained with the warp density increase (Table 1), which increases the
water cup method and Permetest thermal resistance value by more than 20%.
The highest statistically significant increase
Water vapor resistance
(p ¼ 0.00515) of thermal resistance (by about 30–40%)
Water cup Permetest, Ret was calculated with fabrics 5–8 in twill weave, which is
method, R (mm) (m2Pa/W) compact and elastic in comparison with plain weave.
The correlation coefficient between variables (ther-
Coefficient of Coefficient of
mal resistance) evaluated with the thermal conductivity
Fabric variation, variation,
mark Average CV (%) Average CV (%)
method (established by faculty research laboratory)
and the Permetest method is 0.8726, which indicates a
1 2.370 1.18 0.468 2.82 strong positive correlation.
2 2.370 1.43 0.550 1.66
3 2.500 1.56 0.590 2.00
Water vapor diffusion resistance
4 2.700 1.36 0.600 2.27
5 3.220 2.01 0.640 2.09 The results of water vapor diffusion resistance obtained
6 3.330 2.18 0.700 2.38 using the water cup method with PES monofilament
fabric14 are listed in Table 3. Table 3 also presents the
7 3.750 2.23 0.790 2.75
results of water vapor diffusion resistance which were
8 3.770 2.22 0.850 2.15
obtained with the Permetest method.13
The water vapor resistance, R, obtained with the
water cup method15 is presented as the height of the
air layer and is expressed in millimeters (mm).
of thermal resistance, it could be stated that yarn dens- The correlation between the two values of water
ity increase in the weft direction (by 3 yarns) is not high vapor resistance obtained with the water cup method
enough to give a significant thermal resistance increase (developed by Professor D. Jaksic) and Permetest is
of analyzed fabrics, even if the yarn density in the warp demonstrated in Figure 5.
direction increased in that way from 24 to 28 yarns/cm The analysis of the results of water vapor resistance
and fabrics with elastane increased from 24 to 29– of both methods indicates that the water vapor resist-
31 yarns/cm). ance increase, with increasing fabric density and weight,
A statistically significant increase was calculated by is statistically significant (p ¼ 0.0134) (Table 3). The
comparing the values of thermal resistance between latter means that increasing the fabric density in the
fabrics 3, 4, 7, 8, which have incorporated elastane in weft direction from 17 to 20 yarns/cm has a significant
the weft direction and conventional cotton fabrics 1, 2, influence on the water vapor resistance increase
5, 6 (p ¼ 0.0122). The elastane incorporation also causes (by about 30–40%).

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Gorjanc et al. 1505

Figure 5. Relationship between water vapor resistance, Ret, obtained with Permetest and with water cup method, R2 ¼ 0.9025.

As it can be seen from the results, the type of weave vapor resistance level, the following conclusions were
has a statistically significant influence (p ¼ 0.00295) on drawn:
the water vapor resistance increase. The water vapor
resistance increases by about 40% using twill weave, . Thermal and water vapor resistance is the highest
this means that fabrics 5–8 have about 40% higher with fabrics in twill weave, which is more compact
water vapor resistance value than fabrics 1–4 in plain and elastic than plain weave.
weave. . Increasing the density in the weft direction by
Twill weave is more compact and elastic, and conse- 3 yarns/cm (from 17 to 20 yarns/cm) causes an insig-
quently influences the water vapor resistance level nificant increase in the thermal resistance of ana-
(Table 3). lyzed fabrics (comparing fabrics 1, 3, 5, 7 with
The elastane incorporated in the weft direction 17 yarns/cm and 2, 4, 6, 8 with 20 yarns/cm). It
(fabrics 3, 4, 7, 8) causes an increase in the density could be stated that the yarn density increase in
of warp yarns and increases the water vapor resist- the weft direction (by 3 yarns) is not high enough
ance value by approximately 20%. The elastane to influence significantly the increase in the thermal
incorporation in the weft direction significantly resistance of analyzed fabrics.
influences the water vapor resistance increase . In contrast, increasing the fabric density in the
(p ¼ 0.0134). weft direction from 17 to 20 yarns/cm causes a
The values of the water vapor resistance are the significant water vapor resistance increase (from
highest in the case of the twill weave with elastane in 30–40%).
the weft direction (fabrics 7 and 8). The water vapor . The elastane incorporation of cotton fabrics (fabrics
resistance of fabrics 7 and 8 is approximately 40% 3, 4, 7, 8) increases the thermal and water vapor
higher than with other used fabrics. resistance by about 20%.
The correlation coefficient between the variables . The use of twill weave increases the thermal and
(water vapor resistance) obtained with the water cup water vapor resistance by about 30–40%, compared
method and the Permetest method is 0.902, indicating with plain weave.
a strong positive correlation. . Comparing the presented methods, thermal conduct-
ivity method – comparative method and the water
cup method – with the well-known Permetest
method, it becomes clear that a strong positive cor-
Conclusions relation exists among them.
According to the research of the influence of elastane
(Spandex) incorporation in the weft direction of Based upon the conclusions, it is clear that by choos-
cotton fabrics and the structural properties (fabric ing cotton mixtures with elastane (Spandex) in the weft
density, type of weave) on the thermal and water direction for the shirts which are intended for the

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1506 Textile Research Journal 82(14)

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