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SCIENCE (52)

CHEMISTRY
SCIENCE Paper - 2
CLASS X
There will be one paper of two hours duration of 2. Chemical Bonding
80 marks and Internal Assessment of practical work Electrovalent, covalent and co-ordinate
carrying 20 marks. bonding, structures of various compounds,
The paper will be divided into two sections, Electron dot structure.
Section I (40 marks) and Section II (40 marks). (a) Electrovalent bonding:
Section I (compulsory) will contain short answer • Electron dot structure of Electrovalent
questions on the entire syllabus. compounds NaCl, MgCl 2 , CaO.
Section II will contain six questions. Candidates • Characteristic properties of
will be required to answer any four of these six electrovalent compounds – state of
questions. existence, melting and boiling points,
Note: All chemical process/reactions should be conductivity (heat and electricity),
studied with reference to the reactants, products, dissociation in solution and in molten
conditions, observation, the (balanced) equations state to be linked with electrolysis.
and diagrams.
(b) Covalent Bonding:
1. Periodic Properties and variations of • Electron dot structure of covalent
Properties – Physical and Chemical. molecules on the basis of duplet and
octet of electrons (example: hydrogen,
(i) Periodic properties and their variations in chlorine, nitrogen, ammonia, carbon
groups and periods. tetrachloride, methane.
Definitions and trends of the following • Polar Covalent compounds – based on
periodic properties in groups and periods difference in electronegativity:
should be studied: Examples – HCl and H 2 O including
• atomic size structures.
• Characteristic properties of Covalent
• metallic character
compounds – state of existence, melting
• non-metallic character and boiling points, conductivity (heat
• ionisation potential and electricity), ionisation in solution.
• electron affinity Comparison of Electrovalent and
Covalent compounds.
• electronegativity
(c) Coordinate Bonding:
(ii) Periodicity on the basis of atomic number • Definition
for elements.
• The lone pair effect of the oxygen atom
• The study of modern periodic table up to of the water molecule and the nitrogen
period 3 (students to be exposed to the atom of the ammonia molecule to
complete modern periodic table but no explain the formation of H 3 O+ and OH-
questions will be asked on elements ions in water and NH 4 + ion.
beyond period 3 – Argon); The meaning of lone pair; the formation of
hydronium ion and ammonium ion must
• Periodicity and other related be explained with help of electron dot
properties to be explained on the basis diagrams.
of nuclear charge and shells (not
orbitals). 3. Study of Acids, Bases and Salts
(Special reference to the alkali metals and halogen (i) Simple definitions in terms of the molecules
groups). and their characteristic properties.
(ii) Ions present in mineral acids, alkalis and
salts and their solutions; use of litmus and
pH paper to test for acidity and alkalinity.

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• Examples with equation for the (ii) Action of alkalis (NaOH, KOH) on
ionisation/dissociation of ions of acids, certain metals, their oxides and
bases and salts. hydroxides.
• Acids form hydronium ions (only The metals must include aluminium, zinc
positive ions) which turn blue litmus red, and lead, their oxides and hydroxides,
alkalis form hydroxyl ions (only negative which react with caustic alkalis (NaOH,
ions) with water which turns red litmus KOH), showing the amphoteric nature of
blue. these substances.
• Salts are formed by partial or complete 5. Mole Concept and Stoichiometry
replacement of the hydrogen ion of an
acid by a metal. (To be explained with Vapour Density and its relation to relative
suitable examples). molecular mass.
• Molecular mass = 2×vapour density (formal
• Introduction to pH scale to test for proof not required)
acidity, neutrality and alkalinity by using
• Deduction of simple (empirical) and
pH paper or Universal indicator.
molecular formula from:
(iii) Definition of salt; types of salts. (a) the percentage composition of a
Types of salts: normal salts, acid salt, basic compound.
salt, definition and examples. (b) the masses of combining
(iv) Action of dilute acids on salts. elements.
Decomposition of hydrogen carbonates,
6. Electrolysis
carbonates, sulphites and sulphides by
appropriate acids with heating if (i) Electrolytes and non-electrolytes.
necessary. (Relevant laboratory work must Definitions and examples.
be done).
(ii) Substances containing molecules only, ions
only, both molecules and ions.
4. Analytical Chemistry
(i) Action of Ammonium Hydroxide and • Substances containing molecules only
Sodium Hydroxide on solution of salts: ions only, both molecules and ions.
colour of salt and its solution; formation and • Examples; relating their composition
colour of hydroxide precipitated for solutions with their behaviour as strong and weak
of salts of Ca, Fe, Cu, Zn and Pb; special electrolytes as well as non-electrolytes.
action of ammonium hydroxide on solutions
(iii) Definition and explanation of electrolysis,
of copper salt and sodium hydroxide on
electrolyte, electrode, anode, cathode, anion,
ammonium salts.
cation, oxidation and reduction (on the basis
On solution of salts: of loss and gain of electrons).
• Colour of salt and its solution. (iv) An elementary study of the migration of
• Action on addition of Sodium Hydroxide ions, with reference to the factors influencing
to solution of Ca, Fe, Cu, Zn, and Pb selective discharge of ions (reference should
salts drop by drop in excess. Formation be made to the activity series as indicating
and colour of hydroxide precipitated to the tendency of metals,
be highlighted with the help of e.g. Na, Mg, Fe, Cu, to form ions) illustrated
equations. by the electrolysis of:
• Molten lead bromide
• Action on addition of Ammonium
Hydroxide to solution of Ca, Fe, Cu, Zn, • acidified water with platinum electrodes
and Pb salts drop by drop in excess. • Aqueous copper (II) sulphate with copper
Formation and colour of hydroxide electrodes; electron transfer at the
precipitated to be highlighted with the electrodes.
help of equations.
The above electrolytic processes can be
• Special action of Ammonium Hydroxide studied in terms of electrolyte used,
on solutions of copper salts and sodium electrodes used, ionization reaction, anode
hydroxide on ammonium salts. reaction, cathode reaction, use of selective
discharge theory, wherever applicable.

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(v) Applications of electrolysis: heavier than air.
• Electroplating with nickel and silver, • Solubility of hydrogen chloride (fountain
choice of electrolyte for experiment); setting of the apparatus,
electroplating. procedure, observation, inference.
• Electro refining of copper; • Method of preparation of hydrochloric
acid by dissolving the gas in water- the
Reasons and conditions for special arrangement and the mechanism
electroplating; names of the electrolytes by which the back suction is avoided
and the electrodes used should be given. should be learnt.
Equations for the reactions at the
electrodes should be given for • Reaction with ammonia
electroplating, refining of copper. • Acidic properties of its solution -
reaction with metals, their oxides,
7. Metallurgy hydroxides and carbonates to give their
chlorides; decomposition of carbonates,
(i) Occurrence of metals in nature.
hydrogen carbonates, sulphides,
• Mineral and ore - meaning only. sulphites.
• Common ores of aluminium. • Precipitation reactions with silver
nitrate solution and lead nitrate solution.
(ii) Extraction of Aluminium.
B. Ammonia
(a) Chemical method for purifying
bauxite by using NaOH – Baeyer’s Ammonia: its laboratory preparation from
Process. ammonium chloride and collection;
ammonia from nitrides like Mg3 N2 and AlN
(b) Electrolytic extraction – Hall and ammonium salts. Manufacture by
Heroult’s process: Haber’s Process; density and solubility of
Structure of electrolytic cell - the ammonia (fountain experiment); aqueous
various components as part of the solution of ammonia; its reactions with
electrolyte, electrodes and electrode hydrogen chloride and with hot copper (II)
reactions. oxide and chlorine; the burning of ammonia
in oxygen; uses of ammonia.
Description of the changes
occurring, purpose of the substances • Laboratory preparation from
used and the main reactions with ammonium chloride and collection; (the
their equations. preparation to be studied in terms of,
(iii) Alloys – composition and uses setting of the apparatus and diagram,
procedure, observation, collection and
Stainless steel, duralumin, brass, bronze, identification)
fuse metal / solder.
• Ammonia from nitrides like Mg 3 N 2 and
AlN using warm water.
8. Study of Compounds
Ammonia from ammonium salts using
A. Hydrogen Chloride
alkalies.
Hydrogen chloride: preparation of hydrogen
chloride from sodium chloride; refer to the The reactions to be studied in terms of
density and solubility of hydrogen chloride reactants, products, conditions and equations.
(fountain experiment); reaction with • Manufacture by Haber’s Process.
ammonia; acidic properties of its solution.
• Density and solubility of ammonia
• Preparation of hydrogen chloride from (fountain experiment).
sodium chloride; the laboratory method
of preparation can be learnt in terms of • The burning of ammonia in oxygen.
reactants, product, condition, equation, • The catalytic oxidation of ammonia (with
diagram or setting of the apparatus, conditions and reaction)
procedure, observation, precaution, • Its reactions with hydrogen chloride and
collection of the gas and identification. with hot copper (II) oxide and chlorine
• Simple experiment to show the density (both chlorine in excess and ammonia in
of the gas (Hydrogen Chloride) – excess).
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All these reactions may be studied in terms chloride and sodium or potassium
of reactants, products, conditions, equations nitrate.
and observations.
• Aqueous solution of ammonia - reaction 9. Organic Chemistry
with sulphuric acid, nitric acid, (i) Introduction to Organic compounds.
hydrochloric acid and solutions of • Unique nature of Carbon atom – tetra
iron(III) chloride, iron(II) sulphate, lead valency, catenation.
nitrate, zinc nitrate and copper sulphate. • Formation of single, double and triple
• Uses of ammonia - manufacture of bonds, straight chain, branched chain,
fertilizers, explosives, nitric acid, cyclic compounds (only benzene).
refrigerant gas (Chlorofluro carbon – and
its suitable alternatives which are non- (ii) Structure and Isomerism.
ozone depleting), and cleansing agents. • Structure of compounds with single,
double and triple bonds.
C. Nitric Acid
• Structural formulae of hydrocarbons.
Nitric Acid: one laboratory method of Structural formula must be given for:
preparation of nitric acid from potassium alkanes, alkenes, alkynes up to 5 carbon
nitrate or sodium nitrate. Large scale atoms.
preparation. Nitric acid as an oxidizing agent. • Isomerism – structural (chain, position)
• Laboratory preparation of nitric acid (iii) Homologous series – characteristics with
from potassium nitrate or sodium nitrate; examples.
the laboratory method to be studied in Alkane, alkene, alkyne series and their
terms of reactants, products, conditions, gradation in properties and the relationship
equations, setting up of apparatus, with the molecular mass or molecular
diagram, precautions, collection and formula.
identification.
(iv) Simple nomenclature.
• Manufacture of Nitric acid by Ostwald’s
process (Only equations with conditions Simple nomenclature - of the hydrocarbons
where applicable). with simple functional groups – (double
bond, triple bond, alcoholic, aldehydic,
• As an oxidising agent: its reaction with carboxylic group) longest chain rule and
copper, carbon, sulphur. smallest number for functional groups rule
D. Sulphuric Acid – trivial and IUPAC names (compounds
with only one functional group)
Large scale preparation, its behaviour as an (v) Hydrocarbons: alkanes, alkenes, alkynes.
acid when dilute, as an oxidizing agent when
concentrated - oxidation of carbon and • Alkanes - general formula; methane
sulphur; as a dehydrating agent - (greenhouse gas) and ethane - methods
dehydration of sugar and copper (II) of preparation from sodium ethanoate
sulphate crystals; its non-volatile nature. (sodium acetate), sodium propanoate
(sodium propionate), from
• Manufacture by Contact Process iodomethane (methyl iodide) and
Equations with conditions where bromoethane (ethyl bromide).
applicable). Complete combustion of methane and
• Its behaviour as an acid when dilute - ethane, reaction of methane and ethane
reaction with metal, metal oxide, metal with chlorine through substitution.
hydroxide, metal carbonate, metal • Alkenes – (unsaturated hydrocarbons
bicarbonate, metal sulphite, metal with a double bond); ethene as an
sulphide. example. Methods of preparation of
• Concentrated sulphuric acid as an ethene by dehydro halogenation
oxidizing agent - the oxidation of carbon reaction and dehydration reactions.
and sulphur. • Alkynes -(unsaturated hydrocarbons
with a triple bond); ethyne as an
• Concentrated sulphuric acid as a example of alkyne; Methods of
dehydrating agent- (a) the dehydration of preparation from calcium carbide and
sugar (b) Copper (II) sulphate crystals. 1,2 dibromoethane ethylene
• Non-volatile nature of sulphuric acid - dibromide).
reaction with sodium or potassium
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Only main properties, particularly addition Make observations, identify the products and
products with hydrogen and halogen namely make deductions where possible (equations not
Cl 2 , Br 2 and I 2 pertaining to alkenes and required).
alkynes.
2. Make a solution of the unknown substance: add
• Uses of methane, ethane, ethene, ethyne. sodium hydroxide solution or ammonium
hydroxide solution, make observations and
INTERNAL ASSESSMENT OF give your deduction. Warming the mixture may
PRACTICAL WORK be needed. Choose from substances containing
Ca2+, Cu2+, Fe2+, Fe3+, Pb2+, Zn2+, NH 4 +.
Candidates will be asked to observe the effect of
reagents and/or of heat on substances supplied to 3. Supply a solution of a dilute acid and alkali.
them. The exercises will be simple and may include Determine which is acidic and which is basic,
the recognition and identification of certain gases giving two tests for each.
and ions listed below. The examiners will not,
however, be restricted in their choice to substances EVALUATION
containing the listed ions. The assignments/project work are to be evaluated by
Gases: Hydrogen, Oxygen, Carbon dioxide, the subject teacher and by an External Examiner.
Chlorine, Hydrogen chloride, Sulphur dioxide, (The External Examiner may be a teacher nominated
Hydrogen sulphide, Ammonia, Water vapour, by the Head of the school, who could be from the
Nitrogen dioxide. faculty, but not teaching the subject in the
Ions: Calcium, Copper, Iron, Lead, Zinc and section/class. For example, a teacher of Chemistry
Ammonium, Carbonate, Chloride, Nitrate, Sulphide, of Class VIII may be deputed to be an External
Sulphite and Sulphate. Examiner for Class X Chemistry projects.)

Knowledge of a formal scheme of analysis is not The Internal Examiner and the External Examiner
required. Semi-micro techniques are acceptable but will assess the assignments independently.
candidates using such techniques may need to adapt
the instructions given to suit the size of the apparatus Award of marks (20 Marks)
being used.
Subject Teacher (Internal Examiner) 10 marks
Candidates are expected to have completed the External Examiner 10 marks
following minimum practical work: The total marks obtained out of 20 are to be sent
1. Action of heat on the following substances: to the Council by the Head of the school.
(a) Copper carbonate, zinc carbonate The Head of the school will be responsible for the
(b) zinc nitrate, copper nitrate, lead nitrate online entry of marks on the Council’s
CAREERS portal by the due date.

NOTE: According to the recommendation of International Union of Pure and Applied Chemistry
(IUPAC), the groups are numbered from 1 to 18 replacing the older notation of groups IA …. VIIA, VIII,
IB …… VIIB and 0. However, for the examination both notations will be accepted.
Old IA IIA IIIB IVB VB VIB VIIB VIII IB IIB IIIA IVA VA VIA VIIA 0
notation
New 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
notation

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