Unit – I TEST

N.B.: i) All questions are compulsory

ii) Each question carries one mark
iii) Choose the most suitable answers from the given four alternatives 20 x 1 =20

7. Molecular orbital with less energy is a) σ 1s.

b) σ 2s. c) σ 3s. d) σ 4s.

11. Momentum of particle which has de Broglie wavelength of 1A0 is

6.6 x 10 -24 kg ms -1. (Mar-06,11)

12. Bond order of N2 molecule is 3. (June-2006)

13. Nature of hybridisation in IF7 molecules is Sp3 d3.(Oct-2006,10)

14. In a molecule 8 electron present in molecular orbital 4 in anti

bonding orbital bond order is 2. (Mar-2008)

15. Water exists in liquid state. This is due to hydrogen bond.(June08)

16. Energy level of molecular orbitals has been determined experimentally by

Spectroscopic studies. (Oct-2007)
17. Hybridization involved in XeF6 is Sp3d3. (June-07,11)
18. Intermolecular hydrogen bonding is present in HF, H2O and Ethanol.(March
2007)
19. Among the halogen acid the weakest acid is HF.(Model Paper – 2008)
20. The hybridisation in SO4 2- ion is Sp3.

N.B.: i) All questions are compulsory

ii) Each question carries three marks 10*3=30

21. Explain the significance of negative electronic energy

22. Distinguish between particle and wave
23. State Heisenberg’s uncertainty principle
24. Define hybridisation.
25. Why He2 is not formed.
26. What is bond order? And how is it useful in determining the stability of a molecule?
27. What are the conditions for effective Hydrogen bonding ?
28. State Hund’s rule

29.
30. Give any three importance of Hydrogen bonding

N.B.: i) All questions are compulsory

ii) Each question carries five marks 6*5=30

31. Discuss Davisson & Germer’s experiment.

32. Derive de-Broglie wave equation and mention its significance.
33. Give any five postulates of molecular orbital theory.
34. Explain the formation of N2 molecule by MOT.
35. Explain the formation of O2 molecule by molecular orbital theory.

36.
N.B.: i) All questions are compulsory
19. ii) Each question carries ten marks 2*10=20

37. Explain Pauling method to determine ionic radii?

38. Explain the various factors affecting electron affinity.