Arjuna JEE

Board
Chemistry Pattern
Test 02
 SECTION - A

Passage Type Questions (1-2) (2 × 4 = 8)

Read the passage given below and answer the following questions :
1. After the Bohr’s model of atom was put forward postulating that electrons
are revolving around the nucleus in circular orbits, the next studies were
focussed on finding the energies of the electrons revolving in different
orbits, the radii of the different orbits and the velocities with which the
electrons were revolving in different orbits. Bohr himself had given a
formula for calculation of energies of different orbits (called stationary
states or shells). This formula is known as Bohr's formula. Subsequently,
formulae were derived for calculation of radii of different orbits and the
velocities with which the electrons were revolving in these orbits. As total
energy is the sum of potential energy and kinetic energy and knowing that
potential energy of an electron in the nth shell is — Ze2/r, expression for
kinetic energy can be found out.
Question (i)

Why is electronic energy taken as negative? (1)

Question (ii)

Calculate the radius of third orbit of He+ ion. (1)

Question
(iii)
The velocity of electron in the first orbit of hydrogen atom is 2.18 × 106 m s–1.
Then calculate the velocity of electron in third orbit of He + ion.
(1)
Question (iv)

In the Bohr's orbit calculate the ratio of kinetic energy to the total energy of
the electron.
(1)
Read the passage given below and answer the following questions :
2. There are two different approaches that have been put forward to
explain the shapes of molecules. These are Valence Shell Electron Pair
Repulsion (VSEPR) theory and Hybridisation. VSEPR theory is based on
the repulsions among the electron pairs (bond pairs and lone pairs)
present around the central atom so that they take up the directions
where there are no further repulsions between them. Hybridisation is
based on mixing of atomic orbitals of an atom (empty, half-filled or fully-
filled) of comparable energy forming new equivalent orbitals of same
shape and energy, called hybrid orbitals. These hybrid orbitals then
overlap with the orbitals of other atoms. Overlapping may take place
between two half-filled orbitals or one empty and one fully filled orbital.
The direction of overlap gives the direction of bonds formed and hence
the shape of the molecule or ion.
Question (i)

On the basis of VSEPR theory, explain the shape of hydronium (H 3 O + ) ion.

(1)
Question (ii)

On the basis of hybridisation, explain the shape of PCl 5 . Why does it easily
dissociate into PCl3?
(1)
Question
(iii)
H2O involves sp3 hybridisation. Then why bond angle H–O–H is not equal to
109° 28'? Further, why bond angle in H 2 S(H-S-H) is less than that in H 2 O ?

(2)
Objective Type Questions (3–16) (14 × 1 = 14)

Question 3

Law of multiple proportions is illustrated by one of the following pairs

1 H2S and SO2 2 NH3 and NO2

3 Na2S and Na2O 4 N2O and NO

Question 4

A nitic acid solution has a density of 1.41 g mL–1 and mass percent of nitric
acid in it being 69%. The molarity of the solution will be
1 12.8 2 13.2

3 14.4 4 15.4
Question 5

One mole of carbon atoms weigh 12 g. The number of atoms in it is equal to

1 12 × 1023 2 6.022 × 1022

3 12 × 1022 4 6.022 × 1023

Question 6

The number of planar and spherical nodes is 4f-orbital are respectively.

1 4 and 3 2 0 and 3

3 2 and 1 4 3 and 0
Question 7

An element with mass number 81 has 31.7% more neutrons than protons.
The atomic number of the element is
1 35 2 37

3 38 4 39
Question 8

Identify the element for which electronic configuration of +3 oxidation state is

3d5
1 Cr 2 Mn

3 Co 4 Fe
Question 9

The atomic number of the element unnilennium is

1 109 2 119

3 102 4 108
Question 10

In general the property (magnitudes only) that shows an opposite trend in

comparison to other properties across a period is
1 Electron gain enthalpy 2 Electronegativity

3 Ionization enthalpy 4 Atomic radius

Question 11

The shape of ClF3 molecule is

1 triangular 2 pyramidal

3 T-shape 4 Linear
Question 12

Among CH4, CO2, H2O and SO2, the bond angle is the highest in
1 CH4 2 CO2

3 H 2O 4 SO2
Question 12

I, II and III are three isotherms at T1, T2 and T3 respectively as shown below.
Temperature will be in the order

1 T1 = T2 = T3 2 T1 < T2 < T3

3 T1 > T2 > T3 4 T1 > T2 = T3

Question 14

Volume of the air that will be expelled from a vessel of 300 cm 3 when it is
heated from 27°C to 37°C at the same pressure will be
1 310 cm3 2 290 cm3

3 10 cm3 4 37 cm3
Question 15

Which one of the following equation does not correctly represent the first law
of thermodynamics for the given process?
1 isothermal process : q = –w 2 cyclic process: q = – w

3 isochoric process: U = q 4 adiabatic process: U = –w

Question 16

When 1 mol of a gas is heated at constant volume temperature is raised from

298 to 308 K. Heat supplied to the gas is 500 J. Then which statement is
correct?
1 q = w = 500 J, U = 0 2 q = U = 500 J, w = 0

3 q = 500 J, U = w = 0 4 U = 0, q = w = – 500 J
 SECTION - B
Very Short Answer Questions (17–25) (9 × 2 = 18)

Question 17

Calculate the number of atoms in each of the following

(i) 52 moles of He (ii) 52 u of He.
Question 18

State and explain the following

(i) Aufbau’s principle
(ii) Pauli’s exclusion principle.
Question 19

Calculate the uncertainty in the velocity of a wagon of mass 3000 kg whose

position is known to an accuracy of ± 10 pm (Planck’s constant = 6.63 × 10–34J s).
Question 20

(i) Noble gases have positive electron gain enthalpy.

(ii) Cation is smaller in size than its parent atom.
Question 21

Write down the electronic configuration of O2+ ion on the basis of M.O.T. Also
assign its bond order and magnetism
Question 22

Define hybridization. What is the shape of XeF4?

Question 23

Define Boyle’s law. How is it represented mathematically?

Question 24

What are the extensive and intensive properties?

Question 25

Calculate w, q and U when 0.75 mol of an ideal gas expands isothermally and
reversibly at 27°C from a volume of 15 L to 25 L.
 SECTION - C
Short Answer Questions (26–30) (5 × 3 = 15)

Question 26

A compound containing carbon, hydrogen and oxygen gave the following

analytical data:
C = 40.0% and H = 6.67%
Calculate the molecular formula of the compound if its molecular mass is 180.
Question 27

What transition in the hydrogen spectrum would have the same wavelength
as the Balmer transition from n = 4 to n = 2 of He+ spectrum?
Question 28

Define the term ionization enthalpy? How does it vary along a period and
along a group?
Question 29

Account for the following:

(i) Water is a liquid while H2S is a gas.
(ii) NH3 has higher boiling point than PH3.
(ii) Boiling point of HF is lower than that of water.
Question 30

(i) What is kinetic gas equation?

(ii) A sealed tube which can withstand a pressure of 3 atmosphere is filled
with air at 27°C and 760 mm pressure. Find the temperature above
which it will burst.
 SECTION - D
Long Answer Questions (31–33) (3 × 5 = 15)

Question 31

(i) Define the following terms: (2)

(a) Molality
(b) Limiting reactant.
(ii) 30 g of H2 react with 29.0 g of O2 to form H2O
(a) Which is the limiting reactant?
(b) Calculate the maximum amount of H2O that can be formed.
(c) Calculate the amount of the reactant left unreacted. (3)
Question 32

(i) To which block (s, p, d or f) and period, does the element with atomic
number 50 belong? (2)
(ii) Explain the following (3)
(a) Ionization enthalpy of Mg is more than that of Na and Al.
(b) Ionization enthalpy of nitrogen is more than that of oxygen.
(c) Halogens have very high negative electron gain enthalpies. Explain.
Question 33

(i) Why vegetables are cooked with difficulty at a hill station? (1)
(ii) List the important postulates of kinetic theory of gases. (2)
(iii) What will be the pressure exerted by a mixture of 3.2 g of methane and
4.4 g of carbon dioxide contained in a 9 dm3 flask at 27°C? (2)
Thank You