1. Name the inter molecular forces operating in the molecules of:
a) HCl gas b) NaCl and H2O c) Water d) Noble gases 2. i) State Boyle’s Law. ii) Sketch the p vs V graph for a gas at constant temperature. 3. i) Sketch Charles’ Law. ii) Sketch the V vs T graph at various pressures for a gas, illustrating absolute zero. 4. Write the expression for: i) Ideal gas equation. ii) Combined gas law. Explain the symbols involved. 5. i) What is Critical temperature? ii) Critical temperature for Carbon Dioxide and Methane are 31.1 0C and -81.90C respectively. Which one of these has stronger intermolecular forces? 6. Three liquids A, B and C have their vapour pressures 1 bar, 2 bars and 2.5 bars at room temperature. Arrange A, B and C in the increasing order of their boiling points. 7. i) State Dalton’s law of Partial Pressures. ii) What is Partial Pressure? 8. Density of a gas is found to be 5.46gL-1 at 270C. What is its density at STP? 9. A mixture of dihydrogen and Dioxygen at 1 bar pressure contains 20% by weight of dihydrogen. Calculate the partial pressure of dihydrogen. 10. The molar masses of water and ethyl alcohol are 18g mol -1 and 46g mol-1 respectively. Yet the B.P. of water is 373K and that of alcohol is 340K respectively. Give reason. ---------------------------------
Critical Evaluation of Equilibrium Constants Involving 8-Hydroxyquinoline and Its Metal Chelates: Critical Evaluation of Equilibrium Constants in Solution: Part B: Equilibrium Constants of Liquid-Liquid Distribution Systems