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    This document contains 3 chemistry assignments for B.Sc students. The first assignment asks students to discuss crystal field theory in octahedral and tetrahedral fields (5 marks) and define ligands, coordination number, and coordination sphere and explain the difference between double salts and coordination compounds (3 marks). The second assignment asks students to discuss Gabriel phthalimide synthesis of amines and Mannich reaction (5 marks) and distinguish between primary, secondary, and tertiary amines using Hinsberg reagent and nitrous acid (5 marks). The third assignment asks students to derive Nernst's equation (5 marks), write short notes on molar conductivity and concentration cells (5 marks), and describe Kohlrausch's law

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    CHEMISTRY CORE

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    This document contains 3 chemistry assignments for B.Sc students. The first assignment asks students to discuss crystal field theory in octahedral and tetrahedral fields (5 marks) and define ligands, coordination number, and coordination sphere and explain the difference between double salts and coordination compounds (3 marks). The second assignment asks students to discuss Gabriel phthalimide synthesis of amines and Mannich reaction (5 marks) and distinguish between primary, secondary, and tertiary amines using Hinsberg reagent and nitrous acid (5 marks). The third assignment asks students to derive Nernst's equation (5 marks), write short notes on molar conductivity and concentration cells (5 marks), and describe Kohlrausch's law

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    12 views1 page

    Chemistry Core

    Uploaded by

    Laxman
    This document contains 3 chemistry assignments for B.Sc students. The first assignment asks students to discuss crystal field theory in octahedral and tetrahedral fields (5 marks) and define ligands, coordination number, and coordination sphere and explain the difference between double salts and coordination compounds (3 marks). The second assignment asks students to discuss Gabriel phthalimide synthesis of amines and Mannich reaction (5 marks) and distinguish between primary, secondary, and tertiary amines using Hinsberg reagent and nitrous acid (5 marks). The third assignment asks students to derive Nernst's equation (5 marks), write short notes on molar conductivity and concentration cells (5 marks), and describe Kohlrausch's law

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    Core-VIII Semester (IV) B.

    Sc [Chemistry]
    Attempt any two:

    (1) Discuss crystal field theory of coordination compounds in octahedral and tetrahedral crystal
    fields.
    5 Marks
    (2) (i) Define the following terms(a) Ligands (b) Co-ordination no. (c) Co-ordination sphere
    (Ii) What is the difference between double salt and co-ordination compounds?
    (1+1+1) +2 Marks

    (3) (i) What are chelates?


    (ii) Give the IUPAC name of following co-ordination compounds: 3 +(1+1) Marks
    [Co(ONO)(NH3)5] SO4, K3[Al(C2O4)3]

    Core-IX Semester (IV) B.Sc [Chemistry]


    Attempt any two:
    (1) Discuss the followings: (i) Gabriel phthalimide synthesis of Amines (ii) Mannich reaction

    2.5+2.5 Marks
    (2) How you make distinction between 1° ,2° and 3° amines with Hinsberg reagent and nitrous
    acid.
    2.5+2.5 Marks

    (3) Discuss with neat mechanism: (i) Paal-Knorr synthesis of pyrrole (ii) Fischer indole
    synthesis
    2.5+2.5 Marks

    Core-X Semester (IV) B.Sc [Chemistry]


    Attempt any two:
    (1) Derive the Nernst’s equation.
    5 Marks
    (2) Write short notes on the followings:
    (i) Molar conductivity
    (ii) Concentration cells

    2+3 Marks

    (3) Describe the Kohlrausch law of independent migration of ions and its various application.
    5 Marks

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