Biocides of ForeE-7Bio and ForeE-8Bio Grades

Safety Data Sheet registration number: Page 1

TU 2458-014-32110612-2014
32110612.24.38409 of 9
Valid until June 25, 2020

1 Chemical product identification and information on manufacturer and/or supplier

1.1. Chemical product identification
1.1.1. Technical name Biocides of ForeE-7Bio and ForeE-8Bio Grades [1].

1.1.2 Brief recommendations for The product is to be used as the additive to fracturing fluids to
use inhibit growth and development of microorganisms therein [1].
(including restrictions on use)
1.2. Information on manufacturer and supplier
1.2.1. Full legal name Uralplast Limited Liability Company
of organization (Uralplast LLC)
1.2.2. Address (postal and registered) 620024, Ekaterinburg, 1, Bisertskaia Str., lit. 3, office 66

1.2.3. Telephone (including for (343) 270-56-60

emergency consultations and time
limits)
1.2.1 Fax (343) 270-56-60
1.2.5 E-mail info.fh@foresltd.com

2. Hazard(s) identification
2.1 Level of chemical product
hazard as a whole
(hazard classification information in accordance
with the legislation of the Russian Federation
according to GOST 12.1.007 and GHS)
Moderately hazardous products by the degree of health effect;
hazard class according to GOST 12.1.007 – “3” [1,14].
Classification according to GHS:
- oxidizer; class 2;
- skin damage (necrosis)/irritation: class 2;
- severe eye damage/irritation: class 2A;
- acute aquatic toxicity: class 2;
- chronic aquatic toxicity: class 2 [30-33].

2.2 Information on safety marking according to GOST 31340-2013

2.2.1 Hazard symbols
2.2.2 Signal word
2.2.3. Hazard statements
“Flame over circle”
“Exclamation mark”
“Dead fish and tree”
DANGER
Н272: Oxidizer; may increase combustion.
Н315: Causes irritation in case of skin contact.
Н319: Causes express irritation in case of eye contact.
Н411: Toxic to aquatic life with long lasting effects [6].
Emits toxic gas in case of contact with acids.

3. Composition (information on ingredients)

3.1. Information about the products in
general
3.1.1 Chemical name None (mixture) [1].
(according to IUPAC)
3.1.2. Chemical formula None [1].
3.1.3 General characteristics of the The product is a mixture of sorbic, benzoic and
composition dichloroisocyanuric acid salts with
(considering grade assortment; production process dibromonitrilopropionamide [1].
 Biocides of ForeE-7Bio and ForeE-8Bio Grades
Page 2 Safety Data Sheet registration number:
TU 2458-014-32110612-2014
of 9 32110612.24.38409
Valid until June 25, 2020

3.2. Ingredients
(name, CAS and EC numbers, mass fraction (the sum will be 100%), MPC w.z. or SRLI w.z, hazard classes, reference to data
sources)
Table 1 [1,22].
Weight Hazard
Ingredients Working zone CAS EC
fraction, % class
MPC,
mg/m3
Potassium sorbate 25 Not specified None 24634-61-5 246-376-1
Sodium benzoate 25 5(а) 3 532-32-1 208-534-8
Dibromonitrilopropionamid
25 Not specified None 10222-01-2 233-539-7
e
Sodium salt of
25 Not specified None 51580-86-0 None
dichloroisocyanuric acid
Note: a - aerosol

4. First aid measures

4.1. Observed symptoms
4.1.1 Inhalation Weakness, headache, sore throat, coughing,
watery eyes, burning in the eyes and throat [1-5].
4.1.2. Skin contact Symptoms of irritation (dryness, redness, increase in skin
temperature [1-5].
4.1.3. Eye contact Symptoms of irritation: smarting, burning, red sclerosis,
lacrimation [1-5].
4.1.4. Ingestion Nausea, vomiting, abdominal pain [1-5].

4.2. First aid measures to injured

4.2.1 Inhalation Fresh air, rest, warmth [1-5]. Get medical attention if needed.

4.2.2. Skin contact Remove contaminated clothing and immediately wash the
affected area with running water and soap [1-5]. Get medical
attention if needed.
4.2.3. Eye contact Wash wide-opened eyes with plenty of running water during
5-10 minutes [1-5]. Get medical attention.

4.2.4 Ingestion Drink 200-300 ml of milk or water. Get medical attention

immediately [1-5].
4.2.5. Contraindications: Don't cause vomiting! [1-5]

5 Fire and explosion fighting measures and means

5.1. General characteristics of fire and Low-combustible substance [1,9].
explosion hazard
(according to GOST 12.1.044-89)
5.2 Fire and explosion hazard indexes: In general, there is no information available [1]. For sodium
(index classification as per GOST 12.1.044-89
dichloroisocyanurate:
and GOST 30852.0-2002) Flash point, 0C: >225[9].
5.3 Products of combustion and/or Carbon oxides, nitrogen, carbon and bromine oxides, chlorine,
thermal destruction and hazard caused by hydrochloride, hydrobromide, which are toxic gases (symptoms
them of poisoning: dyspnea, asphyxiation, blue
 Biocides of ForeE-7Bio and ForeE-8Bio Grades
TU 2458-014-32110612-2014
5.4. Recommended
extinguishing medium
5.5. Unsuitable extinguishing medium
5.6. Personal Protective Equipment for
firefighters
5.7. Specific features during fire
extinguishing
6. Accidental release measures
6.1 Measures to prevent adverse impact on people, the environment, buildings, structures, etc. in
emergency
6.1.1. Necessary actions of general
nature under emergency response
6.1.2. Personal Protective
Equipment in emergency (PPE for
emergency response crews)
6.2 Accidental release procedure
6.2.1 Actions to eliminate leaks, spills,
scattering
Safety Data Sheet registration number: Page 3
32110612.24.38409 of 9
Valid until June 25, 2020
skin, excitation, disruption of movement coordination, noisy,
bubbling breathing, difficulty breathing, rapid pulse, nausea,
headache, loss of consciousness)
are formed during combustion and thermal destruction [1,3].
Water with wetters [1,9].
Solid water jet [1,9].
Fire retardant clothing complete with self-rescuer SPI-20 [29].
The product contains the oxidizer, which can contribute to the
ignition of combustibles and enhance the combustion [1,9].
Take the vehicle to a safe place.
Isolate the hazardous area within a radius of at least 800 m.
Adjust the specified distance based on the results of chemical
intelligence. Remove unauthorized persons. Enter the
hazardous zone wearing the protective equipment. Follow the
fire safety requirements. Do not smoke. Remove all sources of
fire and sparks. Provide injured people with first aid. Send
people from the affected area for a medical examination [29].
For chemical surveillance and supervisor use Portable
Breathing Device – 3 (during 20 min.) Emergency brigades
should use a Chemical Isolation Kit-5 complete with self-
contained respirator IP-4M. In case of absence of stipulated
models use field-protective suit L-1 or L-2 suits complete with
industrial respirator and KD filter box. Small PFM-1
industrial gas mask, butyl rubber dispersion gloves, special
footwear for protection against oil and petroleum products. At
low concentrations in the air (at the excess of Maximum
Allowable Concentration up to 100 times), it is allowed to use
protective clothing, autonomous protective kit with forced
supply of purified air to the breathing zone with PZU and PZ-
2 filter boxes, RPG filtering gas respirator with KD filter box,
FORT-P filtering respirator, Snezhok-KU-M universal
respirator.
In case of fire - fire retardant clothing complete with self-
rescuer SPI-20 [29].
Report to sanitary and epidemiological inspection bodies.
Do not touch spilled substance.
 Biocides of ForeE-7Bio and ForeE-8Bio Grades
Page 4 Safety Data Sheet registration number:
TU 2458-014-32110612-2014
of 9 32110612.24.38409
Valid until June 25, 2020

(including accidental release measures and
safety precautions ensuring the protection of the
environment)
Barrier the spillages with earth bank. Avoid contact with
petroleum products and other combustible materials.
Collect the spillages and send them for disposal in accordance
with fire safety measures. Insulate the place of the spillage
with sand and rinse it with plenty of water. Treat the area with
30% solution of hydrogen peroxide (hexochlomelamine,
dichloramines). Avoid contact of the substance and flushing
water with petroleum products and other combustible
materials. Rinse the rolling stock surfaces with plenty of water
and detergent compositions [29].

6.2.2. Fire extinguishing procedure Extinguish combustible mixtures with water mist and wetting
agent, foams, powders from the maximum distance.

7. Handling and storage

7.1 Safety measures for safe handling of chemicals
7.1.1. Engineering measures system Production premises must be equipped
with an input and exhaust ventilation system and a local
ventilation systems. The equipment must be sealed. Lighting
should be explosion-proof. Comply with fire safety measures
and equip workplaces with primary fire extinguishing agents.
Use spark-proof equipment during repair works. Use PPE
[1,9,13,17].

7.1.2. Environmental protection Sealing of equipment; treatment of wastewater; measures

measures should be taken to prevent the product from entering the
household, industrial and storm drainage systems, water
bodies, and also soil and vegetation [1].

7.1.3. Recommendations on safe Product may be transported by all means of transport;

carriage and transportation transportation by rail transport should be carried out in
gondola cars, multi-purpose containers. Loading is carried out
using pallets and fastening means [1].
7.2 Conditions for safe chemical product storage
7.2.1. Safe storage conditions and terms The product should be stored in closed undamaged containers, in
covered storage rooms in dry, cool, well-ventilated place, away
(including guaranteed storage life, expiration from sources of ignition at a temperature from 5 °С to 25 °С and
time, incompatibilities) relative air humidity max. 70 %.
Containers with products are to be stored vertically.
Storage of the product together with oxidizers, strong acids,
alkalis, and any other chemical substances forming fire-
hazardous mixtures when in contact with the product is not
allowed.
 Biocides of ForeE-7Bio and ForeE-8Bio Grades
TU 2458-014-32110612-2014
7.2.2 Containers and package
(including materials they are made of)
7.3 Safety precautions and storage
rules in household use
8. Exposure control / personal protection
8.1. Working zone parameters that are
subject to control
(working zone MPC or SRLI)
8.2. Measures to provide the content of
harmful substances within allowable
concentrations
8.3. Personal protective equipment
8.3.1. General recommendations
8.3.2. Respiratory protection
(respiratory protection equipment types)
8.3.3 Protective clothing
(material, type)
8.3.4. Personal protection equipment in
household use
9. Physical and chemical properties
9.1 Physical form
(physical state, colour, odour)
9.2. Parameters that determine basic pro-
perties of the product (temperature points,
pH, solubility, partition n-octanol/water partition
coefficient and other properties of this type of
chemical product)
Safety Data Sheet registration number: Page 5
32110612.24.38409 of 9
Valid until June 25, 2020
Guaranteed storage period is 12 months from the manufacturing
date [1].
Woven polypropylene bags, paper bags [1].
Not intended for household use [1].
In production conditions, control is carried out according to
sodium benzoate: working zone MPC 5 mg/m3 [1, 22].
Ventilation of production premises; air-tight equipment;
systematic monitoring of the air condition in the working
rooms [1,13].
Avoid direct contact with the product, do not inhale
spray; use PPE. Prevent dusting. Preliminary and periodic
medical examinations are required. Strictly follow the rules of
industrial and personal hygiene. Do not smoke or eat in the
working premises. It is necessary to have fire hydrants for a
quick washout of products that have fallen on clothing or
skin. Regular monitoring of content of the aerosol products in
the air of working premises. Persons who have been
instructed, trained and tested their safety knowledge are
allowed to work with the product [1-5,9,11-13,17].
RPG-67, RU-60M or RU-60MU respirators [1,12,13,17,18].
Sealed safety goggles of GR or G1 type, protective shields,
masks or half-mask made of glass or rubber.
Protective clothing made of cotton fabric with vinyl chloride
or silicate casein coating or with removable overlays
[1,12,16,17,19,20].
Not intended for household use [1].
Powder or granules from white to slightly yellowish color
[1].
рН: 5.0 - 8.0 (ForeE-7Bio); 8.0 - 11.0 (ForeE-8Bio)
Tamped Density at 20 0С, g/cm3: 0.7 - 1.4 (ForeE- 7Bio); 0.4
- 0.9 (ForeE-8Bio) [1].

Page 6 Safety Data Sheet registration number:
of 9 32110612.24.38409
Valid until June 25, 2020
10. Stability and reactivity
10.1 Chemical stability:
(specify decomposition products for unstable
products)
10.2. Reactivity
10.3 Conditions to avoid
(including hazardous effects in case of contact with
incompatible substances and materials)
11 Toxicological information
11.1 General description
of impact
(assessment of hazard (toxicity) level of impact
on human health, description of the most
characteristic hazard signs)
11.2. Routes of exposure (inhalation,
ingestion, skin and eyes contact)
11.3. Human organs, tissues and
systems
11.4
beingInformation
affected on exposure to health
hazards in direct contact with products,
and the consequences of these effects
(irritating to the upper respiratory tract, eyes, skin;
skin-resorptive effect and sensitization)
11.5 Information about delayed effects
on human health
(effects on the function of reproduction,
carcinogenicity, mutagenicity, cumulativeness
and other chronic effects)
11.6. Acute toxicity indicators
(DL50 (LD50), exposure route (intragastric, dermal),
animal specimen; CL50 (LK50), exposure time (h),
animal specimen)
12. Information on environment impact
12.1 General characteristics of the
impact on the environment (atmospheric air,
water bodies, soil, including description of
observed exposure signs)
Biocides of ForeE-7Bio and ForeE-8Bio Grades
TU 2458-014-32110612-2014
Stable substance subject to compliance with treatment
conditions [1,30].
Strong oxidizer; interacts with reducing agents,
combustible materials; reacts with acids with the formation
of toxic chlorine gas [1,2].
Storage of the product together with oxidizers, strong
acids, alkalis and any other chemical substances forming
fire-hazardous mixtures when in contact with the product is
not allowed.
Moderately dangerous products. Causes
irritation in case of contact with skin and eyes [1-5].
Contact with skin and eye mucous membranes, inhalation
and ingestion [1-5].
Central nervous system, respiratory organs, kidneys, liver,
skin, eyes [1-5].
Causes severe irritation in case of contact with skin and
mucous membranes of the eyes and respiratory tract. It has
percutaneous (penetrates through intact skin) and sensitizing
(allergic dermatitis in the production conditions) actions [1-
5].
Reprotoxic, mutagenic and carcinogenic effects have not
been detected.
Cumulativity is low [1-5].
In general, there is no information available. Data is
presented by ingredients.
Sodium dichloroisocyanurate: DL50
620-735 mg/kg, intragastric, rats
DL50 1,100 mg/kg, dermal, rats [2].
Dibromonitrilopropionamide: DL50
201 mg/kg, intragastric, rats CL50
310 mg/kg3, 4 h, rats [2].
Products pollute air, water bodies and
soils [1].
Suppression of vegetation cover and changes in the sanitary
condition of water bodies are possible;
 Biocides of ForeE-7Bio and ForeE-8Bio Grades
Safety Data Sheet registration number: Page 7
TU 2458-014-32110612-2014
32110612.24.38409 of 9
Valid until June 25, 2020

high concentrations may result in the death of waterbody

12.2. Environmental exposure routes
inhabitants; changes in the organoleptic properties of water:
appearance of foam, discoloration; causes persistent
contamination of water bodies; presence of foreign smell in the
air [1,23-26].
In case of violation of rules of use, storage and transportation;
in case of unorganized disposal or burial of wastes; as a result
of emergencies [1].

12.3 The most important characteristics of the environmental effects

12.3.1 Hygienic standards
(allowable concentrations in atmospheric air, water including fishery water-objects and soils)
MPC atm. air or SLRI
atm. air, mg/m3 (LNV1,
hazard class)
Sodium
dichloroisocyanurate Safe Reference Level of
Impact - 0.03
Table 2 [23-26]
MPC water2or MPC in fishing3 or SRLI MPC or reference
reference permissible in fishing water, mg/l, permissible
level in water, mg/l, (LNV, hazard class) concentration in
(LNV, hazard class) the soil, mg/kg
(LNV)
0.2, s. and t. , class 2 Not found Not found

1
LNV – limiting nuisance value (tox. – toxicological; s.-t. (san.-tox.) – sanitary-toxicological, org. – organoleptic with specifying the
kind of changes in organoleptic properties of water (odor. – changes water odour, turbid. – increases water turbidity, col. – colour
water, foam – causes foaming, film – creates film on the water surface, flav. – savours water, op. – causes opalescence); refl. –
reflective, res. – resorptive; refl.-res. – reflective-resorptive; com. fish. – commercial fishing (change in saleable qualities of
commercial aquatic organisms); gen. – general sanitary).
2
Water in water bodies used for drinking and in household
3
Water in water bodies with commercial fishing importance (including marine ones)
12.3.2 Environmental toxicity indicators
(CL, EC for fish, Daphnia magna, algae,
etc.)
12.3.3 Migration and transformation in
environment due to biodegradation
and other processes (oxidation,
hydrolysis, etc.)
13. Disposal considerations
13.1 Measures on safe treatment of
waste accumulated at application,
storage and transportation
13.2 Information about locations and
methods of decontamination,
utilization or disposal of waste
including containers (packing)
13.3. Recommendations on disposal of
materials)
wastes formed during household use of
the product
In general, there is no information available. Data is presented
by ingredients.
Sodium dichloroisocyanurate:
Acute toxicity for fish:
CL50 0,22 mg/l, 96 h., Salmo guardneri (steelhead trout)
CL50 0,28 mg/l, 96 h., Lepomis macrochirus (perch) [2].
The product slowly transforms in the environment. Biological
catabolism was not studied [2].
Similar to those used for handling the main products and
described in Sections 7 and 8 hereof.
Products not suitable for use are disposed of in accordance
with SanPiN 2.1.7.1322-03
[10].
Not intended for household use [1].

Page 8 Safety Data Sheet registration number:
of 9 32110612.24.38409
Valid until June 25, 2020
14. Transport information
14.1. UN number
(according to the UN Recommendations on the
Transport of Dangerous Goods)
14.2 Proper shipping and transport
names
14.3 Applicable transportation modes
14.4 Transport hazard class(es)
according to GOST 19433-88:
- class
- sub-class
- classification code
(in accordance with GOST 19433-88 and in
case of railway transportation)
- Number(s) of hazard symbol(s)
14.5 Transport hazard classification
according to UN Recommendations on
the Transport of Dangerous Goods:
- class or sub-class
- additional hazard
- UN packaging group
14.6 Transport labelling
(manipulation signs according to GOST 14192-96)
14.7 Transport emergency cards
(for rail, sea, and other transportation)
15. Information about national and international legislation
15.1. National legislation
15.1.1 Laws of the Russian Federation
15.1.2 Information about documentation
regulating protection of human health
and the environment
15.2. International conventions and
agreements
(whether the product is regulated by the Montreal
Protocol, Stockholm Convention, etc.)
Biocides of ForeE-7Bio and ForeE-8Bio Grades
TU 2458-014-32110612-2014
2465 [1,8].
ACIDS DICHLORIZOCYANURINE SALT
ForeE-Bio Biocides of ForeE-7Bio Grade (ForeE- 8Bio)
[1,8].
The products are transported by all modes of transport in
accordance with the rules for transportation of goods
applicable to this mode of transport [1,27,28].
5 [1,7].
5.1 [1,7].
5112 [1,7,29].
“5” [1,7].
5 [8].
None [8].
II [8].
“Sealed packaging”, “Protect from Sunlight” [1,21].
In case of railway transportation: 501 [29].
“On Protection of the Natural Environment”,
“On the Sanitary and Epidemiological Well-Being of the
Population”, “On the Technical Regulation”
Certificate of Conformance ROSS RU.MM04.Н05655 as of
February 16, 2015; valid until: February 15, 2018
Certificate of Conformance No. TEKSERT RU.01-Н05949
as of April 16, 2015; valid until: April 16, 2018
Certificate for Use No. 153.39.RU.245800.06352.04.15 as
of April 16, 2015
Expert Opinion No. 438g/2015 as of April 15, 2015
[34-36].
The product is not subject to registration in accordance with
the Agreement on Sanitary Measures of the Customs Union
[37].
Not regulated by the Montreal Protocol and the
Stockholm Convention.
 Biocides of ForeE-7Bio and ForeE-8Bio Grades
Safety Data Sheet registration number: Page 9
TU 2458-014-32110612-2014
32110612.24.38409 of 9
Valid until June 25, 2020
16. Additional information
16.1 Information about revision (reissue) of The SDS has been developed for the first time in accordance
the SDS with GOST 30333-2007 [15].
(indicate: “SDS has been developed for the first
time” or “SDS was re-registered upon the
expiration. The pervious SDS No....” or “The
following items have been changed..., date of
changing...”)