SAFETY DATA SHEET

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Trade name or designation
of the mixture
Registration number
Synonyms
LEAD & LEAD ALLOYS
01-2119513221-59-0038
Lead metal, massive, including dilute alloys, non-classified grades, EN 12548:1999

Refined lead: 1 PB9905Axx; 1 PB9905Sxx*

“Blue” lead: 1BLxxx/xx*
Alloys with Cu: 1CUxxx/xx*
Alloys with Sn: 1SNxxx/xx*
Alloys with Te: 1TExxx/xx*
Miscellaneous: BRM001 Crude lead
BRM011 Lead (refined, >99.99%)
BRM014 Lead (Cu alloy family)
BRM015 Lead (Sn & Te alloy family)
BRM051 Softened lead
SDS number BRM001, BRM011, BRM014, BRM015, BRM051
Issue date 29-January-2018
Version number 02
Revision date 27-June-2018
Supersedes date 29-January-2018
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Manufacturing of various parts and products. Registered uses, for this product, can be found in
section 15 of this eSDS.
Uses advised against -
1.3. Details of the supplier of the safety data sheet
Company name Britannia Refined Metals Limited
Address Botany Road
Northfleet
Gravesend
Kent
DA11 9BG - UK
Telephone +44 1474 538200
Email safety.advisor@glencore.uk.com
Contact person Safety Advisor
1.4 Emergency telephone +1 760 476 3961 (Access code: 333085)
number
General in EU 112 (Available 24 hours a day. SDS/Product information may not be available for the
Emergency Service.)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
The substance has been assessed and/or tested for its physical, health and environmental hazards and the following
classification applies.
Classification according to Regulation (EC) No 1272/2008 as amended
Health hazards
Reproductive toxicity Category 1A H360FD - May damage fertility.
May damage the unborn child.
Reproductive toxicity Effects on or via lactation H362 - May cause harm to
breast-fed children.
Specific target organ toxicity - repeated Category 1 (Blood, Central nervous H372 - Causes damage to organs
exposure system, Kidney) (Blood, Central nervous system,
Kidney) through prolonged or
repeated exposure.

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Hazard summary Exposure to powder or dusts may be irritating to eyes, nose and throat. May cause reproductive
effects. Causes damage to organs through prolonged or repeated exposure.
2.2. Label elements
Label according to Regulation (EC) No. 1272/2008 as amended
Contains: Lead
Hazard pictograms

Signal word Danger

Hazard statements
H360FD May damage fertility. May damage the unborn child.
H362 May cause harm to breast-fed children.
H372 Causes damage to organs (Blood, Central nervous system, Kidney) through prolonged or
repeated exposure.
Precautionary statements
Prevention
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe dust/fume.
P263 Avoid contact during pregnancy and while nursing.
P264 Wash thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response
P308 + P313 IF exposed or concerned: Get medical advice/attention.
Storage
P405 Store locked up.
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
Supplemental label information Restricted to professional users.
2.3. Other hazards Not a PBT or vPvB substance or mixture.

SECTION 3: Composition/information on ingredients

3.2. Mixtures
General information
Chemical name % CAS-No. / EC No. REACH Registration No. Index No. Notes
Lead 95 - 100 7439-92-1 01-2119513221-59-0038 082-014-00-7 #
231-100-4
Classification: Repr. 1A;H360D, Repr. 1A;H360F, Lact.;H362, STOT RE 1;H372
Antimony < 0,3 7440-36-0 01-2119475609-24-0011 051-003-00-9
231-146-5
Classification: Acute Tox. 4;H302, Acute Tox. 4;H332, Carc. 2;H351, Aquatic Chronic 2;H411
Cadmium < 0,1 7440-43-9 01-2119489023-40-XXXX 048-002-00-0 M=1000
231-152-8
Classification: Acute Tox. 2;H330, Muta. 2;H341, Carc. 1B;H350, Repr. 2;H361fd, STOT RE 1;H372,
Aquatic Acute 1;H400, Aquatic Chronic 1;H410
Selenium < 0,1 7782-49-2 - 034-001-00-2
231-957-4
Classification: Acute Tox. 3;H301, Acute Tox. 3;H331, STOT RE 2;H373, Aquatic Chronic 4;H413
Copper < 0,1 7440-50-8 - 029-019-01-X
231-159-6
Classification: -
Silver < 0,3 7440-22-4 01-2119555669-21-0033 - #
231-131-3
Classification: -
Tellurium < 0,1 13494-80-9 - -
236-813-4
Classification: -
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 Chemical name % CAS-No. / EC No. REACH Registration No. Index No. Notes
Tin ≤5 7440-31-5 01-2119486474-28-XXXX - #
231-141-8
Classification: -

List of abbreviations and symbols that may be used above

#: This substance has been assigned Union workplace exposure limit(s).
M: M-factor
Composition comments All concentrations are in percent by weight. Occupational Exposure Limits for constituents are
listed in Section 8. The full text for all H-statements is displayed in section 16.

SECTION 4: First aid measures

General information
4.1. Description of first aid measures
Inhalation
Skin contact
Eye contact
Ingestion
4.2. Most important symptoms
and effects, both acute and
delayed
4.3. Indication of any
immediate medical attention
and special treatment needed
IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice
(show the label where possible). Ensure that medical personnel are aware of the material(s)
involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in
attendance.
Move to fresh air. Call a physician if symptoms develop or persist. In case of exposure to fumes or
particulates: Get medical attention immediately.
Contact with dust: Remove and isolate contaminated clothing and shoes. Wash off with soap and
water. Get medical attention if irritation develops and persists. In case of contact with molten
product, cool rapidly with water and seek immediate medical attention. Do not attempt to remove
molten product from skin because skin will tear easily.
Do not rub eyes. Immediately flush eyes with plenty of water for at least 15 minutes. Remove any
contact lenses, if present and easy to do, and open eyes wide apart. Get medical attention if
irritation develops and persists. If molten material contacts the eye, immediately flush with plenty of
water for at least 15 minutes. Get medical attention immediately.
Do not induce vomiting. Rinse mouth thoroughly if dust is ingested. If vomiting occurs, keep head
low so that stomach content doesn't get into the lungs. Get medical attention if symptoms occur.
Dusts may irritate the respiratory tract, skin and eyes. Ingestion of dusts generated during working
operations may cause nausea and vomiting. Prolonged exposure may cause chronic effects. The
principal symptoms of lead poisoning are gastro-intestinal or central nervous system disturbances
and anemia.
Provide general supportive measures and treat symptomatically. Keep victim under observation.
Symptoms may be delayed.

SECTION 5: Firefighting measures

General fire hazards
5.1. Extinguishing media
Suitable extinguishing
media
Unsuitable extinguishing
media
5.2. Special hazards arising
from the substance or mixture
5.3. Advice for firefighters
Special protective
equipment for firefighters
Special fire fighting
procedures
Specific methods
Solid metal is not flammable; however, finely divided metallic dust or powder may form an
explosive mixture with air.
Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Do not use water jet as an extinguisher, as this will spread the fire. Do not use water or
halogenated extinguishing media, where molten material are present. Do not use water on molten
metal: Explosion hazard could result.
During fire, gases hazardous to health may be formed. Metal oxides. Lead fumes.
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Stay upwind. Keep unnecessary personnel away. Move containers from fire area if you can do so
without risk.
Use standard firefighting procedures and consider the hazards of other involved materials.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
For non-emergency Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear
personnel appropriate protective equipment and clothing during clean-up. Do not breathe dust/fume. Ensure
adequate ventilation. Local authorities should be advised if significant spillages cannot be
contained.
For emergency responders Keep unnecessary personnel away. Use personal protection recommended in Section 8 of the
SDS.

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6.2. Environmental precautions
6.3. Methods and material for
containment and cleaning up
Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all
environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into
drains, water courses or onto the ground.
Avoid dispersal of dust in the air (i.e., clearing dust surfaces with compressed air). Collect dust
using a vacuum cleaner equipped with HEPA filter. Prevent product from entering drains. Stop the
flow of material, if this is without risk.

Large Spills: Shovel the material into waste container. Following product recovery, flush area with
water.

Small Spills: Sweep up or vacuum up spillage and collect in suitable container for disposal. Clean
surface thoroughly to remove residual contamination.

Never return spills to original containers for re-use. Put material in suitable, covered, labeled
containers.
6.4. Reference to other For personal protection, see section 8 of the SDS. For waste disposal, see section 13 of the SDS.
sections

SECTION 7: Handling and storage

7.1. Precautions for safe
handling
7.2. Conditions for safe
storage, including any
incompatibilities
7.3. Specific end use(s)
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Follow special provisions related to work with lead and its compounds. Pregnant
or breastfeeding women must not handle this product. Should be handled in closed systems, if
possible. Minimise dust generation and accumulation. Provide appropriate exhaust ventilation at
places where dust is formed. Do not breathe fumes and dusts. Avoid prolonged exposure. Avoid
contact with molten material. Do not use water on molten material. When using, do not eat, drink
or smoke. Wear appropriate personal protective equipment. Wash hands thoroughly after
handling. Avoid release to the environment. Observe good industrial hygiene practices.
Store locked up. Store in original tightly closed container. Store in a well-ventilated place. Store
away from incompatible materials (see section 10 of the SDS).
Ensure that all local regulations regarding handling and storage facilities are followed.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Occupational exposure limits
UK. EH40 Workplace Exposure Limits (WELs)
Components Type Value Form

Antimony (CAS 7440-36-0) TWA 0.5 mg/m3

Cadmium (CAS 7440-43-9) TWA 0.025 mg/m3
Copper (CAS 7440-50-8) STEL 2 mg/m3 Inhalable dusts and mists.
TWA 1 mg/m3 Inhalable dusts and mists.
0.2 mg/m3 Fume.
Lead (CAS 7439-92-1) TWA 0.15 mg/m3
Selenium (CAS 7782-49-2) TWA 0.1 mg/m3
Silver (CAS 7440-22-4) TWA 0.1 mg/m3
Tellurium (CAS 13494-80-9) TWA 0.1 mg/m3
EU. Directive 98/24/EC: on the protection of workers from the risks related to chemical agents at work, Annex I List of
Binding Occupational Exposure Limit Values
Components Type Value
Lead (CAS 7439-92-1) TWA 0.15 mg/m3
EU. Indicative Exposure Limit Values in Directives 91/322/EEC, 2000/39/EC, 2006/15/EC, 2009/161/EU
Components Type Value
Silver (CAS 7440-22-4) TWA 0.1 mg/m3
Tin (CAS 7440-31-5) TWA 2 mg/m3
Biological limit values
EU. Directive 98/24/EC: on the protection of workers from the risks related to chemical agents at work, Annex II Binding
Biological Limit Values and Health Surveillance Measures
Components Value Determinant Specimen
Lead (CAS 7439-92-1) 70 µg/100 ml Lead Blood
Recommended monitoring Follow the schedule for work place measurements when working with lead and its compounds.
procedures

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Derived no effect levels (DNELs)
General Population
Components Value Assessment factor Notes
Antimony (CAS 7440-36-0)
Long-term, Systemic, Dermal 140.8 mg/kg bw/day
Long-term, Systemic, Inhalation 0.1 mg/m3
Long-term, Systemic, Oral 140.8 mg/kg bw/day
Cadmium (CAS 7440-43-9)
Long-term, Systemic, Oral 1 µg/kg bw/day
Silver (CAS 7440-22-4)
Long-term, Systemic, Inhalation 0.04 mg/m3
Long-term, Systemic, Oral 1.2 mg/kg bw/day
Tin (CAS 7440-31-5)
Long-term, Systemic, Dermal 80 mg/kg bw/day
Long-term, Systemic, Inhalation 17 mg/m3
Long-term, Systemic, Oral 5 mg/kg bw/day
Workers
Components Value Assessment factor Notes
Antimony (CAS 7440-36-0)
Long-term, Systemic, Dermal 234.7 mg/kg bw/day
Long-term, Systemic, Inhalation 0.5 mg/m3
Cadmium (CAS 7440-43-9)
Short-term, Systemic, Inhalation 4 µg/m3
Silver (CAS 7440-22-4)
Long-term, Systemic, Inhalation 0.1 mg/m3
Tin (CAS 7440-31-5)
Long-term, Systemic, Dermal 10 mg/kg bw/day
Long-term, Systemic, Inhalation 71 mg/m3
Predicted no effect concentrations (PNECs)
Components Value Assessment factor Notes
Antimony (CAS 7440-36-0)
Freshwater 0.113 mg/l
Marine water 0.011 mg/l
Sediment (freshwater) 11.2 mg/kg
Sediment (marine water) 2.24 mg/kg
Soil 37 mg/kg
STP 2.55 mg/l
Cadmium (CAS 7440-43-9)
Freshwater 0.19 µg/l
Marine water 1.14 µg/l
Secondary poisoning 0.16 mg/kg
Sediment (freshwater) 1.8 mg/kg
Sediment (marine water) 0.64 mg/kg
Soil 0.9 mg/kg
STP 20 µg/l
Lead (CAS 7439-92-1)
Freshwater 3.1 µg/l
Marine water 3.5 µg/l
Secondary poisoning 10.9 mg/kg
Sediment (freshwater) 174 mg/kg
Sediment (marine water) 164 mg/kg
Soil 212 mg/kg
STP 100 µg/l
Silver (CAS 7440-22-4)
Freshwater 0.04 µg/l
Marine water 0.86 µg/l
Sediment (freshwater) 438.13 mg/kg
Sediment (marine water) 438.13 mg/kg
Soil 1.41 mg/kg
STP 0.025 mg/l
8.2. Exposure controls

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Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level. If
engineering measures are not sufficient to maintain concentrations of dust particulates below the
OEL (occupational exposure limit), suitable respiratory protection must be worn. If material is
ground, cut, or used in any operation which may generate dusts, use appropriate local exhaust
ventilation to keep exposures below the recommended exposure limits.
Individual protection measures, such as personal protective equipment
General information Use personal protective equipment as required. Personal protection equipment should be chosen
according to the CEN standards and in discussion with the supplier of the personal protective
equipment.
Eye/face protection Wear dust-resistant safety goggles where there is danger of eye contact. In addition to safety
glasses or goggles, a welding helmet with appropriate shaded shield is required during welding,
burning, or brazing. A face shield is recommended, in addition to safety glasses or goggles, during
sawing, grinding, or machining.
Skin protection
- Hand protection Wear suitable protective gloves to prevent contact, cuts and abrasions. When material is heated,
wear gloves to protect against thermal burns. Suitable gloves can be recommended by the glove
supplier.
- Other Use of an impervious apron is recommended.
Respiratory protection Chemical respirator with organic vapour cartridge, full facepiece, dust and mist filter. In case of
inadequate ventilation or risk of inhalation of dust, use suitable respiratory equipment with particle
filter (type P3). Check with respiratory protective equipment suppliers.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.

Hygiene measures When using, do not eat, drink or smoke. Wash hands after handling. Launder contaminated
clothing before reuse. Private clothes and working clothes should be kept separately. Handle in
accordance with good industrial hygiene and safety practices. Follow up on any medical
surveillance requirements.
Environmental exposure Contain spills and prevent releases and observe national regulations on emissions. Inform
controls appropriate managerial or supervisory personnel of all environmental releases.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Appearance
Physical state Solid.
Form Massive, solid metal.
Colour Grey.
Odour Odourless.
Odour threshold Not applicable.
pH Not applicable.
Melting point/freezing point 326 °C (618.8 °F) ca. 1013 mBar
Initial boiling point and boiling > 600 °C (> 1112 °F) ca. 1013 mBar
range
Flash point Not applicable.
Evaporation rate Not applicable.
Flammability (solid, gas) Non flammable.
Upper/lower flammability or explosive limits
Flammability limit - lower Not applicable.
(%)
Flammability limit - upper Not applicable.
(%)
Vapour pressure Not applicable.
Vapour density Not available.
Relative density 11.45 g/cm3 (23.8 °C)
Solubility(ies) 185 mg/l (20 °C) (water)
Partition coefficient Not applicable.
(n-octanol/water)
Auto-ignition temperature Not applicable.
Decomposition temperature Not applicable.

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Viscosity Not applicable.
Explosive properties Not explosive.
Oxidising properties Not oxidising.
9.2. Other information No relevant additional information available.

SECTION 10: Stability and reactivity

10.1. Reactivity
10.2. Chemical stability
10.3. Possibility of hazardous
reactions
10.4. Conditions to avoid
10.5. Incompatible materials
10.6. Hazardous
decomposition products
The product is stable and non-reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
Hazardous polymerisation does not occur. This product will not undergo hazardous reaction when
used as expected and in recommended environments. Do not use water on molten metal:
Explosion hazard could result.
Contact with incompatible materials. Avoid dust formation.
Acids. Strong oxidising agents.
Thermal decomposition or combustion may liberate toxic gases or fumes. Lead oxide fumes may
be formed at elevated temperatures.

SECTION 11: Toxicological information

General information Occupational exposure to the substance or mixture may cause adverse effects.
Information on likely routes of exposure
Inhalation Elevated temperatures or mechanical action may form dust and fumes which may be irritating to
the eye, mucous membranes and respiratory tract. Dust may irritate respiratory system.
Skin contact May cause irritation through mechanical abrasion. Molten material will produce thermal burns.
Eye contact Dust may irritate the eyes.
Ingestion Not relevant, due to the form of the product. However, ingestion of dusts generated during
working operations may cause nausea and vomiting.
Symptoms Dusts may irritate the respiratory tract, skin and eyes. Ingestion of dusts generated during working
operations may cause nausea and vomiting. Prolonged exposure may cause chronic effects. The
principal symptoms of lead poisoning are gastro-intestinal or central nervous system disturbances
and anemia.
11.1. Information on toxicological effects
Acute toxicity
Components Species Test Results
Silver (CAS 7440-22-4)
Acute
Oral
LD50 Rat > 2000 mg/kg
Tin (CAS 7440-31-5)
Acute
Dermal
LD50 Rat > 2000 mg/kg
Inhalation
LC50 Rat > 4.83 mg/m3
Oral
LD50 Rat > 2000 mg/kg
Skin corrosion/irritation May cause irritation through mechanical abrasion.
Serious eye damage/eye Direct contact with eyes may cause temporary irritation.
irritation
Respiratory sensitisation Based on available data, the classification criteria are not met.
Skin sensitisation Based on available data, the classification criteria are not met.
Germ cell mutagenicity Based on available data, the classification criteria are not met.
Carcinogenicity Based on available data, the classification criteria are not met.
IARC Monographs. Overall Evaluation of Carcinogenicity
Cadmium (CAS 7440-43-9) 1 Carcinogenic to humans.
Lead (CAS 7439-92-1) 2B Possibly carcinogenic to humans.
Selenium (CAS 7782-49-2) 3 Not classifiable as to carcinogenicity to humans.
Reproductive toxicity May cause harm to breastfed babies. May damage fertility or the unborn child.
Specific target organ toxicity - Based on available data, the classification criteria are not met.
single exposure

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Specific target organ toxicity -
repeated exposure
Aspiration hazard
Mixture versus substance
information
Other information
SECTION 12: Ecological information
12.1. Toxicity
Components
Silver (CAS 7440-22-4)
Aquatic
Crustacea
12.2. Persistence and
degradability
12.3. Bioaccumulative potential
Partition coefficient
n-octanol/water (log Kow)
Bioconcentration factor (BCF)
12.4. Mobility in soil
12.5. Results of PBT
and vPvB
assessment
12.6. Other adverse effects
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Residual waste
Contaminated packaging
EU waste code
Disposal methods/information
SECTION 14: Transport information
ADR
14.1. - 14.6.: Not regulated as dangerous goods.
RID
14.1. - 14.6.: Not regulated as dangerous goods.
ADN
14.1. - 14.6.: Not regulated as dangerous goods.
IATA
14.1. - 14.6.: Not regulated as dangerous goods.
IMDG
14.1. - 14.6.: Not regulated as dangerous goods.
14.7. Transport in bulk
according to Annex II of
MARPOL 73/78 and the IBC
Code
LEAD & LEAD ALLOYS
941307 Version #: 02 Revision date: 27-June-2018
Causes damage to organs (Blood, Central nervous system, Kidney) through prolonged or
repeated exposure.
Due to the physical form of the product it is not an aspiration hazard.
The product is a mixture.
Lead is accumulated in the body and may cause damage to the brain and nervous system after
prolonged exposure. Lead may produce maternal toxicity, toxicity to the fetus, and adverse effects
to blood, bone marrow, central/peripheral nervous systems, kidney, liver, and reproductive
system. Prolonged and repeated overexposure to dust and fumes can lead to benign
pneumoconiosis (stannosis).
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Species Test Results
LC50 Daphnia magna 0.0015 mg/l, 24 hours
The product is not expected to be biodegradable.
No data available.
Not applicable.
Not available.
The product is insoluble in water. Lead in massive forms is not mobile in the environment.
Not a PBT or vPvB substance or mixture.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
16 03 03* The Waste code should be assigned in discussion between the user, the producer and
the waste disposal company.
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow
this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches
with chemical or used container. Dispose of contents/container in accordance with
local/regional/national/international regulations.
Not applicable.
SDS UK
Issue date: 29-January-2018 8 / 11
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations
Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I and II, as amended
Not listed.
Regulation (EC) No. 850/2004 On persistent organic pollutants, Annex I as amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 1 as amended
Cadmium (CAS 7440-43-9)
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 2 as amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 3 as amended
Not listed.
Regulation (EU) No. 649/2012 concerning the export and import of dangerous chemicals, Annex V as amended
Not listed.
Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry, as amended
Cadmium (CAS 7440-43-9)
Lead (CAS 7439-92-1)
Regulation (EC) No. 1907/2006, REACH Article 59(10) Candidate List as currently published by ECHA
Cadmium (CAS 7440-43-9) Lead (CAS 7439-92-1)
Authorisations
Regulation (EC) No. 1907/2006, REACH Annex XIV Substances subject to authorisation, as amended
Not listed.
Restrictions on use
Regulation (EC) No. 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as amended
Cadmium (CAS 7440-43-9)
Lead (CAS 7439-92-1)
Directive 2004/37/EC: on the protection of workers from the risks related to exposure to carcinogens and mutagens at
work, as amended.
Cadmium (CAS 7440-43-9)
Other EU regulations
Directive 2012/18/EU on major accident hazards involving dangerous substances, as amended
Cadmium (CAS 7440-43-9)
Selenium (CAS 7782-49-2)
Other regulations This Safety Data Sheet complies with the requirements of Regulation (EC) No 1907/2006, as
amended.
The product is classified and labelled in accordance with Regulation (EC) 1272/2008 (CLP
Regulation) as amended.
National regulations According to Directive 92/85/EEC as amended, pregnant women should not work with the product,
if there is the least risk of exposure.
Young people under 18 years old are not allowed to work with this product according to EU
Directive 94/33/EC on the protection of young people at work, as amended.
Follow national regulation for work with chemical agents in accordance with Directive 98/24/EC, as
amended.
Follow national restrictions on the use of lead.

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15.2. Chemical safety
assessment
SECTION 16: Other information
List of abbreviations
References
Information on evaluation
method leading to the
classification of mixture
Full text of any H-statements
not written out in full under
Sections 2 to 15
Training information
LEAD & LEAD ALLOYS
941307 Version #: 02 Revision date: 27-June-2018
Chemical Safety Assessment has been carried out.
Identified Uses:
Uses by workers in industrial settings
Primary lead production.
Secondary lead production.
Lead battery production.
Lead sheet production.
Use of Lead in production of Hot-Dip Galvanized Steel.
Use of lead metal in the production of a range of lead articles (e.g. cast, rolled and extruded
products, ammunition, lead shot).
Use of lead metal in the production of leaded steels.
Lead powder production.
Use of lead metal in lead oxide production and use of lead oxide in stabiliser production.
Uses by professional workers
Professional use of lead solder.
Professional use of lead ammunition (non miltary).
Professional use of articles with expected dermal contact.
Installation and maintenance of Lead sheet by professional users.
Professional assembly of lead acid batteries.
Professional use of leaded steels.
Professioanl use of inert anodes.
Uses by consumers.
Consumer use of articles with expected dermal exposure.
Consumer use of external lead sheet.
Consumer use of internal lead sheet.
Consumer use of articles with no expected exposure.
Consumer use of sealed batteries.
Consumer use of Solder.
Consumer use of lead ammunition.
Consumer use of lead during the process of reloading spent ammunition rounds.
LC50: Lethal Concentration, 50%.
LD50: Lethal Dose, 50%.
PBT: Persistent, bioaccumulative and toxic.
vPvB: Very Persistent and very Bioaccumulative.
TWA: Time Weighted Average Value.
STEL: Short-Term Exposure Limit.
IARC: International Agency for Research on Cancer.
ECHA registered substances database
The classification for health and environmental hazards is derived by a combination of calculation
methods and test data, if available.
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H330 Fatal if inhaled.
H331 Toxic if inhaled.
H332 Harmful if inhaled.
H341 Suspected of causing genetic defects.
H350 May cause cancer.
H351 Suspected of causing cancer.
H360D May damage the unborn child.
H360F May damage fertility.
H361fd Suspected of damaging fertility. Suspected of damaging the unborn child.
H362 May cause harm to breast-fed children.
H372 Causes damage to organs through prolonged or repeated exposure.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H413 May cause long lasting harmful effects to aquatic life.
Follow training instructions when handling this material.
SDS UK
Issue date: 29-January-2018 10 / 11
Disclaimer This data sheet and the health, safety and environmental information is considered to be accurate
as of the date specified below. We have reviewed any information contained therein which we
received from sources outside Britannia Refined Metals Limited. However, no warranty or
representation, express or implied is made as to the accuracy or completeness of the data and
information contained in this data sheet. Health and safety precautions and environmental advice
noted in this data sheet may not be accurate for all individuals and/or situations. It is the user's
obligation to evaluate and use this product safely and to comply with all applicable laws and
regulations. No statement made in this data sheet shall be construed as a permission,
recommendation or authorization given or implied to practice any patented invention without a
valid licence. Britannia Refined Metals Limited shall not be responsible for any damage or injury
resulting from abnormal use of the material, from any failure to adhere to recommendations, or
from any hazards inherent in the nature of the material.

LEAD & LEAD ALLOYS SDS UK

941307 Version #: 02 Revision date: 27-June-2018 Issue date: 29-January-2018 11 / 11