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The Ins and Outs

of Pipeline
Coatings:

Coatings Used To Protect Oil and Gas Pipelines

C
oating technology in (ARO) designed to protect the main cor-
the oil and gas indus- rosion control coating layer when the
try has come a long pipe is installed via directional drilling—
way. The product evo- as is done for road or river crossings.
lution for protection of Field joint or girth weld coatings offer
steel pipes has migrat- various technologies to optimize perfor-
ed from field-applied asphalt and coal mance with the mainline coating and
tar-based materials to the currently used provide field-application friendliness.
high-tech, field-applied and plant-applied In addition to the above-mentioned
coatings. With most coating plants typi- external coatings, some pipelines are
cally located at or near the steel pipe internally lined with a liquid epoxy or
mill, the economics are good for the FBE system to enhance the flow charac-
pipeline owners to receive coated pipe of teristics of the natural gas or oil travel-
the highest integrity that is designed to ing through the pipeline. Linings are also
last for the full projected life of the asset. used to improve resistance against cor-
The main generic types of pipeline rosion and material build-up in oil and
coatings in use today include coal tar gas production lines.
enamel, polymeric tapes, fusion-bonded To overcome negative buoyancy in
epoxy (FBE), spray-applied liquid coat- offshore applications, wetlands, and
ings, and two- and three-layer polyolefin marshland, the use of concrete weight
coatings. Some coatings are overcoated coatings (CWC) over the corrosion coat-
with an abrasion-resistant overlay ing is required. Onshore barrier coatings
40 JPCL / July 2005 / PCE www.paintsquare.com
By Michael Romano, Tyco Adhesives CPG, with contributions from Matt Dabiri, Williams Companies Inc., and Alan Kehr, 3M

“gasketing effect” that provides protec-


tion from the ingress of water and oxy-
gen, two essential ingredients for corro-
sion (Fig. 1). Spiral and longitudinal weld
areas are typically coated with a strip of
adhesive prior to wrapping to assist with
the step-down from the weld beads to
the main pipe surfaces and to prevent a
bridging effect near the weld area. Cold-
applied tapes have been used since the
1950s and have seen many performance
advances over the years.
Hot-applied tape systems consist of a
fused multi-layer coating system made
up of a thermally activated primer layer,
a thermoplastic elastomer adhesive layer,
Fig. 1: (opposite page and above) Cold-applied tape and coating process and a thermoplastic outer layer. The
Courtesy of Tyco Adhesives Corrosion Protection Group primer is a solvated thermoplastic elas-
tomer that chemically bonds to the adhe-
of cement mortar or bendable concrete Systems typically involve the use of sive layer. This primer contains additives
are used in rocky terrains, where selec- primers designed to meet environmental designed to directly improve the anti-cor-
tive backfill is not used. These coatings regulations for volatile organic com- rosion properties of the system. The
are rare because of cost. pound (VOC) emissions and application adhesive layer is a butyl compound that
It must be noted that degree and level performance requirements. The primer fuses to the outer polyethylene layer. The
of surface preparation as well as dry film wets out the surface of the steel and fills outer layer is typically a high-density
thickness for each corrosion and concrete surface irregularities to assist the adhe- polyethylene (PE). The approach is to
coating application including girth weld sive layer in bonding without the need form an integrated system that bonds to
coatings typically are specified in stan- for applied heat. The adhesive layer is the pipe and resists mechanical damage.
dards, customer specifications, and manu- designed with the primer to maximize The process is one that involves the
facturer recommendations. adhesion to the prepared and clean steel application of heat to achieve the desired
This article gives an overview of the substrate. The primer should be dry performance (Fig. 2). In their current
coatings and linings used to protect oil, before the application of the adhesive form, these systems have been in use
gas, and liquid pipelines. layer so that any residual solvent from since the late 1980s.
the primer has dissipated.
Polymeric Tapes The adhesive layer is typically a blend Heat-Shrinkable Tape Coatings
Cold-applied single or multi-layer tape of butyl rubber and synthetic resins in a Heat shrinkable corrosion prevention
systems have been used primarily in the tape form. The middle and/or outer coatings in tape form have been used
protection of steel and ductile iron pipes layer, which forms a bond with the adhe- since the 1980s for buried and offshore
in the water sector in North America. sive layer, is the mechanical layer and is pipelines operating at temperatures up to
However, these coatings are used in other made of high-density polyethylene or 120 C (250 F). These products consist of
locations around the world for oil and gas polypropylene. The outer layers are resis- a thick, radiation crosslinked polyethyl-
for new or rehabilitation of pipelines. tant to ultraviolet light (UV) for above- ene-based backing coated with a high
These coatings are easy to apply over the ground storage or exposure to sunlight. shear strength, thermoplastic, hot-melt
ditch or with portable plants set up near The total coating system relies on the adhesive.
the pipeline route. use of tension on the tape to provide a When the coating is applied to a pre-
www.paintsquare.com JPCL / July 2005 / PCE 41
Fig. 2: (above and right) Hot-applied tape and coating process
Courtesy of Tyco Adhesives CPG

heated pipe, the thermoplastic adhesive Fusion-Bonded Epoxy (FBE) the epoxy powder. The epoxy powder
melts and flows. The preheated tempera- Fusion-bonded epoxy coatings are 100% melts on contact with the heated steel
ture is critical in ensuring that the adhe- solids, thermosetting materials in pow- pipe, then flows, gels, and cures to form
sive wets out the steel and bonds to its der form that bond to the steel surface as the tough coating required to protect the
surface. The manufacturer’s instructions a result of a heat-generated chemical steel pipe from corrosion (Fig. 4). These
will give the recommended minimum reaction. Formulations consist of epoxy systems became commercially available
temperature. The crosslinked polyethyl- resins, hardeners, pigments, flow control in 1960.
ene backing is heated from the outside additives, and stabilizers to provide ease Dual-layer systems involve the use of
by propane torches and shrinks onto the of application and performance. a second layer of FBE that overcoats the
heated pipe surface so that the adhesive The pipe must be preheated to remove first layer—the corrosion coating. The
bonds to the substrate. moisture, and it must be shot and grit second layer has select characteristics to
Once the product has cooled, the high blasted to attain a clean surface with impart unique properties for special
shear strength adhesive is anchored to proper anchor pattern profile and to applications and service conditions, such
the pipe and can be handled and buried. improve the adhesion properties. It is as mechanical protection for directional
The tape is typically supplied in a two- important to observe the powder manu- drilling. The second layer, or topcoat, is
layer form as rolls of various widths. facturer’s pipe preheat temperature. applied directly after the first layer on
The products are installed by profes- Heating the pipe to be coated is typically the coating line while there is still func-
sional pipe coaters in their factories or done with induction or gas burners to tionality in the primary layer to give a
may be applied nearer the pipeline con- temperatures in the range of 215 to 245 chemical bond at the interface in a con-
struction site using portable coating C (420 to 475 F). tinuous application.
equipment (Fig 3). Electrostatic guns are used to apply Liquid epoxy coatings are also used

Fig. 4: Fusion-bonded Epoxy (FBE) application


Photo courtesy of 3M
Fig. 3: Holiday detection of heat shrink tape coating. Courtesy of Tyco Adhesives CPG

42 JPCL / July 2005 / PCE www.paintsquare.com


Fig. 5: Two-layer polyolefin coating system Fig. 6: Three-layer coating system application
Courtesy of Durabond

over FBE to protect the pipeline against come in various types with butyl-based immediately overcoated with a poly-
abrasion during directional drilling and adhesives or asphalt-based mastics as olefin to the specified thickness.
thrust bore installations. their primary coat and with a side-
extruded or crosshead-extruded poly- Three-Layer Polyolefin Coatings
Two-Layer Polyolefin Coatings olefin layer (Fig. 5). Typically, high-densi- Three-layer polyolefin coatings have
Extrusion of plastic coatings that include ty polyethylene is used as the outer been in use since the 1980s. Multi-layer
an adhesive or sealant to form the inner layer, but polypropylene has also been coating systems consist of an FBE or liq-
layer and provide the bonding and cor- used. uid epoxy primer and copolymer adhe-
rosion protection dates back to the late During application, the adhesive is sive intermediate or tie layer topcoated
1950s when pipelines were first coated heated to obtain the optimal flow char- with a polyolefin.
in the controlled environment of a coat- acteristics to provide a uniform coating Pipelines coated with this system have
ing plant. Two-layer coating systems on the pipe surface. The adhesive is then high electrical resistance. Polyethylene is

Table 1: Types of Field Joint Coatings


Type of Field Joint Coating Description
Hot-Applied Bituminous Tapes Polymer-backed, bituminous-based adhesive tapes. May consist of a bonding primer with a single
or multiple layers of a fusible bituminous tape that is hot applied.
Cold-Applied Polymeric Tapes Polymer-based adhesive tapes, which may consist of a primer with single or multiple layers of a
polymeric tape
Petrolatum Tapes Non-woven synthetic fabric tapes fully impregnated with a natural petrolatum-based compound
Wax Tapes A blend of microcrystalline wax-saturated synthetic fabric in the form of tapes
Heat-Shrinkable Sleeves Cross-linked polyolefin backings coated with a mastic or hot melt type adhesive
Available as there-layer systems with liquid epoxy as the first layer.
Fusion-Bonded Epoxies One-part, heat-curable thermosetting powder epoxy coating
Liquid Epoxies Two-part, ambient temperature-cured, 100% solids (no VOC’s) thermosetting liquid epoxy coatings
with an epoxy resin and a curing agent as the two parts
Liquid Polyurethanes Two-part, 100% solids, liquid coatings with polyisocyanate and polyol as the two components
Flame-Sprayed Polyolefins Multi-layer systems that use a flame-sprayed thermoplastic topcoat over a thermosetting resin,
typically epoxy
Hot-Applied Coal Tar Enamels Consist of primer, coal tar enamel, glass fiber innerwrap, coated glass fiber, or other outerwrap with
comparable performance and optional final wrap of kraft paper

44 JPCL / July 2005 / PCE www.paintsquare.com


typically the topcoat, but polypropylene based on factors such as service temper- Polyurethanes are used in the oil and
is used for higher service temperatures atures, local ground conditions, and gas coating sector as a rehabilitation
and where better mechanical properties ambient conditions. mainline coating or as an abrasion-resis-
are required for handling. The tie layer or CTE is easily repaired with field- tant overlay for directional drills. They
adhesive layer is typically a copolymer or applied coal tar enamel, coal tar epoxy, are applied easily in the field or the
terpolymer adhesive that is grafted and or tape coatings. CTE coatings have plant and are designed to provide excel-
compatible with the outer layer of poly- very good electrical insulating proper- lent performance. Epoxies and
ethylene or polypropylene. ties and low water permeation proper- polyurethanes can be spray-applied,
The FBE layer is applied by electrostatic ties that resist bacterial attack and the although the details of application differ
spray. Induction or gas heating brings the solvent action of petroleum oils. between the two types.
pipe to the required surface temperatures CTE is heated to approximately 240
for the proper application of the powder. C (465 F) and poured over a rotating Field Joint Coatings
The adhesive layer is then applied by side section of pipe surface that has been Many field joint coatings are available
extrusion or spray followed by the poly- prepared and primed in accordance to complete the coating of a pipeline
olefin outer layer (Fig. 6). with the manufacturer’s recommenda- (Table 1). In planning a pipeline coating
tions. A fiber
Coal Tar Enamel and Asphalt Coatings glass inner wrap,
Coal tar coatings have been used for more which becomes
than 80 years and dominated the pipeline saturated with liq-
coatings market for the early years. They uefied enamel, is
were also one of the first pipeline coatings immediately
to be successfully applied in a plant. Coal pulled over the
tar coatings were very popular until the coating. A second
1970s and are still used for corrosion pro- fiber glass or min-
tection onshore as well as under concrete eral felt outer
weight coated (CWC) pipe offshore. wrap, already
Coal tar enamel (CTE) is a polymer- impregnated with
based coating produced from the plasti- coal tar, is applied
Fig. 7: Spray-applied epoxy coatings. Courtesy of Tyco Adhesives CPG
cization of coal tar pitch, coal, and distil- over the first
lates. Inert fillers are added to give the wrap. A second layer of CTE is then system, it is critical to pay attention to
desired properties of the system. The coal applied. Liquid CTE will spread through the field-applied joint protection coat-
tar pitch, which forms the basis for the the wrap. The coating is then finished ing; otherwise, the joint can become the
enamel, consists of poly-nuclear aromatic with one coat of white wash or a single pipeline’s weakest link. Field joint coat-
hydrocarbons and heterocyclic com- wrap of Kraft paper to prevent ultravio- ings are installed under construction
pounds. Over the years, this coating has let (UV) degradation of the enamel dur- conditions anywhere in the world, so
been used in conjunction with a primer, a ing storage in direct sunlight. they must be field friendly to the appli-
fiber glass, or mineral felt reinforcement, cation environment or easy to install
and an outer wrap. The introduction of Spray-Applied Liquid Coatings correctly. Field joint coatings can make
glass fiber inner wraps and the applica- These liquid products are usually two- or break the integrity of the total
tion of outer wraps onto the coating sur- component materials, consisting of an pipeline coating solution (Figs. 8 and 9).
face improved the mechanical strength of “A” and a “B” part. Typical spray- Key considerations for a successful
the system and provided extra protection applied coatings are a high-build epoxy, field joint coating scenario would
against soil stresses and impact damage a polyurethane, or a combination of include project planning, coating selec -
during handling and installation. both. Epoxy coatings are two-part, tion and prequalification, surface
The CTE system is made up of four ambient temperature-cured, 100% preparation, applicator training and
main components: primer, coal tar enamel, solids (no VOCs), thermosetting materi- certification, equipment selection,
glass fiber inner wrap, and glass fiber als with a base resin and curing agent inspection, and storage and handling.
outer wrap. When selecting the enamel (Fig. 7). Polyurethanes are also two-part, Table 2 lists some of the available field
and outer wrap grades, end users must 100% solids coatings but with a polyiso- joint coatings used with various main-
consider the performance requirements, cyanate curing agent and a polyol. line coatings.
www.paintsquare.com JPCL / July 2005 / PCE 45
Fig. 8: Cold tape applied to three-layer mainline coating Fig. 9: Liquid epoxy hand applied onto FBE mainline coating
Courtesy of Tyco Adhesives Courtesy of Tyco Adhesives CPG

Internal Diameter (ID) Coatings cleaning. The main standards governing Internal coatings, besides those men-
Flow efficiency or corrosion coatings the qualification of these coatings are tioned above, have played an important
typically consist of an epoxy liquid that API RP 5L2 and ISO 15741. role in corrosion control and resistance
has a sufficient thickness to coat the The components are pumped to a against scale formation in oil and gas
anchor pattern of the inside of the blast- mixing block on the spray machine, production and paraffin build up in oil
ed steel pipe (Fig. 10). These coatings are where the A and B components are production. Typical systems include
used worldwide for high-pressure gas mixed in the correct ratio. The mixed 100% solids liquid epoxies and FBE. The
transmission pipelines to reduce the material then travels to a single or mul- FBE systems may use a phenolic primer
friction and enhance the gas flow, hence tiple airless spray tip arrangement to be for the adhesion to the metal substrate,
increasing the efficiency of gas delivery applied onto the ID of the pipe. Lance while the FBE topcoat provides the bar-
with less compressor horsepower. This coating is very common and involves a rier against the corrosive environment.
thin coating also provides some degree long boom that travels through the
of corrosion protection, and it helps pipe’s center spraying the liquid epoxy Concrete Weight
accelerate the drying of the pipeline as it travels. Material delivery pressures and Barrier Coatings
after hydrostatic testing, pigging, and can reach 2,000–3,000 psi. Concrete weight coatings (CWC) on
pipes ensure that the pipes laid offshore,
Table 2: Typical Field Joint Solutions versus Mainline Coatings in wetlands and marshland, have a nega-
Mainline Coating Typical Field Joint Coating
tive buoyancy. (Negative buoyancy is a
Fusion Bonded Epoxy (FBE) FBE,
positive downward force created by the
100% solids liquid, epoxy, epoxy-urethane,
weight of the concrete coating to pre-
Heat-shrink sleeves (HSS)
vent the pipe from floating [Fig. 11]).
Cold-and hot-applied tapes
Iron ore in the concrete increases the
Two-Layer Polyethylene (PE) Mastic coated two-layer HSS
density, which lowers the required
Cold-and hot-applied tapes
thickness to provide the negative buoy-
Three-Layer Polethylene Three-layer HSS with epoxy primer and hot melt adhesive
ancy. To prepare the surface for the con-
Multi-layer flame spray with PE
crete weight coating the main corrosion
Three-Layer Polypropylene (PP) Three-layer HSS with epoxy primer and hot melt adhesive
coating surface must be prepared, so
Multi-layer flame spray with PP
that the concrete weight coating is
FBE, Spray-applied adhesive, coextruded PP tape
applied properly.
Polymeric Tapes Cold-and hot-applied tapes
When laying pipe offshore, the
Mastic coated HSS
anchoring of the concrete is very impor-
Coal Tar Enamel/Asphalt Hot applied molten coal tar enamel and asphalt coatings
tant because the longitudinal forces are
Heat shrinkable sleeves with asphalt based mastic adhesive
high when the concrete pipe coating is
held in the tensioner of the lay-barge.
46 JPCL / July 2005 / PCE www.paintsquare.com
yard until the con-
crete has fully cured
(generally 3–7 days,
although cure time
depends on the rela-
tive humidity).
Once out on the
lay-barge the pipe is
welded and field
joint-coated before
the “infill” is applied Fig. 12: Polyurethane infill on the field joint
enters water from laybarge
(Fig. 12). The infill Courtesy of CCSI, A Bayou Company
will build up the
thickness of the field try today. Probably one of the most sig-
Fig. 10: Liquid epoxy used for flow efficiency (inside pipe) joint coating to that nificant is the choice to drill deeper
of the CWC. wells. Pipelines in turn will be operating
This helps avoid slippage of the concrete Polyurethane foam infill is typically used at higher temperatures and pressures
over the corrosion coating. at the joint areas. The foam is poured and this will drive future coating devel-
There are four types of application into a plastic or steel mould that is locat- opments. This will require coatings with
methods for CWC pipe: a wrap (com- ed around the field joint. good hot and wet performance that can
pression), impingement, a combination Onshore concrete or cement mortar- operate at higher temperatures.
of wrap and impingement, and forming. coated pipelines add a degree of mechan- With new pipeline integrity regula-
With the wrap method, the concrete tions recently introduced
mixture is fed onto a belt, and the belt and more anticipated,
wraps and compresses the concrete pipeline coatings will under-
mixture around the pipe. At the same go rigorous inspection, which
time, a steel wire mesh is placed within will lead to the development
the concrete matrix to add reinforce- of even more field friendly
ment to the system. Polyethylene tape is solutions with high perfor-
wrapped around the concrete to hold it mance.
in place and assist in the curing process. To ensure success in devel-
The impingement method involves oping new coating technolo-
spraying concrete at high speed onto the gies, suppliers, applicators,
rotating pipe. contractors, specifiers, and
When the wrap method and the asset owners will have to
Fig. 11: Concrete weight coating plant using the wrap method
impingement method are combined, the Courtesy of The Bayou Companies work together.
first half of the pipe is coated with the
wrap method and is immediately fol- ical protection to the pipeline coating as
lowed by the impingement method for it is being handled during the construc- Based in Houston, TX, Mike
the remainder of the specified thickness. tion process, especially in rocky terrains, Romano is responsible for
The forming method consists of or where selective backfill is too expen- managing Tyco Adhesives’
installing sheet metal forms around the sive. Concrete barrier coatings are avail- North American business,
pipe with reinforcement wires situated able that can be bent in the field. developing global business
within. A spacer holds the wires within Concrete has also been used as an insula- opportunities, and growing
the center space of the form. CWC is tion for casing pipe and for other the company’s relationships with engineering
then poured through the opening at the pipeline-related applications. firms. He has more than 16 years of experi-
top of the form. Once the pipe has been ence with corrosion protection and pipelines.
concrete weight coated, CWC is then Closing Thoughts He can be reached at Tyco Adhesives CPG—
allowed to fully cure. The pipe has limits There are several significant trends fac- tel: 832-526-2696; or email:
on how high it can be stacked in the ing the oil and gas pipeline coating indus- romanom@tycoadhesives.com.
www.paintsquare.com JPCL / July 2005 / PCE . 47

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