Shanghai Baizhi Chemical Co., Ltd.

Chemical

Safety

Data

Sheet

Prepared by: Jiangsu Baizhi Paint Co., Ltd. (Baizhi Chemical

Nantong Production Base)
Date of preparation: December 2018

Chemical Safety Technology Manual

Part One Chemicals and corporate identification

Chemical Chinese name: Baizhi brand high-grade lead-free topcoat
Company Name: Shanghai Baizhi Chemical Co., Ltd.

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P h o n e : 0 2 1 - 6 9 1 3 6 0 1 6 f a x ： 0 2 1 - 6 9 1 3 2 4 9 3
Address: No. 88, Caoan Road, Jiading District, Shanghai
Factory Address: No. 328, Shanghai Road, Binjiang Fine Chemical Park, Qidong City, Jiangsu
Province
 Shanghai Baizhi Chemical Co., Ltd.

Address: No. 88, Lane 3798, Caoan Road, Jiading District, Shanghai
Email address: 188557179@163.com
fax number： 021-69132493 Business emergency phone： 0532-83889090
Technical specification code HD-2018101 effective date： January 01, 2019

Part 2 Composition/Composition Information

1.□Pure ■mixture
2.Chemical name: various colors of high-grade acrylic fatty topcoat
3.Composition information
Main ingredients Content (percentage)

Acrylic aliphatic resin 40～70%

Additives 3～10%
Pigment 5～35%
Solvent 10～15%
4. harmful materials content（%） CASNo
Butyl acetate 5～10 123-86-4
Xylene 0～5 1330-20-7

Part III Overview of Risks

Hazard category: Class 3.2, flammable liquid with high flash point
Entry route: skin contact, eye contact, inhalation, ingestion
Health hazards: It is irritating to the skin. Long-term inhalation of high concentrations can
damage mucous membranes and irritate the respiratory tract. Inhalation of high
concentrations of this product may cause tearing, sore throat, cough, chest tightness, and
shortness of breath. In severe cases, cardiovascular and nervous system symptoms can cause
Conjunctivitis, keratitis, and vacuole formation on the corneal epithelium.
Environmental hazards: a large number of escaping air quality decreases, and a large number
of leaks pollute the air from underground vapor.
Explosion hazard: The mixture of thinner vapor and air reaches the explosion limit and

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P h o n e : 0 2 1 - 6 9 1 3 6 0 1 6 f a x ： 0 2 1 - 6 9 1 3 2 4 9 3
Address: No. 88, Caoan Road, Jiading District, Shanghai
Factory Address: No. 328, Shanghai Road, Binjiang Fine Chemical Park, Qidong City, Jiangsu
Province
 Shanghai Baizhi Chemical Co., Ltd.

explodes in fire.

Part Four First Aid Measures

Skin contact: Rinse with plenty of water or rinse with water, then wash thoroughly with soap
water and then clean
Eye contact: Check and take out the contact lenses, immediately rinse with plenty of water
for at least 5 minutes, and lift the eyelids from time to time to rinse. The severe cases were
sent to hospital.
Inhalation: leave the contaminated area, pay attention to the patient to keep warm and rest.
Ingestion: rinse mouth immediately and rush to hospital

Part 5 Fire Fighting Measures

Hazardous characteristics: Its vapor and air form an explosive mixture, which can cause
combustion and explosion when exposed to fire or high heat, and can react
strongly with oxidants. Its vapor is heavier than air, and can spread to a
relatively far place at a lower level, causing backfire when it encounters a fire
source. If the internal pressure of the container increases due to high heat, there
is a risk of cracking and explosion. Too fast flow rate will cause static electricity
and static electricity accumulation.
Hazardous combustion products: CO, CO2
Fire extinguishing methods and extinguishing agents: foam, carbon dioxide, dry powder,
sand can be used to extinguish
Precautions for fire fighting: fire with water is invalid

Part VI Emergency Response to Leakage

Emergency treatment: cut off the fire source, isolate the fire source, organize firefighting, cut
off the source of the accident as much as possible, prevent it from flowing into
the sewers and ditches, collect spilled liquid or sand and bury as much as
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P h o n e : 0 2 1 - 6 9 1 3 6 0 1 6 f a x ： 0 2 1 - 6 9 1 3 2 4 9 3
Address: No. 88, Caoan Road, Jiading District, Shanghai
Factory Address: No. 328, Shanghai Road, Binjiang Fine Chemical Park, Qidong City, Jiangsu
Province
 Shanghai Baizhi Chemical Co., Ltd.

possible, and organize the containment in time

Fire-fighting method: Use a putty knife or other tools to enclose sandy soil with thinner, and
bury it in an open place upside down

Part VII Handling and storage

Operation precautions: Strengthen the ventilation of the operation site. The operator can
operate with the principle of understanding. Keep away from fire and heat
sources. Smoking is prohibited. Pay attention to cover the equipment
during storage to prevent a large amount of steam from overflowing and
prevent damage. It is recommended that the operator wear a gas mask and
equip enough on site. Fire-fighting equipment and emergency treatment
equipment, possible residues in empty containers
Precautions for storage: Store in a cool and ventilated warehouse, away from fire and heat
sources, sorted and stacked in batches, first in, first out, and lightning
protection in the storage area

Part VIII Exposure Control/Personal Protection

Maximum allowable concentration: ≤45%
Monitoring method: GB11183 no relevant information 86
Engineering control: Fix the amount of xylene and butyl acetate when designing the paint
formula, and determine the solid content of each batch of products according to
the product standard
Respiratory protection: wear a gas mask during operation
Body protection: wear cotton work clothes
Hand protection: wear protective gloves
Other protection: wear protective shoes and socks

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P h o n e : 0 2 1 - 6 9 1 3 6 0 1 6 f a x ： 0 2 1 - 6 9 1 3 2 4 9 3
Address: No. 88, Caoan Road, Jiading District, Shanghai
Factory Address: No. 328, Shanghai Road, Binjiang Fine Chemical Park, Qidong City, Jiangsu
Province
 Shanghai Baizhi Chemical Co., Ltd.

Part 9 Physical and Chemical Properties

1. Appearance: viscous liquid
2. Odor: Slightly scent of butyl acetate
3. Melting point: no relevant information
4. Boiling point: no relevant information
5. Relative density (water = 1): 0.9364
6. Relative vapor density (air=1): no relevant information
7. Flash point (closed cup): 8℃
8. Ignition point: 13℃
9. Upper explosion limit: no relevant information
10. Lower explosion limit: no relevant information
11 Solubility: The paint is soluble in solvents such as esters, ketones, ether esters, etc., and is
limited to petroleum solvents.
12. Main purpose: mainly used for industrial spraying.

Part 10 Stability and Reactivity

Stability: chemically react with moisture in the air
Incompatible materials: strong oxidizer
Conditions to avoid: open flame, high heat, water
Polymerization hazard: does not occur
Decomposition products: carbon monoxide, carbon dioxide

Part 11 Toxicological Information

1. The toxicity data of xylene in the ingredients are:
(1) Acute toxicity:
1) LD50: 5000mg/kg (oral for rats); 4940mg/kg (oral for rabbits)
2) LC 50: 19747mg/m3

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P h o n e : 0 2 1 - 6 9 1 3 6 0 1 6 f a x ： 0 2 1 - 6 9 1 3 2 4 9 3
Address: No. 88, Caoan Road, Jiading District, Shanghai
Factory Address: No. 328, Shanghai Road, Binjiang Fine Chemical Park, Qidong City, Jiangsu
Province
 Shanghai Baizhi Chemical Co., Ltd.

(2) 8 hours (rat inhalation) subacute and chronic toxicity;

(3) Irritation: 400ppm for human eyes
2. The toxicity data of butyl acetate in the ingredients are:
(1) Acute toxicity:
1) LD50: 13100mg/kg (oral for rats); 3200mg/kg (oral for rabbits)
2) LC 50: 9480mg/m3
(2) 8 hours (rat inhalation) subacute and chronic toxicity;
(3) Irritation: 300ppm for human eyes

Part XII Ecological Information

Ecotoxicity: (No relevant information)
Biodegradability: (No relevant information)
Non-biodegradability: (no relevant information)
Bioaccumulation or bioaccumulation: (No relevant information)
Other harmful effects: the substance may be harmful to the environment, special attention
should be paid to the water body.

13. Disposal
Discarded substances: ■Hazardous Waste □Industrial solid waste
Waste disposal method: use controlled incineration
Disposal precautions: In normal operation, waste cloth heads and other concentrated iron
buckets with lids are collected for centralized disposal

14. Product transportation information

Dangerous goods code: 3.2 category (GB33646)
UN Number: 1866
Packaging mark: Ⅲ
Packing method: metal drum, can

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P h o n e : 0 2 1 - 6 9 1 3 6 0 1 6 f a x ： 0 2 1 - 6 9 1 3 2 4 9 3
Address: No. 88, Caoan Road, Jiading District, Shanghai
Factory Address: No. 328, Shanghai Road, Binjiang Fine Chemical Park, Qidong City, Jiangsu
Province
 Shanghai Baizhi Chemical Co., Ltd.

Precautions for product transportation: prevent rain, sun exposure, and avoid collisions

15. Regulatory information

Regulatory Information:
1. "Regulations on the Safety Management of Hazardous Chemicals" (Order No. 344 of the
State Council)
2. "Classification and Marking of Commonly Used Hazardous Chemicals" (GB13690-1992),
which is classified as a flammable liquid with a flash point in Class 3.2.
3. "Compilation of Regulations and Standards for Safety Supervision of Hazardous
Chemicals"-compilation of commonly used laws, regulations and standards for coating
companies, edited by Zhejiang Paint Industry Association,
4. "Safety Management of Hazardous Chemicals", edited by Guangdong Provincial
Administration of Work Safety.

Part Sixteen Other Information

references:
1. "Handbook of Commonly Used Chemical Dangerous Goods"
2. "Hygienic and Safety Practical Manual of Toxic Chemicals"
3. "Complete Book on Toxicity of Chemical Substances"
4. "Encyclopedia of Chemical Industry", published by Chemical Industry Press
Time to fill out the form: December 2019
Filling department: Safety Management Section of Jiangsu Baizhi Paint Co., Ltd.
Data review unit: Office of Shanghai Baizhi Chemical Co., Ltd.
Modification instructions: Complete this safety technical manual in accordance with
GB16483-2000.
other information:
The information provided in this document is not a product indicator: it does not
guarantee specific properties. The information contained in the guarantee is based on the

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P h o n e : 0 2 1 - 6 9 1 3 6 0 1 6 f a x ： 0 2 1 - 6 9 1 3 2 4 9 3
Address: No. 88, Caoan Road, Jiading District, Shanghai
Factory Address: No. 328, Shanghai Road, Binjiang Fine Chemical Park, Qidong City, Jiangsu
Province
 Shanghai Baizhi Chemical Co., Ltd.

general guidance for health and safety provided by our knowledge in the operation, storage
and use of the product. It does not apply to the special or non-standard use of this product
and not in accordance with the instructions and recommendations.

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P h o n e : 0 2 1 - 6 9 1 3 6 0 1 6 f a x ： 0 2 1 - 6 9 1 3 2 4 9 3
Address: No. 88, Caoan Road, Jiading District, Shanghai
Factory Address: No. 328, Shanghai Road, Binjiang Fine Chemical Park, Qidong City, Jiangsu
Province