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Objectives 3.1 Linkage isomerism

Introduction In linkage isomers some atoms (in the same molecular formula) have different neighbors.

Examples:
1. Fundamentals

1.1 Concepts and definitions

1.2 Nomenclature of
complexes
Chemical formula of
complexes
1.3 Chemical Bonding of
complexes

2. Classification of ligands

2.1 Types of ligands

Denticity of Ligands
Chelatling ligands
Bridging ligands
Ambidentate ligands
2.2 List of ligands
Example of
monodentate ligands
Example of bidentate
ligands
Example of tridentate
ligands
Example of
quadridentate ligands
Example of hexadentate
ligands

3. Isomerism

3.1 Structural isomerism

3.2 Stereoisomerism
Geometrical isomerism
Optical isomerism

4. The formation of metal

complexes

4.1 General aspects

4.2 Stepwise complex
formation
4.3 Metal complexe
equilibria in solution
4.4 Properties of metal
complexes
4.5 The stability of metal
complexes
Thermodynamics
Kinetics
The chelate effect
The macrocycle effect
Complexometric
4.6 Titration
Reactions competing
with the formation of
complexes
Competition between
H3O+ and Mn+
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Competition between L JUN JUL JAN
http://chimge.unil.ch/En/complexes/1cpx13a.htm
and OH - [CoIII(NH3)5Br]SO4 Go III(NH ) SO ]Br
[Co 35 4
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7 captures 04 f 🐦
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5. Hard and soft cations and
ligands

5.1 Characterization of
cations
5.2 Characterization of
ligands

6. Dissolving slightly soluble

salts

6.1 The solubility product

6.2 Concentration of ions in
equilibrium with the solid
salt
6.3 Precipitation
6.4 Dissolution of slightly
soluble salts

7. Standart redox potential of

metal complexes

8. Biochemische bedeutung

8.1 Porphyrines
Hem
Chlorophyll
Corrin
8.2 Catalysis
Zinc containing
enzymes
Substances containing
8.3 Mg2+ and Ca2+.
8.4 Decontamination
Chemotherapy
 http://chimge.unil.ch/En/complexes/1cpx13a.htm Go JUN JUL JAN 👤 ⍰❎
In the two complexes Br- and SO42- are bound differently. 04
7 captures f 🐦
4 Jul 2004 - 7 Oct 2009 2003 2004 2005 ▾ About this capture
The above isomerism may also be called ionization isomerism.

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