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Objectives 2.2.2 Examples of bidentate ligands

Introduction
forming a four- carboxylate
membered chelate
1. Fundamentals ring

1.1 Concepts and definitions

1.2 Nomenclature of
complexes
carbonate
Chemical formula of
complexes
1.3 Chemical Bonding of
complexes

2. Classification of ligands sulfate

2.1 Types of ligands
Denticity of Ligands
Chelatling ligands
Bridging ligands
Ambidentate ligands
2.2 List of ligands
Example of
monodentate ligands forming a five- glycinate
Example of bidentate
ligands
membered chelate
Example of tridentate ring
ligands
Example of
quadridentate ligands
Example of hexadentate
ligands oxalate

3. Isomerism

3.1 Structural isomerism

3.2 Stereoisomerism
Geometrical isomerism
Optical isomerism ethylenediamine
(“en”)
4. The formation of metal 1,10-
complexes
phnanthroline
4.1 General aspects oder
4.2 Stepwise complex
formation o-phen oder phen
4.3 Metal complexe
equilibria in solution
4.4 Properties of metal
2,2’bipyridyl oder
complexes bipy oder bpy
4.5 The stability of metal
complexes
Thermodynamics
Kinetics forming a six- acetylacetonate
The chelate effect membered chelate
The macrocycle effect
Complexometric ring
4.6 Titration
Reactions competing
with the formation of
complexes
Competition between
H3O+ and Mn+
 Competition between L
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9 captures 04 f 🐦
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5. Hard and soft cations and
ligands
© Copyright 2003, Chimie Générale - Campus Virtuel Suisse (CVS)
5.1 Characterization of
cations
5.2 Characterization of
ligands

6. Dissolving slightly soluble

salts

6.1 The solubility product

6.2 Concentration of ions in
equilibrium with the solid
salt
6.3 Precipitation
6.4 Dissolution of slightly
soluble salts

7. Standart redox potential of

metal complexes

8. Biochemische bedeutung

8.1 Porphyrines
Hem
Chlorophyll
Corrin
8.2 Catalysis
Zinc containing
enzymes
Substances containing
8.3 Mg2+ and Ca2+.
8.4 Decontamination
Chemotherapy