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To cite this article: Hong He , Yefei Wang & Jian Zhang (2015) Novel Gel with Controllable Strength for In-Depth Conformance
Control: Bulk Gelation Performance and Propagation Properties in Porous Media, Journal of Dispersion Science and Technology,
36:5, 626-633, DOI: 10.1080/01932691.2014.933436
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Journal of Dispersion Science and Technology, 36:626–633, 2015
Copyright # Taylor & Francis Group, LLC
ISSN: 0193-2691 print=1532-2351 online
DOI: 10.1080/01932691.2014.933436
GRAPHICAL ABSTRACT
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Polymer gel has been widely used to control excessive water production in mature oilfields.
However, in view of reservoir conditions characterized by serious heterogeneous thick oil layers,
high strength and in-depth propagation are required of polymer gel to achieve good treatment
efficiency. Based on the concept of in-depth conformance control, a novel gel with controllable
strength composed of polymer, resorcinol/hexamethylenetetramine (HMTA), acetic acid and
gel strength modifier was developed. The effects of component concentrations on bulk gelation
properties were investigated. The microstructures of conventional gel and novel gel at different
aging time were studied by scanning electron microscopy (SEM), which can provide insight into
the mechanism of controllable gel strength. Moreover, sandpack flow experiments were carried
out on sandpacks (U2.5 100 cm) with multi-point pressure taps to investigate whether the novel
gel can propagate in porous media. Compared with the conventional gel, SEM results showed that
the three-dimensional network structure of novel gel was weakened more seriously, resulting in
the decrease of gel strength. Due to decreased gel strength at different aging time, the novel
gel can propagate in porous media to achieve in-depth conformance control.
Keywords Controllable gel strength, in-depth conformance control, microstructure, polymer
gel, propagation properties, scanning electron microscopy (SEM)
1. INTRODUCTION
Polymer flooding has been proved as an effective
Received 13 May 2014; accepted 8 June 2014. method to improve oil recovery in the offshore oilfield of
Address correspondence to Hong He, No. 66, West Bohai Bay in China.[1,2] However, due to reservoir hetero-
Changjiang Road, Huangdao, 266580, Qingdao, P. R. China. geneity and long-term flushing by polymer solution,
E-mail: hehong1103@gmail.com breakthrough of injected polymer solution along the high
Color versions of one or more of the figures in the article can
permeability channel occurs, resulting in poor sweep
be found online at www.tandfonline.com/ldis.
626
NOVEL GEL FOR IN-DEPTH CONFORMANCE CONTROL 627
efficiency and excessive water production, which significantly investigate the effect of component concentrations on bulk
increases the operation cost. Conformance control that gen- gelation properties; (2) study the effect of gel strength
erally refers to using chemical or mechanical methods to modifier concentration on gelation properties and gel
reduce undesired water production has been proved as an morphology to reveal the mechanism of controllable gel
effective water control technology, which can improve sweep strength; and (3) evaluate the gel propagation properties
efficiency and thus result in an increase in ultimate oil recov- in porous media to demonstrate whether the gel can
ery.[3–8] Polymer gels have been successfully applied to con- propagate in porous media.
trol water production from hydrocarbon wells in many
mature oilfields. Due to the covalent bonds between polymer
and the organic crosslinker, organically cross-linked gels 2. EXPERIMENTAL SECTION
have good long term thermal stability such as 2.1. Materials
phenol-formaldehyde polymer gel, which has been widely
The polymer used in this study was partially hydrolyzed
used to control water production in high temperature reser-
polyacrylamide with high molecular weight of 2 107
voirs.[9–13] However, the key issues associated with phenol
Dalton and a hydrolysis degree of 24.25%. The crosslinkers
and formaldehyde are that they are not environment
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value was used as the gel strength of the sample. strength can be controlled by adding gel strength modifier
and change with time under reservoir condition. The novel
gel with controllable strength has some characteristic proper-
2.4. Sandpack Flow Experiments ties as follows: (1) easy to be injected and can propagate into
Figure 2 shows the schematic diagram of sandpack flow in-depth formation; (2) changeable gel strength with gel
experimental apparatus used to determine whether the strength modifier concentration and aging time; (3) possible
novel gel can propagate in porous media with aging time. synergic effects of conventional gel with variable strength,
The sandpack (U2.5 cm 100 cm) with multi-point press- which can achieve in-depth fluid diversion in different loca-
ure taps was used to simulate porous media. The experi- tions in reservoir. For the conventional gel, although the gel
mental procedure was as follows: strength can change with time, only the weak gel can propa-
gate into in-depth formation. Figure 3 shows the transport
1. The sandpacks were filled with clean quartz sand of dif-
schematics of combined conventional polymer gel with differ-
ferent mesh size and saturated with synthetic formation
ent strength and novel gel during propagation into formation.
brine.
2. The sandpacks were flooded with synthetic formation
3.1.2. Gelation Mechanism
brine at a flow rate of 1 mL min1 until the pressure
The gelation mechanism is as follows:
drop across the sandpacks was stable. The permeability
of sandpack was measured by use of Darcy’s law. 1. The hexamethylenetetramine can decompose formalde-
3. Then 0.3PV (pore volume) of gelant solution was hyde slowly under high temperature and acidic condition:
injected into the sandpacks at a flow rate of
1 mL min1. Then the sandpacks were shut in for a
Hþ
period of time at the reservoir condition. ðCH2 Þ6 N4 þ 6H2 O ! 6CH2 O þ 4NH3 : ½1
4. Then several pore volumes of synthetic formation brine
were injected into the sandpacks to measure the 2. Then the formaldehyde can react with resorcinol to
multi-point pressure at different aging time. According form hydroxymethyl resorcinol:
FIG. 8. SEM images of conventional gel and novel gel aged for 30 days: (a) initial SEM image of conventional gel; (b) initial SEM image of novel
gel; (c) SEM image of conventional gel aged for 30 days; (d) SEM image of novel gel aged for 30 days.
FIG. 9. The propagation of novel gel in porous media (sandpack) FIG. 10. The propagation of novel gel in porous media (sandpack)
after aging for 3 days. after aging for 30 days.
strength was adjusted by adding gel strength modifier [3] Sydansk, R. (1988) A new conformance-improvement-treat-
TBHP rather than changing component concentration. ment chromium gel technology. Paper SPE 17329, presented
The TBHP decompose spontaneously to release free at the SPE Enhanced Oil Recovery Symposium, April 16–21,
radicals under reservoir temperature, which can destroy Tulsa, Oklahoma.
[4] Sydansk, R. and Southwell, G. (2000) SPE Production &
the polymer chain, weakening three-dimensional network
Facilities, 15 (4): 270–278.
structures and decreasing the gel strength. The gelation
[5] Chung, T., Bae, W., Nguyen, N., Dang, C., Lee, W., and
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changed with increasing TBHP concentration at different Engineering, 37 (4): 1131–1141.
aging time. The higher the TBHP concentration was, the [7] Liu, Y., Bai, B., and Shuler, P. (2006) Application and Develop-
lower gel strength was. SEM results showed that the initial ment of Chemical-Based Conformance Control Treatments in
gel microstructure of conventional gel was similar to that China Oilfields, Paper SPE 99641-MS presented at SPE=DOE
of the novel gel. However, after aging for 30 days, the net- Symposium on Improved Oil Recovery, April 22–26, Tulsa,
work structure of novel gel was weakened more seriously Oklahoma, 2006.
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[8] Liu, Y., Bai, B., and Wang, Y. (2010) Oil & Gas Science
than conventional gel, resulting in the decrease of gel
and Technology–Revue d’IFP Energies Nouvelles, 65 (6):
strength, which can further confirm the mechanism of con-
859–878.
trollable gel strength. Propagation properties in porous [9] Moradi-Araghi, A., Bjornson, G., and Doe, P. (1993) SPE
media demonstrated that according to the pressure change Advanced Technology Series, 1 (1): 140–145.
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in porous media to achieve in-depth conformance control. [11] Albonico, P., Bartosek, M., Malandrino, A., Bryant, S., and
This study could provide direct evidence of mechanism of Lockhart, T. (1995) Studies on phenol-formaldehyde cross-
controllable gel strength, provide a basis for the appli- linked polymer gels in bulk and in porous media, Paper
cation of novel gel with controllable gel strength for SPE 28983 presented at SPE International Symposium on
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[12] Bryant, S.L., Bartosek, M., and Lockhart, T.P. (1997) Jour-
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ACKNOWLEDGMENT applications of high temperature organic gels for water
Thanks to all individuals associated with the project. control. Paper SPE 35444 presented at SPE=DOE
Improved Oil Recovery Symposium, April 21–24, Tulsa,
Oklahoma.
FUNDING [14] Zhuang, Y., Pandey, S., McCool, C., and Willhite, G.
The authors gratefully acknowledge financial support (2000) SPE Reservoir Evaluation & Engineering, 3 (5):
provided by National S&T Major Project (Grant No. 386–393.
[15] Banerjee, R., Ghosh, B., Khilar, K., Boukadi, F., and Bemani,
2011ZX05024-004) on chemical flooding in Bohai heavy
A. (2006) Energy Sources, Part A, 30 (19): 1779–1787.
oil reservoir, Program for Changjiang Scholars and [16] Gommes, C.J. and Roberts, A.P. (2008) Physical Review E,
Innovative Reserch Team in University (IRT1294) and 77 (4): 041409.
the ‘‘Taishan Scholars’’ Construction Engineering (No. [17] Jia, H., Pu, W.-F., Zhao, J.-Z., and Liao, R. (2011) Energy &
ts20070704). Fuels, 25 (2): 727–736.
[18] Sengupta, B., Sharma, V., and Udayabhanu, G. (2012)
Journal of Petroleum Science and Engineering, 81: 145–150.
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