Organic and Analytical Chemistry
CLD
10803
¢
TUTORIAL 9 (Amine and Amide) Mons K
1. Draw the structure of the following compound (amine and amid)
? Ts
2 a) Metbanamine -
oY {° $2) 2propanamine € ae v “4
nets c) 3-octanamine b)
d) 2,2-dimethyk1-propanamine
QB Fe) Nisoprogy2zreanamine tegen
) N-methyfamine (Pent ataraine) He Gres
hy atte gg 49) NiN-diméthy-2-butanamine
JN’ 3 bP N.N-dimethyl1-propanamine *
at lew, ) N-ethyl-N-methy-2-propanamine "
: ack )) Ethanamide
DAE a CHC k) Propanaqide
o~ )_N.N-dimethylpropanamide
° m) N.N-diethyInonamide
» nel n) Neethy-N-methylbutanamide
wit A, 2. Classify the types of amine.
yo
374 3. Write the IUPAC name for each of the following compounds.
oid, woe O33 ie ne Lae pro Propanamine
cig —
Fonte! + eat
~
ie methy!
Gis
F anit methy /
OP Ostin enn =2 Propanamine
fe
3-methy! butanamid
ae
so NN- dimety] beneenamide
NNMY, 2020
o-chhro aniine v
Q-chloranillng vwh organ and nail Chemisty
vn
gett bt eu
‘ amine .
aledld Ho 4S b-amav - 3~hexano/
1%
On
i 3-0K0-2- Jut anaming
rts
(>
9) ‘
4. Give the synthesis of the following amides and give the IUPAC name of
products.
f)
) CHsCHsCHalke + CHsCHaC(=0)C1 2 products
) NHaCHa + CHsCHECHCH.OH > 1 product the, catalyst used is
AlaOs)
Getaramide reduced using LAK wil” produced
Give the chemical Téaction (Hint: Show the
Structure of reactant and product)
d) 3-methyldecanoic acid +NHs > 1 product
e) Heptnamide undergoes acid hydrolysis. will produce
(Shows the chemical reaction)
f) Pentanamide undergoes base hydrolysis will produce
(Shows the chemical reaction)
g . °
4 cucdscay NG sD E-C He Coy > CH;CH, C-N-CacH CH
4
. 4 +H0)
» CH, Nf + “O}ERGL CHC H. Mo, +H,0
4 one “CHS > ANC cA CH, 742
c) o ™ *
CHyCHACH,CH, CH, CH CH,C~NH3 By,
v
yay fv 4
eee eC — -¢-C-¢-C-NH,
“ghbh db hohg
i 4
fen +o
AO“ of + MaiC?~
o
Nag . savy, 2029
NA“ Oe + mH, re