SCHOOL CHEMISTRY 3

Corrosion, redox reaction stoichiometry and Faraday's law in electrolysis cells

GROUP 3

1. AMELIANA FITRIYANTI (18035054)

2. ANISA PRADILA (18035056)
3. FAIZAH AZ ZAHRA (18035061)
4. FEBI ZANIA PUTRI (18035062)

CHEMISTRY EDUCATION A

LECTURES : ZONALIA FITRIZA S.Pd, M.Pd

FACULTY OF MATHEMATIC AND NATURAL SCIENCE

UNIVERSITAS NEGERI PADANG

2020
 Description of Core Competence , Basic Competence
Achievement Indicator Competence and Teaching Learning Objectives

Core Competence (Knowledge) Core Competence (Psikomotor)

3 Understanding, implementing and analysing factual, conceptual, 4 Processing, thinking, and presenting in concrete and abstract field t
procedural, metacognitive knowledge based on curiosity about sc hat appropriate for development from learned in the school indepe
ience, technology, art, culture, and humanity with insight of huma ndently, doing creatively and effectively, and also able to use meth
nity, nationality, nationhood, and civilization related to phenome od that appropriate to rule of lore.
non and event, and also implementing procedural knowledge on s
pecific study field that appropriate with the talent and interest to s
olve problems.

Description of Basic Competence 3.5 & 3.6 (Knowledge)

Basic Competence Achievement Indicator Competence Teaching Learning Objective

3.5 Analyze the factors that
influence the occurrence of
corrosion and how to
prevent it (C-4)
3.6 Apply redox reaction
stoichiometry and
Faraday's law to calculate
the quantities associated
with electrolysis cells
(C-3)
3.5.1 Students are able to analyze the
factors that influence the
occurrence of corrosion (C-4)
3.5.2 Students are able to analyze how
to prevent the corrosion (C-4)
3.6.1 Students are able to explain the
redox reactions that occur at the
anode and cathode in electrolysis
cells (C-2) (Support Indicator)
3.6.2 students are able to apply redox
stoichiometry to calculate the
quantities associated with
electrolysis cells (C-3)
3.6.3 Students are able to apply
Faraday law to calculate the
quantities related to electrolysis
cells (C-3)
3.5.1.1 Students are able to analyze the factors that
influence the occurrence of corrosion based on
problem based learning models
3.5.2.1 Students are able to analyze how to prevent the
corrosion based on problem based learning models
3.6.1.1 Students are able to explain the redox reactions that
occur at the anode and cathode in electrolysis cells
based on problem based learning mode
3.6.2.1 Students are able apply redox stoichiometry to
calculate the quantities associated with electrolysis
cells to based on problem based learning model
3.6.3.1 Students are able to apply Faraday I law to calculate
the quantities related to electrolysis cells based on
problem based learning model
3.6.3.2 Students are able to apply Faraday II law to
calculate the quantities related to electrolysis cells
based on problem based learning model
 Description of Basic Competence 4.5 & 4.6 (Psikomotor)

Basic Competence Achievement Indicator Competence Teaching Learning Objective

4.5 Students are able to propose
ideas to prevent and solve
corrosion (KA-5)
4.6 Students are able to present a
design procedure for
electroplating with a certain
thickness layer (KA-5)
4.5.1 Students are able to proporse ideas
independently to prevent corrosion
(KA-5)
4.6.1 Students are able to present a design
procedure for electroplating with a
certain thickness layer (KA-5)
4.5.1.1 Students are able to proporse ideas to prevent
corrosion based on problem based learning
4.5.1.2 Students are able to proporse ideas to solve
corrosion based on problem based learning
4.6.1.1 Students are able to present a design procedure
for electroplating with a certain thickness layer
based on problem based learning model

Teaching Learning :
KD 3.5 And 4.5

Through the problem-based learning model by looking for information based on the problems given from various examples of the corotion, investigation, information
processing, problem analysis and presenting solutions (products) to the problems given with a scientific approach, it is hoped that students can increase their faith and
devotion to God almighty and active in the learning process, being honest, disciplined, responsible and careful in answering questions, expressing opinions, providing
suggestions and criticism in the learning process, and being able to analyze the factors that influence the occurrence of corrosion and how to prevent it and then be able
to propose ideas to prevent and solve corrosion.

KD 3.6 And 4.6

Through the problem-based learning model by looking for information based on the problems given from various examples of application of Faraday law, investigation,
information processing, problem analysis and presenting solutions (products) to the problems given with a scientific approach, it is hoped that students can increase their
faith and devotion to God. who is almighty and active in the learning process, being honest, disciplined, responsible and careful in answering questions, expresses
opinions, provides suggestions and criticism in the learning process, and can apply redox reaction stoichiometry and Faraday's law to calculate the quantities associated
with electrolysis cells then able to present a design procedure for electroplating with a certain thickness layer.
 CONCEPT ANALYSIS

Concept Concept Definition Types of Attribute Position Example Non Example

Label Concepts Critical Variable Superordinates Coordinate Subordinate

Reduction Reduction-oxidation Concept - Oxidation Type of - - -Reduction - Zn + Cu2 + → Zn2+ + HCl (aq) + NaOH(I) →
Oxidation reactions are events of state the reduction substance -Oxidation Cu NaCl (aq) + H2O (l)
(Redox) binding and releasing symbol reaction
Reaction oxygen, transfer of - Oxygen - Fe2O3 (s) + 3CO (g)
electrons and changes in binding → 2Fe (s) + 3CO2 (g)
oxidation numbers and release
events
- Electron
transfer
- Oxidation
changes

oxidation oxidation is the release of Concept state Release of Element or Redox reaction reduction Electrochemica Fe → Fe2+ + 2e O2 + 2H2O
electrons, capture of the process electrons, compound l cells + 4e → 4OH-
oxygen, an increase in addition of
the oxidation number of oxidation
an element or compound states,
(Brady, 2011) capture of
oxygen

reduction reduction is the capture Concept state Electron Element or Redox reaction oxidation Electrochmistry O2 + 2H2O + 4e → Fe → Fe2+ + 2e
of electrons, release of the process capture, compound cells 4OH-
oxygen, decrease in oxidation
oxidation state in a decline,
compound or release
elements (Brady, 2011) oxygen
Electrochem The electrochemical cell Concrete transfer of Types of -Oxidation - Voltaic batteries: dry Light bulb
istry Cells is a device that produces concept with chemical cells, types -Reduction cells, batteries, lithium
a form of chemical abstract energy into of electrolysis batteries, and fuel
energy transfer into example electrical electrodes, cells cell mercury
electrical energy or vice energy and the batteries, and
versa that involves involving strength of batteries
electrodes so that there is the the electric
mutual interaction electrodes current
between redox and
electric currents.
(Chang, 2003)

Cell The electrolysis cell is a Concrete devices direct Electrochemi Voltaic cells Faraday’s Oxygen and Preparation of a
Electrolysis device used in the concept used in the current cal cells laws, redox hydrogen are made sugar solution
electrolysis process, electrolysis source and stoichiometry, by electrolyzing
which consists of a direct process positive Electroplating, water
current source and and and electrode
positive and negative negative
electrodes. electrodes
(Sudarmo, 2013)

Volta cells Voltaic cells are a tool that Concrete A tool to Types of Electrochemi Electrolysis Corrosion Galvani and Accu refill
can be used to convert concept convert electrolyt cal cells cell and alessandro voltaic
chemical energy into chemical e electrode (daniell cell)
electrical energy (Syukri, energy into dissolutio experiments and
1999) energy n batteries
electricity

Electrode The electrodes are places Abstract the place Types Cell - Anode and Li metal, Solution
reaction taking place based take place conductor, electrolysis, cathode K, Ba, Ca, Na CuSO4
redok in electrochemical concepts his reaction types Galvanic cells /
cells with redok cells and voltaic cells
(Ahmad, 2001) examples types
concrete redox
Anode Anode is an electrode Abstract Cell Types of Electrode Cathode Inert Zn Cu Cu
where an oxidation based oxidation cell electrodes, Zn electode electode 2+ +
reaction occurs in an concepts reactions oxidation active -> 2e + Zn2+ 2e -
electrochemical cell with reactions electrodes > Cu
(Ahmad, 2001) examples
concrete
Cathode The cathode is the place Abstract Cell Types of Electrode Anode Reduction Cu Cu electode Zn Zn
for reduction in based reduction cell 2+ + 2e -> electode ->
electrochemical cells concepts reactions reduction 2e + Zn2+
Cu
(Ahmad, 2001) with reactions
examples
concrete
Active Abstract based Reactive Electrod Anode, cathode Inert - Copper, iron, Platinum, gold
electrodes The active electrode is concepts with electrodes es, electrodes etc.
Electrodes that are reactive
examples
reactive (Syukri, 1999)
concrete

Inert electrodes Inert electrodes Abstract based Electrode Electrodes Anode, cathode The - Platinum, gold Copper,
An electrode that is very concepts with s that are , not electrodes gold
unreactive (Syukri, not reactive are active
examples
1999) reactive
concrete

Electroplating plating metal coats metal Concept as -plating metal Type of Electrolysis cell - - gold plating water
with other metals using process (electroplating metal electrode with
an electric current ) inert electrode
-coats metal
with other
metal
-using electric
current
Corrosion Corrosion is a reaction Concrete Reactions Types of Galvanic / Electrodes Air Stainless steel Wood
between metals and concept between metals and voltaic cells humidity, plapukan
other substances that metals and acid strength electrolytes,
touch their surface to other temperature,
form metal oxides substances to pH,
(Syukri, 1999) form metal oxidation
oxides reactions,
reduction
reactions,
painting,
galvaization,
bandages
with plastic
and
cathodic
protection
Air humidity Air humidity is a state Concept The state of Media Corrosion Electrolyte - H2O and O2 Sand
of air that contains a lot concrete the air type s,
of water vapor so that it which temperatur
accelerates corrosion contains a e and pH
(Sudarmo, 2013) lot of water
 vapor
accelerates
at corrosion
Electrolyte Electrolytes are a good Abstract The Media Corrosion Humidity, - Gold plaster Acetic acid
medium for charge concepts with medium type temperature, solution
transfer (Sudarmo, concrete for the pH
2003) examples transfer of
loads
Temperature Temperature is a Concept states The amount Media Corrosion Moisture, - Nail in hot Standardizati
quantity that expresses size stated type electrolytes, water on on food
degrees degrees and pH cans
heat from an object of heat
(Syukri, 1999)
pH pH A is the degree of Concept states Acidity Media Corrosion Humidity, - Nail in acid Nail in oil
acidity used to express size type electrolyte, solution (pH
the level of acidity or temperature <7)
alkalinity of a solution
(Syukri, 1999)
Painting Painting is a metal Concrete Metallic Type of Corrosion Galvanizatio - Painted Unpainted
plating process with non- concept coating with paint n, dressing fence fence
polar compounds non polar with plastics,
(Chang, 2003) compounds cathodic
protection

Galvanization Galvanization is a metal Abstract Metal Metal Corrosion Painting, - Metal plating Metal
coating with Zn (Sudarmo, concepts with plating reduction dressing (telephone poles, removal
2013) concrete with Zn potential with plastic car bodies, iron (telephone
examples and cathodic pipes with Zn) poles, car
protection bodies, iron
pipes with
Zn)

Plastic Plastic wrapping is a Concrete Prevention Plastic Corrosion Painting, - The handle of the The handle of
dressing process of preventing concept of iron type Galvanizatio knife, machete, the knife,
metal contact contact with n, Cathodic Sa bit covered by Paran g, the
with water and air water and Protection plastic sickle
(Chang, 2003) water lined by
wood
Cathodic Cathodic protection is a Abstract Metal Electrode Corrosion Painting, - Metal plating Metal
protection metal plating concept plating potential galvanizatio with Mg plating
with other metals that with concrete with other metal n, with
have a very low electrode examples metals that And gold
potential (Sudarmo, 2013) have very dressing
low with plastic
electrode
potentials
Stoichiometry Stoichiometry is the Concept - Quantity -Quantitiy Electrolysis Faraday’s Volume, CdSO4 have the If current
redox science of chemistry that based on change change cell law pH, and mass 2 gra,. that
studies the quantity of a principle coefficient Ar=112 and used
- Substance
Volume of equal to I
substance, including mass, - composition oxygen (STP)? as long as t
number of moles, volume, Answer : mass of
and number of particles Katoda : Cd2+ + substance
(Chang, 2005:74) 2e → Cd that
Anoda : 2H2O → released
O2 + 4H+ + 4e G≈it
So, 2 Cd2+ +
2H2O → 2 Cd +
O2 + 4H+
2 Cd = gram/Ar
=2/112
=0.017
O2 = ½ x 0.017 =
8.92 x 10-3
n = V/22.4
8.92 x 10-3 =
v/22.4
V = 8.92 x 10-3 x
22.4
=0.2 L

Volume gas Capacity is a calculation Concept -the number -amount of Stoichiometry pH, mole - 1 ml, 1 liter 1 gram, 1
of how much space can be states size of volume redox and mole
occupied in gas attributes -type of coefficient
compound
-the unit

Mole The number of substance Concept -amount of Type of Stoichiometry pH, - 1 mole, 2 mole 1 gram, 2
containing particles that based on substance substance redox volume,and liter
make a atom, molecule, or principle constituent coefficient
of atoms
other paticles in which the
-molecule
exact number of atom
Coefficient The coefficient is a form Concept - The -amount of Stoichiometry Volume, - Number 1,2,3, or A,B,C, or
of the ratio of moles, states size of number coefficient redox mole and pH etc. etc.
volume, or number attributes
particles.

Faraday's law Faraday's law is a law in Concept Laws in Electric Electrolysis Electrodes, Faraday I The sound of Faraday II's
electrochemistry that based on electrochem current, cell Faraday Law, Faraday's First law is that if
explains the quantitative symbols istry that time, Law Faraday II Law is the an equal
take place in charge 1 amount of
relationship between Law amount of
electrolysis mole of substance
electric current, time and cells electrons produced at the electric
the charge of 1 mole of electrode during charge is
electrons in metals that electrolysis is applied to
occurs in electrolytic cells proportional to several
formed in electrode the amount of solutions
electric charge containing
that is flowed
metals, the
during
electrolysis. mass of the
metal
deposited is
directly
proportional
to its
equivalent
mass
Law I Law I Concept The amount Amount Law Law II Mass of If current If the mass of
Faraday Faraday based of substance of faraday faraday substance, that the substance
is n symbols released is substance, equivalent used that
amount of substance directly electric weight, equal to I released, G.
that proportional charge, strong as long as t and the masses
generated in to the electrolysi mass of substance substance
electrode amount of s current that equivalent,
on electricity electricity, released ME then
event flowing time of G≈it G≈ME
through the electric
electrolysis
solution charge
comparable
with
amount
payload
 electricity
flowed during electrolysis
(Sudarmo, 20 13)
Faraday's Faraday's second law is Concept The amount Amoun Faraday's law I Faraday's Mass of If the mass of the If the current
Second Law that if an equal amount of based on of weight of t of Law substance, substance being used is I for
electric charge is applied symbols the electric equivalent liberated is G the mass t of
substance ity, weight,
to several solutions and the the substance
released is amount strong
containing metals, the directly of current equivalent mass liberated is
mass of the metal that proportional electrol electricity, of the substance, G≈it
settles is directly to its yte, time of ME then G≈ME
proportional to its equivalent equival electric
equivalent mass weight a ent charge
(Sudarmo, 20 weight
The mass of The mass of a substance is Concepts The Particles Faraday's Equivalen - Mass of NaOH Mass of
the substance the amount of material based on number of , matter, first law, t weight, 39.997 g / mol NaOH 50 g /
contained in an object concrete particles matter faraday's electric mol
(Chang, 2005) contained
second current,
in objects /
substances law time,
electric
charge
Mass Mass Concept Relative Mass Ar, Law I Mass of - On Cu2+ + On Cu2+ + 2
atomic mass ionic substance,
equivalent equivalent Based on
divided by charge
Faraday, 2 e- Cu e- Cu
is the mass symbols Faraday's electric
atom ionic charge Second Law current, time, Then the mass Then the
relative (Ar) electric charge of the metal mass of the
divided equivalent of Cu metal
with
(Ar Cu = 63.5) = equivalent of
change
number e Cu Cu (Ar Cu =
oxidation = 63.5 / 2 = 63.5) = e Cu
data load 31.75 = 63.5 / 1
the ion = 63.5
(Syukri, 1999)
Strong Strong currents Concept The flow of Electric Law I Mass of - Current Time that
currents electricity based electric charge, faraday, substance, electric inside needed
electricity is a n concrete charge in a time law II mass 10 seconds if in a
load flow certain time faraday equivalent, known circuit if
electricity strong load size strong currents
get through currents electricity = 40 C equal to 4
 a conductor within a electricity, ? The ampere
certain period of time payload Answer: I = Q / t and the
(Johari, 2006) electricity = 40/10 payload is 40
= 4 Amperes C? answer:

t=Q/I=
40/4
= 10 seconds
Time Time is Concept The Quantitati I Faraday's Law, mass of - Time required The amount
standard based quantitative ve Faraday's II substanc in a of electric
quantitative n concrete standard in standards, Law e, mass Suite current in
that electric electric if the current is
equivalent, 10 seconds
needed current current, strong
passing if the
how much equal to 4 amount of
through a Ampere and
long flow
point electric
electricity big
charge is
get through the payload
a point 40 C is? known = 40
on the wire (Johari, 2006) answer: t = Q / I = C?
40/4 = 10 Answer: I =
second Q / t = 40/10
= 4 Amperes
Electrical Electric charge is a basic Types based The basic Charges, Law I farday, Mass of the - An electric The time it
charge charge on concrete charge of the particles, law II faraday substance, current that takes in a
Carried out by particles particles attractive mass passes through an circuit if the
So that causes causes the forces, equivalent, current is
obstacle in a
n particles particles to repel current. strong
experience series with an
experience electric current of equal to 4
attraction and repulsion attractive
4.0 amperes and Ampere and
and
(Johari, 2006) big
repulsive within 10
forces the payload is
seconds, how 40
much is the C is?
electric charge? answer:
Answer:
I=Q/t t=Q/I=
4.0 amperes = 40/4
Q / 10 second = 10 seconds
Q = 4.0 amperes
x 10
seconds
Q = 40 C
CONCEPT MAP