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DESIGN OF OPTIMIZED MODEL OF SMOKELESS CHULHABY USING GEO-POLYMER AND INSTALLATION FOR POOR VILLAGERS IN NORTH EAST INDIA View project
All content following this page was uploaded by Aminul Laskar on 11 May 2016.
Received: 30 December 2014 / Accepted: 23 April 2015 / Published online: 5 May 2015
© King Fahd University of Petroleum & Minerals 2015
Abstract Ground granulated blast furnace slag (GGBS)- lead to decrease in shear strength associated with swelling,
based geopolymer is an excellent binder that attains high shrinkage, settlement, consolidation and disruption under
strength by curing at room temperature. Fly ash-based imposed wheel load due to vehicular traffic. Improvement
geopolymer binder, on the other hand, attains high strength of clayey soil by treating with lime, cement, slag and fly ash
when heated in particular temperature range. Although liter- are nowadays established methods used widely around the
atures on GGBS- and fly ash-based geopolymer are plenty, world. Lime stabilization is preferred as a stabilizer because
reported literatures on soil–geopolymer system are lim- of its simplicity and overall economy of construction. On the
ited. An attempt has therefore been made in the present other hand, cement is the most common stabilizing agent used
paper to investigate soil–geopolymer incorporating slag, fly extensively for sub-grade, sub-base and base construction in
ash and blending of slag and fly ash as source materials. pavement engineering since 1950. Cement stabilization is an
It was observed that unconfined compressive strength of established technology to improve the engineering proper-
soil–geopolymer system increases with the source material ties of wide variety of soils including granular materials, silt
content. Molar concentration of alkali activator, alkali-to- and clay. Mixing of soil and cement in the presence of water
source material ratio and percent content of source material causes mark improvement in soil characteristics like increase
altogether affect the unconfined compressive strength of sta- in internal friction, decrease in shrinkage–swelling behavior
bilized soil that is not straightforward. Na/Al and Si/Al ratios and decrease in settlement due to continuous evolution of
of the geopolymer mix ultimately govern the strength of sta- hydration products [1]. The hydration products are responsi-
bilized soil. It was also observed that slag content is the most ble for strength gain in soil–cement system by holding soil
dominating factor affecting unconfined compressive strength particles within themselves [2]. The replacement of cement
rather than Na/Al ratio in case blending of GGBS and fly ash. by waste materials, such as fly ash (FA), rice husk ash, and
biomass ash, has been extensively applied in practice. The
Keywords Geopolymer · Blast furnace slag · Fly ash · application of fly ash to geotechnical engineering is reported
Unconfined compressive strength · Clayey soil by many researchers. There are plenty of literatures avail-
able at present on soil stabilization by lime, fly ash, rice husk
and slag [3–6]. Among all stabilization techniques, cement
1 Introduction stabilization is proven to the best for obvious reasons.
Geopolymer technology was first patented and reported
Clayey soils are considered as problematic soil with their by Joseph Davidovits more than 30 years ago [7,8]. Since
unpredictable performance in the presence of moisture. A then, a considerable knowledge has been gained in this
little change in moisture content in this type of soil may discipline. Civil engineers could make use of geopolymer
successfully in concrete and mortar, and today, a large num-
B Aminul Islam Laskar ber of literatures are available on geopolymer concrete and
aminul.nits@gmail.com
mortar [9,10]. Works on geopolymer–soil are very recent
1 Department of Civil Engineering, National Institute and are limited in number [11–15]. It is reported that fly
of Technology, Silchar 788010, India ash-based soil–geopolymer may attain unconfined compres-
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394 Arab J Sci Eng (2016) 41:393–400
sive strength up to 50 N/mm2 after curing for one year at 2.2 Fly Ash
elevated temperature [14,15]. The aforesaid literatures on
soil–geopolymer are based on fly ash-based geopolymer ASTM class C fly ash obtained from thermal power plant at
only. Zhang et al. [16] examined the feasibility of metakaolin- Farakka (India) was used in the present study. The properties
based geopolymer–soil. Reported literature on slag-based of fly ash are shown in Tables 1 and 2.
geopolymer–soil system is rare. Recently, Yi et al. [17] inves-
tigated the use of slag-based geopolymer in marine clay. 2.3 Alkali Activators
However, detail study on the factors affecting unconfined
compressive strength of clayey soil–geopolymer needs to be The most common alkaline liquids used in geopolymeriza-
explored. In the present study, an attempt has been made tion are combination of either sodium hydroxide (NaOH) and
to study various mix parameters which control the strength sodium silicate or potassium hydroxide (KOH) and potas-
gain process in the soil–geopolymer. Attempt was also made sium silicate [9]. Sodium hydroxide solution was chosen
to explain how unconfined compressive strength of soil– in the present study as alkali activator. Sodium-based solu-
geopolymer is actually controlled by Na/Al and Si/Al ratios. tions were chosen because they are cheaper and because it
is reported that NaOH possesses greater capacity to liber-
ate silicate and aluminate monomers [18]. It is also reported
2 Materials and Mixtures that sodium cations have better zeolitization capabilities in
geopolymer-forming systems [19]. The commercial-grade
2.1 Ground Granulated Blast Furnace Slag sodium hydroxide in pallets (purity 98 %; specific gravity
2.13) was used to prepare the solution with tap water. The
Commercially available ultra-fine GGBS was used as the mass of NaOH pallets in a solution varied according to the
source material for geopolymer binder. The properties of molar strength (M). Alkali solution was prepared one day
GGBS are presented in Tables 1 and 2. prior to use. Sodium silicate used in the study had specific
gravity 1.5, and its purity was 97 %. The molecular weight of
the sodium silicate (Na2 SiO3 · 5H2 O) was 212. The weight
Table 1 Chemical composition of source material ratio of SiO2 /Na2 O is 0.97 and percentage of Na2 O and SiO2
Particulars Content [mass (%)] are 29.25 and 28.30 % in sodium silicate, respectively.
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Arab J Sci Eng (2016) 41:393–400 395
The soil mixed with binder were rolled, put in PVC molds
and compacted until air was expelled from the mix.
3.1 Curing
3.2 Unconfined Compressive Strength Fig. 2 UCS of soil–slag-based geopolymer system at various percent-
age of slag at M = 14.5
The cured samples due for testing were taken out from the
curing yard. The molds of the samples were removed and
immersed in water for 24-h soaking. The soaked samples UCS was found to increase from 12 % slag content onwards.
were again air-dried at room temperature for 1 h before test- At higher slag content, UCS increased steadily due to the
ing. Unconfined compressive strength test of the specimens availability of more quantity of binder in the geopolymer–
was performed as per the Indian Standard Code of Prac- soil matrix. More was the alkali-to-slag ratio (R), more was
tice IS—2720 (Part 10): 1991—Determination of unconfined the strength because of more binder.
compressive strength. The specimens were placed in the Tests were also carried out at M = 14.5 of NaOH solution,
compression testing machine, and the compression load was and the results are shown in Fig. 2 for R values 0.45, 0.65
applied till the sample failed. Constant rate of loading were and 0.85 after 28 days of curing. UCS for R = 0.65 showed
maintained during the UCS test. a steady rise with increase in slag content beyond 8 % and
developed an UCS as high as 11.3 N/mm2 at 20 % slag con-
tent. In case of R = 0.45, there was steep increase in UCS
4 Test Results and Discussion between 12 and 15 % slag content, and slope of the curve
became gentle beyond 12 % slag content. When R = 0.85, the
4.1 Slag-Based Geopolymer–Soil specimens showed maximum values of UCS up to 12 % slag
content compared to the other two, and the slope became
Figure 1 shows the variation of UCS of slag-based almost flat with the further increase in slag content.
geopolymer–soil samples with % slag content at M = 12
and R = 0.45, 0.65 and 0.85 after 28 days of curing, where 4.2 Fly Ash-Based Geopolymer–Soil
M = represents molar concentration of NaOH solution and
R represents alkali-to-slag ratio (by weight). Samples with Figure 3 presents the variation of UCS of stabilized samples
alkali activated slag did not yield significant UCS when slag with fly ash content at M = 12 and R = 0.45, 0.65 and 0.85.
content was ≤8 % for R = 0.65 and 0.85. In case of R = 0.45, As the fly ash content increased, UCS was found to increase
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396 Arab J Sci Eng (2016) 41:393–400
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Arab J Sci Eng (2016) 41:393–400 397
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398 Arab J Sci Eng (2016) 41:393–400
R = 0.65 showed lower UCS at every Si/Al ratio. Speci- 4.5 Effect of Na/Al and Si/Al Ratios on UCS
men with M = 10 and R = 0.80 showed lowest UCS up to with Blended Source Materials
Si/Al = 1.80. The differences of UCS in all three cases of
Fig. 9 may be attributed to the role played by Na/Al ratio. Cal- Na/Al and Si/Al ratios vary with the change in blending
culation of Na/Al ratio shows that in case of specimens with proportion of slag and fly ash. In the present study, two dif-
M = 12 and R = 0.65, Na/Al is closer to its optimum range than ferent molar concentrations of NaOH solution, namely 12
any other specimens at a particular Si/Al ratio. To investigate and 14.5 M, were considered to study the effect of blending.
further, sodium hydroxide is replaced by sodium silicate in Blending of slag and fly ash as source material with 12 M
samples with M = 10, R = 0.80 so that a very high values of alkali activator was designated as Type I and 14.5 M alkali
Si/Al ratio is obtained. At constant Na/Al ratio of 1.15, the activator was designated as Type II. Variation of Na/Al and
maximum Si/Al ratio could be achieved is 2.06 by 100 % Si/Al ratios for samples with blended source material is pre-
replacement of NaOH. Increase in Si/Al ratio beyond 2.06 sented in Table 6. In Table 6, FA0SL100 means that fly ash
was not possible, because further increase in sodium silicate and slag contents were 0 and 100 %, respectively, of the total
would lead to change in both Si/Al and Na/Al ratios. Maxi- source material (i.e., blend of fly ash and slag). Similarly,
mum UCS (18.9 N/mm2 ) was observed at Si/Al ratio equal FA20SL80 means that fly ash was 20 % and slag was 80 %
to 2.06 (Fig. 9). Xu and Deventer [22] reported that when by weight of source material and so on. Table 6 shows that
Na/Al ratio lies within 0.75–1.25, strength of geopolymer with the increasing slag content, Na/Al ratio of both Type I
paste was the maximum provided, Si/Al = 2.0. Thokchom et and Type II increases. Variation of molar concentration also
al. [23] reported that there is continuous increase in strength changes the Na/Al ratio. Na/Al ratio of entire Type I series
of fly ash-based geopolymer binder at elevated temperature lies within 1.20–1.25, and for Type II series, it lies between
beyond Si/Al ratio more than 2.0. It needs further investi- 1.36 and 1.41. Figure 10 shows the variation of UCS of spec-
gation to explain why UCS increases with increase in Si/Al imens with the variation of Na/Al ratio containing blended
ratio beyond 2.0 at ambient temperature. source materials. The increase in UCS was steady with the
increase in Na/Al ratio from ‘A’ to ‘B’ (Fig. 10). Similar
increasing trends was noticed in UCS with the increase in
Na/Al ratio from point ‘C’ to ‘D,’ but the curves are dis-
continuous. Apparently, from ‘B’ to ‘C,’ there was sudden
drop in UCS with the increase in Na/Al ratio. The variation
in Na/Al was associated with two factors: One was due to
variation in source material (A–B and C–D) and the other
was due to variation in alkalinity. With reference to Table 6,
curves of Fig. 10 correspond to different alkalinity of NaOH,
viz 12 and 14.5 M, and the discontinuity was due to change
in molarity of alkali. The observed Na/Al ratio for maximum
UCS in both Type I and Type II is not in line with the findings
of Rees [20]. Increase in Na/Al ratio in both Type 1 and Type
Fig. 9 Effect of Si/Al ratio on UCS 2 specimens in Table 6 means increase in slag content rela-
Table 6 Different Na/Al and Si/Al ratios blended source material at R = 0.65
Mix designation Sample type Blended mix content Mix parameters Na/Al ratio Sample designation Si/Al ratio
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Arab J Sci Eng (2016) 41:393–400 399
5 Conclusions
tive to fly ash in the blended source material. The dissolution
of Si+ and Al+ is comparatively less in fly ash because of its Experimental investigation on soil–geopolymer incorporat-
high binding energy compared to slag [24]. ing fly ash, GGBS and their blending as source materials
Strength gain of Type I and Type II samples with the was carried out. It was observed that geopolymer is an excel-
increase in Na/Al ratio was predominantly due to the avail- lent material for soil stabilization. The following are general
ability of more and more slag in the system. Thus, in case conclusions derived from the present study:
of slag–fly ash blending, slag content was more dominating
rather than the Na/Al ratio of the blend because of different 1. UCS of stabilized soil steadily increases with the increase
dissolution potentials of two different source materials. For in slag content. Below 8 % slag content, gain in UCS is
similar reasons, point C onwards, UCS increases although not significant.
Na/Al ratio was beyond optimal range (i.e., 0.75–1.25) [22]. 2. When fly ash is used as source material for geopolymer
Dissolution extent of blended source materials at different stabilization, UCS is much less compared to UCS of slag-
blend proportions is still not clear from the present study. based geopolymer stabilized soil.
It needs further investigation to know the actual partici- 3. Effect of molar strength of alkali, alkali-to-binder ratio,
pating Na/Al ratio in geopolymer–soil with blended source source material content on UCS of stabilized soil is not
material. straightforward. UCS of stabilized soil eventually is con-
trolled by Na/Al and Si/Al ratios.
4.6 Effect of Mechanical Activation of Fly Ash 4. When slag and fly ash are blended, slag content is
more dominating rather than Na/Al ratio of the blending
Mechanically activated fly ash (i.e., fly ash after further grind- because of different dissolution potentials of slag and fly
ing) improves the compressive strength in geopolymer paste ash.
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400 Arab J Sci Eng (2016) 41:393–400
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16. Zhang, M.; Guo, H.; El-Korchi, T.; Zhang, G.; Tao, M.: Experi-
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