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Minerals Engineering 19 (2006) 1377–1379

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Technical note

Effects of media shape on milling kinetics


N.S. Lameck *, M.H. Moys
School of Process and Materials Engineering, University of the Witwatersrand, Private Bag 3, Johannesburg, WITS 2050, South Africa

Received 31 August 2005; accepted 7 December 2005


Available online 15 February 2006

Abstract

Spherical balls are the dominant grinding media used in ball mills. However, balls which are initially spherical, wear into non-
spherical fragments. The proportion of worn, non-spherical balls in the charge of a mill fed with 50 mm balls is dominant in ball sizes
less than 30 mm. Their effects on mill performance in terms of material breakage are not yet established.
The variations of specific rate of breakage with single size feed and fractional filling U, were studied for the two media shapes
(spherical and worn balls). Higher breakage rates were noted with spherical media than worn balls but the differences narrow with
decreasing feed size and increasing material fractional filling, U.
 2005 Elsevier Ltd. All rights reserved.

Keywords: Grinding; Comminution; Breakage kinetics; Grinding media

1. Introduction This work focuses on investigating the impact of worn


balls on milling kinetics and assesses whether the effect of
Spherical balls are the dominant media shape used in the worn balls on mill performance requires any action to
tumbling mills. However spherical balls wear into non- maintain maximum mill productivity. In the study, two
spherical fragments as a result of breakage due to impact media shapes are considered: spherical and worn balls.
and different wearing mechanisms inside the mill. Thus at
any one time a mill charge is a mixture ranging from larger 2. Experimental equipment and programme
spherical balls to worn irregular fragments (Banisi et al.,
2000; Vermeulen and Howat, 1989). To date, not much Experiments were conducted using a 0.54 m internal
has been done to assess the impact of worn balls on mill diameter laboratory mill. The mill is 0.4 m internal length
performance. fitted with twelve 20 mm high trapezoidal lifters with 45
It would be expected that increased surface contact by face angle and 50 mm base width. The mill is driven by a
polygonal balls and flat chips (compared to only point con- 2.5 kW variable speed motor mounted on a mill rig and
tact that is made by spherical media) ideally should pro- has been described previously (Moys et al., 1996). The mill
mote increased grinding by attrition. On the other hand, filled with balls to 20% by volume was operated at 75%
worn balls may pack closely thus reducing the void space critical speed. Single sized feed quartz (300 · 425,
available for material to be ground. The larger surface area 600 · 860 and 1180 · 1700 lm) was used at 20%, 50%
per unit mass of polygonal (worn) media may also result in and 80% fractional filling, U.
more effective support of the media by the ore, leading to Perfectly spherical balls in various size ranges were used
reduced media–media forces in the grinding zones. to conduct experiments. The worn media were obtained
from an industrial dry ball mill used by ESKOM (South
Africa power utility) to produce pulverized fuel following
*
Corresponding author. Tel.: +27 11 717 7558; fax: +27 11 403 1471. an experiment done to characterise ball size and shape
E-mail address: nlameck@prme.wits.ac.za (N.S. Lameck). distribution (Lameck, 2005). The typical characteristic

0892-6875/$ - see front matter  2005 Elsevier Ltd. All rights reserved.
doi:10.1016/j.mineng.2005.12.008
1378 N.S. Lameck, M.H. Moys / Minerals Engineering 19 (2006) 1377–1379

features of industrial ball shape distribution are shown in 1


Fig. 1. It was clearly observed that balls below 31 mm,
which constituted about 15–40% of the sample, are no
longer spherical. Thirty millimeter top size balls were
used-all perfectly spherical or all non-spherical in the two

Wi (t)
ball loads used. The balls size distribution used in experi- 0.1
ments was decided based on this experiment as well.
Material properties such as coefficient of friction, size Worn balls (1180x1700 µm)
Spheres (1180x1700 µm)
and shape affect media packing (Zhou et al., 2002). With Worn balls (600x850 µm)
this fact in consideration, spherical balls charge mass was Spheres (600x850 µm)
calculated by assuming the voidage of 0.4 at the desired 0.01
0 1 2 3 4 5
mill filling level. The charge mass involving worn balls Time (Min)
was equivalent to that of spherical balls. This implies that
media shapes were compared based on the same mass Fig. 2. First order plot of batch ball milling of quartz.
criterion.

3. Discussion of results Fractional filling, U (600x850 μm)

0 0.2 0.4 0.6 0.8 1


The results presented in Fig. 2 compare the first order 10 10

Specific rate of breakage (Min-1)


plot of quartz with feed size of 1180 · 1700 lm and
600 · 850 lm for spherical and worn grinding media Worn balls
shapes. The results suggested that, for the two media Spheres
shapes studied, breakage followed first order.
The variation of specific rate of breakage with feed sizes 1 1
shown in Fig. 3 (bottom axis), indicated that spherical
media have higher breakage rate but the difference narrows
as the feed becomes finer.
It is understood that larger particles undergo impact
breakage when impacted by balls with sufficient kinetic 0.1 0.1
energy. As particles get smaller, they become difficult to 100 1000 10000
break by impact hence breakage rates decrease with Particle size, U = 0.8 (μm)
decreasing particle size. Considering the two media
Fig. 3. Variation of specific rate of breakage with particle size and
charges, worn balls have surface, linear and point contacts
fractional filling.
while spheres have only point contact. This might lead one
to expect increased breakage by abrasion for worn balls.
On the other hand, the use of test screens in sizing the screen size class, the non-spherical (worn) media consti-
media might be the factor accounting for higher breakage tuted heavier balls as relatively bigger balls could easily
rate for spherical media with coarse feed. For the same reorient and pass through the screen aperture. To maintain

Fig. 1. Characteristic feature of balls inside ball mill.


N.S. Lameck, M.H. Moys / Minerals Engineering 19 (2006) 1377–1379 1379

an equal total mass and the same screens mass fractions, were observed with spherical media. The difference is more
1489 worn balls were used compared to 1758 spherical significant with coarse feed.
balls. The increased spherical balls number results in more However considering that worn balls in industrial mill
ball-to-ball and ball to liner collisions for spherical balls charge constitute about 15–40% and that only marginal
than worn balls, which results in higher catastrophic break- differences in breakage rate was observed, the effect of
age by impact for larger particle sizes. While the trend the presence of worn balls inside the mill charge is negligi-
observed shown faster breakage rate with spherical media, bly small. Thus, the benefit that can be obtained does not
Ipek (2006) comparison of spherical media and cylpebs justify the cost of their removal from mills.
suggested that cylpebs have higher rate of breakage than
spheres. Acknowledgement
The variations in specific rates of breakage, S with frac-
tional fillings U were studied using 600 · 850 lm material The authors acknowledge the financial support from Es-
feed size (Fig. 3, top axis). It was observed that the specific kom without which this work would not have been
rate of breakage decreased with increasing fractional filling, possible.
U.
Austin et al. (1984) equation relating specific rate of References
breakage, S with particle size xi when xi  d (d is ball
diameter) was extended to include the effect of fractional Austin, L.G., Klimpel, R.R., Luckie, P.T., 1984. Process Engineering of
filling U and Eq. (1) was obtained as representative of Size Reduction: Ball Milling. SME, New York, USA.
Banisi, S., Langari-Zadeh, G., Pourkan, M., Kargar, M., 2000. Measure-
the effect of feed size and interstitial filling have on specific ment of ball size distribution and wear kinetics in 8 m by 5 m primary
rate of breakage. mill of Sarcheshmeh copper mine. CIM Bulletin 93 (1041), 145–149.
Ipek, H., 2006. The effects of grinding media shape on breakage rate.
S i ¼ a0 xai ExpðkU Þ; ð1Þ
Minerals Engineering 19 (1), 91–93.
0 Lameck, N.S. 2005. Effects of grinding media shapes on ball mill
where a is proportionality constant resulting from Austin
performance. MSc. Dissertation, University of Witwatersrand,
et al. (1984) equation and the effect of mill filling.
Johannesburg.
Moys, M.H., van Nierop, M.A., Smit, I., 1996. Progress in measuring and
4. Conclusion modelling Load behaviour in pilot industrial mills. Minerals Engi-
neering 9 (12), 1201–1214.
Spherical balls have slightly higher rates of breakage Vermeulen, L.A., Howat, D.D., 1989. A sampling procedure validated.
Journal of South African institute of Mineral and Metallurgy 89 (12),
than worn balls. For normal operating material fractional
365–370.
filling (0.8 < U 6 1.0), the specific rates of breakage for sin- Zhou, Y.C., Xu, B.H., Yu, A.B., Zulli, P., 2002. An experimental and
gle size feed of 600 · 850 lm were similar for the two numerical study of the angle of repose of coarse spheres. Powder
shapes, but for lower material fractional filling, higher rates Technology 125, 45–54.

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