IITJEE (MAIN) - 2014 (Physics, Chemistry and Mathematics) Code - E Solutions Part-A: Physics 1. Correct Option

IITJEE MAIN | PHYSICS, CHEMISTRY AND MATHEMATICS
Paper – 2014
IITJEE (MAIN) – 2014

(Physics, Chemistry and Mathematics)
Code - E
SOLUTIONS
PART–A : PHYSICS
1. Correct option (1)

The current voltage relation is I = (e 1000V/T – 1) m A …… (1)
When I  5mA
5 mA = (e1000 V/ T  1)
e1000 V/ T  6mA
Differentiating equation (1), we get
1000
dI = (e1000 V/ T )  dV
T
On substituting the values, e1000 V/ T  6 mA ,T= 300K , dV= 0.01
1000
= (6 mA)   (0.01)
300
=0.2 mA
Therefore the error in the value of current is m A = 0.2 mA.
H is the height of the tower.
www.topperlearning.com 1
Paper – 2014
u
Time taken by the particle to reach highest point of its path is t 1 
g
We know that v 2  u2  2gh
So speed on reaching ground ,v = u2  2gh
Now v = u + at ( for particle thrown upwards)
 v = -u + gt (For speed of particle reaching to ground)
 u2  2gh  -u + gt
On solving, we get
u  u2  2gH
t=
g
Given that time taken by particle to hit ground is n times that
taken by it to reach the highest point of its path.
u  u2  2gH
t = = n t1
g
u  u2  2gH u
=n
g g
On solving the equation, we get
2gH = n(n-2)u2
3. Correct Option (2)
Paper – 2014
Acceleration a = R  
Now, For the block of mass m, mg -T = ma ---------- equation(1)
Tension T  perpendicular distance R  I
i e T  R  mR 2 ......(2)
a
T  R  mR 2  ma  R
R
or T=ma ......(3)
Substituting equation (3) in equation (1), we get
mg -T = ma
mg -ma = ma
mg = 2 ma
g
 a=
2
x3
Given y =
6
dy x2 x2
On differentiating  3 =
dx 6 2
dy x2

dx 2
Let  be the angle at which block start slipping.
Under the condition of limiting equilibrium, we have
  tan 
Paper – 2014
where  is the coefficient of friction = 0.5

From the figure, we get that
dy
tan  =
dx
Substituting in   tan 
dy
0.5 
dx
x2
0.5 =
2
x=  1
x3 1
Now, putting value of x in y = ,y 
6 6
The maximum horizontal distance from origin where the block can be placed
without slipping is x=1
Hence, vertical height
1
y=
6

Let the rubber band be stretched by a distance 'x'.
The magnitude of restoring force is F =ax  bx2
The work done in stretching the rubber-band
 dW =  F.dx
L
W   (ax  bx 2
) dx
0
L L
  ax dx +  bx dx
2
0 0
L2 L3
a +b
2 3
aL2 bL3
The work done in stretching the rubber-band by L is +
2 3
Paper – 2014
Conical pendulum is rotating with an angular velocity ω with the vertical axis.
Torque changes angular momentum
Angular momentum of the pendulum about the suspension point 'O' is
L = m(r  v)
r can be resolved into two components, radial components and axial components.
Due to rradial , L will be axial and due to raxial , L will be radially outwards.
Here the angular momentum is not conserved.
So magnitude of net angular momentum will be constant |L| = |m(r × v)| but its direction
changes as shown in the figure.

Let the four particles of mass M be placed at the four corners of a square as they are
equidistant from each other as shown in the figure.
The ‘x’ be the distance between the masses and using Pythagoras theorem we can find x as
x2  R 2  R 2
x 2 R
Under the action of mutual gravitational attraction, they move along the circle of radius R.
The necessary centripetal force of attraction is provided by gravitational force.
Let us consider a single particle acted upon by three other adjacent particles.
Paper – 2014
The two forces acting on that will be the sum of resultant of the force due to adjacent two
masses and that of the third one diagonally opposite to it.
Mv 2
 F' Fdiagonally opposite mass
R
F' = F2  F2  2FFcos90
F' = 2 F
GM2
= 2
x2
GM2 GM2
F' = 2  2
 
2
2R 2R 2
GM2
Fdiagonally opposite mass 
2R 
2
GM2 GM2 Mv 2
2  
2R 2  2R 2 R
GM2  1 1  Mv 2
  R
R 2  4 2
On solving for v, we get
GM  2  4 
v=  
R  4 2 
1 GM
= (1+2 2 )
2 R

As length is kept constant, we have
L
Strain =   Q
L
 Strain =  Q
  Coefficient of thermal expansion
and Q  Temperature change
Thermal stress generated = strain  
Pressure =stress =   strain
= 2 x 1011   Q
= 2 x 1011  1.1 x 10-5  100
= 2.2  108 Pa
Pressure to be applied = 2.2  108 Pa
Paper – 2014
On equating the pressure at A from both L.HS and R.H.S, we get

h1d1g  h2d2g  h3d2g  h4d1g
h1d1g  h4d1g  h2d2g  h3d2g ......(1)
h1  R  R cos(90   )
h1  (R  R sin  )
h2  R sin 
h3  R sin(90   )
h3 =Rcos 
h4 =R-R cos
Substituting in (1), we get
(R  R sin  )d1g  (R-R cos )d1g  R sin d2g  Rcos d2g
(R cos  R sin  )d1g  (Rcos   R sin  )d2g
d1 cos   sin  1  tan 
  =
d2 cos  sin  1  tan 
10. Correct option- No option matches the correct answer
When the bubble detaches, force of surface tension will act on complete circumference and
the resultant will be in the downward direction.
The Bubble will detach if
Paper – 2014
Buoyant force ≥ Surface Tension Force

Buoyant force = density  (cross sectional area)  g
4
Buoyant force  w  R 3  g
3
r
From figure, sin  =
R
Surface Tension Force =  T  dlsin 
r
= T  2r 
R
On equating both forces, we get
4 3 r
w R g  T  2r 
3 R
2R w g
4
r2 
3T
2w g
r  R2
3T
2w g
The value of r just before bubbles detach is R 2 .
3T
Given
A c  A B  AS  4 cm2
LC  46 cm LB  13 cm LS  12 cm
K C  0.92 K B  0.26 K S  0.12 (in CGS units)
KA(T1  T2 )
Q
l
Paper – 2014
Now,
Qc  QB  QS
K C AC (T1  T2 ) K B A B (T1  T2 ) K S AS (T1  T2 )
= 
LC LB LS
0.92  4(100  T) 0.26  4(T  0) 0.12  4(T  0)
 = 
46 13 12
 200 - 2T = 2T +T
 T = 40C
Hence, rate of heat flow through copper rod is
0.92  4(100  40)
Qc   4.8 cal/s
46
Change in internal energy is given as,

f
U = nRT
2
For diatomic gas molecule, f = 5
For cyclic process U = 0
Process CA:
5
U =  1  R  400  600   U =-500 R
2
Process AB:
5
U =  1  R  800  400   U =+1000 R
2
Process BC:
5
U =  1  R  600  800   U =-500 R
2
Paper – 2014
Let length of the air colunm above mercury in the tube be x.

For the air colunm trapped in tube,
P1 V1  P2V2 ......(1)
P1  Patm  gh  g  76
P2  Patm  g 54  x 
= g  76  g 54  x 
P2 =g  22  x 
V  Area of cross section  length of air colunm

V1  A  8
V2  A  x
Now substituting all these values in eq(1), we get

76g  8A   g 22  x  xA 
 608gA  22gAx  x 2gA (Divide by gA)
 x2  22x  608  0
 x2  22x  38  16   0
Solving this, we get
x =16 cm
x  Acos t  The particle starts from rest 

Displacement in time t is = A - x =A -Acos t
For t =  :
 a =A -Acos 
 a = A 1-cos   ......(1)
For t = 2  + :
 2a+a =A -Acos2
 3a = A 1-cos2  ......(2)
Now, by taking ratio of eq(1) and (2), we get

1-cos  1

1-cos2 3
1-cos  1-cos  1
  

2sin  2 1-cos  3
2 2

Paper – 2014
Let cos   x
1-x 1-x 1
  

2 1-x 2
 21-x 1  x  3
1 1
 
21+x  3
 2  2x  3
1
x  cos 
2
  2  
      
3  T  3
 T  6
Hence,time period of the motion is 6.
From (1);
 1
a = A  1-   A=2a
 2
Hence, amplitude of the motion is 2a.
15. Correct option: (3)
f
2n  1 v
4L
L  85 cm =0.85 m
For frequencies below 1250 Hz
f
2n  1 v  1250 Hz
4L

2n  1340
 1250 Hz
4  0.85
  2n  1  12.5 Hz
 n  6.75
n 6
Number of possible natural oscillations having frequency below 1250 Hz is 6.
Paper – 2014
Potential difference dV = -E.dx

E  30x2 i
dV = -E.dx
VA 2
  dV    30x 2dx
V0 0
2
 x3 
 VA  V0  30  
 3 0
 VA  V0  80 J
E0 
E 
K K0
   EK0
   3  104  2.2  8.85  1012
   6  107 C/m2
Power P = VI
Total power:
P = 15  40  5  100   5  80   1  1000 
 P  VI  2500 W
2500
I  11.36 A
220
Hence, minimum capacity of the main fuse should be 12 A.
Work W
Power  
Time t
2
W   Fext .dx
0
Fext  BIL
1 2
t 0
P Fext .dx
Paper – 2014
1 2
P
t 0
 
3  104 e0.2x 10 3 dx
1
 
2
= 3 0
3  104 e0.2x 10 3 dx
5  10
2
=1.8 e0.2x dx
0
2
 e0.2x 
=1.8   
 0.2  0
=9 1  e0.4 
 P  2.97 W
The coerctivity of 3  103 Am1 of a magnet implies that magnetic intensity H = 3  103 Am1
is required in opposite direction to demagnetise it.
Number of turns per unit length of the solenoid

100
n=  1000 turns m-1
0.1 m
For solenoid
B
=H
0
Now, B = 0nI
H = nI
H 3  103
I=  3 A
n 1000

After changing the switch, the circuit will acts as an L-R discharging circuit.
Applying Kirchhoff’s loop equation in the circuit, we get
VR  VL  0
 VR   VL
VR
  1
VL

During the propagation of electromagnetic waves in a medium, the energy density of both
the electric as well as magnetic field is the same.
Paper – 2014

According to the Lens Maker’s formula
1  1 1 
  n21  1   
f  R1 R2 
When crown glass is kept in air, its focal length is f
1  3/2   1 1   3  2  1 1 
  1        
f  1   R1 R2   2   R1 R 2 
1 1 1 1  1  1 1 1 
     Let   
f 2  R 1 R 2  2R  R R1 R2 
 f  2R ...... (1)
4
When crown glass is kept in liquid with n  , we get
3
1  3/2  1 1  9  1 1 
  1      1  
f1  4/3   R 1 R 2   8   R1 R2 
1 1 1 1  1
   
f1 8  R 1 R 2  8R
f1  8R  4f ...... (2)
5
When crown glass is kept in liquid with n  , we get
3
1  3/2   1 1   9  1 1 
  1      1  
f2  5/3   R 1 R 2   10   R 1 R 2 
1 1  1 1  1
   
f2 10  R 1 R 2  10R
f2  10R  5f ...... (3)
From (1), (2) and (3), we get

f1  f , and f2 becomes negative

We know that, whether the light will refract out to the second medium or totally internally
reflect back in the first medium depends on the critical angle.
Now, critical angle for water to air medium is given as
1
sin c 
n water
We know that, for a light of higher wavelength, i.e., lower frequency the refractive index is
less. This will make c greater for these light rays.
When these light rays travel from water to air, they do not suffer total internal reflection
and refract out in the air medium.
Paper – 2014

The initial intensities of the two beams are IA and IB respectively.
The two beams have mutually perpendicular planes of polarization.
When the Polaroid is rotated through 30, the intensities of both the beams become equal.
If  = 30 for beam A, then  = 60 for beam B.
Then from Malus’ law, we get

3
I'A  IA cos2   IA cos2 30  IA 
4
1
I'B  IB cos2   IB cos2 60  IB 
4
Since I’A = I’B, the ratio is
I'A  I'B
3 1
IA   IB 
4 4
I 1 4 1
 A  
IB 4 3 3

The radius ‘r’ of the path taken by an electron of mass ‘m’ and charge ‘e’ inside a magnetic
field is
mv mv
r 
qB eB
m2v 2  r2e2B2
r2e2B2
mv 2 
m
1 r2e2B2
 mv 2 
2 2m
This energy will be in joules. Hence, energy in eV will be given as
1 2 r2e2B2 1
mv   eV
2 2m e
2 2
r eB
 eV
2m
Therefore, we have
 10  103   1.6  1019  3  104 
2 2
1
mv 
2
2 2  9.1  1031
1 1.44  1030
 mv 2   0.79 eV
2 1.82  1030
The transition of electron is between 3 → 2 states
Paper – 2014
Thus, we have
1 1 1 1 5
E  13.6  2  2   13.6     13.6   1.89 eV
2 3   4 9 36
Thus, the work function of the metal will be
  1.89 eV  0.79 eV  1.1 eV

The spectral formula is given as
1 1 1 
 Rz2  2  2 
 p n 
p  1 and n  2
1 1 1
  Rz2  2  2 
 1 2 
1 3
  Rz2
 4
Now, for Hydrogen 1H1, we have
1 3 3
1
 
 R 12  R
4 4
For Deuterium 1H2, we have
1 3 3 1
2
 
 R 12  R 
4 4 1
2  1
For Helium 2He4, we have
1 3 3 4
3
 
 R 22  R  4 
4 4 1
1  43
For Lithium 3Li6, we have
1 3 3 9
4
 
 R 32  R  9 
4 4 1
1  9 4
Therefore, we have
1  2  43  94

A diode is said to be forward biased when the positive side (p) is at a higher potential than
the negative side (n).
Paper – 2014
List I List II
(a) Infrared waves (i) To treat muscular strain
(b) Radio waves (ii) For broadcasting
(c) X-rays (iii) To detect fracture of bones
Absorbed by the ozone layer of the
(d) Ultraviolet rays (iv)
atmosphere
30. Correct option (B)

The student measures the value as 3.50 cm. This indicates that there is an uncertainty in
the second digit after the decimal point.
Hence, the least count of the instrument should be 0.01 cm = 0.1 mm.
A meter scale has a least count of 1 mm. Hence, the instrument cannot be a meter scale.
Least count of a vernier calliper is calculated as

L.C  one main scale division  One vernier scale division
Now, for the given vernier calliper there are 10 divisions in 1 cm on the main scale.
Hence, one main scale division is 1 mm
Now, 10 divisions on the vernier scale coincide with 9 divisions on the main scale. Thus, 10
divisions on vernier scale correspond to 9 mm.
Thus, one vernier scale division is 9/10 = 0.9 mm
Hence, the least count of the vernier calliper is

L.C  1 mm  0.9 mm
 0.1 mm
 0.01 cm
Least count of a screw gauge is

Pitch
L.C 
Number of divisions on the circular scale
Hence, for a screw gauge with pitch 1 mm and 100 divisions, we have
1 mm
L.C   0.01 mm
100
And, for a screw gauge with pitch 1 mm and 50 divisions, we have
1 mm
L.C   0.02 mm
50
Hence, the instrument has to be a vernier calliper.
Paper – 2014
PART–B : CHEMISTRY

Z = 37
Rb is in fifth period.
Electronic configuration: 1s22s22p63s23p63d104s24p65s1
So last electron enters 5s orbital
Hence n = 5, l = 0, m = 0, s = + 1/2 -1/2

PV
Compressibility factor (Z)
RT
(For one mole of real gas)
van der Waal equation is given by,
 
 P+ a   v -b = RT
 2 
 V 
At low pressure; V – b  V
 a 
 P+  V = RT

 V2 
a
PV + =RT
V
a
PV = RT -
V
PV a
=1-
RT VRT
a
Therefore, Z = 1 -
VRT

In CsCl, Cl- lies at corners of simple cube and Cs+ at the body centre.
Hence, along the body diagonal, Cs+ and Cl- touch each other so,
2r - +2rcs + = 3 a
CI
3a
r - +rcs + =
CI 2
Paper – 2014

As per the question.
Normality Volume
H2SO4 N 60mL
5
NaOH N 20mL
10
Mass of organic compound is = 1.4 g

 ngeq H SO4 =  ngeq NaOH +  ngeq NH
2 3
1 60
x
1
= x
20
5 1000 10 1000
+ ngeq
NH  
3
6
=
1
500 500
+ ngeq
NH  
3
ngeq =
5
=
NH3 500 100
1
 nmol N =  nmol NH3 =  ngeq NH3 = 100

1
14
(Mass)N = = 0.14 g
100
0.14
Percentage of 'N' = x 100 = 10%
1.4
Paper – 2014

For 0.2 M solution,
R = 50 
 = 1.4 S m–1 = 1.4 × 10–2 S cm–1
1 1
ρ= = Ω cm
ς 1.4x10-2
l
Now, R = ρ
a
l R
 = = 50 x 1.4 x10-2
ς ρ
For 0.5 M solution,
R = 280 
= ?
l
= 50 x 1.4 x10-2
a
l
R =ρ
a
1 1 l
 x x
ρ R a
1
ς= x 50 x 1.4 x 10-2
280
1
= x 70 x 10-2
280
= 2.5 x 10-3 S cm-1
ς x 1000
Νow, λ m =
M
2.5 x 10-3 x 1000
=
0.5
= 5 S cm mol-1
2
= 5 x 10-4 S m2 mol-1
Paper – 2014

C2H OH + 3O2  2CO2 + 3H2O
5 (l) (g) (g) (l)
Bomb calorimeter gives  U of the reaction. Hence, as per the question,
 U = - 1364.47 kJ mol-1
 ng = -1
 H =  U +  ngRT
1 x 8.314 x 298
= -1364.47 -
1000
= - 1366.93 kJ mol-1

According to Debye Huckle onsager equation,
λc = λ  - A C
Here, A = B
Therefore, λc = λ  - B C

π = i CRT
πC2H OH = 1 x 0.500 x R x T = 0.5 RT
5
πMg3(PO4 )2 = 5 x 0.100 x R x T = 0.5 RT
πKBr = 2 x 0.250 x R x T = 0.5 RT

πNa PO = 4 x 0.125 x R x T = 0.5 RT
3 4

1
SO2 + O2 SO3
(g) 2 (g) (g)
Kp = KC (RT)X
X = Δng = no. of gaseous moles in product – no. of gaseous moles in reactant
 1 3 -1
= 1-  1+  = 1- =
 2 2 2
Paper – 2014

2A + B  C + D
-1 d[A] d[B]
Rate of Reaction  =-
2 dt dt
d[C] d[D]
 =
dt dt
Let rate of Reaction = k[A]x[B]y
d[C] y
Or = k[A]x [B]
dt
Now from table,
1.2 × 10–3 = k [0.1]x[0.1]y ...(i)
1.2 × 10–3 = k [0.1] [0.2]
x y ...(ii)
2.4 × 10–3 = k [0.2] [0.1]
x y ...(iii)
Dividing equation (i) by (ii)

y
1.2 x 10-3 k[0.1]x [0.1]
 = x y
1.2 x 10-3 k[0.1] [0.2]
y
1 
 1=  
2
 y=0
Now dividing equation (i) by (iii)
y
1.2 x 10-3 k[0.1]x [0.1]
 = x y
2.4 x 10-3 k[0.2] [0.1]
-1 x
1  1 
  = 
2 2
 x =1
d[C]
Hence = k[A]1[B]0.
dt
Paper – 2014

Decreasing order of strength of oxoacids:
HClO4> HClO3> HClO2> HOCl
The given acids will get ionised as follows:
HClO4 ⇆ ClO4- + H+
HOCl ⇆ ClO- + H+
The structures of conjugate bases are as follows:
The resonance structure for ClO4- is as follows:
From the above resonating structures, negative charge is more delocalized on ClO4- due to
resonanace.
The resonanace stability order of conjuhate base is,
ClO4- > ClO3- > ClO2- > ClO-
Therefore, the acidic strength oreder is,
HClO4 > HClO3 > HClO2 > HOCl
Paper – 2014

Only Ca2+ can not be dischrged as Ca at cathode on electrolysis as in Ca2+ case, H2 gas
gets discharged at cathode.
This is due to the fact that, higher the position of element in the electrochemical series,
more difficult is the reduction of its cations. If Ca2+ is electrolysed then water is reduced
in preference to it. Therefore, Ca2+ can not be reduced electrolytically from an aqueous
solutions.
The chemical equations for cathode are as follows:
In case of Ag2+
At cathode: Ag2+ + e-→ Ag
In case of Ca2+
At cathode: H2O + e-→ ½ H2 + OH-
In case of Cu2+
At cathode: Cu2+ + 2e-→ Cu
In case of Cr3+
At cathode: Cr3+ + 2e-→ Cr

Given:
Ligands L1 L2 L3 L4
Wavelength Red Green Yellow Blue
(λ) absorbed
region
Now,
Increase in the order of energy of wavelengths absorbed reflect in the greater extent of
crystal-field splitting which in turn reflect into higher field strength of the ligand.
The order of energy of the different regions are as follows:
Red(L1)< Orange< Yellow(L3)< Green(L2)< Blue(L4)< Violet
The ligand which absorb lower energy light has lower strength.
Therefore, the order for the strength of ligand is as follows:
L1<L3< L2< L4
Paper – 2014

Nitric oxide (NO) is paramagnetic in gaseous state. The electronic configuration of NO is
as follows:
σ1s2σ1s*2σ2s 2σ2s *2σ2pz 2σ2pz*2π2px2 = π2py2 π2px*1
NO is paramagnetic since it has one unpaired electron in its outermost shell.

Reducing agent gets oxidised itself by releasing electrons.
The oxidation number of oxygen in the reactants and product are shown as a power in
brackets in the given following reactions:
(a) H2O2(-1) + 2H+ +2e- → 2H2O(-2)
(0)
(b) H2O2(-1) – 2e- → O 2 + 2H+
(-2)
(c) H2O2(-1) + 2e- → 2 O H-
(0)
(d) H2O2(-1) + 2OH- - 2e- → O 2 + 2H2O
From the oxidation numbers of oxygen in the above reactions, H2O2 acts as reducing
agent in (b) and (d) reactions where oxidation number of oxygen shifts to positive side.

It is a fact that CsI3 contains one Cs+ ion and I3- ions.

The mass ratio of O2 to N2 is given as 1:4.
Let the mass of O2 = x
Hence, the mass of N2 = 4x
x
Number of moles of O2 =
32
4x x
Number of moles of N2 = 
28 7
x x
Now, ratio of moles of O2 to N2 = : = 7:32
32 7
Therefore, the ratio of number of molecules of O 2 to N2 = 7:32
Paper – 2014

Mn2+ +2e-  Mn E 0   1.18 V
2(Mn3+ + e-  Mn 2+ ) E 0   1.51V
Mn3+ 
+1.51V
 Mn 2+ 
-1.18V
 Mn
Therefore, for 3Mn 2+  Mn +2Mn3+
E 0 for Mn2+ disproportionation   1.18 V-(  1.51V)
= - 2.69 V
Since -2.69 V < 0, reaction is non-spontaneous.

The correct option (option 4) is as follows:
Fe 
O2
Heat
 Fe3O4 
CO
6000C
 FeO 
CO
7000C
 Fe is a correct series of reaction.
Fe 
O2
Heat
 Fe3O4 is a combustion reaction of Fe.
Fe3O4 
CO
6000C
 FeO 
CO
7000C
 Fe
This series of reactions correspond to the production of Fe by reduction of Fe 3O4.
The other options are as follows:

(1) Fe + H2SO4 → FeSO4 + H2,
2FeSO4 + H2SO4 + ½ O2 →Fe2(SO4)3 +H2O

Fe2(SO4)3   Fe2O3(s) + 3SO3  (This reaction is given incorrectly).
(2) Fe 
O2

 FeO (The products can be Fe2O3 or Fe3O4)
FeO 
dil. H2SO4
 FeSO4 + H2O

2FeSO4   Fe2O3 + SO2 + SO3

(3) Fe 
Cl2
 FeCl3 
ir
 no reaction (it cannot give FeCl2)
Paper – 2014

Option (1) Li2O + 2KCl → 2LiCl + K2O
The compound K2O cannot be generated.
Option (2) [CoCl(NH3)5]++5H+→ Co2+ + 5NH4+ + Cl-

This is a correct option. The complex [CoCl(NH3)5]+ decomposes under acidic medium.
All ammine complexes can be decomposed by adding H+.
Option (3) [Mg(H2O)6]2+ + (EDTA)4- 

excess NaOH
[Mg(EDTA)]2+ + 6H2O
The formula of the complex in the product must be [Mg(EDTA)] 2-
Option (4) CuSO4 + 4KCN → K2[Cu(CN)4] + K2SO4

It is an incorrect option. The correctly balanced reaction is as follows:
2CuSO4 + 10 KCN → 2 K3[Cu(CN)4] + 2K2SO4 + (CN)2
51. Correct option: ( 2)

In SN2, the order of reactivity depends on the stearic hindrance.
So as the stearic hindrance around the electrophilic carbon increases in the order CH 3X
> 10>20>30. Thus the order of reactivity in SN2 reactions is: CH3Cl > (CH3)CH2– Cl >
(CH3)2CH – Cl > (CH3)3CCl

When aliphatic primary amine is treated with chloroform and ethanolic potassium
hydroxide alkyl isocyanide is obtained.
R – NH2 + CHCl3 R– CH2– NC

Pyridinium chlorochromate is the mild oxidising agent and converts the alcohol to
aldehyde.
R – CH2 - OH  R-CHO
2-Butyne
Paper – 2014

In aliphatic amines, the order of basic strength in aqueous solution is as follows:
Since pKb = - log Kb
So (CH3)2NH will have smallest pKb value.

In quinol and thioquinol, the –OH and –SH groups do not cancellise their dipole moment
because they exist in different conformations.
Same as in thioquinol.
Paper – 2014

Dacron is a condensation polymer of ethylene glycol and terepthalic acid.

Quinoline is an alkaloid. DNA contains ATGC bases Adenine, Thymine, Guanine and
Cytocine.
PART–C : MATHEMATICS
61.Correct Option: (2)
Let us rewrite the given equation as

X 1  3 n

 3n  1,n  N
 
 32 n
 
C2  n C3  ...  3n2 ,n  N expanding by binomial expansion
 Divisible by 9
Now let us consider the set Y
Given that
Y=9 n  1 ,n  N
 All multiples of 9
Thus, X  Y
 X  Y=Y
Paper – 2014
We know that z1  z2  z1  z2
1
Now consider z+
2
1 1
z   z+
2 2
1 1
 z+  2
2 2
3
 zmin 
2
 Minimum value lies in the interval 1,2 
3  x  x   2  x  x   a2  0

2
 2 

 
 3  x2  x   a2
3 
2
 1 1
 3  x     a2
 3 3
1 1 2
 0  x  1 and   x  
3 3 3
2
 1 4
 0  3  x   
 3 3
2
1  1 1
  3  x     1
3  3 3
For non-interval solution 0<a2  1 and a   1,0   0,1
Paper – 2014
From the given quadratic equation, we have

q r
+= ;  
p p
Given p,q,r in A.P.
 2q=p+r....(1)
Also, given that
1 1
 4
 

 4

q
p
 4
r
p
q
 4
r
 q  4r and p=  9r
  
2
   4
2
 q  r
     4
 p  p
q2  4pr
  
p
16r2  36r2 2 13
   
9r 9
Paper – 2014
Consider the determinant

3 1+f 1 1+f 2 
1+f 1 1+f 2  1+f 3
1+f 2  1+f 3 1+f  4 
1+1+1 1++ 1+2 +2
 1++ 1+2 +2 1+3+3
1+2 +2 1+3+3 1+ 4 +4
1 1 1 1  2
   1  1  2
2 2 1 1 1 1
 1    1         
2 2 2
 
Equating this with the given equation,
we have K=1

BB '  B A 1  A ' '  since B  A 1  A '

 A 1  A '   A 1

 A' '
 A 1  A '  A ' ' A 1  '

 A 1  A ' A  A 1 '  
 
 A 1  A  A ' A 1 ' sin ce A'  A=A  A'
 
 A 1  A   A ' A 1 '
   

 I  A ' A 1 ' 
 A '  A '
1
I
Paper – 2014
1  ax  bx  1  2x 
2 18
 1  ax  bx   C  C1 2x   C2 2x   C3 2x   C4 2x   ... 

2 18 18 18 2 18 3 18 4
0
Therefore, coefficient of x3
  18 C3  23  a  18
C2  22  2b 18 C1  0
18  17  16 4a  18  17
 8  36b  0
6 2
 51  16  8  a  36  17  36b  0
 6528  a  36  17  36b  0
 51a  3b  544
By checking the options it is clear that,
option (2) satisfies the above equation.
Let s= 10   2  11  10   3  11  10   ...  10 11  k 10  ,

9 1 8 2 7 9 9
11
x  11  108  2  11 10   3  11  10   ...  9 11  1110
2 7 3 6 9
10
Subtracting the above two equations, we have
 11 
1  10  x  10   11  10   11  10   ...  11  11
9 1 8 2 7 9 10
 
  11  
10
109 1    
1 
  10   Sum of n terms in 
 11
10
 x  
10 11 Geometric progression
1
10
 
1
x  109

1010  1110

10
 11
10 
10
10 10 1
1
  x  1010  1110  1110
10
1
  x  1010
10
 x  1011
Given that 1011  k 10 
9
Thus, we have
k=100
Paper – 2014
Let a, ar and ar2 be three positive integers in a G.P.
Now consider the middle term, which is ar

Given that the middle term is doubled.
Therefore, the new middle term is 2ar,
Hence the three terms, a, 2ar and ar2 form an AP
 4ar=a+ar2
 4r  1  r 2
 r2  4r  1  0
42 3
r 
2
 r  2  3 or r  2  3
Since r>1, GP is increasing, we have r  2  3
We need to evaluate the expression lim


sin  cos2 x 
2
x 0 x
lim

sin  cos2 x   lim sin   1  sin x   2
2
x 0 x x 0 x2
 lim

sin    sin2 x 
2
x 0 x
 lim

sin  sin2 x   sin       sin  
2
x 0 x
 lim

sin  sin2 x    sin 2
x
2 2
x 0  sin x x
 lim

sin  sin x 2
  lim  sin 2
x
2 2
x 0  sin x x 0 x
  lim

sin  sin x 2
  lim sin 2
x
2 2
x 0  sin x x 0 x
  lim

sin  sin x 2
  lim  sin x  2
 sin2 x  x 
x 0 x 0
 
 sin  
   1  12  lim  1
 0  

Paper – 2014
71. Correct Option: (2)
Since g(x) is the inverse of f(x),
1
g '  f ( x)  
f '( x)
1
 g '  f ( x)    1  x5
1
1  x5
Assuming x  g ( y)
 g '( y )  1   g ( y )
5
 g '( x)  1   g ( x)
5
Consider
f  x   2g  x   h  x 
Since f and g are continuous and differentiable in 0,1
h  x  is also continuous and differentiable.
Also we have
h  0   f 0   2g 0   2  0  2
and
h 1  f 1  2g 1  6  2  2  2
Thus, h  x  satisfies the conditions of Rolles Theorem in  0,1
Using Rolle's Theorem,
f (1)  f (0) 6  2
f '(c)   4
1 0 1 0
g (1)  g (0) 2  0
g '(c)   2
1 0 1 0
Hence, f '(c)  2 g '(c)
Paper – 2014
Given,
f ( x)   log x   x 2  x

 f '( x)   2 x  1  0 at x  1, 2
x
Hence, at x  1 ,
  2  1  0
   2  1 -----Equation 1
And at x  2 ,

 4  1  0
2
   8  2 -----Equation 2
Solving equations 1 and 2, we get
1
  2,   
2
Paper – 2014

1
x
Let f  x   e x
 1
1  x  x 
f '( x)  (1  )e
x2
 1
 1   x+ 
Let I=  1+x  e x dx
 x
Rewrite the given integrand as:
 1  1  1
 1   x+ x   x+  1  x+ 
1+x   e = e x  +x(1  2 )e x 
 x x
Thus, we have,

 1
1   x+ x    x+1x  1  x+ x  
 1
  1+x 
x
e dx =   e  
+x(1 
x 2
)e dx
 
We know that   xf'(x)+f(x)dx = xf(x)+c
Thus,
  x+1x  1  x+ x  
 1
x+
1
I =  e  
+x(1  2 )e dx = xe x +c
 x 


x x

0
1  4sin 2
2
 4sin dx
2

x
  2sin  1 dx
0
2

3 
x x
 
0
(1  2sin )dx   (2sin  1) dx
2  2
3
 
 x 3  x 
  x  4 cos    4 cos  x 
 2 0  2  3
 4 3  3 
   4   0    4  
3 2  2 3 

 4 3 4
3
Paper – 2014
x2  y 2  1 and y 2  1  x intersect at x  0,1
Area of the shaded region =Area of semi-circle plus area bounded by parabola and y-axis
 (1)2 1
Area of the shaded region =   ydx
2 1
Since y2  1  x  y   1  x
Thus, we have,
 (1) 2 1
Area    (1  x)dx
2 1
 (1) 2 1
  2 (1  x)dx  the parabola is symmetric about x-axis 
2 0
1
  2(1  x) 3 2 
  (1) 
2  3 
 2 0
 4
  (0  (1))
2 3
 4
 
2 3
Paper – 2014
Given,
Given equation is:

1
p '(t ) p (t )  200
2
Rewriting the above equation, we have
1
p '(t )  p(t )  200....(1)
2
This is a linear differential equation of the form
dy
 Py  Q, where P and Q are functions of x.
dx
1
From equation (1), we have, P   and Q  200
2
1
The integrating factor I.F.  e 
Pdt  t
2
=e
Hence,
The solution is of the form,
ye    Q e 
Pdx Pdx
dx  c
Thus, we have,
1 1
 t t  t
p(t )e 2
  200e 2
dt  400e 2
c
t
 p(t )  400  ce 2
Since, p (0) = 100,
=>100 = 400 + c
 C = -300
t
 Hence, p(t )  400  300e 2
Paper – 2014
S is the mid-point of QR.
 7  6 3  1   13 
Hence, S =  ,    ,1
 2 2  2 
2 1 2
Slope of PS = 
13 9
2
2
Equation of the line passing through (1,-1) and parallel to PS is
2
y  (1)   ( x  1)
9
 9 y  9  2 x  2
 2x  9 y  7  0
The point of intersection of the lines 4ax  2ay  c  0 and 5bx  2by  d  0 is given by
x 4 1
 
2ad  2bc 4ad  5bc 8ab  10ab
2(ad  bc)
x
2ab
5bc  4ad
y
2ab
As the point of intersection is in the fourth quadrant, x is positive and y is negative. Also
the distance from the axes is same.
Hence, x = -y
2(ad  bc) (5bc  4ad )


2ab 2ab
 2ad  2bc  5bc  4ad
 3bc  2ad  0
Paper – 2014
Let us rewrite the given equation of the ellipse.
x2  3y2  6
x2 3y2 6
  
6 6 6
2 2
x y
  1
6 2
Now compare the above equation with the
x2 y2
general equation of the ellipse  1
a2 b2
 a2  6;b2  2
Equation of a line through (h, k) & perpendicular to line joining it to origin is
h
( y  k)  ( x  h)
k
h h2  k 2
y x
k k
Since the above line is tangent to the ellipse,
it should satisfy the following condition.
C2  a 2 m2  b 2
Substituting the values of C, a 2 , m and b 2 , we have
2
 h2  k 2  h2
   6 2
 k  k2
  x2  y 2   6 x2  2 y 2
2
Paper – 2014
P  ( x  1) 2  ( y  1) 2  1
Radius of M= y
M touches P externally
(0-1) 2  ( y  1) 2  (1  y ) 2
 1 y2 1 2 y  1 y2  2 y
If y > 0,
y2  2  2 y  1  y 2  2 y
 4y 1
1
y
4
If y < 0,
y2  2  2 y  1  y 2  2 y
1 2
Which is not possible
1
y 
4
Paper – 2014

1
Let the equation of the tangent to y 2  4 x be y=mx+
m
The above tangent is also a tangent to x 2  32 y
x 2  32 y
 1
 x 2  32  mx+ 
 m
32
 x 2  32mx  0
m
Since roots are equal, the discriminant is zero.
Thus,
32
D  0   32m   4  0
2
m
 32m3  4
1
 m3 
8
1
m
2
Paper – 2014
Let B'  a,b,c  be the image of the point B 1,3,4 

The direction ratios of the line BB' is
a 1 b  3 c  4
  
2 1 1
Any point on the line BB' is of the form
 a=2  1, b  3   , c  4  
Let P  x,y,z  mid point of the line BB'.
 2  1  1 3    3 4    4 
Thus, P   , , 
 2 2 2 
  
 P     1,3  , 4  
 2 2
Since the point P lies in the plane, 2x  y  z  3  0, we have
   
2    1   3     4    3  0
 2  2
 
2  2  3  4 3 0
2 2
3  6  0
   2
Substituting the value of  in
a 1 b  3 c  4
  
2 1 1
we have
a  3, b  5, c  2
Hence the equation of the required line is
x 3 y 5 z 2
 
3 1 5
Paper – 2014
l  m  n  0..................(i )
l 2  m 2  n 2 ....................(ii )
 l 2  m 2  (l  m) 2  0
 2m( m  l )  0
m  0 or l  m
So direction ratios are  -1, 0, 1 and  -1, 1, 0 
 a1a2  b1b2  c1c2 
 cos    
 a b2 c 2 a 2 b 2 c 2
2 
 1 1 1 2 2 2 
1 0  0 1
 cos   
2 2 2

 
3
LHS = a  b b  c c  a 
  p b  c c  a  
where p  a  b 
   . c  a 
 p b  c
  p.c  b   p.b  c .  c  a 
 a b c  b  a b c  c .  c  a  
where p  a  b 
 a b c   b c a   0  a b b 0 
 
2
 a b c  b c a a b c
2
RHS   a b c 
  1
Paper – 2014
1 1 5
P( A  B)   P( A  B)  1  
6 6 6
1 1 3
P( A)   P( A)  1  
4 4 4
Now, P( A  B)  P( A)  P( B)  P( A  B)
5 3 1
   P( B) 
6 4 4
5 3 1 1
 P( B)    
6 4 4 3
Thus, we observe that P( A)  P( B) .
Hence, events A and B are not equally likely.
3 1 1
Also, P( A)  P( B)     P( A  B)
4 3 4
Thus, events A and B are independent.
Solution:
Variance,  2

 x   x
2
i
2
N
22  42  62  ..........  100 2  2  4  6  ......  100 
2
  2
 
50  50 
50
4(12  22  32  ..........  502 2 
 2  100 
 
50 50
 50  (50  1)  (2  50  1) 
 
   51
 4 6 2
 50 
 
 50  51101 
 4    51
2
 50  6 
 3434  2601
 2  833
Paper – 2014
Solution:
f k ( x) 
1
k
 sin k x  cos k x 
f 4 ( x)  f 6 ( x)   sin 4 x  cos 4 x    sin 6 x  cos 6 x 

1 1
4 6
 1  2sin 2 x cos 2 x   1  3sin 2 x cos 2 x 
1 1
4 6
1 1 1 1
  sin 2 x cos 2 x   sin 2 x cos 2 x
4 2 6 2
1 1
 
4 6
1

12
t = 1 second
From the figure, we have
20 20
tan 45o  1  a  20
a a
20 1 20
and tan 30o   
ab 3 20  b
 b  20  3 1 
i.e. Speed  20  
3 1 m / s
Paper – 2014
p q q p q ( p  q) pq
F F T F T T
F T F T F F
T F T T F F
T T F F T T
Thus, p q  is equivalent to p  q

IITJEE (MAIN) - 2014 (Physics, Chemistry and Mathematics) Code - E Solutions Part-A: Physics 1. Correct Option

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IITJEE (MAIN) - 2014 (Physics, Chemistry and Mathematics) Code - E Solutions Part-A: Physics 1. Correct Option

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IITJEE MAIN | PHYSICS, CHEMISTRY AND MATHEMATICS

IITJEE (MAIN) – 2014

1. Correct option (1)

2. Correct option (3)

H is the height of the tower.

3. Correct Option (2)

4. Correct option (1)

where  is the coefficient of friction = 0.5

5. Correct option (3)

6. Correct option (3)

7. Correct option (4)

8. Correct option (1)

9. Correct option (3)

On equating the pressure at A from both L.HS and R.H.S, we get

10. Correct option- No option matches the correct answer

Buoyant force ≥ Surface Tension Force

11. Correct option (3)

12. Correct option (4)

Change in internal energy is given as,

13. Correct option (1)

Let length of the air colunm above mercury in the tube be x.

V  Area of cross section  length of air colunm

Now substituting all these values in eq(1), we get

14. Correct option (4)

x  Acos t  The particle starts from rest 

Now, by taking ratio of eq(1) and (2), we get

15. Correct option: (3)

16. Correct option (3)

Potential difference dV = -E.dx

17. Correct option (1)

18. Correct option (3)

19. Correct option (2)

20. Correct option (3)

Number of turns per unit length of the solenoid

21. Correct option (3)

22. Correct option (3)

23. Correct option (2)

From (1), (2) and (3), we get

24. Correct option (2)

25. Correct option (4)

Then from Malus’ law, we get

26. Correct option (2)

The transition of electron is between 3 → 2 states

27. Correct option (3)

28. Correct option (1)

29. Correct option (4)

30. Correct option (B)

Least count of a vernier calliper is calculated as

Thus, one vernier scale division is 9/10 = 0.9 mm

Hence, the least count of the vernier calliper is

Least count of a screw gauge is

31. Correct option: (1)

32. Correct option: (2)

33. Correct option (3)

34. Correct option: (2)

Mass of organic compound is = 1.4 g

 nmol N =  nmol NH3 =  ngeq NH3 = 100

35. Correct option: (1)

36. Correct option: (1)

37. Correct option: (3)

38. Correct option: (1)

πKBr = 2 x 0.250 x R x T = 0.5 RT