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n-Ethanol - Acetone n-Ethanol - Acetic Acid

Mole Mole
Excess
fraction Temperat Pressure fraction Temperat
No. enthalpy No.
ETHAN- ure (K) (N/sqm) ETHAN- ure (K)
(J/kmol)
01 01

7 0.5271 298.1444 101325 1108170 1 0.0288 298.1444


8 0.457 298.1444 101325 1110110 2 0.0655 298.1444
9 0.3544 298.1444 101325 1040480 3 0.1042 298.1444
10 0.2381 298.1444 101325 850410 4 0.1426 298.1444
11 0.14 298.1444 101325 583070 5 0.1844 298.1444
12 0.0683 298.1444 101325 316390 6 0.2381 298.1444
13 0.9519 323.1371 101325 237710 7 0.3042 298.1444
14 0.8968 323.1371 101325 477090 8 0.4103 298.1444
15 0.8017 323.1371 101325 799280 9 0.5085 298.1444
16 0.7009 323.1371 101325 1038710 10 0.608 298.1444
17 0.6175 323.1371 101325 1166150 11 0.7123 298.1444
18 0.5955 323.1371 101325 1196430 12 0.812 298.1444
19 0.5346 323.1371 101325 1226430 13 0.8864 298.1444
20 0.483 323.1371 101325 1235910 14 0.9423 298.1444
21 0.3901 323.1371 101325 1184480 enthalpies of (an alkanol + a
carboxylic acid) at 298.15 K
22 0.2891 323.1371 101325 1037550 measured with a Picker
23 0.196 323.1371 101325 806100 calorimeter
24 0.0932 323.1371 101325 439920
25 Nicolaides,
0.049 323.1371
G. L.; Eckert,101325
C. A. J. 244760
Chem. Eng. Data, 1978, 23,
152-6 Experimental heats of
mixing of some miscible and
partially miscible
nonelectrolyte systems
anol - Acetic Acid n-Ethanol - dipropylamine Methanol -
Liquid Vapor
Excess mole mole Total
Pressure Temperat
enthalpy No. fraction fraction pressure No.
(N/sqm) ure (K)
(J/kmol) ETHAN- ETHAN- (N/sqm)
01 01

101300 99860
101300 186270
101300 244020
101300 308250
101300 336550
101300 352950
101300 350730
101300 302900
101300 239780
101300 156210
101300 80960
101300 44620
101300 23020
101300 10840
ies of (an alkanol + a
ylic acid) at 298.15 K
ured with a Picker
calorimeter
Methanol - dipropylamine Methanol - butylamine
Liquid Vapor
Mole
mole mole Total Excess
Temperat fraction Temperat Pressure
fraction fraction pressure No. enthalpy
ure (K) METHAN ure (K) (N/sqm)
METHA- METHA- (N/sqm) (J/kmol)
OL
01 01

7 0.817 293.1454 101000 -2539690


8 0.78 293.1454 101000 -2920430
9 0.748 293.1454 101000 -3146370
10 0.659 293.1454 101000 -3732130
11 0.584 293.1454 101000 -3970620
12 0.512 293.1454 101000 -3974800
13 0.433 293.1454 101000 -3686100
14 0.35 293.1454 101000 -3242600
15 0.258 293.1454 101000 -2543870
16 0.17 293.1454 101000 -1757280
17 0.092 293.1454 101000 -987420
18 0.026 293.1454 101000 -315474
1 0.026 293.1454 101325 -315500
2 0.092 293.1454 101325 -987000
3 0.17 293.1454 101325 -1757000
4 0.258 293.1454 101325 -2544000
5 0.35 293.1454 101325 -3243000
6 0.433 293.1454 101325 -3686000
7 0.512 293.1454 101325 -3975000
8 0.584 293.1454 101325 -3971000
9 0.659 293.1454 101325 -3732000
10 0.748 293.1454 101325 -3146000
11 0.78 293.1454 101325 -2920000
12 0.817 293.1454 101325 -2540000
13 0.852 293.1454 101325 -2113000
14 0.884 293.1454 101325 -1715000
15 0.911 293.1454 101325 -1326000
16 0.938 293.1454 101325 -950000
17 0.965 293.1454 101325 -506000
18 0.99 293.1454 101325 -152700
2 0.199 298.1444 101325 -1900000
3 0.207 298.1444 101325 -2023900
4 0.244 298.1444 101325 -2383500
6 0.284 298.1444 101325 -2535000
7 0.358 298.1444 101325 -3239500
9 0.391 298.1444 101325 -3353400
10 0.445 298.1444 101325 -3587800
11 0.469 298.1444 101325 -3675300
12 0.508 298.1444 101325 -3711700
17 0.804 298.1444 101325 -2522500
19 0.9 298.1444 101325 -1278400
1 0.1883 298.1444 101325 -1949800
2 0.2043 298.1444 101325 -2028400
3 0.2929 298.1444 101325 -2861300
4 0.3399 298.1444 101325 -3122600
5 0.4329 298.1444 101325 -3666600
6 0.4746 298.1444 101325 -3806600
7 0.5411 298.1444 101325 -3860300
8 0.6402 298.1444 101325 -3765000
9 0.7348 298.1444 101325 -3270000
10 0.8205 298.1444 101325 -2471500
11 0.87 298.1444 101325 -1904000
12 0.9242 298.1444 101325 -1230200
1 0.58 298.1444 101000 -3888600
2 0.606 298.1444 101000 -3866000
3 0.63 298.1444 101000 -3845900
4 0.679 298.1444 101000 -3642600
5 0.729 298.1444 101000 -3360200
6 0.753 298.1444 101000 -3134600
7 0.787 298.1444 101000 -2680300
8 0.822 298.1444 101000 -2237200
9 0.856 298.1444 101000 -1870700
10 0.873 298.1444 101000 -1675700
11 0.927 298.1444 101000 -943900
12 0.963 298.1444 101000 -434300
13 0.064 298.1444 101000 -468200
14 0.162 298.1444 101000 -1366100
15 0.21 298.1444 101000 -1712100
16 0.254 298.1444 101000 -2061500
17 0.293 298.1444 101000 -2317500
18 0.328 298.1444 101000 -2548100
19 0.367 298.1444 101000 -2919600
20 0.401 298.1444 101000 -3188600
21 0.433 298.1444 101000 -3396600
22 0.479 298.1444 101000 -3646400
23 0.517 298.1444 101000 -3837100
24 0.55 298.1444 101000 -3859700
1 0.1506 298.1444 101325 -1586700
2 0.218 298.1444 101325 -2132400
3 0.2915 298.1444 101325 -2782400
4 0.3555 298.1444 101325 -3185800
5 0.4469 298.1444 101325 -3717600
6 0.5433 298.1444 101325 -3901000
7 0.6337 298.1444 101325 -3758900
8 0.725 298.1444 101325 -3390800
9 0.7785 298.1444 101325 -2915800
10 0.814 298.1444 101325 -2556300
11 0.834 298.1444 101325 -2093200
12 0.8627 298.1444 101325 -1981000
13 0.8938 298.1444 101325 -1393600
14 0.9259 298.1444 101325 -909700
1 0.064 298.1444 101325 -468000
2 0.162 298.1444 101325 -1366000
3 0.21 298.1444 101325 -1712000
4 0.254 298.1444 101325 -2062000
5 0.293 298.1444 101325 -2318000
6 0.328 298.1444 101325 -2548000
7 0.367 298.1444 101325 -2920000
8 0.401 298.1444 101325 -3189000
9 0.433 298.1444 101325 -3397000
10 0.479 298.1444 101325 -3646000
11 0.517 298.1444 101325 -3837000
12 0.55 298.1444 101325 -3860000
13 0.58 298.1444 101325 -3889000
14 0.606 298.1444 101325 -3866000
15 0.63 298.1444 101325 -3846000
16 0.679 298.1444 101325 -3643000
17 0.729 298.1444 101325 -3360000
18 0.753 298.1444 101325 -3135000
19 0.787 298.1444 101325 -2680000
20 0.822 298.1444 101325 -2237000
21 0.856 298.1444 101325 -1871000
22 0.873 298.1444 101325 -1676000
23 0.927 298.1444 101325 -944000
26 0.963 298.1444 101325 -434000

Nakanishi, K.; Touhara, H.; Watanabe, N. Bull. C


Ratkovics, F.; laszlo, A. Magy. Kem. Foly., 1973,
Ratkovics, F.; Laszlo-Parragi, M. Acta Chim. Aca
Dutta-Choudhury, M. K.; Mathur, H. B. J. Chem
Dutta-Choudhury, M. K.; Mathur, H. B. Indian J
Mato, F.; Berrueta, J. An. Quim., 1978, 74, 1290
Pradhan, S. D.; Mathur, H. B. Proc. Indian Acad
Christensen, C.; Gmehling, J.; Rasmussen, P.; W
Methanol - tert-butylamine Methanol - diethylamine

Mole Mole
Excess
fraction Temperat Pressure fraction Temperat
No. enthalpy No.
METHA- ure (K) (N/sqm) METHA- ure (K)
(J/kmol)
01 01

7 0.1982 298.1444 101325 -2392900 10 0.556 298.1444


8 0.26 298.1444 101325 -2952900 11 0.598 298.1444
9 0.2642 298.1444 101325 -3142400 12 0.605 298.1444
10 0.3128 298.1444 101325 -3507500 14 0.667 298.1444
11 0.3909 298.1444 101325 -4165700 16 0.706 298.1444
13 0.4948 298.1444 101325 -4672700 17 0.74 298.1444
15 0.5973 298.1444 101325 -4776100 18 0.846 298.1444
17 0.6045 298.1444 101325 -4537400 21 0.932 298.1444
18 0.7244 298.1444 101325 -3923200 4 0.302 318.4885
20 0.7913 298.1444 101325 -3303000 5 0.341 318.4885
21 0.8742 298.1444 101325 -2263000 8 0.445 318.4885
22 0.8784 298.1444 101325 -2012400 13 0.624 318.4885
23 0.9522 298.1444 101325 -687000 15 0.701 318.4885
12 0.4041 313.1401 101325 -3848100 19 0.853 318.4885
14 0.515 313.1401 101325 -4321600 20 0.908 318.4885
16 0.5989 313.1401 101325 -4342800 Nakanishi, K.; Touhara, H.; Watana
Bull. Chem. Soc. Jpn., 1970, 43, 26
19 0.7409 313.1401 101325 -3438000 Associated solutions: II heat of mix
methanol with aliphatic amine
Pradhan, S. D.; Mathur, H. B.
Proc. Indian Acad. Sci., Sect. A,
1979, 88, 337
ra, H.; Watanabe, N. Bull. Chem. Soc. Jpn., 1970, 43, 2671-6 Associated solutions: II heat of mixing of methanol with aliphatic amines
A. Magy. Kem. Foly., 1973, 79, 276-8 Properties of mixtures containing amines and alcohols: II heat of mixing for systems consisting of
Parragi, M. Acta Chim. Acad. Sci. Hung., 1973, 79, 395-400 Properties of some alcohol + amine mixtures: II heat of mixing of butylamin
. K.; Mathur, H. B. J. Chem. Eng. Data, 1974, 19, 145 Heats of Mixing of n-Butyl Amine-Water and n-Butyl Amine-Alcohol Sys.
. K.; Mathur, H. B. Indian J. Chem., Sect. A: Inorg., Bio-inorg., Phys., Theor. Anal. Chem., 1976, 14, 735
. An. Quim., 1978, 74, 1290-1293 Heat of mixing in exothermic systems
ur, H. B. Proc. Indian Acad. Sci., Sect. A, 1979, 88, 337
hling, J.; Rasmussen, P.; Weidlich, U. Heats of Mixture Data Collection, 1984, Vol. III, DECHEMA Chemistry Data Series, Frankfurt/Main
nol - diethylamine Methanol - triethylamine Ethanol -

Mole
Excess Excess
Pressure fraction Temperat Pressure
enthalpy No. enthalpy No.
(N/sqm) METHA- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01

101325 -4489900 1 0.201 298.1444 101325 -918400 7


101325 -4581600 2 0.235 298.1444 101325 -996300 8
101325 -4566900 4 0.349 298.1444 101325 -1307300 9
101325 -4565300 6 0.409 298.1444 101325 -1618300
101325 -4307400 7 0.45 298.1444 101325 -1777000
101325 -3770300 8 0.509 298.1444 101325 -1908400
101325 -2370100 9 0.532 298.1444 101325 -2041100
101325 -1072900 13 0.698 298.1444 101325 -1842300
101325 -3191000 14 0.867 298.1444 101325 -1272100
101325 -3592000 15 0.903 298.1444 101325 -967800
101325 -4194800 1 0.9367 298.1444 101320 -711000
101325 -4166300 2 0.8551 298.1444 101320 -1399000
101325 -3684500 3 0.7935 298.1444 101320 -1676000
101325 -2193000 4 0.6217 298.1444 101320 -2000000
101325 -1465100 5 0.5938 298.1444 101320 -1965000
hi, K.; Touhara, H.; Watanabe, N. 6 0.5163 298.1444 101320 -1932000
em. Soc. Jpn., 1970, 43, 2671-6
ed solutions: II heat of mixing of 7 0.3927 298.1444 101320 -1604000
hanol with aliphatic amines 8 0.2949 298.1444 101320 -1278000
9 0.1673 298.1444 101320 -761000
7 0.687 318.1285 101000 -2008320
8 0.538 318.1285 101000 -2016690
9 0.422 318.1285 101000 -2066900
10 0.408 318.1285 101000 -1845140
11 0.214 318.1285 101000 -887010
12 0.21 318.1285 101000 -1125500
3 0.327 318.4885 101325 -1258700
5 0.398 318.4885 101325 -1440400
10 0.551 318.4885 101325 -1904600
11 0.601 318.4885 101325 -1929300
12 0.685 318.4885 101325 -1899600
16 0.906 318.4885 101325 -1007200
17 0.935 318.4885 101325 -936800

Findlay, T. J. V. Aust. J. Chem., 1961, 14,


520 The heat of mixing for binary mixtures
of triethylamine with alcohols
Nakanishi, K.; Touhara, H.; Watanabe, N.
Bull. Chem. Soc. Jpn., 1970, 43, 2671-6
Associated solutions: II heat of mixing of
methanol with aliphatic amines
1977, 22, 289 Thermodynamic properties
of alcohol + amine mixtures: excess
enthalpies of methanol + triethylamine
and ethanol + triethylamine
nol with aliphatic amines
g for systems consisting of butyl amines and normal alcohols
eat of mixing of butylamine with n-primary alcohols
mine-Alcohol Sys.

ata Series, Frankfurt/Main, vol. 3,


Ethanol - diethylamine Ethanol - ethylamine

Mole Liquid Vapor


Excess Total
fraction Temperat Pressure mole Temperat mole
enthalpy No. pressure
ETHAN- ure (K) (N/sqm) fraction ure (K) fraction
(J/kmol) (N/sqm)
01 ETHANOL ETHANOL

0.316735 293.1454 101000 -1426740


0.121305 293.1454 101000 -782410
0.042196 293.1454 101000 -210037
Szeiler, B.; Devay, J. Acta Chim. Acad. Sci.
Hung., 1973, 77, 249-65 Mixing properties
of the ethanol + diethylamine +
triethylamine system
1-Propanol - propylamine 1-Propanol - dipropylamine
Liquid
Mole Excess mole
Temperat Pressure Temperat
No. fraction enthalpy No. fraction
ure (K) (N/sqm) ure (K)
1-PRO-01 (J/kmol) PROPAN
OL

7 0.35 298.15 101000 -2440570


8 0.4 298.15 101000 -2636240
9 0.45 298.15 101000 -2774350
10 0.5 298.15 101000 -2849240
11 0.525 298.15 101000 -2861630
12 0.55 298.15 101000 -2856810
13 0.575 298.15 101000 -2834550
14 0.6 298.15 101000 -2794750
15 0.65 298.15 101000 -2662620
16 0.7 298.15 101000 -2461730
17 0.75 298.15 101000 -2194870
18 0.8 298.15 101000 -1865830
19 0.85 298.15 101000 -1478810
20 0.9 298.15 101000 -1037610
21 0.95 298.15 101000 -544690
22 1 298.15 101000 0
Acta, 1998, 310, 69-76 Excess enthalpies
of alcohol + amine mixtures. Experimental
results and theoretical description using
the ERAS-model
nol - dipropylamine 2-Propanol - dipropylamine Methanol - n,n-d
Vapor
Liquid Vapor
mole Total Total
mole Temperat mole
fraction pressure No. pressure No.
fraction ure (K) fraction
PROPAN (N/sqm) (N/sqm)
ISOPR-01 ISOPR-01
OL

7
8
9
10
11
12
13
14
15
16
17
18
19
1
2
3
4
5
6
7
8
9
10
11
12
13
14
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
1
2
3
4
5
6
7
8
9
10
11
12
Methanol - n,n-dimethylformamide Ethanol - n,n-dimethylformamide

Mole Mole
Excess Excess
fraction Temperat Pressure fraction Temperat Pressure
enthalpy No. enthalpy
METHA- ure (K) (N/sqm) ETHAN- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01 01

0.65 293.138 101000 -96700 7 0.65 293.138 101000 391700


0.6 293.138 101000 -101700 8 0.6 293.138 101000 408500
0.55 293.138 101000 -105100 9 0.55 293.138 101000 415000
0.5 293.138 101000 -107000 10 0.5 293.138 101000 411500
0.45 293.138 101000 -107400 11 0.45 293.138 101000 398500
0.4 293.138 101000 -106200 12 0.4 293.138 101000 376500
0.35 293.138 101000 -103200 13 0.35 293.138 101000 346300
0.3 293.138 101000 -98100 14 0.3 293.138 101000 308700
0.25 293.138 101000 -90600 15 0.25 293.138 101000 264800
0.2 293.138 101000 -80200 16 0.2 293.138 101000 216000
0.15 293.138 101000 -66600 17 0.15 293.138 101000 163400
0.1 293.138 101000 -49200 18 0.1 293.138 101000 108700
0.05 293.138 101000 -27200 19 0.05 293.138 101000 53600
0.278 298.1444 101325 -91540 1 0.1 293.1454 101325 108700
0.388 298.1444 101325 -108780 2 0.3 293.1454 101325 308700
0.4 298.1444 101325 -122220 3 0.4 293.1454 101325 376500
0.405 298.1444 101325 -111540 4 0.5 293.1454 101325 411500
0.41 298.1444 101325 -112630 5 0.6 293.1454 101325 408500
0.423 298.1444 101325 -114560 6 0.7 293.1454 101325 364600
0.427 298.1444 101325 -114810 7 0.8 293.1454 101325 216000
0.438 298.1444 101325 -113600 8 0.8 293.1454 101325 279900
0.455 298.1444 101325 -112550 9 0.9 293.1454 101325 156700
0.475 298.1444 101325 -108620 1 0.0402 298.1444 101300 44100
0.495 298.1444 101325 -108200 2 0.0839 298.1444 101300 94200
0.582 298.1444 101325 -109660 3 0.1478 298.1444 101300 169800
0.613 298.1444 101325 -108120 4 0.2097 298.1444 101300 241200
0.737 298.1444 101325 -83800 5 0.2697 298.1444 101300 304400
0.0678 303.1431 101325 -18050 6 0.3279 298.1444 101300 365400
0.0809 308.1416 101325 -15380 7 0.3843 298.1444 101300 420600
0.1162 303.1431 101325 -32870 8 0.4391 298.1444 101300 467500
0.1463 308.1416 101325 -34860 9 0.4923 298.1444 101300 506300
0.1868 303.1431 101325 -57670 10 0.544 298.1444 101300 533500
0.2587 308.1416 101325 -71750 11 0.5942 298.1444 101300 546300
0.2606 303.1431 101325 -81520 12 0.643 298.1444 101300 544700
0.3047 308.1416 101325 -86200 13 0.6905 298.1444 101300 531600
0.305 303.1431 101325 -90980 14 0.7367 298.1444 101300 505900
0.3549 303.1431 101325 -101680 15 0.7817 298.1444 101300 461100
0.3809 308.1416 101325 -101500 16 0.8254 298.1444 101300 401200
0.415 303.1431 101325 -110530 17 0.8681 298.1444 101300 329400
0.425 308.1416 101325 -114900 18 0.8959 298.1444 101300 274100
0.467 303.1431 101325 -118040 19 0.9233 298.1444 101300 212700
0.5368 308.1416 101325 -118020 20 0.9501 298.1444 101300 146700
0.55 303.1431 101325 -111680 21 0.9766 298.1444 101300 71900
0.562 308.1416 101325 -110600 1 0.9301 313.15 101300 184000
0.6052 303.1431 101325 -108120 2 0.8678 313.15 101300 306000
0.62 308.1416 101325 -95040 3 0.8423 313.15 101300 345000
0.675 303.1431 101325 -87880 4 0.7669 313.15 101300 443000
0.71 303.1431 101325 -78110 5 0.725 313.15 101300 472000
0.7517 308.1416 101325 -62500 6 0.6382 313.15 101300 518000
0.8067 308.1416 101325 -44110 7 0.5691 313.15 101300 520000
0.8204 303.1431 101325 -45080 8 0.5488 313.15 101300 504000
0.8748 303.1431 101325 -28150 9 0.4981 313.15 101300 487000
0.0505 298.1444 101300 -19500 10 0.4699 313.15 101300 472000
0.1104 298.1444 101300 -44500 11 0.3979 313.15 101300 413000
0.1939 298.1444 101300 -73700 12 0.3473 313.15 101300 375000
0.2708 298.1444 101300 -95900 13 0.2463 313.15 101300 275000
0.3418 298.1444 101300 -107400 14 0.2103 313.15 101300 229000
0.3861 298.1444 101300 -110100 15 0.1491 313.15 101300 182000
0.4283 298.1444 101300 -110400 16 0.1163 313.15 101300 133000
0.4685 298.1444 101300 -108500 17 0.0895 313.15 101300 112000
0.5068 298.1444 101300 -104600 1 0.0522 298.15 101325 73700
0.5434 298.1444 101300 -97900 2 0.1031 298.15 101325 137700
0.5952 298.1444 101300 -89900 3 0.128 298.15 101325 169900
0.6593 298.1444 101300 -72400 4 0.1527 298.15 101325 199900
0.7181 298.1444 101300 -58100 5 0.2014 298.15 101325 264000
0.7724 298.1444 101300 -45300 6 0.2482 298.15 101325 316100
0.8226 298.1444 101300 -37400 7 0.2947 298.15 101325 358000
0.8693 298.1444 101300 -28700 8 0.3397 298.15 101325 397900
0.9126 298.1444 101300 -18900 9 0.3615 298.15 101325 413900
0.9432 298.1444 101300 -13300 10 0.3836 298.15 101325 435600
0.9723 298.1444 101300 -7600 11 0.4256 298.15 101325 467900
0.9909 298.1444 101300 -2900 12 0.4264 298.15 101325 464700
0.9504 313.15 101300 -9500 13 0.4683 298.15 101325 493200
0.9043 313.15 101300 -16400 14 0.4683 298.15 101325 491900
0.8848 313.15 101300 -19200 15 0.4683 298.15 101325 494000
0.8256 313.15 101300 -30600 16 0.5691 298.15 101325 522400
0.7913 313.15 101300 -36100 17 0.5691 298.15 101325 521600
0.7173 313.15 101300 -54000 18 0.6645 298.15 101325 510800
0.6552 313.15 101300 -68000 19 0.6645 298.15 101325 516600
0.6363 313.15 101300 -70600 20 0.7551 298.15 101325 448600
0.5882 313.15 101300 -84800 21 0.7551 298.15 101325 449000
0.5605 313.15 101300 -89900 22 0.8323 298.15 101325 366700
0.4874 313.15 101300 -105500 23 0.9224 298.15 101325 200000
0.4336 313.15 101300 -110800 24 0.9302 298.15 101325 190300
0.3198 313.15 101300 -109700 25 0.9538 298.15 101325 129300
0.277 313.15 101300 -103400 26 0.9771 298.15 101325 65500
0.2013 313.15 101300 -85900 Grote, L.; Riesel, G.; Bittrich, H.-J. Z.
Chem., 1967, 7, 444 Mixing enthalpies of
0.1593 313.15 101300 -73900 binary systems with dimethylformamide
0.124 313.15 101300 -60800 (dmfa)
0.0862 313.15 101300 -44600
Komarov, E. V.; Krogan, I. V.;
Morachevskii, A. G. Zh. Prikl. Khim.
(Leningrad), 1973, 46, 1384
Komarov, E. V.; Krogan, I. V.;
0.9195 298.15 101325 -22800 Morachevskii, A. G. Zh. Prikl. Khim.
0.8383 298.15 101325 -43500 (Leningrad), 1973, 46, 1384
0.7591 298.15 101325 -68700
0.6763 298.15 101325 -95000 Chao, J. P.; Dai, M.; Wang, Y. X. J. Chem.
0.5969 298.15 101325 -115400 Thermodyn., 1989, 21, 1169
0.5173 298.15 101325 -136300 METHANOL, ETHANOL AND l-PROPANOL
WITH FORMAMIDE, ii
0.4748 298.15 101325 -129100 -METHYLFORMAMIDE AND NJV-
0.3935 298.15 101325 -135200 DIMETHYLFORMAMIDE
0.3134 298.15 101325 -130300 Excess enthalpies and excess heat
capacities of the ternary system ethanol +
0.2346 298.15 101325 -114000 N,N-dimethyl-formamide + cyclohexane at
0.158 298.15 101325 -87800 298.15 K
0.0771 298.15 101325 -47800
Grote, L.; Riesel, G.; Bittrich, H.-J. Z.
Chem., 1967, 7, 444 Mixing enthalpies of
binary systems with dimethylformamide
(dmfa)

Quitzsch, K.; Prinz, H. P.; Suehnel, K.;


Geiseler, G. Z. Phys. Chem. (Leipzig), 1969,
311, 420-8
Singh, P. P.; Verma, D. V.; Arora, P. S.
Thermochim. Acta, 1976, 15, 267-80
Thermodynamics of binary methanol
solutions

Chao, J. P.; Dai, M.; Wang, Y. X. J. Chem.


Thermodyn., 1989, 21,
-METHYLFORMAMIDE AND1169
NJV-
DIMETHYLFORMAMIDE
1-Propanol - n,n-dimethylformamide 2-Propanol - n,n-dimethylacetamide
Liquid Vapor
mole mole Total Mole
Temperat Temperat
No. fraction fraction pressure No. fraction
ure (K) ure (K)
PROPAN PROPAN (N/sqm) ISOPR-01
OL OL

7 0.3276 298.1444 101300 569800 7 0.5951 313.1401


8 0.3793 298.1444 101300 638300 8 0.547 313.1401
9 0.4308 298.1444 101300 696300 9 0.499 313.1401
10 0.4821 298.1444 101300 749300 10 0.448 313.1401
11 0.5333 298.1444 101300 779100 11 0.3739 313.1401
12 0.5843 298.1444 101300 790800 12 0.3295 313.1401
13 0.6352 298.1444 101300 786400 13 0.2303 313.1401
14 0.6859 298.1444 101300 764500 14 0.2264 313.1401
15 0.7364 298.1444 101300 716500 15 0.1976 313.1401
16 0.7868 298.1444 101300 643000 16 0.1273 313.1401
17 0.837 298.1444 101300 541800 17 0.1076 313.1401
18 0.8704 298.1444 101300 457800 18 0.0826 313.1401
19 0.9037 298.1444 101300 358000 1 0.8958 298.15
20 0.937 298.1444 101300 241700 2 0.8002 298.15
21 0.9702 298.1444 101300 122000 3 0.7017 298.15
1 0.9122 313.15 101300 320000 4 0.6027 298.15
2 0.8862 313.15 101300 398000 5 0.5132 298.15
3 0.8369 313.15 101300 522000 6 0.4998 298.15
4 0.8067 313.15 101300 582000 7 0.4099 298.15
5 0.7199 313.15 101300 704000 8 0.3091 298.15
6 0.6731 313.15 101300 737000 9 0.208 298.15
7 0.575 313.15 101300 769000 10 0.11 298.15
8 0.5078 313.15 101300 751000
9 0.4872 313.15 101300 738000 Pikkarainen, L. J. Solution Chem., 1
10 0.4092 313.15 101300 662000 15, 473-9
11 0.3405 313.15 101300 575000 Iloukhani, H.; Zarei, H. A. Phys. Chem
2004, 42, 75-79 Excess molar enth
12 0.2937 313.15 101300 497000 of amides and some alkan-2-ols
13 0.2034 313.15 101300 379000 298.15K
14 0.1722 313.15 101300 310000
15 0.1204 313.15 101300 231000
16 0.0933 313.15 101300 177000
17 0.0714 313.15 101300 144000
1 0.9024 298.15 101325 399600
2 0.8006 298.15 101325 669400
3 0.6928 298.15 101325 819000
4 0.5968 298.15 101325 859700
5 0.5019 298.15 101325 836200
6 0.4963 298.15 101325 829700
7 0.3988 298.15 101325 745900
8 0.2988 298.15 101325 605000
9 0.1994 298.15 101325 430600
10 0.1005 298.15 101325 229000
Pikkarainen, L. Thermochim. Acta, 1991,
Chao,
178, J. P.; Dai,EXCESS
311-319 M.; Wang, Y. X. J. Chem.
ENTHALPIES OF
Thermodyn.,
BINARY SOLVENT1989, 21, 1169OF
MIXTURES
METHANOL, ETHANOL AND l-PROPANOL
WITH FORMAMIDE, ii
-METHYLFORMAMIDE AND NJV-
DIMETHYLFORMAMIDE
Iloukhani, H.; Zarei, H. A. J. Chem. Eng.
Data, 2002, 47, 195-197 Excess Molar
Enthalpies of N,N-Dimethylformamide +
Alkan-1-ols (C1-C6) at 298.15K
n,n-dimethylacetamide Methanol - Dichloromethane Ethanol - Di

Mole
Excess Excess
Pressure fraction Temperat Pressure
enthalpy No. enthalpy No.
(N/sqm) METHA- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01

101000 459200 7 0.171 308.132 101325 741000


101000 455100 8 0.155 308.132 101325 749000
101000 438300 9 0.065 308.132 101325 540000
101000 408900 10 0.042 308.132 101325 431000
101000 367100 11 0.019 308.132 101325 222000
101000 333400 Moelwyn-Hughes, E. A.; Missen, R. W. J.
Phys. Chem., 1957, 61, 518
101000 250200 Thermodynamic properties of methyl
101000 237400 alcohol-chloromethane solutions.
101000 218300
101000 139800
101000 128700
101000 93100
101000 318600
101000 500400
101000 593100
101000 614400
101000 594700
101000 581700
101000 524000
101000 426600
101000 304200
101000 169500

nen, L. J. Solution Chem., 1986,


15, 473-9
H.; Zarei, H. A. Phys. Chem. Liq.,
, 75-79 Excess molar enthalpies
ides and some alkan-2-ols at
298.15K
Ethanol - Dichloromethane Methanol - Chloroform
Liquid Vapor
Mole
mole mole Total Excess
Temperat fraction Temperat Pressure
fraction fraction pressure No. enthalpy
ure (K) METHA- ure (K) (N/sqm)
ETHAN- ETHAN- (N/sqm) (J/kmol)
01
01 01

7 0.0859 298.136 101000 298319


8 0.69988 298.156 101000 -1574021
1 0.88456 298.136 101325 -433900
2 0.79587 298.136 101325 -593700
3 0.69988 298.136 101325 -606700
4 0.52855 298.136 101325 -348900
5 0.3655 298.136 101325 14200
6 0.3355 298.136 101325 80300
7 0.1958 298.136 101325 313800
8 0.0859 298.136 101325 393300
1 0.949 308.132 101325 -213000
2 0.883 308.132 101325 -414000
3 0.792 308.132 101325 -548000
4 0.669 308.132 101325 -511000
5 0.507 308.132 101325 -213000
6 0.35 308.132 101325 147000
7 0.192 308.132 101325 440000
8 0.191 308.132 101325 440000
9 0.081 308.132 101325 440000
10 0.035 308.132 101325 264000
1 0.9744 323.1371 101325 -96800
2 0.9441 323.1371 101325 -194400
3 0.907 323.1371 101325 -283400
4 0.9026 323.1371 101325 -297400
5 0.8626 323.1371 101325 -364600
6 0.8553 323.1371 101325 -369500
7 0.8245 323.1371 101325 -400300
8 0.7986 323.1371 101325 -407400
9 0.7825 323.1371 101325 -409900
10 0.7432 323.1371 101325 -394800
11 0.714 323.1371 101325 -369100
12 0.7079 323.1371 101325 -364600
13 0.6816 323.1371 101325 -328900
14 0.6728 323.1371 101325 -316200
15 0.6544 323.1371 101325 -287200
16 0.6532 323.1371 101325 -284300
17 0.6378 323.1371 101325 -255700
18 0.626 323.1371 101325 -237500
19 0.613 323.1371 101325 -208500
20 0.6037 323.1371 101325 -189400
21 0.5569 323.1371 101325 -90100
22 0.5567 323.1371 101325 -87900
23 0.5047 323.1371 101325 31200
24 0.4947 323.1371 101325 51500
25 0.4345 323.1371 101325 194300
26 0.4092 323.1371 101325 241000
27 0.3437 323.1371 101325 390300
28 0.2669 323.1371 101325 524500
29 0.2145 323.1371 101325 587200
30 0.2091 323.1371 101325 573300
31 0.1437 323.1371 101325 590900
32 0.0868 323.1371 101325 523900
33 0.0776 323.1371 101325 489100
34 0.0422 323.1371 101325 334000
35 0.0203 323.1371 101325 186300
36 0.0033 323.1371 101325 33900
1 0.92 303.1431 101000 -253700
2 0.84 303.1431 101000 -366500
3 0.79 303.1431 101000 -394800
4 0.76 303.1431 101000 -396700
5 0.68 303.1431 101000 -357400
6 0.61 303.1431 101000 -273000
7 0.58 303.1431 101000 -214900
8 0.52 303.1431 101000 -104200
9 0.47 303.1431 101000 -6600
10 0.4 303.1431 101000 134100
11 0.37 303.1431 101000 188500
12 0.32 303.1431 101000 271000
13 0.25 303.1431 101000 351600
14 0.2 303.1431 101000 374100
15 0.16 303.1431 101000 364600
16 0.1 303.1431 101000 298800
17 0 303.1431 101000 0
1 0.9 303.1431 101325 -284700
2 0.8 303.1431 101325 -400400
3 0.7 303.1431 101325 -377800
4 0.6 303.1431 101325 -125800
5 0.5 303.1431 101325 -66100
6 0.4 303.1431 101325 136000
7 0.3 303.1431 101325 302500
8 0.2 303.1431 101325 377100
9 0.1 303.1431 101325 298400
1 0.0173 298.1444 101325 142000
2 0.0609 298.1444 101325 330400
3 0.1313 298.1444 101325 392600
4 0.2237 298.1444 101325 277800
5 0.3007 298.1444 101325 130400
6 0.3836 298.1444 101325 -53000
7 0.464 298.1444 101325 -228200
8 0.5562 298.1444 101325 -407000
9 0.6196 298.1444 101325 -528100
10 0.7021 298.1444 101325 -608100
11 0.748 298.1444 101325 -630800
12 0.8009 298.1444 101325 -593000
13 0.8662 298.1444 101325 -484700
14 0.9317 298.1444 101325 -287400
15 0.9847 298.1444 101325 -69300
16 0.9965 298.1444 101325 -17600
Hirobe, H. J. Faculty Sci. Imp. Univ. Tokyo,
1925, 1, 155-222 Thermochemical Studies
II. The Thermochemistry of Concentrated
Solutions Part 1

Hirobe, H. J. Faculty Sci. Imp. Univ. Tokyo,


1926, 1, 155 Thermochemical studies
Moelwyn-Hughes, E. A.; Missen, R. W. J.
Phys. Chem., 1957, 61, 518
Thermodynamic properties of methyl
alcohol-chloromethane solutions.
Van Ness, H. C. J. Chem. Eng. Data, 1975,
20, 403-5 Excess thermodynamic
functions for ternary systems: I acetone +
chloroform + methanol at 50c

Singh, P. P.; Sharma, B. R.; Sidhu, K. S. Can.


J. Chem., 1979, 57, 387 Thermodynamics
of chloroform and methanol mixtures
Singh, P. P.; Sharma, B. R.; Sidhu, K. S. Can.
J. Chem., 1979, 57, 385
Ethanol - Chloroform 1-Propanol - Chloroform

Mole
Excess Mole
fraction Temperat Pressure Temperat
No. enthalpy No. fraction
ETHAN- ure (K) (N/sqm) ure (K)
(J/kmol) PROP
01

1 0.87845 298.136 101325 -507500 7 0.31775 298.156


2 0.82355 298.136 101325 -643900 8 0.2589 298.156
3 0.68254 298.136 101325 -624300 9 0.01414 298.156
4 0.62235 298.136 101325 -488700 10 0.83598 298.226
5 0.52298 298.136 101325 -246400 1 0.95136 298.136
6 0.4284 298.136 101325 -8800 2 0.83598 298.136
7 0.25298 298.136 101325 364400 3 0.72058 298.136
8 0.165 298.136 101325 456900 4 0.66008 298.136
9 0.0588 298.136 101325 386600 5 0.49889 298.136
7 0.9264 303.1431 101325 -344600 6 0.48775 298.136
8 0.8925 303.1431 101325 -451100 7 0.31775 298.136
11 0.8291 303.1431 101325 -565300 8 0.2589 298.136
13 0.8081 303.1431 101325 -581000 9 0.1653 298.136
16 0.7699 303.1431 101325 -585000 10 0.06414 298.136
18 0.7364 303.1431 101325 -566100 1 0.0261 298.1444
19 0.7319 303.1431 101325 -561900 2 0.0674 298.1444
20 0.7279 303.1431 101325 -557800 3 0.1431 298.1444
22 0.6927 303.1431 101325 -519600 4 0.181 298.1444
24 0.6779 303.1431 101325 -508000 5 0.2399 298.1444
26 0.6514 303.1431 101325 -468500 6 0.2963 298.1444
27 0.628 303.1431 101325 -424400 7 0.3631 298.1444
29 0.6017 303.1431 101325 -369100 8 0.4333 298.1444
32 0.5396 303.1431 101325 -197100 9 0.5332 298.1444
34 0.5146 303.1431 101325 -135400 10 0.5694 298.1444
36 0.4863 303.1431 101325 -66100 11 0.6113 298.1444
38 0.4609 303.1431 101325 -1900 12 0.6547 298.1444
40 0.4142 303.1431 101325 117100 13 0.7132 298.1444
43 0.3828 303.1431 101325 186500 14 0.7649 298.1444
44 0.3453 303.1431 101325 266900 15 0.8299 298.1444
46 0.2959 303.1431 101325 360300 16 0.8816 298.1444
50 0.2481 303.1431 101325 436600 17 0.9444 298.1444
51 0.2228 303.1431 101325 470500 18 0.9829 298.1444
53 0.2005 303.1431 101325 495900 19 0.0291 308.1416
54 0.1716 303.1431 101325 510000 20 0.0777 308.1416
56 0.148 303.1431 101325 515800 21 0.1612 308.1416
57 0.1216 303.1431 101325 505300 22 0.2493 308.1416
58 0.1037 303.1431 101325 486000 23 0.2931 308.1416
60 0.0722 303.1431 101325 420500 24 0.3686 308.1416
63 0.0468 303.1431 101325 329200 25 0.4341 308.1416
67 0.0222 303.1431 101325 184700 26 0.4853 308.1416
69 0.014 303.1431 101325 123300 27 0.5097 308.1416
71 0.0029 303.1431 101325 25100 28 0.5302 308.1416
9 0.8679 323.1371 101325 -355900 29 0.5562 308.1416
10 0.8521 323.1371 101325 -366000 30 0.6065 308.1416
12 0.8134 323.1371 101325 -370100 31 0.6637 308.1416
14 0.7969 323.1371 101325 -362300 32 0.7448 308.1416
15 0.7818 323.1371 101325 -351100 33 0.798 308.1416
17 0.7529 323.1371 101325 -318300 34 0.8897 308.1416
21 0.7205 323.1371 101325 -269400 35 0.9414 308.1416
23 0.6871 323.1371 101325 -206700 36 0.9774 308.1416
25 0.6551 323.1371 101325 -138500 1 0.9301 303.1431
28 0.6256 323.1371 101325 -68700 2 0.8799 303.1431
30 0.599 323.1371 101325 -2700 3 0.8247 303.1431
31 0.5661 323.1371 101325 102100 4 0.7497 303.1431
33 0.5363 323.1371 101325 180200 5 0.6301 303.1431
35 0.504 323.1371 101325 264600 6 0.5548 303.1431
37 0.4766 323.1371 101325 335500 7 0.5103 303.1431
39 0.4368 323.1371 101325 432200 8 0.4899 303.1431
41 0.4117 323.1371 101325 484400 9 0.4448 303.1431
42 0.383 323.1371 101325 542600 10 0.3902 303.1431
45 0.3394 323.1371 101325 623500 11 0.3497 303.1431
47 0.2959 323.1371 101325 688800 12 0.29 303.1431
48 0.2677 323.1371 101325 720100 13 0.2298 303.1431
49 0.256 323.1371 101325 727900 14 0.1603 303.1431
52 0.2049 323.1371 101325 749200 15 0.1199 303.1431
55 0.1535 323.1371 101325 721800 16 0.0901 303.1431
59 0.0982 323.1371 101325 610900 1 0.9302 303.1431
61 0.0719 323.1371 101325 512000 2 0.8799 303.1431
62 0.0547 323.1371 101325 426100 3 0.8247 303.1431
64 0.0391 323.1371 101325 328300 4 0.7197 303.1431
65 0.0309 323.1371 101325 268900 5 0.6301 303.1431
66 0.0226 323.1371 101325 203300 6 0.5548 303.1431
68 0.0178 323.1371 101325 163500 7 0.5103 303.1431
70 0.0107 323.1371 101325 100800 8 0.4899 303.1431
Data, 1975, 20, 406-9 Excess 9 0.4448 303.1431
thermodynamic functions for
ternary systems: II chloroform 10 0.3902 303.1431
+ ethanol + n-heptane at 50c 11 0.3497 303.1431
12 0.29 303.1431
Hirobe, H. J. Faculty Sci. Imp.
Univ. Tokyo, 1926, 1, 155 13 0.2298 303.1431
Thermochemical studies 14 0.1603 303.1431
15 0.1199 303.1431
16 0.0901 303.1431
Hirobe, H. J. Faculty Sci. Imp. Univ.
1925, 1, 155-222 Thermochemical S
II. The Thermochemistry of Concen
Solutions Part 1

Hirobe, H. J. Faculty Sci. Imp. Univ.


1926, 1, 155 Thermochemical stu
(Leipzig), 1978, 259, 1109-16 Exc
enthalpies for binary mixtures
chloroform with alcohols.
Sharma, B. R.; Singh, P. P. Thermo
Acta, 1979, 32, 213-23 Thermodyn
of Chloroform and n-Propanol Mix

Singh, P. P.; Sharma, B. R.; Sidhu, K.


J. Chem., 1979, 57, 385
panol - Chloroform 2-Propanol - Chloroform Methanol - Tet

Excess Mole Excess


Pressure Temperat Pressure
enthalpy No. fraction enthalpy No.
(N/sqm) ure (K) (N/sqm)
(J/kmol) ISOPR-01 (J/kmol)

101000 506682 7 0.3291 298.1444 101325 739700 7


101000 562748 8 0.3852 298.1444 101325 678300 8
101000 387857 9 0.4644 298.1444 101325 556400 9
101000 -332628 10 0.5171 298.1444 101325 456100 10
101325 -211700 11 0.5472 298.1444 101325 392500 11
101325 -415100 12 0.6375 298.1444 101325 201600 12
101325 -341800 13 0.7222 298.1444 101325 22500 13
101325 -244300 14 0.7682 298.1444 101325 -63600 14
101325 131400 15 0.8121 298.1444 101325 -129300 15
101325 151500 16 0.8577 298.1444 101325 -172600 16
101325 515500 17 0.8843 298.1444 101325 -177100 17
101325 586600 18 0.91 298.1444 101325 -171400 18
101325 636400 19 0.9479 298.1444 101325 -130800 19
101325 449400 20 0.9844 298.1444 101325 -49400 1
101325 227500 21 0.0299 308.1416 101325 251900 2
101325 445000 22 0.0532 308.1416 101325 418500 3
101325 589500 23 0.0757 308.1416 101325 541400 4
101325 601500 24 0.1043 308.1416 101325 658100 5
101325 573800 25 0.1474 308.1416 101325 780600 6
101325 510800 26 0.1884 308.1416 101325 851000 7
101325 403000 27 0.1908 308.1416 101325 851300 8
101325 263100 28 0.2227 308.1416 101325 881500 9
101325 36200 29 0.2495 308.1416 101325 893600 10
101325 -47800 30 0.2832 308.1416 101325 895900 11
101325 -141800 31 0.3258 308.1416 101325 879600 12
101325 -232600 32 0.4101 308.1416 101325 796900 1
101325 -334500 33 0.4875 308.1416 101325 674500 2
101325 -394300 34 0.5762 308.1416 101325 496500 3
101325 -411500 35 0.6833 308.1416 101325 252300 4
101325 -364300 36 0.7826 308.1416 101325 38000 5
101325 -214600 37 0.8322 308.1416 101325 -46900 6
101325 -76900 38 0.8806 308.1416 101325 -100400 7
101325 239600 39 0.898 308.1416 101325 -104600 8
101325 494400 40 0.9379 308.1416 101325 -95600 9
101325 664000 41 0.9777 308.1416 101325 -48600 10
101325 667400 42 0.0304 298.1444 101325 258800 11
101325 631500 43 0.0853 298.1444 101325 550900 12
101325 526400 Fujiwara, K.; Ogasawara, Y. Z. Phys. Chem. 13
(Leipzig), 1978, 259, 1109-16 Excess
101325 404200 enthalpies for binary mixtures of 14
101325 295200 chloroform with alcohols. 15
101325 233500 16
101325 193100 17
101325 126400 18
101325 9800 19
101325 -113800 20
101325 -256600 21
101325 -311300 22
101325 -291900 23
101325 -197900 24
101325 -88000 25
101325 -165070 26
101325 -221230 27
101325 -235170 28
101325 -152820 29
101325 -10810 30
101325 136350 31
101325 225090 32
101325 264750 33
101325 346940 34
101325 436470 35
101325 486550 36
101325 535790 37
101325 541960 38
101325 482150 39
101325 410580 40
101325 338250 41
101325 -165070 42
101325 -221230 43
101325 -235170 44
101325 -152820 45
101325 -10810 46
101325 136350 47
101325 225090 48
101325 264750 49
101325 346940 50
101325 436470 51
101325 486550 52
101325 535790 53
101325 541960 54
101325 482150 55
101325 410580 56
101325 338250 57
. J. Faculty Sci. Imp. Univ. Tokyo, 58
155-222 Thermochemical Studies
ermochemistry of Concentrated 59
Solutions Part 1 60
61
. J. Faculty Sci. Imp. Univ. Tokyo, 62
, 155 Thermochemical studies 63
g), 1978, 259, 1109-16 Excess
alpies for binary mixtures of 64
hloroform with alcohols. 65
66
B. R.; Singh, P. P. Thermochim.
79, 32, 213-23 Thermodynamics 67
oform and n-Propanol Mixtures 68
69
P.; Sharma, B. R.; Sidhu, K. S. Can. 70
J. Chem., 1979, 57, 385 1
2
3
4
5
6
7
8
9
10
11
12
13
1
2
3
4
5
6
7
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
Methanol - Tetrachloromethane Ethanol - Tetrachloromethane

Mole Excess Mole Excess


Temperat Pressure Temperat Pressure
fraction enthalpy No. fraction enthalpy
ure (K) (N/sqm) ure (K) (N/sqm)
METH (J/kmol) Ethanol (J/kmol)

0.35 293.138 101000 247693 3 0.968 288.1466 101325 -56500


0.4 293.138 101000 228028 4 0.8786 288.1466 101325 -115800
0.45 293.138 101000 207108 5 0.7796 288.1466 101325 -108800
0.5 293.138 101000 184096 6 0.7247 288.1466 101325 -79300
0.55 293.138 101000 157318 7 0.6662 288.1466 101325 -34600
0.6 293.138 101000 126775 8 0.6021 288.1466 101325 13100
0.65 293.138 101000 92466 9 0.5352 288.1466 101325 67800
0.7 293.138 101000 57739 10 0.4634 288.1466 101325 125700
0.75 293.138 101000 25104 11 0.3861 288.1466 101325 191900
0.8 293.138 101000 -2929 12 0.3028 288.1466 101325 255200
0.85 293.138 101000 -20920 13 0.215 288.1466 101325 302700
0.9 293.138 101000 -25941 14 0.1123 288.1466 101325 316300
0.95 293.138 101000 -17991 1 0.1412 298.1444 101325 403338
0.9 308.132 101325 0 2 0.2475 298.1444 101325 424258
0.827 308.132 101325 25000 3 0.3303 298.1444 101325 405430
0.703 308.132 101325 121000 4 0.3968 298.1444 101325 368192
0.55 308.132 101325 268000 5 0.5979 298.1444 101325 249366
0.542 308.132 101325 272000 6 0.6206 298.1444 101325 225099
0.389 308.132 101325 381000 7 0.6415 298.1444 101325 193301
0.226 308.132 101325 444000 8 0.7525 298.1444 101325 165268
0.12 308.132 101325 444000 9 0.8588 298.1444 101325 135143
0.119 308.132 101325 435000 22 0.00037 298.1444 101325 6783.289
0.07 308.132 101325 402000 23 0.00074 298.1444 101325 13576.35
0.035 308.132 101325 331000 24 0.0011 298.1444 101325 20107.86
0.019 308.132 101325 251000 25 0.00146 298.1444 101325 26722.73
0.011 273.1 101325 100420 26 0.00182 298.1444 101325 33190.88
0.024 273.1 101325 125520 27 0.00216 298.1444 101325 39227.09
0.051 273.1 101325 146440 28 0.00283 298.1444 101325 50965.16
0.071 273.1 101325 158990 29 0.00348 298.1444 101325 62075.22
0.109 273.1 101325 163180 30 0.00412 298.1444 101325 72828.7
0.125 273.1 101325 158990 31 0.00473 298.1444 101325 82713.01
0.165 273.1 101325 154810 32 0.00533 298.1444 101325 92035.62
0.26 273.1 101325 117150 33 0.00648 298.1444 101325 109124.3
0.273 273.1 101325 117150 34 0.00754 298.1444 101325 123696.4
0.47 273.1 101325 8370 35 0.00855 298.1444 101325 136562.8
0.475 273.1 101325 20920 36 0.0089 298.1444 101325 140868
0.634 273.1 101325 -79500 37 0.00949 298.1444 101325 147579.1
0.645 273.1 101325 -75310 38 0.01039 298.1444 101325 157418.2
0.734 273.1 101325 -104600 39 0.0158 298.1444 101325 202310.2
0.735 273.1 101325 -108780 40 0.0222 298.1444 101325 240732.4
0.861 273.1 101325 -96230 41 0.033 298.1444 101325 284327
0.93 273.1 101325 -66940 42 0.0436 298.1444 101325 314410.8
0.934 273.1 101325 -62760 43 0.623 298.1444 101325 122602.7
0.026 293.138 101325 221750 44 0.6502 298.1444 101325 96889.42
0.038 293.138 101325 234300 45 0.6784 298.1444 101325 71342.72
0.073 293.138 101325 280330 46 0.7124 298.1444 101325 42411.45
0.094 293.138 101325 297060 47 0.7484 298.1444 101325 15252.09
0.118 293.138 101325 313800 48 0.7675 298.1444 101325 2319.769
0.144 293.138 101325 313800 49 0.7881 298.1444 101325 -10186.9
0.169 293.138 101325 313800 50 0.8095 298.1444 101325 -21126.74
0.279 293.138 101325 284510 51 0.8322 298.1444 101325 -30581.85
0.463 293.138 101325 175730 52 0.8561 298.1444 101325 -37697
0.633 293.138 101325 66940 53 0.8815 298.1444 101325 -41783.1
0.73 293.138 101325 8370 54 0.9085 298.1444 101325 -41397.62
0.859 293.138 101325 -41840 55 0.9371 298.1444 101325 -35601.93
0.93 293.138 101325 -41840 56 0.9521 298.1444 101325 -30145.3
0.931 293.138 101325 -29290 57 0.9676 298.1444 101325 -22540.82
0.05 308.132 101325 376560 58 0.9836 298.1444 101325 -12614.47
0.087 308.132 101325 426770 1 0.0206 298.1444 101300 230400
0.168 308.132 101325 456060 2 0.0389 298.1444 101300 303800
0.268 308.132 101325 460240 3 0.0624 298.1444 101300 353300
0.274 308.132 101325 447690 4 0.1024 298.1444 101300 402000
0.287 308.132 101325 460240 5 0.1705 298.1444 101300 430000
0.474 308.132 101325 313800 6 0.2243 298.1444 101300 426000
0.478 308.132 101325 322170 7 0.3313 298.1444 101300 378000
0.641 308.132 101325 179910 8 0.3921 298.1444 101300 327200
0.642 308.132 101325 192460 9 0.4728 298.1444 101300 258400
0.728 308.132 101325 117150 10 0.5344 298.1444 101300 200800
0.729 308.132 101325 117150 11 0.5822 298.1444 101300 154800
0.865 308.132 101325 29290 12 0.6204 298.1444 101300 121700
0.022 323.127 101325 301250 13 0.6364 298.1444 101300 106500
0.035 323.127 101325 376560 15 0.9677 298.1444 101325 -38640
0.052 323.127 101325 476980 16 0.8777 298.1444 101325 -69520
0.053 323.127 101325 468610 17 0.8299 298.1444 101325 -63140
0.075 323.127 101325 548100 18 0.7253 298.1444 101325 1000
0.096 323.127 101325 585760 19 0.6619 298.1444 101325 57110
0.12 323.127 101325 623420 20 0.6004 298.1444 101325 118000
0.121 323.127 101325 627600 21 0.5328 298.1444 101325 193200
0.137 323.127 101325 627600 22 0.4584 298.1444 101325 260500
0.14 323.127 101325 648520 23 0.3823 298.1444 101325 325300
0.149 323.127 101325 669440 24 0.2981 298.1444 101325 382500
0.155 323.127 101325 648520 25 0.1079 298.1444 101325 405400
0.254 323.127 101325 694540 26 0.0659 298.1444 101325 326700
0.258 323.127 101325 665260 1 0.016 308.132 101325 200830
0.468 323.127 101325 556470 2 0.023 308.132 101325 271960
0.631 323.127 101325 389110 3 0.049 308.132 101325 389110
0.632 323.127 101325 368190 4 0.07 308.132 101325 447690
0.637 323.127 101325 368190 5 0.09 308.132 101325 489530
0.732 323.127 101325 225940 6 0.115 308.132 101325 506260
0.736 323.127 101325 230120 7 0.195 308.132 101325 564840
0.739 323.127 101325 234300 8 0.211 308.132 101325 569020
0.867 323.127 101325 87860 9 0.381 308.132 101325 472790
0.87 323.127 101325 100420 10 0.558 308.132 101325 338900
0.943 323.127 101325 29290 11 0.658 308.132 101325 192460
0.468 323.127 101325 531370 12 0.66 308.132 101325 184100
0.0465 298.136 101000 279073 13 0.812 308.132 101325 29290
0.1274 298.136 101000 337230 14 0.815 308.132 101325 29290
0.1346 298.136 101000 339741 2 0.0948 308.1416 101325 497000
0.1796 298.136 101000 344762 27 0.9478 308.1416 101325 -23210
0.2072 298.136 101000 336812 28 0.9032 308.1416 101325 -22030
0.2705 298.136 101000 315892 29 0.7592 308.1416 101325 62030
0.301 298.136 101000 310871 30 0.7043 308.1416 101325 123800
0.304 298.136 101000 312963 31 0.6459 308.1416 101325 191800
0.4195 298.136 101000 250203 32 0.5151 308.1416 101325 362500
0.4892 298.136 101000 198322 33 0.4436 308.1416 101325 448000
0.6034 298.136 101000 121336 34 0.3647 308.1416 101325 512600
0.8577 298.136 101000 -9205 35 0.2817 308.1416 101325 575700
0.9127 298.136 101000 -25104
0.039 298.1444 101000 278000 Brown, I.; Fock, W. Aust. J. Chem., 1955, 8,
0.04 298.1444 101000 283000 361 Heats of mixing of alcohol solutions
0.198 298.1444 101000 361000
Findlay, T. J. V. Aust. J. Chem., 1961, 14,
0.2 298.1444 101000 363000 520 The heat of mixing for binary mixtures
0.299 298.1444 101000 336000 of triethylamine with alcohols
0.3 298.1444 101000 334000 Faraday Soc., 1962, 58, 879-89
Thermodynamic properties of solutions of
0.4 298.1444 101000 281000 alcohols and carbon tetrachloride: part 2
0.0306 298.1444 101325 238600 heats and entropies of mixing
0.0702 298.1444 101325 296400 Application of wilson's equation to
determination of vapor-liquid equilibrium
0.1203 298.1444 101325 321800 data and heats of mixing for non-ideal
0.1777 298.1444 101325 326500 solutions
0.2896 298.1444 101325 297100 Stokes, R. H.; Burfitt, C. J. Chem.
Thermodyn., 1973, 5, 623-31 Enthalpies of
0.3538 298.1444 101325 268800 dilution and transfer of ethanol in non-
0.4664 298.1444 101325 202900 polar solvents
0.5609 298.1444 101325 141500
0.6239 298.1444 101325 99600 Nagata, I.; Tamura, K. J. Chem.
0.678 298.1444 101325 64600 Thermodyn., 1984, 16, 975-80
0.6981 298.1444 101325 53000
Luo, Y. S.; Cen, P. L.; Li, B. G.; Zhou, J. D.;
0.7075 298.1444 101325 46700 Zhu, Z. -Q. Fluid Phase Equilib., 1985, 20,
0.7382 298.1444 101325 31900 137-44
0.7833 298.1444 101325 7800
0.8299 298.1444 101325 -11700
0.8799 298.1444 101325 -24500
0.9031 298.1444 101325 -26500
0.9437 298.1444 101325 -23300
0.9719 298.1444 101325 -14700
Scatchard, G.; Ticknor, L. B.; Goates, J. R.;
McCartney, E. R. J. Am. Chem. Soc., 1952,
74, 3721-4 Heats of mixing in some
nonelectrolyte solutions
Moelwyn-Hughes, E. A.; Missen, R. W. J.
Phys. Chem., 1957, 61, 518
Phys. Chem., 1957, 61, 518
Thermodynamic properties of methyl
alcohol-chloromethane solutions.
Faraday Soc., 1962, 58, 879-89
Thermodynamic properties of solutions of
alcohols and carbon tetrachloride: part 2
heats and entropies of mixing
Dacre, B.; Benson, G. C. Can. J. Chem.,
1963, 41, 278 Application of quasi-lattice
theory to alcohol-carbon tetrachloride
systems
Abramov, E. V.; Mirzayan, A. S.; Devina, O.
A. Izv. Akad. Nauk Kaz. SSR, Ser. Khim.,
1973, 23, 29 Heats of formation of ternary
systems: III
1983, 15, 67-79 Excess enthalpies of
binary and ternary mixtures of methanol
with acetone, chloroform, benzene, and
tetrachloromethane.
1-Propanol - Tetrachloromethane 2-Propanol - Tetrachloromethane

Mole Excess Mole


Temperat Pressure Temperat
No. fraction enthalpy No. fraction
ure (K) (N/sqm) ure (K)
1-PRO-01 (J/kmol) ISOPR-01

7 0.101 273.1 101325 230120 4 0.06 308.1416


8 0.168 273.1 101325 242670 5 0.076 308.1416
9 0.324 273.1 101325 146440 6 0.098 308.1416
10 0.482 273.1 101325 46020 7 0.144 308.1416
11 0.492 273.1 101325 41840 8 0.193 308.1416
12 0.604 273.1 101325 -66940 9 0.365 308.1416
13 0.766 273.1 101325 -121340 10 0.523 308.1416
14 0.879 273.1 101325 -117150 11 0.666 308.1416
15 0.885 273.1 101325 -108780 1 0.9553 288.1466
16 0.937 273.1 101325 -75310 2 0.9013 288.1466
17 0.013 293.138 101325 188280 3 0.8443 288.1466
18 0.025 293.138 101325 267780 4 0.728 288.1466
19 0.039 293.138 101325 301250 5 0.6672 288.1466
20 0.054 293.138 101325 338900 6 0.6045 288.1466
21 0.069 293.138 101325 359820 7 0.4748 288.1466
22 0.082 293.138 101325 380740 8 0.406 288.1466
23 0.101 293.138 101325 397480 9 0.33 288.1466
24 0.179 293.138 101325 439320 10 0.2594 288.1466
25 0.182 293.138 101325 451870 11 0.1814 288.1466
26 0.321 293.138 101325 414220 12 0.1245 288.1466
27 0.486 293.138 101325 263590 13 0.942 298.1444
28 0.49 293.138 101325 251040 14 0.8876 298.1444
29 0.603 293.138 101325 138070 15 0.8316 298.1444
30 0.606 293.138 101325 129700 16 0.7145 298.1444
31 0.772 293.138 101325 4184 17 0.5902 298.1444
32 0.773 293.138 101325 -4184 18 0.525 298.1444
33 0.879 293.138 101325 -41840 19 0.4561 298.1444
34 0.885 293.138 101325 -41840 20 0.4 298.1444
35 0.936 293.138 101325 -29290 21 0.3167 298.1444
36 0.019 308.132 101325 238490 22 0.2406 298.1444
37 0.029 308.132 101325 338900 23 0.1658 298.1444
38 0.063 308.132 101325 476980 24 0.1065 298.1444
39 0.101 308.132 101325 548100 25 0.9381 308.1416
40 0.185 308.132 101325 644340 26 0.8861 308.1416
41 0.19 308.132 101325 635970 27 0.8314 308.1416
42 0.338 308.132 101325 610860 28 0.717 308.1416
43 0.343 308.132 101325 602500 29 0.5957 308.1416
44 0.346 308.132 101325 610860 30 0.5307 308.1416
45 0.49 308.132 101325 497900 31 0.4652 308.1416
46 0.639 308.132 101325 297060 32 0.3976 308.1416
47 0.762 308.132 101325 133890 33 0.3278 308.1416
48 0.887 308.132 101325 29290 34 0.2557 308.1416
49 0.937 308.132 101325 8370 35 0.1812 308.1416
50 0.101 308.132 101325 556470 36 0.1237 308.1416
51 0.04 323.127 101325 476980 1 0.0099 298.1444
52 0.059 323.127 101325 569020 2 0.038 298.1444
53 0.074 323.127 101325 665260 3 0.1138 298.1444
54 0.093 323.127 101325 723830 4 0.2312 298.1444
55 0.176 323.127 101325 861900 5 0.3343 298.1444
56 0.182 323.127 101325 857720 6 0.4121 298.1444
57 0.336 323.127 101325 870270 7 0.4801 298.1444
58 0.484 323.127 101325 744750 8 0.5364 298.1444
59 0.597 323.127 101325 577390 9 0.5365 298.1444
60 0.603 323.127 101325 564840 10 0.5499 298.1444
61 0.771 323.127 101325 292880 11 0.5796 298.1444
62 0.89 323.127 101325 108780 12 0.6115 298.1444
63 0.902 323.127 101325 92050 13 0.6578 298.1444
64 0.093 323.127 101325 719650 14 0.7085 298.1444
1 0.9635 298.1444 101000 -16800 15 0.7671 298.1444
2 0.0104 298.1444 101000 156400 16 0.8291 298.1444
3 0.0617 298.1444 101000 380100 17 0.867 298.1444
4 0.1541 298.1444 101000 475700 18 0.9097 298.1444
5 0.273 298.1444 101000 485300 19 0.9526 298.1444
6 0.3601 298.1444 101000 441600 of isopropyl alcohol in binary syst
containing carbon tetrachlorid
7 0.4184 298.1444 101000 394300 diisopropyl ether, and poly-(propy
8 0.4707 298.1444 101000 343400 oxide)
9 0.5108 298.1444 101000 301300
Sabesan, R.; Varadarajan, R.;
10 0.5528 298.1444 101000 255100 Sargurumoorthy, M. Adv. Mol. Re
11 0.5643 298.1444 101000 238200 Interact. Processes, 1981, 20, 137
12 0.5829 298.1444 101000 221500
Luo, Y. S.; Cen, P. L.; Li, B. G.; Zhou,
13 0.5968 298.1444 101000 202200 Zhu, Z. -Q. Fluid Phase Equilib., 198
14 0.6377 298.1444 101000 157500 137-44
15 0.6813 298.1444 101000 111800
16 0.703 298.1444 101000 90000 Nagata, I.; Tamura, K. J. Chem
17 0.7602 298.1444 101000 40800 Thermodyn., 1986, 18, 827-33
18 0.8265 298.1444 101000 -700
19 0.9194 298.1444 101000 -24100
Faraday Soc., 1962, 58, 879-89
Thermodynamic properties of solutions of
alcohols and carbon tetrachloride: part 2
heats and entropies of mixing

Nagata, I.; Tamura, K. J. Chem.


Thermodyn., 1986, 18, 827-33
l - Tetrachloromethane Methanol - Acetic acid Methanol -

Mole
Excess Excess
Pressure fraction Temperat Pressure
enthalpy No. enthalpy No.
(N/sqm) METHA- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01

101325 81400 7 0.344 298.1444 101000 -8400 7


101325 99360 8 0.403 298.1444 101000 -36500 8
101325 121370 9 0.441 298.1444 101000 -61900 9
101325 157480 10 0.502 298.1444 101000 -88400 10
101325 184070 11 0.543 298.1444 101000 -108000 11
101325 209280 12 0.557 298.1444 101000 -113000 12
101325 177170 13 0.6 298.1444 101000 -125000 13
101325 130170 14 0.65 298.1444 101000 -131000 14
101325 38360 15 0.7 298.1444 101000 -135000
101325 89180 16 0.8 298.1444 101000 -111000
101325 146100 17 0.868 298.1444 101000 -82900
101325 261100 18 0.898 298.1444 101000 -67500
101325 316700 19 0.95 298.1444 101000 -35100
101325 368800 1 0.051 298.1444 101300 34370
101325 465300 2 0.1357 298.1444 101300 44400
101325 502200 3 0.1912 298.1444 101300 25510
101325 537200 4 0.2448 298.1444 101300 3850
101325 540100 5 0.3007 298.1444 101300 -30980
101325 507200 6 0.4139 298.1444 101300 -119800
101325 423800 7 0.5294 298.1444 101300 -198480
101325 71580 8 0.6426 298.1444 101300 -261590
101325 141300 9 0.6923 298.1444 101300 -268710
101325 217100 10 0.7348 298.1444 101300 -268460
101325 373400 11 0.8008 298.1444 101300 -256440
101325 535200 12 0.8602 298.1444 101300 -212440
101325 591000 13 0.912 298.1444 101300 -133180
101325 648800 14 0.9445 298.1444 101300 -77830
101325 690700 1 0.0348 303.15 1550000 45450
101325 713000 2 0.0689 303.15 1550000 70500
101325 711600 3 0.1351 303.15 1550000 81490
101325 648800 4 0.2297 303.15 1550000 51650
101325 555600 5 0.3191 303.15 1550000 1150
101325 101200 6 0.4309 303.15 1550000 -71870
101325 191400 7 0.535 303.15 1550000 -126900
101325 296200 8 0.6321 303.15 1550000 -152800
101325 494500 9 0.7231 303.15 1550000 -153000
101325 694200 10 0.8084 303.15 1550000 -126500
101325 780700 11 0.8689 303.15 1550000 -94050
101325 852100 12 0.9268 303.15 1550000 -55460
101325 883500 13 0.9639 303.15 1550000 -27890
101325 879800 14 0.9821 303.15 1550000 -14760
101325 841400 15 0.0351 323.15 1550000 33550
101325 764300 16 0.0696 323.15 1550000 59270
101325 641500 17 0.1363 323.15 1550000 75340
101000 159500 18 0.2315 323.15 1550000 52970
101000 348800 19 0.3213 323.15 1550000 6460
101000 552800 20 0.4334 323.15 1550000 -61990
101000 697500 21 0.5375 323.15 1550000 -113200
101000 739200 22 0.6345 323.15 1550000 -138500
101000 723600 23 0.7251 323.15 1550000 -137100
101000 683000 24 0.8099 323.15 1550000 -113200
101000 631000 25 0.8701 323.15 1550000 -85550
101000 627900 26 0.9274 323.15 1550000 -50720
101000 613700 27 0.9643 323.15 1550000 -25870
101000 582500 28 0.9823 323.15 1550000 -11230
101000 537800 Abramov, E. V.; Mirzayan, A. S.; Devina, O.
A. Izv. Akad. Nauk Kaz. SSR, Ser. Khim.,
101000 474200 1973, 23(3), 29 Heats of formation of
101000 398600 ternary systems: III
101000 309200 Thermodyn., 1989, 21, 811 Excess molar
enthalpies of (an alkanol + a carboxylic
101000 214800 acid) at 298.15 K measured with a Picker
101000 159900 calorimeter
101000 104200 Fluid Phase Equilib., 2001, 180(1-2), 221-
234 Phase equilibria and excess properties
101000 50300 for binary systems in reactive distillation
ropyl alcohol in binary systems processes Part I. Methyl acetate synthesis
aining carbon tetrachloride,
opyl ether, and poly-(propylene
oxide)

besan, R.; Varadarajan, R.;


umoorthy, M. Adv. Mol. Relax.
t. Processes, 1981, 20, 137-48

.; Cen, P. L.; Li, B. G.; Zhou, J. D.;


Q. Fluid Phase Equilib., 1985, 20,
137-44

ata, I.; Tamura, K. J. Chem.


rmodyn., 1986, 18, 827-33
Methanol - Propionic acid Ethanol - Acetic acid

Mole Mole
Excess Excess
fraction Temperat Pressure fraction Temperat Pressure
enthalpy No. enthalpy
METHA- ure (K) (N/sqm) ETHAN- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01 01

0.5847 298.1444 101300 118460 7 0.3 295.637 101325 240000


0.6655 298.1444 101300 38050 8 0.2 295.637 101325 220000
0.7205 298.1444 101300 -6800 9 0.1 295.637 101325 150000
0.7608 298.1444 101300 -32950 1 0.0288 298.1444 101300 99860
0.7989 298.1444 101300 -40370 2 0.0655 298.1444 101300 186270
0.8398 298.1444 101300 -45090 3 0.1042 298.1444 101300 244020
0.8816 298.1444 101300 -41450 4 0.1426 298.1444 101300 308250
0.926 298.1444 101300 -34040 5 0.1844 298.1444 101300 336550
Thermodyn., 1989, 21, 811 Excess molar 6 0.2381 298.1444 101300 352950
enthalpies of (an alkanol + a carboxylic
acid) at 298.15 K measured with a Picker 7 0.3042 298.1444 101300 350730
calorimeter 8 0.4103 298.1444 101300 302900
9 0.5085 298.1444 101300 239780
10 0.608 298.1444 101300 156210
11 0.7123 298.1444 101300 80960
12 0.812 298.1444 101300 44620
13 0.8864 298.1444 101300 23020
14 0.9423 298.1444 101300 10840
1 0.9753 323.15 1548000 45100
2 0.9507 323.15 1548000 84400
3 0.9013 323.15 1548000 145000
4 0.8271 323.15 1548000 196000
5 0.7527 323.15 1548000 215000
6 0.6533 323.15 1548000 212000
7 0.5536 323.15 1548000 182000
8 0.4536 323.15 1548000 148000
9 0.3533 323.15 1548000 111000
10 0.2527 323.15 1548000 80300
11 0.1771 323.15 1548000 60800
12 0.1013 323.15 1548000 38900
13 0.0507 323.15 1548000 21100
14 0.0254 323.15 1548000 11700
Longtin, B. J. Phys. Chem., 1942, 46, 399-
405 Heats of mixing in the ternary system
ethanol - acetic acid - ethyl acetate by a
rapid approximate method
Thermodyn., 1989, 21, 811 Excess molar
enthalpies of (an alkanol + a carboxylic
acid) at 298.15 K measured with a Picker
calorimeter
376, 48-54 Phase equilibria and excess
properties for binary systems in reactive
distillation processes Part II. Ethyl acetate
synthesis
Ethanol - Propionic acid 1-Propanol - Acetic acid

Mole
Excess Mole
fraction Temperat Pressure Temperat
No. enthalpy No. fraction
ETHAN- ure (K) (N/sqm) ure (K)
(J/kmol) 1-PRO-01
01

7 0.3503 298.1444 101300 456920 7 0.4336 298.1444


8 0.4148 298.1444 101300 425600 8 0.5064 298.1444
9 0.4773 298.1444 101300 379730 9 0.6049 298.1444
10 0.5644 298.1444 101300 305850 10 0.6967 298.1444
11 0.6557 298.1444 101300 215770 11 0.787 298.1444
12 0.7459 298.1444 101300 129450 12 0.8733 298.1444
13 0.8364 298.1444 101300 52800 13 0.9357 298.1444
14 0.8995 298.1444 101300 20280 1 0.0488 313.15
Thermodyn., 1989, 21, 811 Excess molar 2 0.0507 313.15
enthalpies of (an alkanol + a carboxylic
acid) at 298.15 K measured with a Picker 3 0.1002 313.15
calorimeter 4 0.101 313.15
5 0.2002 313.15
6 0.2005 313.15
7 0.2951 313.15
8 0.2964 313.15
9 0.4 313.15
10 0.4001 313.15
11 0.4995 313.15
12 0.5006 313.15
13 0.5994 313.15
14 0.6 313.15
15 0.6998 313.15
16 0.6999 313.15
17 0.7991 313.15
18 0.7996 313.15
19 0.8989 313.15
20 0.8997 313.15
21 0.9503 313.15
22 0.9511 313.15
Thermodyn., 1989, 21, 811 Excess
enthalpies
Letyanina,ofI.;(an alkanol
Tsvetov, N.;+ Zvereva
a carbo
acid) at 298.15
Samarov, A.;KToikka,
measured withPha
A. Fluid a
Equilib., 2014,calorimeter
381, 77-82 Excess m
enthalpies for binary mixtures o
propanol, acetic acid, and n-pro
acetate at 313.15 K and atmosph
pressure
panol - Acetic acid 1-Propanol - Propionic acid 2-Propano

Excess Mole Excess


Pressure Temperat Pressure
enthalpy No. fraction enthalpy No.
(N/sqm) ure (K) (N/sqm)
(J/kmol) 1-PRO-01 (J/kmol)

101300 328270 7 0.3814 298.1444 101300 557900


101300 313990 8 0.4413 298.1444 101300 544010
101300 275080 9 0.5098 298.1444 101300 508690
101300 233370 10 0.5971 298.1444 101300 433930
101300 171850 11 0.689 298.1444 101300 320200
101300 113760 12 0.7949 298.1444 101300 202290
101300 52790 13 0.8834
Zhao, 298.1444
J.; Bao, J.; Hu,101300 122920
Y. J. Chem.
101000 122000 Thermodyn., 1989, 21, 811 Excess molar
enthalpies of (an alkanol + a carboxylic
101000 126000 acid) at 298.15 K measured with a Picker
101000 218000 calorimeter
101000 219000
101000 338000
101000 338000
101000 389000
101000 390000
101000 408000
101000 409000
101000 393000
101000 392000
101000 358000
101000 359000
101000 307000
101000 307000
101000 237000
101000 236000
101000 137000
101000 136000
101000 73000
101000 69200
dyn., 1989, 21, 811 Excess molar
ies
ina,ofI.;(an alkanol
Tsvetov, N.;+ Zvereva,
a carboxylic
I.;
298.15
rov, A.;KToikka,
measured withPhase
A. Fluid a Picker
2014,calorimeter
381, 77-82 Excess molar
pies for binary mixtures of n-
nol, acetic acid, and n-propyl
e at 313.15 K and atmospheric
pressure
2-Propanol - Acetic acid 2-Propanol - Propionic acid

Liquid Vapor Liquid Vapor


Total Total
mole Temperat mole mole Temperat mole
pressure No. pressure
fraction ure (K) fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
2PROP 2PROP ISOPR-01 ISOPR-01
Methanol - Methyl Formate Methanol - Methyl Acetate

Mole Mole
Excess
fraction Temperat Pressure fraction Temperat
No. enthalpy No.
METHA- ure (K) (N/sqm) METHA- ure (K)
(J/kmol)
01 01

7 0.4689 298.15 101300 1038000 7 0.837 293.3379


8 0.4276 298.15 101300 1045000 1 0.837 293.3379
9 0.3866 298.15 101300 1046000 2 0.669 293.3379
10 0.3251 298.15 101300 1021000 3 0.561 293.3379
11 0.2387 298.15 101300 909000 4 0.493 293.3379
12 0.1865 298.15 101300 807000 5 0.373 293.3379
13 0.1152 298.15 101300 600000 6 0.306 293.3379
14 0.0568 298.15 101300 340000 7 0.168 293.3379
1 0.98 298.15 100000 75000 1 0.05 298.1444
2 0.9513 298.15 100000 179000 2 0.1 298.1444
3 0.9167 298.15 100000 311000 3 0.15 298.1444
4 0.8775 298.15 100000 441000 4 0.2 298.1444
5 0.833 298.15 100000 577000 5 0.25 298.1444
6 0.7865 298.15 100000 703000 6 0.3 298.1444
7 0.7387 298.15 100000 817000 7 0.35 298.1444
8 0.6914 298.15 100000 914000 8 0.4 298.1444
9 0.6499 298.15 100000 987000 9 0.45 298.1444
10 0.6356 298.15 100000 1010000 10 0.5 298.1444
11 0.6057 298.15 100000 1054000 11 0.55 298.1444
12 0.5923 298.15 100000 1074000 12 0.6 298.1444
13 0.5428 298.15 100000 1131000 13 0.65 298.1444
14 0.4873 298.15 100000 1179000 14 0.7 298.1444
15 0.4217 298.15 100000 1196000 15 0.75 298.1444
16 0.354 298.15 100000 1178000 16 0.8 298.1444
17 0.2822 298.15 100000 1105000 17 0.85 298.1444
18 0.2158 298.15 100000 984000 18 0.9 298.1444
19 0.1483 298.15 100000 808000 19 0.95 298.1444
20 0.0902 298.15 100000 584000 1 0.0134 298.1444
21 0.0495 298.15 100000 339000 2 0.0269 298.1444
Lopez, M.; Fernandez, J.; Sarmiento, F.; 3 0.0391 298.1444
Legido, J. L.; Romani, L.; Jimenez Cuesta,
E.; Paz Andrade, M. I. J. Chem. 4 0.0474 298.1444
Thermodyn., 1992, 24, 809-814 5 0.0537 298.1444
6 0.0761 298.1444
Fernandez, L.; Ortega, J.; Perez, N.;
Toledo, F. J. Chem. Thermodyn., 2015, 86, 7 0.1087 308.1416
80-89 8 0.2142 298.1444
9 0.2221 308.1416
10 0.3132 298.1444
11 0.3139 308.1416
12 0.3341 308.1416
13 0.3648 308.1416
14 0.4072 308.1416
15 0.4089 298.1444
16 0.4277 308.1416
17 0.4531 308.1416
18 0.51 298.1444
19 0.5117 308.1416
20 0.557 308.1416
21 0.5655 298.1444
22 0.6062 308.1416
23 0.6086 308.1416
24 0.6088 298.1444
25 0.7063 298.1444
26 0.7068 308.1416
27 0.7989 308.1416
28 0.8034 298.1444
29 0.8184 308.1416
30 0.8762 298.1444
31 0.8936 308.1416
32 0.9539 298.1444
1 0.0134 298.1444
2 0.0269 298.1444
3 0.0391 298.1444
4 0.0474 298.1444
5 0.0537 298.1444
6 0.0761 298.1444
7 0.1043 318.1386
8 0.1087 308.1416
9 0.2115 318.1386
10 0.2142 298.1444
11 0.2221 308.1416
12 0.311 318.1386
13 0.3132 298.1444
14 0.3139 308.1416
15 0.3341 308.1416
16 0.3648 308.1416
17 0.4072 308.1416
18 0.4086 318.1386
19 0.4089 298.1444
20 0.4277 308.1416
21 0.4531 308.1416
22 0.5054 318.1386
23 0.51 298.1444
24 0.5117 308.1416
25 0.557 308.1416
26 0.5655 298.1444
27 0.6062 308.1416
28 0.6081 318.1386
29 0.6086 308.1416
30 0.6088 298.1444
31 0.7063 298.1444
32 0.7067 318.1386
33 0.7068 308.1416
34 0.7099 318.1386
35 0.7542 318.1386
36 0.7989 308.1416
37 0.8034 298.1444
38 0.8184 308.1416
39 0.8762 298.1444
40 0.8936 308.1416
41 0.8994 318.1386
42 0.9513 318.1386
43 0.9539 298.1444

Onken, U. Z. Phys. Chem. (Leipzig),


33, 162
33, 162-9 Enthalpies of mixing of
systems methyl acetate - metha
acetone - chloroform, and cyclohex
aniline
heats of mixing of two liquids exc
enthalpies of ethyl acetate + n-bu
and methyl acetate + methanol mix
at 25c
Nagata, I.; Tago, O.; Takahashi, T. K
Kogaku, 1970, 34, 1107 Heats of m
for binary methyl ethyl ketone - m
acetate - alcohol systems
Eng. Jpn., 1972, 5, 227-31 Exce
thermodynamic functions of me
acetate + methanol and methyl ace
ethanol systems
nol - Methyl Acetate Methanol - Ethyl Acetate Methanol -

Mole
Excess Excess
Pressure fraction Temperat Pressure
enthalpy No. enthalpy No.
(N/sqm) METHA- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01

101325 532000 7 0.4941 298.136 101325 1042400 7


101000 590781 8 0.5698 298.136 101325 977100 8
101000 900815 9 0.653 298.136 101325 889400 9
101000 975709 10 0.7401 298.136 101325 660400 10
101000 946839 11 0.7805 298.136 101325 577100 11
101000 871527 12 0.8371 298.136 101325 444300 12
101000 767764 13 0.899 298.136 101325 286900 13
101000 464842 14 0.9438 298.136 101325 159900 14
101325 248000 15 0.9796 298.136 101325 65900 15
101325 455000 1 0.9617 298.1444 101325 128700 16
101325 624000 2 0.9576 308.1416 101325 180200 17
101325 759000 3 0.9569 308.1416 101325 188400 18
101325 862000 4 0.9345 298.1444 101325 210000
101325 938000 5 0.9026 298.1444 101325 296800
101325 988000 6 0.837 308.1416 101325 549200
101325 1016000 7 0.8067 298.1444 101325 554700
101325 1022000 8 0.7314 308.1416 101325 766900
101325 1009000 9 0.7019 298.1444 101325 774100
101325 978000 10 0.6414 308.1416 101325 915500
101325 931000 11 0.593 298.1444 101325 978200
101325 868000 12 0.561 308.1416 101325 997700
101325 790000 13 0.4853 298.1444 101325 1057000
101325 698000 14 0.485 308.1416 101325 1030000
101325 590000 15 0.3986 308.1416 101325 1013000
101325 467000 16 0.3846 298.1444 101325 1013000
101325 329000 17 0.3056 308.1416 101325 982400
101325 173000 18 0.3042 298.1444 101325 942200
101325 73930 19 0.303 308.1416 101325 973600
101325 143300 20 0.2057 308.1416 101325 784700
101325 204800 21 0.1706 298.1444 101325 672200
101325 240500 22 0.115 298.1444 101325 526700
101325 273000 23 0.1065 308.1416 101325 487000
101325 374500 24 0.0569 308.1416 101325 308000
101325 517400 25 Murti,
0.0524 298.1444
P. S.; 101325
Van Winkle, M. Chem.281400
Eng.
101325 805700 26 Data
0.0123 298.1444 101325 75600
Ser., 1958, 3, 65-71 Heats of mixing
101325 864500 and excess thermodynamic properties at
25deg of binary systems of methanol,
101325 957800 ethyl alcohol, 1-propanol, and 2-propanol
101325 1003000 with ethyl acetate
101325 1021000 gibbs free energies and heats of mixing for
binary systems ethyl acetate with
101325 1031000 methanol, ethanol, 1-propanol, and 2-
101325 1075000 propanol
101325 998600
101325 1061000
101325 1063000
101325 973000
101325 1060000
101325 1041000
101325 951500
101325 976400
101325 966100
101325 925500
101325 769200
101325 798100
101325 620100
101325 558100
101325 564100
101325 400400
101325 353200
101325 156600
101325 73920
101325 143290
101325 204780
101325 240490
101325 273010
101325 374480
101325 535510
101325 517390
101325 870600
101325 805680
101325 864490
101325 1044990
101325 957800
101325 1003010
101325 1021010
101325 1031010
101325 1075010
101325 1101000
101325 997610
101325 1060980
101325 1062990
101325 1106990
101325 973000
101325 1059980
101325 1040970
101325 951480
101325 976380
101325 991710
101325 966090
101325 925480
101325 759210
101325 844400
101325 798100
101325 844610
101325 844480
101325 620110
101325 558080
101325 564110
101325 400390
101325 353210
101325 351000
101325 179500
101325 156600

U. Z. Phys. Chem. (Leipzig), 1961,


33, 162
2-9 Enthalpies of mixing of the
ms methyl acetate - methanol,
- chloroform, and cyclohexane -
aniline
of mixing of two liquids excess
ies of ethyl acetate + n-butanol
hyl acetate + methanol mixtures
at 25c
.; Tago, O.; Takahashi, T. Kagaku
1970, 34, 1107 Heats of mixing
ry methyl ethyl ketone - methyl
cetate - alcohol systems
Jpn., 1972, 5, 227-31 Excess
odynamic functions of methyl
methanol and methyl acetate +
ethanol systems
Methanol - Propyl Acetate Methanol - Butyl Acetate

Mole Mole
Excess Excess
fraction Temperat Pressure fraction Temperat Pressure
enthalpy No. enthalpy
METHA- ure (K) (N/sqm) METHA- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01 01

0.5221 298.15 101325 945300 1 0.1201 298.15 101325 647600


0.5621 298.15 101325 924000 2 0.2117 298.15 101325 930300
0.6321 298.15 101325 842000 3 0.2807 298.15 101325 1086700
0.6676 298.15 101325 791300 4 0.3369 298.15 101325 1159300
0.703 298.15 101325 731800 5 0.3953 298.15 101325 1200200
0.7435 298.15 101325 664100 6 0.4478 298.15 101325 1203100
0.7843 298.15 101325 577100 7 0.4973 298.15 101325 1186700
0.8254 298.15 101325 488900 8 0.5414 298.15 101325 1150000
0.8693 298.15 101325 382400 9 0.5825 298.15 101325 1103500
0.9117 298.15 101325 270300 10 0.6137 298.15 101325 1051200
0.9486 298.15 101325 162100 11 0.6669 298.15 101325 966900
0.9785 298.15 101325 71700 12 0.7055 298.15 101325 869200
13 0.7447 298.15 101325 792600
Ortega, J. Int. DATA Ser., Sel. Data
Mixtures, Ser. A, 1995, 23, 154-83 Excess 14 0.786 298.15 101325 681100
enthalpy 15 0.8274 298.15 101325 556300
16 0.8683 298.15 101325 451700
17 0.9055 298.15 101325 326200
18 0.9338 298.15 101325 238500
19 0.9598 298.15 101325 153600
20 0.9812 298.15 101325 70800
1 0.0956 318.15 101000 360000
2 0.1761 318.15 101000 658000
3 0.2722 318.15 101000 932000
4 0.3517 318.15 101000 1077000
5 0.4208 318.15 101000 1143000
6 0.4831 318.15 101000 1152000
7 0.5375 318.15 101000 1141000
8 0.5894 318.15 101000 1102000
9 0.635 318.15 101000 1052000
10 0.6767 318.15 101000 991000
11 0.7139 318.15 101000 922000
12 0.7483 318.15 101000 852000
13 0.7771 318.15 101000 779000
14 0.8031 318.15 101000 710000
15 0.8247 318.15 101000 641000
16 0.8445 318.15 101000 582000
17 0.8617 318.15 101000 522000
1 1 298.15 101000 0
2 0.8984 298.15 101000 350500
3 0.7928 298.15 101000 667000
4 0.6926 298.15 101000 913300
5 0.5938 298.15 101000 1090400
6 0.4957 298.15 101000 1188100
7 0.3933 298.15 101000 1192300
8 0.2923 298.15 101000 1084100
9 0.1915 298.15 101000 850400
10 0.0941 298.15 101000 490900
11 0 298.15 101000 0
Elektrochem., 1951, 55, 199-200
Thermodynamics of mixed phases: viii the
vaporization equilibrium of methanol +
butyl acetate

Ortega, J. Int. DATA Ser., Sel. Data


Mixtures, Ser. A, 1995, 23, 154-83 Excess
enthalpy
Advances in the Correlation of
Thermodynamic Properties of Binary
Systems Applied to Methanol Mixtures
with Butyl Esters
Measurement and Correlation of Excess
Molar Enthalpy of Binary Mixtures
Containing Butyl Acetate + 1-Alkanols (C1
C6) at 298.15 K
Ethanol - Ethyl Formate Ethanol - propyl Formate

Mole Mole
Excess
fraction Temperat Pressure fraction Temperat
No. enthalpy No.
ETHAN- ure (K) (N/sqm) ETHAN- ure (K)
(J/kmol)
01 01

7 0.8027 318.1386 101325 784000 7 0.5048 298.15


8 0.7093 308.1416 101325 969000 8 0.4495 298.15
9 0.701 298.1444 101325 858000 9 0.447 298.15
10 0.7006 318.1386 101325 1020000 10 0.3872 298.15
11 0.6073 298.1444 101325 998000 11 0.3119 298.15
12 0.6073 308.1416 101325 1117000 12 0.2322 298.15
13 0.6062 318.1386 101325 1169000 13 0.1504 298.15
14 0.511 308.1416 101325 1188000 14 0.0788 298.15
15 0.5053 298.1444 101325 1043000 Lopez, M.; Fernandez, J.; Sarmient
Legido, J. L.; Romani, L.; Jimenez Cu
16 0.5024 308.1416 101325 1205000 E.; Paz Andrade, M. I. J. Chem
17 0.4568 318.1386 101325 1223000 Thermodyn., 1992, 24, 809-81
18 0.4112 318.1386 101325 1213000
19 0.4073 298.1444 101325 1043000
20 0.4053 308.1416 101325 1206000
21 0.3328 318.1386 101325 1138000
22 0.3105 308.1416 101325 1091000
23 0.3086 318.1386 101325 1140000
24 0.3045 298.1444 101325 949000
25 0.2911 308.1416 101325 1077000
26 0.2184 298.1444 101325 807000
27 0.2172 308.1416 101325 928000
28 0.2005 318.1386 101325 895000
29 0.1701 318.1386 101325 812000
30 0.1639 308.1416 101325 786000
31 0.1189 298.1444 101325 531000
32 0.1154 308.1416 101325 603000
33 0.1056 318.1386 101325 565000
34 0.05 308.1416 101325 301000
1 0.9298 298.15 101300 340000
2 0.8652 298.15 101300 604000
3 0.7886 298.15 101300 861000
4 0.7449 298.15 101300 976000
5 0.6551 298.15 101300 1162000
6 0.5948 298.15 101300 1245000
7 0.5698 298.15 101300 1280000
8 0.5201 298.15 101300 1330000
9 0.4697 298.15 101300 1350000
10 0.4402 298.15 101300 1356000
11 0.4149 298.15 101300 1353000
12 0.3815 298.15 101300 1342000
13 0.3543 298.15 101300 1328000
14 0.3162 298.15 101300 1290000
15 0.2749 298.15 101300 1223000
16 0.2276 298.15 101300 1127000
17 0.1719 298.15 101300 973000
18 0.1079 298.15 101300 708000
19 0.0588 298.15 101300 434000
1 0.975 298.15 101300 104600
2 0.95 298.15 101300 230900
3 0.9 298.15 101300 458400
4 0.85 298.15 101300 648000
5 0.8 298.15 101300 815000
6 0.75 298.15 101300 959000
7 0.7 298.15 101300 1080000
8 0.65 298.15 101300 1181000
9 0.6 298.15 101300 1262000
10 0.55 298.15 101300 1323000
11 0.5 298.15 101300 1363000
12 0.45 298.15 101300 1383000
13 0.4 298.15 101300 1378000
14 0.35 298.15 101300 1349000
15 0.3 298.15 101300 1292000
16 0.25 298.15 101300 1205000
17 0.2 298.15 101300 1079000
18 0.15 298.15 101300 908000
19 0.1 298.15 101300 683000
20 0.05 298.15 101300 381600
21 0.025 298.15 101300 205700
gibbs free energies and heats of mixing for
binary systems: ethyl formate with
methanol, ethanol, 1-propanol, and 2-
propanol
Lopez, M.; Fernandez, J.; Sarmiento, F.;
Legido, J. L.; Romani, L.; Jimenez Cuesta,
E.; Paz Andrade, M. I. J. Chem.
Thermodyn., 1992, 24, 809-814
thermodynamic properties of binary
mixtures of ethyl formate with benzene,
ethanol, and 2,2,2-trifluoroethan-1-ol at
298.15 K
ol - propyl Formate Ethanol - Butyl Formate Ethanol - M

Mole
Excess Excess
Pressure fraction Temperat Pressure
enthalpy No. enthalpy No.
(N/sqm) ETHAN- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01

101300 1170000 7 0.8948 298.15 101300 385000 7


101300 1182000 8 0.8059 298.15 101300 625000 8
101300 1180000 9 0.7229 298.15 101300 790000 9
101300 1166000 10 0.6335 298.15 101300 927000 10
101300 1106000 11 0.6035 298.15 101300 959000 11
101300 966000 12 0.5519 298.15 101300 1004000 12
101300 730000 13 0.5143 298.15 101300 1028000 13
101300 443000 Lopez, M.; Fernandez, J.; Sarmiento, F.; 14
M.; Fernandez, J.; Sarmiento, F.; Legido, J. L.; Romani, L.; Jimenez Cuesta,
E.; Paz Andrade, M. I. J. Chem. 15
. L.; Romani, L.; Jimenez Cuesta,
Paz Andrade, M. I. J. Chem. Thermodyn., 1992, 24, 809-814 16
rmodyn., 1992, 24, 809-814 17
18
19
20
21
22
23
24
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
Ethanol - Methyl Acetate Ethanol - Ethyl Acetate

Mole Mole
Excess Excess
fraction Temperat Pressure fraction Temperat Pressure
enthalpy No. enthalpy
ETHAN- ure (K) (N/sqm) ETHAN- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01 01

0.4014 308.1416 101325 1460000 7 0.7679 298.1444 101325 893000


0.4037 298.1444 101325 1405000 8 0.6797 308.1416 101325 1141000
0.4584 298.1444 101325 1415000 9 0.6769 298.1444 101325 1079000
0.5046 308.1416 101325 1453000 10 0.5903 298.1444 101325 1211000
0.5054 298.1444 101325 1403000 11 0.5865 308.1416 101325 1243000
0.5548 308.1416 101325 1411000 12 0.5824 308.1416 101325 1293000
0.5559 298.1444 101325 1373000 13 0.5049 308.1416 101325 1330000
0.5945 308.1416 101325 1370000 14 0.4986 308.1416 101325 1328000
0.6037 298.1444 101325 1324000 15 0.481 298.1444 101325 1281000
0.6071 308.1416 101325 1355000 16 0.408 308.1416 101325 1367000
0.6875 308.1416 101325 1219000 17 0.3869 308.1416 101325 1352000
0.7047 298.1444 101325 1114000 18 0.3807 298.1444 101325 1256000
0.7599 308.1416 101325 1057000 19 0.3071 308.1416 101325 1230000
0.8013 298.1444 101325 863800 20 0.2844 298.1444 101325 1129000
0.847 298.1444 101325 696600 21 0.2725 308.1416 101325 1207000
0.8739 308.1416 101325 643700 22 0.2311 308.1416 101325 1127000
0.9043 298.1444 101325 474200 23 0.2037 308.1416 101325 1032000
0.9321 308.1416 101325 367100 24 0.1879 298.1444 101325 896000
0.95 298.1444 101325 253000 25 0.1115 308.1416 101325 720000
0.9 298.1444 101325 470000 26 0.1105 298.1444 101325 644000
0.85 298.1444 101325 655000 27 0.0932 298.1444 101325 568000
0.8 298.1444 101325 812000 28 0.0669 308.1416 101325 461000
0.75 298.1444 101325 946000 29 0.0601 308.1416 101325 437000
0.7 298.1444 101325 1057000 30 0.0384 298.1444 101325 276000
0.65 298.1444 101325 1149000 1 0.1 295.637 101325 600000
0.6 298.1444 101325 1223000 2 0.2 295.637 101325 1000000
0.55 298.1444 101325 1277000 3 0.3 295.637 101325 1170000
0.5 298.1444 101325 1313000 4 0.4 295.637 101325 1260000
0.45 298.1444 101325 1329000 5 0.5 295.637 101325 1240000
0.4 298.1444 101325 1323000 6 0.6 295.637 101325 1150000
0.35 298.1444 101325 1292000 7 0.7 295.637 101325 1000000
0.3 298.1444 101325 1234000 8 0.8 295.637 101325 780000
0.25 298.1444 101325 1142000 9 0.9 295.637 101325 440000
0.2 298.1444 101325 1013000 gibbs free energies and heats of mixing for
binary systems ethyl acetate with
0.15 298.1444 101325 842000 methanol, ethanol, 1-propanol, and 2-
0.1 298.1444 101325 612000 propanol
0.05 298.1444 101325 343000 Longtin, B. J. Phys. Chem., 1942, 46, 399-
405 Heats of mixing in the ternary system
0.0765 298.1444 101325 494870 ethanol - acetic acid - ethyl acetate by a
0.0898 318.1386 101325 678220 rapid approximate method
0.1084 308.1416 101325 671890
0.1207 298.1444 101325 709190
0.2074 318.1386 101325 1157970
0.2107 308.1416 101325 1089990
0.2945 318.1386 101325 1366980
0.308 298.1444 101325 1277990
0.3423 308.1416 101325 1405990
0.3983 318.1386 101325 1492980
0.4014 308.1416 101325 1459990
0.4037 298.1444 101325 1404990
0.4584 298.1444 101325 1414990
0.5046 308.1416 101325 1453000
0.5054 298.1444 101325 1402980
0.5142 318.1386 101325 1547980
0.5548 308.1416 101325 1410980
0.5559 298.1444 101325 1373010
0.5945 308.1416 101325 1369990
0.6037 298.1444 101325 1323990
0.6056 318.1386 101325 1461000
0.6071 308.1416 101325 1355010
0.6875 308.1416 101325 1219010
0.6986 318.1386 101325 1297990
0.7047 298.1444 101325 1113980
0.7599 308.1416 101325 1057010
0.8013 298.1444 101325 863780
0.8018 318.1386 101325 964580
0.847 298.1444 101325 696590
0.8739 308.1416 101325 643680
0.9043 298.1444 101325 474190
0.9321 308.1416 101325 367110
Nagata, I.; Tago, O.; Takahashi, T. Kagaku
Kogaku, 1970, 34, 1107 Heats of mixing
for binary methyl ethyl ketone - methyl
acetate - alcohol systems
Thermodynamic study of ester-alcohol
molecular interactions I parameters of
mixing of binary systems: ethyl acetate
and methyl acetate with different alcohols
Eng. Jpn., 1972, 5, 227-31 Excess
thermodynamic functions of methyl
acetate + methanol and methyl acetate +
ethanol systems
Ethanol - Propyl Acetate Ethanol - Butyl Acetate

Mole Mole
Excess
fraction Temperat Pressure fraction Temperat
No. enthalpy No.
ETHAN- ure (K) (N/sqm) ETHAN- ure (K)
(J/kmol)
01 01

7 0.465 348.15 101325 1665000 7 0.6341 298.15


8 0.515 348.15 101325 1658000 8 0.6787 298.15
9 0.564 348.15 101325 1625000 9 0.7155 298.15
10 0.614 348.15 101325 1552000 10 0.7557 298.15
11 0.662 348.15 101325 1435000 11 0.7959 298.15
12 0.708 348.15 101325 1298000 12 0.8361 298.15
13 0.753 348.15 101325 1063000 13 0.8758 298.15
14 0.8 348.15 101325 883000 14 0.9126 298.15
15 0.839 348.15 101325 676000 15 0.9421 298.15
16 0.881 348.15 101325 474000 16 0.9736 298.15
17 0.921 348.15 101325 302000 1 1 298.15
18 0.961 348.15 101325 169000 2 0.8951 298.15
enthalpies for binary mixtures of ethanol 3 0.7961 298.15
+ benzene, + cyclohexane, + propyl
acetate and 1-propanol + benzene, + 4 0.6987 298.15
cyclohexane, + heptane at 348.15K 5 0.5976 298.15
6 0.4907 298.15
7 0.3986 298.15
8 0.2931 298.15
9 0.1949 298.15
10 0.0992 298.15
11 0 298.15

Ortega, J. Int. DATA Ser., Sel. Da


Mixtures, Ser. A, 1995, 23, 154-83 E
enthalpy
Measurement and Correlation of E
Molar Enthalpy of Binary Mixtur
Containing Butyl Acetate + 1-Alkano
C6) at 298.15 K
nol - Butyl Acetate Methanol - Pentane Methano
Liquid Vapor
Excess mole mole Total
Pressure Temperat
enthalpy No. fraction fraction pressure No.
(N/sqm) ure (K)
(J/kmol) METHA- METHA- (N/sqm)
01 01

101325 1217600
101325 1133200
101325 1030700
101325 921000
101325 793400
101325 660700
101325 516400
101325 380600
101325 260300
101325 126100
101000 0
101000 441400
101000 772900
101000 1033700
101000 1210500
101000 1306100
101000 1311700
101000 1184000
101000 936100
101000 566900
101000 0

a, J. Int. DATA Ser., Sel. Data


, Ser. A, 1995, 23, 154-83 Excess
enthalpy
ement and Correlation of Excess
r Enthalpy of Binary Mixtures
ng Butyl Acetate + 1-Alkanols (C1
C6) at 298.15 K
Methanol - Heptane Methanol - Octane
Liquid Vapor Liquid Vapor
mole mole Total mole mole Total
Temperat Temperat
fraction fraction pressure No. fraction fraction pressure
ure (K) ure (K)
METHA- METHA- (N/sqm) METHA- METHA- (N/sqm)
01 01 01 01
Ethanol - Hexane Ethanol - Heptane

Mole Excess Mole


Temperat Pressure Temperat
No. fraction enthalpy No. fraction
ure (K) (N/sqm) ure (K)
ETHANOL (J/kmol) ETHANOL

7 0.47 298.136 101325 563200 7 0.6715 298.136


8 0.679 298.136 101325 470700 8 0.746 298.136
9 0.83 298.136 101325 333000 9 0.8115 298.136
10 0.865 298.136 101325 305400 10 0.83 298.136
11 0.877 298.136 101325 290400 11 0.855 298.136
3 0.1394 298.136 101325 471000 12 0.875 298.136
6 0.2392 298.136 101325 545000 13 0.884 298.136
7 0.2512 298.136 101325 553000 14 0.91 298.136
9 0.2546 298.136 101325 552000 15 0.932 298.136
13 0.4134 298.136 101325 573000 16 0.95 298.136
14 0.4274 298.136 101325 572000 1 0.0377 293.1454
15 0.4372 298.136 101325 569000 2 0.0377 298.1444
17 0.4396 298.136 101325 569000 3 0.0379 303.1431
20 0.6819 298.136 101325 457000 4 0.0543 303.1431
23 0.6842 298.136 101325 453000 5 0.0876 298.1444
24 0.6984 298.136 101325 445000 6 0.0885 303.1431
25 0.6986 298.136 101325 448000 7 0.0901 293.1454
28 0.7009 298.136 101325 443000 8 0.1017 303.1431
31 0.8685 298.136 101325 253000 9 0.1584 303.1431
11 0.00051 298.1444 101325 11820.87 10 0.16 298.1444
12 0.001 298.1444 101325 23186.79 11 0.1621 303.1431
13 0.00151 298.1444 101325 34858.48 12 0.1659 293.1454
14 0.00198 298.1444 101325 45469.59 13 0.2738 303.1431
15 0.00246 298.1444 101325 56072.72 14 0.2758 298.1444
16 0.00292 298.1444 101325 65973.99 15 0.279 303.1431
17 0.00383 298.1444 101325 84395.12 16 0.2843 293.1454
18 0.00472 298.1444 101325 101048 17 0.4302 303.1431
19 0.00557 298.1444 101325 115321.5 18 0.4324 298.1444
20 0.0064 298.1444 101325 127816.7 19 0.4425 293.1454
21 0.0072 298.1444 101325 138674.3 20 0.5693 303.1431
22 0.00873 298.1444 101325 156720.1 21 0.5715 298.1444
23 0.01017 298.1444 101325 171333 22 0.5812 293.1454
24 0.01153 298.1444 101325 183378.7 23 0.6536 303.1431
25 0.0123 298.1444 101325 187940.5 24 0.6555 298.1444
26 0.01282 298.1444 101325 193758 25 0.6647 293.1454
27 0.01403 298.1444 101325 202379.1 26 0.692 298.1444
28 0.0216 298.1444 101325 242611.9 27 0.707 303.1431
29 0.0299 298.1444 101325 275847 28 0.7145 293.1454
30 0.0445 298.1444 101325 319323.3 29 0.7204 293.1454
31 0.0581 298.1444 101325 351330.6 30 0.726 303.1431
32 0.6914 298.1444 101325 454469.7 31 0.7269 298.1444
33 0.7159 298.1444 101325 434028.3 32 0.7677 303.1431
34 0.7423 298.1444 101325 410318.6 33 0.7833 293.1454
35 0.7707 298.1444 101325 381895.2 34 0.7957 298.1444
36 0.8013 298.1444 101325 348210.4 35 0.8052 303.1431
37 0.8345 298.1444 101325 307294.2 36 0.8461 303.1431
38 0.8522 298.1444 101325 283147.2 37 0.8668 293.1454
39 0.8705 298.1444 101325 256572.9 38 0.8851 303.1431
40 0.8897 298.1444 101325 226591.2 39 0.8875 298.1444
41 0.9098 298.1444 101325 192768.2 40 0.9389 303.1431
42 0.9308 298.1444 101325 154394 41 0.9422 293.1454
43 0.9526 298.1444 101325 110851.2 42 0.969 298.1444
44 0.964 298.1444 101325 86239.44 43 0.9703 293.1454
45 0.9752 298.1444 101325 61187.95 1 0.0025 303.1431
46 0.9879 298.1444 101325 30433.84 2 0.0064 323.1371
1 0.0738 308.132 101325 475000 3 0.0135 323.1371
2 0.1391 308.132 101325 583000 4 0.0171 303.1431
8 0.254 308.132 101325 676000 5 0.0245 323.1371
11 0.4122 308.132 101325 688000 6 0.0364 303.1431
16 0.4391 308.132 101325 683000 7 0.0521 323.1371
19 0.6807 308.132 101325 536000 8 0.0673 303.1431
22 0.6826 308.132 101325 533000 9 0.08 323.1371
26 0.7006 308.132 101325 516000 10 0.1179 323.1371
30 0.8647 308.132 101325 296000 11 0.1312 303.1431
4 0.1399 318.1285 101325 719000 12 0.1734 323.1371
5 0.2369 318.1285 101325 813000 13 0.2243 323.1371
10 0.255 318.1285 101325 827000 14 0.2455 303.1431
12 0.4133 318.1285 101325 833000 15 0.2942 323.1371
18 0.4404 318.1285 101325 826000 16 0.3397 303.1431
21 0.682 318.1285 101325 629000 17 0.3747 323.1371
27 0.7006 318.1285 101325 606000 18 0.4145 303.1431
29 0.8646 318.1285 101325 337000 19 0.4395 323.1371
47 0.00051 318.1386 101325 11321.32 20 0.4898 303.1431
48 0.00101 318.1386 101325 22399.35 21 0.5034 323.1371
49 0.00199 318.1386 101325 44030.51 22 0.558 323.1371
50 0.00247 318.1386 101325 54427.53 23 0.5588 303.1431
51 0.00294 318.1386 101325 64695.04 24 0.601 303.1431
52 0.00386 318.1386 101325 84515.31 25 0.6091 323.1371
53 0.00475 318.1386 101325 103436.3 26 0.6432 303.1431
54 0.00561 318.1386 101325 121277.2 27 0.6519 323.1371
55 0.00725 318.1386 101325 153809.2 28 0.6697 303.1431
56 0.00879 318.1386 101325 182531.8 29 0.6931 323.1371
57 0.01025 318.1386 101325 208174.1 30 0.7018 303.1431
58 0.01162 318.1386 101325 230388.6 31 0.7132 323.1371
59 0.0124 318.1386 101325 248721.1 32 0.718 323.1371
60 0.01291 318.1386 101325 249896.7 33 0.7244 303.1431
61 0.01413 318.1386 101325 267044.7 34 0.7342 323.1371
62 0.0215 318.1386 101325 352171.9 35 0.7521 303.1431
63 0.0303 318.1386 101325 418398.4 36 0.7569 323.1371
64 0.0451 318.1386 101325 497412.2 37 0.7813 323.1371
65 0.0585 318.1386 101325 545269.7 38 0.7814 303.1431
39 0.8089 303.1431
Bykov, V. T. Zh. Fiz. Khim., 1939, 13, 1013 40 0.8097 323.1371
Heats of mixing of liquids 41 0.8337 323.1371
42 0.8374 303.1431
Brown, I.; Fock, W.; Smith, F. Aust. J.
Chem., 1964, 17, 1106 Heats of mixing V 43 0.852 323.1371
systems of alcohol with n-hexane 44 0.8763 303.1431
Stokes, R. H.; Burfitt, C. J. Chem. 45 0.8814 323.1371
Thermodyn., 1973, 5, 623-31 Enthalpies of
dilution and transfer of ethanol in non- 46 0.9021 323.1371
polar solvents 47 0.9138 303.1431
48 0.9222 323.1371
49 0.9365 303.1431
50 0.9429 323.1371
51 0.9576 303.1431
52 0.9637 323.1371
53 0.9775 323.1371
54 0.98 303.1431
55 0.9871 303.1431
56 0.988 323.1371
57 0.9922 323.1371
58 0.9968 303.1431
59 0.9976 323.1371
1 0 298.15
2 0.0876 298.15
3 0.1785 298.15
4 0.2587 298.15
5 0.3311 298.15
6 0.3956 298.15
7 0.449 298.15
8 0.5013 298.15
9 0.5491 298.15
10 0.5987 298.15
11 0.6484 298.15
12 0.6846 298.15
13 0.7209 298.15
14 0.7546 298.15
15 0.7879 298.15
16 0.8215 298.15
17 0.8572 298.15
18 0.8908 298.15
19 0.9226 298.15
20 0.9531 298.15
21 0.9759 298.15
22 1 298.15
23 0.0634 318.15
24 0.0823 318.15
25 0.1258 318.15
26 0.1887 318.15
27 0.2453 318.15
28 0.2958 318.15
29 0.3971 318.15
30 0.4794 318.15
31 0.5417 318.15
32 0.5943 318.15
33 0.631 318.15
34 0.6363 318.15
35 0.6754 318.15
36 0.7253 318.15
37 0.7769 318.15
38 0.827 318.15
39 0.8723 318.15
40 0.914 318.15
41 0.9478 318.15
42 0.9759 318.15

Bykov, V. T. Zh. Fiz. Khim., 1939, 13


Heats of mixing of liquids
Naz. Lincei Cl. Sci. Fis. Mat. Nat. R
1968, 45, 540-9 Vapor-liquid equili
and heat of mixing of the ethylened
+ benzene system
C. J. Chem. Eng. Data, 1975, 20, 4
Excess thermodynamic functions
ternary systems: II chloroform + eth
n-heptane at 50c
Method for Vapor-Liquid Equilibria
Excess Enthalpies for Nonideal Solu
Using a Genetic Algorithm. Applicati
Ethanol + an n-Alkane Mixture
hanol - Heptane Ethanol - Octane Methano

Excess Mole Excess


Pressure Temperat Pressure
enthalpy No. fraction enthalpy No.
(N/sqm) ure (K) (N/sqm)
(J/kmol) ETHANOL (J/kmol)

101325 534700 7 0.1635 308.1416 101325 604000 7


101325 456400 8 0.1749 293.1454 101325 495000 8
101325 425500 9 0.1812 298.1444 101325 565000 9
101325 352300 10 0.281 308.1416 101325 687000 10
101325 326400 11 0.2978 293.1454 101325 568000 11
101325 290400 12 0.307 298.1444 101325 637000 12
101325 282000 13 0.4388 308.1416 101325 708000 13
101325 249800 14 0.4589 293.1454 101325 587000 14
101325 196600 15 0.4699 298.1444 101325 644000 15
101325 177000 16 0.5778 308.1416 101325 667000 16
101325 275000 17 0.5971 293.1454 101325 554000 17
101325 341000 18 0.6078 298.1444 101325 594000 18
101325 352000 19 0.6614 308.1416 101325 603000 19
101325 402000 20 0.6792 293.1454 101325 511000 1
101325 418000 21 0.6887 298.1444 101325 541000 2
101325 481000 22 0.6895 308.1416 101325 577000 3
101325 384000 23 0.7101 308.1416 101325 557000 4
101325 496000 24 0.7156 293.1454 101325 488000 5
101325 580000 25 0.7173 308.1416 101325 556000 6
101325 522000 26 0.7186 298.1444 101325 515000 7
101325 576000 27 0.7335 293.1454 101325 470000 8
101325 474000 28 0.7557 298.1444 101325 480000 9
101325 657000 29 0.7809 308.1416 101325 478000 10
101325 599000 30 0.7961 293.1454 101325 414000 11
101325 656000 31 0.8158 308.1416 101325 432000 12
101325 548000 32 0.8172 298.1444 101325 408000 13
101325 669000 33 0.8562 308.1416 101325 369000 1
101325 621000 34 0.8754 293.1454 101325 308000 2
101325 569000 35 0.8979 308.1416 101325 288000 3
101325 621000 36 0.8994 298.1444 101325 274000 4
101325 576000 37 0.9462 293.1454 101325 161000 5
101325 534000 38 0.9465 308.1416 101325 171000 6
101325 558000 39 0.9729 298.1444 101325 91000 7
101325 527000 1 0.0475 293.1454 101000 311000 8
101325 488000 2 0.0964 293.1454 101000 404000 9
101325 499000 3 0.1749 293.1454 101000 495000 10
101325 520000 4 0.2978 293.1454 101000 568000 11
101325 453000 5 0.4589 293.1454 101000 587000 12
101325 449000 6 0.5971 293.1454 101000 554000 13
101325 500000 7 0.6792 293.1454 101000 511000 14
101325 471000 8 0.7156 293.1454 101000 488000 15
101325 456000 9 0.7335 293.1454 101000 470000 16
101325 390000 10 0.7961 293.1454 101000 414000 17
101325 398000 11 0.8754 293.1454 101000 308000 18
101325 408000 12 0.9462 293.1454 101000 161000 19
101325 349000 13 0.0439 298.1444 101000 347000 1
101325 285000 14 0.1003 298.1444 101000 467000 2
101325 281000 15 0.1812 298.1444 101000 565000 3
101325 265000 16 0.307 298.1444 101000 637000 4
101325 168000 17 0.4699 298.1444 101000 644000 5
101325 148000 18 0.6078 298.1444 101000 549000 6
101325 88000 19 0.6887 298.1444 101000 541000 7
101325 81000 20 0.7186 298.1444 101000 515000 8
101325 52300 21 0.7556 298.1444 101000 480000 5
101325 143800 22 0.8172 298.1444 101000 408000 9
101325 269300 23 0.8994 298.1444 101000 274000 12
101325 243600 24 0.9729 298.1444 101000 91000 16
101325 411200 25 0.0342 303.1431 101000 353000 19
101325 336500 26 0.0879 303.1431 101000 497000 22
101325 588300 27 0.1635 303.1431 101000 604000 25
101325 426800 28 0.281 303.1431 101000 687000 28
101325 694400 29 0.4388 303.1431 101000 708000 31
101325 792600 30 0.5778 303.1431 101000 667000 33
101325 534800 31 0.6614 303.1431 101000 603000 36
101325 884600 32 0.6895 303.1431 101000 577000 38
101325 938000 33 0.7101 303.1431 101000 557000 42
101325 634700 34 0.7173 303.1431 101000 556000 44
101325 978100 35 0.7809 303.1431 101000 478000 47
101325 665600 36 0.8158 303.1431 101000 432000 51
101325 985900 37 0.8562 303.1431 101000 369000 54
101325 666600 38 0.8979 303.1431 101000 288000 58
101325 968600 39 0.9465 303.1431 101000 171000 63
101325 651200 1 0 298.15 101000 0 14
101325 934000 2 0.1066 298.15 101000 466500 15
101325 891200 3 0.2045 298.15 101000 596200 16
101325 623600 4 0.2915 298.15 101000 659800 17
101325 600100 5 0.3692 298.15 101000 684300 18
101325 840800 6 0.4305 298.15 101000 683200 19
101325 571800 7 0.4889 298.15 101000 677100 20
101325 790500 8 0.5413 298.15 101000 650600 21
101325 551200 9 0.589 298.15 101000 630000 22
101325 735200 10 0.6501 298.15 101000 584200 23
101325 523400 11 0.6765 298.15 101000 563700 24
101325 709200 12 0.704 298.15 101000 537900 25
101325 698200 13 0.7407 298.15 101000 493100 26
101325 502100 14 0.7791 298.15 101000 446800 27
101325 675700 15 0.8236 298.15 101000 384400 28
101325 473000 16 0.8686 298.15 101000 298200 29
101325 637800 17 0.911 298.15 101000 218600 30
101325 593700 18 0.9484 298.15 101000 137900 31
101325 438800 19 0.979 298.15 101000 66500 32
101325 403100 20 1 298.15 101000 0 33
101325 538200 21 0.0603 318.15 101000 586100 34
101325 487800 22 0.1149 318.15 101000 796400 35
101325 361600 23 0.1877 318.15 101000 900400 36
101325 446700 24 0.2596 318.15 101000 942900 37
101325 297300 25 0.3197 318.15 101000 950600 38
101325 375300 26 0.3849 318.15 101000 955300 39
101325 320900 27 0.4411 318.15 101000 940100 1
101325 224300 28 0.4925 318.15 101000 925200 4
101325 264500 29 0.5377 318.15 101000 895100 7
101325 174100 30 0.5794 318.15 101000 871800 8
101325 201800 31 0.6233 318.15 101000 830400 11
101325 122300 32 0.6664 318.15 101000 790900 14
101325 133500 33 0.7125 318.15 101000 749900 17
101325 85800 34 0.7563 318.15 101000 687400 20
101325 61200 35 0.8037 318.15 101000 609000 23
101325 39900 36 0.8486 318.15 101000 517500 27
101325 45900 37 0.8899 318.15 101000 412900 30
101325 30200 38 0.9249 318.15 101000 304600 34
101325 9700 39 0.954 318.15 101000 203500 37
101325 9500 40 0.9798 318.15 101000 98800 40
101000 0 Naz. Lincei Cl. Sci. Fis. Mat. Nat. Rend., 43
1968, 45, 540-9 Vapor-liquid equilibrium
101000 400400 and heat of mixing of the ethylenediamine 45
101000 537800 + benzene system 49
101000 593800 Ramalho, R. S.; Ruel, M. Can. J. Chem. 52
Eng., 1968, 46, 456-61 Heats of Mixing for
101000 625100 Binary Systems: n-Alkanes + n-Alcohols 55
101000 634900 and n-Alcohols alcohols 57
101000 629800 Method for Vapor-Liquid Equilibria and 60
Excess Enthalpies for Nonideal Solutions
101000 620900 Using a Genetic Algorithm. Application to 62
101000 600100 Ethanol + an n-Alkane Mixtures 40
101000 572400 41
101000 538900 42
101000 510000 43
101000 475700 44
101000 436900 45
101000 393300 46
101000 350600 47
101000 302500 48
101000 246800 49
101000 191600 50
101000 123900 51
101000 74500 52
101000 0 9
101000 560000 10
101000 654600 11
101000 753100 12
101000 842900 13
101000 887000 14
101000 901700 15
101000 893700 16
101000 869800 17
101000 843300 2
101000 798600 3
101000 768600 6
101000 757000 10
101000 721400 13
101000 664600 15
101000 591900 18
101000 506600 21
101000 406400 24
101000 299700 26
101000 197100 29
101000 99100 32
35
T. Zh. Fiz. Khim., 1939, 13, 1013 39
Heats of mixing of liquids 41
cei Cl. Sci. Fis. Mat. Nat. Rend., 46
, 540-9 Vapor-liquid equilibrium
of mixing of the ethylenediamine 48
+ benzene system 50
em. Eng. Data, 1975, 20, 406-9 53
thermodynamic functions for
ystems: II chloroform + ethanol + 56
n-heptane at 50c 59
for Vapor-Liquid Equilibria and 61
nthalpies for Nonideal Solutions
Genetic Algorithm. Application to 64
anol + an n-Alkane Mixtures
Methanol - Benzene Methanol - Toluene

Mole Mole
Excess Excess
fraction Temperat Pressure fraction Temperat Pressure
enthalpy No. enthalpy
METHA- ure (K) (N/sqm) METHA- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01 01

0.35 293.138 101000 662746 7 0.937 298.136 101325 96000


0.4 293.138 101000 658562 8 0.959 298.136 101325 67000
0.45 293.138 101000 647683 9 0.98 298.136 101325 33000
0.5 293.138 101000 627600 1 0.2442 308.132 101325 798400
0.55 293.138 101000 594965 2 0.2499 298.136 101325 756500
0.6 293.138 101000 549359 3 0.4007 308.132 101325 785800
0.65 293.138 101000 491620 4 0.4125 298.136 101325 744100
0.7 293.138 101000 426350 5 0.5497 298.136 101325 666000
0.75 293.138 101000 357732 6 0.6355 308.132 101325 616800
0.8 293.138 101000 291206 7 0.646 298.136 101325 554000
0.85 293.138 101000 228446 8 0.7286 298.136 101325 440000
0.9 293.138 101000 167778 9 0.7965 298.136 101325 339500
0.95 293.138 101000 99161 10 0.7971 308.132 101325 359800
0.9519 293.1454 101325 52580 11 0.8598 298.136 101325 310300
0.8978 293.1454 101325 121520 12 0.9133 298.136 101325 163300
0.8368 293.1454 101325 196510 13 0.9136 308.132 101325 163700
0.7672 293.1454 101325 286010 14 0.9575 298.136 101325 84100
0.6872 293.1454 101325 381060 1 0.0197 298.136 101325 239000
0.5942 293.1454 101325 471240 2 0.0629 298.136 101325 506000
0.4849 293.1454 101325 556500 3 0.0975 298.136 101325 600000
0.3545 293.1454 101325 615820 4 0.1235 298.136 101325 657000
0.1962 293.1454 101325 609770 5 0.1706 298.136 101325 695000
0.1604 293.1454 101325 578550 6 0.2235 298.136 101325 724000
0.123 293.1454 101325 519120 7 0.2358 298.136 101325 727000
0.0839 293.1454 101325 400040 8 0.2928 298.136 101325 729000
0.0429 293.1454 101325 229210 9 0.3306 298.136 101325 720000
0.0298 298.136 101325 349000 10 0.3577 298.136 101325 715000
0.0312 298.136 101325 358000 11 0.4 298.136 101325 697000
0.0863 298.136 101325 575000 12 0.4405 298.136 101325 671000
0.1327 298.136 101325 660000 13 0.4574 298.136 101325 666000
0.1393 298.136 101325 672000 14 0.5089 298.136 101325 629000
0.2081 298.136 101325 724000 15 0.5532 298.136 101325 592000
0.2317 298.136 101325 734000 16 0.5679 298.136 101325 578000
0.2608 298.136 101325 735000 17 0.6412 298.136 101325 506000
0.3432 298.136 101325 725000 18 0.6528 298.136 101325 497000
0.3529 298.136 101325 726000 19 0.7401 298.136 101325 397000
0.4331 298.136 101325 684000 20 0.7924 298.136 101325 329000
0.454 298.136 101325 674000 21 0.8124 298.136 101325 297000
0.5268 298.136 101325 610000 1 0.022 298.136 101325 267500
0.5965 298.136 101325 547000 2 0.04 308.132 101325 428000
0.6527 298.136 101325 480000 3 0.043 298.136 101325 404700
0.6827 298.136 101325 448000 4 0.043 318.1285 101325 490800
0.7391 298.136 101325 373000 5 0.058 318.1285 101325 583800
0.7827 298.136 101325 318000 6 0.071 308.132 101325 583800
0.7835 298.136 101325 313000 7 0.079 298.136 101325 535000
0.175 298.136 101325 652700 8 0.087 318.1285 101325 718700
0.221 298.136 101325 681990 9 0.104 308.132 101325 686200
0.326 298.136 101325 702910 10 0.119 318.1285 101325 818800
0.359 298.136 101325 690360 11 0.134 298.136 101325 635000
0.51 298.136 101325 615050 12 0.154 308.132 101325 774600
0.633 298.136 101325 481160 13 0.163 318.1285 101325 907100
0.796 298.136 101325 284510 14 0.197 298.136 101325 693100
0.901 298.136 101325 146440 15 0.22 318.1285 101325 965300
0.374 298.136 101325 695500 16 0.224 308.132 101325 835000
0.45 298.136 101325 655900 17 0.258 298.136 101325 704800
0.512 298.136 101325 614100 18 0.271 308.132 101325 849000
0.576 298.136 101325 555900 19 0.272 318.1285 101325 988600
0.625 298.136 101325 507100 20 0.306 308.132 101325 853600
0.687 298.136 101325 441900 21 0.307 318.1285 101325 993200
0.723 298.136 101325 397700 22 0.322 298.136 101325 704800
0.771 298.136 101325 332600 23 0.34 308.132 101325 849000
0.825 298.136 101325 258200 24 0.341 318.1285 101325 988600
0.871 298.136 101325 193100 25 0.372 318.1285 101325 979200
0.923 298.136 101325 116300 26 0.379 308.132 101325 835000
0.948 298.136 101325 76800 27 0.381 298.136 101325 688500
0.021 298.136 101325 244200 28 0.414 308.132 101325 816400
0.037 298.136 101325 360500 29 0.428 298.136 101325 667600
0.069 298.136 101325 502400 30 0.442 318.1285 101325 939700
0.103 298.136 101325 586200 31 0.461 308.132 101325 788500
0.146 298.136 101325 651300 32 0.486 298.136 101325 632700
0.211 298.136 101325 700100 33 0.5 308.132 101325 758300
0.282 298.136 101325 716400 34 0.5 318.1285 101325 890900
0.9519 298.1444 101325 59780 35 0.502 298.136 101325 621000
0.8978 298.1444 101325 139380 36 0.541 298.136 101325 590800
0.8368 298.1444 101325 224410 37 0.55 318.1285 101325 839700
0.7672 298.1444 101325 314480 38 0.554 308.132 101325 709400
0.6872 298.1444 101325 420180 39 0.58 298.136 101325 558200
0.5942 298.1444 101325 524680 40 0.596 318.1285 101325 783900
0.4849 298.1444 101325 608650 41 0.601 308.132 101325 660600
0.3545 298.1444 101325 677450 42 0.619 298.136 101325 521000
0.1962 298.1444 101325 673130 43 0.634 318.1285 101325 732700
0.1604 298.1444 101325 639290 44 0.639 308.132 101325 616400
0.123 298.1444 101325 566900 45 0.657 298.136 101325 483800
0.0839 298.1444 101325 435690 46 0.666 318.1285 101325 688500
0.0429 298.1444 101325 247210 47 0.671 308.132 101325 576800
0.9519 303.1431 101325 59460 48 0.714 318.1285 101325 611700
0.8978 303.1431 101325 142480 49 0.715 298.136 101325 418700
0.8368 303.1431 101325 234250 50 0.72 308.132 101325 504700
0.7672 303.1431 101325 336750 51 0.77 308.132 101325 428000
0.6872 303.1431 101325 445510 52 0.774 298.136 101325 346600
0.5942 303.1431 101325 557100 53 0.775 318.1285 101325 502400
0.4849 303.1431 101325 645350 54 0.818 308.132 101325 348900
0.3545 303.1431 101325 719850 55 0.821 298.136 101325 281400
0.1962 303.1431 101325 713740 56 0.848 318.1285 101325 355900
0.1604 303.1431 101325 676750 57 0.87 308.132 101325 260500
0.123 303.1431 101325 611740 58 0.875 298.136 101325 204700
0.0839 303.1431 101325 466890 59 0.912 318.1285 101325 216300
0.0429 303.1431 101325 253390 60 0.923 308.132 101325 160500
0.313 308.132 101325 835000 61 0.929 298.136 101325 121000
0.364 308.132 101325 821100 62 0.971 318.1285 101325 74400
0.412 308.132 101325 797800 63 0.973 308.132 101325 58100
0.449 308.132 101325 774600 64 0.976 298.136 101325 41900
0.506 308.132 101325 725700 Washburn, E. R.; Lightbody, A. J. Phys.
Chem., 1930, 34, 2701 The changes in
0.551 308.132 101325 681500 volume and temperature that accompany
0.59 308.132 101325 639600 the mixing of organic liquids I
0.65 308.132 101325 567500 Mason, L. S.; Washburn, E. R. J. Phys.
Chem., 1936, 40, 481 Specific heats and
0.697 308.132 101325 500100 related properties of the binary system
0.768 308.132 101325 395400 methyl alcohol + toluene
0.823 308.132 101325 304700
Tsao, C. C.; Smith, J. M. Chem. Eng. Prog.
0.88 308.132 101325 209300 Symp. Ser., 1953, 49(7), 107-17 Heats of
0.938 308.132 101325 109300 mixing of liquids
0.976 308.132 101325 41900 Mrazek, R. V.; Van Ness, H. C. AIChE J.,
1961, 7, 190-5 Heats of mixing: alcohol -
0.033 308.132 101325 374500 aromatic binary systems at 25, 35 and 45
0.05 308.132 101325 479200 c.
0.074 308.132 101325 583800
0.107 308.132 101325 679200
0.148 308.132 101325 753600
0.201 308.132 101325 807100
0.242 308.132 101325 828100
0.275 308.132 101325 835000
0.9519 308.1416 101325 63130
0.8978 308.1416 101325 152540
0.8368 308.1416 101325 255960
0.7672 308.1416 101325 366530
0.6872 308.1416 101325 476030
0.5942 308.1416 101325 600260
0.4849 308.1416 101325 699150
0.3545 308.1416 101325 761390
0.1962 308.1416 101325 767750
0.1604 308.1416 101325 738160
0.123 308.1416 101325 653280
0.0839 308.1416 101325 497940
0.0429 308.1416 101325 269040
0.179 318.1285 101325 861900
0.207 318.1285 101325 895380
0.298 318.1285 101325 937220
0.345 318.1285 101325 941400
0.419 318.1285 101325 907930
0.53 318.1285 101325 807510
0.703 318.1285 101325 577390
0.803 318.1285 101325 397480
0.899 318.1285 101325 200830
0.324 318.1285 101325 960600
0.352 318.1285 101325 953700
0.408 318.1285 101325 928100
0.46 318.1285 101325 888500
0.512 318.1285 101325 839700
0.561 318.1285 101325 783900
0.599 318.1285 101325 735000
0.658 318.1285 101325 651300
0.702 318.1285 101325 590800
0.744 318.1285 101325 516400
0.808 318.1285 101325 395400
0.856 318.1285 101325 302400
0.903 318.1285 101325 207000
0.948 318.1285 101325 111600
0.98 318.1285 101325 41900
0.054 318.1285 101325 537300
0.069 318.1285 101325 621000
0.094 318.1285 101325 725700
0.128 318.1285 101325 814100
0.167 318.1285 101325 883900
0.22 318.1285 101325 935100
0.261 318.1285 101325 956000
0.293 318.1285 101325 963000
Scatchard, G.; Ticknor, L. B.; Goates, J. R.;
McCartney, E. R. J. Am. Chem. Soc., 1952,
74, 3721-4 Heats of mixing in some
nonelectrolyte solutions

Tsao, C. C.; Smith, J. M. Chem. Eng. Prog.


Symp. Ser., 1953, 49(7), 107-17 Heats of
mixing of liquids
Williamson, A. G.; Scott, R. L. J. Phys.
Chem., 1960, 64, 440 Heats of mixing of
nonelectrolyte solutions: I ethanol +
benzene and methanol + benzene
Mrazek, R. V.; Van Ness, H. C. AIChE J.,
1961, 7, 190-5 Heats of mixing: alcohol -
aromatic binary systems at 25, 35 and 45
c.
Battler, J. R.; Rowley, R. L. J. Chem.
Thermodyn., 1985, 17, 719-32 Excess
enthalpies between 293 and 323 K for
constituent binaries of ternary mixtures
exhibiting partial miscibility
Methanol - p-Xylene Methanol - m-Xylene

Mole Mole
Excess
fraction Temperat Pressure fraction Temperat
No. enthalpy No.
METHA- ure (K) (N/sqm) METHA- ure (K)
(J/kmol)
01 01

7 0.8698 298.1444 170000 263600 7 0.4811 298.2


8 0.8188 298.1444 170000 342200 8 0.4128 298.2
9 0.811 298.1444 170000 354200 9 0.3273 298.2
10 0.7508 298.1444 170000 433100 10 0.2975 298.2
11 0.7437 298.1444 170000 431400 11 0.233 298.2
12 0.6677 298.1444 170000 532500 12 0.1577 298.2
13 0.6633 298.1444 170000 531700 13 0.0923 298.2
14 0.6265 298.1444 170000 576600 14 0.0656 298.2
15 0.5845 298.1444 170000 613100 Letcher, T. M.; Prasad, A. K.; Schoon
16 0.5636 298.1444 170000 626500 F. E. Z.; Mercer-Chalmers, J. J. Ch
Thermodyn., 1990, 22, 765-70 Ex
17 0.5632 298.1444 170000 629400 enthalpies of (a xylene + an alkano
18 0.5631 298.1444 170000 628400 298.2 K
19 0.5381 298.1444 170000 650600
20 0.5282 298.1444 170000 656900
21 0.5037 298.1444 170000 674200
22 0.4866 298.1444 170000 686500
23 0.4785 298.1444 170000 684400
24 0.4291 298.1444 170000 716000
25 0.3981 298.1444 170000 721600
26 0.3645 298.1444 170000 735900
27 0.3481 298.1444 170000 742300
28 0.3437 298.1444 170000 742300
29 0.3142 298.1444 170000 747500
30 0.2914 298.1444 170000 744400
31 0.2867 298.1444 170000 745800
32 0.286 298.1444 170000 747900
33 0.2564 298.1444 170000 744400
34 0.2394 298.1444 170000 743300
35 0.2253 298.1444 170000 736000
36 0.197 298.1444 170000 717700
37 0.1926 298.1444 170000 717100
38 0.1581 298.1444 170000 689400
39 0.153 298.1444 170000 682900
40 0.1135 298.1444 170000 637700
41 Christensen,
0.0574 298.1444 170000
J. J.; Rossiter, 482900
B. E.; O'Neil, T.
K.; Hanks, R. W. J. Chem. Thermodyn.,
1978, 10, 829-833 The excess enthalpies
of six p-xylene + alcohol mixtures at
298.15 K
hanol - m-Xylene Methanol - o-Xylene Ethano

Mole
Excess Excess
Pressure fraction Temperat Pressure
enthalpy No. enthalpy No.
(N/sqm) METHA- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01

101325 699700 7 0.5005 298.2 101325 696700 7


101325 727500 8 0.393 298.2 101325 746600 8
101325 742200 9 0.3245 298.2 101325 762600 9
101325 742200 10 0.2453 298.2 101325 752100 1
101325 733900 11 0.174 298.2 101325 704700 2
101325 675100 12 0.0996 298.2 101325 563300 3
101325 530500 13 Letcher,
0.0527 298.2 A.101325
T. M.; Prasad, 360400
K.; Schoonbaert, 4
101325 419200 F. E. Z.; Mercer-Chalmers, J. J. Chem. 5
Thermodyn., 1990, 22, 765-70 Excess
T. M.; Prasad, A. K.; Schoonbaert, enthalpies of (a xylene + an alkanol) at 6
; Mercer-Chalmers, J. J. Chem. 298.2 K 1
odyn., 1990, 22, 765-70 Excess
ies of (a xylene + an alkanol) at 2
298.2 K 3
4
5
6
1
2
3
4
5
6
7
8
9
10
11
12
13
14
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2
3
4
5
6
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9
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11
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13
14
15
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17
18
19
20
21
22
23
24
25
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9
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17
18
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58
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63
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65
66
67
68
69
1
2
3
4
5
6
7
8
9
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
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43
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47
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52
53
54
55
56
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58
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64
65
66
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68
69
70
71
72
73
74
75
76
77
1
2
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4
5
6
7
8
9
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13
14
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20
21
22
23
1
2
3
4
5
6
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8
9
10
11
12
13
14
15
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17
18
1
2
3
4
5
6
7
8
9
10
11
12
13
14
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17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
Ethanol - Benzene Ethanol - Toluene

Mole Excess Mole Excess


Temperat Pressure Temperat Pressure
fraction enthalpy No. fraction enthalpy
ure (K) (N/sqm) ure (K) (N/sqm)
ETHANOL (J/kmol) ETHANOL (J/kmol)

0.896 298.136 101325 167000 7 0.05 308.132 101325 525700


0.932 298.136 101325 109000 8 0.06 298.136 101325 507100
0.967 298.136 101325 63000 9 0.073 308.132 101325 649000
0.13 318.1285 101000 1047000 10 0.073 318.1285 101325 716400
0.189 318.1285 101000 1231000 11 0.098 298.136 101325 630300
0.276 318.1285 101000 1298000 12 0.101 318.1285 101325 846700
0.33 318.1285 101000 1320000 13 0.103 308.132 101325 758300
0.547 318.1285 101000 1096000 14 0.13 318.1285 101325 942000
0.549 318.1285 101000 1098000 15 0.143 308.132 101325 853600
0.05 298.136 101325 492763.1 16 0.152 298.136 101325 730400
0.1 298.136 101325 680355 17 0.176 318.1285 101325 1044400
0.2 298.136 101325 855968 18 0.196 308.132 101325 932700
0.4 298.136 101325 898766.4 19 0.222 298.136 101325 800100
0.6 298.136 101325 714547.2 20 0.224 318.1285 101325 1109500
0.8 298.136 101325 394489.6 21 0.249 308.132 101325 974600
0.168 318.1285 101325 999980 22 0.252 318.1285 101325 1135100
0.264 318.1285 101325 1125500 23 0.28 318.1285 101325 1151400
0.346 318.1285 101325 1142230 24 0.284 308.132 101325 986200
0.398 318.1285 101325 1112940 25 0.306 318.1285 101325 1156000
0.482 318.1285 101325 1041820 26 0.309 308.132 101325 988600
0.548 318.1285 101325 970690 27 0.312 298.136 101325 821100
0.549 318.1285 101325 958140 28 0.329 318.1285 101325 1158300
0.551 318.1285 101325 970690 29 0.334 308.132 101325 988600
0.571 318.1285 101325 937220 30 0.363 318.1285 101325 1151400
0.572 318.1285 101325 949770 31 0.364 298.136 101325 809400
0.588 318.1285 101325 891190 32 0.405 308.132 101325 960600
0.629 318.1285 101325 820060 33 0.407 298.136 101325 788500
0.758 318.1285 101325 569020 34 0.41 318.1285 101325 1128100
0.877 318.1285 101325 292880 35 0.46 308.132 101325 918800
0.057 298.136 101325 510000 36 0.463 298.136 101325 749000
0.13 298.136 101325 715000 37 0.466 318.1285 101325 1081600
0.13 298.136 101325 725000 38 0.507 308.132 101325 874600
0.146 318.1285 101325 970000 39 0.51 298.136 101325 707100
0.162 308.132 101325 905000 40 0.512 318.1285 101325 1030400
0.164 308.132 101325 880000 41 0.548 308.132 101325 825700
0.269 298.136 101325 845000 42 0.55 318.1285 101325 981600
0.278 298.136 101325 855000 43 0.551 298.136 101325 665200
0.294 318.1285 101325 1130000 44 0.584 318.1285 101325 930400
0.335 308.132 101325 1005000 45 0.591 298.136 101325 621000
0.343 308.132 101325 995000 46 0.611 308.132 101325 742000
0.541 298.136 101325 710000 47 0.628 298.136 101325 574300
0.552 308.132 101325 820000 48 0.637 318.1285 101325 842000
0.552 308.132 101325 810000 49 0.656 298.136 101325 537300
0.56 298.136 101325 690000 50 0.656 308.132 101325 667600
0.567 318.1285 101325 925000 51 0.678 318.1285 101325 760600
0.569 318.1285 101325 930000 52 0.698 298.136 101325 476800
0.571 318.1285 101325 945000 53 0.706 308.132 101325 581500
0.637 318.1285 101325 815000 54 0.732 318.1285 101325 651300
0.649 308.132 101325 680000 55 0.756 298.136 101325 390800
0.658 298.136 101325 555000 56 0.765 308.132 101325 472200
0.66 298.136 101325 540000 57 0.795 318.1285 101325 509400
0.822 318.1285 101325 420000 58 0.823 298.136 101325 281400
0.859 308.132 101325 295000 59 0.83 308.132 101325 346600
0.865 298.136 101325 220000 60 0.854 298.136 101325 232600
0.0983 298.136 101325 692870 61 0.854 318.1285 101325 369800
0.1723 298.136 101325 853536 62 0.893 308.132 101325 218600
0.2089 298.136 101325 881569 63 0.896 298.136 101325 162800
0.2572 298.136 101325 894958 64 0.915 318.1285 101325 216300
0.3397 298.136 101325 902907 65 0.943 298.136 101325 88400
0.3618 298.136 101325 899978 66 0.963 308.132 101325 74400
0.4207 298.136 101325 868180 67 0.974 318.1285 101325 67500
0.4677 298.136 101325 821738 1 0.0054 298.136 101325 78520
0.558 298.136 101325 713790 2 0.0098 298.136 101325 138100
0.5668 298.136 101325 692870 3 0.0144 298.136 101325 195000
0.5797 298.136 101325 676971 4 0.0166 318.1285 101325 230200
0.6515 298.136 101325 570698 5 0.0195 298.136 101325 250700
0.6693 298.136 101325 547267 6 0.0224 333.124 101325 314000
0.7227 298.136 101325 450198 7 0.0247 318.1285 101325 327600
0.7542 298.136 101325 406266 8 0.0253 298.136 101325 305300
0.8751 298.136 101325 210455 9 0.0291 333.124 101325 397000
0.9069 298.136 101325 157737 10 0.0315 298.136 101325 355100
0.9687 298.136 101325 47698 11 0.0339 318.1285 101325 419100
0.031 308.132 101325 379100 12 0.0366 298.136 101325 390000
0.034 298.136 101325 379100 13 0.0368 333.124 101325 485600
0.044 318.1285 101325 530300 14 0.0402 318.1285 101325 481900
0.045 308.132 101325 493100 15 0.041 298.136 101325 416800
0.052 298.136 101325 488500 16 0.0449 298.136 101325 438300
0.059 318.1285 101325 635000 17 0.0458 318.1285 101325 527100
0.065 308.132 101325 611700 18 0.0472 333.124 101325 592700
0.076 298.136 101325 590800 19 0.05 298.136 101325 464100
0.078 318.1285 101325 749000 20 0.0541 333.124 101325 657100
0.087 308.132 101325 709400 21 0.06 298.136 101325 506500
0.1 318.1285 101325 849000 22 0.0658 333.124 101325 753000
0.108 298.136 101325 686200 23 0.073 318.1285 101325 716000
0.114 308.132 101325 795500 24 0.0828 333.124 101325 867300
0.126 318.1285 101325 935100 25 0.098 298.136 101325 629400
0.148 298.136 101325 765300 26 0.1 333.124 101325 957600
0.149 308.132 101325 879200 27 0.101 318.1285 101325 847200
0.155 318.1285 101325 1011800 28 0.116 333.124 101325 1037000
0.188 308.132 101325 944400 29 0.13 318.1285 101325 942100
0.189 318.1285 101325 1079300 30 0.135 333.124 101325 1112000
0.195 298.136 101325 823400 31 0.152 298.136 101325 729600
0.229 318.1285 101325 1132800 32 0.159 333.124 101325 1190000
0.24 308.132 101325 997900 33 0.176 318.1285 101325 1044000
0.252 298.136 101325 860600 34 0.192 333.124 101325 1269000
0.262 318.1285 101325 1160700 35 0.222 298.136 101325 799700
0.266 308.132 101325 1011800 36 0.223 333.124 101325 1324000
0.286 318.1285 101325 1172300 37 0.224 318.1285 101325 1106000
0.287 308.132 101325 1018800 38 0.252 318.1285 101325 1135000
0.306 318.1285 101325 1177000 39 0.28 318.1285 101325 1147000
0.308 308.132 101325 1021100 40 0.28 333.124 101325 1385000
0.314 298.136 101325 869900 41 0.306 318.1285 101325 1155000
0.326 318.1285 101325 1177000 42 0.312 298.136 101325 820000
0.328 308.132 101325 1021100 43 0.329 318.1285 101325 1155000
0.345 318.1285 101325 1177000 44 0.33 333.124 101325 1404000
0.365 298.136 101325 856000 45 0.363 318.1285 101325 1152000
0.366 308.132 101325 1011800 46 0.364 298.136 101325 807900
0.372 318.1285 101325 1167700 47 0.373 333.124 101325 1399000
0.415 308.132 101325 986200 48 0.407 298.136 101325 786800
0.42 318.1285 101325 1139700 49 0.41 318.1285 101325 1122000
0.422 298.136 101325 825700 50 0.411 333.124 101325 1380000
0.464 308.132 101325 946700 51 0.446 333.124 101325 1354000
0.465 318.1285 101325 1097900 52 0.463 298.136 101325 748400
0.477 298.136 101325 781500 53 0.466 318.1285 101325 1080000
0.503 308.132 101325 907100 54 0.476 333.124 101325 1322000
0.505 318.1285 101325 1053700 55 0.504 333.124 101325 1287000
0.515 298.136 101325 744300 56 0.51 298.136 101325 707200
0.56 298.136 101325 693100 57 0.512 318.1285 101325 1029000
0.567 308.132 101325 825700 58 0.528 333.124 101325 1254000
0.568 318.1285 101325 963000 59 0.55 318.1285 101325 980100
0.62 298.136 101325 621000 60 0.55 333.124 101325 1218000
0.635 308.132 101325 716400 61 0.551 298.136 101325 665500
0.638 318.1285 101325 842000 62 0.584 318.1285 101325 930500
0.692 308.132 101325 616400 63 0.589 333.124 101325 1150000
0.697 318.1285 101325 723400 64 0.591 298.136 101325 621200
0.7 298.136 101325 500100 65 0.622 333.124 101325 1086000
0.725 308.132 101325 553600 66 0.628 298.136 101325 574700
0.751 298.136 101325 416400 67 0.641 318.1285 101325 830700
0.752 318.1285 101325 607100 68 0.656 298.136 101325 537100
0.799 308.132 101325 409400 69 0.684 333.124 101325 955400
0.8 318.1285 101325 490800 70 0.698 298.136 101325 476400
0.802 298.136 101325 332600 71 0.704 318.1285 101325 708500
0.852 318.1285 101325 362900 72 0.749 333.124 101325 791500
0.854 298.136 101325 241900 73 0.756 298.136 101325 391100
0.864 308.132 101325 276800 74 0.795 318.1285 101325 508500
0.905 318.1285 101325 232600 75 0.807 333.124 101325 627700
0.908 308.132 101325 183800 76 0.823 298.136 101325 281100
0.909 298.136 101325 148900 77 0.854 298.136 101325 233200
0.951 318.1285 101325 118600 78 0.868 333.124 101325 441100
0.964 298.136 101325 58100 79 0.882 318.1285 101325 299700
0.974 308.132 101325 51200 80 0.896 298.136 101325 162100
0.025 297.9861 101000 314847.4 81 0.913 333.124 101325 296300
0.0586 297.9861 101000 468921.6 82 0.943 298.136 101325 88150
0.1615 297.9861 101000 795492 83 0.974 318.1285 101325 67360
0.2673 297.9861 101000 906442.2 84 0.979 333.124 101325 73400
0.4668 297.9861 101000 824799.6 Mrazek, R. V.; Van Ness, H. C. AIChE J.,
1961, 7, 190-5 Heats of mixing: alcohol -
0.5602 297.9861 101000 705057.1 aromatic binary systems at 25, 35 and 45
0.7018 297.9861 101000 489855.6 c.
0.7074 297.9861 101000 480644.6 L.; Machado, R. L. J. Chem. Eng. Data,
1967, 12(2), 217-224 Thermodynamic
0.9058 297.9861 101000 158261 Excess Properties of Three Alcohol-
0.00034 298.1444 101325 5353.179 Hydrocarbon Systems
0.00069 298.1444 101325 10825.53
0.00103 298.1444 101325 16123.48
0.00136 298.1444 101325 21241.47
0.00168 298.1444 101325 26180.74
0.00201 298.1444 101325 31272.92
0.00263 298.1444 101325 40657.79
0.00324 298.1444 101325 49863.52
0.00383 298.1444 101325 58679.79
0.0044 298.1444 101325 67155.21
0.00495 298.1444 101325 75261.6
0.006 298.1444 101325 90473.88
0.00704 298.1444 101325 105345.9
0.00794 298.1444 101325 117996.8
0.0083 298.1444 101325 121985.1
0.00883 298.1444 101325 130317.7
0.00967 298.1444 101325 141732.1
0.0144 298.1444 101325 201251.6
0.0205 298.1444 101325 269671
0.0309 298.1444 101325 363834.1
0.0407 298.1444 101325 432992.5
0.6035 298.1444 101325 644880.5
0.6313 298.1444 101325 606107.9
0.6619 298.1444 101325 561485.1
0.6953 298.1444 101325 510153.9
0.7326 298.1444 101325 450367.8
0.7528 298.1444 101325 417032.5
0.774 298.1444 101325 381684.2
0.7966 298.1444 101325 343500.3
0.8204 298.1444 101325 302644.3
0.8457 298.1444 101325 259286.6
0.8727 298.1444 101325 212635.3
0.9014 298.1444 101325 163269
0.9165 298.1444 101325 137596.9
0.9321 298.1444 101325 111009.9
0.9482 298.1444 101325 83793.19
0.9649 298.1444 101325 56220.86
0.9822 298.1444 101325 28042.99
0.00041 318.1386 101325 6417.968
0.00075 318.1386 101325 11728.7
0.00109 318.1386 101325 17018.13
0.00142 318.1386 101325 22120.54
0.00174 318.1386 101325 27044.66
0.00206 318.1386 101325 31946.45
0.00274 318.1386 101325 42271.66
0.00334 318.1386 101325 51397.36
0.00448 318.1386 101325 68682.92
0.00556 318.1386 101325 84871.48
0.00657 318.1386 101325 99795.31
0.00753 318.1386 101325 113743.6
0.0082 318.1386 101325 124512.6
0.00843 318.1386 101325 126805.1
0.00928 318.1386 101325 139011.5
0.0144 318.1386 101325 209909.2
0.0205 318.1386 101325 288144.4
0.0306 318.1386 101325 402535.6
0.0404 318.1386 101325 496228.4
0.01101 303.15 101000 228850
0.07932 303.15 101000 641200
0.16175 303.15 101000 841360
0.23489 303.15 101000 906660
0.29611 303.15 101000 927630
0.3483 303.15 101000 919710
0.39536 303.15 101000 900440
0.43394 303.15 101000 875320
0.46773 303.15 101000 847220
0.60887 303.15 101000 702660
0.62129 303.15 101000 684400
0.64058 303.15 101000 654280
0.66062 303.15 101000 621340
0.6845 303.15 101000 579550
0.70585 303.15 101000 546600
0.73071 303.15 101000 502310
0.75756 303.15 101000 454930
0.78599 303.15 101000 402340
0.81549 303.15 101000 347070
0.8501 303.15 101000 280570
0.88398 303.15 101000 214270
0.92143 303.15 101000 144040
0.96502 303.15 101000 60770
0.1 348.15 101325 686000
0.148 348.15 101325 860000
0.199 348.15 101325 992000
0.251 348.15 101325 1085000
0.301 348.15 101325 1146000
0.349 348.15 101325 1169000
0.401 348.15 101325 1173000
0.451 348.15 101325 1140000
0.499 348.15 101325 1077000
0.55 348.15 101325 990000
0.599 348.15 101325 896000
0.651 348.15 101325 778000
0.7 348.15 101325 656000
0.75 348.15 101325 524000
0.801 348.15 101325 391000
0.85 348.15 101325 281000
0.9 348.15 101325 193000
0.95 348.15 101325 128000
0.064 308.15 101000 585200
0.1049 308.15 101000 771400
0.1248 308.15 101000 843600
0.1542 308.15 101000 868200
0.1828 308.15 101000 959100
0.2381 308.15 101000 1003100
0.2908 308.15 101000 1013800
0.3413 308.15 101000 1021800
0.3895 308.15 101000 1001900
0.4357 308.15 101000 958200
0.4506 308.15 101000 958100
0.4799 308.15 101000 931600
0.5224 308.15 101000 871700
0.5631 308.15 101000 833200
0.6023 308.15 101000 769300
0.6761 308.15 101000 640800
0.7447 308.15 101000 519700
0.8084 308.15 101000 396000
0.8678 308.15 101000 277100
0.4357 308.15 101000 960400
0.064 318.15 101000 628500
0.1248 318.15 101000 932700
0.1828 318.15 101000 1077900
0.2381 318.15 101000 1134600
0.2908 318.15 101000 1176600
0.3413 318.15 101000 1174200
0.3895 318.15 101000 1160300
0.4799 318.15 101000 1080900
0.5631 318.15 101000 967400
0.6023 318.15 101000 902500
0.6761 318.15 101000 771900
0.7447 318.15 101000 629600
0.8084 318.15 101000 484100
0.8678 318.15 101000 337700
0.9233 318.15 101000 185200

Washburn, E. R.; Lightbody, A. J. Phys. Chem., 1930, 34, 2701 The changes in volume and temperature that accompany the
Brown, I.; Fock, W. Aust. J. Chem., 1955, 8, 361 Heats of mixing of alcohol solutions
Schnaible, H. W.; Van Ness, H. C.; Smith, J. M. AIChE J., 1957, 3, 147-52 Heats of mixing of liquids
Williamson, A. G.; Scott, R. L. J. Phys. Chem., 1960, 64, 440 Heats of mixing of nonelectrolyte solutions: I ethanol + benzene
Brown, I.; Fock, W. Aust. J. Chem., 1961, 14, 387 Heats of mixing IV solutions of n-alcohols with benzene at 25, 35, and 45
Goates, J. R.; Snow, R. L.; James, M. R. J. Phys. Chem., 1961, 65, 335 Application of quasi-lattice theory to heats of mixing in
Mrazek, R. V.; Van Ness, H. C. AIChE J., 1961, 7, 190-5 Heats of mixing: alcohol - aromatic binary systems at 25, 35 and 45 c
Jones, H. K. D.; Lu, B. C.-Y. J. Chem. Eng. Data, 1966, 11, 488-492 Heats of Mixing of Liquids ifor the System Ethanol-Benzen
Stokes, R. H.; Burfitt, C. J. Chem. Thermodyn., 1973, 5, 623-31 Enthalpies of dilution and transfer of ethanol in non-polar so
Yan, W.; Lin, R.; Yen, W. Thermochim. Acta, 1990, 169, 171-84 Excess enthalpies of seven binary liquid systems
Lien, P.-J.; Lin, H. M.; Lee, M. J. Fluid Phase Equilib., 2004, 215, 187-193 Excess molar enthalpies for binary mixtures of etha
Missopolinou, D.; Tsivintzelis, I.; Panayiotou, C. Fluid Phase Equilib., 2006, 245, 89-101 Excess enthalpies of binary mixture
Ethanol - p-Xylene Ethanol - o-Xylene

Liquid Vapor
Total Mole
mole Temperat mole Temperat
No. pressure No. fraction
fraction ure (K) fraction ure (K)
(N/sqm) ETHANOL
ETHANOL ETHANOL

7 0.4007 298.2
8 0.3565 298.2
9 0.3046 298.2
10 0.2212 298.2
11 0.1488 298.2
12 0.1148 298.2
F. E. Z.; Mercer-Chalmers, J. J. Ch
Thermodyn., 1990, 22, 765-70 Ex
enthalpies of (a xylene + an alkano
298.2 K
rature that accompany the mixing of organic liquids I

utions: I ethanol + benzene and methanol + benzene


benzene at 25, 35, and 45
heory to heats of mixing in some alcohol - hydrocarbon systems
systems at 25, 35 and 45 c.
he System Ethanol-Benzene-n-Hexane
of ethanol in non-polar solvents
liquid systems
for binary mixtures of ethanol + benzene, + cyclohexane, + propyl acetate and 1-propanol + benzene, + cyclohexane, + heptane at 348
thalpies of binary mixtures of 2-ethoxyethanol with four hydrocarbons at 298.15, 308.15, and 318.15K An experimental and theoretica
anol - o-Xylene Methanol - diethyl ether Methanol - t

Mole
Excess Excess
Pressure fraction Temperat Pressure
enthalpy No. enthalpy No.
(N/sqm) METHA- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01

101325 840700 7 0.92585 298.256 101000 48534 7


101325 852800 1 0.95 298.1444 101000 50210 8
101325 865300 2 0.9 298.1444 101000 100420 9
101325 840200 3 0.85 298.1444 101000 146440 10
101325 753600 4 0.8 298.1444 101000 196650 11
101325 656000 5 0.75 298.1444 101000 242670 12
; Mercer-Chalmers, J. J. Chem. 6 0.7 298.1444 101000 288700 13
odyn., 1990, 22, 765-70 Excess
ies of (a xylene + an alkanol) at 7 0.65 298.1444 101000 330540 14
298.2 K 8 0.6 298.1444 101000 368190 15
9 0.55 298.1444 101000 405850 16
10 0.5 298.1444 101000 439320 17
11 0.45 298.1444 101000 468610 18
12 0.4 298.1444 101000 489530 19
13 0.35 298.1444 101000 493710 1
14 0.3 298.1444 101000 493710 2
15 0.25 298.1444 101000 481160 3
16 0.2 298.1444 101000 443500 4
17 0.15 298.1444 101000 368190 5
18 0.1 298.1444 101000 267780 6
19 0.05 298.1444 101000 142260 7
1 0.0306 298.1444 101300 170700 8
2 0.0937 298.1444 101300 320000 9
3 0.1631 298.1444 101300 415200 10
4 0.2331 298.1444 101300 461900 11
5 0.3348 298.1444 101300 490800 12
6 0.4174 298.1444 101300 478100 13
7 0.5363 298.1444 101300 418400 14
8 0.6335 298.1444 101300 344300 15
9 0.7145 298.1444 101300 266600 16
10 0.783 298.1444 101300 189500 17
11 0.8416 298.1444 101300 132400 18
12 0.8924 298.1444 101300 66600 19
13 0.9369 298.1444 101300 19800 20
14 0.9523 298.1444 101300 13800 21
15 0.9762 298.1444 101300 9600 22
16 0.9898 298.1444 101300 5500 23
24
Hirobe, H. J. Faculty Sci. Imp. Univ. Tokyo, 25
1926, 1, 155-222 Thermochemical studies 26
densities, thermodynamic mixing 27
functions, and refractive indexes of the
methanol - diethyl ether binary system at 28
25 29
1982, 14, 251-8 Calorimetric investigation
of the interactions between oxygen and
hydroxyl groups in alcohol + ether at
298.15 k.
ohexane, + heptane at 348.15K
xperimental and theoretical study
Methanol - tetrahydrofuran Ethanol - diethyl ether

Mole
Excess Mole Excess
fraction Temperat Pressure Temperat Pressure
enthalpy No. fraction enthalpy
METHA- ure (K) (N/sqm) ure (K) (N/sqm)
(J/kmol) ETHANOL (J/kmol)
01

0.4791 298.136 101000 489530 7 0.322 273.15 101325 611000


0.4437 298.136 101000 493710 8 0.359 273.15 101325 602000
0.4188 298.136 101000 493710 9 0.361 273.15 101325 623000
0.3872 298.136 101000 489530 10 0.379 273.15 101325 607000
0.3501 298.136 101000 485340 11 0.4 273.15 101325 602000
0.3028 298.136 101000 468610 12 0.413 273.15 101325 594000
0.2415 298.136 101000 426770 13 0.45 273.15 101325 594000
0.2394 298.136 101000 430950 14 0.465 273.15 101325 573000
0.2018 298.136 101000 380740 15 0.496 273.15 101325 582000
0.1495 298.136 101000 301250 16 0.523 273.15 101325 556000
0.1313 298.136 101000 271960 17 0.546 273.15 101325 544000
0.0869 298.136 101000 205020 18 0.581 273.15 101325 510000
0.0717 298.136 101000 171540 19 0.631 273.15 101325 464000
0.8597 298.1444 101000 169200 1 0.101 290.1398 101325 310000
0.8103 298.1444 101000 234600 2 0.19 290.1398 101325 444000
0.7979 298.1444 101000 254300 3 0.207 290.1398 101325 445800
0.7534 298.1444 101000 314400 4 0.29 290.1398 101325 515000
0.6673 298.1444 101000 402700 5 0.35 290.1398 101325 515000
0.5776 298.1444 101000 483800 6 0.376 290.1398 101325 511000
0.5136 298.1444 101000 527400 7 0.42 290.1398 101325 502000
0.4557 298.1444 101000 541500 8 0.54 290.1398 101325 440000
0.409 298.1444 101000 539500 9 0.6 290.1398 101325 394700
0.3973 298.1444 101000 539500 10 0.85 290.1398 101325 177900
0.3139 298.1444 101000 524400 11 0.92 290.1398 101325 96000
0.2343 298.1444 101000 463400 12 0.95 290.1398 101325 59400
0.14 298.1444 101000 337400 1 0.0058 298.1444 101300 65900
0.1397 298.1444 101000 343500 2 0.0214 298.1444 101300 141900
0.0831 298.1444 101000 225500 3 0.0368 298.1444 101300 209100
0.0313 298.1444 101000 91700 4 0.067 298.1444 101300 324300
0.8965 307.1419 101000 128400 5 0.1191 298.1444 101300 456800
0.8197 307.1419 101000 235100 6 0.1742 298.1444 101300 551800
0.8164 307.1419 101000 243700 7 0.2589 298.1444 101300 635200
0.7526 307.1419 101000 324300 8 0.3322 298.1444 101300 660700
0.6572 307.1419 101000 433500 9 0.4453 298.1444 101300 627900
0.5342 307.1419 101000 539700 10 0.5455 298.1444 101300 585500
0.4914 307.1419 101000 564100 11 0.6347 298.1444 101300 503800
0.4443 307.1419 101000 559500 12 0.7147 298.1444 101300 411100
0.3484 307.1419 101000 572100 13 0.7867 298.1444 101300 313600
0.3418 307.1419 101000 556100 14 0.8521 298.1444 101300 222800
0.225 307.1419 101000 480200 15 0.9116 298.1444 101300 143100
0.1536 307.1419 101000 384600 16 0.9327 298.1444 101300 105700
0.1083 307.1419 101000 290600 17 0.9661 298.1444 101300 55700
18 0.9854 298.1444 101300 21500
Arm, H.; Bankay, D.; Schaller, R.; Waelti, Desmaroux, M. Mem. Poudres, 1928, 23,
M. Helv.J.;
Matous, Chim. Acta,
Zivny, 1966, J.49,
A.; Biros, 2598
Collect. 198 Mixture of anhydrous alcohol and
Czech. Chem. Commun., 1972, 37, 3960- ethyl ether
3964 Thermodynamic mixing functions on
the system tetrahydrofuran(1) +
methanol( 2) Calvet, E.; Sebille, G. C. R. Hebd. Seances
Acad. Sci., 1946, 222, 84
1982, 14, 251-8 Calorimetric investigation
of the interactions between oxygen and
hydroxyl groups in alcohol + ether at
298.15 k.
Ethanol - Diisopropyl ether Ethanol - Dipropyl ether

Mole Excess Mole


Temperat Pressure Temperat
No. fraction enthalpy No. fraction
ure (K) (N/sqm) ure (K)
ETHANOL (J/kmol) ETHANOL

7 0.564 298.15 101325 348500 7 0.4481 298.1444


8 0.641 298.15 101325 289900 8 0.3851 298.1444
9 0.694 298.15 101325 233200 9 0.3048 298.1444
10 0.789 298.15 101325 150000 10 0.1939 298.1444
11 0.871 298.15 101325 74100 11 0.0665 298.1444
12 0.882 298.15 101325 59100 12 0.5998 308.1416
13 0.934 298.15 101325 28700 13 0.5747 308.1416
14 0.935 298.15 101325 25700 14 0.4949 308.1416
15 0.985 298.15 101325 3400 15 0.4615 308.1416
1 0.9788 303.15 101000 10048 Gutierrez Losa, C. J. Chem. Thermo
1988, 20, 193 Molar excess enthalp
2 0.9563 303.15 101000 21906 volumes of some (butanone o
3 0.9324 303.15 101000 37741 dipropylether + an alkanol) mixtu
4 0.9069 303.15 101000 57098
5 0.8796 303.15 101000 79274
6 0.8503 303.15 101000 105006
7 0.8189 303.15 101000 134259
8 0.785 303.15 101000 166780
9 0.7484 303.15 101000 201984
10 0.7088 303.15 101000 240109
11 0.6657 303.15 101000 276573
12 0.6187 303.15 101000 318279
13 0.5672 303.15 101000 359941
14 0.5106 303.15 101000 400777
15 0.4479 303.15 101000 434130
16 0.3783 303.15 101000 460345
17 0.3005 303.15 101000 470996
18 0.2129 303.15 101000 441139
19 0.1136 303.15 101000 327487
Eng. Data, 1995, 40, 997-1000 Excess
Molar Enthalpies of an Alkanol + a
Branched Chain Ether at the Temperature
298.15 K

Kim, H.-D.; Hwang, I.-C.; Park, S.-J. J.


Chem. Eng. Data, 2009, 54(11), 3051-3058
ol - Dipropyl ether Ethanol - tetrahydrofuran Methano

Excess Mole Excess


Pressure Temperat Pressure
enthalpy No. fraction enthalpy No.
(N/sqm) ure (K) (N/sqm)
(J/kmol) ETHANOL (J/kmol)

101300 681000 7 0.4204 298.1444 101300 836500 7


101300 628000 8 0.4744 298.1444 101300 835200 8
101300 526000 9 0.5266 298.1444 101300 816100 9
101300 355000 10 0.577 298.1444 101300 783500 10
101300 120000 11 0.6258 298.1444 101300 738600 11
101300 711000 12 0.6729 298.1444 101300 681300 12
101300 719000 13 0.7335 298.1444 101300 593500 13
101300 702000 14 0.7915 298.1444 101300 490300 14
101300 692000 15 0.8471 298.1444 101300 381200 15
z Losa, C. J. Chem. Thermodyn., 16 0.9005 298.1444 101300 257200 16
193 Molar excess enthalpies and
umes of some (butanone or 17
ylether + an alkanol) mixtures Chao, J. P.; Dai, M. J. Chem. Thermodyn., 18
1989, 21, 977 Excess enthalpies of (an
alkan-1-ol + tetrahydrofuran or 19
cyclohexanone) at 298.15 K 1
2
3
4
5
6
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
Methanol - Acetone Methanol - 2-Butanone

Mole Mole
Excess Excess
fraction Temperat Pressure fraction Temperat Pressure
enthalpy No. enthalpy
METHA- ure (K) (N/sqm) METHA- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01 01

0.65 298.136 101325 598310 7 0.4067 308.1416 101325 753600


0.6 298.136 101325 640150 8 0.3709 308.1416 101325 750700
0.55 298.136 101325 673620 9 0.3061 308.1416 101325 691200
0.5 298.136 101325 690360 10 0.2217 308.1416 101325 572000
0.45 298.136 101325 694540 11 0.1631 308.1416 101325 495600
0.4 298.136 101325 686180 12 0.0869 308.1416 101325 298600
0.35 298.136 101325 661070 1 0.0866 298.1444 101325 300830
0.3 298.136 101325 623420 2 0.1055 298.1444 101325 352293
0.25 298.136 101325 564840 3 0.1927 298.1444 101325 538481
0.2 298.136 101325 493710 4 0.2302 298.1444 101325 592036
0.15 298.136 101325 401660 5 0.3094 298.1444 101325 674461
0.1 298.136 101325 288700 6 0.3461 298.1444 101325 701657
0.05 298.136 101325 154810 7 0.4156 298.1444 101325 729271
0.353 303.1431 101325 714100 8 0.5019 298.1444 101325 713372
0.4055 303.1431 101325 735500 9 0.5714 298.1444 101325 658562
0.5218 303.1431 101325 724700 10 0.5963 298.1444 101325 653541
0.6452 303.1431 101325 635000 11 0.7549 298.1444 101325 474884
0.8451 303.1431 101325 341300 12 0.9038 298.1444 101325 217150
0.9647 303.1431 101325 86500 13 0.9411 298.1444 101325 138490
0.0697 323.1371 101325 231300 1 0.9169 313.1401 101325 195000
0.1605 323.1371 101325 464900 2 0.8997 313.1401 101325 244000
0.2835 323.1371 101325 667900 3 0.8468 313.1401 101325 352000
0.3836 323.1371 101325 751500 4 0.8158 313.1401 101325 427000
0.4645 323.1371 101325 770700 5 0.7508 313.1401 101325 527000
0.5263 323.1371 101325 758800 6 0.6891 313.1401 101325 626000
0.5805 323.1371 101325 730700 7 0.6202 313.1401 101325 704000
0.6009 323.1371 101325 717100 8 0.5261 313.1401 101325 769000
0.6203 323.1371 101325 700000 9 0.472 313.1401 101325 781000
0.6218 323.1371 101325 699700 10 0.4499 313.1401 101325 793000
0.6492 323.1371 101325 672300 11 0.3544 313.1401 101325 761000
0.6517 323.1371 101325 671100 12 0.3091 313.1401 101325 728000
0.6837 323.1371 101325 635000 13 0.2479 313.1401 101325 672000
0.6847 323.1371 101325 632400 14 0.1812 313.1401 101325 556000
0.7217 323.1371 101325 585600 15 0.1418 313.1401 101325 459000
0.7652 323.1371 101325 520100 Nagata, I.; Tago, O.; Takahashi, T. Kagaku
Kogaku, 1970, 34, 1107 Heats of mixing
0.8076 323.1371 101325 464400 for binary methyl ethyl ketone - methyl
0.8651 323.1371 101325 332300 acetate - alcohol systems
0.9228 323.1371 101325 200900 Nagata, I.; Ohta, T.; Nakagawa, S. J. Chem.
Eng. Jpn., 1976, 9, 276 Excess gibbs free
0.968 323.1371 101325 86500 energy and heats of mixing for binary
liquid mixtures of alcohols.
Kister, A. T.; Waldman, D. C. J. Phys.
Chem., 1958, 62, 245-6 Heat of mixing of
acetone with water and with methanol Pikkarainen, L. Thermochim. Acta, 1987,
114, 239-244 EXCESS ENTHALPIES OF
BINARY SOLVENT MIXTURES OF 2-
BUTANONE WITH ALIPHATIC ALCOHOLS
Pikkarainen, L. Thermochim. Acta, 1987,
114, 239-244 EXCESS ENTHALPIES OF
BINARY SOLVENT MIXTURES OF 2-
Pichamuthu, R. K.; Laddha, G. S. Indian BUTANONE WITH ALIPHATIC ALCOHOLS
Morris, J.Chem. Eng., 1968,
W.; Mulvey, P. J.; 10, 22 M. M.;
Abbott,
Van Ness, H. C. J. Chem. Eng. Data, 1975,
20, 403-5 Excess thermodynamic
functions for ternary systems: I acetone +
chloroform + methanol at 50c
Methanol - 2-Pentanone Ethanol - Acetone

Mole Mole
Excess
fraction Temperat Pressure fraction Temperat
No. enthalpy No.
METHA- ure (K) (N/sqm) ETHAN- ure (K)
(J/kmol)
01 01

7 0.451 298.15 101325 690300 7 0.5271 298.1444


8 0.376 298.15 101325 669100 8 0.457 298.1444
9 0.298 298.15 101325 606900 9 0.3544 298.1444
10 0.21 298.15 101325 491000 10 0.2381 298.1444
Letcher, T. M.; Nevines, J. A. J. Chem. Eng. 11 0.14 298.1444
Data, 1995, 40, 995-6 Excess Enthalpies of
Ketone + Alkanol at the Temperature 12 0.0683 298.1444
298.15 K 13 0.9519 323.1371
14 0.8968 323.1371
15 0.8017 323.1371
16 0.7009 323.1371
17 0.6175 323.1371
18 0.5955 323.1371
19 0.5346 323.1371
20 0.483 323.1371
21 0.3901 323.1371
22 0.2891 323.1371
23 0.196 323.1371
24 0.0932 323.1371
25 0.049 323.1371
Nicolaides, G. L.; Eckert, C. A. J. Ch
Eng. Data, 1978, 23, 152-6 Experim
heats of mixing of some miscible
partially miscible nonelectrolyte sy
hanol - Acetone Ethanol - 2-Butanone Ethanol -

Mole
Excess Excess
Pressure fraction Temperat Pressure
enthalpy No. enthalpy No.
(N/sqm) ETHAN- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01

101325 1108170 7 0.7011 298.1444 101325 866000 7


101325 1110110 8 0.6963 298.1444 101325 860000 8
101325 1040480 10 0.5994 298.1444 101325 999000 9
101325 850410 13 0.4989 298.1444 101325 1075000 10
101325 583070 14 0.4956 298.1444 101325 1078000
101325 316390 16 0.4112 298.1444 101325 1083000
101325 237710 19 0.2999 298.1444 101325 972000
101325 477090 20 0.2918 298.1444 101325 960000
101325 799280 22 0.2083 298.1444 101325 786000
101325 1038710 23 0.2049 298.1444 101325 776000
101325 1166150 24 0.1541 298.1444 101325 646000
101325 1196430 26 0.1074 298.1444 101325 504000
101325 1226430 27 0.1005 298.1444 101325 479000
101325 1235910 28 0.0966 298.1444 101325 466000
101325 1184480 1 0.9174 298.1444 101300 357000
101325 1037550 2 0.8904 298.1444 101300 451000
101325 806100 3 0.837 298.1444 101300 610000
101325 439920 4 0.766 298.1444 101300 782000
101325 244760 5 0.7013 298.1444 101300 892000
des, G. L.; Eckert, C. A. J. Chem. 6 0.6859 298.1444 101300 910000
a, 1978, 23, 152-6 Experimental
of mixing of some miscible and 7 0.665 298.1444 101300 955000
miscible nonelectrolyte systems 8 0.6234 298.1444 101300 989000
9 0.5491 298.1444 101300 1032000
10 0.4571 298.1444 101300 1012000
11 0.4148 298.1444 101300 985000
12 0.3192 298.1444 101300 893000
13 0.2328 298.1444 101300 734000
14 0.1637 298.1444 101300 569000
15 0.1129 298.1444 101300 420000
16 0.0943 298.1444 101300 342000
9 0.6127 308.1416 101325 1048000
11 0.5528 308.1416 101325 1105000
12 0.5049 308.1416 101325 1125000
15 0.4558 308.1416 101325 1112000
17 0.4056 308.1416 101325 1105000
18 0.3145 308.1416 101325 1029000
21 0.2171 308.1416 101325 820900
25 0.1173 308.1416 101325 539500
17 0.9175 308.1416 101300 357000
18 0.8768 308.1416 101300 528000
19 0.8088 308.1416 101300 741000
20 0.7396 308.1416 101300 887000
21 0.5363 308.1416 101300 1076000
22 0.474 308.1416 101300 1068000
23 0.4682 308.1416 101300 1070000
24 0.4433 308.1416 101300 1056000
25 0.417 308.1416 101300 1041000
26 0.2919 308.1416 101300 892000
27 0.1935 308.1416 101300 661000
28 0.0619 308.1416 101300 261000
1 0.9395 313.1401 101325 268000
2 0.9125 313.1401 101325 362000
3 0.8618 313.1401 101325 535000
4 0.7935 313.1401 101325 758000
5 0.7548 313.1401 101325 849000
6 0.6768 313.1401 101325 976000
7 0.6064 313.1401 101325 1076000
8 0.5316 313.1401 101325 1120000
9 0.4356 313.1401 101325 1139000
10 0.3833 313.1401 101325 1155000
11 0.2762 313.1401 101325 975000
12 0.2372 313.1401 101325 877000
13 0.1333 313.1401 101325 589000
14 0.103 313.1401 101325 489000
Nagata, I.; Ohta, T.; Nakagawa, S. J. Chem.
Eng. Jpn., 1976, 9, 276 Excess gibbs free
energy and heats of mixing for binary
liquid mixtures of alcohols.
Pikkarainen, L. Thermochim. Acta, 1987,
114, 239-244 EXCESS ENTHALPIES OF
BINARY SOLVENT MIXTURES OF 2-
BUTANONE WITH ALIPHATIC ALCOHOLS
Gutierrez Losa, C. J. Chem. Thermodyn.,
1988, 20, 193 Molar excess enthalpies and
volumes of some (butanone or
dipropylether + an alkanol) mixtures
Ethanol - 2-Pentanone Methanol - Acetonitrile

Mole Mole
Excess Excess
fraction Temperat Pressure fraction Temperat Pressure
enthalpy No. enthalpy
ETHAN- ure (K) (N/sqm) METHA- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01 01

0.486 298.15 101325 879500 7 0.43 298.1444 101325 1097100


0.41 298.15 101325 856900 8 0.5326 298.1444 101325 1068000
0.365 298.15 101325 817400 9 0.6042 298.1444 101325 1006600
0.262 298.15 101325 669400 10 0.6542 298.1444 101325 940900
Letcher, T. M.; Nevines, J. A. J. Chem. Eng. 11 0.7533 298.1444 101325 761200
Data, 1995, 40, 995-6 Excess Enthalpies of
Ketone + Alkanol at the Temperature 12 0.847 298.1444 101325 528400
298.15 K 13 0.9339 298.1444 101325 252200
14 0.9781 298.1444 101325 88500
15 0.0222 308.1416 101325 132500
16 0.0603 308.1416 101325 334300
17 0.1091 308.1416 101325 553300
18 0.2204 308.1416 101325 902400
19 0.3486 308.1416 101325 1104900
20 0.4736 308.1416 101325 1146600
21 0.5548 308.1416 101325 1104900
22 0.6188 308.1416 101325 1038100
23 0.6574 308.1416 101325 983300
24 0.7362 308.1416 101325 837500
25 0.8167 308.1416 101325 642500
26 0.8988 308.1416 101325 391900
27 0.9328 308.1416 101325 271400
28 0.9663 308.1416 101325 142100
Nagata, I.; Tamura, K. Fluid Phase Equilib.,
1985, 24, 289 Excess enthalpies of binary
and ternary mixtures of acetonitrile wit
methanol, ethanol and benzene
Methanol - Propionitrile Methanol - Butyronitrile
Liquid Vapor
Mole
mole mole Total
Temperat fraction Temperat
No. fraction fraction pressure No.
ure (K) METHA- ure (K)
METHAN METHAN (N/sqm)
01
OL OL

7 0.4596 298.15
8 0.4652 298.15
9 0.4795 298.15
10 0.486 298.15
11 0.492 298.15
12 0.5586 298.15
13 0.5796 298.15
14 0.7979 298.15
15 0.8403 298.15
16 0.9368 298.15
17 0.9851 298.15
Excess functions at T = 298.15 K
(butanenitrile + methanol, + pentan
+ heptan-1-ol, + nonan-1-ol, or + de
ol)
anol - Butyronitrile Ethanol - Acetonitrile Ethanol -

Mole
Excess Excess
Pressure fraction Temperat Pressure
enthalpy No. enthalpy No.
(N/sqm) ETHAN- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01

101325 980000 1 0.05 298.136 101000 373631


101325 997000 2 0.1 298.136 101000 682410
101325 991000 3 0.15 298.136 101000 933032
101325 978000 4 0.2 298.136 101000 1133027
101325 988000 5 0.25 298.136 101000 1286998
101325 947000 6 0.3 298.136 101000 1400803
101325 917000 7 0.35 298.136 101000 1478626
101325 582000 8 0.4 298.136 101000 1524231
101325 486000 9 0.45 298.136 101000 1540549
101325 226000 10 0.5 298.136 101000 1530507
101325 50000 11 0.55 298.136 101000 1494943
s functions at T = 298.15 K of 12 0.6 298.136 101000 1435949
itrile + methanol, + pentan-1- ol,
1-ol, + nonan-1-ol, or + decan-1- 13 0.65 298.136 101000 1352687
ol) 14 0.7 298.136 101000 1245995
15 0.75 298.136 101000 1114199
16 0.8 298.136 101000 956044
17 0.85 298.136 101000 769019
18 0.9 298.136 101000 549778
19 0.95 298.136 101000 294972
3 0.8149 298.1444 101325 892400
7 0.7719 298.1444 101325 1046100
9 0.7439 298.1444 101325 1120500
11 0.7188 298.1444 101325 1182500
14 0.6928 298.1444 101325 1246900
16 0.6633 298.1444 101325 1311400
19 0.6208 298.1444 101325 1390700
23 0.5798 298.1444 101325 1435300
29 0.4948 298.1444 101325 1502200
30 0.4688 298.1444 101325 1499800
33 0.4487 298.1444 101325 1494800
38 0.3692 298.1444 101325 1452700
41 0.3388 298.1444 101325 1415500
44 0.318 298.1444 101325 1380800
45 0.2918 298.1444 101325 1338600
49 0.264 298.1444 101325 1266700
52 0.2319 298.1444 101325 1187400
54 0.2125 298.1444 101325 1125400
56 0.1884 298.1444 101325 1048600
59 0.1611 298.1444 101325 937000
1 0.8442 308.1416 101325 825000
2 0.8282 308.1416 101325 924900
5 0.7939 308.1416 101325 1019700
10 0.7275 308.1416 101325 1229800
13 0.6962 308.1416 101325 1301500
18 0.6606 308.1416 101325 1378400
21 0.6198 308.1416 101325 1463000
22 0.5886 308.1416 101325 1506500
26 0.5403 308.1416 101325 1552600
28 0.495 308.1416 101325 1575700
31 0.4683 308.1416 101325 1575700
32 0.4546 308.1416 101325 1573100
35 0.4206 308.1416 101325 1560300
36 0.4022 308.1416 101325 1544900
40 0.3627 308.1416 101325 1521900
42 0.3362 308.1416 101325 1473200
47 0.2754 308.1416 101325 1352800
50 0.2459 308.1416 101325 1268200
53 0.2128 308.1416 101325 1165700
57 0.1769 308.1416 101325 1047900
4 0.8106 318.1386 101325 1013100
6 0.7773 318.1386 101325 1132200
8 0.7474 318.1386 101325 1235300
12 0.7159 318.1386 101325 1320000
15 0.6904 318.1386 101325 1386100
17 0.6609 318.1386 101325 1452200
20 0.6207 318.1386 101325 1534200
24 0.5733 318.1386 101325 1589800
25 0.566 318.1386 101325 1629500
27 0.4983 318.1386 101325 1648000
34 0.448 318.1386 101325 1632100
37 0.3976 318.1386 101325 1605700
39 0.3629 318.1386 101325 1571300
43 0.3252 318.1386 101325 1513100
46 0.2847 318.1386 101325 1428400
48 0.2643 318.1386 101325 1372900
51 0.2403 318.1386 101325 1298800
55 0.2082 318.1386 101325 1195600
58 0.1754 318.1386 101325 1071300
60 0.1485 318.1386 101325 941700
283 Experimental Investigation of the
Two-Component Systems: Water-Aceto-
Nitrole, Water-Dioxane, Ethanol-
Acetonitrile and Cyclohexane-Dioxane
Thacker, R.; Rowlinson, J. S. Trans.
Faraday Soc., 1954, 50, 1036-42 Phys.
Prop. of Some Polar Sol. Part 1. Volumes
and Heats of Mixing of mixing
Collect. Czech. Chem. Commun., 1982, 47,
3177 Liquid-vapour equilibrium and heats
of mixing in the ethanol-acetonitrile
system
Ethanol - Propionitrile Ethanol - Butyronitrile

Liquid Vapor Mole


Total Excess
mole Temperat mole fraction Temperat Pressure
pressure No. enthalpy
fraction ure (K) fraction ETHAN- ure (K) (N/sqm)
(N/sqm) (J/kmol)
ETHANOL ETHANOL 01

7 0.0133 298.15 101325 97000


8 0.0142 298.15 101325 103000
9 0.0189 298.15 101325 136000
10 0.0451 298.15 101325 286000
11 0.0736 298.15 101325 449000
12 0.1361 298.15 101325 769000
13 0.3322 298.15 101325 1301000
14 0.3718 298.15 101325 1323000
15 0.4662 298.15 101325 1333000
16 0.5749 298.15 101325 1235000
17 0.6908 298.15 101325 1034000
18 0.7883 298.15 101325 776000
19 0.9072 298.15 101325 401000
20 0.971 298.15 101325 150000
1 0 298.15 101325 0
2 0.141 298.15 101325 756000
3 0.188 298.15 101325 907000
4 0.268 298.15 101325 1081000
5 0.337 298.15 101325 1166000
6 0.415 298.15 101325 1209000
7 0.527 298.15 101325 1162000
8 0.627 298.15 101325 1054000
9 0.729 298.15 101325 871000
10 0.785 298.15 101325 728000
11 0.834 298.15 101325 588000
12 0.892 298.15 101325 406000
13 0.92 298.15 101325 299000
14 1 298.15 101325 0
J. Chem. Thermodyn., 1995, 27, 481-91
Vapor pressures at several temperatures T
and excess functions at T = 298.1 5 K of
(butanenitrile + ethanol or butan-1-ol)
molar enthalpies and excess molar
volumes of (an alkanol + a nitrile
compound) at T = 298.15 K and p = 0.1
MPa
Methanol - Ethanol Methanol - 1-Propanol

Mole Mole
Excess
fraction Temperat Pressure fraction Temperat
No. enthalpy No.
METHA- ure (K) (N/sqm) METHA- ure (K)
(J/kmol)
01 01

1 0.0734 297.9944 101300 900 1 0.0319 297.9944


2 0.146 297.9944 101300 1700 2 0.0916 297.9944
3 0.2348 297.9944 101300 2500 3 0.1794 297.9944
4 0.3167 297.9944 101300 3200 4 0.2693 297.9944
5 0.3974 297.9944 101300 3900 5 0.3577 297.9944
6 0.4712 297.9944 101300 4400 6 0.4427 297.9944
7 0.5394 297.9944 101300 4600 7 0.5226 297.9944
8 0.6002 297.9944 101300 4700 8 0.5816 297.9944
9 0.6519 297.9944 101300 4600 9 0.5894 297.9944
10 0.6965 297.9944 101300 4400 10 0.6347 297.9944
11 0.7998 297.9944 101300 3500 11 0.6488 297.9944
12 0.8535 297.9944 101300 2700 12 0.6916 297.9944
13 0.9049 297.9944 101300 1900 13 0.6981 297.9944
14 0.9465 297.9944 101300 1200 14 0.7403 297.9944
15 0.9756 297.9944 101300 600 15 0.7475 297.9944
16 0.803 297.9944
17 0.8525 297.9944
Pflug, H. D.; Pope, A. E.; Benson, G. C. J.
Chem. Eng. Data, 1968, 13, 408-10 Heats 18 0.897 297.9944
of Mixing of Normal ALcohols at 25 deg C 19 0.9319 297.9944
20 0.9646 297.9944
21 0.9875 297.9944
1 0.9282 298.1444
2 0.8632 298.1444
3 0.7788 298.1444
4 0.6507 298.1444
5 0.566 298.1444
6 0.4396 298.1444
7 0.3341 298.1444
8 0.1899 298.1444

Pflug, H. D.; Pope, A. E.; Benson, G


Chem. Eng. Data, 1968, 13, 408-10
of Mixing of Normal ALcohols at 25
Khurma, J. R.; Fenby, D. V. J. Phys. C
1979, 83, 2443-7 Thermochemical
of deuterium exchange reactions in
+ alcohol and alcohol + alcohol sys
anol - 1-Propanol Methanol - 2-Propanol Methano

Mole
Excess Excess
Pressure fraction Temperat Pressure
enthalpy No. enthalpy No.
(N/sqm) METHA- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01

101300 7500 1 0.1 298.1444 101325 -36800 1


101300 21400 2 0.2 298.1444 101325 -61000 2
101300 39800 3 0.3 298.1444 101325 -74400 3
101300 56200 4 0.4 298.1444 101325 -78700 4
101300 69800 5 0.5 298.1444 101325 -75700 5
101300 78300 6 0.6 298.1444 101325 -66700 6
101300 83100 7 0.7 298.1444 101325 -53200 7
101300 83800 8 0.8 298.1444 101325 -36800 8
101300 84100 9 0.9 298.1444 101325 -18600 9
101300 82700 1 0.944 298.15 101000 -29880 10
101300 82200 2 0.8572 298.15 101000 -74520 11
101300 78900 3 0.7766 298.15 101000 -110670 12
101300 78500 4 0.6552 298.15 101000 -157920 13
101300 73600 5 0.5688 298.15 101000 -180550 1
101300 72500 6 0.4851 298.15 101000 -191370 2
101300 63000 7 0.329 298.15 101000 -182470 3
101300 51800 8 0.2511 298.15 101000 -150100 4
101300 39200 9 0.1566 298.15 101000 -95270 5
101300 27400 investigations of nearly ideal binary 6
solvents: I standard heats and volume
101300 15000 changes of solution in methanol + 7
101300 5500 isopropanol mixtures at 25 c 8
101000 29700 9
101000 50400 Nan, Y.; Hou, Y.; Yu, Q. Acta Chimica 10
Sinica, 1998, 56, 105-108 Measurment of
101000 71800 Excess Molar Enthalpies of Some Alkan-1- 11
101000 84700 ol/iso-Propanol Binary Systems 12
101000 87300 13
101000 81800 14
101000 69700 15
101000 45000 16
17
18
D.; Pope, A. E.; Benson, G. C. J.
ng. Data, 1968, 13, 408-10 Heats 19
of Normal ALcohols at 25 deg C 20
J. R.; Fenby, D. V. J. Phys. Chem., 21
, 2443-7 Thermochemical study
ium exchange reactions in water 22
l and alcohol + alcohol systems. 23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
Methanol - 1-Butanol Ethanol - 1-Propanol

Mole Mole
Excess Excess
fraction Temperat Pressure fraction Temperat Pressure
enthalpy No. enthalpy
METHA- ure (K) (N/sqm) ETHAN- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01 01

0.2039 298.136 101000 64434 1 0.0342 297.9944 101300 2500


0.345 298.136 101000 102090 2 0.0926 297.9944 101300 6100
0.3486 298.136 101000 102090 3 0.1777 297.9944 101300 10800
0.3773 298.136 101000 110458 4 0.2653 297.9944 101300 14500
0.4431 298.136 101000 132633 5 0.3548 297.9944 101300 17000
0.6356 298.136 101000 146022 6 0.4358 297.9944 101300 18600
0.668 298.136 101000 141419 7 0.51 297.9944 101300 19100
0.6683 298.136 101000 140164 8 0.5914 297.9944 101300 19100
0.6768 298.136 101000 140164 9 0.6552 297.9944 101300 18400
0.7293 298.136 101000 130122 10 0.7223 297.9944 101300 16800
0.7405 298.136 101000 131796 11 0.7858 297.9944 101300 14500
0.7729 298.136 101000 127194 12 0.8494 297.9944 101300 11300
0.8277 298.136 101000 107529 13 0.9051 297.9944 101300 7700
0.9531 293.1454 101325 36030 14 0.949 297.9944 101300 4500
0.9003 293.1454 101325 73280 15 0.9806 297.9944 101300 1800
0.8405 293.1454 101325 105990 1 0.0993 293.1454 101000 7000
0.7721 293.1454 101325 131110 2 0.1807 293.1454 101000 12000
0.6931 293.1454 101325 147370 3 0.3554 293.1454 101000 21000
0.6009 293.1454 101325 152400 4 0.4981 293.1454 101000 22000
0.4918 293.1454 101325 135470 5 0.5485 293.1454 101000 23000
0.3608 293.1454 101325 106100 6 0.637 293.1454 101000 22000
0.2006 293.1454 101325 58520 7 0.6448 293.1454 101000 22000
0.1641 293.1454 101325 45660 8 0.7595 293.1454 101000 17000
0.126 293.1454 101325 33550 9 0.8876 293.1454 101000 10000
0.086 293.1454 101325 19040 10 0.9405 293.1454 101000 6000
0.0441 293.1454 101325 3720 11 0.0942 298.1444 101000 7000
0.9531 298.1444 101325 34510 12 0.1721 298.1444 101000 11000
0.9003 298.1444 101325 69690 13 0.2937 298.1444 101000 16000
0.8405 298.1444 101325 99610 14 0.421 298.1444 101000 19000
0.7721 298.1444 101325 122610 15 0.5091 298.1444 101000 20000
0.6931 298.1444 101325 136860 16 0.5678 298.1444 101000 19000
0.6009 298.1444 101325 138290 17 0.5918 298.1444 101000 19000
0.4918 298.1444 101325 127830 18 0.6802 298.1444 101000 18000
0.3608 298.1444 101325 95760 19 0.8091 298.1444 101000 13000
0.2006 298.1444 101325 56740 20 0.9444 298.1444 101000 5000
0.1641 298.1444 101325 43850 21 0.0916 303.1431 101000 5000
0.126 298.1444 101325 31770 22 0.1678 303.1431 101000 9000
0.086 298.1444 101325 18420 23 0.2871 303.1431 101000 14000
0.0441 298.1444 101325 3690 24 0.413 303.1431 101000 17000
0.9531 303.1431 101325 32680 25 0.5009 303.1431 101000 18000
0.9003 303.1431 101325 66570 26 0.5741 303.1431 101000 17000
0.8405 303.1431 101325 95060 27 0.584 303.1431 101000 18000
0.7721 303.1431 101325 117170 28 0.6688 303.1431 101000 16000
0.6931 303.1431 101325 129690 29 0.8015 303.1431 101000 12000
0.6009 303.1431 101325 130220 30 0.9416 303.1431 101000 4000
0.4918 303.1431 101325 117230
Pflug, H. D.; Pope, A. E.; Benson, G. C. J.
0.3608 303.1431 101325 90820 Chem. Eng. Data, 1968, 13, 408-10 Heats
0.2006 303.1431 101325 48650 of Mixing of Normal ALcohols at 25 deg C
0.1641 303.1431 101325 38830 Ramalho, R. S.; Ruel, M. Can. J. Chem.
Eng., 1968, 46, 456-61 Heats of Mixing for
0.126 303.1431 101325 27050 Binary Systems: n-Alkanes + n-Alcohols
0.086 303.1431 101325 15210 and n-Alcohols alcohols
0.0441 303.1431 101325 3390
0.9531 323.1371 101325 28750
0.9003 323.1371 101325 58450
0.8405 323.1371 101325 82390
0.7721 323.1371 101325 99490
0.6931 323.1371 101325 108370
0.6009 323.1371 101325 104110
0.4918 323.1371 101325 88700
0.3608 323.1371 101325 61260
0.2006 323.1371 101325 29500
0.1641 323.1371 101325 22170
0.126 323.1371 101325 15380
0.086 323.1371 101325 8230
0.0441 323.1371 101325 2370

Diaz Pena, M.; Fernandez-Martin, F. An. R.


Soc. Esp. Fis. Quim., B, 1963, 59, 323
Battler, J. R.; Rowley, R. L. J. Chem.
Thermodyn., 1985, 17, 719-32 Excess
enthalpies between 293 and 323 K for
constituent binaries of ternary mixtures
exhibiting partial miscibility
Ethanol - 2-Propanol Ethanol - 1-Butanol

Mole Mole
Excess
fraction Temperat Pressure fraction Temperat
No. enthalpy No.
ETHAN- ure (K) (N/sqm) ETHAN- ure (K)
(J/kmol)
01 01

1 0.21 298.136 101325 -39800 1 0.0484 298.136


2 0.219 298.136 101325 -41900 2 0.1601 298.136
3 0.396 298.136 101325 -47300 3 0.2998 298.136
4 0.398 298.136 101325 -48600 4 0.427 298.136
5 0.565 298.136 101325 -51900 5 0.4474 298.136
6 0.565 298.136 101325 -53200 6 0.4818 298.136
7 0.724 298.136 101325 -42700 7 0.5253 298.136
8 0.726 298.136 101325 -41900 8 0.5341 298.136
9 0.866 298.136 101325 -30100 9 0.5864 298.136
10 0.873 298.136 101325 -30600 10 0.6125 298.136
1 0.05 298.15 101300 -10200 11 0.6626 298.136
2 0.1 298.15 101300 -19300 12 0.6733 298.136
3 0.15 298.15 101300 -26100 13 0.7375 298.136
4 0.2 298.15 101300 -32700 14 0.818 298.136
5 0.25 298.15 101300 -36800 15 0.8881 298.136
6 0.3 298.15 101300 -40500 16 0.9401 298.136
7 0.35 298.15 101300 -43000 Pope, A. E.; Pflug, H. D.; Dacre, B.; B
G. C. Can. J. Chem., 1967, 45, 266
8 0.4 298.15 101300 -44500 Molar excess enthalpies of binar
9 0.45 298.15 101300 -45200 alcohol systems at 25 C
10 0.5 298.15 101300 -45300
11 0.55 298.15 101300 -44800
12 0.6 298.15 101300 -43300
13 0.65 298.15 101300 -40200
14 0.7 298.15 101300 -36600
15 0.75 298.15 101300 -32400
16 0.8 298.15 101300 -27000
17 0.85 298.15 101300 -21300
18 0.9 298.15 101300 -14900
19 0.95 298.15 101300 -8000
1 0.9376 298.15 101000 -27320
2 0.8668 298.15 101000 -52600
3 0.7776 298.15 101000 -80200
4 0.654 298.15 101000 -107030
5 0.5575 298.15 101000 -118920
6 0.5334 298.15 101000 -120570
7 0.384 298.15 101000 -116400
8 0.2958 298.15 101000 -103400
9 0.1512 298.15 101000 -63920
10 0.0893 298.15 101000 -40560
11 0.08715 298.15 101000 -40360
Parks, G. S.; Kelley, K. K. J. Phys. Chem.,
1925, 29, 727-32 Some Physical-chemical
Properties of Mixtures of Ethyl and
Properties of Mixtures of Ethyl and
Isopropyl Alcohols
Phase Equilib., 1998, 149, 147-161 Excess
molar enthalpies HE of ternary mixtures of
(methanol + ethanol + 1-propanol or 2-
propanol) at 298.15 K
Nan, Y.; Hou, Y.; Yu, Q. Acta Chimica
Sinica, 1998, 56, 105-108 Measurment of
Excess Molar Enthalpies of Some Alkan-1-
ol/iso-Propanol Binary Systems
anol - 1-Butanol Ethanol - 2-Butanol Butylam

Liquid Vapor
Excess Total
Pressure mole Temperat mole
enthalpy No. pressure No.
(N/sqm) fraction ure (K) fraction
(J/kmol) (N/sqm)
ETHANOL ETHANOL

101000 7000 1
101000 21800 2
101000 36400 3
101000 45300 4
101000 46300 5
101000 47700 6
101000 48900 7
101000 48700 8
101000 49300 9
101000 48400 10
101000 47500 1
101000 46200 2
101000 43000 3
101000 34700 4
101000 24200 5
101000 14100 6
E.; Pflug, H. D.; Dacre, B.; Benson, 7
an. J. Chem., 1967, 45, 2665-74
excess enthalpies of binary n- 8
alcohol systems at 25 C 9
10
11
12
13
14
Butylamine - Hexane Butylamine - p-Xylene

Mole Excess Mole Excess


Temperat Pressure Temperat Pressure
fraction enthalpy No. fraction enthalpy
ure (K) (N/sqm) ure (K) (N/sqm)
N-BUT-01 (J/kmol) N-BUT-01 (J/kmol)

0.0466 298.136 101325 229283 1 0 298.1444 101000 0


0.1105 298.136 101325 494130 2 0.1 298.1444 101000 222100
0.1613 298.136 101325 640152 3 0.2 298.1444 101000 438200
0.2794 298.136 101325 902070 4 0.3 298.1444 101000 574100
0.3917 298.136 101325 994118 5 0.4 298.1444 101000 632000
0.4905 298.136 101325 975290 6 0.501 298.1444 101000 631700
0.6069 298.136 101325 943492 7 0.6 298.1444 101000 590100
0.7037 298.136 101325 821738 8 0.7 298.1444 101000 517000
0.8197 298.136 101325 554798 9 0.8 298.1444 101000 417300
0.8987 298.136 101325 336394 10 0.9 298.1444 101000 273800
0.054 303.1431 101325 281500 11 1 298.1444 101000 0
0.1073 303.1431 101325 526900
0.1647 303.1431 101325 730700 Pfestorf, R.; Schuemichen, A.; Quitzsch, K.
0.2207 303.1431 101325 891600 Z. Phys. Chem. (Leipzig), 1989, 270, 1135
0.3193 303.1431 101325 1052200
0.3852 303.1431 101325 1097000
0.466 303.1431 101325 1107000
0.5139 303.1431 101325 1087800
0.6036 303.1431 101325 1005300
0.6662 303.1431 101325 892200
0.7542 303.1431 101325 732500
0.8181 303.1431 101325 592200
0.873 303.1431 101325 421300
0.9532 303.1431 101325 168500
mixing for binary mixtures: III the
intermolecular energy of hydrogen
bonding between alcohol and several
other polar molecules

Fernandez, J.; Velasco, I.; Otin, S. Int.


DATA Ser., Sel. Data Mixtures, Ser. A,
1987, 15(3), 205-214
Butylamine - Ethylbenzene Hexane - Heptane

Mole Excess Mole


Temperat Pressure Temperat
No. fraction enthalpy No. fraction
ure (K) (N/sqm) ure (K)
N-BUT-01 (J/kmol) N-HEX-01

1 0.0514 303.15 101300 123000 1 0.05 298.1444


2 0.1012 303.15 101300 224000 2 0.1 298.1444
3 0.1693 303.15 101300 340000 3 0.15 298.1444
4 0.2487 303.15 101300 450000 4 0.2 298.1444
5 0.3324 303.15 101300 533000 5 0.25 298.1444
6 0.4029 303.15 101300 579000 6 0.3 298.1444
7 0.4538 303.15 101300 593000 7 0.35 298.1444
8 0.5006 303.15 101300 595000 8 0.4 298.1444
9 0.5448 303.15 101300 587000 9 0.4 298.1444
10 0.5992 303.15 101300 564000 10 0.45 298.1444
11 0.6522 303.15 101300 524000 11 0.5 298.1444
12 0.7117 303.15 101300 468000 12 0.5 298.1444
13 0.7913 303.15 101300 373000 13 0.55 298.1444
14 0.8423 303.15 101300 296000 14 0.6 298.1444
15 0.9199 303.15 101300 161000 15 0.6 298.1444
16 0.65 298.1444
Fernandez, J.; Garriga, R.; Velasco, I.; Otin, 17 0.7 298.1444
S. Fluid Phase Equilib., 1999, 163, 231-242 18 0.7 298.1444
19 0.75 298.1444
20 0.8 298.1444
21 0.85 298.1444
22 0.9 298.1444
23 0.95 298.1444
Kimura, F.; Benson, G. C.; Halpin,
Fluid Phase Equilib., 1983, 11, 245
Excess enthalpies of binary mixture
heptane with hexane isomers
xane - Heptane Hexane - Benzene Hexane

Excess Mole Excess


Pressure Temperat Pressure
enthalpy No. fraction enthalpy No.
(N/sqm) ure (K) (N/sqm)
(J/kmol) BENZE-01 (J/kmol)

101325 120 7 0.22 323.1371 101325 460200 1


101325 210 8 0.25 313.1401 101325 540300 2
101325 290 9 0.31 298.1444 101325 710700 3
101325 350 10 0.32 313.1401 101325 642700 4
101325 400 11 0.32 323.1371 101325 612300 5
101325 430 12 0.33 293.1454 101325 760900 6
101325 440 13 0.42 293.1454 101325 873600 7
101325 470 14 0.42 313.1401 101325 720600 1
101325 460 15 0.42 323.1371 101325 650800 2
101325 470 16 0.43 298.1444 101325 843200 3
101325 460 17 0.51 313.1401 101325 754300 4
101325 460 18 0.53 298.1444 101325 873500 5
101325 440 19 0.53 323.1371 101325 694300 6
101325 420 20 0.54 293.1454 101325 916800 7
101325 410 21 0.61 293.1454 101325 898100 8
101325 390 22 0.61 298.1444 101325 833600 9
101325 350 23 0.62 313.1401 101325 735800 10
101325 330 24 0.62 323.1371 101325 658600 11
101325 280 25 0.74 298.1444 101325 699800 12
101325 200 26 0.75 293.1454 101325 727700 13
101325 150 27 0.75 313.1401 101325 598600 14
101325 100 28 0.75 323.1371 101325 528200 15
101325 40 29 0.8 313.1401 101325 518400 16
, F.; Benson, G. C.; Halpin, C. J. 30 0.81 293.1454 101325 622300 17
ase Equilib., 1983, 11, 245-250
nthalpies of binary mixtures of n- 31 0.81 323.1371 101325 415000 18
tane with hexane isomers. 1 0.1 297.9861 101000 405850 19
2 0.2 297.9861 101000 656890 20
3 0.3 297.9861 101000 828430 21
4 0.4 297.9861 101000 903740 22
5 0.5 297.9861 101000 903740 23
6 0.6 297.9861 101000 840980 24
7 0.7 297.9861 101000 711280 1
8 0.8 297.9861 101000 523000 2
9 0.9 297.9861 101000 284510 3
1 0.825 293.138 101325 452000 4
2 0.699 293.138 101325 657000 5
3 0.69 293.138 101325 669000 1
4 0.597 293.138 101325 795000 2
5 0.53 293.138 101325 841000 3
6 0.437 293.138 101325 866000 4
7 0.333 293.138 101325 837000 5
8 0.212 293.138 101325 628000 6
9 0.134 293.138 101325 469000 7
1 0.8481 298.136 101325 430500 8
2 0.7864 298.136 101325 543100 9
3 0.6425 298.136 101325 776100 10
4 0.5322 298.136 101325 877400 11
5 0.4758 298.136 101325 893300 12
6 0.3573 298.136 101325 868200 13
7 0.3503 298.136 101325 858600 14
8 0.3043 298.136 101325 820500 15
9 0.2789 298.136 101325 792000 16
10 0.1925 298.136 101325 649800
11 0.0843 298.136 101325 346400
1 0.9 297.9861 101000 275976.6
2 0.8 297.9861 101000 483628.6
3 0.7 297.9861 101000 651448.8
4 0.6 297.9861 101000 794332.4
5 0.5 297.9861 101000 860230.4
6 0.4 297.9861 101000 865251.2
7 0.3 297.9861 101000 795796.8
8 0.2 297.9861 101000 653959.2
9 0.1 297.9861 101000 402835.5
1 0.8074 298.1444 101325 498600
2 0.7001 298.1444 101325 706200
3 0.6584 298.1444 101325 787400
4 0.6123 298.1444 101325 822000
5 0.5258 298.1444 101325 880500
6 0.485 298.1444 101325 894900
7 0.4249 298.1444 101325 896900
8 0.4218 298.1444 101325 884500
9 0.3682 298.1444 101325 877400
10 0.3422 298.1444 101325 845400
11 0.303 298.1444 101325 806200
12 0.2651 298.1444 101325 752500
13 0.2075 298.1444 101325 641300
14 0.1512 298.1444 101325 509300
1 0.925 323.1371 101325 194000
2 0.8492 323.1371 101325 369000
3 0.7849 323.1371 101325 499000
4 0.7313 323.1371 101325 590000
5 0.6763 323.1371 101325 668000
6 0.625 323.1371 101325 727000
7 0.5795 323.1371 101325 767000
8 0.539 323.1371 101325 794000
9 0.5026 323.1371 101325 809000
10 0.4835 323.1371 101325 815000
11 0.4696 323.1371 101325 817000
12 0.4677 323.1371 101325 821000
13 0.4613 323.1371 101325 817000
14 0.4434 323.1371 101325 816000
15 0.4384 323.1371 101325 816000
16 0.4374 323.1371 101325 816000
17 0.4165 323.1371 101325 809000
18 0.4111 323.1371 101325 810000
19 0.4074 323.1371 101325 810000
20 0.3874 323.1371 101325 798000
21 0.3824 323.1371 101325 799000
22 0.3801 323.1371 101325 799000
23 0.3549 323.1371 101325 777000
24 0.3543 323.1371 101325 785000
25 0.3514 323.1371 101325 781000
26 0.3326 323.1371 101325 768000
27 0.3192 323.1371 101325 749000
28 0.3165 323.1371 101325 752000
29 0.2795 323.1371 101325 706000
30 0.2787 323.1371 101325 714000
31 0.237 323.1371 101325 653000
32 0.2353 323.1371 101325 641000
33 0.1918 323.1371 101325 571000
34 0.1878 323.1371 101325 553000
35 0.1427 323.1371 101325 451000
36 0.1421 323.1371 101325 459000
37 0.0934 323.1371 101325 316000
38 0.0913 323.1371 101325 319000
39 0.0458 323.1371 101325 168000
40 0.0421 323.1371 101325 159000
1 0.8074 298.1444 101325 498600
2 0.7001 298.1444 101325 706200
3 0.6584 298.1444 101325 787400
4 0.6123 298.1444 101325 822000
5 0.5258 298.1444 101325 880500
6 0.485 298.1444 101325 894900
7 0.4249 298.1444 101325 896900
8 0.4218 298.1444 101325 884600
9 0.3682 298.1444 101325 877400
10 0.3422 298.1444 101325 845400
11 0.303 298.1444 101325 806200
12 0.2651 298.1444 101325 752500
13 0.2075 298.1444 101325 641300
14 0.1512 298.1444 101325 509300
1 0.8518 298.1444 101300 393700
2 0.7409 298.1444 101300 620000
3 0.6591 298.1444 101300 743000
4 0.5859 298.1444 101300 813800
5 0.5427 298.1444 101300 845600
6 0.48 298.1444 101300 856600
7 0.4464 298.1444 101300 857000
8 0.4067 298.1444 101300 871800
9 0.3782 298.1444 101300 864300
10 0.3483 298.1444 101300 848400
11 0.3109 298.1444 101300 819400
12 0.2519 298.1444 101300 749100
13 0.2072 298.1444 101300 660900
14 0.1514 298.1444 101300 520200
15 0.0904 298.1444 101300 335000
1 0.0342 298.15 101325 153000
2 0.0639 298.15 101325 277000
3 0.1031 298.15 101325 402000
4 0.1405 298.15 101325 532000
5 0.1738 298.15 101325 614000
6 0.2367 298.15 101325 752000
7 0.266 298.15 101325 793000
8 0.3089 298.15 101325 848000
9 0.3672 298.15 101325 901000
10 0.3978 298.15 101325 928000
11 0.4328 298.15 101325 933000
12 0.442 298.15 101325 939000
13 0.4426 298.15 101325 938000
14 0.4632 298.15 101325 939000
15 0.5378 298.15 101325 899000
16 0.596 298.15 101325 857000
17 0.6146 298.15 101325 839000
18 0.6562 298.15 101325 785000
19 0.7166 298.15 101325 689000
20 0.7333 298.15 101325 657000
21 0.785 298.15 101325 562000
22 0.8546 298.15 101325 399000
23 0.9314 298.15 101325 200000
24 0.0371 308.15 101325 153000
25 0.0759 308.15 101325 290000
26 0.1002 308.15 101325 370000
27 0.1304 308.15 101325 487000
28 0.1607 308.15 101325 559000
29 0.2442 308.15 101325 736000
30 0.3126 308.15 101325 828000
31 0.3399 308.15 101325 855000
32 0.3927 308.15 101325 888000
33 0.4639 308.15 101325 889000
34 0.4918 308.15 101325 872000
35 0.5003 308.15 101325 872000
36 0.5492 308.15 101325 861000
37 0.585 308.15 101325 825000
38 0.6615 308.15 101325 740000
39 0.7286 308.15 101325 625000
40 0.8055 308.15 101325 496000
41 0.8603 308.15 101325 380000
42 0.9333 308.15 101325 210000
1 0.9201 298.15 101300 231000
2 0.8606 298.15 101300 395000
3 0.7866 298.15 101300 567000
4 0.7371 298.15 101300 673000
5 0.6837 298.15 101300 754000
6 0.6139 298.15 101300 847000
7 0.5588 298.15 101300 892000
8 0.5162 298.15 101300 912000
9 0.4627 298.15 101300 940000
10 0.4105 298.15 101300 916000
11 0.3686 298.15 101300 899000
12 0.3108 298.15 101300 849000
13 0.2544 298.15 101300 782000
14 0.2198 298.15 101300 724000
15 0.1846 298.15 101300 655000
16 0.1062 298.15 101300 432000
17 0.069 298.15 101300 303000
18 0.0367 298.15 101300 168000
1 0.929 298.15 101300 246000
2 0.892 298.15 101300 365000
3 0.783 298.15 101300 581000
4 0.561 298.15 101300 879000
5 0.458 298.15 101300 922000
6 0.369 298.15 101300 904000
7 0.332 298.15 101300 882000
8 0.28 298.15 101300 825000
9 0.14 298.15 101300 599000
10 0.08 298.15 101300 466000
11 0.054 298.15 101300 280000
12 0.019 298.15 101300 181000

M. C.; Jimenez Cuesta, E.; Hernandez, C.


Acta Cient. Compostelana, 1970, 7, 147-
154 Heats of mixing at mean
temperatures hexane + benzene system
Kireev, V. A. Acta Physicochim. URSS, 1937, 7, 363 Heats of mixing o
Mathieson, A. R.; Thynne, J. C. J. J. Chem. Soc., 1956, 3708 Thermody
Jones, H. K. D.; Lu, B. C.-Y. J. Chem. Eng. Data, 1966, 11, 488-492 Hea
Ridgway, K.; Butler, P. A. J. Chem. Eng. Data, 1967, 12, 509-515 Some
Paz Andrade, M. I. Int. DATA Ser., Sel. Data Mixtures, Ser. A, 1973, , 9
Diaz Pena, M.; Menduina, C. J. Chem. Thermodyn., 1974, 6, 1097 Exc
Romani, L.; Paz Andrade, M. I. An. Quim., 1974, 70, 422-5 Thermody
Bao, J.; Xie, Y.; Zhang, K.; Hu, Y. Huadong Huagong Xueyuan Xuebao,
Casad, H.; Segade, Luisa; Franjo, C.; Jimenez Cuesta, E.; Paz Andrade
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Yi, C. K.; Park, Y.; You, S.-S. Korean J. Chem. Eng., 2009, 26(1), 220-22
Hexane - Toluene Hexane - p-xylene

Mole Excess Mole Excess


Temperat Pressure Temperat Pressure
fraction enthalpy No. fraction enthalpy
ure (K) (N/sqm) ure (K) (N/sqm)
N-HEX-01 (J/kmol) N-HEX-01 (J/kmol)

0.215 293.138 101325 326000 1 0 298.15 101000 0


0.386 293.138 101325 427000 2 0.05 298.15 101000 61930
0.478 293.138 101325 469000 3 0.1 298.15 101000 119530
0.523 293.138 101325 456000 4 0.15 298.15 101000 170970
0.68 293.138 101325 427000 5 0.2 298.15 101000 215060
0.71 293.138 101325 402000 6 0.25 298.15 101000 251100
0.746 293.138 101325 360000 7 0.3 298.15 101000 278860
0.17 298.1444 101325 354700 8 0.35 298.15 101000 298450
0.17 323.1371 101325 280500 9 0.4 298.15 101000 310260
0.23 298.1444 101325 440900 10 0.45 298.15 101000 314880
0.23 323.1371 101325 365900 11 0.5 298.15 101000 313000
0.29 298.1444 101325 482400 12 0.55 298.15 101000 305340
0.29 323.1371 101325 401500 13 0.6 298.15 101000 292550
0.29 298.1444 101325 491100 14 0.65 298.15 101000 275150
0.37 298.1444 101325 538600 15 0.7 298.15 101000 253450
0.37 323.1371 101325 460800 16 0.75 298.15 101000 227420
0.37 323.1371 101325 459100 17 0.8 298.15 101000 196660
0.47 298.1444 101325 592300 18 0.85 298.15 101000 160300
0.47 323.1371 101325 497700 19 0.9 298.15 101000 116910
0.49 298.1444 101325 585400 20 0.95 298.15 101000 64410
0.49 323.1371 101325 489400 21 1 298.15 101000 0
0.49 298.1444 101325 589600 EXCESS MOLAR ENTHALPY OF BINARY
MIXTURES OF HEXANE+ETHYL BENZENE,
0.49 323.1371 101325 487500 o-XYLENE, m-XYLENE AND p-XYLENE AT
0.55 298.1444 101325 572700 298.15 K
0.55 323.1371 101325 477300
0.55 298.1444 101325 580600
0.68 298.1444 101325 503400
0.68 323.1371 101325 434000
0.68 298.1444 101325 507800
0.76 298.1444 101325 444500
0.76 323.1371 101325 366300
0.1501 298.15 101300 258800
0.3503 298.15 101300 527430
0.4987 298.15 101300 573420
0.6518 298.15 101300 520540
0.8491 298.15 101300 303140
0.0525 298.15 101000 123100
0.0957 298.15 101000 212300
0.1586 298.15 101000 316300
0.2119 298.15 101000 391300
0.2672 298.15 101000 456700
0.3135 298.15 101000 493800
0.3766 298.15 101000 528400
0.4264 298.15 101000 543300
0.4723 298.15 101000 546700
0.5414 298.15 101000 534300
0.6641 298.15 101000 479900
0.6927 298.15 101000 455600
0.7484 298.15 101000 393000
0.8045 298.15 101000 326000
0.8657 298.15 101000 241100
0.9023 298.15 101000 183200
Hydrocarbon Mixtures. II. The Heats of
Mixing of the Binary Mixtures Formed by
Benzene, Cyclohexane, Heptane, Toluene,
and Hexane.

Paz Andrade, M. I.; Baluja, M. C. Acta


Cient. Compostelana, 1969, 6, 245-8
Enthalpies of mixing of the binary hexane
+ toluene system at 25 c and 50 c
Zhang, Y.; Lin, H.; Wang, Y.; Shi, J. Huaxue
Gongcheng, 1996, 24, 56-62 Excess
enthalpy of ternary system of toluene-
ethanol-hexane or tetrachloromethane
E. J. Chem. Thermodyn., 2007, 39, 621-
626 Physical properties of (propyl
propanoate + hexane + toluene) at 298.15
K
7, 7, 363 Heats of mixing of liquids. 3. Integral and partial heats of mixing of normal liquids
Soc., 1956, 3708 Thermodynamics of Hydrocarbon Mixtures. II. The Heats of Mixing of the Binary Mixtures Formed by Benzene, Cycloh
ata, 1966, 11, 488-492 Heats of Mixing of Liquids ifor the System Ethanol-Benzene-n-Hexane
a, 1967, 12, 509-515 Some Physical Properties of the Ternary System Benzene-Cyclohexane-n-Hexane
a Mixtures, Ser. A, 1973, , 97-104
modyn., 1974, 6, 1097 Excess enthalpies at 323.15 k of binary mixtures of benzene with n-alkanes.
1974, 70, 422-5 Thermodynamic excess functions at 25 c: III. benzene + hexane isomers.
Huagong Xueyuan Xuebao, 1985, 11(4), 467-478 A Study on the Excess Enthalpies for the Ternary System Benzene-Cyclohexane-n-Hexa
ez Cuesta, E.; Paz Andrade, M. I. J. Chem. Eng. Data, 2000, 45, 445-449 Excess molar enthalpies of propyl propanoate + hexane + benze
do, J. L.; Galinanes, A. V.; Inmaculada Paz Andrade, M. J. Chem. Eng. Data, 2002, 47, 1436-41
. Eng., 2009, 26(1), 220-224 Measurement of excess enthalpies using a high-pressure flow microcalorimeter and determination of bina
Hexane - m-Xylene Hexane - o-Xylene

Mole Excess Mole


Temperat Pressure Temperat
No. fraction enthalpy No. fraction
ure (K) (N/sqm) ure (K)
N-HEX-01 (J/kmol) N-HEX-01

1 0.16 298.1444 101325 200500 1 0.16 298.1444


2 0.19 308.1416 101325 219000 2 0.24 298.1444
3 0.19 323.1371 101325 200000 3 0.32 298.1444
4 0.19 323.1371 101325 223600 4 0.4 298.1444
5 0.24 298.1444 101325 274400 5 0.42 298.1444
6 0.26 308.1416 101325 271700 6 0.54 298.1444
7 0.26 323.1371 101325 267700 7 0.56 298.1444
8 0.32 298.1444 101325 322700 8 0.65 298.1444
9 0.32 308.1416 101325 318600 9 0.74 298.1444
10 0.32 323.1371 101325 297600 10 0.82 298.1444
11 0.4 298.1444 101325 363100 11 0.65 298.1444
12 0.4 308.1416 101325 352800 12 0.19 308.1416
13 0.4 323.1371 101325 334000 13 0.26 308.1416
14 0.43 298.1444 101325 377900 14 0.32 308.1416
15 0.5 308.1416 101325 374000 15 0.4 308.1416
16 0.5 323.1371 101325 359500 16 0.49 308.1416
17 0.53 308.1416 101325 375000 17 0.53 308.1416
18 0.53 323.1371 101325 351600 18 0.59 308.1416
19 0.53 323.1371 101325 362200 19 0.72 308.1416
20 0.54 298.1444 101325 381000 20 0.79 308.1416
21 0.57 298.1444 101325 380800 21 0.26 308.1416
22 0.59 308.1416 101325 362100 22 0.72 308.1416
23 0.59 323.1371 101325 336500 23 0.19 323.1371
24 0.65 298.1444 101325 359900 24 0.26 323.1371
25 0.71 323.1371 101325 293000 25 0.32 323.1371
26 0.72 308.1416 101325 310600 26 0.4 323.1371
27 0.74 298.1444 101325 307200 27 0.5 323.1371
28 0.79 308.1416 101325 253500 28 0.53 323.1371
29 0.79 323.1371 101325 236000 29 0.58 323.1371
30 0.83 298.1444 101325 239800 30 0.71 323.1371
1 0 298.15 101000 0 31 0.79 323.1371
2 0.05 298.15 101000 68000 32 0.32 323.1371
3 0.1 298.15 101000 134510 33 0.4 323.1371
4 0.15 298.15 101000 196090 1 0 298.15
5 0.2 298.15 101000 250280 2 0.05 298.15
6 0.25 298.15 101000 295480 3 0.1 298.15
7 0.3 298.15 101000 330830 4 0.15 298.15
8 0.35 298.15 101000 356050 5 0.2 298.15
9 0.4 298.15 101000 371390 6 0.25 298.15
10 0.45 298.15 101000 377420 7 0.3 298.15
11 0.5 298.15 101000 375000 8 0.35 298.15
12 0.55 298.15 101000 365080 9 0.4 298.15
13 0.6 298.15 101000 348610 10 0.45 298.15
14 0.65 298.15 101000 326450 11 0.5 298.15
15 0.7 298.15 101000 299170 12 0.55 298.15
16 0.75 298.15 101000 267020 13 0.6 298.15
17 0.8 298.15 101000 229720 14 0.65 298.15
18 0.85 298.15 101000 186410 15 0.7 298.15
19 0.9 298.15 101000 135490 16 0.75 298.15
20 0.95 298.15 101000 74500 17 0.8 298.15
21 1 298.15 101000 0 18 0.85 298.15
Paz Andrade, M. I.; Jimenez Cuesta, E.; 19 0.9 298.15
Baluja, M. C. An. Quim., 1970, 66, 955-9
Enthalpies of mixing at 25 c, 35 c and 50 c 20 0.95 298.15
of the hexane + m-xylene system 21 1 298.15
EXCESS MOLAR ENTHALPY OF BINARY Paz Andrade, M. I.; Castromil, S.; B
MIXTURES OF HEXANE+ETHYL BENZENE, M. C. J. Chem. Thermodyn., 1970, 2
o-XYLENE, m-XYLENE AND p-XYLENE AT Enthalpies of mixing: n-hexane + o-
298.15 K at 25, 35, and 50 deg C
EXCESS MOLAR ENTHALPY OF BIN
MIXTURES OF HEXANE+ETHYL BEN
o-XYLENE, m-XYLENE AND p-XYLEN
298.15 K
ormed by Benzene, Cyclohexane, Heptane, Toluene, and Hexane.

nzene-Cyclohexane-n-Hexane
panoate + hexane + benzene at 298.15 and 308.15 K

and determination of binary interaction parameters for thermodynamic models


xane - o-Xylene Hexane - n,n-dimethylformamide Heptane - n,n-d

Excess Mole Excess


Pressure Temperat Pressure
enthalpy No. fraction enthalpy No.
(N/sqm) ure (K) (N/sqm)
(J/kmol) N-HEX-01 (J/kmol)

101325 236000 1 0.8755 313.15 101300 961000 1


101325 334600 2 0.9103 313.15 101300 816000 2
101325 389800 3 0.9398 313.15 101300 640000 3
101325 434000 4 0.9561 313.15 101300 452000 4
101325 432200 5 0.9626 313.15 101300 406000 5
101325 443500 6 0.9829 313.15 101300 193000 6
101325 446500 7 0.9863 313.15 101300 165000 7
101325 407400 8 0.9924 313.15 101300 92000 8
101325 357900 9 0.9945 313.15 101300 66000 9
101325 287300 enthalpies of (N,N-dimethylformamide or 10
N,N-dimethylacetamide + hexane or
101325 411900 benzene or toluene or p-xylene or 11
101325 266000 mesitylene) 12
101325 329500 13
101325 370000 14
101325 412600 15
101325 427700 16
101325 421500 17
101325 406500
101325 343900
101325 299000
101325 332000
101325 345300
101325 242000
101325 328000
101325 356200
101325 391000
101325 400200
101325 394500
101325 380000
101325 330900
101325 282000
101325 368000
101325 375800
101000 0
101000 77750
101000 153630
101000 222410
101000 281330
101000 329370
101000 366680
101000 394080
101000 412610
101000 423280
101000 426750
101000 423280
101000 412610
101000 394080
101000 366680
101000 329370
101000 281330
101000 222410
101000 153630
101000 77750
101000 0
rade, M. I.; Castromil, S.; Baluja,
hem. Thermodyn., 1970, 2, 775-7
s of mixing: n-hexane + o-xylene
at 25, 35, and 50 deg C
MOLAR ENTHALPY OF BINARY
ES OF HEXANE+ETHYL BENZENE,
E, m-XYLENE AND p-XYLENE AT
298.15 K
Heptane - n,n-dimethylformamide Hexane - Dichloromethane

Mole Excess Mole Excess


Temperat Pressure Temperat Pressure
fraction enthalpy No. fraction enthalpy
ure (K) (N/sqm) ure (K) (N/sqm)
N-HEP-01 (J/kmol) N-HEX-01 (J/kmol)

0.8884 298.1444 699000 1 0.878 297.9944 101000 618000


0.7482 298.1444 675000 2 0.78 297.9944 101000 961000
0.6007 298.1444 679000 3 0.746 297.9944 101000 1055000
0.5167 298.1444 676000 4 0.666 297.9944 101000 1205000
0.2457 298.1444 660000 5 0.661 297.9944 101000 1210000
0.1299 298.1444 669000 6 0.577 297.9944 101000 1262000
0.8875 308.1416 896000 7 0.5 297.9944 101000 1313000
0.8596 308.1416 889000 8 0.497 297.9944 101000 1309000
0.7599 308.1416 889000 9 0.427 297.9944 101000 1307000
0.5216 308.1416 855000 10 0.354 297.9944 101000 1261000
0.2472 308.1416 830000 11 0.272 297.9944 101000 1140000
0.1204 308.1416 812000 12 0.203 297.9944 101000 959000
0.8244 318.1386 1137000 13 0.125 297.9944 101000 681000
0.7191 318.1386 1116000 14 0.076 297.9944 101000 449000
0.6598 318.1386 1086000 G. J. Chem. Thermodyn., 1971, 3, 393
Enthalpies and volumes of mixing of
0.2542 318.1386 1011000 alkanes with carbon tetrachloride,
0.1631 318.1386 996000 chloroform, and
Belousov, V. P.; Shutin, S. G. Z. Phys.
Chem. (Leipzig), 1989, 270(4), 683-688
Calorimetric Study of Binary Systems with
a Solubility Gap_ 2.n-Heptane + N,N-
Dimethylformamid, + Ethylenegl
Hexane - Chloroform Hexane - tetrachloromethane

Mole Excess Mole


Temperat Pressure Temperat
No. fraction enthalpy No. fraction
ure (K) (N/sqm) ure (K)
N-HEX-01 (J/kmol) N-HEX-01

1 0.894 297.9944 101000 276000 1 0.942 297.9944


2 0.808 297.9944 101000 468000 2 0.856 297.9944
3 0.719 297.9944 101000 605000 3 0.735 297.9944
4 0.59 297.9944 101000 718000 4 0.595 297.9944
5 0.504 297.9944 101000 750000 5 0.546 297.9944
6 0.501 297.9944 101000 761000 6 0.545 297.9944
7 0.397 297.9944 101000 738000 7 0.501 297.9944
8 0.302 297.9944 101000 670000 8 0.433 297.9944
9 0.205 297.9944 101000 527000 9 0.426 297.9944
10 0.093 297.9944 101000 287000 10 0.291 297.9944
1 0.9402 308.1416 101300 67030 11 0.22 297.9944
2 0.8898 308.1416 101300 132900 12 0.217 297.9944
3 0.8197 308.1416 101300 228250 13 0.106 297.9944
4 0.6501 308.1416 101300 450380 1 0.82 300.044
5 0.5799 308.1416 101300 518170 2 0.768 300.044
6 0.42 308.1416 101300 586040 3 0.571 300.044
7 0.3703 308.1416 101300 572110 4 0.417 300.044
8 0.2498 308.1416 101300 471960 5 0.416 300.044
9 0.1999 308.1416 101300 405060 6 0.293 300.044
10 0.1605 308.1416 101300 344820 7 0.187 300.044
11 0.1097 308.1416 101300 249780 8 0.105 300.044
12 0.0701 308.1416 101300 162150 1 0.8562 298.1444
1 0.9191 298.15 101000 153100 2 0.7379 298.1444
2 0.8313 298.15 101000 355200 3 0.6133 298.1444
3 0.7467 298.15 101000 473900 4 0.5291 298.1444
4 0.6657 298.15 101000 605800 5 0.5061 298.1444
5 0.5929 298.15 101000 687300 6 0.2514 298.1444
6 0.5286 298.15 101000 726600 1 0.8384 298.1444
7 0.4666 298.15 101000 746100 2 0.6944 298.1444
8 0.4174 298.15 101000 739700 3 0.5901 298.1444
9 0.3747 298.15 101000 722600 4 0.4969 298.1444
10 0.3377 298.15 101000 697800 5 0.4239 298.1444
11 0.2934 298.15 101000 657300 6 0.3047 298.1444
12 0.2474 298.15 101000 602200 7 0.1568 298.1444
13 0.2004 298.15 101000 527400 1 0.9459 293.1454
14 0.1594 298.15 101000 440300 2 0.9459 293.1454
15 0.1144 298.15 101000 338600 3 0.9458 293.1454
16 0.0713 298.15 101000 225500 4 0.927 313.1401
17 0.0326 298.15 101000 113400 5 0.9232 293.1454
Enthalpies and volumes of mixing of 6 0.9035 293.1454
alkanes with carbon tetrachloride,
chloroform, and methylene chloride at 7 0.899 293.1454
25.deg. 8 0.8886 303.1431
Thermochim. Acta, 1975, 11, 105-14 9 0.8885 313.1401
Thermodynamics of weak interactions:
excess enthalpy
Ortega, and excess
J.; Placido, gibbs energies
J. ELDATA: The 10 0.8589 313.1401
InternationalofElectronic
mixing. Journal of 11 0.8326 303.1431
Physico-Chemical Data, 1995, 1, 59-67 12 0.8156 293.1454
Excess enthalpies of trichloromethane +
n-alkanes. Measurement and comparison 13 0.7497 313.1401
with the DISQUAC model 14 0.7477 293.1454
15 0.6907 293.1454
16 0.6696 313.1401
17 0.6656 313.1401
18 0.6642 313.1401
19 0.6397 313.1401
20 0.6393 313.1401
21 0.6359 303.1431
22 0.6019 293.1454
23 0.5985 313.1401
24 0.5935 293.1454
25 0.566 313.1401
26 0.5632 313.1401
27 0.5261 293.1454
28 0.5032 313.1401
29 0.5031 313.1401
30 0.5005 313.1401
31 0.5001 313.1401
32 0.4899 303.1431
33 0.4807 293.1454
34 0.4388 313.1401
35 0.4315 313.1401
36 0.4276 293.1454
37 0.4274 293.1454
38 0.4272 313.1401
39 0.4264 313.1401
40 0.425 293.1454
41 0.4246 293.1454
42 0.3828 303.1431
43 0.3566 293.1454
44 0.3317 293.1454
45 0.3207 293.1454
46 0.3102 303.1431
47 0.3017 313.1401
48 0.3008 313.1401
49 0.2756 293.1454
50 0.2723 293.1454
51 0.2712 293.1454
52 0.2667 313.1401
53 0.24 313.1401
54 0.2362 303.1431
55 0.2225 313.1401
56 0.2206 313.1401
57 0.2179 293.1454
58 0.2179 313.1401
59 0.2168 293.1454
60 0.2139 293.1454
61 0.1983 293.1454
62 0.1857 303.1431
63 0.1581 293.1454
64 0.1575 303.1431
65 0.1562 293.1454
66 0.1548 293.1454
67 0.1541 293.1454
68 0.1538 293.1454
69 0.1505 293.1454
70 0.1257 293.1454
71 0.1105 293.1454
72 0.1088 293.1454
73 0.0838 303.1431
74 0.0836 293.1454
75 0.0832 293.1454
76 0.0828 293.1454
77 0.0825 293.1454
78 0.0727 313.1401
79 0.0578 293.1454
80 0.0563 313.1401
81 0.0543 293.1454
82 0.0434 313.1401
83 0.0422 293.1454
84 0.0421 293.1454
85 0.0413 293.1454
86 0.0409 293.1454
87 0.0409 293.1454
88 0.0281 293.1454
1 0.8971 298.1444
2 0.8477 298.1444
3 0.7996 298.1444
4 0.7528 298.1444
5 0.7072 298.1444
6 0.6627 298.1444
7 0.6193 298.1444
8 0.577 298.1444
9 0.5358 298.1444
10 0.4955 298.1444
11 0.4562 298.1444
12 0.4178 298.1444
13 0.3803 298.1444
14 0.3436 298.1444
15 0.3078 298.1444
16 0.2728 298.1444
17 0.2386 298.1444
18 0.2051 298.1444
19 0.1724 298.1444
20 0.1404 298.1444
21 0.109 298.1444
22 0.0783 298.1444
23 0.0482 298.1444
1 1 298.15
2 0.896 298.15
3 0.793 298.15
4 0.702 298.15
5 0.606 298.15
6 0.495 298.15
7 0.432 298.15
8 0.364 298.15
9 0.307 298.15
10 0.236 298.15
11 0.152 298.15
12 0.07 298.15
13 0 298.15

Bissell, T. G.; Okafor, G. E


Jain, D. V. S.; Yadav, O. P.
Berryman, J. M. ; Heric, E
Recko, W.; Sadowska, K.
Harsted, B. S.; Thomsen,
Grolier, J. -P. E.; Benson,
Parsa, J. B.; Yazdi, M. J. C
tetrachloromethane Heptane - Chloroform Heptane - tetr

Excess Mole Excess


Pressure Temperat Pressure
enthalpy No. fraction enthalpy No.
(N/sqm) ure (K) (N/sqm)
(J/kmol) N-HEP-01 (J/kmol)

101000 59000 1 0.892 297.9944 101000 280000 1


101000 137000 2 0.828 297.9944 101000 421000 2
101000 234000 3 0.751 297.9944 101000 563000 3
101000 294000 4 0.602 297.9944 101000 743000 4
101000 305000 5 0.506 297.9944 101000 797000 5
101000 301000 6 0.405 297.9944 101000 792000 6
101000 319000 7 0.298 297.9944 101000 708000 7
101000 318000 8 0.203 297.9944 101000 570000 8
101000 319000 9 0.158 297.9944 101000 481000 9
101000 285000 10 0.098 297.9944 101000 328000 1
101000 245000 1 0.9 298.1444 101325 240000 2
101000 247000 2 0.8 298.1444 101325 440000 3
101000 141000 3 0.7 298.1444 101325 610000 4
101325 144700 4 0.6 298.1444 101325 740000 5
101325 193800 5 0.5 298.1444 101325 810000 6
101325 257800 6 0.4 298.1444 101325 800000 7
101325 295200 7 0.3 298.1444 101325 700000 8
101325 319500 8 0.2 298.1444 101325 530000 9
101325 263800 9 0.1 298.1444 101325 300000 10
101325 217700 1 0.813 298.1444 101325 449500 11
101325 125600 2 0.722 298.1444 101325 604000 12
101000 144000 3 0.592 298.1444 101325 737500 1
101000 230000 4 0.448 298.1444 101325 803200 2
101000 280000 5 0.325 298.1444 101325 736600 3
101000 316000 6 0.249 298.1444 101325 648400 4
101000 316000 7 0.109 298.1444 101325 364600 5
101000 260000 1 0.9862 303.1131 101325 38300 6
101325 151900 2 0.9852 323.1371 101325 39900 7
101325 247800 3 0.9697 323.1371 101325 81000 8
101325 295000 4 0.9559 303.1131 101325 122000 9
101325 306000 5 0.9427 323.1371 101325 149300 10
101325 311400 6 0.9311 303.1131 101325 186300 11
101325 292400 7 0.9123 303.1131 101325 233100 12
101325 190500 8 0.8995 323.1371 101325 251600 13
101325 57900 9 0.8652 323.1371 101325 326800 14
101325 56300 10 0.8461 303.1131 101325 384300 1
101325 58100 11 0.8052 323.1371 101325 444300 2
101325 71300 12 0.7918 303.1131 101325 490800 3
101325 80800 13 0.7499 323.1371 101325 538200 4
101325 98600 14 0.7404 303.1131 101325 577200 5
101325 103900 15 0.6819 323.1371 101325 632600 6
101325 109800 16 0.6732 303.1131 101325 669000 7
101325 105000 17 0.6268 303.1131 101325 718700 8
101325 129600 18 0.6127 323.1371 101325 702900 9
101325 155000 19 0.5748 303.1131 101325 760300 10
101325 177600 20 0.5165 323.1371 101325 763900 1
101325 207600 21 0.5134 303.1131 101325 788900 2
101325 226600 22 0.4702 303.1131 101325 796000 3
101325 259600 23 0.4597 323.1371 101325 772800 4
101325 253300 24 0.4367 303.1131 101325 793600 5
101325 251000 25 0.4146 323.1371 101325 765600 6
101325 251000 26 0.4018 303.1131 101325 783700 7
101325 263200 27 0.39296 323.1371 101325 757900 8
101325 263900 28 0.3635 303.1131 101325 762300 9
101325 273900 29 0.3297 303.1131 101325 736500 1
101325 300100 30 0.329 323.1371 101325 721300 2
101325 277400 31 0.3094 323.1371 101325 702100 3
101325 306000 32 0.2892 303.1131 101325 695300 4
101325 287600 33 0.2747 323.1371 101325 663100 5
101325 287600 34 0.2497 303.1131 101325 643600 6
101325 322500 35 0.2443 323.1371 101325 620600 7
101325 300700 36 0.2132 303.1131 101325 584600 8
101325 299900 37 0.2111 323.1371 101325 567600 9
101325 299000 38 0.1766 303.1131 101325 515300 10
101325 302600 39 0.1665 323.1371 101325 481900 11
101325 313100 40 0.1339 303.1131 101325 419900 12
101325 327400 41 0.1267 323.1371 101325 391900 13
101325 305500 42 0.1038 303.1131 101325 341900 14
101325 298600 43 0.0891 323.1371 101325 292900 15
101325 330400 44 0.075 323.1371 101325 252000 16
101325 329300 45 0.0723 303.1131 101325 250400 17
101325 301100 46 0.0539 323.1371 101325 187400 18
101325 302700 47 0.0454 303.1131 101325 165200 19
101325 328100 48 0.0367 323.1371 101325 131100 20
101325 331100 49 0.0315 303.1131 101325 117200 21
101325 305400 50 0.022 323.1371 101325 80400 22
101325 317800 51 0.0161 303.1131 101325 61200 23
101325 308900 52 0.0124 323.1371 101325 46100 24
101325 305600 53 0.003 323.1371 101325 11300 25
101325 286800 1 0.9 298.1444 101325 244000 26
101325 274800 2 0.8 298.1444 101325 452000 27
101325 274300 3 0.7 298.1444 101325 618000 28
101325 287600 4 0.6 298.1444 101325 739000 29
101325 288400 5 0.5 298.1444 101325 806000 30
101325 286700 6 0.4 298.1444 101325 811000 31
101325 256400 7 0.3 298.1444 101325 746000 32
101325 245000 8 0.2 298.1444 101325 599000 33
101325 248400 9 0.1 298.1444 101325 355000 34
101325 231900 1 0.9069 298.15 101000 208200 35
101325 232500 2 0.813 298.15 101000 403400 36
101325 257800 3 0.7229 298.15 101000 568200 37
101325 231200 4 0.6416 298.15 101000 681600 38
101325 252200 5 0.5662 298.15 101000 760800 1
101325 254700 6 0.5013 298.15 101000 798900 2
101325 234000 7 0.4441 298.15 101000 806700 3
101325 209500 8 0.3957 298.15 101000 793200 4
101325 206800 9 0.3528 298.15 101000 767300 5
101325 190400 10 0.317 298.15 101000 730400 6
101325 200900 11 0.3052 298.15 101000 714600 7
101325 201900 12 0.2638 298.15 101000 661400 8
101325 202100 13 0.2216 298.15 101000 592100 9
101325 201900 14 0.1792 298.15 101000 517900 10
101325 199800 15 0.1369 298.15 101000 428400 11
101325 166400 16 0.1003 298.15 101000 327600 12
101325 153900 17 0.0619 298.15 101000 217000 13
101325 153200 18 0.0294 298.15 101000 109100 14
101325 108900 15
101325 123000 Bissell, T. G.; Okafor, G. E.; Williamson, 16
101325 118400 Kehiaian, H. V. J. Chim. Phys. Phys.-Chim. B 17
101325 121000 Abello, L. J. Chim. Phys. Phys.-Chim. Biol. 18
101325 122300 Shatas, J. P.; Abbott, M. M.; Van Ness, H. 19
101325 99100 Biros, J.; Zivny, A.; Pouchly, J. Collect. 20
101325 86800 Ortega, J.; Placido, J. ELDATA: The Intern 21
101325 77900 1
101325 82000 2
101325 61300 3
101325 61700 4
101325 61600 5
101325 64700 6
101325 64300 7
101325 64300 8
101325 39400 9
101325 108300 10
101325 151400 11
101325 188800 1
101325 221400 2
101325 247600 3
101325 268600 4
101325 289200 5
101325 301400 6
101325 312000 7
101325 315500 8
101325 317400 9
101325 315500 10
101325 310100 11
101325 299800 12
101325 287400
101325 269000
101325 248400
101325 226000
101325 200400
101325 170500
101325 137800
101325 104700
101325 67400
101000 0
101000 138500
101000 201600
101000 240600
101000 285600
101000 310200
101000 310400
101000 297300
101000 277300
101000 242100
101000 205800
101000 144900
101000 0

Bissell, T. G.; Okafor, G. E.; Williamson, A. G. J. Chem. Thermodyn., 1971, 3, 393 Enthalpies and volumes of mixing of alkanes with carb
Jain, D. V. S.; Yadav, O. P.; Gill, S. S. Indian J. Chem., 1971, 9, 339-41 Thermodynamics of alkane solutions: II excess heats of mixing of
Berryman, J. M. ; Heric, E. L. Can. J. Chem., 1972, 50, 3799 Some mixtures of carbon tetrachloride with several n-alkanes: enthalpies a
Recko, W.; Sadowska, K. W. Bull. Acad. Pol. Sci.-Chim., 1972, 20, 73
Harsted, B. S.; Thomsen, E. S. J. Chem. Thermodyn., 1974, 6, 557-63
Grolier, J. -P. E.; Benson, G. C.; Picker, P. Int. DATA Ser., Sel. Data Mixtures, Ser. A, 1975, 3(1), 1
Parsa, J. B.; Yazdi, M. J. Chem. Eng. Data, 2008, 53(4), 995-997 Excess Enthalpies and Thermal Conductivity Coefficients for Binary Mix
Heptane - tetrachloromethane heptane - Propionic acid

Mole Excess Mole Excess


Temperat Pressure Temperat Pressure
fraction enthalpy No. fraction enthalpy
ure (K) (N/sqm) ure (K) (N/sqm)
N-HEP-01 (J/kmol) N-HEP-01 (J/kmol)

0.9122 298.136 101325 80300 1 0.9799 308.1416 101325 59413


0.7622 298.136 101325 184100 2 0.9686 308.1416 101325 89119
0.6782 298.136 101325 286600 3 0.9608 298.1444 101325 117152
0.6312 298.136 101325 311300 4 0.9538 298.1444 101325 128867
0.5122 298.136 101325 347300 5 0.9464 298.1444 101325 146022
0.3779 298.136 101325 256900 6 0.9461 308.1416 101325 137654
0.1931 298.136 101325 176100 7 0.9054 298.1444 101325 235978
0.1609 298.136 101325 166900 8 0.8973 308.1416 101325 275726
0.1537 298.136 101325 161500 9 0.8025 298.1444 101325 409614
0.58 297.9861 101325 398000 10 0.8025 308.1416 101325 389949
0.521 297.9861 101325 402000 11 0.7179 308.1416 101325 498314
0.4494 297.9861 101325 384070 12 0.7003 298.1444 101325 543502
0.365 297.9861 101325 349110 13 0.6177 298.1444 101325 615048
0.264 297.9861 101325 270620 14 0.6047 308.1416 101325 592036
0.1491 297.9861 101325 173800 15 0.5177 298.1444 101325 666930
0.142 297.9861 101325 166140 16 0.5166 308.1416 101325 625926
0.1133 297.9861 101325 138620 17 0.513 308.1416 101325 624253
0.0814 297.9861 101325 90860 18 0.4292 308.1416 101325 621324
0.0751 297.9861 101325 80290 19 0.4206 298.1444 101325 667348
0.0387 297.9861 101325 33570 20 0.2938 308.1416 101325 548941
0.033 297.9861 101325 31020 21 0.2913 298.1444 101325 591199
0.894 297.9944 101000 113000 22 0.1999 298.1444 101325 476139
0.803 297.9944 101000 168000 23 0.1863 308.1416 101325 424258
0.705 297.9944 101000 263000 24 0.1013 308.1416 101325 278236
0.602 297.9944 101000 307000 25 0.0971 298.1444 101325 274470
0.529 297.9944 101000 326000 26 0.0504 298.1444 101325 156063
0.524 297.9944 101000 337000 27 0.0503 308.1416 101325 153134
0.504 297.9944 101000 341000 28 0.0283 298.1444 101325 89538
0.442 297.9944 101000 344000 29 0.0261 308.1416 101325 74475
0.405 297.9944 101000 342000 1 0.9988 303.1431 101325 6500
0.404 297.9944 101000 344000 2 0.9987 303.1431 101325 7500
0.4 297.9944 101000 350000 3 0.9977 303.1431 101325 11300
0.306 297.9944 101000 320000 4 0.9973 303.1431 101325 13000
0.208 297.9944 101000 259000 5 0.9972 303.1431 101325 13300
0.092 297.9944 101000 146000 6 0.9956 303.1431 101325 18800
0.869 300.044 101325 102900 7 0.9942 303.1431 101325 23000
0.781 300.044 101325 153100 8 0.991 303.1431 101325 33300
0.747 300.044 101325 195000 9 0.9889 303.1431 101325 39500
0.645 300.044 101325 215100 10 0.987 303.1431 101325 44900
0.485 300.044 101325 328000 11 0.9856 303.1431 101325 48700
0.419 300.044 101325 329300 12 0.9825 303.1431 101325 58500
0.36 300.044 101325 309800 13 0.9778 303.1431 101325 72200
0.343 300.044 101325 297900 14 0.9757 303.1431 101325 79100
0.185 300.044 101325 185100 1 0.8629 308.1416 101000 230400
0.094 300.044 101325 140700 2 0.821 308.1416 101000 291300
0.9 298.1444 101325 107000 3 0.7785 308.1416 101000 353600
0.8 298.1444 101325 198000 4 0.6919 308.1416 101000 467200
0.7 298.1444 101325 270000 5 0.6555 308.1416 101000 497900
0.6 298.1444 101325 321000 6 0.5913 308.1416 101000 552300
0.5 298.1444 101325 348000 7 0.5316 308.1416 101000 576300
0.4 298.1444 101325 349000 8 0.4595 308.1416 101000 577000
0.3 298.1444 101325 319000 9 0.3949 308.1416 101000 545900
0.2 298.1444 101325 255000 10 0.3043 308.1416 101000 472000
0.1 298.1444 101325 150000 11 0.2203 308.1416 101000 368000
0.9259 313.1401 101325 74000 12 0.1712 308.1416 101000 295600
0.9133 303.1431 101325 90900 13 0.0845 308.1416 101000 152500
0.8813 313.1401 101325 115000 1 0.9012 298.15 101325 197700
0.8442 293.1454 101325 160400 2 0.8388 298.15 101325 300200
0.8442 293.1454 101325 158000 3 0.6972 298.15 101325 487700
0.8421 303.1431 101325 153600 4 0.5834 298.15 101325 570200
0.8251 313.1401 101325 162600 5 0.4796 298.15 101325 589900
0.8013 313.1401 101325 181500 6 0.3897 298.15 101325 570800
0.7268 313.1401 101325 232900 7 0.3121 298.15 101325 522900
0.6889 303.1431 101325 271000 8 0.2431 298.15 101325 459400
0.6469 313.1401 101325 270600 9 0.1785 298.15 101325 378800
0.5742 293.1454 101325 331600 10 0.1215 298.15 101325 281500
0.5716 303.1431 101325 323000 11 0.0888 298.15 101325 218200
0.5692 313.1401 101325 306100 12 0.03 298.15 101325 71500
0.5073 313.1401 101325 321500
0.5005 293.1454 101325 349600 Nagata, I.; Nagashima, M.; Kazuma, K.; Nakaga
0.5002 293.1454 101325 351000 Woycicka, M. K.; Kalinowska, B. Bull. Acad. Pol.
0.496 293.1454 101325 353700 Lark, B. S.; Banipal, T. S. Thermochim. Acta, 198
0.471 303.1431 101325 344000 Wilhelm, E.; Inglese, A.; Grolier, J.-P. E. J. Chem
0.3993 313.1401 101325 327000
0.3424 293.1454 101325 345300
0.3406 293.1454 101325 345600
0.34 293.1454 101325 345600
0.3244 303.1431 101325 327400
0.3095 313.1401 101325 303500
0.3026 293.1454 101325 325700
0.2473 313.1401 101325 276700
0.2456 303.1431 101325 292500
0.1948 313.1401 101325 240300
0.1609 303.1431 101325 227900
0.1427 313.1401 101325 195600
0.0754 293.1454 101325 127100
0.075 293.1454 101325 128400
0.075 293.1454 101325 126000
0.0749 293.1454 101325 126900
0.0635 313.1401 101325 101800
0.0582 313.1401 101325 94800
0.0384 313.1401 101325 64800
0.7652 298.1444 101325 234200
0.7227 298.1444 101325 263000
0.6815 298.1444 101325 286000
0.6416 298.1444 101325 306000
0.6028 298.1444 101325 322300
0.5653 298.1444 101325 334000
0.5288 298.1444 101325 343000
0.4934 298.1444 101325 349000
0.4589 298.1444 101325 351200
0.4255 298.1444 101325 351000
0.393 298.1444 101325 346800
0.3613 298.1444 101325 339400
0.3305 298.1444 101325 330900
0.3006 298.1444 101325 317900
0.2714 298.1444 101325 304000
0.243 298.1444 101325 287200
0.2153 298.1444 101325 268700
0.1883 298.1444 101325 245500
0.1619 298.1444 101325 222500
0.1362 298.1444 101325 194400
0.1112 298.1444 101325 167800
0.9193 298.1444 101325 80100
0.7882 298.1444 101325 194600
0.6818 298.1444 101325 274300
0.5761 298.1444 101325 323300
0.4868 298.1444 101325 346900
0.4029 298.1444 101325 347500
0.3229 298.1444 101325 327700
0.2496 298.1444 101325 290000
0.1757 298.1444 101325 233900
0.1115 298.1444 101325 161800
0.072 298.1444 101325 112400
1 298.15 101000 0
0.835 298.15 101000 182100
0.71 298.15 101000 250900
0.612 298.15 101000 311600
0.53 298.15 101000 337800
0.488 298.15 101000 345400
0.444 298.15 101000 340300
0.385 298.15 101000 335700
0.304 298.15 101000 310400
0.2 298.15 101000 260200
0.133 298.15 101000 201900
0 298.15 101000 0

Bykov, V. T. Zh. Fiz. Khim., 1939, 13, 1013 Heats of mixing of liquids
Vilcu, R.; Stanciu, F. An. Univ. "C.I. Parhon" Bucuresti, Ser. Stiint. Nat., 1963, 12, 87 Heats of Mixing in Binary Sys
Bissell, T. G.; Okafor, G. E.; Williamson, A. G. J. Chem. Thermodyn., 1971, 3, 393 Enthalpies and volumes of mixin
Jain, D. V. S.; Yadav, O. P.; Gill, S. S. Indian J. Chem., 1971, 9, 339-41 Thermodynamics of alkane solutions: II exce
Kehiaian, H. V. J. Chim. Phys. Phys.-Chim. Biol., 1971, 68, 935-40 Analysis of the enthalpy of mixing of normal-ch
Harsted, B. S.; Thomsen, E. S. J. Chem. Thermodyn., 1974, 6, 557-63
Grolier, J.-P. E.; Inglese, A. Can. J. Chem., 1976, 54, 1952 Enthalpies of mixing of carbon tetrachloride with hydro
Inglese, A.; Grolier, J.-P. E. Thermochim. Acta, 1977, 18, 257-64 Measurement of heats of a mixture of two liquid
Parsa, J. B.; Yazdi, M. J. Chem. Eng. Data, 2008, 53(4), 995-997 Excess Enthalpies and Thermal Conductivity Coeffi

mixing of alkanes with carbon tetrachloride, chloroform, and methylene chloride at 25.deg.
excess heats of mixing of n-alkanes in carbon tetrachloride
ral n-alkanes: enthalpies and energies of mixing

Coefficients for Binary Mixtures of Carbon Tetrachloride and Four Alkanes (C5 to C8) at a Temperature of 298.15 K
Octane - Acetic acid Octane - Propionic acid

Liquid Vapor
Total Mole
mole Temperat mole Temperat
No. pressure No. fraction
fraction ure (K) fraction ure (K)
(N/sqm) N-OCT-01
OCT OCT

1 0.9166 313.15
2 0.8461 313.15
3 0.7856 313.15
4 0.7332 313.15
5 0.6469 313.15
6 0.5788 313.15
7 0.4781 313.15
8 0.4072 313.15
9 0.3141 313.15
10 0.2339 313.15
11 0.1863 313.15
12 0.1324 313.15
13 0.1027 313.15
14 Comelli,
0.0709F.; Francesconi,
313.15 R. J. Chem
Data, 1996, 41, 101-104 Excess M
Enthalpies and Excess Molar Volum
Propionic Acid + Octane, + Cyclohex
1,3,5-Trimethylbenzene, + Oxane,
1,4-Dioxane at 313.15 K
a, M.; Kazuma, K.; Nakagawa, S. J. Chem. Eng. Jpn., 1975, 8, 261-5 Heats of mixing for binary systems and data reduction based on a tr
nowska, B. Bull. Acad. Pol. Sci.-Chim., 1978, 26, 371 Excess enthalpies and heat capacities of diluted propionic acid solutions in n-hepta
. S. Thermochim. Acta, 1985, 91, 141 Excess enthalpies and excess volumes of some carboxilic acid mixtures with n-heptane.
A.; Grolier, J.-P. E. J. Chem. Thermodyn., 1999, 31, 1165-1174 Excess molar enthalpies of (an alkanoic acid + n-heptane, or cyclohexane
ats of Mixing in Binary Systems
lpies and volumes of mixing of alkanes with carbon tetrachloride, chloroform, and methylene chloride at 25.deg.
of alkane solutions: II excess heats of mixing of n-alkanes in carbon tetrachloride
lpy of mixing of normal-chain ethers with carbon tetrachloride at 25c in terms of molecular surface interactions in the zeroth approxim

n tetrachloride with hydrocarbons using the picker dynamic-flow microcalorimeter equipped with separators
s of a mixture of two liquids without programmation of the flow rates using at picker microcalorimeter
Thermal Conductivity Coefficients for Binary Mixtures of Carbon Tetrachloride and Four Alkanes (C5 to C8) at a Temperature of 298.15
ne - Propionic acid Octane - Butyric acid Octane - is

Liquid Vapor
Excess Total
Pressure mole Temperat mole
enthalpy No. pressure No.
(N/sqm) fraction ure (K) fraction
(J/kmol) (N/sqm)
OCT OCT

101320 150000
101320 272000
101320 358000
101320 435000
101320 528000
101320 579000
101320 612000
101320 612000
101320 545000
101320 460000
101320 390000
101320 299000
101320 237000
F.; Francesconi,101320 170000
R. J. Chem. Eng.
996, 41, 101-104 Excess Molar
es and Excess Molar Volumes of
Acid + Octane, + Cyclohexane, +
imethylbenzene, + Oxane, or +
1,4-Dioxane at 313.15 K
ta reduction based on a triplet model of guggenheim.
ic acid solutions in n-heptane.
with n-heptane.
n-heptane, or cyclohexane, or benzene) at T=298.15K
ons in the zeroth approximation

a Temperature of 298.15 K
Octane - isoButyric acid Hexane - Methyl formate

Liquid Vapor
Total Mole Excess
mole Temperat mole Temperat Pressure
pressure No. fraction enthalpy
fraction ure (K) fraction ure (K) (N/sqm)
(N/sqm) N-HEX-01 (J/kmol)
OCT OCT

1 0.9182 298.15 101000 710400


2 0.8403 298.15 101000 1216700
3 0.7642 298.15 101000 1614900
4 0.6944 298.15 101000 1874100
5 0.6303 298.15 101000 2040000
6 0.5813 298.15 101000 2110300
7 0.5304 298.15 101000 2147400
8 0.4855 298.15 101000 2142400
9 0.4431 298.15 101000 2101500
10 0.4085 298.15 101000 2052400
11 0.3752 298.15 101000 1977100
12 0.3349 298.15 101000 1870000
13 0.2933 298.15 101000 1748300
14 0.2495 298.15 101000 1592600
15 0.204 298.15 101000 1403300
16 0.1614 298.15 101000 1198100
17 0.1155 298.15 101000 938900
18 0.0662 298.15 101000 599900
19 0.0249 298.15 101000 264400
1 0.8592 291.15 101320 1059900
2 0.748 291.15 101320 1625900
3 0.6621 291.15 101320 1934600
4 0.5992 291.15 101320 2058200
5 0.5382 291.15 101320 2110500
6 0.4906 291.15 101320 2098600
7 0.4499 291.15 101320 2063200
8 0.4138 291.15 101320 2013400
9 0.3843 291.15 101320 1931800
10 0.3432 291.15 101320 1836400
11 0.2967 291.15 101320 1713400
12 0.2483 291.15 101320 1546700
13 0.2029 291.15 101320 1382000
14 0.155 291.15 101320 1175400
15 0.1077 291.15 101320 916900
16 0.0708 291.15 101320 640100
17 0.0335 291.15 101320 374800

Ortega, J.; Placido, J.; Toledo, F.; Vidal, M.;


Siimer, E.; Legido, J. L. Phys. Chem. Chem.
Phys., 1999, 1(12), 2967-2974
52(1), 215-225 Isobaric Vapor-Liquid
Equilibrium Data and Excess Properties of
Binary Systems Comprised of Alkyl
Methanoates + Hexane
Hexane - Ethyl formate Hexane - propyl formate

Mole Excess Mole


Temperat Pressure Temperat
No. fraction enthalpy No. fraction
ure (K) (N/sqm) ure (K)
N-HEX-01 (J/kmol) N-HEX-01

1 0.946 298.1444 101325 417800 1 0.9299 298.15


2 0.9007 298.1444 101325 698200 2 0.8496 298.15
3 0.8541 298.1444 101325 929700 3 0.7693 298.15
4 0.8048 298.1444 101325 1120600 4 0.6927 298.15
5 0.7107 298.1444 101325 1395600 5 0.6216 298.15
6 0.614 298.1444 101325 1566800 6 0.5608 298.15
7 0.529 298.1444 101325 1579000 7 0.5036 298.15
8 0.4611 298.1444 101325 1561800 8 0.4525 298.15
9 0.4177 298.1444 101325 1521600 9 0.4078 298.15
10 0.2934 298.1444 101325 1324500 10 0.385 298.15
11 0.1949 298.1444 101325 1039400 11 0.3683 298.15
12 0.1016 298.1444 101325 623700 12 0.3375 298.15
13 0.0396 298.1444 101325 264400 13 0.2893 298.15
1 0.8784 298.15 101300 720000 14 0.2357 298.15
2 0.7801 298.15 101300 1096000 15 0.1829 298.15
3 0.6921 298.15 101300 1356000 16 0.1365 298.15
4 0.6185 298.15 101300 1500000 17 0.0831 298.15
5 0.5511 298.15 101300 1576000 18 0.0358 298.15
6 0.5061 298.15 101300 1586000 1 0.9031 291.15
7 0.4679 298.15 101300 1581000 2 0.814 291.15
8 0.3748 298.15 101300 1487000 3 0.7344 291.15
9 0.3245 298.15 101300 1400000 4 0.6684 291.15
10 0.2713 298.15 101300 1268000 5 0.6079 291.15
11 0.2148 298.15 101300 1090000 6 0.5542 291.15
12 0.1586 298.15 101300 880000 7 0.5059 291.15
13 0.1018 298.15 101300 607000 8 0.4644 291.15
14 0.0484 298.15 101300 327000 9 0.4242 291.15
1 0.8658 318.15 101300 590200 10 0.3679 291.15
2 0.7782 318.15 101300 948100 11 0.3095 291.15
3 0.6807 318.15 101300 1280500 12 0.2467 291.15
4 0.5868 318.15 101300 1521600 13 0.1829 291.15
5 0.5019 318.15 101300 1612900 14 0.115 291.15
6 0.4351 318.15 101300 1610600 15 0.0547 291.15
7 0.3928 318.15 101300 1581300 16 0.9152 318.15
8 0.3373 318.15 101300 1490700 17 0.8111 318.15
9 0.2913 318.15 101300 1404300 18 0.7066 318.15
10 0.2388 318.15 101300 1231700 19 0.6146 318.15
1 0.908 291.15 101320 448800 20 0.5376 318.15
2 0.791 291.15 101320 955500 21 0.479 318.15
3 0.6825 291.15 101320 1274200 22 0.4055 318.15
4 0.5925 291.15 101320 1447500 23 0.3369 318.15
5 0.5323 291.15 101320 1522900 24 0.2632 318.15
6 0.4839 291.15 101320 1539900 25 0.1846 318.15
7 0.4319 291.15 101320 1525300 26 0.1094 318.15
8 0.3815 291.15 101320 1437600 27 0.0477 318.15
9 0.3286 291.15 101320 1335800
10 0.2728 291.15 101320 1198600 Ortega, J.; Placido, J.; Tol
11 0.2159 291.15 101320 1015900 Ortega, J.; Sabater, G.; de
12 0.157 291.15 101320 787100
13 0.0978 291.15 101320 531100
14 0.0486 291.15 101320 305200
15 0.8997 318.15 101320 622300
16 0.8105 318.15 101320 1019400
17 0.7158 318.15 101320 1352000
18 0.6287 318.15 101320 1534200
19 0.5505 318.15 101320 1627900
20 0.4863 318.15 101320 1647000
21 0.4401 318.15 101320 1619100
22 0.4009 318.15 101320 1565800
23 0.3205 318.15 101320 1409900
24 0.2407 318.15 101320 1175200
25 0.1701 318.15 101320 902300
26 0.1186 318.15 101320 646800
27 0.0785 318.15 101320 439800
28 0.034 318.15 101320 213200

Nagata, I.; Nagashima, M.; Kazuma, K.; Nakagawa, S. J. Chem. Eng. Jpn., 1975, 8, 261-5 He
Ortega, J.; Legido, J. L.; Fernandez, J.; Lopez, M.; Pias, L.; Paz Andrade, M. I. Fluid Phase Eq
Ortega, J.; Espiau, F.; Dieppa, R. Fluid Phase Equilib., 2004, 215, 175-186 Measurement an
Ortega, J.; Sabater, G.; de la Nuez, I.; Quintana, J. J. J. Chem. Eng. Data, 2007, 52(1), 215-22
e - propyl formate Hexane - Butyl formate Hexane -

Excess Mole Excess


Pressure Temperat Pressure
enthalpy No. fraction enthalpy No.
(N/sqm) ure (K) (N/sqm)
(J/kmol) N-HEX-01 (J/kmol)

101000 464800 1 0.9377 298.15 101000 353900


101000 778500 2 0.8655 298.15 101000 615600
101000 1009200 3 0.7926 298.15 101000 819700
101000 1169400 4 0.7232 298.15 101000 954400
101000 1264200 5 0.6602 298.15 101000 1037700
101000 1300100 6 0.5989 298.15 101000 1089300
101000 1301700 7 0.5424 298.15 101000 1103800
101000 1283200 8 0.4943 298.15 101000 1091000
101000 1236900 9 0.4856 298.15 101000 1087100
101000 1213600 10 0.4406 298.15 101000 1060000
101000 1187600 11 0.3907 298.15 101000 1011200
101000 1139700 12 0.3372 298.15 101000 937300
101000 1038700 13 0.2809 298.15 101000 836800
101000 908300 14 0.2226 298.15 101000 708400
101000 756100 15 0.1636 298.15 101000 554900
101000 589700 16 0.1044 298.15 101000 375800
101000 381000 17 0.0459 298.15 101000 182800
101000 178200 1 0.9135 291.15 101320 321700
101320 492500 2 0.8412 291.15 101320 562400
101320 782600 3 0.7697 291.15 101320 764200
101320 983200 4 0.7027 291.15 101320 905200
101320 1105300 5 0.6449 291.15 101320 989700
101320 1178100 6 0.5919 291.15 101320 1037900
101320 1210200 7 0.546 291.15 101320 1056900
101320 1215000 8 0.4886 291.15 101320 1051200
101320 1200500 9 0.4394 291.15 101320 1017700
101320 1148300 10 0.3823 291.15 101320 953200
101320 1080700 11 0.3225 291.15 101320 859800
101320 964000 12 0.2594 291.15 101320 738000
101320 814700 13 0.1933 291.15 101320 584500
101320 643200 14 0.127 291.15 101320 401200
101320 415400 15 0.06 291.15 101320 212800
101320 191600 16 0.9192 318.15 101320 440300
101320 472800 17 0.8374 318.15 101320 704800
101320 845700 18 0.7585 318.15 101320 907600
101320 1122600 19 0.689 318.15 101320 1035600
101320 1275700 20 0.6177 318.15 101320 1119800
101320 1340900 21 0.5536 318.15 101320 1150900
101320 1338600 22 0.5118 318.15 101320 1147700
101320 1291900 23 0.4896 318.15 101320 1151500
101320 1190300 24 0.4339 318.15 101320 1114900
101320 1025100 25 0.37 318.15 101320 1046200
101320 793700 26 0.2925 318.15 101320 916100
101320 518000 27 0.2096 318.15 101320 730600
101320 248600 28 0.132 318.15 101320 505700
29 0.0588 318.15 101320 270000
Ortega, J.; Placido, J.; Toledo, F.; Vidal, M.; Siimer, E Ortega, J.; Placido, J.; Toledo, F.; Vidal, M.; Siimer, E.; Legido, J. L. Phys. Chem. C
Ortega, J.; Sabater, G.; de la Nuez, I.; Quintana, J. Ortega, J.; Sabater, G.; de la Nuez, I.; Quintana, J. J. J. Chem. Eng. Data, 2007, 52

ng. Jpn., 1975, 8, 261-5 Heats of mixing for binary systems and data reduction based on a triplet model of guggenheim.
drade, M. I. Fluid Phase Equilib., 1990, 56, 219-34 Analysis of excess enthalpies of ethyl formate + n-alkane or 1-alkanol with two group
175-186 Measurement and correlation of isobaric vapour?liquid equilibrium data and excess properties of ethyl methanoate with alka
. Data, 2007, 52(1), 215-225 Isobaric Vapor-Liquid Equilibrium Data and Excess Properties of Binary Systems Comprised of Alkyl Metha
Hexane - diethyl ether Hexane - tetrahydrofuran

Liquid Vapor
Total Mole Excess
mole Temperat mole Temperat Pressure
pressure No. fraction enthalpy
fraction ure (K) fraction ure (K) (N/sqm)
(N/sqm) HEXANE (J/kmol)
HEX-01 HEX-01

1 0.9 298.1444 101325 288000


2 0.8 298.1444 101325 496000
3 0.7 298.1444 101325 640000
4 0.6 298.1444 101325 732000
5 0.5 298.1444 101325 762000
6 0.4 298.1444 101325 737000
7 0.3 298.1444 101325 651000
8 0.2 298.1444 101325 512000
9 0.1 298.1444 101325 297000
1 0.9 298.1444 101325 276100
2 0.8 298.1444 101325 493500
3 0.7 298.1444 101325 650200
4 0.6 298.1444 101325 746000
5 0.5 298.1444 101325 780100
6 0.4 298.1444 101325 751800
7 0.3 298.1444 101325 660400
8 0.2 298.1444 101325 505100
9 0.1 298.1444 101325 285200
1 0.8883 303.1431 101325 306000
2 0.8287 303.1431 101325 428000
3 0.7812 303.1431 101325 519000
4 0.6819 303.1431 101325 652000
5 0.6066 303.1431 101325 704000
6 0.5079 303.1431 101325 740000
7 0.4092 303.1431 101325 715000
8 0.3249 303.1431 101325 649000
9 0.2044 303.1431 101325 489000
10 0.1129 303.1431 101325 308000
1 0.9009 298.15 101300 265000
2 0.8532 298.15 101300 390000
3 0.7922 298.15 101300 505000
4 0.7211 298.15 101300 626000
5 0.6562 298.15 101300 689000
6 0.5866 298.15 101300 735000
7 0.4959 298.15 101300 775000
8 0.4894 298.15 101300 768000
9 0.4263 298.15 101300 759000
10 0.3371 298.15 101300 695000
11 0.2491 298.15 101300 601000
12 0.1776 298.15 101300 464000
13 0.141 298.15 101300 390000
14 0.1003 298.15 101300 291000
15 0.0618 298.15 101300 188000
1 0.95 298.15 101325 151570
2 0.9 298.15 101325 283770
3 0.8501 298.15 101325 394020
Legido, J. L. Phys. Chem. Chem. Phys., 1999, 1(12), 2967-2974 4 0.7999 298.15 101325 492960
Chem. Eng. Data, 2007, 52(1), 215-225 Isobaric Vapor-Liquid 5 0.75 298.15 101325 573750
6 0.7002 298.15 101325 643550
7 0.6497 298.15 101325 688140
8 0.5997 298.15 101325 724950
9 0.5496 298.15 101325 748030
10 0.4995 298.15 101325 750720
11 0.4492 298.15 101325 750140
12 0.3997 298.15 101325 729390
13 0.3497 298.15 101325 695860
14 0.2998 298.15 101325 646100
15 0.25 298.15 101325 581020
16 0.1985 298.15 101325 498970
17 0.1499 298.15 101325 396080
18 0.1002 298.15 101325 289830
19 0.0501 298.15 101325 152770

Pouchly, J.; Biros, J. J. Polym. Sci., 1969, 7,


463 Site of specific solvation in the
poly(vinyl chloride) molecule
Phys. Phys.-Chim. Biol., 1975, 72, 385
Thermodynamic interaction of some
mono- and dichloroalkanes with
r 1-alkanol with two group contribution models tetrahydrofuran
hexane and of tetrachloromethane with
thyl methanoate with alkanes (hexane to decane) furan, 1,4-dioxane, tetrahydrofuran, and
Comprised of Alkyl Methanoates + Hexane tetrahydropyran tetrahydropyran
Paz Andrade, M. I. J. Chem. Thermodyn.,
1994, 26, 29-33 Excess enthalpies of
( tetrahydrofuran or tetrahydropyran + an
n-alkane) at the temperature 298.15 K
Chem. Eng. Data, 2003, 48, 190-194
Excess Enthalpies of the Ternary Mixtures:
Tetrahydrofuran + (Hexane or
Cyclohexane) + Decane at 298.15K
Heptane - Diisopropyl ether Heptane - tetrahydrofuran

Mole Excess Mole


Temperat Pressure Temperat
No. fraction enthalpy No. fraction
ure (K) (N/sqm) ure (K)
HEPTANE (J/kmol) HEPTANE

1 0.0279 298.1444 101000 26400 1 0.9056 298.1444


2 0.0678 298.1444 101000 62400 2 0.7581 298.1444
3 0.1213 298.1444 101000 105000 3 0.6434 298.1444
4 0.1784 298.1444 101000 144200 4 0.5337 298.1444
5 0.2369 298.1444 101000 176800 5 0.444 298.1444
6 0.2888 298.1444 101000 200500 6 0.3623 298.1444
7 0.3426 298.1444 101000 220200 7 0.2865 298.1444
8 0.3896 298.1444 101000 231900 8 0.2188 298.1444
9 0.4464 298.1444 101000 240900 9 0.1522 298.1444
10 0.4732 298.1444 101000 242800 10 0.0956 298.1444
11 0.4926 298.1444 101000 243500 11 0.0632 298.1444
12 0.5013 298.1444 101000 243800 1 0.9269 298.15
13 0.5233 298.1444 101000 242900 2 0.84 298.15
14 0.5487 298.1444 101000 241500 3 0.7557 298.15
15 0.6058 298.1444 101000 232500 4 0.7049 298.15
16 0.6555 298.1444 101000 219700 5 0.6125 298.15
17 0.7106 298.1444 101000 199600 6 0.5921 298.15
18 0.7653 298.1444 101000 173900 7 0.5049 298.15
19 0.8312 298.1444 101000 135900 8 0.4592 298.15
20 0.8917 298.1444 101000 93200 9 0.397 298.15
21 0.9395 298.1444 101000 54000 10 0.2915 298.15
22 0.9702 298.1444 101000 28000 11 0.2518 298.15
1 0.932 298.15 101325 62400 12 0.1881 298.15
2 0.88 298.15 101325 105200 13 0.1536 298.15
3 0.82 298.15 101325 144600 14 0.1198 298.15
4 0.76 298.15 101325 176600 15 0.0595 298.15
5 0.62 298.15 101325 231100 1 0.952 298.15
6 0.476 298.15 101325 242100 2 0.902 298.15
7 0.348 298.15 101325 219900 3 0.805 298.15
8 0.191 298.15 101325 145700 4 0.598 298.15
9 0.11 298.15 101325 93500 5 0.504 298.15
1 0.95 298.15 101325 47410 6 0.406 298.15
2 0.9 298.15 101325 93440 7 0.206 298.15
3 0.8501 298.15 101325 131650 8 0.102 298.15
4 0.8 298.15 101325 164540 9 0.05 298.15
5 0.7498 298.15 101325 192700 1 0.4 298.15
6 0.6998 298.15 101325 214450 2 0.3502 298.15
7 0.6498 298.15 101325 232410 3 0.3001 298.15
8 0.606 298.15 101325 241710 4 0.2501 298.15
9 0.5516 298.15 101325 252390 5 0.1984 298.15
10 0.4999 298.15 101325 254780 6 0.1535 298.15
11 0.4502 298.15 101325 250580 7 0.0999 298.15
12 0.3999 298.15 101325 243460 8 0.0501 298.15
13 0.3497 298.15 101325 231660 9 0.9001 298.15
14 0.3 298.15 101325 214530 10 0.8502 298.15
15 0.2497 298.15 101325 192100 11 0.8002 298.15
16 0.2 298.15 101325 164480 12 0.7502 298.15
17 0.15 298.15 101325 131450 13 0.7004 298.15
18 0.1 298.15 101325 92200 14 0.6504 298.15
19 0.0502 298.15 101325 49900 15 0.6003 298.15
1 0.949 298.15 101300 39000 16 0.5503 298.15
2 0.949 298.15 101300 41700 17 0.5004 298.15
3 0.898 298.15 101300 71300 18 0.4503 298.15
4 0.847 298.15 101300 101400 19 0.4498 298.15
5 0.745 298.15 101300 146200
Inglese, A.; Wilhelm, E.; Grolier, J.-
6 0.644 298.15 101300 181600 Kehiaian, H. V. J. Chem. Thermod
7 0.544 298.15 101300 202000 1980, 12, 217-22
8 0.444 298.15 101300 208100 Paz Andrade, M. I. J. Chem. Thermo
1994, 26, 29-33 Excess enthalpie
9 0.344 298.15 101300 192200 ( tetrahydrofuran or tetrahydropyra
10 0.245 298.15 101300 157900 n-alkane) at the temperature 298
11 0.147 298.15 101300 108800 propan-1-ol + tetrahydrofuran +
heptane at 298.1K. Experimental r
12 0.049 298.15 101300 40900 and ERAS model calculations of GE
1 0.089 303.15 101000 84400 and VE
2 0.167 303.15 101000 144300 mixtures: {tetrahydrofuran + (2,2
trimethylpentane or heptane)
3 0.248 303.15 101000 192200 methylcyclohexane} at the temper
4 0.304 303.15 101000 218700 298.15 K
5 0.39 303.15 101000 245600
6 0.497 303.15 101000 255900
7 0.584 303.15 101000 248600
8 0.694 303.15 101000 217300
9 0.779 303.15 101000 175300
10 0.865 303.15 101000 120000
11 0.911 303.15 101000 83700
Chem. Thermodyn., 1977, 9, 407-14
Excess enthalpies and volumes for N,N-
dimethylacetamide + n-alcohols at 298 .15
K
volumes of ternary mixtures containing 1-
propanol or 1-butanol, and ether
(diisopropyl ether or dibutyl ether), and
heptane
B. C.-Y. Fluid Phase Equilib., 2001, 181,
215-224 Excess enthalpies of the ternary
mixtures; diisopropyl ehter + n-octane +
(n-heptane or n-dodecane) at 298.15 K
capacities of diisopropyl ether with
several alkanols at 298.15K Application of
the symmetrical extended real associated
solution model

Didaoui, S.; Ait-Kaci, A. Fluid Phase


Equilib., 2010, 299(1), 60-64
e - tetrahydrofuran Hexane - Acetone Hexane -

Excess Mole Excess


Pressure Temperat Pressure
enthalpy No. fraction enthalpy No.
(N/sqm) ure (K) (N/sqm)
(J/kmol) HEXANE (J/kmol)

101300 270800 1 0.9593 243.224 101325 334000 1


101300 563600 2 0.9491 273.2 101325 405000 2
101300 714500 3 0.9469 273.2 101325 428000 3
101300 783800 4 0.942 293.188 101325 460000 4
101300 793000 5 0.915 253.216 101325 587000 5
101300 754600 6 0.9068 243.224 101325 618000 6
101300 681700 7 0.8812 293.188 101325 813000 7
101300 579900 8 0.8605 243.224 101325 806000 8
101300 456200 9 0.8483 273.2 101325 919000 1
101300 313800 10 0.8288 253.216 101325 934000 2
101300 220900 11 0.8179 293.188 101325 1067000 3
101300 216000 12 0.8021 273.2 101325 1070000 4
101300 432000 13 0.7676 243.224 101325 1048000 5
101300 578000 14 0.7513 293.188 101325 1276000 6
101300 662000 15 0.746 273.2 101325 1206000 7
101300 770000 16 0.7435 253.216 101325 1148000 8
101300 771000 17 0.6819 273.2 101325 1356000 9
101300 820000 18 0.6817 293.188 101325 1425000 10
101300 811000 19 0.6686 243.224 101325 1179000 11
101300 797000 20 0.6416 253.216 101325 1301000 12
101300 706000 21 0.6197 243.224 101325 1232000 13
101300 643000 22 0.6181 273.2 101325 1426000 14
101300 532000 23 0.6136 293.188 101325 1534000 15
101300 460000 24 0.5775 253.216 101325 1331000 16
101300 373000 25 0.5682 243.224 101325 1252000 17
101300 201000 26 0.5534 273.2 101325 1451000 18
101300 128500 27 0.5413 273.2 101325 1462000 19
101300 285800 28 0.5401 253.216 101325 1357000
101300 493100 29 0.5228 293.188 101325 1572000
101300 740100 30 0.5098 253.216 101325 1379000
101300 762200 31 0.4848 293.188 101325 1549000
101300 745900 32 0.4757 273.2 101325 1472000
101300 536700 33 0.4722 243.224 101325 1267000
101300 310300 34 0.4474 253.216 101325 1326000
101300 152900 35 0.4396 253.216 101325 1328000
101325 767970 36 0.4259 293.188 101325 1513000
101325 739630 37 0.4132 293.188 101325 1491000
101325 692930 38 0.41 253.216 101325 1316000
101325 625670 39 0.397 243.224 101325 1236000
101325 538960 40 0.3943 273.2 101325 1406000
101325 449520 41 0.3879 273.2 101325 1399000
101325 314810 42 0.3815 293.188 101325 1459000
101325 173590 43 0.3635 253.216 101325 1274000
101325 276820 44 0.3393 253.216 101325 1261000
101325 394010 45 0.3381 293.188 101325 1374000
101325 496730 46 0.3082 293.188 101325 1359000
101325 583620 47 0.294 243.224 101325 1112000
101325 655690 48 0.2659 273.2 101325 1181000
101325 715860 49 0.252 253.216 101325 1100000
101325 751580 50 0.2511 293.188 101325 1218000
101325 779780 51 0.2465 253.216 101325 1093000
101325 792710 52 0.2128 243.224 101325 980000
101325 791940 53 0.2064 243.224 101325 955000
101325 787820 54 0.1921 273.2 101325 1002000
55 0.1818 243.224 101325 883000
A.; Wilhelm, E.; Grolier, J.-P. E.;
an, H. V. J. Chem. Thermodyn., 56 0.1598 293.188 101325 887000
1980, 12, 217-22 57 0.155 253.216 101325 815000
ade, M. I. J. Chem. Thermodyn., 58 0.151 273.2 101325 802000
26, 29-33 Excess enthalpies of
drofuran or tetrahydropyran + an 59 0.133 243.224 101325 718000
e) at the temperature 298.15 K 60 0.0938 253.216 101325 559000
n-1-ol + tetrahydrofuran + n- 61 0.0913 243.224 101325 534000
at 298.1K. Experimental results
AS model calculations of GE, HE 62 0.0837 273.2 101325 515000
and VE 63 0.074 293.188 101325 482000
es: {tetrahydrofuran + (2,2,4- 64 0.0498 253.216 101325 223000
ethylpentane or heptane) +
yclohexane} at the temperature 65 0.0321 243.224 101325 216000
298.15 K 66 0.032 273.2 101325 213000
1 0.9 243.174 101325 630000
2 0.9 253.166 101325 690000
3 0.9 273.15 101325 710000
4 0.9 293.138 101325 730000
5 0.8 243.174 101325 980000
6 0.8 253.166 101325 1020000
7 0.8 273.15 101325 1080000
8 0.8 293.138 101325 1130000
9 0.7 243.174 101325 1160000
10 0.7 253.166 101325 1220000
11 0.7 273.15 101325 1330000
12 0.7 293.138 101325 1400000
13 0.6 243.174 101325 1250000
14 0.6 253.166 101325 1330000
15 0.6 273.15 101325 1450000
16 0.6 293.138 101325 1540000
17 0.5 243.174 101325 1280000
18 0.5 253.166 101325 1360000
19 0.5 273.15 101325 1460000
20 0.5 293.138 101325 1560000
21 0.4 243.174 101325 1240000
22 0.4 253.166 101325 1320000
23 0.4 273.15 101325 1410000
24 0.4 293.138 101325 1500000
25 0.3 243.174 101325 1140000
26 0.3 253.166 101325 1200000
27 0.3 273.15 101325 1280000
28 0.3 293.138 101325 1340000
29 0.2 243.174 101325 950000
30 0.2 253.166 101325 980000
31 0.2 273.15 101325 1070000
32 0.2 293.138 101325 1080000
33 0.1 243.174 101325 580000
34 0.1 253.166 101325 640000
35 0.1 273.15 101325 650000
36 0.1 293.138 101325 660000
1 0.9487 298.136 101325 409614
2 0.9329 298.136 101325 497896
3 0.9229 298.136 101325 572371
4 0.8534 298.136 101325 916714
5 0.8252 298.136 101325 1046837
6 0.6413 298.136 101325 1516700
7 0.4439 298.136 101325 1573184
8 0.2643 298.136 101325 1208339
9 0.1012 298.136 101325 551033
1 0.9002 303.1431 101325 773622
2 0.8185 303.1431 101325 1216707
3 0.6927 303.1431 101325 1468584
4 0.6004 303.1431 101325 1523813
5 0.4952 303.1431 101325 1597033
6 0.3015 303.1431 101325 1356871
7 0.0962 303.1431 101325 686176
8 0.8229 313.1401 101325 1381138
9 0.6989 313.1401 101325 1636362
10 0.6075 313.1401 101325 1763974
11 0.512 313.1401 101325 1866482
12 0.3081 313.1401 101325 1580297
13 0.1895 313.1401 101325 1307918
1 0.0958 308.15 101000 590000
2 0.0995 308.15 101000 603000
3 0.1931 308.15 101000 1060000
4 0.2191 308.15 101000 1171000
5 0.2229 308.15 101000 1185000
6 0.3651 308.15 101000 1622000
7 0.3655 308.15 101000 1629000
8 0.3831 308.15 101000 1659000
9 0.388 308.15 101000 1668000
10 0.5551 308.15 101000 1825000
11 0.5651 308.15 101000 1824000
12 0.6219 308.15 101000 1780000
13 0.7677 308.15 101000 1430000
14 0.7713 308.15 101000 1423000
15 0.8714 308.15 101000 943000

Schaefer, K.; Rohr, F. J. Z. Phys. Chem. (Munich), 1960, 24, 130-51 Th


Schaefer, K. Dechema Monogr., 1962, 41, 165
Murakami, S.; Amaya, K.; Fujishiro, R. Bull. Chem. Soc. Jpn., 1964, 37
Srinivasan, D.; Lakshmanan, C. M.; Degaleesan, T. E.; Laddha, G. S. In
Singh, P. P.; Malik, R.; Maken, S.; Acree Jr., W. E.; Tucker, S. A. Therm
Hexane - 2-Butanone Heptane - Acetone

Mole Excess Mole Excess


Temperat Pressure Temperat Pressure
fraction enthalpy No. fraction enthalpy
ure (K) (N/sqm) ure (K) (N/sqm)
HEXANE (J/kmol) HEPTANE (J/kmol)

0.9437 298.136 101325 354385 1 0.875 298.136 101325 896000


0.9181 298.136 101325 494967 2 0.75 298.136 101325 1382000
0.8576 298.136 101325 687013 3 0.5 298.136 101325 1702000
0.7602 298.136 101325 984077 4 0.5 298.136 101325 1707000
0.6695 298.136 101325 1161478 5 0.25 298.136 101325 1356000
0.5658 298.136 101325 1266497 6 0.125 298.136 101325 844000
0.4453 298.136 101325 1244322 1 0.95 298.1444 101000 411000
0.2475 298.136 101325 946002 2 0.89999 298.1444 101000 725200
0.95 298.1444 101325 319700 3 0.85 298.1444 101000 977000
0.9 298.1444 101325 567500 4 0.79999 298.1444 101000 1184300
0.85 298.1444 101325 765900 5 0.74999 298.1444 101000 1343500
0.8 298.1444 101325 925100 6 0.69999 298.1444 101000 1469300
0.75 298.1444 101325 1045400 7 0.64998 298.1444 101000 1563000
0.7 298.1444 101325 1136400 8 0.59998 298.1444 101000 1630500
0.65 298.1444 101325 1200100 9 0.54998 298.1444 101000 1667400
0.6 298.1444 101325 1240200 10 0.49998 298.1444 101000 1674000
0.55 298.1444 101325 1259100 11 0.44999 298.1444 101000 1658700
0.5 298.1444 101325 1252400 12 0.39999 298.1444 101000 1617500
0.45 298.1444 101325 1228900 13 0.34998 298.1444 101000 1549300
0.4 298.1444 101325 1182800 14 0.29999 298.1444 101000 1452000
0.35 298.1444 101325 1114700 15 0.24999 298.1444 101000 1318900
0.3 298.1444 101325 1026900 16 0.19999 298.1444 101000 1153100
0.25 298.1444 101325 915500 17 0.14999 298.1444 101000 945500
0.2 298.1444 101325 782500 18 0.1 298.1444 101000 690800
0.15 298.1444 101325 625800 19 0.05 298.1444 101000 378600
0.1 298.1444 101325 442300 1 0.8535 323.15 101000 1069000
0.05 298.1444 101325 233800 2 0.7718 323.15 101000 1404000
Chem. Soc. Jpn., 1964, 37, 1776-80 Heats 3 0.7354 323.15 101000 1507000
of mixing for binary mixtures the energy
of hydrogen bonding between alcohol and 4 0.5949 323.15 101000 1754000
ketone molecules 5 0.4858 323.15 101000 1782000
mixtures containing ketones I. Excess 6 0.3903 323.15 101000 1700000
enthalpies of some aliphatic ketones + n-
hexane, + benzene, and + 7 0.32 323.15 101000 1570000
tetrachloromethane 8 0.2881 323.15 101000 1497000
9 0.2313 323.15 101000 1315000
10 0.1482 323.15 101000 968900
11 0.0926 323.15 101000 664700
12 0.0474 323.15 101000 369600
1 0.0419 308.15 101000 273000
2 0.0864 308.15 101000 525000
3 0.0898 308.15 101000 546000
4 0.1761 308.15 101000 955000
5 0.2004 308.15 101000 1060000
6 0.2039 308.15 101000 1073000
7 0.3393 308.15 101000 1493000
8 0.3398 308.15 101000 1491000
9 0.3568 308.15 101000 1530000
10 0.3615 308.15 101000 1538000
11 0.5271 308.15 101000 1754000
12 0.5372 308.15 101000 1750000
13 0.5951 308.15 101000 1748000
14 0.747 308.15 101000 1489000
15 0.7508 308.15 101000 1480000
16 0.8582 308.15 101000 1027000
Eng. Data, 1960, 5(1), 30-34 Relation of
Binary Heats of Mixing and Distribution of
Ketone between Phases in some Ketone-
Water-Solvent Ternaries.
and Molar Isentropic Compressibilities of
Mixtures of 2-Propanone
Shen, S.; Wang, Y.; Shi, J.; with Heptane,
Benson, G. C.;
Benzene andJ.Trichloromethane
Lu, B. C.-Y. Chem. Thermodyn., at 298.15
1990,
K
22, 387-92 Excess enthalpies of (propan-2-
one + an n-alkane) and of (4-
methylpentan-2- one + benzene or
toluene or cyclohexane or
trichloromethane)

Singh, P. P.; Malik, R.; Maken, S.; Acree Jr.,


W. E.; Zvaigzne, A. I. Thermochim. Acta,
1990, 165, 113
unich), 1960, 24, 130-51 Thermal investigations of acetone with n-hydrocarbons

Chem. Soc. Jpn., 1964, 37, 1776-80 Heats of mixing for binary mixtures the energy of hydrogen bonding between alcohol and ketone
esan, T. E.; Laddha, G. S. Indian Chem. Manuf., 1973, 11(2), 23-8 Enthalpy-composition diagram for the acetone + n-hexane system.
W. E.; Tucker, S. A. Thermochim. Acta, 1990, 162, 291
Heptane - 2-butanone Benzene - Toluene

Mole Excess Mole


Temperat Pressure Temperat
No. fraction enthalpy No. fraction
ure (K) (N/sqm) ure (K)
HEPTANE (J/kmol) BENZE-01

1 0.875 298.136 101325 712000 1 0.324 290.6395


2 0.749 298.136 101325 1105000 2 0.49 290.6395
3 0.5 298.136 101325 1341000 3 0.6 290.6395
4 0.5 298.136 101325 1325000 4 0.75 290.6395
5 0.25 298.136 101325 991000 5 0.857 290.6395
6 0.125 298.136 101325 609000 1 0.15 301.1348
1 0.9 298.1444 101325 544000 2 0.307 301.1348
2 0.8 298.1444 101325 943000 3 0.471 301.1348
3 0.7 298.1444 101325 1205000 4 0.624 301.1348
4 0.6 298.1444 101325 1342000 5 0.804 301.1348
5 0.5 298.1444 101325 1365000 1 0.615 298.136
6 0.4 298.1444 101325 1289000 2 0.604 298.136
7 0.3 298.1444 101325 1125000 3 0.495 298.136
8 0.2 298.1444 101325 875000 4 0.476 298.136
9 0.1 298.1444 101325 520000 5 0.458 298.136
1 0.9476 298.1444 101325 346700 1 0.501 279.4462
2 0.8897 298.1444 101325 646000 2 0.5 287.8412
3 0.7625 298.1444 101325 1047800 3 0.498 337.624
4 0.6536 298.1444 101325 1247500 4 0.497 279.4462
5 0.4677 298.1444 101325 1323600 5 0.496 337.624
6 0.3781 298.1444 101325 1235600 6 0.495 327.0258
7 0.2213 298.1444 101325 922400 7 0.495 337.624
8 0.1462 298.1444 101325 704200 8 0.494 279.4462
9 0.0473 298.1444 101325 276300 9 0.494 287.8412
10 0.03 298.1444 101325 175500 10 0.494 317.7286
1 0.05 298.1444 101325 257000 11 0.494 317.7286
2 0.1 298.1444 101325 493400 12 0.492 287.8412
3 0.15 298.1444 101325 695800 13 0.49 317.7286
4 0.2 298.1444 101325 862100 14 0.49 327.0258
5 0.25 298.1444 101325 1006800 15 0.487 307.6322
6 0.3 298.1444 101325 1118600 16 0.486 297.5362
7 0.35 298.1444 101325 1209100 17 0.486 327.0258
8 0.4 298.1444 101325 1275000 18 0.485 307.6322
9 0.45 298.1444 101325 1317700 19 0.484 327.0258
10 0.5 298.1444 101325 1337500 20 0.483 297.5362
11 0.5 298.1444 101325 1338100 21 0.481 307.6322
12 0.55 298.1444 101325 1338900 22 0.479 297.5362
13 0.6 298.1444 101325 1314900 1 0.199 293.138
14 0.65 298.1444 101325 1266300 2 0.39 293.138
15 0.7 298.1444 101325 1193600 3 0.56 293.138
16 0.75 298.1444 101325 1095000 4 0.665 293.138
17 0.8 298.1444 101325 964500 5 0.78 293.138
18 0.85 298.1444 101325 799900 1 0.29 293.138
19 0.9 298.1444 101325 592700 2 0.29 313.14
20 0.95 298.1444 101325 329500 3 0.29 293.138
1 0.9235 298.1944 101300 468000 4 0.29 313.14
2 0.8576 298.1944 101300 765000 5 0.35 293.138
3 0.7067 298.1944 101300 1151000 6 0.35 313.14
4 0.5466 298.1944 101300 1297000 7 0.42 293.138
5 0.3765 298.1944 101300 1208000 8 0.42 313.14
6 0.1375 298.1944 101300 615000 9 0.42 293.138
7 0.056 298.1944 101300 289000 10 0.42 313.14
8 0.9235 318.1885 101300 488000 11 0.48 293.138
9 0.8576 318.1885 101300 776000 12 0.48 313.14
10 0.7067 318.1885 101300 1179000 13 0.59 293.138
11 0.5466 318.1885 101300 1328000 14 0.59 313.14
12 0.3765 318.1885 101300 1238000 15 0.59 293.138
13 0.2313 318.1885 101300 941000 16 0.59 313.14
14 0.1375 318.1885 101300 620000 17 0.65 293.138
15 0.056 318.1885 101300 292000 18 0.65 313.14
16 0.7067 328.1855 101300 1238000 19 0.72 293.138
17 0.5466 328.1855 101300 1382000 20 0.72 313.14
18 0.3765 328.1855 101300 1268000 21 0.77 293.138
19 0.2313 328.1855 101300 974000 22 0.77 313.14
20 0.1375 328.1855 101300 630000 23 0.77 293.138
21 0.056 328.1855 101300 300000 24 0.77 313.14
22 0.5 298.1444 101300 1320000 1 0.6295 288.141
Eng. Data, 1960, 5(1), 30-34 Relation of 2 0.5377 288.141
Binary Heats of Mixing and Distribution of
Ketone between Phases in some Ketone- 3 0.475 288.141
Water-Solvent Ternaries. 4 0.41 288.141
Biros, J.; Zivny, A.; Pouchly, J. Collect. 5 0.6638 298.136
Czech. Chem. Commun., 1978, 43, 829-
836 Heats of mixing of butanone and 6 0.6066 298.136
chloroform with alkanes: binary systems 7 0.5406 298.136
Chim. Phys. Phys.-Chim. Biol., 1979, 76, 8 0.4852 298.136
433 Enthalpies of n-alkyl alkanoates and
2-alkanones in homologous series with a 9 0.4262 298.136
normal alkane 10 0.2844 298.136
Thermodynamic Properties of Binary 11 0.6661 308.132
Mixtues Containing Ketones III. Excess
Enthalpies of n-Alkanes + Some Aliphatic 12 0.6122 308.132
Ketones 13 0.5115 308.132
Fuchs, R.; Krenzer, L.; Gaube, J. Ber. 14 0.4489 308.132
Bunsen-Ges. Phys. Chem., 1984, 88, 642 15 0.3848 308.132
Excess properties of binary mixtures
composed of a polar component and an 1 0.0393 298.1444
alkane 2 0.0804 298.1444
3 0.1248 298.1444
4 0.1746 298.1444
5 0.2227 298.1444
6 0.2783 298.1444
7 0.3383 298.1444
8 0.3938 298.1444
9 0.4393 298.1444
10 0.4668 298.1444
11 0.489 298.1444
12 0.5065 298.1444
13 0.5317 298.1444
14 0.5474 298.1444
15 0.5719 298.1444
16 0.592 298.1444
17 0.609 298.1444
18 0.639 298.1444
19 0.6839 298.1444
20 0.7311 298.1444
21 0.7848 298.1444
22 0.8262 298.1444
23 0.8705 298.1444
24 0.9101 298.1444
25 0.9533 298.1444
1 0.1 298.1444
2 0.2 298.1444
3 0.3 298.1444
4 0.4 298.1444
5 0.5 298.1444
6 0.6 298.1444
7 0.7 298.1444
8 0.8 298.1444
9 0.9 298.1444
1 0.0358 323.1371
2 0.0709 323.1371
3 0.104 323.1371
4 0.1351 323.1371
5 0.163 323.1371
6 0.1866 323.1371
7 0.2112 323.1371
8 0.2336 323.1371
9 0.2559 323.1371
10 0.2783 323.1371
11 0.297 323.1371
12 0.3137 323.1371
13 0.3313 323.1371
14 0.3487 323.1371
15 0.3655 323.1371
16 0.3817 323.1371
17 0.3974 323.1371
18 0.4092 323.1371
19 0.4206 323.1371
20 0.4315 323.1371
21 0.4399 323.1371
22 0.5132 323.1371
23 0.5412 323.1371
24 0.5725 323.1371
25 0.6073 323.1371
26 0.6456 323.1371
27 0.6887 323.1371
ween alcohol and ketone molecules 28 0.7382 323.1371
one + n-hexane system. 29 0.7955 323.1371
30 0.8618 323.1371
31 0.9411 323.1371
1 0.865 298.1444
2 0.7663 298.1444
3 0.7009 298.1444
4 0.6268 298.1444
5 0.5443 298.1444
6 0.4593 298.1444
7 0.3785 298.1444
8 0.2369 298.1444
9 0.1374 298.1444
1 0.1 300.044
2 0.2 300.044
3 0.3 300.044
4 0.4 300.044
5 0.5 300.044
6 0.5 300.044
7 0.6 300.044
8 0.7 300.044
9 0.8 300.044
10 0.9 300.044
1 0.2156 298.1444
2 0.3039 298.1444
3 0.4571 298.1444
4 0.4932 298.1444
5 0.6185 298.1444
6 0.7919 298.1444
7 0.8724 298.1444
8 0.91 298.1444
9 0.9493 298.1444
10 0.9784 298.1444
11 0.9913 298.1444

Baud, E. Bull. Soc. Chim. F


Trew, V. C. G.; Spencer, J
Canning, J.; Cheesman, G
Cheesman, G. H.; Ladner,
Mathieson, A. R.; Thynne
Paz Andrade, M. I. Acta C
Rastogi, R. P.; Nath, J.; M
Murakami, S.; Lam, V. T.;
Sturtevant, J. M.; Lyons, P
Diaz Pena, M.; Menduina
Hsu, K.-Y.; Clever, H. L. J.
Sharma, S. C.; Lakhanpal,
Diez, D.; Ruiz, B.; Royo, R
nzene - Toluene Benzene - Ethylbenzene Toluene -

Excess Mole Excess


Pressure Temperat Pressure
enthalpy No. fraction enthalpy No.
(N/sqm) ure (K) (N/sqm)
(J/kmol) BENZE-01 (J/kmol)

101325 62000 1 0.9013 298.1444 101325 47300 1


101325 75300 2 0.8067 298.1444 101325 76900 2
101325 70300 3 0.6942 298.1444 101325 89500 3
101325 56100 4 0.5931 298.1444 101325 98600 4
101325 36000 5 0.5022 298.1444 101325 104500 5
101325 54600 6 0.4032 298.1444 101325 98000 6
101325 83800 7 0.3 298.1444 101325 82900 7
101325 99900 8 0.1908 298.1444 101325 58100 8
101325 79600 9 0.1019 298.1444 101325 35900 9
101325 40300 1 0.95 298.1444 101325 22530 1
101325 62400 2 0.9 298.1444 101325 41750 2
101325 62400 3 0.85 298.1444 101325 57880 3
101325 64800 4 0.8 298.1444 101325 71130 4
101325 67100 5 0.75 298.1444 101325 81410 5
101325 66300 6 0.7 298.1444 101325 89300 6
101325 74300 7 0.65 298.1444 101325 94630 7
101325 72600 8 0.6 298.1444 101325 97750 8
101325 51400 9 0.55 298.1444 101325 98700 9
101325 75600 10 0.5 298.1444 101325 97630 10
101325 49300 11 0.5 298.1444 101325 97560 11
101325 54500 12 0.45 298.1444 101325 94800 12
101325 51100 13 0.45 298.1444 101325 94760 13
101325 75600 14 0.4 298.1444 101325 90040 14
101325 71100 15 0.35 298.1444 101325 83770 15
101325 57700 16 0.3 298.1444 101325 75870 16
101325 58100 17 0.25 298.1444 101325 66530 17
101325 71400 18 0.2 298.1444 101325 55800 18
101325 58700 19 0.15 298.1444 101325 43550 19
101325 54000 20 0.1 298.1444 101325 30290 20
101325 63100 21 0.05 298.1444 101325 15820
101325 68200 6, 141 Enthalpies of mixing of some binary
mixtures of benzene, cyclohexane, and
101325 54600 pyridine, and their methyl and ethyl
101325 63200 derivatives part 2
101325 53700 Thermodyn., 1976, 8, 259-268 Excess
enthalpies of some ethylbenzene +
101325 67100 aromatic hydrocarbon mixtures at 298.15
101325 62500 K
101325 67500
101325 43500
101325 64000
101325 67800
101325 61500
101325 48100
101325 56900
101325 49400
101325 56100
101325 50200
101325 60700
101325 55200
101325 66500
101325 59400
101325 65300
101325 60200
101325 69500
101325 64000
101325 63600
101325 57700
101325 64400
101325 59000
101325 56900
101325 49800
101325 48500
101325 42300
101325 40200
101325 34700
101325 36800
101325 35100
101000 51882
101000 61505
101000 62342
101000 61505
101000 41003
101000 49371
101000 50208
101000 58576
101000 57739
101000 42677
101000 38074
101000 45606
101000 53555
101000 50208
101000 47279
101325 9600
101325 19100
101325 28000
101325 37200
101325 45000
101325 52600
101325 58600
101325 63600
101325 66200
101325 67800
101325 67800
101325 68400
101325 68100
101325 68100
101325 67700
101325 66800
101325 66200
101325 64200
101325 60400
101325 54900
101325 47700
101325 40800
101325 32200
101325 23400
101325 12800
101325 22800
101325 41200
101325 54900
101325 63700
101325 67300
101325 65600
101325 58100
101325 44800
101325 25500
101325 10000
101325 17000
101325 23000
101325 28000
101325 32000
101325 35000
101325 38000
101325 40000
101325 43000
101325 45000
101325 46000
101325 48000
101325 49000
101325 50000
101325 50000
101325 51000
101325 52000
101325 52000
101325 52000
101325 52000
101325 52000
101325 52000
101325 52000
101325 51000
101325 51000
101325 50000
101325 49000
101325 44000
101325 38000
101325 29000
101325 14000
101325 32384.2
101325 49538.6
101325 58994.4
101325 65019.4
101325 67404.2
101325 66985.8
101325 62550.8
101325 46233.2
101325 29999.3
101325 13800
101325 31300
101325 47600
101325 58900
101325 63100
101325 63200
101325 59500
101325 48600
101325 32500
101325 14700
101325 41100
101325 54100
101325 60200
101325 62100
101325 56500
101325 38500
101325 27000
101325 22000
101325 7500
101325 3500
101325 2600

Baud, E. Bull. Soc. Chim. Fr., 1915, 17, 329-45 Thermodynamic Analysis of Binary Mixtures
Trew, V. C. G.; Spencer, J. F. Trans. Faraday Soc., 1936, 32, 701 Magnetic susceptibility and other properties of binary mixtures of orga
Canning, J.; Cheesman, G. H. J. Chem. Soc., 1955, 1230 Heats of mixing of liquids
Cheesman, G. H.; Ladner, W. R. Proc. R. Soc. London, Ser. A, 1955, 229, 387 The variation of the heat of mixing with temperature
Mathieson, A. R.; Thynne, J. C. J. J. Chem. Soc., 1956, 3708 Thermodynamics of Hydrocarbon Mixtures. II. The Heats of Mixing of the B
Paz Andrade, M. I. Acta Cient. Compostelana, 1964, 1, 117
Rastogi, R. P.; Nath, J.; Misra, J. J. Phys. Chem., 1967, 71, 1277 Thermodynamics of Weak Interactions in Liquid Mixtures I. Mixtures o
Murakami, S.; Lam, V. T.; Benson, G. C. J. Chem. Thermodyn., 1969, 1, 397-407 The thermodynamic properties of binary aromatic syst
Sturtevant, J. M.; Lyons, P. A. J. Chem. Thermodyn., 1969, 1, 201-9 Application of flow calorimetry to the determination of the enthal
Diaz Pena, M.; Menduina, C. An. Quim., 1973, 69, 857 Semicontinuous calorimeter for measuring heats of mixing
Hsu, K.-Y.; Clever, H. L. J. Chem. Thermodyn., 1975, 7, 435-442 The Excess Enthalpies of the 15 Binary Mixtures Formed from Cyclohe
Sharma, S. C.; Lakhanpal, M. L.; Rampaul, M. L. Indian J. Chem., Sect. A: Inorg., Bio-inorg., Phys., Theor. Anal. Chem., 1981, 20, 770-2
Diez, D.; Ruiz, B.; Royo, R. M.; Gutierrez Losa, C. J. Chem. Thermodyn., 1985, 17, 371-7
Toluene - Ethylbenzene Benzene - n,n-dimethylformamide

Mole Excess Mole Excess


Temperat Pressure Temperat Pressure
fraction enthalpy No. fraction enthalpy
ure (K) (N/sqm) ure (K) (N/sqm)
TOLUE-01 (J/kmol) BENZE-01 (J/kmol)

0.911 298.1444 101325 -3900 1 0.073 298.136 101000 7950


0.8012 298.1444 101325 -6200 2 0.302 298.136 101000 15899
0.7977 298.1444 101325 -7700 3 0.464 298.136 101000 6276
0.5931 298.1444 101325 -9100 4 0.511 298.136 101000 12970
0.4956 298.1444 101325 -8500 5 0.634 298.136 101000 25941
0.3888 298.1444 101325 -7800 6 0.905 298.136 101000 43932
0.2802 298.1444 101325 -7600 1 0.9638 298.1444 101325 19510
0.1929 298.1444 101325 -5400 2 0.9241 298.1444 101325 27910
0.1097 298.1444 101325 -4400 3 0.8484 298.1444 101325 28970
0.05 298.1444 101325 -1670 4 0.7959 298.1444 101325 26300
0.1 298.1444 101325 -3210 5 0.7479 298.1444 101325 23660
0.15 298.1444 101325 -4550 6 0.6957 298.1444 101325 21170
0.2 298.1444 101325 -5810 7 0.6317 298.1444 101325 19070
0.25 298.1444 101325 -6710 8 0.5815 298.1444 101325 18170
0.3 298.1444 101325 -7560 9 0.5395 298.1444 101325 17950
0.35 298.1444 101325 -8220 10 0.5012 298.1444 101325 17790
0.4 298.1444 101325 -8690 11 0.4999 298.1444 101325 17940
0.45 298.1444 101325 -9030 12 0.4737 298.1444 101325 17980
0.5 298.1444 101325 -9160 13 0.4677 298.1444 101325 18110
0.5 298.1444 101325 -9250 14 0.4441 298.1444 101325 18200
0.55 298.1444 101325 -9180 15 0.4394 298.1444 101325 18490
0.6 298.1444 101325 -8940 16 0.4055 298.1444 101325 18890
0.65 298.1444 101325 -8520 17 0.3654 298.1444 101325 19260
0.7 298.1444 101325 -7890 18 0.3252 298.1444 101325 19430
0.75 298.1444 101325 -7060 19 0.2743 298.1444 101325 19630
0.8 298.1444 101325 -6050 20 0.2335 298.1444 101325 18680
0.85 298.1444 101325 -4840 21 0.187 298.1444 101325 17420
0.9 298.1444 101325 -3420 22 0.1406 298.1444 101325 15150
0.95 298.1444 101325 -1790 23 0.0864 298.1444 101325 11120
6, 141 Enthalpies of mixing of some binary 24 0.0455 298.1444 101325 6480
mixtures of benzene, cyclohexane, and
pyridine, and their methyl and ethyl 1 0.0284 303.15 101300 3000
Tanaka, derivatives
R.; Benson, part
G. C.2J. Chem. 2 0.0536 303.15 101300 12000
Thermodyn., 1976, 8, 259-268 Excess 3 0.0933 303.15 101300 14000
enthalpies of some ethylbenzene +
aromatic hydrocarbon mixtures at 298.15 4 0.1205 303.15 101300 17000
K 5 0.1483 303.15 101300 21000
6 0.2081 303.15 101300 20000
7 0.2527 303.15 101300 18000
8 0.3333 303.15 101300 16000
9 0.418 303.15 101300 9000
10 0.4267 303.15 101300 9000
11 0.4799 303.15 101300 8000
12 0.5495 303.15 101300 7000
13 0.5687 303.15 101300 7000
14 0.5992 303.15 101300 8000
15 0.7049 303.15 101300 14000
16 0.7841 303.15 101300 17000
17 0.7978 303.15 101300 16000
18 0.8515 303.15 101300 17000
19 0.9144 303.15 101300 15000
20 0.9474 303.15 101300 13000
Studies of the Thermodynamics of Binary
Liquid Mixtures with Homologous
Formamides: II. The Benzene +
Dimethylformamide System
Fujishiro, R. J. Chem. Thermodyn., 1974, 6,
201-6 Excess enthalpies of n,n-dialkyl
amides + cyclohexane, + benzene, and +
toluene at 298.15 k
enthalpies of (N,N-dimethylformamide or
N,N-dimethylacetamide + hexane or
benzene or toluene or p-xylene or
mesitylene)
of binary mixtures of organic liquids

ing with temperature


he Heats of Mixing of the Binary Mixtures Formed by Benzene, Cyclohexane, Heptane, Toluene, and Hexane.

uid Mixtures I. Mixtures of Carbon Tetrachloride, Benzene, Toluene, and p-Xylene


ties of binary aromatic systems: II excess enthalpies and volumes of benzene + toluene and toluene + isomeric xylene mixtures at 25!3
etermination of the enthalpies of mixing of organic liquids
ures Formed from Cyclohexane, Benzene, Toluene, 1,4-Dimethylbenzene, 1,2,4-Trimethylbenzene, and 1,3,5- Trimethylbenzene at 298
l. Chem., 1981, 20, 770-2
Toluene - n,n-dimethylformamide Benzene - Chloroform

Mole Excess Mole


Temperat Pressure Temperat
No. fraction enthalpy No. fraction
ure (K) (N/sqm) ure (K)
TOLUE-01 (J/kmol) BENZENE

1 0.9537 298.1444 101325 65600 1 0.933 290.6395


2 0.9113 298.1444 101325 106120 2 0.77 290.6395
3 0.8763 298.1444 101325 131420 3 0.66 290.6395
4 0.8217 298.1444 101325 160300 4 0.416 290.6395
5 0.7712 298.1444 101325 178500 5 0.263 290.6395
6 0.7318 298.1444 101325 188600 6 0.15 290.6395
7 0.6848 298.1444 101325 196300 1 0.85386 298.136
8 0.6321 298.1444 101325 200600 2 0.68855 298.146
9 0.5883 298.1444 101325 201300 3 0.54161 298.136
10 0.5496 298.1444 101325 199500 4 0.4399 298.136
11 0.5174 298.1444 101325 196300 5 0.24282 298.166
12 0.4815 298.1444 101325 191600 6 0.13186 298.156
13 0.4452 298.1444 101325 185300 1 0.9 298.136
14 0.427 298.1444 101325 181300 2 0.8 298.136
15 0.4263 298.1444 101325 183100 3 0.7 298.136
16 0.4001 298.1444 101325 177200 4 0.6 298.136
17 0.3688 298.1444 101325 168800 5 0.5 298.136
18 0.3316 298.1444 101325 157500 6 0.4 298.136
19 0.2896 298.1444 101325 143400 7 0.3 298.136
20 0.2431 298.1444 101325 125500 8 0.2 298.136
21 0.199 298.1444 101325 106300 9 0.1 298.136
22 0.1547 298.1444 101325 85840 1 0.782 298.136
23 0.1088 298.1444 101325 62850 2 0.642 298.136
24 0.0677 298.1444 101325 40290 3 0.545 298.136
25 0.0347 298.1444 101325 21410 4 0.472 298.136
1 0.968 323.1371 101325 46000 5 0.402 298.136
2 0.937 323.1371 101325 85000 6 0.309 298.136
3 0.798 323.1371 101325 190000 7 0.183 298.136
4 0.702 323.1371 101325 230000 8 0.119 298.136
5 0.517 323.1371 101325 252000 9 0.083 298.136
6 0.421 323.1371 101325 242000 1 0.8467 297.9944
7 0.341 323.1371 101325 225000 2 0.766 297.9944
8 0.229 323.1371 101325 178000 3 0.7396 297.9944
9 0.193 323.1371 101325 155000 4 0.6629 297.9944
10 0.086 323.1371 101325 75000 5 0.5714 297.9944
11 0.071 323.1371 101325 74000 6 0.48 297.9944
12 0.045 323.1371 101325 45000 7 0.3991 297.9944
1 0.1303 303.15 101300 82000 8 0.3762 297.9944
2 0.1989 303.15 101300 109000 9 0.3698 297.9944
3 0.2623 303.15 101300 137000 10 0.3307 297.9944
4 0.3635 303.15 101300 172000 11 0.2199 297.9944
5 0.4283 303.15 101300 193000 12 0.2164 297.9944
6 0.4592 303.15 101300 196000 13 0.206 297.9944
7 0.4929 303.15 101300 204000 1 0.023 298.1444
8 0.5364 303.15 101300 208000 2 0.0453 298.1444
9 0.601 303.15 101300 204000 3 0.0681 298.1444
10 0.6509 303.15 101300 203000 4 0.0895 298.1444
11 0.7217 303.15 101300 196000 5 0.113 298.1444
12 0.8066 303.15 101300 172000 6 0.1358 298.1444
13 0.8467 303.15 101300 155000 7 0.1856 298.1444
14 0.8961 303.15 101300 121000 8 0.2325 298.1444
15 0.9263 303.15 101300 106000 9 0.2764 298.1444
1 0.8999 298.15 101325 147100 10 0.3271 298.1444
2 0.8297 298.15 101325 219600 11 0.3809 298.1444
3 0.8006 298.15 101325 242400 12 0.438 298.1444
4 0.7754 298.15 101325 249800 13 0.4416 298.1444
5 0.7693 298.15 101325 248500 14 0.5098 298.1444
6 0.7419 298.15 101325 255700 15 0.5878 298.1444
7 0.7115 298.15 101325 259900 16 0.641 298.1444
8 0.703 298.15 101325 258700 17 0.703 298.1444
9 0.6724 298.15 101325 260600 18 0.7545 298.1444
10 0.6413 298.15 101325 253900 19 0.7939 298.1444
11 0.6246 298.15 101325 254600 20 0.8299 298.1444
12 0.5871 298.15 101325 249400 21 0.9127 298.1444
13 0.5791 298.15 101325 243700 22 0.9548 298.1444
14 0.5272 298.15 101325 236100
15 0.5255 298.15 101325 231100 Baud, E. Bull. Soc. Chim. F
16 0.4524 298.15 101325 210100 Hirobe, H. J. Faculty Sci. I
17 0.4126 298.15 101325 195200 Kireev, V. A. Acta Physico
18 0.3641 298.15 101325 178100 Campbell, A. N.; Kartzma
19 0.304 298.15 101325 153800 Rastogi, R. P.; Nath, J.; M
20 0.2356 298.15 101325 123300 Nagata, I.; Tamura, K.; To
21 0.1722 298.15 101325 92600
22 0.1008 298.15 101325 53100
Fujishiro, R. J. Chem. Thermodyn., 1974, 6,
201-6 Excess enthalpies of n,n-dialkyl
amides + cyclohexane, + benzene, and +
toluene at 298.15 k

Saskovetz, V. V.; Semenov, L. V.; Gaile, A.


A.; Ivanov, G. D. Zh. Prikl. Khim.
(Leningrad), 1983, 56, 1603-7
enthalpies of (N,N-dimethylformamide or
N,N-dimethylacetamide + hexane or
benzene or toluene or p-xylene or
mesitylene)
1996, 114, 189-97 Excess enthalpies of
binary mixtures of N,N-
dimethylformamide with substituted
benzenes at 298.15 K
ic xylene mixtures at 25!31c
- Trimethylbenzene at 298.15K
ene - Chloroform Benzene - tetrachloromethane Toluene -

Excess Mole Excess


Pressure Temperat Pressure
enthalpy No. fraction enthalpy No.
(N/sqm) ure (K) (N/sqm)
(J/kmol) BENZENE (J/kmol)

101325 -63178 1 0.967 290.6395 101325 13305.1 1


101325 -192460 2 0.744 290.6395 101325 85772 2
101325 -267780 3 0.557 290.6395 101325 110458 3
101325 -359820 4 0.493 290.6395 101325 110876 4
101325 -305430 5 0.462 290.6395 101325 106274 5
101325 -200830 6 0.364 290.6395 101325 97487 6
101000 -196650 7 0.236 290.6395 101325 71965 7
101000 -324260 1 0.70038 298.196 101000 91211 8
101000 -401246 2 0.64942 298.196 101000 105855 9
101000 -424258 3 0.49876 298.216 101000 107110.4 10
101000 -369029 4 0.38231 298.206 101000 104181.6 11
101000 -238488 5 0.26907 298.206 101000 88701 1
101325 -150620 6 0.13248 298.166 101000 53974 2
101325 -251040 1 0.792 298.136 101325 76149 3
101325 -322170 2 0.597 298.136 101325 103763 4
101325 -372380 3 0.484 298.136 101325 108366 5
101325 -405850 4 0.351 298.136 101325 85772 6
101325 -418400 5 0.344 298.136 101325 99161 7
101325 -393300 6 0.268 298.136 101325 80333
101325 -322170 1 0.1408 298.136 101325 40417.4
101325 -184100 2 0.2102 298.136 101325 53974
101000 -251040 3 0.4135 298.136 101325 77822
101000 -380740 4 0.4135 298.136 101325 78659
101000 -443500 5 0.5207 298.136 101325 87027
101000 -451870 6 0.6261 298.136 101325 86190
101000 -430950 7 0.7141 298.136 101325 73638
101000 -376560 8 0.7141 298.136 101325 78659
101000 -288700 9 0.7141 298.136 101325 76986
101000 -246860 10 0.816 298.136 101325 56066
101000 -196650 1 0.897864 283.094 101325 39500
101325 -184000 2 0.892316 283.094 101325 34000
101325 -267000 3 0.882949 283.094 101325 53100
101325 -292000 4 0.810675 283.094 101325 54200
101325 -360000 5 0.809963 283.094 101325 55700
101325 -400000 6 0.797736 283.094 101325 61400
101325 -430000 7 0.748638 283.094 101325 73600
101325 -421000 8 0.745489 283.094 101325 71300
101325 -418000 9 0.664977 283.094 101325 79200
101325 -407000 10 0.645087 283.094 101325 81300
101325 -398000 11 0.623664 283.094 101325 80700
101325 -318000 12 0.582786 283.094 101325 99600
101325 -308000 13 0.568628 283.094 101325 83900
101325 -309000 14 0.566583 283.094 101325 79800
101325 -40600 15 0.427552 283.094 101325 88900
101325 -79500 16 0.301789 283.094 101325 74500
101325 -116400 17 0.902749 293.088 101325 44700
101325 -151900 18 0.821951 293.088 101325 62100
101325 -185100 19 0.774043 293.088 101325 73300
101325 -216800 20 0.757994 293.088 101325 77500
101325 -276000 21 0.755668 293.088 101325 91800
101325 -321400 22 0.707292 293.088 101325 86400
101325 -354700 23 0.647833 293.088 101325 100400
101325 -385200 24 0.638636 293.088 101325 99300
101325 -404700 25 0.613182 293.088 101325 89900
101325 -413800 26 0.562475 293.088 101325 103300
101325 -415200 27 0.328495 293.088 101325 89600
101325 -407400 28 0.755668 293.0881 101325 80400
101325 -383700 29 0.911798 303.084 101325 45100
101325 -357100 30 0.901532 303.084 101325 49000
101325 -321200 31 0.867637 303.084 101325 68200
101325 -275200 32 0.813513 303.084 101325 70200
101325 -234200 33 0.79263 303.084 101325 95400
101325 -197400 34 0.760312 303.084 101325 89800
101325 -106200 35 0.73994 303.084 101325 91300
101325 -55400 36 0.718905 303.084 101325 93200
37 0.665868 303.084 101325 112100
Baud, E. Bull. Soc. Chim. Fr., 1915, 17, 32 38 0.652387 303.084 101325 103600
Hirobe, H. J. Faculty Sci. Imp. Univ. Tokyo 39 0.647833 303.084 101325 111300
Kireev, V. A. Acta Physicochim. URSS, 1937, 40 0.646919 303.084 101325 111400
Campbell, A. N.; Kartzmark, E. M.; Friesen, 41 0.608366 303.084 101325 113600
Rastogi, R. P.; Nath, J.; Misra, R. R. J. C 42 0.432448 303.084 101325 117000
Nagata, I.; Tamura, K.; Tokuriki, S. Thermo 43 0.301789 303.084 101325 99200
44 0.647833 303.0841 101325 108700
45 0.895405 313.08 101325 42100
46 0.889211 313.08 101325 35000
47 0.826126 313.08 101325 85200
48 0.747852 313.08 101325 96000
49 0.685171 313.08 101325 95500
50 0.673831 313.08 101325 99400
51 0.656008 313.08 101325 103700
52 0.650569 313.08 101325 112000
53 0.648746 313.08 101325 107300
54 0.570667 313.08 101325 114300
55 0.463554 313.08 101325 122700
56 0.448153 313.08 101325 135900
57 0.311725 313.08 101325 105700
58 0.269802 313.08 101325 71400
59 0.656008 313.0801 101325 111100
1 0 288.141 101000 0
2 0.041 298.136 101000 17991
3 0.065 288.141 101000 25606.1
4 0.172 298.136 101000 61505
5 0.199 288.141 101000 62760
6 0.297 298.136 101000 88701
7 0.316 288.141 101000 84935
8 0.394 298.136 101000 102926
9 0.414 288.141 101000 94558
10 0.482 298.136 101000 111713
11 0.511 288.141 101000 99161
12 0.547 288.141 101000 99579
13 0.634 298.136 101000 109202
14 0.642 288.141 101000 92885
15 0.731 298.136 101000 92466
16 0.744 288.141 101000 78659
17 0.806 298.136 101000 73638
18 0.866 288.141 101000 47698
19 0.894 298.136 101000 46024
20 0.969 298.136 101000 13807
21 1 288.141 101000 0
1 0.95 293.138 101000 18828
2 0.9 293.138 101000 38074
3 0.85 293.138 101000 56484
4 0.8 293.138 101000 74057
5 0.75 293.138 101000 89538
6 0.7 293.138 101000 103345
7 0.65 293.138 101000 114223
8 0.6 293.138 101000 122173
9 0.55 293.138 101000 127194
10 0.5 293.138 101000 128867
11 0.45 293.138 101000 127194
12 0.4 293.138 101000 122173
13 0.35 293.138 101000 114223
14 0.3 293.138 101000 103345
15 0.25 293.138 101000 89538
16 0.2 293.138 101000 74057
17 0.15 293.138 101000 56484
18 0.1 293.138 101000 38074
19 0.05 293.138 101000 18828
1 0.29 308.132 101000 110458
2 0.35 308.132 101000 115897
3 0.45 308.132 101000 130959
4 0.49 308.132 101000 125102
5 0.55 308.132 101000 120499
6 0.59 308.132 101000 111713
7 0.66 308.132 101000 105018
8 0.68 308.132 101000 92048
9 0.76 308.132 101000 76149
10 0.81 308.132 101000 64015
11 0.35 308.132 101000 118407
12 0.45 308.132 101000 127612
13 0.59 308.132 101000 110039
14 0.76 308.132 101000 76149
15 0.81 308.132 101000 61923
16 0.21 331.5245 101000 126357
17 0.28 331.5245 101000 143511
18 0.39 331.5245 101000 173636
19 0.41 331.5245 101000 175728
20 0.43 331.5245 101000 176983
21 0.45 331.5245 101000 179912
22 0.49 331.5245 101000 180330
23 0.56 331.5245 101000 176146
24 0.57 331.5245 101000 173636
25 0.59 331.5245 101000 172799
26 0.63 331.5245 101000 160666
27 0.68 331.5245 101000 151879
28 0.76 331.5245 101000 127612
29 0.81 331.5245 101000 108366
30 0.85 331.5245 101000 84098
31 0.21 331.5245 101000 122591
32 0.28 331.5245 101000 139327
33 0.39 331.5245 101000 171962
34 0.43 331.5245 101000 176983
35 0.49 331.5245 101000 176146
36 0.57 331.5245 101000 179075
37 0.59 331.5245 101000 180749
38 0.63 331.5245 101000 162758
39 0.68 331.5245 101000 151461
40 0.76 331.5245 101000 125938
41 0.81 331.5245 101000 109621
42 0.57 331.5245 101000 175310

Baud, E. Bull. Soc. Chim. Fr., 1915, 17, 329-45 Thermodynamic Analy
Hirobe, H. J. Faculty Sci. Imp. Univ. Tokyo, 1926, 1, 155-222 Thermoc
Kireev, V. A.; Bykov, V. T.; Khodorchenko, V. V. Zh. Fiz. Khim., 1937, 1
Vold, R. D. J. Am. Chem. Soc., 1937, 59, 1515 A calorimetric test of th
Boissonnas, C. G.; Cruchaud, M. Helv. Chim. Acta, 1944, 27, 994 Influ
Schulze, W. Z. Phys. Chem. (Leipzig), 1951, 197, 105-15 Binary liquid
Scatchard, G.; Ticknor, L. B.; Goates, J. R.; McCartney, E. R. J. Am. Ch
Andrade, M. I. P.; Casanova, J.; Ocon, J. An. R. Soc. Esp. Fis. Quim., 19
Toluene - Chloroform Toluene - tetrachloromethane

Mole Excess Mole Excess


Temperat Pressure Temperat Pressure
fraction enthalpy No. fraction enthalpy
ure (K) (N/sqm) ure (K) (N/sqm)
TOLUENE (J/kmol) TOLUENE (J/kmol)

0.8502 307.9916 101325 -417000 1 0.604 283.094 101000 18828


0.7725 307.9916 101325 -558000 2 0.5345 283.094 101000 25104
0.7223 307.9916 101325 -633000 3 0.4764 283.094 101000 27196
0.7125 307.9916 101325 -636000 4 0.3522 283.094 101000 17154
0.6777 307.9916 101325 -666000 5 0.6389 293.138 101000 30962
0.5639 307.9916 101325 -719000 6 0.5389 293.138 101000 33054
0.4908 307.9916 101325 -716000 7 0.48 293.138 101000 38074
0.4566 307.9916 101325 -695000 8 0.4099 293.138 101000 35982
0.3577 307.9916 101325 -628000 9 0.3547 293.138 101000 30962
0.2788 307.9916 101325 -547000 10 0.696 303.134 101000 33890
0.2209 307.9916 101325 -447000 11 0.5902 303.134 101000 40166
0.793 298.1444 101325 -426300 12 0.539 303.134 101000 40166
0.695 298.1444 101325 -573000 13 0.4869 303.134 101000 47279
0.509 298.1444 101325 -716300 14 0.414 303.134 101000 40166
0.413 298.1444 101325 -710100 15 0.3312 303.134 101000 36819
0.397 298.1444 101325 -703400 1 0.8351 298.1944 101000 -12100
0.241 298.1444 101325 -533600 2 0.7123 298.1944 101000 -18300
0.155 298.1444 101325 -381000 3 0.6065 298.1944 101000 -18500
Chem. Thermodyn., 1971, 3, 307-17 4 0.5241 298.1944 101000 -18400
Thermodynamics of weak interactions in
liquid mixtures of chloroform and 5 0.3286 298.1944 101000 -14100
aromatic hydrocarbons 6 0.1932 298.1944 101000 -6900
1973, 70, 1355 Heats of mixing of the 7 0.1417 298.1944 101000 -5500
binary systems chloroform or
methylchloroform with aromatic 8 0.815 308.1915 101000 -3000
hydrocarbons: I experimental data 9 0.6772 308.1915 101000 -5900
10 0.5033 308.1915 101000 -5100
11 0.3551 308.1915 101000 -2700
12 0.2685 308.1915 101000 -1100
13 0.1806 308.1915 101000 1100
14 0.121 308.1915 101000 1000
15 0.815 313.19 101000 800
16 0.6518 313.19 101000 1000
17 0.5478 313.19 101000 600
18 0.488 313.19 101000 0
19 0.4439 313.19 101000 -200
20 0.4038 313.19 101000 -200
21 0.3552 313.19 101000 1600
22 0.2923 313.19 101000 2400
23 0.2483 313.19 101000 3300
24 0.1498 313.19 101000 3900
25 0.8409 318.1885 101000 3100
26 0.7198 318.1885 101000 5200
27 0.6065 318.1885 101000 5500
28 0.4977 318.1885 101000 4600
29 0.4864 318.1885 101000 5000
30 0.3979 318.1885 101000 6300
31 0.3208 318.1885 101000 6700
32 0.1932 318.1885 101000 7000
33 0.1417 318.1885 101000 5900
34 0.815 338.1834 101000 15400
35 0.7198 338.1834 101000 18000
36 0.6065 338.1834 101000 21200
37 0.4976 338.1834 101000 21600
38 0.3206 338.1834 101000 20500
39 0.1898 338.1834 101000 15000
1 0.8478 302.9931 101325 -5100
2 0.7736 302.9931 101325 -6900
3 0.656 302.9931 101325 -8300
4 0.5502 302.9931 101325 -11300
5 0.428 302.9931 101325 -14200
6 0.3492 302.9931 101325 -14200
7 0.2378 302.9931 101325 -13700
1 0.95 298.1444 101325 -1580
2 0.9 298.1444 101325 -3420
3 0.85 298.1444 101325 -5300
4 0.8 298.1444 101325 -7440
5 0.75 298.1444 101325 -9630
6 0.7 298.1444 101325 -11450
7 0.65 298.1444 101325 -13130
8 0.6 298.1444 101325 -14680
9 0.55 298.1444 101325 -15900
10 0.5 298.1444 101325 -16970
11 0.5 298.1444 101325 -16930
12 0.45 298.1444 101325 -17480
13 0.4 298.1444 101325 -17680
14 0.35 298.1444 101325 -17420
15 0.3 298.1444 101325 -16590
16 0.25 298.1444 101325 -15330
17 0.2 298.1444 101325 -13580
18 0.15 298.1444 101325 -11080
19 0.1 298.1444 101325 -8190
20 0.05 298.1444 101325 -4440
of Weak Interactions in Liquid Mixtures I.
Mixtures of Carbon Tetrachloride,
Benzene, Toluene, and p-Xylene
Chem. Soc. A, 1969, 673-8 Enthalpies of
mixing and complex formation of carbon
tetrachloride with benzene, toluene, p-
xylene, and mesitylene
Chem. Thermodyn., 1971, 3, 307-17
Thermodynamics of weak interactions in
liquid mixtures of chloroform and
aromatic hydrocarbons

Handa, Y. P.; Benson, G. C. Fluid Phase


Equilib., 1980, 4, 261
-45 Thermodynamic Analysis of Binary Mixtures
1926, 1, 155-222 Thermochemical studies
V. V. Zh. Fiz. Khim., 1937, 10, 807-12 Heat of mixing of liquids: V heat of mixing of benzene with dichloroethane, benzene with carbon t
15 A calorimetric test of the solubility equation for regular solutions
m. Acta, 1944, 27, 994 Influence of Temperature on the Heat of Formation of Mixtures. Systems Carbon Tetrachloride-Benzene
197, 105-15 Binary liquid mixtures: I. Heats of the mixing of the ethyl alchohol + bromobenzene and ethyl alcohol +toluene systems
McCartney, E. R. J. Am. Chem. Soc., 1952, 74, 3721-4 Heats of mixing in some nonelectrolyte solutions
. R. Soc. Esp. Fis. Quim., 1965, 61 b, 783-786 Heat of Mixing at Temperatures Near Boiling Point
Benzene - Acetic acid Benzene - Propionic acid

Mole Excess Mole


Temperat Pressure Temperat
No. fraction enthalpy No. fraction
ure (K) (N/sqm) ure (K)
BENZENE (J/kmol) BENZENE

1 0.92 293.1454 101325 96000 1 0.8957 298.15


2 0.755 293.1454 101325 285000 2 0.7915 298.15
3 0.711 293.1454 101325 276000 3 0.6978 298.15
4 0.624 293.1454 101325 343000 4 0.6032 298.15
5 0.598 293.1454 101325 360000 5 0.5129 298.15
6 0.421 293.1454 101325 389000 6 0.4281 298.15
7 0.258 293.1454 101325 368000 7 0.3464 298.15
8 0.196 293.1454 101325 343000 8 0.2638 298.15
9 0.138 293.1454 101325 293000 9 0.1858 298.15
10 0.082 293.1454 101325 218000 10 0.1385 298.15
1 0.9648 308.4915 101325 67000 11 0.0486 298.15
2 0.9471 308.4915 101325 86200 Chem. Thermodyn., 1999, 31, 1165
Excess molar enthalpies of (an alka
3 0.9068 308.4915 101325 117200 acid + n-heptane, or cyclohexane
4 0.9026 308.4915 101325 119300 benzene) at T=298.15K
5 0.8064 308.4915 101325 182500
6 0.7061 308.4915 101325 231900
7 0.6206 308.4915 101325 266200
8 0.5081 308.4915 101325 285900
9 0.4062 308.4915 101325 286300
10 0.2978 308.4915 101325 259500
11 0.1769 308.4915 101325 190000
12 0.1034 308.4915 101325 130600
13 0.0916 308.4915 101325 118500
14 0.0334 308.4915 101325 50700
15 0.0194 308.4915 101325 31400
1 0.9203 298.15 101325 86000
2 0.8682 298.15 101325 126500
3 0.7445 298.15 101325 208900
4 0.6393 298.15 101325 257000
5 0.5385 298.15 101325 284200
6 0.447 298.15 101325 291300
7 0.3648 298.15 101325 281300
8 0.2891 298.15 101325 259900
9 0.2157 298.15 101325 224700
10 0.149 298.15 101325 177600
11 0.1098 298.15 101325 143200
12 0.0377 298.15 101325 53800

Liszi, J. Acta Chim. Acad. Sci. Hung., 1970,


66, 411-30 Thermodynamic properties of
binary mixtures containing hoac
Nakagawa, S. J. Chem. Eng. Jpn., 1975, 8,
261-5 Heats of mixing for binary systems
and data reduction based on a triplet
and data reduction based on a triplet
model of guggenheim.
Wilhelm, E.; Inglese, A.; Grolier, J.-P. E. J.
Chem. Thermodyn., 1999, 31, 1165-1174
Excess molar enthalpies of (an alkanoic
acid + n-heptane, or cyclohexane, or
benzene) at T=298.15K
ane, benzene with carbon tetrachloride, and hexane with heptane

achloride-Benzene
lcohol +toluene systems
ne - Propionic acid Toluene - Acetic acid Benzene - M

Excess Mole Excess


Pressure Temperat Pressure
enthalpy No. fraction enthalpy No.
(N/sqm) ure (K) (N/sqm)
(J/kmol) TOLUENE (J/kmol)

101325 63200 1 0.811 290.6395 101325 225518 1


101325 91900 2 0.742 290.6395 101325 286604 2
101325 106500 3 0.676 290.6395 101325 328026 3
101325 112600 4 0.563 290.6395 101325 368190 4
101325 111800 5 0.518 290.6395 101325 372794 5
101325 105000 6 0.463 290.6395 101325 371958 6
101325 94500 7
Baud, E. Bull. Soc. Chim. Fr., 1915, 17,
101325 79800 329-45 Thermodynamic Analysis of Binary 8
101325 61200 Mixtures 9
101325 48200 10
101325 18000 11
hermodyn., 1999, 31, 1165-1174 12
molar enthalpies of (an alkanoic
n-heptane, or cyclohexane, or 13
benzene) at T=298.15K 14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
Benzene - Methyl Acetate Benzene - Ethyl Acetate

Mole Excess Mole Excess


Temperat Pressure Temperat Pressure
fraction enthalpy No. fraction enthalpy
ure (K) (N/sqm) ure (K) (N/sqm)
BENZENE (J/kmol) BENZENE (J/kmol)

0.9746 308.1416 101325 36000 1 0.9057 298.216 101000 32635


0.9736 308.1416 101325 37000 2 0.7521 298.226 101000 61505
0.9463 298.1444 101325 87000 3 0.6306 298.216 101000 90793
0.9194 308.1416 101325 104000 4 0.4935 298.216 101000 97906
0.8812 298.1444 101325 176000 5 0.3676 298.206 101000 93722
0.849 298.1444 101325 206000 6 0.2024 298.206 101000 74851.8
0.8082 308.1416 101325 213000 7 0.124 298.186 101000 40379.78
0.7803 298.1444 101325 270000 1 0.9 297.9861 101000 33890
0.7366 298.1444 101325 297000 2 0.8 297.9861 101000 60668
0.715 308.1416 101325 275000 3 0.7 297.9861 101000 81170
0.6952 298.1444 101325 334000 4 0.6 297.9861 101000 92885
0.6146 308.1416 101325 319000 5 0.5 297.9861 101000 97906
0.5904 298.1444 101325 369000 6 0.4 297.9861 101000 95814
0.5346 298.1444 101325 382000 7 0.3 297.9861 101000 88701
0.511 308.1416 101325 334000 8 0.2 297.9861 101000 73220
0.4896 298.1444 101325 379000 9 0.1 297.9861 101000 43095
0.4022 308.1416 101325 326000 1 0.8644 308.132 101325 179158.9
0.4017 308.1416 101325 327000 2 0.7702 308.132 101325 274135.7
0.3993 298.1444 101325 374000 3 0.4073 308.132 101325 264177.8
0.3962 298.1444 101325 371000 4 0.312 308.132 101325 236228.6
0.3035 308.1416 101325 286000 5 0.2078 308.132 101325 179493.6
0.2882 298.1444 101325 314000 6 0.0978 308.132 101325 106399.1
0.2031 308.1416 101325 221000 7 0.0383 308.132 101325 49203.8
0.1841 298.1444 101325 241000 1 0.9167 298.1444 101325 26800
0.1497 298.1444 101325 204000 2 0.8888 298.1444 101325 36000
0.1074 308.1416 101325 142000 3 0.8617 298.1444 101325 46400
0.097 298.1444 101325 147000 4 0.8344 298.1444 101325 50200
0.0568 308.1416 101325 89000 5 0.8071 298.1444 101325 53500
0.052 298.1444 101325 84000 6 0.8007 298.1444 101325 64800
0.0178 308.1416 101325 30000 7 0.7509 298.1444 101325 68200
0.0104 308.1416 101325 21000 8 0.7173 298.1444 101325 82400
0.9024 298.1444 101325 121700 9 0.6316 298.1444 101325 85300
0.8711 298.1444 101325 152700 10 0.5412 298.1444 101325 87400
0.8401 298.1444 101325 178200 11 0.4527 298.1444 101325 77800
0.8086 298.1444 101325 201700 12 0.257 298.1444 101325 68200
0.7782 298.1444 101325 233900 13 0.2268 298.1444 101325 67400
0.7456 298.1444 101325 253100 14 0.1988 298.1444 101325 59400
0.716 298.1444 101325 275700 15 0.1626 298.1444 101325 54000
0.6798 298.1444 101325 311700 16 0.1342 298.1444 101325 50200
0.5793 298.1444 101325 369400 17 0.1016 298.1444 101325 36000
0.4993 298.1444 101325 372000 18 0.0681 298.1444 101325 26400
0.4003 298.1444 101325 335100 19 0.0514 298.1444 101325 18400
0.2585 298.1444 101325 249800 1 0.975 298.15 101325 10000
0.2283 298.1444 101325 243900 2 0.95 298.15 101325 19600
0.201 298.1444 101325 223000 3 0.9 298.15 101325 36300
0.1719 298.1444 101325 202900 4 0.85 298.15 101325 50700
0.1445 298.1444 101325 174500 5 0.8 298.15 101325 62300
0.1143 298.1444 101325 143900 6 0.75 298.15 101325 72100
0.0867 298.1444 101325 104200 7 0.7 298.15 101325 79800
0.0563 298.1444 101325 74100 8 0.65 298.15 101325 85500
0.0417 298.1444 101325 56100 9 0.6 298.15 101325 89600
K. J. Chem. Eng. Jpn., 1973, 6, 129-34 10 0.55 298.15 101325 92800
Thermodynamic properties of methyl
acetate-benzene and methyl acetate- 11 0.5 298.15 101325 93800
cyclohexane mixtures 12 0.45 298.15 101325 92500
Mixtures. Excess Enthalpies and Excess 13 0.4 298.15 101325 90100
Volumes for Alkyl Acetates and Alkyl
Benzoates + Alkanes, + Benzene, + 14 0.35 298.15 101325 85500
Toluene, + Ethylbenzene 15 0.3 298.15 101325 79300
16 0.25 298.15 101325 71200
17 0.2 298.15 101325 61100
18 0.15 298.15 101325 49200
19 0.1 298.15 101325 34900
20 0.05 298.15 101325 18400
21 0.025 298.15 101325 9500
1 0.9491 298.15 100000 21601.7
2 0.8983 298.15 100000 40677.1
3 0.8662 298.15 100000 51410.5
4 0.8341 298.15 100000 61144.5
5 0.7879 298.15 100000 73421.8
6 0.7417 298.15 100000 83684
7 0.697 298.15 100000 91717.7
8 0.6524 298.15 100000 97929.1
9 0.607 298.15 100000 102406.6
10 0.5616 298.15 100000 105061.5
11 0.5153 298.15 100000 105923.9
12 0.4691 298.15 100000 104959.5
13 0.4219 298.15 100000 102129.8
14 0.3748 298.15 100000 97470.1
15 0.3267 298.15 100000 90874.6
16 0.2787 298.15 100000 82451.2
17 0.2298 298.15 100000 72040.1
18 0.1809 298.15 100000 59812.5
19 0.131 298.15 100000 45517.6
20 0.0812 298.15 100000 29416.1
21 0.0406 298.15 100000 14995.8
22 0.9491 308.15 100000 27262.86
23 0.8983 308.15 100000 50793.62
24 0.8662 308.15 100000 63779.04
25 0.8341 308.15 100000 75360.46
26 0.7879 308.15 100000 89635.94
27 0.7417 308.15 100000 101182.4
28 0.697 308.15 100000 109847.7
29 0.6524 308.15 100000 116158.4
30 0.607 308.15 100000 120259.1
31 0.5616 308.15 100000 122124.6
32 0.5153 308.15 100000 121830.4
33 0.4691 308.15 100000 119426.7
34 0.4219 308.15 100000 114914.8
35 0.3748 308.15 100000 108433.2
36 0.3267 308.15 100000 99918.03
37 0.2787 308.15 100000 89593.09
38 0.2298 308.15 100000 77350.39
39 0.1809 308.15 100000 63482.07
40 0.131 308.15 100000 47800.99
41 0.0812 308.15 100000 30693.78
42 0.0406 308.15 100000 15799.3

Hirobe, H. J. Faculty Sci. Imp. Univ. Tokyo,


1926, 1, 155-222 Thermochemical studies
Kireev, V. A. Acta Physicochim. URSS,
1937, 7, 363 Heats of mixing of liquids. 3.
Integral and partial heats of mixing of
normal liquids
Ratnam, A. V.; Rao, C. V.; Murti, P. S.
Chem. Eng. Sci., 1962, 17, 392
Thermodynamic Proerties of Liquid
Mixtures - Heats of Mixing at 35 deg C
Mixtures. Excess Enthalpies and Excess
Volumes for Alkyl Acetates and Alkyl
Benzoates + Alkanes, + Benzene, +
Toluene, + Ethylbenzene
Excess thermodynamic properties of
binary mixtures of ethyl acetate with
benzene, ethanol, and 2,2,2-
Shivabasappa, K. L.; Babu,atP.298.15
trifluoroethan-1-ol N.; Rao, Y. J.
Braz. J. Chem. Eng., 2008, 25(1), 167-174
ENTHALPY OF MIXING AND HEAT OF
VAPORIZATION OF ETHYL ACETATE WITH
BENZENE AND TOLUENE AT 298.15 K AND
308.15 K
Benzene - Propyl Acetate Benzene - Butyl Acetate

Liquid Vapor
Total Mole
mole Temperat mole Temperat
No. pressure No. fraction
fraction ure (K) fraction ure (K)
(N/sqm) BENZENE
BENZENE BENZENE

1 0.8731 308.15
2 0.7477 308.15
3 0.5971 308.15
4 0.5425 308.15
5 0.5042 308.15
6 0.4381 308.15
7 0.3401 308.15
8 0.2721 308.15
9 0.2286 308.15
10 0.1286 308.15

Maken, S.; Deshwal, B. R.; Chadha


Anu; Singh, K. C.; Kim, H.; Park, J.-W
Phase Equilib., 2005, 235, 42-4
ne - Butyl Acetate Toluene - Methyl Acetate Toluene -

Liquid Vapor
Excess Total
Pressure mole Temperat mole
enthalpy No. pressure No.
(N/sqm) fraction ure (K) fraction
(J/kmol) (N/sqm)
TOL TOL

101300 -7500 1
101300 -14000 2
101300 -20900 3
101300 -22700 4
101300 -24500 5
101300 -26400 6
101300 -27400 7
101300 -26000 Chart8 Title
101300 -24500 180000 9
101300 -20400 160000 10
11
S.; Deshwal, B. R.; Chadha, R.; 140000
h, K. C.; Kim, H.; Park, J.-W. Fluid 12
120000
se Equilib., 2005, 235, 42-49 13
100000 14
80000 15
60000 16
40000
17
18
20000
1
0
0 0.1 0.2 0.3 0.4 2 0.5 0.6 0
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
Toluene - Ethyl Acetate Benzene - Diisopropyl ether

Mole Excess Mole Excess


Temperat Pressure Temperat Pressure
fraction enthalpy No. fraction enthalpy
ure (K) (N/sqm) ure (K) (N/sqm)
TOLUENE (J/kmol) BENZENE (J/kmol)

0.9838 298.15 101325 4200 1 0.9034 308.1416 101300 74100


0.9612 298.15 101325 9900 2 0.7993 308.1416 101300 128400
0.906 298.15 101325 23900 3 0.657 308.1416 101300 158600
0.8554 298.15 101325 36100 4 0.5993 308.1416 101300 164400
0.8034 298.15 101325 47900 5 0.4803 308.1416 101300 159400
0.7031 298.15 101325 67600 6 0.374 308.1416 101300 144800
0.6043 298.15 101325 81900 7 0.2021 308.1416 101300 93300
Chart Title 0.51 298.15 101325 89900 8 0.053 308.1416 101300 11400
0.5081 298.15 101325 89600 1 0.131 303.15 101000 45200
0.5081 298.15 101325 90000 2 0.216 303.15 101000 71500
0.4148 298.15 101325 91500 3 0.256 303.15 101000 84300
0.3202 298.15 101325 85700 4 0.322 303.15 101000 96000
0.2277 298.15 101325 72300 5 0.39 303.15 101000 110800
0.1359 298.15 101325 50300 6 0.498 303.15 101000 132800
0.0907 298.15 101325 36100 7 0.602 303.15 101000 154900
0.045 298.15 101325 19200 8 0.7 303.15 101000 158400
0.0263 298.15 101325 11500 9 0.757 303.15 101000 151000
0.0089 298.15 101325 4100 10 0.77 303.15 101000 140900
0.9402 298.15 100000 9032.2 11 0.822 303.15 101000 126100
0.4 0.5 0.8805
0.6 298.150.8
0.7 100000
0.9 19274.4
1 12 0.885 303.15 101000 94400
0.8413 298.15 100000 26498.9 13 0.915 303.15 101000 77900
0.8021 298.15 100000 33954 Chem. Thermodyn., 1982, 14, 855-8
Excess volumes and excess enthalpies of
0.7538 298.15 100000 43243.4 diisopropyl ether with aromatic
0.7055 298.15 100000 52394.8 hydrocarbons
0.6673 298.15 100000 59348.1 2005, 79, 85-88 ENTHALPIES OF MIXING
OF BINARY AND TERNARY MIXTURES
0.6292 298.15 100000 65914.2 CONTAINING DIISOPROPYLETHER,
0.5822 298.15 100000 73274.5 BENZENE AND CYCLOHEXANE AT 303.15 K
0.5352 298.15 100000 79597
0.4889 298.15 100000 84564.5
0.4427 298.15 100000 88049.8
0.3971 298.15 100000 89804.7
0.3515 298.15 100000 89661.8
0.3065 298.15 100000 87442.8
0.2616 298.15 100000 82942.2
0.2173 298.15 100000 76071.9
0.1731 298.15 100000 66572.6
0.1382 298.15 100000 57090.2
0.1033 298.15 100000 45741.8
0.0516 298.15 100000 25306.1
0.9402 308.15 100000 12435.2
0.8805 308.15 100000 25562.4
0.8413 308.15 100000 34418
0.8021 308.15 100000 43301.3
0.7538 308.15 100000 54076.9
0.7055 308.15 100000 64418.6
0.6673 308.15 100000 72107.7
0.6292 308.15 100000 79232.7
0.5822 308.15 100000 87043.4
0.5352 308.15 100000 93559.3
0.4889 308.15 100000 98472.4
0.4427 308.15 100000 101666.7
0.3971 308.15 100000 102908.6
0.3515 308.15 100000 102034.3
0.3065 308.15 100000 98886
0.2616 308.15 100000 93254.9
0.2173 308.15 100000 85080.5
0.1731 308.15 100000 74092.7
0.1382 308.15 100000 63309.7
0.1033 308.15 100000 50551.8
0.0516 308.15 100000 27835.9

Delcros, S.; Jimenez Cuesta, E.; Romani, L.;


Roux, A. H.; Grolier, J.-P. E.; Kehiaian, H. V.
Fluid Phase Equilib., 1995, 108, 135-52
ENTHALPY OF MIXING AND HEAT OF
VAPORIZATION OF ETHYL ACETATE WITH
BENZENE AND TOLUENE AT 298.15 K AND
308.15 K
Toluene - Tetrahydrofuran Benzene - Acetone

Mole Excess Mole


Temperat Pressure Temperat
No. fraction enthalpy No. fraction
ure (K) (N/sqm) ure (K)
TOLUENE (J/kmol) Benzene

1 0.8251 298.1444 101000 -208363 1 0.843 318.1285


2 0.7567 298.1444 101000 -259408 2 0.721 318.1285
3 0.6875 298.1444 101000 -302503 3 0.512 318.1285
4 0.5948 298.1444 101000 -339322 4 0.507 318.1285
5 0.5444 298.1444 101000 -354385 5 0.406 318.1285
6 0.452 298.1444 101000 -352711 6 0.398 318.1285
7 0.44 298.1444 101000 -351456 7 0.396 318.1285
8 0.3679 298.1444 101000 -328444 8 0.212 318.1285
9 0.278 298.1444 101000 -287022 1 0.77 298.136
10 0.1399 298.1444 101000 -179912 2 0.626 298.136
1 0.0308 298.15 101300 -30700 3 0.508 298.136
2 0.0598 298.15 101300 -62700 4 0.452 298.136
3 0.1128 298.15 101300 -126900 5 0.382 298.136
4 0.1602 298.15 101300 -182400 6 0.292 298.136
5 0.2027 298.15 101300 -223700 7 0.171 298.136
6 0.2761 298.15 101300 -279700 1 0.4414 308.1416
7 0.3371 298.15 101300 -311900 2 0.4378 308.1416
8 0.4328 298.15 101300 -337100 3 0.4341 298.1444
9 0.5337 298.15 101300 -334200 4 0.4326 308.1416
10 0.6041 298.15 101300 -315300 5 0.4159 308.1416
11 0.6959 298.15 101300 -264200 6 0.4042 298.1444
12 0.7532 298.15 101300 -218900 7 0.4022 298.1444
13 0.8207 298.15 101300 -153200 8 0.3648 308.1416
14 0.8592 298.15 101300 -109100 1 0.95 298.1444
15 0.9115 298.15 101300 -55100 2 0.89999 298.1444
16 0.9482 298.15 101300 -22500 3 0.84999 298.1444
1 0.9 298.15 101325 -121400 4 0.79999 298.1444
2 0.85 298.15 101325 -176100 5 0.74999 298.1444
3 0.8 298.15 101325 -222600 6 0.69999 298.1444
4 0.75 298.15 101325 -263100 7 0.64999 298.1444
5 0.7 298.15 101325 -296600 8 0.59999 298.1444
6 0.65 298.15 101325 -324100 9 0.54998 298.1444
7 0.6 298.15 101325 -344400 10 0.49999 298.1444
8 0.55 298.15 101325 -357500 11 0.44999 298.1444
9 0.5 298.15 101325 -363200 12 0.39999 298.1444
10 0.45 298.15 101325 -361500 13 0.34999 298.1444
11 0.4 298.15 101325 -352200 14 0.29999 298.1444
12 0.35 298.15 101325 -335500 15 0.24999 298.1444
13 0.3 298.15 101325 -311300 16 0.19999 298.1444
14 0.25 298.15 101325 -278800 17 0.15 298.1444
15 0.2 298.15 101325 -238400 18 0.1 298.1444
16 0.15 298.15 101325 -189800 19 0.05 298.1444
17 0.1 298.15 101325 -133100 1 0.8989 298.1444
Chem. Eng. Data, 1978, 23, 150-152 2 0.7965 298.1444
Thermodynamic evidence for complex
formation between tetrahydrofuran and 3 0.7003 298.1444
aromatic hydrocarbons 4 0.5982 298.1444
Data, 1992, 37, 230-232 Excess enthalpies 5 0.5517 298.1444
and excess volumes of binary mixtures
containing toluene + cyclic ethers at 6 0.4976 298.1444
298.15 K 7 0.4481 298.1444
8 0.405 298.1444
Brocos, P.; Calvo, E.; Bravo, R.; Pintos, M.;
Amigo, A.; Roux, A. H.; Roux-Desgranges, 9 0.2958 298.1444
G. J. Chem. Eng. Data, 1999, 44, 67-72 10 0.1956 298.1444
11 0.0923 298.1444

Moebius, H. H. J. Prakt. C
Brown, I.; Fock, W. Aust.
Campbell, A. N.; Kartzma
Mattingley, B. I.; Fenby, D
Akamatsu, Y.; Ogawa, H.;
Marongiu, B.; Dernini, S.;
nzene - Acetone Benzene - 2-Butanone Toluene

Excess Mole Excess


Pressure Temperat Pressure
enthalpy No. fraction enthalpy No.
(N/sqm) ure (K) (N/sqm)
(J/kmol) BENZENE (J/kmol)

101325 116000 1 0.97 298.1444 101325 6260 1


101325 147000 2 0.95 298.1444 101325 8280 2
101325 159000 3 0.93 298.1444 101325 9050 3
101325 158000 4 0.91 298.1444 101325 8650 4
101325 152000 5 0.9 298.1444 101325 8270 5
101325 148000 6 0.89 298.1444 101325 7570 6
101325 145000 7 0.85 298.1444 101325 3520 7
101325 108000 8 0.8 298.1444 101325 -4060 8
101000 117150 9 0.75 298.1444 101325 -12830 9
101000 167360 10 0.7 298.1444 101325 -22030 1
101000 192460 11 0.65 298.1444 101325 -30660 2
101000 192460 12 0.6 298.1444 101325 -38370 3
101000 171540 13 0.55 298.1444 101325 -44710 4
101000 125520 14 0.5 298.1444 101325 -49530 5
101000 75310 15 0.45 298.1444 101325 -52700 6
101325 147000 16 0.4 298.1444 101325 -53980 7
101325 146800 17 0.35 298.1444 101325 -53290 8
101325 144100 18 0.3 298.1444 101325 -50700 9
101325 146100 19 0.3 298.1444 101325 -50700 10
101325 146800 20 0.3 298.1444 101325 -50650 11
101325 142300 21 0.25 298.1444 101325 -46160 12
101325 143800 22 0.2 298.1444 101325 -39910 13
101325 143500 23 0.15 298.1444 101325 -32120 14
101000 39700 24 0.1 298.1444 101325 -22750 15
101000 67900 25 0.05 298.1444 101325 -12010
101000 89000 1 0.9003 298.1444 101300 9000
101000 105100 2 0.7987 298.1444 101300 -5000
101000 117600 3 0.6948 298.1444 101300 -24000
101000 126700 4 0.6065 298.1444 101300 -39000
101000 133200 5 0.4996 298.1444 101300 -50000
101000 135900 6 0.4017 298.1444 101300 -55000
101000 138200 7 0.2979 298.1444 101300 -51000
101000 138400 8 0.1956 298.1444 101300 -40000
101000 136800 9 0.1024 298.1444 101300 -23000
enthalpies of some aliphatic ketones + n-
101000 132700 hexane, + benzene, and +
101000 126500 tetrachloromethane
101000 118000 Matteoli, E. Thermochim. Acta, 1989, 149,
111 Calorimetric study of molecular
101000 106700 interactions in mixtures of substances
101000 92700 containing carbonyl groups
101000 76100
101000 55000
101000 27000
101300 63000
101300 107000
101300 135000
101300 147000
101300 148000
101300 146000
101300 142000
101300 134000
101300 111000
101300 81000
101300 43000

Moebius, H. H. J. Prakt. Chem., 1955, 2, 95


Brown, I.; Fock, W. Aust. J. Chem., 1957, 10, 417 Heats of mixing III. Acetone and alcohol solutions
Campbell, A. N.; Kartzmark, E. M.; Friesen, H. Can. J. Chem., 1961, 39, 735 The equilibrium diagrams, heats of mixing, dipole moments
Mattingley, B. I.; Fenby, D. V. J. Chem. Thermodyn., 1975, 7, 307-8 Excess enthalpies of triethylamine + benzene and of acetone + ben
Akamatsu, Y.; Ogawa, H.; Murakami, S. Thermochim. Acta, 1987, 113, 141 Molar Excess Enthalpies, Molar Excess Volumes and Molar
Marongiu, B.; Dernini, S.; Lepori, L.; Matteoli, E. Thermochim. Acta, 1989, 149, 111 Calorimetric study of molecular interactions in mix
Toluene - Acetone Toluene- 2-Butanone

Mole Excess Mole Excess


Temperat Pressure Temperat Pressure
fraction enthalpy No. fraction enthalpy
ure (K) (N/sqm) ure (K) (N/sqm)
TOLUENE (J/kmol) TOLUENE (J/kmol)

0.738 317.9785 101325 182004 1 0.886 298.136 101325 65300


0.6183 317.9785 101325 229283 2 0.742 298.136 101325 109200
0.5454 317.9785 101325 248111 3 0.632 298.136 101325 118800
0.4726 317.9785 101325 254806 4 0.588 298.136 101325 105900
0.4177 317.9785 101325 246019 5 0.428 298.136 101325 95000
0.4038 317.9785 101325 240162 6 0.37 298.136 101325 84500
0.3535 317.9785 101325 223844 7 0.208 298.136 101325 56100
0.2832 317.9785 101325 199577 8 0.072 298.136 101325 26800
0.2213 317.9785 101325 166942 1 0.034 298.15 101300 -1000
0.028 298.15 101300 21800 2 0.0657 298.15 101300 -1800
0.0545 298.15 101300 40900 3 0.1234 298.15 101300 -1700
0.1034 298.15 101300 81100 4 0.1743 298.15 101300 100
0.1875 298.15 101300 134800 5 0.2196 298.15 101300 2200
0.2571 298.15 101300 172800 6 0.2969 298.15 101300 8200
0.3158 298.15 101300 200900 7 0.3602 298.15 101300 15100
0.4091 298.15 101300 226000 8 0.4578 298.15 101300 28000
0.5095 298.15 101300 243800 9 0.5588 298.15 101300 43600
0.5806 298.15 101300 242300 10 0.6281 298.15 101300 53900
0.675 298.15 101300 221900 11 0.717 298.15 101300 64400
0.7347 298.15 101300 202500 12 0.7716 298.15 101300 66400
0.806 298.15 101300 165600 13 0.8352 298.15 101300 64000
0.847 298.15 101300 138800 14 0.8711 298.15 101300 57600
0.8925 298.15 101300 104000 15 0.9102 298.15 101300 46300
0.9432 298.15 101300 56100 16 0.953 298.15 101300 29200
PRoperties of Some Binary Solutions
COntaining Hydrocarbons and Polar 17 0.9643 298.15 101300 23500
Organic Solvents 1 0.975 298.15 101325 7590
Acta, 1993, 216, 35-44 Excess enthalpies 2 0.95 298.15 101325 12370
for binary mixtures of toluene, p-xylene or
pseudocumene + methyl-n-alkyl ketones. 3 0.9 298.15 101325 17530
Application of an extended cell model 4 0.84999 298.15 101325 17700
5 0.79998 298.15 101325 14520
6 0.75 298.15 101325 9680
7 0.70001 298.15 101325 3280
8 0.65 298.15 101325 -3450
9 0.6 298.15 101325 -10160
10 0.5 298.15 101325 -22360
11 0.45 298.15 101325 -26550
12 0.4 298.15 101325 -29540
13 0.35 298.15 101325 -31190
14 0.30001 298.15 101325 -31410
15 0.25001 298.15 101325 -30070
16 0.2 298.15 101325 -27080
17 0.15001 298.15 101325 -22450
18 0.10001 298.15 101325 -16380
19 0.05001 298.15 101325 -8740
20 Arm,0.025 298.15
H.; Hugli, 101325
F.; Signer, -5440
R. Helv. Chim.
Acta, 1957, 40, 1200 Thermodynamics
measurements for mixtures of
ethylbezene with toluene and
methylethylketone
Acta, 1993, 216, 35-44 Excess enthalpies
for binary mixtures of toluene, p-xylene or
pseudocumene + methyl-n-alkyl ketones.
Application of an extended cell model
butanone + cyclohexane, or
methylcyclohexane, or benzene, or
toluene, or chlorobenzene, or
cyclohexanone) at T = 298.15 K

of mixing, dipole moments, densities, and boiling points of the system acetone-chloroform-benzene.
zene and of acetone + benzene
Excess Volumes and Molar Isentropic Compressibilities of Mixtures of 2-Propanone with Heptane, Benzene and Trichloromethane a
olecular interactions in mixtures of substances containing carbonyl groups
Benzene - Acetonitrile Toluene - Acetonitrile

Mole Excess Mole


Temperat Pressure Temperat
No. fraction enthalpy No. fraction
ure (K) (N/sqm) ure (K)
BENZENE (J/kmol) TOLUENE

1 0.85 318.1285 101325 249000 1 0.6316 317.9785


2 0.689 318.1285 101325 398000 2 0.5355 317.9785
3 0.493 318.1285 101325 501000 3 0.4583 317.9785
4 0.416 318.1285 101325 496000 4 0.3359 317.9785
5 0.408 318.1285 101325 489000 5 0.3288 317.9785
6 0.334 318.1285 101325 475000 6 0.2857 317.9785
7 0.331 318.1285 101325 467000 7 0.2257 317.9785
8 0.133 318.1285 101325 287000 8 0.2014 317.9785
1 0.5127 318.1285 101000 476139.2 1 0.9371 321.3376
2 0.4442 318.1285 101000 488482 2 0.8026 321.3376
3 0.4438 318.1285 101000 488691.2 3 0.6928 321.3376
1 0.9152 317.9886 101325 138072 4 0.6296 321.3376
2 0.8222 317.9886 101325 249785 5 0.5006 321.3376
3 0.7463 317.9886 101325 326770 6 0.3967 321.3376
4 0.6691 317.9886 101325 393296 7 0.2983 321.3376
5 0.5952 317.9886 101325 442667 8 0.1983 321.3376
6 0.5188 317.9886 101325 477394 9 0.1055 321.3376
7 0.4597 317.9886 101325 491202 1 0.054 298.1444
8 0.4292 317.9886 101325 493294 2 0.113 298.1444
9 0.3975 317.9886 101325 491620 3 0.181 298.1444
10 0.3569 317.9886 101325 478650 4 0.225 298.1444
11 0.354 317.9886 101325 481997 5 0.27 298.1444
12 0.3195 317.9886 101325 465679 6 0.303 298.1444
13 0.2592 317.9886 101325 430534 7 0.322 298.1444
14 0.1984 317.9886 101325 372794 8 0.337 298.1444
15 0.1331 317.9886 101325 283675 9 0.36 298.1444
16 0.0639 317.9886 101325 153134 10 0.4 298.1444
1 0.811 318.1386 101325 243000 11 0.442 298.1444
2 0.81 318.1386 101325 257400 12 0.51 298.1444
3 0.783 318.1386 101325 280000 13 0.637 298.1444
4 0.741 318.1386 101325 318000 14 0.784 298.1444
5 0.631 318.1386 101325 419000 15 0.968 298.1444
6 0.573 318.1386 101325 452000 16 0.1115 314.3397
7 0.46 318.1386 101325 477000 17 0.174 314.3397
8 0.454 318.1386 101325 486000 18 0.245 314.3397
9 0.279 318.1386 101325 435000 19 0.296 314.3397
10 0.166 318.1386 101325 324400 20 0.328 314.3397
11 0.101 318.1386 101325 228100 21 0.335 314.3397
1 0.9248 298.1444 101325 107600 22 0.354 314.3397
2 0.8965 298.1444 101325 139800 23 0.393 314.3397
3 0.8616 298.1444 101325 180000 24 0.436 314.3397
4 0.8159 298.1444 101325 226900 25 0.482 314.3397
5 0.7607 298.1444 101325 292200 26 0.53 314.3397
6 0.6944 298.1444 101325 340700 27 0.581 314.3397
7 0.6187 298.1444 101325 394700 28 0.719 314.3397
8 0.5367 298.1444 101325 436200 29 0.865 314.3397
9 0.4537 298.1444 101325 460500 1 0.822 298.1444
10 0.3713 298.1444 101325 456700 2 0.755 298.1444
11 0.2958 298.1444 101325 434900 3 0.734 298.1444
12 0.2315 298.1444 101325 389700 4 0.61 298.1444
13 0.177 298.1444 101325 331500 5 0.495 298.1444
14 0.1336 298.1444 101325 273800 6 0.376 298.1444
15 0.073 298.1444 101325 167400 7 0.138 298.1444
1 0.9016 298.1444 101325 140000 8 0.093 298.1444
2 0.9013 298.1444 101325 140000 1 0.9518 298.15
3 0.831 298.1444 101325 220000 2 0.906 298.15
4 0.78 298.1444 101325 270000 3 0.906 298.15
5 0.6992 298.1444 101325 340000 4 0.8623 298.15
nd Trichloromethane a 6 0.6981 298.1444 101325 340000 5 0.8623 298.15
7 0.5989 298.1444 101325 420000 6 0.8206 298.15
8 0.5971 298.1444 101325 410000 7 0.8165 298.15
9 0.4987 298.1444 101325 470000 8 0.7063 298.15
10 0.4972 298.1444 101325 460000 9 0.6642 298.15
11 0.4808 298.1444 101325 480000 10 0.6379 298.15
12 0.4804 298.1444 101325 470000 11 0.5357 298.15
13 0.425 298.1444 101325 480000 12 0.4258 298.15
14 0.4116 298.1444 101325 490000 13 0.3309 298.15
15 0.4 298.1444 101325 480000 14 0.2479 298.15
16 0.3951 298.1444 101325 470000 15 0.1749 298.15
17 0.3022 298.1444 101325 460000 16 0.11 298.15
18 0.3009 298.1444 101325 450000 17 0.0521 298.15
19 0.2042 298.1444 101325 380000 18 0.0521 298.15
20 0.2008 298.1444 101325 370000 Orye, R. V.; Prausnitz, J. M
21 0.1022 298.1444 101325 230000 Kesarwani, V. S.; Chandak
22 0.1003 298.1444 101325 230000 Di Cave, S.; De Santis, R.;
1 0.042 298.1444 100000 102090 Li, I. F.; Gaile, A. A.; Seme
2 0.0855 298.1444 100000 194974 Cardelli, C.; Conti, G.; Gia
3 0.133 298.1444 100000 277399
4 0.185 298.1444 100000 347272
5 0.2415 298.1444 100000 404174
6 0.2705 298.1444 100000 430952
7 0.312 298.1444 100000 447688
8 0.347 298.1444 100000 458566
9 0.357 298.1444 100000 454382
10 0.3955 298.1444 100000 459822
11 0.436 298.1444 100000 459822
12 0.495 298.1444 100000 448943
13 0.579 298.1444 100000 407940
14 0.661 298.1444 100000 360242
15 0.762 298.1444 100000 276981
16 0.88 298.1444 100000 159829
17 0.0645 314.3397 100000 150206
18 0.137 314.3397 100000 276981
19 0.219 314.3397 100000 376560
20 0.315 314.3397 100000 451872
21 0.358 314.3397 100000 470700
22 0.417 314.3397 100000 477813
23 0.461 314.3397 100000 481578
24 0.507 314.3397 100000 472792
25 0.557 314.3397 100000 459822
26 0.61 314.3397 100000 439738
27 0.667 314.3397 100000 407103
28 0.826 314.3397 100000 256061
1 0.9053 298.1444 101325 126500
2 0.823 298.1444 101325 214600
3 0.7432 298.1444 101325 290500
4 0.6757 298.1444 101325 346600
5 0.6008 298.1444 101325 398000
6 0.5449 298.1444 101325 427900
7 0.4791 298.1444 101325 451300
8 0.4236 298.1444 101325 459900
9 0.3909 298.1444 101325 459600
10 0.3404 298.1444 101325 447200
11 0.2853 298.1444 101325 423900
12 0.2274 298.1444 101325 382700
13 0.1747 298.1444 101325 327800
14 0.126 298.1444 101325 261500
15 0.0817 298.1444 101325 184600
16 0.0384 298.1444 101325 94800
1 0.9617 303.1431 101300 59600
2 0.8988 303.1431 101300 137100
3 0.7916 303.1431 101300 247200
4 0.6684 303.1431 101300 352900
5 0.5559 303.1431 101300 421000
6 0.4674 303.1431 101300 451700
7 0.3995 303.1431 101300 457300
8 0.3754 303.1431 101300 455300
9 0.3539 303.1431 101300 452400
10 0.3353 303.1431 101300 446900
11 0.2784 303.1431 101300 420300
12 0.2042 303.1431 101300 359500
13 0.1372 303.1431 101300 276200
14 0.08 303.1431 101300 179900
15 0.0413 303.1431 101300 100100
16 0.018 303.1431 101300 45400
1 0.7804 298.15 101000 239900
2 0.7032 298.15 101000 319000
3 0.6124 298.15 101000 376800
4 0.5423 298.15 101000 428900
5 0.4705 298.15 101000 441500
6 0.372 298.15 101000 452200
7 0.2831 298.15 101000 423900
8 0.2285 298.15 101000 398800
9 0.1649 298.15 101000 318800
10 0.129 298.15 101000 269200
11 0.0899 298.15 101000 202100

Brown, I.; Fock, W. Aust. J. Chem., 1956, 9, 180-183 Heats of mixing II. Acetonitrile and nit
Anderson, R.; Prausnitz, J. M. Rev. Sci. Instrum., 1961, 32, 1224 High precision, semimicro,
Palmer, D. A.; Smith, B. D. J. Chem. Eng. Data, 1972, 17, 71-6 Thermodynamic Excess Prop
Lien, T. R.; Missen, R. W. J. Chem. Eng. Data, 1974, 19, 84-86 Excess enthalpies at 45 c for
Absood, A. H.; Tutunji, M. S.; Hsu, K.-Y.; Clever, H. L. J. Chem. Eng. Data, 1976, 21, 304 The
Fedorova, V. I.; Sumarokova, T. N. Izv. Akad. Nauk Kaz. SSR, Ser. Khim., 1978, 28, 71-3 The
Di Cave, S.; De Santis, R.; Marrelli, L. J. Chem. Eng. Data, 1980, 25, 70-72 Excess enthalpies
Nagata, I.; Tamura, K.; Tokuriki, S. Fluid Phase Equilib., 1982, 8, 75-86 Excess enthalpies fo
Nagata, I.; Tamura, K. J. Chem. Thermodyn., 1989, 21, 955
Marongiu, B.; Porcedda, S.; Falconieri, D.; Piras, A. J. Chem. Eng. Data, 2010, 55(12), 5406-
ene - Acetonitrile Diethylamine - Dipropylamine Diethylamine -

Liquid Vapor
Excess Total
Pressure mole Temperat mole
enthalpy No. pressure No.
(N/sqm) fraction ure (K) fraction
(J/kmol) (N/sqm)
DIETH-01 DIETH-01

101325 422166
101325 495386
101325 507519
101325 501243
101325 487018
101325 456893
101325 420492
101325 383673
101000 53470
101000 216400
101000 338100
101000 414800
101000 502920
101000 493080
101000 452580
101000 371000
101000 211400
100000 151461
100000 283675
100000 394133
100000 447688
100000 490365
100000 512540
100000 521326
100000 531368
100000 535552
100000 543083
100000 541828
100000 527184
100000 451872
100000 303340
100000 62342
100000 285349
100000 398317
100000 484507
100000 527184
100000 547267
100000 568187
100000 577392
100000 590781
100000 598730
100000 597475
100000 588270
100000 569024
100000 468608
100000 282838
101325 306400
101325 393300
101325 403100
101325 487800
101325 586000
101325 569500
101325 347300
101325 257900
101000 83200
101000 162300
101000 156200
101000 217900
101000 218700
101000 268700
101000 272300
101000 394100
101000 432600
101000 449900
101000 508100
101000 537600
101000 522300
101000 457700
101000 382000
101000 274800
101000 145600
101000 143500
Orye, R. V.; Prausnitz, J. M. Trans. Faraday Soc., 1965, 61, 1338 Thermodynamic PRoperties of Some Binary Solutions COntaining Hyd
Kesarwani, V. S.; Chandak, B. S.; Kher, M. G. Chem. Petro-Chem. J., 1979, 10, 3
Di Cave, S.; De Santis, R.; Marrelli, L. J. Chem. Eng. Data, 1980, 25, 70-72 Excess enthalpies for mixtures of acetonitrile and aromatic h
Li, I. F.; Gaile, A. A.; Semenov, L. V.; Pul'tsin, M. N. Russ. J. Phys. Chem., 1981, 55, 1493-5
Cardelli, C.; Conti, G.; Gianni, P. J. Therm. Anal. Calorim., 2000, 61(2), 377-388 EXCESS MOLAR ENTHALPIES OF THE TERNARY SYSTEMS
xing II. Acetonitrile and nitromethane systems
High precision, semimicro, hydrostatic calorimeter for heats of mixing of liquids
ermodynamic Excess Property Measurements for Acetonitrile-Benzene-n- Heptane System at 45 C
cess enthalpies at 45 c for ternary system acetonitrile + benzene + carbon tetrachloride
g. Data, 1976, 21, 304 The density and enthalpy of mixing of solutions of acetonitrile and of dimethyl sulfoxide with several aromatic h
Khim., 1978, 28, 71-3 Thermochemical study of tin(iv) chloride + benzene, acetonitrile + benzene, and benzonitrile + benzene systems
5, 70-72 Excess enthalpies for mixtures of acetonitrile and aromatic hydrocarbons
75-86 Excess enthalpies for the systems acetonitrile + benzene + tetrachloromethane and acetonitrile + dichloromethane + tetrachloro

Data, 2010, 55(12), 5406-5412 Calorimetric Study of Nitrile Group-Solvent Interactions and Comparison with Dispersive Quasi-Chemic
Diethylamine - Diisopropylamine Diethylamine - Triethylamine

Liquid Vapor
Total Mole Excess
mole Temperat mole Temperat Pressure
pressure No. fraction enthalpy
fraction ure (K) fraction ure (K) (N/sqm)
(N/sqm) DIETH-01 (J/kmol)
DIETH-01 DIETH-01

1 0.1 287.1416 101325 103000


2 0.1 291.1392 101325 115000
3 0.1 298.136 101325 151000
4 0.2 287.1416 101325 152000
5 0.2 291.1392 101325 186000
6 0.2 298.136 101325 216000
7 0.3 287.1416 101325 205000
8 0.3 291.1392 101325 273000
9 0.3 298.136 101325 267000
10 0.4 287.1416 101325 258000
11 0.4 291.1392 101325 283000
12 0.4 298.136 101325 325000
13 0.5 287.1416 101325 281000
14 0.5 291.1392 101325 306000
15 0.5 298.136 101325 360000
16 0.6 287.1416 101325 260000
17 0.6 291.1392 101325 285000
18 0.6 298.136 101325 332000
19 0.7 287.1416 101325 209000
20 0.7 291.1392 101325 243000
21 0.7 298.136 101325 281000
22 0.8 287.1416 101325 160000
23 0.8 291.1392 101325 176000
24 0.8 298.136 101325 210000
25 0.9 287.1416 101325 96000
26 0.9 291.1392 101325 104000
27 0.9 298.136 101325 139000
1 0.112592 293.1454 101000 113805
2 0.265332 293.1454 101000 248111
3 0.420468 293.1454 101000 356477
4 0.55393 293.1454 101000 385346
5 0.696615 293.1454 101000 356477
6 0.80752 293.1454 101000 293298
7 0.862268 293.1454 101000 235559
8 0.926427 293.1454 101000 148532
9 0.966323 293.1454 101000 71965
Phys. Chem. (Leipzig), 1962, 219, 387 The
thermodynamics of the diethylamine +
triethylamine system enthalpies of mixing
at 14, 18, and 25 c
Szeiler, B.; Devay, J. Acta Chim. Acad. Sci.
Hung., 1973, 77, 249-65 Mixing properties
of the ethanol + diethylamine +
triethylamine system
Solutions COntaining Hydrocarbons and Polar Organic Solvents

cetonitrile and aromatic hydrocarbons

OF THE TERNARY SYSTEMS (ACETONITRILE+METHYL ISOBUTYRATE +TOLUENE) AND (PROPIONITRILE+METHYL ISOBUTYRATE+ETHYLBE


de with several aromatic hydrocarbons
onitrile + benzene systems: III.

loromethane + tetrachloromethane at 298.15 k.

h Dispersive Quasi-Chemical (DISQUAC) Predictions


Diethylamine - Chloroform Diisopropylamine - Chloroform

Liquid Vapor Liquid


Total
mole Temperat mole mole Temperat
No. pressure No.
fraction ure (K) fraction fraction ure (K)
(N/sqm)
DIETHYL DIETHYL DIIP
YL ISOBUTYRATE+ETHYLBENZENE) AT 298.15 K
ylamine - Chloroform Diethylamine - Ethyl Acetate methylamine

Vapor Liquid Vapor


Total Total
mole mole Temperat mole
pressure No. pressure No.
fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
DIIP DIETH-01 DIETH-01
methylamine - dimethylamine methylformamide - methylacetamide
Liquid Vapor
Liquid Vapor
mole mole Total Total
Temperat mole Temperat mole
fraction fraction pressure No. pressure
ure (K) fraction ure (K) fraction
METHY- METHY- (N/sqm) (N/sqm)
METF METF
01 01
dimethylformamide - chloroform dimethylformamide - acetic acid

Liquid Vapor Liquid


Total
mole Temperat mole mole Temperat
No. pressure No.
fraction ure (K) fraction fraction ure (K)
(N/sqm)
DMF DMF DMF
ormamide - acetic acid methylacetamide - acetic acid dimethylaceta

Vapor Liquid Vapor


Total Total
mole mole Temperat mole
pressure No. pressure No.
fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
DMF MA MA

1
2
3
4
5
6
7
8
9
dimethylacetamide - acetic acid dimethylformamide - Methylformate

Liquid Vapor
Mole Excess Total
Temperat Pressure mole Temperat mole
fraction enthalpy No. pressure
ure (K) (N/sqm) fraction ure (K) fraction
N:N-D-02 (J/kmol) (N/sqm)
N:N-D-01 N:N-D-01

0.9 298.1444 101325 -1070000


0.8 298.1444 101325 -2163000
0.7 298.1444 101325 -3088000
0.6 298.1444 101325 -3707000
0.5 298.1444 101325 -3936000
0.4 298.1444 101325 -3743000
0.3 298.1444 101325 -3151000
0.2 298.1444 101325 -2235000
0.1 298.1444 101325 -1124000

Di Cave, S.; Carli, A. Br. Chem. Eng.


Process. Technol., 1972, 17, 439 Heats of
mixing of dimethylformamide and
dimethylacetamide
dimethylformamide - Ethyl acetate dimethylformamide - dipropyl ether

Liquid
Mole Excess
Temperat Pressure mole Temperat
No. fraction enthalpy No.
ure (K) (N/sqm) fraction ure (K)
N:N-D-01 (J/kmol)
N:N-D-01

1 0.0927 298.15 101325 60000


2 0.165 298.15 101325 105000
3 0.201 298.15 101325 120000
4 0.2756 298.15 101325 144000
5 0.3468 298.15 101325 159000
6 0.4047 298.15 101325 167000
7 0.4561 298.15 101325 168000
8 0.4963 298.15 101325 168000
9 0.5495 298.15 101325 193000
10 0.6351 298.15 101325 173000
11 0.7005 298.15 101325 153000
12 0.7795 298.15 101325 116000
13 0.8394 298.15 101325 89000
14 Venkateswarlu,
0.9066 298.15 101325R. S.;52000
P.; Ramadevi, Rao,
M. V. P.; Prasad, D. H. L. J. Chem. Eng.
Data, 2000, 45, 515-517 Excess molar
enthalpies of N,N-dimethylformamide
with chloroethanes and acetates at
298.15 K
mamide - dipropyl ether dimethylacetamide - diisopropyl ether dimethylformam

Vapor Liquid Vapor


Total Total
mole mole Temperat mole
pressure No. pressure No.
fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
N:N-D-01 DMA DMA

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
dimethylformamide - 2-propanone dimethylformamide - 2-butanone

Mole Excess Mole Excess


Temperat Pressure Temperat Pressure
fraction enthalpy No. fraction enthalpy
ure (K) (N/sqm) ure (K) (N/sqm)
N:N-D-01 (J/kmol) N:N-D-01 (J/kmol)

0.796 298.1444 101325 18030 1 0.1258 298.15 101300 57500


0.795 298.1444 101325 18200 2 0.1497 298.15 101300 70500
0.703 298.1444 101325 25900 3 0.1957 298.15 101300 89600
0.681 298.1444 101325 28200 4 0.2446 298.15 101300 104900
0.678 298.1444 101325 28620 5 0.2956 298.15 101300 114300
0.6 298.1444 101325 35600 6 0.3447 298.15 101300 121700
0.587 298.1444 101325 34980 7 0.3971 298.15 101300 123800
0.57 298.1444 101325 36440 8 0.4478 298.15 101300 123600
0.549 298.1444 101325 36740 9 0.4972 298.15 101300 145600
0.528 298.1444 101325 36990 10 0.5462 298.15 101300 141400
0.519 298.1444 101325 37070 11 0.5997 298.15 101300 139200
0.505 298.1444 101325 36940 12 0.6503 298.15 101300 127900
0.501 298.1444 101325 36900 13 0.7662 298.15 101300 93900
0.47 298.1444 101325 35400 14 0.8222 298.15 101300 72200
0.46 298.1444 101325 35270 15 0.8702 298.15 101300 56800
0.444 298.1444 101325 34180 16 Venkatesu, P.; Prabhakara Rao, M.43800
0.9022 298.15 101300 V.;
0.377 298.1444 101325 29540 Prasad, D.H.L.; Ravi-Kumar, Y. V. L.
Thermochim. Acta, 1999, 342, 73-78
Quitzsch, K.; Prinz, H. P.; Suehnel, K.; Excess molar enthalpies of N,N-
Geiseler, G. Z. Phys. Chem. (Leipzig), 1969, dimethylformamide with ketones at
311, 420-8 298.15 K
dimethylacetamide - 2-propanone Dichloromethane - Chloroform

Liquid Vapor
Total Mole
mole Temperat mole Temperat
No. pressure No. fraction
fraction ure (K) fraction ure (K)
(N/sqm) CH2CL2
DMA DMA

1 0.784 297.8361
2 0.76 297.8361
3 0.588 297.8361
4 0.524 297.8361
5 0.524 297.8361
6 0.479 297.8361
7 0.475 297.8361
8 0.474 297.8361
9 0.445 297.8361
10 0.444 297.8361
11 0.444 297.8361
12 0.332 297.8361
13 0.301 297.8361

Cheesman, G. H.; Whitaker, A. M. P


Soc. London, Ser. A, 1952, 212, 40
determination of heats of mixin
methane - Chloroform Dichloromethane - Tetrachloromethane Chloroform - Te

Excess Mole Excess


Pressure Temperat Pressure
enthalpy No. fraction enthalpy No.
(N/sqm) ure (K) (N/sqm)
(J/kmol) CH2CL2 (J/kmol)

101000 11900 1 0.821 297.8361 101000 372000 1


101000 12600 2 0.813 297.8361 101000 375000 2
101000 17000 3 0.794 297.8361 101000 403000 3
101000 17900 4 0.703 297.8361 101000 503000 4
101000 17600 5 0.702 297.8361 101000 500000 5
101000 18100 6 0.675 297.8361 101000 523000 6
101000 17900 7 0.628 297.8361 101000 556000 7
101000 17700 8 0.567 297.8361 101000 581000 1
101000 17300 9 0.527 297.8361 101000 591000 2
101000 17700 10 0.525 297.8361 101000 591000 3
101000 17700 11 0.492 297.8361 101000 590000 4
101000 16000 12 0.491 297.8361 101000 588000 5
101000 14700 13 0.491 297.8361 101000 587000 6
14 0.491 297.8361 101000 587000 7
n, G. H.; Whitaker, A. M. Proc. R.
don, Ser. A, 1952, 212, 406 The 15 0.376 297.8361 101000 545000 8
mination of heats of mixing, 16 0.376 297.8361 101000 543000 9
17 0.35 297.8361 101000 528000 1
18 0.344 297.8361 101000 530000 2
19 0.344 297.8361 101000 527000 3
20 0.277 297.8361 101000 465000 4
21 0.257 297.8361 101000 438000 5
22 0.252 297.8361 101000 431000 6
1 0.0553 298.1444 101325 125700 7
2 0.1178 298.1444 101325 248900 8
3 0.1943 298.1444 101325 374700 9
4 0.2545 298.1444 101325 454600 10
5 0.3236 298.1444 101325 523200 11
6 0.397 298.1444 101325 572300 12
7 0.4629 298.1444 101325 595300 13
8 0.5307 298.1444 101325 599200 14
9 0.5946 298.1444 101325 583100 15
10 0.6109 298.1444 101325 572100 16
11 0.6334 298.1444 101325 560000 17
12 0.7005 298.1444 101325 509700 18
13 0.7744 298.1444 101325 429400 19
14 0.8442 298.1444 101325 328800 20
15 0.9092 298.1444 101325 208000 21
16 0.9701 298.1444 101325 75100 22
1 0.858 298.1444 100000 319900 23
2 0.779 298.1444 100000 433600 24
3 0.693 298.1444 100000 521800 25
4 0.648 298.1444 100000 555000 26
5 0.601 298.1444 100000 580000 27
6 0.552 298.1444 100000 593400 28
7 0.501 298.1444 100000 598700 29
8 0.448 298.1444 100000 585300 30
9 0.392 298.1444 100000 568300 31
10 0.334 298.1444 100000 527500 32
11 0.274 298.1444 100000 475500 1
12 0.21 298.1444 100000 393900 2
1 0.0533 298.1444 101325 137000 3
2 0.1165 298.1444 101325 270000 4
3 0.1948 298.1444 101325 397000 5
4 0.2884 298.1444 101325 510000 6
5 0.3603 298.1444 101325 567000 7
6 0.4369 298.1444 101325 602000 8
7 0.4987 298.1444 101325 608000 9
8 0.5621 298.1444 101325 594000 10
9 0.6372 298.1444 101325 548000 11
10 0.706 298.1444 101325 481000 12
11 0.7955 298.1444 101325 360000 13
12 0.8477 298.1444 101325 277000 14
13 0.9276 298.1444 101325 135000 15
16
Cheesman, G. H.; Whitaker, A. M. Proc. R. S 17
Nagata, I.; Tamura, K.; Tokuriki, S. Fluid 18
Siddiqi, M. A.; Lucas, K. J. Chem. Thermodyn 19
Marongiu, B. Int. DATA Ser., Sel. Data Mixtur 20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
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86
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88
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91
92
93
94
95
96
97
98
99
100
101
102
103
104
105
Chloroform - Tetrachloromethane Dichloromethane - Acetic acid

Liquid Vapor
Mole Excess Total
Temperat Pressure mole Temperat mole
fraction enthalpy No. pressure
ure (K) (N/sqm) fraction ure (K) fraction
CHCL3 (J/kmol) (N/sqm)
DICHL-01 DICHL-01

0.885 298.186 101000 103345


0.7572 298.186 101000 175730
0.6377 298.196 101000 219242
0.5669 298.176 101000 228028
0.4589 298.196 101000 226354
0.2705 298.186 101000 184514.4
0.1822 298.196 101000 146440
0.1 297.9861 101000 76567
0.2 297.9861 101000 139746
0.3 297.9861 101000 187025
0.4 297.9861 101000 217568
0.5 297.9861 101000 225936
0.6 297.9861 101000 222589
0.7 297.9861 101000 200832
0.8 297.9861 101000 157318
0.9 297.9861 101000 90793
0.771 297.8361 101000 158000
0.769 297.8361 101000 157000
0.769 297.8361 101000 158000
0.752 297.8361 101000 170000
0.751 297.8361 101000 171000
0.748 297.8361 101000 170000
0.651 297.8361 101000 213000
0.647 297.8361 101000 213000
0.616 297.8361 101000 221000
0.614 297.8361 101000 222000
0.613 297.8361 101000 223000
0.579 297.8361 101000 228000
0.578 297.8361 101000 228000
0.551 297.8361 101000 228000
0.549 297.8361 101000 228000
0.547 297.8361 101000 230000
0.513 297.8361 101000 231000
0.51 297.8361 101000 230000
0.495 297.8361 101000 230000
0.471 297.8361 101000 228000
0.47 297.8361 101000 229000
0.468 297.8361 101000 228000
0.441 297.8361 101000 227000
0.438 297.8361 101000 228000
0.434 297.8361 101000 227000
0.332 297.8361 101000 204000
0.327 297.8361 101000 202000
0.324 297.8361 101000 202000
0.322 297.8361 101000 203000
0.3 297.8361 101000 196000
0.296 297.8361 101000 196000
0.293 297.8361 101000 195000
0.827 283.1481 101325 133600
0.737 283.1481 101325 182400
0.69 283.1481 101325 199700
0.594 283.1481 101325 224400
0.545 283.1481 101325 232500
0.495 283.1481 101325 233000
0.444 283.1481 101325 229800
0.392 283.1481 101325 223300
0.285 283.1481 101325 190300
0.175 283.1481 101325 134900
0.827 293.1454 101325 133300
0.782 293.1454 101325 158700
0.69 293.1454 101325 199400
0.594 293.1454 101325 226000
0.545 293.1454 101325 231700
0.495 293.1454 101325 233800
0.392 293.1454 101325 222500
0.339 293.1454 101325 209500
0.231 293.1454 101325 165100
0.827 293.1454 101325 139700
0.782 293.1454 101325 167300
0.69 293.1454 101325 208500
0.594 293.1454 101325 235000
0.545 293.1454 101325 241800
0.495 293.1454 101325 243100
0.392 293.1454 101325 232200
0.339 293.1454 101325 218700
0.231 293.1454 101325 171600
0.827 293.1454 101325 146000
0.782 293.1454 101325 172900
0.69 293.1454 101325 217500
0.594 293.1454 101325 245400
0.545 293.1454 101325 251500
0.495 293.1454 101325 254100
0.392 293.1454 101325 241600
0.339 293.1454 101325 227400
0.231 293.1454 101325 180400
0.827 303.1431 101325 133600
0.737 303.1431 101325 181200
0.69 303.1431 101325 199700
0.594 303.1431 101325 223900
0.545 303.1431 101325 230900
0.495 303.1431 101325 233000
0.444 303.1431 101325 230900
0.392 303.1431 101325 222700
0.285 303.1431 101325 190500
0.175 303.1431 101325 135200
0.827 313.1401 101325 162600
0.782 313.1401 101325 156700
0.737 313.1401 101325 177600
0.69 313.1401 101325 219600
0.643 313.1401 101325 211500
0.594 313.1401 101325 222100
0.545 313.1401 101325 227500
0.495 313.1401 101325 230000
0.444 313.1401 101325 227400
0.392 313.1401 101325 214600
0.339 313.1401 101325 206200
0.285 313.1401 101325 170000
0.231 313.1401 101325 163100
0.175 313.1401 101325 132900
0.782 313.1401 101325 184300
0.737 313.1401 101325 191500
0.643 313.1401 101325 230700
0.594 313.1401 101325 236100
0.545 313.1401 101325 238300
0.495 313.1401 101325 235300
0.444 313.1401 101325 245600
0.339 313.1401 101325 224100
0.231 313.1401 101325 177000
0.175 313.1401 101325 137600
0.782 313.1401 101325 168200
0.643 313.1401 101325 227800
0.594 313.1401 101325 240600
0.545 313.1401 101325 246200
0.495 313.1401 101325 248400
0.175 313.1401 101325 143900
0.828 323.1371 101325 134300
0.827 323.1371 101325 129500
0.737 323.1371 101325 175800
0.642 323.1371 101325 208700
0.545 323.1371 101325 224600
0.495 323.1371 101325 226600
0.494 323.1371 101325 234500
0.444 323.1371 101325 223700
0.339 323.1371 101325 202700
0.285 323.1371 101325 185100
0.284 323.1371 101325 190500
0.175 323.1371 101325 130700
0.173 323.1371 101325 135300
0.827 323.1371 101325 135600
0.737 323.1371 101325 181900
0.642 323.1371 101325 215800
0.545 323.1371 101325 231300
0.495 323.1371 101325 242000
0.444 323.1371 101325 233000
0.339 323.1371 101325 209800
0.285 323.1371 101325 197000
0.175 323.1371 101325 141000
0.827 323.1371 101325 139200
0.737 323.1371 101325 189200
0.642 323.1371 101325 223000
0.545 323.1371 101325 239800
0.444 323.1371 101325 238600
0.339 323.1371 101325 218500

Hirobe, H. J. Faculty Sci. Imp. Univ. Tokyo, 1926, 1, 155-222 Thermochemical studies
Kireev, V. A. Acta Physicochim. URSS, 1937, 7, 363 Heats of mixing of liquids. 3. Integral and partial heats of mix
Cheesman, G. H.; Whitaker, A. M. Proc. R. Soc. London, Ser. A, 1952, 212, 406 The determination of heats of mix
Siddiqi, M. A.; Lucas, K. Fluid Phase Equilib., 1984, 16, 87-98 Excess enthalpy of the system chloroform + carbon
Dichloromethane - Butyric acid

Liquid
mole Temperat
No.
fraction ure (K)
DICHL-01
al and partial heats of mixing of normal liquids
ermination of heats of mixing,
stem chloroform + carbon tetrachloride and a thermo
Ethanol - Acetone Ethanol - Acetic acid
1 n-Ethanol 1 n-Ethanol
2 n-Acetone 2 Acetic acid
Liquid Vapor Liquid
mole mole Total mole
Temperat Temperat
No. fraction fraction pressure No. fraction
ure (K) ure (K)
ETHAN- ETHAN- (N/sqm) ETHAN-
01 01 01

1 0.1 329.9749 0.071 101320 1 0.085 388.1714


2 0.2 330.9746 0.135 101320 2 0.111 387.2216
3 0.3 331.9743 0.198 101320 3 0.154 385.4219
4 0.4 333.974 0.261 101320 4 0.195 383.3223
5 0.5 334.974 0.326 101320 5 0.238 382.5225
6 0.6 336.974 0.395 101320 6 0.29 379.923
7 0.65 337.974 0.434 101320 7 0.321 378.6233
8 0.7 338.974 0.476 101320 8 0.377 375.9238
9 0.75 339.974 0.522 101320 9 0.447 374.1242
10 0.8 341.974 0.583 101320 10 0.557 368.1254
11 0.85 343.9739 0.652 101320 11 0.607 367.0256
12 0.9 345.9737 0.738 101320 12 0.667 364.0262
13 0.95 348.9734 0.845 101320 13 0.725 361.6267
1 0 329.3751 0 101320 14 0.779 359.2272
2 0.125 330.2749 0.081 101320 15 0.846 356.528
3 0.264 331.7744 0.173 101320 16 0.931 353.329
4 0.42 333.774 0.274 101320 1 0 391.43
5 0.556 335.974 0.364 101320 2 0.0364 389.53
6 0.661 338.374 0.445 101320 3 0.0772 387.9
7 0.724 339.874 0.506 101320 4 0.1219 386.25
8 0.825 343.274 0.624 101320 5 0.1707 384.29
9 0.879 345.3738 0.703 101320 6 0.2245 382.43
10 0.942 348.1735 0.827 101320 7 0.2839 379.91
11 1 351.5732 1 101320 8 0.3498 376.93
1 0 329.3251 0 101320 9 0.4235 374.31
2 0.1 330.0749 0.07 101320 10 0.4388 373.68
3 0.2 331.0746 0.13 101320 11 0.4788 371.79
4 0.3 332.2243 0.197 101320 12 0.5188 369.93
5 0.4 333.474 0.265 101320 13 0.5587 368.01
6 0.5 335.074 0.33 101320 14 0.5987 366.35
7 0.6 336.924 0.405 101320 15 0.6387 364.76
8 0.7 339.174 0.49 101320 16 0.6788 363.37
9 0.8 342.174 0.59 101320 17 0.7189 361.71
10 0.9 346.2237 0.745 101320 18 0.7588 359.79
11 1 351.4232 1 101320 19 0.7989 358.36
1 0 329.3351 0 101320 20 0.8389 356.84
2 0.125 330.4348 0.083 101320 21 0.8789 355.01
3 0.25 331.5545 0.161 101320 22 0.919 353.72
4 0.375 333.654 0.238 101320 23 0.9589 352.56
5 0.5 335.304 0.312 101320 24 1 351.46
6 0.625 337.944 0.414 101320
7 0.75 340.934 0.526 101320 AmerAmezaga, S.; FernandezBiarge
8 0.875 345.3238 0.706 101320 Zhu, D.; Gao, D.; Zhang, H.; Winter,
9 0.938 347.8535 0.802 101320
10 1 351.4232 1 101320
1 0 329.26 0 101320
2 0.049 329.69 0.035 101320
3 0.099 330.17 0.071 101320
4 0.151 330.66 0.102 101320
5 0.204 331.2 0.133 101320
6 0.255 331.81 0.165 101320
7 0.312 332.43 0.197 101320
8 0.361 333.06 0.223 101320
9 0.414 333.78 0.251 101320
10 0.462 334.51 0.281 101320
11 0.519 335.37 0.315 101320
12 0.567 336.24 0.349 101320
13 0.62 337.32 0.391 101320
14 0.672 338.39 0.429 101320
15 0.724 339.81 0.483 101320
16 0.773 341.17 0.537 101320
17 0.825 342.69 0.597 101320
18 0.868 344.53 0.675 101320
19 0.915 346.65 0.768 101320
20 0.956 348.91 0.871 101320
21 1 351.44 1 101320

Chu, J. C. ; Getty, R. J.; Brennecke, L. F.; Paul, R. Distillation Equilibrium Data, 1950, Reinhold: New Yo
Hellwig, L. R.; Van Winkle, M. Ind. Eng. Chem., 1953, 45, 624 Vapour-liquid equilibria for ethyl alcoho
Morachevskii, A. G.; Leont'ev, N. P. Zh. Fiz. Khim., 1960, 34, 2347
Vinichenko, I. G.; Susarev, M. P. Zh. Prikl. Khim. (Leningrad), 1966, 39, 1583
Ku, H. -C.; Tu, C. -H. Fluid Phase Equilib., 2005, 231, 99-108 Isobaric vapor liquid equilibria for mixture
Ethanol - dipropylamine Methanol - dipropylamin
1 n-Ethanol 1 Methanol
2 Dipropylamine 2 Dipropylamine
Vapor Liquid Vapor
mole Total mole mole Total
Temperat
fraction pressure No. fraction fraction pressure No.
ure (K)
ETHAN- (N/sqm) ETHAN- ETHAN- (N/sqm)
01 01 01

0.161 101320 1 0 381.6527 0 98660 1


0.211 101320 2 0.1 373.5643 0.298 98660 2
0.28 101320 3 0.2 368.4353 0.461 98660 3
0.373 101320 4 0.3 364.826 0.573 98660 4
0.416 101320 5 0.4 362.1366 0.661 98660 5
0.503 101320 6 0.5 359.7871 0.734 98660 6
0.547 101320 7 0.6 357.8876 0.798 98660 7
0.631 101320 8 0.7 356.0082 0.855 98660 8
0.692 101320 9 0.8 354.3187 0.908 98660 9
0.816 101320 10 0.9 352.5592 0.956 98660 10
0.847 101320 11 1 350.7898 1 98660 11
0.892 101320
0.925 101320 Kato, M.; Tanaka, H. J. Chem. Eng. Data,
0.949 101320 1989, 34, 203 Vapor-Liquid Equilibrium
Determination with a Flow-Type
0.972 101320 Ebulliometer for Six Binary Systems Made
0.991 101320 of Alcohol and Amine
0 101325
0.1161 101325
0.2098 101325
0.2829 101325
0.34 101325
0.4277 101325
0.5151 101325
0.6008 101325
0.6739 101325
0.7052 101325
0.7531 101325
0.7999 101325
0.8256 101325
0.8491 101325
0.8705 101325
0.8901 101325
0.9256 101325
0.942 101325
0.9522 101325
0.9678 101325
0.9768 101325
0.9846 101325
0.9986 101325
1 101325
ezaga, S.; FernandezBiarge, J. An. Quim., 1973, 69, 569
ao, D.; Zhang, H.; Winter, B.; Lucking, P.; Sun, H.; Guan, H.; Chen, H.; Shi, J. J. Chem. Eng. Data, 2013, 58, 41-47

a, 1950, Reinhold: New York


equilibria for ethyl alcohol binary systems.

iquid equilibria for mixtures of acetone, ethanol, and 2,2,4-trimethylpentane at 101.3 kPa
Methanol - dipropylamine Methanol - butylamine
1 Methanol
Dipropylamine 2 n-Butylamine
Liquid Vapor Liquid Vapor
mole mole Total mole mole Total
Temperat Temperat
fraction fraction pressure No. fraction fraction pressure
ure (K) ure (K)
METHA- METHA- (N/sqm) METHA- METHA- (N/sqm)
01 01 01 01

0 381.6527 0 98660 1 0.28 350.6233 0.279 101300


0.1 369.885 0.373 98660 2 0.349 350.5233 0.377 101300
0.2 362.8064 0.557 98660 3 0.556 348.7234 0.635 101300
0.3 357.9476 0.674 98660 4 0.655 347.2236 0.752 101300
0.4 354.2687 0.757 98660 5 0.69 346.8236 0.796 101300
0.5 350.9797 0.821 98660 6 0.71 345.8237 0.81 101300
0.6 348.0006 0.872 98660 7 0.72 345.2238 0.828 101300
0.7 345.1315 0.913 98660 8 0.781 344.4239 0.888 101300
0.8 342.2923 0.947 98660 9 0.87 340.824 0.975 101300
0.9 339.5531 0.976 98660
1 337.0036 1 98660

Kato, M.; Tanaka, H. J. Chem. Eng. Data, Nakanishi, K.; Shirai, H.; Minamiyama, T. J.
1989, 34, 203 Vapor-Liquid Equilibrium Chem. Eng. Data, 1967, 12, 591-4 Vapor-
Determination with a Flow-Type Liquid Equilibria of Binary Systems
Ebulliometer for Six Binary Systems Made Containing Alcohols (Methanol with
of Alcohol and Amine Aliphatic Amines)
Methanol - tert-butylamine Methanol - diethylamine
1 Methanol 1 Methanol
2 tert-butylamine 2 Diethylamine
Liquid Vapor Liquid
mole mole Total mole
Temperat Temperat
No. fraction fraction pressure No. fraction
ure (K) ure (K)
METHAN METHAN (N/sqm) METHAN
OL OL OL

1 0 317.55 0 101000 1 0.169 330.5248


2 0.0438 318.9 0.0054 101000 2 0.192 331.0246
3 0.093 320.26 0.0137 101000 3 0.258 332.2243
4 0.1449 321.85 0.0275 101000 4 0.268 332.3242
5 0.1869 323.2 0.0406 101000 5 0.355 334.124
6 0.2288 325.25 0.0552 101000 6 0.453 335.824
7 0.272 327.16 0.0919 101000 7 0.492 336.724
8 0.3154 328.45 0.1156 101000 8 0.589 338.424
9 0.3403 329.86 0.1349 101000 9 0.6 338.724
10 0.3933 331.75 0.1885 101000 10 0.66 339.624
11 0.4237 332.7 0.2233 101000 11 0.674 339.924
12 0.4669 334.18 0.2817 101000 12 0.679 339.824
13 0.4908 335.2 0.3155 101000 13 0.68 340.024
14 0.5078 336 0.3444 101000 14 0.719 340.024
15 0.5556 337.2 0.4183 101000 15 0.758 340.424
16 0.5978 338.05 0.4711 101000 16 0.781 340.224
17 0.6346 338.66 0.5416 101000 17 0.782 340.124
18 0.6736 339.35 0.593 101000 18 0.799 340.224
19 0.6999 339.65 0.6413 101000 19 0.836 340.124
20 0.7217 339.97 0.6812 101000 20 0.943 338.824
21 0.7253 340.05 0.6982 101000 1 0 328.4
22 0.7735 340.25 0.7857 101000 2 0.032 329
23 0.7889 340.15 0.8122 101000 3 0.066 329.5
24 0.8071 340.06 0.8405 101000 4 0.09 329.9
25 0.8683 339.85 0.9067 101000 5 0.114 330.2
26 0.8992 339.46 0.9351 101000 6 0.159 330.9
27 0.9277 339.17 0.9585 101000 7 0.236 332.1
28 0.9627 338.75 0.982 101000 8 0.307 333.2
29 0.9898 338.45 0.9958 101000 9 0.375 334.4
30 Hao, Y.;1Zhang,
337.85 1 101000
S.; Yao, K. J. Chem. Eng. 10 0.424 335.4
Data, 2012, 57, 1244-1248 Vapor Liquid 11 0.478 336.3
Equilibrium Data for Methanol + tert- 12 0.51 337
Butylamine + N,N-Dimethylformamide
and Constituent Binary Systems at 13 0.551 337.7
Atmospheric Pressure 14 0.595 338.4
15 0.639 339.1
16 0.682 339.6
17 0.725 339.8
18 0.746 339.9
19 0.766 339.8
20 0.789 339.7
21 0.815 339.6
22 0.848 339.4
23 0.879 339.1
24 0.905 338.8
25 0.928 338.5
26 0.94 338.3
27 1 337.7
1 0.032 329
2 0.066 329.5
3 0.09 329.9
4 0.114 330.2
5 0.159 330.9
6 0.236 332.1
7 0.307 333.2
8 0.375 334.4
9 0.424 335.4
10 0.478 336.3
11 0.51 337
12 0.551 337.7
13 0.595 338.4
14 0.639 339.1
15 0.682 339.6
16 0.725 339.8
17 0.746 339.9
18 0.766 339.8
19 0.789 339.7
20 0.815 339.6
21 0.848 339.4
22 0.879 339.1
23 0.905 338.8
24 0.928 338.5
25 0.94 338.3
1 0 328.67
2 0.057 329.55
3 0.149 331.18
4 0.249 333.05
5 0.329 334.64
6 0.412 336.45
7 0.491 337.89
8 0.537 338.55
9 0.609 339.33
10 0.719 340.2
11 0.752 340.08
12 0.839 339.77
13 0.91 339.15
14 0.951 338.58
15 0.969 338.31
16 0.986 338.07
17 1 337.82
Nakanishi, K.; Shirai, H.; Minamiyam
Chem. Eng. Data, 1967, 12, 591-4 V
Liquid Equilibria of Binary Syste
Containing Alcohols (Methanol w
Aliphatic Amines)

Aucejo, A.; Loras, S.; Munoz, R.; Wi


J.; Segura, H. J. Chem. Eng. Data, 19
1201
Aucejo, A.; Wisniak, J.; Segura, H.;
S.; Munoz, R. J. Chem. Eng. Data, 1
1997, 1201-7 Phase Equilibria a
Multiple Azeotropy in the Associa
System
Zhang, P.; Methanol
Feng, Y. J. +Chem.
Diethylamin
Eng. D
2013, 58, 482-487 Isobaric Vapor L
Equilibrium for the Binary System
Methanol, Diethylamine, and N
Diethylethanolamine at p = (60.0
101.3) kPa
mine Methanol - triethylamine Ethanol - diethylamine
1 Methanol 1 n-Ethanol
2 Triethylamine 2 Diethylamine
Vapor Liquid Vapor
mole Total mole mole Total
Temperat
fraction pressure No. fraction fraction pressure No.
ure (K)
METHAN (N/sqm) METHAN METHAN (N/sqm)
OL OL OL

0.094 101300 1 0.053 356.223 0.208 101300 1


0.108 101300 2 0.126 351.1232 0.361 101300 2
0.147 101300 3 0.189 348.3235 0.435 101300 3
0.153 101300 4 0.227 347.1236 0.476 101300 4
0.222 101300 5 0.285 345.6238 0.535 101300 5
0.314 101300 6 0.371 343.8239 0.591 101300 6
0.368 101300 7 0.417 342.924 0.637 101300 7
0.501 101300 8 0.475 342.324 0.66 101300 8
0.515 101300 9 0.54 341.524 0.699 101300 9
0.599 101300 10 0.583 341.124 0.718 101300 10
0.623 101300 11 0.623 340.624 0.744 101300 11
0.623 101300 12 0.659 340.324 0.758 101300 12
0.639 101300 13 0.726 339.724 0.802 101300 13
0.7 101300 14 0.777 339.224 0.833 101300 14
0.755 101300 15 0.831 338.824 0.866 101300 15
0.791 101300 16 0.879 338.424 0.9 101300 16
0.783 101300 17 0.919 338.124 0.935 101300 17
0.812 101300 18 0.962 337.824 0.966 101300 18
0.857 101300 Nakanishi, K.; Shirai, H.; Minamiyama, T. J.
0.964 101300 Chem. Eng. Data, 1967, 12, 591-4 Vapor-
Liquid Equilibria of Binary Systems
0 101300 Containing Alcohols (Methanol with
0.016 101300 Aliphatic Amines)
0.034 101300
0.046 101300
0.058 101300
0.08 101300
0.123 101300
0.168 101300
0.215 101300
0.261 101300
0.324 101300
0.371 101300
0.426 101300
0.49 101300
0.562 101300
0.64 101300
0.706 101300
0.742 101300
0.773 101300
0.808 101300
0.843 101300
0.883 101300
0.916 101300
0.939 101300
0.957 101300
0.967 101300
1 101300
0.016 101300
0.034 101300
0.046 101300
0.058 101300
0.08 101300
0.123 101300
0.168 101300
0.215 101300
0.261 101300
0.324 101300
0.371 101300
0.426 101300
0.49 101300
0.562 101300
0.64 101300
0.706 101300
0.742 101300
0.773 101300
0.808 101300
0.843 101300
0.883 101300
0.916 101300
0.939 101300
0.957 101300
0.967 101300
0 101300
0.021 101300
0.064 101300
0.129 101300
0.196 101300
0.284 101300
0.376 101300
0.439 101300
0.542 101300
0.711 101300
0.75 101300
0.867 101300
0.95 101300
0.984 101300
0.992 101300
0.997 101300
1 101300
, K.; Shirai, H.; Minamiyama, T. J.
ng. Data, 1967, 12, 591-4 Vapor-
d Equilibria of Binary Systems
ning Alcohols (Methanol with
Aliphatic Amines)

A.; Loras, S.; Munoz, R.; Wisniak,


, H. J. Chem. Eng. Data, 1997, 42,
1201
A.; Wisniak, J.; Segura, H.; Loras,
oz, R. J. Chem. Eng. Data, 1997,
1201-7 Phase Equilibria and
e Azeotropy in the Associating
m Methanol
P.; Feng, Y. J. +Chem.
Diethylamine
Eng. Data,
8, 482-487 Isobaric Vapor Liquid
rium for the Binary Systems of
anol, Diethylamine, and N,N-
ethanolamine at p = (60.0 and
101.3) kPa
Ethanol - diethylamine Ethanol - ethylamine
1 n-Ethanol
Diethylamine 2 n-ethylamine

Liquid Vapor Liquid Vapor


Total Total
mole Temperat mole mole Temperat mole
pressure No. pressure
fraction ure (K) fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
ETHANOL ETHANOL ETHANOL ETHANOL

0.086 330.035 0.029 101000 1 0 290.146 0 101992


0.143 331.0348 0.049 101000 2 0.128 293.3453 0.002 101992
0.197 332.3345 0.073 101000 3 0.246 297.6445 0.004 101992
0.296 334.934 0.125 101000 4 0.286 300.9437 0.005 101992
0.341 335.9338 0.149 101000 5 0.345 305.3424 0.015 101992
0.381 337.1336 0.175 101000 6 0.412 310.6408 0.025 101992
0.44 338.8332 0.224 101000 7 0.46 315.2394 0.041 101992
0.495 340.6328 0.278 101000 8 0.502 320.138 0.064 101992
0.568 342.9321 0.35 101000 9 0.561 325.6363 0.1 101992
0.594 343.8318 0.397 101000 10 0.64 333.2344 0.175 101992
0.64 345.3314 0.458 101000 11 0.73 339.3331 0.303 101992
0.735 347.8306 0.608 101000 12 0.815 343.6319 0.462 101992
0.778 348.9303 0.682 101000 13 0.873 346.631 0.625 101992
0.806 349.4302 0.727 101000 14 0.949 349.6301 0.822 101992
0.833 349.93 0.778 101000 15 1 351.9294 1 101992
0.855 350.2299 0.814 101000
0.926 351.1297 0.912 101000
0.968 351.1297 0.962 101000 Rauh, W. Thesis, Technical University
Nakanishi, K.; Toba, R.; Shirai, H. J. Chem. Leuna-Merseburg, GDR (1975)
Eng. Jpn., 1969, 2, 4-7 Vapor-liquid
equilibria of binary systems containing
alcohols ethanol with nitromethane and
diethylamine
1-Propanol - propylamine 1-Propanol - dipropylamine
1 n-Propanol 1 n-Propanol
2 n-propylamine 2 Dipropylamine
Liquid Vapor Liquid
mole mole Total mole
Temperat Temperat
No. fraction fraction pressure No. fraction
ure (K) ure (K)
PROPAN PROPAN (N/sqm) PROPAN
OL OL OL

1 0 321.1377 0 101320 1 0 381.5227


2 0.106 324.3367 0.006 101320 2 0.082 379.6731
3 0.221 328.8353 0.019 101320 3 0.119 378.9232
4 0.34 334.7341 0.042 101320 4 0.208 377.6235
5 0.397 337.5335 0.058 101320 5 0.304 376.2737
6 0.421 339.0332 0.073 101320 6 0.451 374.824
7 0.466 341.8324 0.097 101320 7 0.557 373.8742
8 0.537 346.9309 0.146 101320 8 0.713 372.5245
9 0.683 356.628 0.331 101320 9 0.827 371.6247
10 0.775 361.6267 0.507 101320 10 1 370.225
11 0.826 364.5261 0.63 101320
12 1 370.225 1 101320 Krichevtsov, B. K.; Komarov, V. M
Krichevtsov, B. K.; Komarov, V. M. Zh. Prikl. Khim. (Leningrad), 1970, 43,
Prikl. Khim. (Leningrad), 1970, 43, 112-5 Liquid-Vapor Equilibria in Systems F
Liquid-Vapor Equilibria in Systems Formed by n-Propylamines, n-Propyl Alcoho
by n-Propylamines, n-Propyl Alcohol, and Water
Water
ylamine 2-Propanol - dipropylamine Methanol - n,n-dimethyl
1 2-propanol 1 Methanol
2 Dipropylamine 2 n,n-dimethylformamide
Vapor
Liquid Vapor
mole Total Total
mole Temperat mole
fraction pressure No. pressure No.
fraction ure (K) fraction
PROPAN (N/sqm) (N/sqm)
ISOPR-01 ISOPR-01
OL

0 101320 1 0 381.6527 0 98660 1


0.112 101320 2 0.1 374.0442 0.282 98660 2
0.172 101320 3 0.2 369.745 0.433 98660 3
0.286 101320 4 0.3 366.8356 0.54 98660 4
0.402 101320 5 0.4 364.4361 0.627 98660 5
0.552 101320 6 0.5 362.3765 0.703 98660 6
0.64 101320 7 0.6 360.6469 0.771 98660 7
0.781 101320 8 0.7 359.0373 0.834 98660 8
0.87 101320 9 0.8 357.5477 0.893 98660 9
1 101320 10 0.9 356.1481 0.948 98660 10
11 1 354.7286 1 98660 11
tsov, B. K.; Komarov, V. M. Zh.
m. (Leningrad), 1970, 43, 112-5 Kato, M.; Tanaka, H. J. Chem. Eng. Data,
por Equilibria in Systems Formed 1989, 34, 203 Vapor-Liquid Equilibrium
pylamines, n-Propyl Alcohol, and Determination with a Flow-Type
Water Ebulliometer for Six Binary Systems Made
of Alcohol and Amine
Methanol - n,n-dimethylformamide Ethanol - n,n-dimethylformamide
1 n-Ethanol
n,n-dimethylformamide 2 n,n-dimethylformamide
Liquid Vapor Liquid Vapor
mole mole Total mole mole Total
Temperat Temperat
fraction fraction pressure No. fraction fraction pressure
ure (K) ure (K)
METHA- METHA- (N/sqm) ETHAN- ETHAN- (N/sqm)
01 01 01 01

0 426.5354 0 101320 1 0.424 376.2 0.872 101300


0.045 413.132 0.3 101320 2 0.476 372.7 0.901 101300
0.095 403.13 0.525 101320 3 0.513 370.7 0.931 101300
0.145 393.127 0.675 101320 4 0.551 367.7 0.937 101300
0.21 383.126 0.79 101320 5 0.592 366.2 0.951 101300
0.3 373.124 0.875 101320 6 0.621 363.8 0.955 101300
0.415 363.123 0.93 101320 7 0.666 362 0.968 101300
0.575 353.123 0.968 101320 8 0.727 360.2 0.976 101300
0.7 348.1235 0.99 101320 9 0.775 358.2 0.982 101300
0.82 343.624 0.996 101320 10 0.808 357.2 0.986 101300
0.83 343.124 0.9924 101320 11 0.838 356.2 0.987 101300
Delzenne, A. Chem. Eng. Sci., 1953, 2, 220 12 0.864 355.8 0.992 101300
Liquid-vapor equilibrium: 2 a benzene + 13 0.898 355.2 0.99 101300
dimethylformamide system under one 1 0 426.3 0 101300
atmosphere absolute b methyl alcohol +
dimethylformamide system under one 2 0.0084 425.26 0.0546 101300
atmosphere absolute 3 0.0542 421.65 0.21 101300
4 0.123 416.95 0.3156 101300
5 0.1342 415.65 0.3706 101300
6 0.1946 411.95 0.4324 101300
7 0.2687 406.66 0.5804 101300
8 0.3046 403.46 0.6701 101300
9 0.3585 397.15 0.7448 101300
10 0.4058 387.65 0.8055 101300
11 0.476 378.74 0.8986 101300
12 0.561 368.65 0.9643 101300
13 0.5818 368.45 0.9661 101300
14 0.6996 364.95 0.9843 101300
15 0.7588 361.47 0.9873 101300
16 0.8675 358.46 0.9938 101300
17 0.9115 356.53 0.9956 101300
18 0.945 355.3 0.9965 101300
19 0.9756 354.83 0.9984 101300
20 0.9901 353.26 0.999 101300
Komatsu, H.; Yamamoto, H. Acc. Chem.
21 Res.,
0.9954
1996, 5,352.06 0.9995
5 Vapor-liquid 101300
equilibrium
22 data for 1 ternary
351.42 systems of 1 101300
acetone-
ethanol-N,N-dimethyl formanide(DMF),
ethyl acetate-water-DMF and acetone-
chloroform-ethyl
Hua, C.; Bai,acetate at Ma,
P.; Li, X.; atmospheric
P.
pressure 2005, 34(6),
Petrochemical Technology,
4;547 Atmospheric Vapor-Liquid
Equilibrium of Ethanol-N,N-Dimethyl
Formamide and Ethyl Acetate-N,N-
Dimethyl Formamide Systems
1-Propanol - n,n-dimethylformamide 2-Propanol - n,n-dimethylacetamide
1 n-Propanol 1 2-propanol
2 n,n-dimethylformamide 2 n,n-dimethylacetamide

Liquid Vapor Liquid


Total
mole Temperat mole mole Temperat
No. pressure No.
fraction ure (K) fraction fraction ure (K)
(N/sqm)
PROP-01 PROP-01 ISOPR-01

1 1 369.75 1 101300 1 0 440.31


2 0.969 370.71 0.997 101300 2 0.063 427.31
3 0.933 371.58 0.993 101300 3 0.115 418.87
4 0.892 372.69 0.988 101300 4 0.171 410.88
5 0.847 373.95 0.982 101300 5 0.222 404.33
6 0.802 375.4 0.975 101300 6 0.282 397.99
7 0.755 377.02 0.965 101300 7 0.336 392.84
8 0.707 378.82 0.952 101300 8 0.394 388.05
9 0.656 380.85 0.937 101300 9 0.448 383.52
10 0.603 383.06 0.919 101300 10 0.496 379.31
11 0.553 385.37 0.896 101300 11 0.551 375.44
12 0.499 388.02 0.869 101300 12 0.601 372.18
13 0.445 390.98 0.833 101300 13 0.656 369.08
14 0.391 394.27 0.79 101300 14 0.712 366.47
15 0.338 397.57 0.742 101300 15 0.745 364.32
16 0.285 401.23 0.686 101300 16 0.802 362.48
17 0.226 405.38 0.602 101300 17 0.841 360.9
18 0.172 409.78 0.5 101300 18 0.875 359.42
19 0.115 414.9 0.372 101300 19 0.911 358.05
20 Lladosa, 419.92 J. B. ;0.218
0.064E.; Monton, Burguet,101300
M. C.; 20 Zhang,
0.951 356.73
Z.; Yang, L.; Xing, Y.; Li, W. J.
21 Munoz,0R. J. Chem.
425.63Eng. Data,02007, 101300
52, 21 Eng. Data,
1 2013,
355.41
58, 357-363 Vapor
532-537 Phase Equilibria Involved in Equilibrium for Ternary and Bina
Extractive Distillation of Dipropyl Ether + Mixtures of 2-Isopropoxypropane
1-Propyl Alcohol Using N,N- Propanol, and N,N-Dimethylacetam
Dimethylformamide as Entrainer 101.3 kPa
methylacetamide Methanol - Dichloromethane Ethanol - Dichlorometha
1 Methanol 1 n-Ethanol
2 Dichloromethane 2 Dichloromethane
Liquid Vapor
Vapor
Total mole mole Total
mole Temperat
pressure No. fraction fraction pressure No.
fraction ure (K)
(N/sqm) METHA- METHA- (N/sqm)
ISOPR-01
01 01

0 101300 1 0.027 312.1404 0.103 101320 1


0.283 101300 2 0.1 311.1407 0.136 101320 2
0.443 101300 3 0.2 310.9407 0.156 101320 3
0.563 101300 4 0.3 311.3406 0.174 101320 4
0.652 101300 5 0.4 311.7405 0.196 101320 5
0.731 101300 6 0.5 312.7402 0.224 101320 6
0.783 101300 7 0.6 314.0398 0.262 101320 7
0.825 101300 8 0.7 316.4391 0.32 101320 8
0.861 101300 9 0.8 320.2379 0.41 101320 9
0.895 101300 10 0.9 326.736 0.574 101320 1
0.928 101300 11 0.95 331.7347 0.724 101320 2
0.949 101300 1 0 312.8901 0 101320 3
0.965 101300 2 0.009 312.0804 0.033 101320 4
0.976 101300 3 0.032 311.0307 0.09 101320 5
0.985 101300 4 0.256 310.7808 0.166 101320 6
0.988 101300 5 0.394 311.3206 0.185 101320 1
0.991 101300 6 0.47 312.3603 0.211 101320 2
0.994 101300 7 0.53 313.0001 0.223 101320 3
0.996 101300 8 0.573 314.1897 0.248 101320 4
Yang, L.; Xing, Y.;0.998
Li, W. J.101300
Chem. 9 0.723 318.6984 0.35 101320 5
, 2013, 58, 357-363 Vapor 1 101300
Liquid 10 0.737 320.058 0.376 101320 6
brium for Ternary and Binary 11 0.789 322.0874 0.445 101320 7
es of 2-Isopropoxypropane, 2-
, and N,N-Dimethylacetamide at 12 0.887 326.676 0.613 101320 8
101.3 kPa 13 0.916 329.2452 0.691 101320 9
14 0.929 330.175 0.715 101320 10
15 0.95 332.2845 0.785 101320 11
16 Khanina, 1E. 337.6635
P.; Pavlenko, T. G.; 1Malysheva,
101320
O. A.; Timofeev, V. S. Zh. Fiz. Khim., 1978,
52, 1558 The liquid-liquid-vapor
equilibrium in the methylene chloride +
methanol + water system: II.
Murthy, S.; Chhotray, S. K.; Sarma, H.;
Singh, R. P.; Kudchadker, A. P. Trans.
Indian Inst. Chem. Eng., 1978, Indian
Chem. Eng., 20, 45
Ethanol - Dichloromethane Methanol - Chloroform
1 Methanol
Dichloromethane 2 Chloroform
Liquid Vapor Liquid Vapor
mole mole Total mole mole Total
Temperat Temperat
fraction fraction pressure No. fraction fraction pressure
ure (K) ure (K)
ETHAN- ETHAN- (N/sqm) METHA- METHA- (N/sqm)
01 01 01 01

0 312.6902 0 101320 1 0.03 331.0246 0.125 101000


0.1806 313.28 0.0557 101320 2 0.063 329.4251 0.188 101000
0.3766 315.0595 0.0842 101320 3 0.096 328.3254 0.232 101000
0.5529 318.3785 0.1299 101320 4 0.145 327.5257 0.27 101000
0.7019 324.2067 0.216 101320 5 0.203 327.0258 0.299 101000
0.7814 330.5349 0.3342 101320 6 0.247 326.8259 0.316 101000
0.9108 342.6022 0.6547 101320 7 0.333 326.626 0.345 101000
0.9748 348.8603 0.8987 101320 8 0.364 326.626 0.354 101000
1 350.9597 1 101320 9 0.372 326.626 0.357 101000
0 312.6902 0 101320 10 0.443 326.8259 0.381 101000
0.2 313.24 0.045 101320 11 0.48 326.9259 0.393 101000
0.4 315.4394 0.087 101320 12 0.541 327.1258 0.42 101000
0.6 319.938 0.15 101320 13 0.575 327.4257 0.436 101000
0.8 332.1346 0.37 101320 14 0.617 327.8256 0.46 101000
1 350.9597 1 101320 15 0.668 328.4254 0.493 101000
0.051 312.8701 0.039 101320 16 0.713 329.0252 0.528 101000
0.112 312.7302 0.065 101320 17 0.77 330.1249 0.58 101000
0.224 313.7599 0.082 101320 18 0.804 330.9247 0.622 101000
0.337 314.7496 0.102 101320 19 0.854 332.4242 0.696 101000
0.394 315.2694 0.112 101320 20 0.905 334.024 0.785 101000
0.434 315.6693 0.12 101320 21 0.935 335.124 0.846 101000
0.488 316.759 0.13 101320 22 0.96 336.124 0.898 101000
0.617 319.7481 0.166 101320 1 0.026 330.9648 0.125 101325
0.71 323.337 0.219 101320 2 0.051 329.5251 0.185 101325
0.788 327.9856 0.303 L.101320
Aleksandrova, M. V.; Boldina, A.; 3 0.166 326.9159 0.285 101325
0.884 336.3037
Komarova, 0.488 N. V.;
V. F.; Kistereva, 101320 4 0.177 326.9059 0.293 101325
Fedorova, T. S. Sb. Nauch. Tr. Vladimir. 5 0.249 326.586 0.321 101325
Politekh. Inst., 1971, , 140 Liquid-vapor
equilibrium in binary mixtures with 6 0.282 326.516 0.337 101325
methylene chloride 7 0.309 326.4861 0.343 101325
8 0.328 326.4661 0.345 101325
Aleksandrova, M. V.; Moiseeva, L. D. Uch.
Zap., Erevan. Univ., Estestv. Nauki, 1971, 9 0.353 326.4661 0.352 101325
3, 62 10 0.359 326.4661 0.355 101325
11 0.401 326.496 0.365 101325
Dobroserdov, L. L.; Bagrov, I. V.; Il'ina, V.
P.; Lysenko, K. D. Tr. Probl. Lab. Leningrad. 12 0.46 326.596 0.379 101325
Inst. Tekst. Legk. Prom., 1971, , 337-9 13 0.491 326.706 0.395 101325
14 0.53 326.8759 0.407 101325
15 0.59 327.3058 0.437 101325
16 0.621 327.5757 0.456 101325
17 0.684 328.2855 0.502 101325
18 0.759 329.5251 0.567 101325
19 0.792 330.3449 0.609 101325
20 0.853 332.0146 0.695 101325
21 0.982 336.9036 0.954 101325
1 0.026 330.98 0.125 101300
2 0.051 329.54 0.185 101300
3 0.166 326.93 0.285 101300
4 0.177 326.92 0.293 101300
5 0.249 326.6 0.321 101300
6 0.282 326.53 0.337 101300
7 0.309 326.5 0.343 101300
8 0.328 326.48 0.345 101300
9 0.353 326.48 0.352 101300
10 0.359 326.48 0.355 101300
11 0.401 326.51 0.365 101300
12 0.46 326.61 0.379 101300
13 0.491 326.72 0.395 101300
14 0.53 326.89 0.407 101300
15 0.59 327.32 0.437 101300
16 0.621 327.59 0.456 101300
17 0.684 328.3 0.502 101300
18 0.759 329.54 0.567 101300
19 0.792 330.36 0.609 101300
20 0.853 332.03 0.695 101300
21 0.982 336.92 0.954 101300
1 0 333.96 0 100000
2 0.0195 331.45 0.0877 100000
3 0.0371 329.77 0.1592 100000
4 0.0593 328.67 0.1988 100000
5 0.0869 327.85 0.2312 100000
6 0.1143 327.27 0.2547 100000
7 0.1438 326.91 0.2732 100000
8 0.1822 326.6 0.294 100000
9 0.2179 326.41 0.3107 100000
10 0.2548 326.27 0.3231 100000
11 0.2872 326.21 0.3344 100000
12 0.3315 326.17 0.3456 100000
13 0.3653 326.17 0.3546 100000
14 0.4023 326.22 0.3646 100000
15 0.4479 326.29 0.3769 100000
16 0.4908 326.42 0.3941 100000
17 0.5358 326.64 0.4139 100000
18 0.5797 326.93 0.4352 100000
19 0.6315 327.3 0.4626 100000
20 0.6782 327.92 0.4934 100000
21 0.7298 328.73 0.5353 100000
22 0.7782 329.74 0.5873 100000
23 0.8233 330.86 0.6442 100000
24 0.8618 332 0.7009 100000
25 0.8919 332.99 0.7537 100000
26 0.9195 333.97 0.8084 100000
27 0.9416 334.8 0.8569 100000
28 0.9587 335.51 0.8922 100000
29 0.9769 336.29 0.9371 100000
30 1 337.41 1 100000
Nagata, I. J. Chem. Eng. Data, 1962, 7,
367-73 Isobaric Vapor-Liquid Equilibria for
the Ternary System Chloroform-
Methanol-Ethyl Acetate

Tochigi, K.; Hiaki, T.; Kojima, K. CODATA-


Symposium, 1984, Warsaw, May, ,
Eng. Data, 1994, 39, 714-719 Vapor-Liquid
Equilibria for Acetone + Chloroform +
Methanol and Constituent Binary Systems
at 101.3 kPa

Orchilles, A. V.; Miguel, P. J.; Vercher, E.;


Martinez-Andreu, A. J. Chem. Eng. Data,
2010, 55, 1209-1214
Ethanol - Chloroform 1-Propanol - Chloroform
1 n-Ethanol 1 n-Propanol
2 Chloroform 2 Chloroform
Liquid Vapor
Liquid
mole mole Total
Temperat mole Temperat
No. fraction fraction pressure No.
ure (K) fraction ure (K)
ETHAN- ETHAN- (N/sqm)
1-PROP
01 01

1 0 334.324 0 101000 1 0.952 365.65


2 0.02 333.624 0.05 101000 2 0.907 362.25
3 0.105 332.6741 0.128 101000 3 0.843 357.45
4 0.169 332.3242 0.166 101000 4 0.806 355.05
5 0.197 332.3742 0.177 101000 5 0.747 351.35
6 0.307 332.8741 0.23 101000 6 0.673 347.55
7 0.367 333.274 0.248 101000 7 0.597 344.35
8 0.494 334.624 0.293 101000 8 0.504 342.05
9 0.618 336.724 0.355 101000 9 0.439 340.35
10 0.705 339.024 0.431 101000 10 0.336 338.45
11 0.735 340.024 0.467 101000 11 0.247 337.35
12 0.77 341.024 0.501 101000 12 0.14 336.05
13 0.796 341.974 0.541 101000 13 0.06 335.25
14 0.844 344.0739 0.625 101000 14 0.016 334.85
15 0.925 347.7235 0.797 101000
16 1 351.4232 1 101000
Wang, S.; Cai, S. Huaxue Gongche
1 0 334.324 0 101320 1994, 22, 36-40 VLE Data for Chloro
2 0.2 332.3242 0.18 101320 n-Propanol and Its System Containi
3 0.3 332.7241 0.225 101320
4 0.4 333.424 0.26 101320
5 0.5 334.674 0.295 101320
6 0.6 336.374 0.345 101320
7 0.7 338.774 0.425 101320
8 0.8 342.024 0.545 101320
9 0.9 346.4237 0.735 101320
10 1 351.4232 1 101320
1 0.0127 333.9242 0.0236 101320
2 0.0554 333.0244 0.0847 101320
3 0.0819 332.8244 0.109 101320
4 0.1429 332.6345 0.1471 101320
5 0.3182 333.1644 0.2167 101320
6 0.4577 334.1342 0.2864 101320
7 0.6082 335.9938 0.3483 101320
8 0.6305 337.1636 0.3805 101320
9 0.6798 338.1434 0.4107 101320
10 0.7263 339.4131 0.4612 101320
11 0.773 340.083 0.5171 101320
12 0.7861 341.0927 0.564 101320
13 0.8231 342.3823 0.5915 101320
14 0.8495 344.1717 0.6341 101320
15 0.8718 345.0615 0.6684 101320
16 0.9217 347.2208 0.7736 101320
17 0.95 348.6904 0.8686 101320
18 0.9735 349.8101 0.9144 101320
1 0 334.28 0 101300
2 0.0111 334.03 0.0207 101300
3 0.0387 333.83 0.0642 101300
4 0.0474 333.06 0.0744 101300
5 0.061 332.99 0.0898 101300
6 0.0756 332.85 0.1021 101300
7 0.089 332.72 0.1127 101300
8 0.1008 332.61 0.1207 101300
9 0.1404 332.46 0.1476 101300
10 0.1503 332.43 0.1531 101300
11 0.1701 332.41 0.1641 101300
12 0.2093 332.47 0.1738 101300
13 0.2799 332.69 0.2067 101300
14 0.331 333.12 0.2226 101300
15 0.3552 333.24 0.2331 101300
16 0.3696 333.35 0.2388 101300
17 0.384 333.45 0.2447 101300
18 0.4035 333.5 0.2532 101300
19 0.4524 333.64 0.2643 101300
20 0.4608 334.15 0.2709 101300
21 0.5003 334.63 0.2889 101300
22 0.5559 335.32 0.3243 101300
23 0.5862 335.76 0.3451 101300
24 0.6066 336.38 0.355 101300
25 0.6393 337.03 0.3873 101300
26 0.6765 338.02 0.4152 101300
27 0.7146 339.04 0.4491 101300
28 0.7614 340.5 0.5023 101300
29 0.7929 341.73 0.5457 101300
30 0.8038 342.1 0.5634 101300
31 0.8235 342.87 0.59 101300
32 0.8682 344.73 0.6687 101300
33 0.882 345.39 0.6948 101300
34 0.8943 346 0.7195 101300
35 0.9162 346.7 0.7669 101300
36 0.9328 347.54 0.806 101300
37 0.942 348.05 0.829 101300
38 0.9779 349.96 0.9255 101300
39 0.9898 350.98 0.9699 101300
40 0.9948 351.22 0.9841 101300
41 1 351.3 1 101300
1 0 333.96 0 100000
2 0.015 333.44 0.029 100000
3 0.03 333.07 0.052 100000
4 0.049 332.77 0.074 100000
5 0.068 332.53 0.098 100000
6 0.089 332.37 0.115 100000
7 0.111 332.27 0.131 100000
8 0.14 332.2 0.146 100000
9 0.17 332.24 0.16 100000
10 0.199 332.24 0.172 100000
11 0.231 332.34 0.185 100000
12 0.265 332.49 0.197 100000
13 0.291 332.59 0.206 100000
14 0.326 332.78 0.218 100000
15 0.368 333.03 0.235 100000
16 0.409 333.35 0.251 100000
17 0.45 333.75 0.268 100000
18 0.495 334.29 0.289 100000
19 0.543 334.92 0.316 100000
20 0.602 335.84 0.354 100000
21 0.653 337.04 0.391 100000
22 0.716 338.66 0.447 100000
23 0.774 340.48 0.512 100000
24 0.822 342.39 0.585 100000
25 0.862 344.13 0.654 100000
26 0.898 345.7 0.732 100000
27 0.926 347.13 0.792 100000
28 0.947 348.3 0.849 100000
29 0.971 349.54 0.911 100000
30 0.984 350.29 0.951 100000
31 1 351.2 1 100000
Morachevskii, A. G.; Rabinovich, R. Sh. Zh.
Prikl. Khim. (Leningrad), 1959, 32, 458
Liq.-vap. equil. in the system chloroform-
ethyl alcohol.

Morachevskii, A. G.; Leont'ev, N. P. Zh. Fiz.


Khim., 1960, 34, 2347

Ernst, P. Thesis, Technical University


Dortmund, Dortmund, Germany (1975)
361-6 Phase equilibria at
superatmospheric pressures for systems
containing halohydrocarbon, aromatic
hydrocarbon, and alcohol

Orchilles, A. V.; Miguel, P. J.; Vercher, E.;


Martinez-Andreu, A. J. Chem. Eng. Data,
2008, 53, 2642-2648
orm 2-Propanol - Chloroform Methanol - Tetrachlorom
1 2-propanol 1 Methanol
2 Chloroform 2 Tetrachloromethane

Vapor Liquid Vapor


Total Total
mole mole Temperat mole
pressure No. pressure No.
fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
1-PROP ISOPR-01 ISOPR-01

0.796 101300 1 0.02 334.0342 0.04 101000 1


0.654 101300 2 0.079 333.9342 0.079 101000 2
0.501 101300 3 0.13 334.3341 0.11 101000 3
0.435 101300 4 0.185 334.834 0.135 101000 4
0.344 101300 5 0.21 335.134 0.15 101000 5
0.264 101300 6 0.27 335.9338 0.17 101000 6
0.208 101300 7 0.315 336.6337 0.189 101000 7
0.16 101300 8 0.39 337.7335 0.22 101000 8
0.132 101300 9 0.45 338.6333 0.245 101000 9
0.106 101300 10 0.495 339.2332 0.255 101000 10
0.088 101300 11 0.545 340.3329 0.29 101000 11
0.061 101300 12 0.61 341.6325 0.35 101000 12
0.031 101300 13 0.69 343.9318 0.429 101000 13
0.013 101300 14 0.768 345.7313 0.515 101000 14
15 0.808 347.1309 0.58 101000 15
16 Hanumantha
0.865 348.8303 0.666 101000
Rao, G.; Subbarao, B. V. 16
S.; Cai, S. Huaxue Gongcheng,
36-40 VLE Data for Chloroform - 17 ndian
0.909 351.6295
J. Technol., 1974, 12,0.783 101000
292-5 Isobaric 17
ol and Its System Containing Salt vapor-liquid equilibria: chloroform + 18
isopropanol, tertiary butanol + toluene,
and tertiary butanol + trichloroethylene 19
systems 20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
Methanol - Tetrachloromethane Ethanol - Tetrachloromethane
1 n-Ethanol
Tetrachloromethane 2 Tetrachloromethane

Liquid Vapor Liquid Vapor


Total Total
mole Temperat mole mole Temperat mole
pressure No. pressure
fraction ure (K) fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
METH-01 METH-01 ETH-01 ETH-01

1 337.824 1 101000 1 1 351.5232 1 101320


0.999 337.724 0.995 101000 2 0.995 351.1832 0.985 101320
0.997 337.624 0.988 101000 3 0.992 350.8832 0.972 101320
0.993 337.224 0.9665 101000 4 0.966 349.1534 0.88 101320
0.986 336.624 0.939 101000 5 0.956 348.4535 0.832 101320
0.979 335.924 0.91 101000 6 0.941 347.7535 0.8 101320
0.962 334.924 0.864 101000 7 0.927 346.9436 0.765 101320
0.948 333.974 0.823 101000 8 0.904 345.7237 0.715 101320
0.938 333.524 0.803 101000 9 0.895 345.0438 0.7 101320
0.9175 332.6242 0.753 101000 10 0.895 345.1238 0.705 101320
0.897 331.7244 0.716 101000 11 0.878 344.5239 0.665 101320
0.883 331.3245 0.6955 101000 12 0.792 341.374 0.555 101320
0.868 330.8247 0.677 101000 13 0.782 341.174 0.543 101320
0.838 330.2249 0.649 101000 14 0.715 339.754 0.486 101320
0.813 329.875 0.63 101000 15 0.685 339.454 0.47 101320
0.764 329.4751 0.605 101000 16 0.678 339.334 0.469 101320
0.727 329.1252 0.595 101000 17 0.666 339.154 0.462 101320
0.725 329.1252 0.591 101000 18 0.615 338.754 0.439 101320
0.676 328.8753 0.576 101000 19 0.569 338.504 0.424 101320
0.625 328.8753 0.563 101000 20 0.508 338.414 0.407 101320
0.603 328.8253 0.561 101000 21 0.385 338.164 0.387 101320
0.5965 328.8253 0.558 101000 22 0.365 338.414 0.385 101320
0.5655 328.8253 0.552 101000 23 0.323 338.514 0.377 101320
0.55 328.7753 0.552 101000 24 0.21 338.724 0.337 101320
0.505 328.8253 0.5485 101000 25 0.21 338.734 0.338 101320
0.498 328.8753 0.545 101000 26 0.197 338.754 0.335 101320
0.4525 328.8753 0.541 101000 27 0.115 339.624 0.295 101320
0.401 328.9253 0.5365 101000 28 0.094 340.004 0.28 101320
0.248 329.3751 0.522 101000 29 0.055 341.414 0.247 101320
0.124 330.0749 0.5 101000 30 0.048 341.724 0.235 101320
0.107 330.3248 0.49 101000 31 0.039 342.234 0.23 101320
0.0505 332.5242 0.445 101000 32 0.019 345.1838 0.14 101320
0.03 335.124 0.383 101000 33 0.014 346.3137 0.124 101320
0.017 339.974 0.264 101000 34 0.012 347.2236 0.075 101320
0.013 340.724 0.2415 101000 35 0.01 347.8235 0.063 101320
0.004 345.4738 0.12 101000 36 0.007 348.3235 0.05 101320
0.002 349.2234 0.02 101000 37 0.007 348.7434 0.039 101320
0.002 348.9734 0.027 101000 38 0 349.8833 0 101320
0 349.8233 0 101000 1 0.996 350.6798 0.987 100260
0.992 336.884 0.9638 101000 2 0.987 349.3802 0.926 100260
0.9885 336.564 0.9482 101000 3 0.95 347.2308 0.832 100260
0.9865 336.404 0.9435 101000 4 0.919 345.3814 0.754 100260
0.986 336.394 0.9399 101000 5 0.885 343.7819 0.678 100260
0.9855 336.354 0.9384 101000 6 0.883 344.1318 0.68 100260
0.981 335.984 0.9222 101000 7 0.865 342.7322 0.635 100260
0.973 335.344 0.8908 101000 8 0.836 341.1327 0.587 100260
0.9675 334.964 0.871 101000 9 0.778 340.133 0.512 100260
0.9675 334.984 0.8734 101000 10 0.766 339.833 0.518 100260
0.963 334.664 0.857 101000 11 0.669 338.6333 0.483 100260
0.9595 334.374 0.8425 101000 12 0.658 338.2334 0.459 100260
0.9585 334.284 0.8414 101000 13 0.615 338.0834 0.434 100260
0.9565 334.124 0.835 101000 14 0.557 337.7834 0.414 100260
0.939 333.244 0.7945 101000 15 0.545 337.9334 0.419 100260
0.932 332.7641 0.778 101000 16 0.318 337.7834 0.382 100260
0.931 332.8441 0.777 101000 17 0.193 338.0334 0.344 100260
0.9285 332.5642 0.7695 101000 18 0.104 339.0332 0.302 100260
0.8775 330.9846 0.6988 101000 19 0.074 340.1829 0.286 100260
0.8665 330.6547 0.6862 101000 20 0.055 341.1327 0.23 100260
0.8522 330.3848 0.6714 101000 21 0.028 342.5822 0.196 100260
0.8405 330.1849 0.6605 101000 22 0.021 344.2317 0.142 100260
0.8275 329.945 0.6509 101000 23 0.014 346.0812 0.083 100260
0.8025 329.5451 0.6278 101000 24 0.01 347.4808 0.045 100260
0.7414 328.9253 0.5945 101000 25 0.003 348.6304 0.01 100260
0.7358 328.8853 0.5935 101000 26 0 348.9803 0 100260
0.73 328.8553 0.5875 101000 Hirata, M.; Hirose, Y.; Yanagawa, Y.
Kagaku Kogaku, 1960, 24, 561 Vapor-
0.7248 328.8353 0.5865 101000 liquid equilibria of the systems carbon
0.6833 328.7453 0.5774 101000 tetrachloride + n-alcohols
0.6608 328.7453 0.5726 101000 Chim. Ind. Genie Chim., 1969, 102, 21324
Vapor-liquid equilibrium: VI Systems ethyl
0.6417 328.6453 0.5685 101000 alcohol + carbon tetrachloride and ethyl
0.6095 328.6054 0.5628 101000 alcohol + trichloroethylene
0.525 328.6453 0.5486 101000
0.4892 328.6753 0.5445 101000
0.389 328.8053 0.5354 101000
0.3166 328.8853 0.529 101000
0.304 328.9253 0.5273 101000
0.2462 329.0852 0.5171 101000
0.2435 329.1452 0.519 101000
0.2376 329.2052 0.5164 101000
0.2261 329.2852 0.5164 101000
0.2138 329.3351 0.5148 101000
0.1332 329.875 0.5025 101000
0.1101 330.0949 0.4981 101000
0.077 331.3345 0.4673 101000
0.0736 331.4945 0.4624 101000
0.073 333.274 0.4195 101000
0.0641 332.5142 0.4452 101000
0.0565 334.264 0.4035 101000
0.0378 335.314 0.38 101000
0.0358 339.474 0.2791 101000
0.0358 337.874 0.3174 101000
0.0252 341.954 0.2788 101000
0.0108 343.144 0.1861 101000
0.0108 342.474 0.206 101000
0.0081 343.044 0.192 101000
0.006 344.3539 0.1344 101000
1954, 46, 2524 Vapor-Recirculating
Equilibrium Still. Data on Heptane-
Toluene and Methanol-Carbon
Tetrachloride
Quim., B, 1958, 54, 413-20 Vapour liquid
equilibrium: III a study of a new equilibri
still the system methanol + carbon
tetrachloride
1-Propanol - Tetrachloromethane 2-Propanol - Tetrachloromethane
1 n-Propanol 1 2-propanol
2 Tetrachloromethane 2 Tetrachloromethane

Liquid Vapor Liquid


Total
mole Temperat mole mole Temperat
No. pressure No.
fraction ure (K) fraction fraction ure (K)
(N/sqm)
1-PROP 1-PROP 2-PROP

1 1 370.3137 1 101000 1 1 355.133


2 0.942 363.9231 0.747 101000 2 0.942 352.2731
3 0.859 357.623 0.55 101000 3 0.896 348.8334
4 0.7 351.4232 0.367 101000 4 0.868 347.6036
5 0.559 348.9234 0.293 101000 5 0.862 348.0235
6 0.478 347.8235 0.261 101000 6 0.86 347.3936
7 0.317 347.0236 0.218 101000 7 0.842 346.8336
8 0.182 346.5237 0.182 101000 8 0.81 345.6637
9 0.149 346.7236 0.169 101000 9 0.775 344.9038
10 0.05 347.3236 0.105 101000 10 0.764 344.7438
11 0 349.8733 0 101000 11 0.72 343.9939
1 1 370.2849 1 101000 12 0.711 343.7539
2 0.9912 368.5253 0.9411 101000 13 0.706 343.6339
3 0.9833 367.8154 0.9084 101000 14 0.683 343.244
4 0.9777 366.8856 0.8726 101000 15 0.657 342.664
5 0.964 365.8258 0.8188 101000 16 0.623 342.824
6 0.9533 364.876 0.7852 101000 17 0.578 342.274
7 0.9354 363.3463 0.731 101000 18 0.538 342.554
8 0.9171 361.7067 0.6707 101000 19 0.506 341.584
9 0.865 357.9576 0.5797 101000 20 0.488 341.984
10 0.8316 356.3281 0.5083 101000 21 0.413 341.434
11 0.7999 354.9885 0.4757 101000 22 0.339 341.684
12 0.7844 354.0688 0.4373 101000 23 0.319 341.884
13 0.7574 353.159 0.4118 101000 24 0.307 341.874
14 0.752 352.5292 0.4116 101000 25 0.259 342.034
15 0.7425 352.1294 0.3967 101000 26 0.258 342.024
16 0.706 351.1397 0.3759 101000 27 0.242 342.004
17 0.6972 349.7401 0.3433 101000 28 0.211 342.124
18 0.6959 350.9097 0.3688 101000 29 0.211 342.204
19 0.6829 350.3299 0.3523 101000 30 0.176 342.404
20 0.6614 349.3302 0.3366 101000 31 0.153 342.404
21 0.6418 348.8104 0.3206 101000 32 0.146 342.714
22 0.6345 348.5304 0.3096 101000 34 0.054 344.5239
23 0.613 348.3305 0.3057 101000 36 0.011 347.9135
24 0.5678 347.7307 0.2893 101000 37 0 349.7333
25 0.5164 347.3808 0.2743 101000 1 1 355.513
26 0.473 347.0309 0.2619 101000 2 0.966 353.023
27 0.4405 346.9309 0.2603 101000 3 0.938 351.6232
28 0.4246 346.801 0.2573 101000 4 0.908 349.9233
29 0.3936 346.771 0.2461 101000 5 0.827 347.1236
30 0.3622 346.611 0.2427 101000 6 0.776 345.9237
31 0.3575 346.591 0.2427 101000 7 0.658 343.7239
32 0.3443 346.551 0.2364 101000 8 0.588 342.824
33 0.3198 346.4811 0.2296 101000 9 0.514 342.224
34 0.2804 346.4311 0.2296 101000 10 0.422 342.124
35 0.2774 346.4311 0.2231 101000 11 0.353 341.924
36 0.2742 346.3711 0.2213 101000 12 0.27 342.024
37 0.2525 346.3411 0.2213 101000 13 0.196 342.224
38 0.2445 346.3711 0.2075 101000 14 0.12 343.324
39 0.2428 346.2611 0.2109 101000 15 0.057 345.3238
40 0.2232 346.2311 0.2024 101000 16 0.03 347.2236
41 0.2024 346.2611 0.199 101000 17 0 349.8233
42 0.1938 346.2611 0.1956 101000 1 1 355.5083
43 0.1904 346.2611 0.1956 101000 2 0.9938 354.8585
44 0.1758 346.2711 0.1886 101000 3 0.986 354.3487
45 0.1617 346.2911 0.1818 101000 4 0.9781 353.8588
46 0.1582 346.2911 0.1836 101000 5 0.957 352.7692
47 0.143 346.3311 0.1758 101000 6 0.9355 351.5395
48 0.1213 346.4811 0.1635 101000 7 0.9178 350.3399
49 0.0847 346.8409 0.1405 101000 8 0.8877 349.0003
50 0.0704 346.9509 0.1371 101000 9 0.8712 348.1905
51 0.0633 347.1409 0.1336 101000 10 0.8503 347.1508
52 0.0528 347.3608 0.1194 101000 11 0.8325 346.551
53 0.0424 347.7107 0.1072 101000 12 0.8053 345.8912
54 0.035 347.9206 0.088 101000 13 0.781 345.2714
55 0.0264 348.2405 0.0739 101000 14 0.764 344.8315
56 0.0227 348.4805 0.0688 101000 15 0.7379 344.2617
57 0.021 348.7404 0.0546 101000 16 0.6974 343.6619
58 0.0194 348.6304 0.0635 101000 17 0.6672 343.392
59 0.0175 349.0403 0.0425 101000 18 0.6327 342.9921
60 0.0158 349.1003 0.035 101000 19 0.5942 342.5622
61 0.0052 349.4802 0.0194 101000 20 0.5567 342.3823
62 0 349.88 0 101000 21 0.529 342.1623
1 0.937 361.8266 0.731 100000 22 0.5004 342.1324
2 0.904 359.1273 0.644 100000 23 0.4727 342.0024
3 0.903 358.9273 0.642 100000 24 0.449 341.8924
4 0.86 356.1282 0.575 100000 25 0.423 341.8624
5 0.66 348.3305 0.331 100000 26 0.3974 341.8324
6 0.525 346.531 0.277 100000 27 0.3754 341.8125
7 0.44 345.8312 0.25 100000 28 0.3524 341.8125
8 0.321 345.1315 0.228 100000 29 0.3314 341.8324
9 0.22 345.1315 0.199 100000 30 0.314 341.8324
10 0.175 345.2314 0.175 100000 31 0.3016 341.8524
11 0.129 345.7313 0.159 100000 32 0.3002 341.8524
12 0.072 346.8309 0.123 100000 33 0.2805 341.9724
1 0.952 365.95 0.823 101320 34 0.2568 342.0324
2 0.905 363.25 0.715 101320 35 0.2298 342.1024
3 0.802 359.65 0.548 101320 36 0.2036 342.2023
4 0.648 356.45 0.402 101320 37 0.1759 342.3623
5 0.601 355.25 0.371 101320 38 0.1526 342.5622
6 0.521 353.55 0.322 101320 39 0.1263 342.9021
7 0.428 352.65 0.271 101320 40 0.0931 343.352
8 0.337 352.05 0.228 101320 41 0.0698 344.7216
9 0.258 351.55 0.201 101320 42 0.0627 345.2414
10 0.131 351.05 0.102 101320 43 0.0529 345.9012
11 0.102 350.05 0.098 101320 44 0.0364 346.4611
1 0.935 363.95 0.729 101300 45 0.0292 347.1209
2 0.865 358.35 0.558 101300 46 0.0209 347.3508
3 0.771 353.95 0.419 101300 47 0.0168 347.8606
4 0.68 350.75 0.336 101300 48 0.007 348.6904
5 0.583 348.55 0.286 101300 49 0.0033 348.5804
6 0.498 347.45 0.256 101300 1 0.8776 350.25
7 0.41 346.95 0.236 101300 2 0.7419 345.88
8 0.302 346.75 0.217 101300 3 0.698 344.87
9 0.218 346.45 0.192 101300 4 0.6425 343.18
10 0.128 346.35 0.154 101300 5 0.5499 342.74
11 0.046 346.95 0.1 101300 6 0.4848 342.29
12 0.01 348.85 0.036 101300 7 0.447 342.12
Carley, J. F.; Bertelsen, L. W. Ind. Eng. 8 0.3146 342.02
Chem., 1949, 41, 2806 Vapor-Liquid
Equilibrium Data for System Carbon 9 0.2489 342.19
Tetrachloride - n-Propyl Alcohol 10 0.2012 342.67
Ocon, J.; Tojo, G.; Bao, M.; Arce, A. An. 11 0.1615 343.85
Quim., 1973, 69, 539 Liquid-vapor
equilibrium. XI. normal binary carbon 12 0.1149 344.66
tetrachloride-propanol system. 13 0.0949 344.99
Khim. (Leningrad), 1974, 47, 2492-5 14 0.0798 345.46
Determination of phase equilibria in an
apparatus with reversed flow and phase
circulation
(Bucharest), 1993, 44, 1042-5 Liquid-vapor Yuan, K. S.; Lu, B. C.-Y. J. Chem. Eng
equilibrium in a binary system formed 1963, 8, 549 Vapor-Liquid Equilibria
from carbon tetrachloride and n-propanol System Carbon-Tetrachloride-Cyclo
or isobutanol Propanol-1 at Atmospheric Press
Xuebao, Ziran Kexueban, 1998, 34, 63-68
Vapor-Liquid Equilibrium Data for Carbon
Tetrachloride-1-Propanol Systems Nagata, I. J. Chem. Eng. Data, 1965
Containing Dissolved Salt 106 Vapor-Liquid Equilibrium Da
Quim., 1973, 69, 673 Liquid-vap
equilibrium. XII. binary systems no
isopropanol-proponal and carb
tetrachloride-isopropanol.
Baniceru, M. Fluid Phase Equilib., 1
136, 307-14 Excess properties of b
systems formed by carbon tetrach
with isopropanol and n-butano
hloromethane Methanol - Acetic acid Methanol - Propionic aci
1 Methanol 1 Methanol
2 Acetic acid 2 Propionic acid

Vapor Liquid Vapor


Total Total
mole mole Temperat mole
pressure No. pressure No.
fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
2-PROP METh METH

1 101320 1 0.963 338.8332 0.996 101320 1


0.862 101320 2 0.9 340.9327 0.991 101320 2
0.717 101320 3 0.867 342.2323 0.986 101320 3
0.604 101320 4 0.828 344.2317 0.978 101320 4
0.69 101320 5 0.774 346.731 0.964 101320 5
0.604 101320 6 0.73 348.7304 0.952 101320 6
0.655 101320 7 0.685 351.1297 0.937 101320 7
0.601 101320 8 0.615 355.0285 0.897 101320 8
0.567 101320 9 0.593 356.628 0.881 101320 9
0.562 101320 10 0.532 359.7271 0.841 101320 10
0.537 101320 11 0.493 361.8266 0.811 101320 11
0.527 101320 12 0.408 367.0256 0.727 101320 12
0.517 101320 13 0.379 368.0254 0.705 101320 13
0.503 101320 14 0.345 370.025 0.664 101320 14
0.5 101320 15 0.294 372.6245 0.605 101320 15
0.469 101320 16 0.202 378.0234 0.466 101320 16
0.416 101320 17 0.161 380.3229 0.41 101320 17
0.442 101320 18 0.09 385.222 0.241 101320 18
0.412 101320 19 0.058 387.8214 0.164 101320 19
0.411 101320 1 0.878 340.5328 0.996 101000 20
0.381 101320 2 0.841 341.7325 0.98 101000 21
0.359 101320 3 0.824 342.5322 0.978 101000 22
0.351 101320 4 0.81 343.232 0.97 101000 23
0.371 101320 5 0.797 343.432 0.955 101000
0.33 101320 6 0.749 345.2314 0.959 101000
0.332 101320 7 0.718 346.631 0.945 101000
0.325 101320 8 0.687 347.6307 0.943 101000
0.292 101320 9 0.6 351.4296 0.905 101000
0.305 101320 10 0.514 355.8282 0.844 101000
0.289 101320 11 0.468 358.1276 0.797 101000
0.258 101320 12 0.357 365.026 0.684 101000
0.265 101320 13 0.305 366.8256 0.643 101000
0.158 101320 14 0.282 368.9252 0.591 101000
0.06 101320 15 0.178 375.224 0.441 101000
0 101320 16 0.143 378.2234 0.377 101000
1 101320 17 0.112 380.6229 0.323 101000
0.886 101320 18 0.098 381.3227 0.279 101000
0.815 101320 19 0.088 381.6227 0.275 101000
0.748 101320 20 0.071 383.4223 0.222 101000
0.624 101320
AmerAmezaga, S.; FernandezBiarge, J. An.
Quim., 1973, 69, 569
0.558 101320 AmerAmezaga, S.; FernandezBiarge, J. An.
0.466 101320 Quim.,
Sawistowski, H.; 1973, 69, 569
Pilavakis, P. A. J. Chem.
0.425 101320 Eng. Data, 1982, 27, 64-71 Vapor-liquid
equilibrium with association in both
0.396 101320 phases. multicomponent systems
0.36 101320 containing acetic acid.
0.335 101320
0.308 101320
0.281 101320
0.24 101320
0.179 101320
0.107 101320
0 101320
1 101000
0.9724 101000
0.9512 101000
0.929 101000
0.8774 101000
0.8242 101000
0.7674 101000
0.708 101000
0.6754 101000
0.6304 101000
0.5992 101000
0.5779 101000
0.543 101000
0.5254 101000
0.5017 101000
0.4754 101000
0.4604 101000
0.4428 101000
0.4207 101000
0.4102 101000
0.3972 101000
0.388 101000
0.3793 101000
0.374 101000
0.3688 101000
0.3535 101000
0.343 101000
0.3392 101000
0.3314 101000
0.327 101000
0.3274 101000
0.3224 101000
0.317 101000
0.305 101000
0.3028 101000
0.2896 101000
0.2793 101000
0.2688 101000
0.2489 101000
0.2299 101000
0.1815 101000
0.165 101000
0.1387 101000
0.1276 101000
0.0972 101000
0.0738 101000
0.0655 101000
0.0444 101000
0.05 101000
0.7527 101325
0.5795 101325
0.5248 101325
0.4729 101325
0.4219 101325
0.3809 101325
0.3749 101325
0.3249 101325
0.3058 101325
0.2688 101325
0.2378 101325
0.1755 101325
0.1553 101325
0.1448 101325

S.; Lu, B. C.-Y. J. Chem. Eng. Data,


49 Vapor-Liquid Equilibria Part I.
arbon-Tetrachloride-Cyclohxane
nol-1 at Atmospheric Pressure

I. J. Chem. Eng. Data, 1965, 10,


apor-Liquid Equilibrium Data
., 1973, 69, 673 Liquid-vapor
um. XII. binary systems normal
opanol-proponal and carbon
etrachloride-isopropanol.
u, M. Fluid Phase Equilib., 1997,
7-14 Excess properties of binary
formed by carbon tetrachioride
isopropanol and n-butanol.
Methanol - Propionic acid Ethanol - Acetic acid
1 n-Ethanol
Propionic acid 2 Acetic acid
Liquid Vapor Liquid Vapor
mole mole Total mole mole Total
Temperat Temperat
fraction fraction pressure No. fraction fraction pressure
ure (K) ure (K)
METHA- METHA- (N/sqm) ETHAN- ETHAN- (N/sqm)
01 01 01 01

0 414.2162 0 101320 1 0.085 388.1714 0.161 101320


0.012 411.1168 0.087 101320 2 0.111 387.2216 0.211 101320
0.012 411.2168 0.092 101320 3 0.154 385.4219 0.28 101320
0.03 408.4173 0.174 101320 4 0.195 383.3223 0.373 101320
0.056 403.6183 0.286 101320 5 0.238 382.5225 0.416 101320
0.069 399.1192 0.394 101320 6 0.29 379.923 0.503 101320
0.094 396.0198 0.461 101320 7 0.321 378.6233 0.547 101320
0.145 392.3205 0.537 101320 8 0.377 375.9238 0.631 101320
0.174 387.7215 0.619 101320 9 0.447 374.1242 0.692 101320
0.216 383.6223 0.681 101320 10 0.557 368.1254 0.816 101320
0.28 377.6235 0.756 101320 11 0.607 367.0256 0.847 101320
0.33 373.4243 0.801 101320 12 0.667 364.0262 0.892 101320
0.419 367.6255 0.86 101320 13 0.725 361.6267 0.925 101320
0.495 363.0264 0.897 101320 14 0.779 359.2272 0.949 101320
0.556 359.6271 0.92 101320 15 0.846 356.528 0.972 101320
0.616 355.8282 0.944 101320 16 0.931 353.329 0.991 101320
0.683 352.5292 0.96 101320 1 0 390.95 0 101300
0.741 349.3302 0.973 101320 2 0.025 388 0.16 101300
0.799 345.8312 0.983 101320 3 0.051 385.93 0.18 101300
0.876 342.2323 0.991 101320 4 0.08 383.95 0.282 101300
0.93 340.033 0.995 101320 5 0.12 380.01 0.381 101300
0.97 338.7333
AmerAmezaga, 0.9981975,
S. An. Quim., 101320
71, 6 0.201 374.99 0.52 101300
1 337.8334
117 Liquid-vapor equilibrium of1 the101320
binary 7 0.458 367.2 0.675 101300
systems formed by propionic acid and 8 0.516 366.43 0.72 101300
methyl, ethyl, propyl, isopropyl, n-butyl,
isobutyl, sec-butyl, and t- butyl alcohol 9 0.55 365.54 0.745 101300
760 mm 10 0.592 364.51 0.8 101300
11 0.625 363.86 0.83 101300
12 0.667 363.05 0.858 101300
13 0.733 361.75 0.868 101300
14 0.833 360.64 0.883 101300
15 0.883 358.44 0.954 101300
16 0.925 355.86 0.95 101300
17 1 351.65 1 101300
1 0 391.43 0 101325
2 0.0364 389.53 0.1161 101325
3 0.0772 387.9 0.2098 101325
4 0.1219 386.25 0.2829 101325
5 0.1707 384.29 0.34 101325
6 0.2245 382.43 0.4277 101325
7 0.2839 379.91 0.5151 101325
8 0.3498 376.93 0.6008 101325
9 0.4235 374.31 0.6739 101325
10 0.4388 373.68 0.7052 101325
11 0.4788 371.79 0.7531 101325
12 0.5188 369.93 0.7999 101325
13 0.5587 368.01 0.8256 101325
14 0.5987 366.35 0.8491 101325
15 0.6387 364.76 0.8705 101325
16 0.6788 363.37 0.8901 101325
17 0.7189 361.71 0.9256 101325
18 0.7588 359.79 0.942 101325
19 0.7989 358.36 0.9522 101325
20 0.8389 356.84 0.9678 101325
21 0.8789 355.01 0.9768 101325
22 0.919 353.72 0.9846 101325
23 0.9589 352.56 0.9986 101325
24 1 351.46 1 101325

AmerAmezaga, S.; FernandezBiarge, J. An.


Quim., 1973, 69, 569
Spectroscopy Laboratory, 2012, 29(1),
529-531 Determination and Relevance of
Vapour Liquid Equilibrium Data of Acetic
Acid-Ethanol System

Zhu, D.; Gao, D.; Zhang, H.; Winter, B.;


Lucking, P.; Sun, H.; Guan, H.; Chen, H.;
Shi, J. J. Chem. Eng. Data, 2013, 58, 41-47
Ethanol - Propionic acid 1-Propanol - Acetic acid
1 n-Ethanol 1 n-Propanol
2 Propionic acid 2 Acetic acid
Liquid Vapor
Liquid
mole mole Total
Temperat mole Temperat
No. fraction fraction pressure No.
ure (K) fraction ure (K)
ETHAN- ETHAN- (N/sqm)
PROP
01 01

1 0 414.2162 0 101320 1 1 370.3249


2 0.04 411.0168 0.166 101320 2 0.973 371.2248
3 0.051 408.4173 0.194 101320 3 0.892 373.6243
4 0.094 403.5183 0.306 101320 4 0.833 375.8238
5 0.129 400.019 0.408 101320 5 0.783 377.0236
6 0.165 397.4195 0.482 101320 6 0.752 378.3233
7 0.206 393.9202 0.546 101320 7 0.74 378.8232
8 0.269 389.7211 0.636 101320 8 0.713 379.823
9 0.294 387.9214 0.671 101320 9 0.711 379.6231
10 0.377 383.4223 0.751 101320 10 0.684 380.7229
11 0.406 380.7229 0.785 101320 11 0.645 381.6227
12 0.428 378.4233 0.809 101320 12 0.58 383.1224
13 0.459 377.3235 0.819 101320 13 0.525 384.7221
14 0.495 374.3241 0.852 101320 14 0.443 386.1218
15 0.549 371.3247 0.885 101320 15 0.368 387.2216
16 0.602 368.3253 0.909 101320 16 0.312 387.5215
17 0.648 365.8258 0.93 101320 17 0.248 388.5213
18 0.719 362.3265 0.953 101320 18 0.16 389.3211
19 0.767 359.927 0.967 101320 19 0.159 389.4211
20 0.839 356.728 0.982 101320 20 0.114 390.021
21 0.887 354.8285 0.988 101320 21 0 390.8708
22 AmerAmezaga,
0.914 353.6289 0.9921975,
S. An. Quim., 101320
71, 1 0.916 372.6245
23 117 Liquid-vapor
1 351.4296
equilibrium of1 the101320
binary 2 0.883 373.7243
systems formed by propionic acid and 3 0.847 374.5241
methyl, ethyl, propyl, isopropyl, n-butyl,
isobutyl, sec-butyl, and t- butyl alcohol 4 0.795 376.3237
760 mm 5 0.726 378.5233
6 0.66 380.8228
7 0.586 382.7225
8 0.575 383.1224
9 0.528 384.0222
10 0.471 385.222
11 0.405 386.6217
12 0.283 388.6213
13 0.192 389.5211
14 0.184 389.6211

AmerAmezaga, S.; FernandezBiarge


Quim., 1973, 69, 587

AmerAmezaga, S.; FernandezBiarge


Quim., 1973, 69, 569
acid 1-Propanol - Propionic acid 2-Propanol - Acetic acid
1 n-Propanol 1 2-propanol
2 Propionic acid 2 Acetic acid
Liquid Vapor
Vapor
Total mole mole Total
mole Temperat
pressure No. fraction fraction pressure No.
fraction ure (K)
(N/sqm) PROPAN PROPAN (N/sqm)
PROP
OL OL

1 101320 1 0 414.2162 0 101320 1


0.993 101320 2 0.019 413.1164 0.036 101320 2
0.965 101320 3 0.068 410.6169 0.15 101320 3
0.935 101320 4 0.094 408.9172 0.213 101320 4
0.901 101320 5 0.132 407.3175 0.28 101320 5
0.878 101320 6 0.189 404.6181 0.372 101320 6
0.867 101320 7 0.26 402.2186 0.466 101320 7
0.842 101320 8 0.31 400.019 0.546 101320 8
0.839 101320 9 0.324 398.7193 0.57 101320 9
0.817 101320 10 0.388 396.0198 0.643 101320 10
0.778 101320 11 0.433 393.4203 0.701 101320 11
0.704 101320 12 0.487 390.5209 0.762 101320 12
0.646 101320 13 0.548 387.8214 0.811 101320 13
0.548 101320 14 0.62 384.822 0.857 101320 14
0.457 101320 15 0.671 382.2226 0.894 101320 15
0.393 101320 16 0.731 379.6231 0.923 101320 16
0.308 101320 17 0.778 377.5235 0.943 101320 17
0.197 101320 18 0.827 375.6239 0.961 101320 18
0.203 101320 19 0.862 374.4241 0.972 101320 19
0.134 101320 20 0.918 372.6245 0.986 101320
0 101320 21 1 370.3249 1 101320
0.978 101320 1 0 414.53 0 101300
0.965 101320 2 0.0025 413.55 0.0031 101300
0.949 101320 3 0.0171 412.25 0.0432 101300
0.918 101320 4 0.0385 411.25 0.0919 101300
0.866 101320 5 0.0635 409.55 0.1432 101300
0.8 101320 6 0.0854 408.15 0.1824 101300
0.725 101320 7 0.1055 406.55 0.216 101300
0.714 101320 8 0.1474 404.15 0.3066 101300
0.664 101320 9 0.2114 399.45 0.4456 101300
0.581 101320 10 0.2559 396.71 0.531 101300
0.497 101320 11 0.2757 395.55 0.56 101300
0.346 101320 12 0.3229 393.25 0.6359 101300
0.221 101320 13 0.3699 390.35 0.7106 101300
0.228 101320 14 0.4547 386.35 0.7857 101300
15 0.5375 383.05 0.8534 101300
ezaga, S.; FernandezBiarge, J. An. 16 0.6093 380.45 0.894 101300
Quim., 1973, 69, 587 17 0.6452 379.39 0.9139 101300
18 0.6796 378.3 0.9306 101300
ezaga, S.; FernandezBiarge, J. An. 19 0.725 377 0.9486 101300
Quim., 1973, 69, 569
20 0.7714 375.83 0.9647 101300
21 0.8477 374.21 0.98 101300
22 0.8872 373.07 0.9879 101300
23 0.9232 372.23 0.9926 101300
24 0.9643 371.27 0.9965 101300
25 1 370.29 1 101300
systems formed by propionic acid and
methyl, ethyl, propyl, isopropyl, n-butyl,
isobutyl, sec-butyl, and t- butyl alcohol
760 mm

Altman, E.; Stefanidis, G. D.; Gerven, T. v.;


Stankiewicz, A. I. J. Chem. Eng. Data, 2011,
56, 2322-2328
2-Propanol - Acetic acid 2-Propanol - Propionic acid
2-propanol 1 2-propanol
Acetic acid 2 Propionic acid

Liquid Vapor Liquid Vapor


Total Total
mole Temperat mole mole Temperat mole
pressure No. pressure
fraction ure (K) fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
2PROP 2PROP ISOPR-01 ISOPR-01

1 355.5283 1 101320 1 0 414.2162 0 101320


0.954 357.1279 0.993 101320 2 0.017 412.4165 0.046 101320
0.905 358.5274 0.979 101320 3 0.066 408.3173 0.188 101320
0.876 359.827 0.973 101320 4 0.104 404.918 0.305 101320
0.789 363.2264 0.939 101320 5 0.166 400.5189 0.436 101320
0.723 365.9258 0.902 101320 6 0.21 396.8196 0.522 101320
0.693 367.6255 0.882 101320 7 0.27 392.7205 0.609 101320
0.642 369.5251 0.843 101320 8 0.341 388.7213 0.692 101320
0.586 371.6247 0.796 101320 9 0.398 384.7221 0.761 101320
0.526 374.3241 0.724 101320 10 0.465 380.8228 0.814 101320
0.444 377.5235 0.649 101320 11 0.521 377.6235 0.854 101320
0.392 379.3231 0.589 101320 12 0.544 375.8238 0.872 101320
0.326 381.3227 0.498 101320 13 0.601 373.1244 0.897 101320
0.236 384.4221 0.362 101320 14 0.657 370.025 0.924 101320
0.188 385.6219 0.299 101320 15 0.704 367.3255 0.943 101320
0.139 386.9216 0.221 101320 16 0.757 364.5261 0.961 101320
0.093 388.1214 0.16 101320 17 0.818 362.0266 0.973 101320
0.027 390.021 0.051 101320 18 0.856 359.927 0.982 101320
0 390.8708 0 101320 19 0.917 357.7277 0.991 101320
20 1 355.5283
AmerAmezaga, S. An. Quim.,11975,
101320
71,
AmerAmezaga, S.; FernandezBiarge, J. An. 117 Liquid-vapor equilibrium of the binary
Quim., 1973, 69, 587 systems formed by propionic acid and
methyl, ethyl, propyl, isopropyl, n-butyl,
isobutyl, sec-butyl, and t- butyl alcohol
760 mm
Methanol - Methyl Formate Methanol - Methyl Acetate
1 Methanol 1 Methanol
2 Methyl Formate 2 Methyl Acetate
Liquid Vapor Liquid
mole mole Total mole
Temperat Temperat
No. fraction fraction pressure No. fraction
ure (K) ure (K)
METHA- METHA- (N/sqm) METHA-
01 01 01

1 0.0411 304.8 0.0347 101330 1 0.043 329.0252


2 0.0974 305.05 0.0704 101330 2 0.128 328.0255
3 0.1596 305.44 0.0992 101330 3 0.19 327.4257
4 0.228 305.98 0.1236 101330 4 0.312 327.1258
5 0.2923 306.55 0.1435 101330 5 0.427 327.2258
6 0.3616 307.21 0.1624 101330 6 0.56 327.8256
7 0.4498 308.21 0.1868 101330 7 0.716 329.2252
8 0.5528 309.72 0.2184 101330 8 0.89 332.9241
9 0.6109 310.83 0.2401 101330 9 0.951 335.224
10 0.6991 313.05 0.2832 101330 1 0 329.4251
11 0.791 316.61 0.355 101330 2 0.05 328.5254
12 0.888 323 0.5038 101330 3 0.094 327.9256
13 0.9528 330.27 0.7177 101330 4 0.21 326.8259
14 0.9808 334.63 0.8675 101330 5 0.304 326.626
6 0.352 326.626
Zeng, J.; Fu, C.; Hu, W. Tianranqi Huagong,
2000, 25, 3;54 Study on the VLE for 7 0.393 326.626
methyl formate - methanol system 8 0.45 326.7259
9 0.503 327.0258
10 0.58 327.2258
11 0.648 327.4257
12 0.725 328.4254
13 0.849 330.2249
14 0.93 333.324
15 1 337.624
1 0 329.9849
2 0.151 327.6257
3 0.29 327.0258
4 0.352 326.9459
5 0.405 327.0058
6 0.62 328.1655
7 0.679 328.6254
8 0.827 330.9247
1 0.047 329.0353
2 0.101 328.1356
3 0.17 326.4361
4 0.328 326.9359
5 0.436 327.1359
6 0.524 327.5357
7 0.612 328.0356
8 0.703 329.1353
9 0.804 330.4349
10 0.84 331.4347
11 0.86 332.0346
12 0.924 333.7343
13 0.955 335.234
14 0.974 336.4337
1 0 329.7851
2 0.032 329.5351
3 0.108 328.0356
4 0.25 327.1359
5 0.3 326.9359
6 0.32 326.8859
7 0.35 326.9359
8 0.45 327.1359
9 0.55 327.4358
10 0.668 328.4355
11 0.753 329.4852
12 0.846 331.5347
13 0.848 331.6347
14 0.866 331.9346
15 0.894 332.7844
16 0.904 333.1344
17 0.906 333.1344
18 0.914 333.2344
19 0.926 333.8342
20 1 337.8334
1 0 329.89
2 0.1002 327.91
3 0.1999 326.97
4 0.3 326.62
5 0.4035 326.63
6 0.5004 327
7 0.5963 327.51
8 0.6986 328.53
9 0.7994 330.1
10 0.8996 332.82
11 1 337.6
1 0.019 329.34
2 0.076 328.27
3 0.115 327.8
4 0.205 327.17
5 0.258 327.02
6 0.281 326.99
7 0.304 326.98
8 0.327 326.98
9 0.364 327.01
10 0.368 327.02
11 0.463 327.28
12 0.481 327.36
13 0.515 327.52
14 0.56 327.8
15 0.581 327.95
16 0.629 328.34
17 0.646 328.51
18 0.673 328.8
19 0.705 329.2
20 0.734 329.6
21 0.784 330.45
22 0.801 330.78
23 0.835 331.54
24 0.852 331.97
25 0.855 332.03
26 0.877 332.67
27 0.879 332.73
28 0.896 333.24
29 0.897 333.27
30 0.926 334.29
31 0.946 335.05
32 0.991 337.15
1 0 329.97
2 0.098 327.89
3 0.194 326.96
4 0.294 326.6
5 0.397 326.79
6 0.489 326.96
7 0.594 327.65
8 0.701 328.51
9 0.797 330.08
10 0.898 332.82
11 1 337.57
Vapor-Liquid Equilibrium and Liquid
Equilibrium of Methyl Acetate
Methanol + 1-Ethyl-3-methylimidaz
Acetate
Chem. Liq., 2011, 49, 52-71 Pha
equilibria of binary mixtures conta
methyl acetate, water, methano
ethanol at 101.3 kPa

Topphoff, M.; Kiepe, J.; Gmehling


Chem. Eng. Data, 2001, 46, 133
80, 338 Vapor-liquid equilibrium of
mixtures of alcohols and acetic a
esters. I. Systems with methanol, et
n-propanol and isopropanol at 760
Nagata, I. J. Chem. Eng. Data, 1969
418-20 Vapor-Liquid Equilibrium Da
the Binary Systems Methanol-Ben
and Methyl Acetate-Methano
Dobroserdov, L. L.; Bagrov, I. V. Zh.
Khim. (Leningrad), 1967, 40, 875 P
Khim. (Leningrad), 1967, 40, 875 P
equilibriums of the methyl aceta
methanol liquid-vapor system
Zasshi, 1952, 55, 801-3 Extracti
Distillation II. Vapor-liquid Equilib
Relation of Methyl Acetate-Metha
Water Systems
Serafimov, L. A. Zh. Fiz. Khim., 196
1210 Physicochemical studies of
system methyl acetate - methanol
various pressures
Acetate Methanol - Ethyl Acetate Methanol - Propyl Aceta
1 Methanol 1 Methanol
2 n-Ethyl Acetate 2 n-Propyl Acetate
Vapor Liquid Vapor
mole Total mole mole Total
Temperat
fraction pressure No. fraction fraction pressure No.
ure (K)
METHA- (N/sqm) METHA- METHA- (N/sqm)
01 01 01

0.08 101320 1 0 350.2733 0 101320 1


0.18 101320 2 0.0125 349.2734 0.0475 101320 2
0.239 101320 3 0.032 347.2736 0.133 101320 3
0.316 101320 4 0.08 344.3739 0.2475 101320 4
0.381 101320 5 0.155 340.874 0.365 101320 5
0.449 101320 6 0.251 338.774 0.455 101320 6
0.544 101320 7 0.3465 337.274 0.5205 101320 7
0.727 101320 8 0.402 337.174 0.556 101320 8
0.864 101320 9 0.4975 336.374 0.597 101320 9
0 101325 10 0.561 336.074 0.638 101320 1
0.08 101325 11 0.589 335.674 0.656 101320 2
0.165 101325 12 0.622 335.774 0.667 101320 3
0.25 101325 13 0.696 335.674 0.7 101320 4
0.335 101325 14 0.765 335.474 0.742 101320 5
0.352 101325 15 0.825 335.774 0.789 101320 6
0.38 101325 16 0.855 335.974 0.807 101320 7
0.39 101325 17 0.916 336.374 0.86 101320 8
0.43 101325 18 0.955 337.074 0.929 101320 9
0.47 101325 19 1 337.874 1 101320 10
0.51 101325 1 0.028 347.5236 0.12 101000 11
0.566 101325 2 0.037 347.1236 0.133 101000 12
0.666 101325 3 0.073 344.6239 0.22 101000 13
0.82 101325 4 0.123 342.424 0.31 101000 14
1 101325 5 0.211 339.524 0.42 101000 15
0 101320 6 0.236 339.124 0.442 101000 16
0.212 101320 7 0.239 338.924 0.44 101000 17
0.309 101320 8 0.265 338.424 0.468 101000 18
0.343 101320 9 0.352 337.124 0.526 101000 19
0.371 101320 10 0.408 336.824 0.558 101000 20
0.484 101320 11 0.44 336.724 0.573 101000
0.523 101320 12 0.533 336.224 0.62 101000
0.658 101320 13 0.585 336.024 0.647 101000
0.095 101000 14 0.664 335.524 0.687 101000
0.153 101000 15 0.708 335.524 0.711 101000
0.224 101000 16 0.748 335.524 0.737 101000
0.328 101000 17 0.793 335.524 0.768 101000
0.393 101000 18 0.822 335.624 0.79 101000
0.44 101000 19 0.883 335.924 0.842 101000
0.493 101000 20 0.961 337.124 0.934 101000
0.548 101000 1 0 350.2233 0 101320
0.638 101000 2 0.019 347.9235 0.079 101320
0.681 101000 3 0.024 347.1236 0.093 101320
0.708 101000 4 0.056 345.4238 0.181 101320
0.8 101000 5 0.181 340.224 0.384 101320
0.871 101000 6 0.311 337.824 0.492 101320
0.914 101000 7 0.35 337.324 0.52 101320
0 101330 8 0.403 336.724 0.557 101320
0.047 101330 9 0.566 335.724 0.64 101320
0.16 101330 10 0.616 335.524 0.675 101320
0.272 101330 11 0.646 335.524 0.678 101320
0.32 101330 12 0.708 335.424 0.711 101320
0.325 101330 13 0.72 335.224 0.716 101320
0.349 101330 14 0.734 335.424 0.717 101320
0.395 101330 15 0.743 335.624 0.732 101320
0.443 101330 16 0.744 335.724 0.733 101320
0.52 101330 17 0.81 335.624 0.779 101320
0.583 101330 18 0.815 335.524 0.784 101320
0.687 101330 19 0.889 335.924 0.846 101320
0.687 101330 20 0.939 336.424 0.903 101320
0.702 101330 21 1 337.824 1 101320
0.747 101330 1 0.018 348.2305 0.091 101320
0.763 101330 2 0.086 344.6316 0.284 101320
0.763 101330 3 0.138 343.0321 0.361 101320
0.775 101330 4 0.195 341.3326 0.402 101320
0.802 101330 5 0.263 339.5331 0.46 101320
1 101330 6 0.382 337.5335 0.539 101320
0 101300 7 0.497 336.7337 0.604 101320
0.1554 101300 8 0.63 336.1338 0.67 101320
0.2518 101300 9 0.8 336.1338 0.77 101320
0.3134 101300 10 0.898 336.7337 0.848 101320
0.3728 101300 11 0.952 336.9336 0.912 101320
0.426 101300 1 0.175 340.5828 0.401 101000
0.4656 101300 2 0.2 339.5331 0.437 101000
0.5329 101300 3 0.234 338.9332 0.475 101000
0.6212 101300 4 0.301 337.9334 0.525 101000
0.7388 101300 5 0.372 337.0836 0.565 101000
1 101300 6 0.412 336.9336 0.583 101000
0.035 101300 7 0.477 336.2837 0.602 101000
0.119 101300 8 0.525 336.0338 0.625 101000
0.163 101300 9 0.625 335.4839 0.669 101000
0.243 101300 10 0.685 335.3339 0.699 101000
0.279 101300 11 0.692 335.234 0.702 101000
0.293 101300 12 0.825 335.7339 0.795 101000
0.307 101300 13 0.855 335.8838 0.821 101000
0.32 101300 14 0.916 336.4337 0.892 101000
0.34 101300 1 0.05 346.531 0.181 101300
0.342 101300 2 0.1 343.182 0.282 101300
0.391 101300 3 0.15 341.2326 0.355 101300
0.401 101300 4 0.2 339.6331 0.4 101300
0.418 101300 5 0.25 338.6333 0.45 101300
0.443 101300 6 0.3 337.8334 0.48 101300
0.455 101300 7 0.4 336.7337 0.555 101300
0.484 101300 8 0.5 336.2338 0.602 101300
0.495 101300 9 0.6 335.7339 0.664 101300
0.514 101300 10 0.7 335.5339 0.692 101300
0.538 101300 11 0.75 335.5339 0.743 101300
0.562 101300 12 0.8 335.6339 0.761 101300
0.609 101300 13 0.9 336.2338 0.845 101300
0.627 101300 14 0.95 337.1336 0.9 101300
0.668 101300 1 0 350.15 0 100000
0.691 101300 2 0.028 347.05 0.108 100000
0.694 101300 3 0.048 345.95 0.168 100000
0.728 101300 4 0.068 344.85 0.207 100000
0.731 101300 5 0.088 343.95 0.245 100000
0.758 101300 6 0.128 342.75 0.316 100000
0.76 101300 7 0.227 339.65 0.436 100000
0.814 101300 8 0.299 338.45 0.499 100000
0.855 101300 9 0.333 337.95 0.522 100000
0.973 101300 10 0.409 337.05 0.564 100000
0 101300 11 0.45 336.75 0.584 100000
0.155 101300 12 0.487 336.45 0.603 100000
0.252 101300 13 0.522 336.25 0.621 100000
0.313 101300 14 0.554 336.15 0.639 100000
0.372 101300 15 0.603 335.95 0.664 100000
0.427 101300 16 0.673 335.75 0.696 100000
0.465 101300 17 0.712 335.65 0.719 100000
0.532 101300 18 0.74 335.65 0.733 100000
0.621 101300 19 0.754 335.65 0.74 100000
0.74 101300 20 0.811 335.85 0.78 100000
1 101300 21 0.834 335.95 0.799 100000
uid Equilibrium and Liquid-Liquid 22 0.889 336.35 0.851 100000
ibrium of Methyl Acetate +
l + 1-Ethyl-3-methylimidazolium 23 0.919 336.65 0.883 100000
Acetate 24 0.933 336.85 0.899 100000
m. Liq., 2011, 49, 52-71 Phase 25 0.974 337.35 0.951 100000
a of binary mixtures containing
l acetate, water, methanol or 26 0.987 337.65 0.974 100000
ethanol at 101.3 kPa 27 1 337.85 1 100000
5706 Vapor-Liquid Equilibria for Ethyl
Acetate + Methanol at (0.1, 0.5, and 0.7)
off, M.; Kiepe, J.; Gmehling, J. J. MPa. Measurements with a New
m. Eng. Data, 2001, 46, 1333 Ebulliometer
apor-liquid equilibrium of binary
res of alcohols and acetic acid Rajendran, M.; Renganarayanan, S.;
Systems with methanol, ethanol, Madhavan, P. R.; Srinivasan, D. Chem.
ol and isopropanol at 760 mmHg Eng. Commun., 1988, 74, 179
I. J. Chem. Eng. Data, 1969, 14, Chem. Biotechnol., 1974, 24, 709-29 The
apor-Liquid Equilibrium Data for vapor-liquid equilibrium of ternary
ary Systems Methanol-Benzene systems with limited miscibility at
Methyl Acetate-Methanol atmospheric pressure
rdov, L. L.; Bagrov, I. V. Zh. Prikl. Chem. Eng. Data, 1971, 16, 70-2 Salt
eningrad), 1967, 40, 875 Phase effect in vapor-liquid equilibriums of
effect in vapor-liquid equilibriums of
methanol + ethyl actate + calcium chloride
system
hi, 1952, 55, 801-3 Extractive
tion II. Vapor-liquid Equilibrium Akita, K.; Yoshida, F. J. Chem. Eng. Data,
n of Methyl Acetate-Methanol- 1963, 8, 484 Phase-Equilibria in Methanol-
Water Systems Ethyl Acetate-Water System
ov, L. A. Zh. Fiz. Khim., 1967, 41, Nagata, I. J. Chem. Eng. Data, 1962, 7,
hysicochemical studies of the 367-73 Isobaric Vapor-Liquid Equilibria for
methyl acetate - methanol under the Ternary System Chloroform-
various pressures Methanol-Ethyl Acetate
Eng., 1958, 3, 72-81 Vapor-Liquid
Equilibria for Binary Systems of Methanol,
Ethyl Alcohol, 1-Propanol, and 2-Propanol
with Ethyl Acetate and 1-Propanol-Water
Methanol - Propyl Acetate Methanol - Butyl Acetate
1 Methanol
n-Propyl Acetate 2 n-Butyl Acetate
Liquid Vapor Liquid Vapor
mole mole Total mole mole Total
Temperat Temperat
fraction fraction pressure No. fraction fraction pressure
ure (K) ure (K)
METHA- METHA- (N/sqm) METHA- METHA- (N/sqm)
01 01 01 01

0.076 362.5265 0.343 101325 1 0 398.9692 0 101320


0.201 352.9291 0.664 101325 2 0.05 382.9724 0.531 101320
0.283 348.6304 0.685 101325 3 0.067 378.9732 0.624 101320
0.385 345.1315 0.768 101325 4 0.109 367.9754 0.718 101320
0.485 342.9321 0.809 101325 5 0.3 351.9794 0.86 101320
0.594 341.2326 0.839 101325 6 0.73 340.9827 0.94 101320
0.701 339.833 0.872 101325 7 1 337.9834 1 101320
0.805 338.8332 0.899 101325 1 0 398.65 0 101300
0.906 338.0334 0.936 101325 2 0.028 387.65 0.314 101300
0 374.4 0 101300 3 0.114 367.85 0.679 101300
0.022 370.3 0.163 101300 4 0.179 359.95 0.777 101300
0.053 365.2 0.308 101300 5 0.236 354.45 0.828 101300
0.096 360.2 0.439 101300 6 0.376 347.45 0.883 101300
0.121 357.9 0.492 101300 7 0.448 345.45 0.9 101300
0.141 355.9 0.528 101300 8 0.571 343.05 0.922 101300
0.183 352.4 0.583 101300 9 0.699 341.45 0.936 101300
0.26 347.9 0.662 101300 10 0.794 340.15 0.949 101300
0.323 345.8 0.698 101300 11 0.897 338.95 0.967 101300
0.442 344.2 0.757 101300 12 0.943 338.35 0.979 101300
0.505 343.3 0.783 101300 13 0.989 337.85 0.992 101300
0.575 342.2 0.806 101300 14 1 337.65 1 101300
0.65 341 0.835 101300 Patlasov, V. P.; Naumova, T. B.;
Sergacheva, N. I.; Balashov, M. I. Tr. Inst. -
0.709 340.2 0.849 101300 Mosk. Inst. Tonkoi Khim. Tekhnol. im. M.
0.771 339.1 0.872 101300 V. Lomonosova, 1977, 7, 179
0.826 338.3 0.886 101300
Resa, J. M.; Gonzalez, C.; Moradillo, B.;
0.881 337.7 0.919 101300 Lanz, J. J. Chem. Thermodyn., 1998, 30,
0.922 337.6 0.924 101300 1207-1219
0.964 A. V.;337.7
Grishunin, 0.96
Balashov, M. 101300
I.; Patlasov,
1 337.9 1 101300
V. P.; Kissel, V. L.; Serafimov, L. A. Osnovn.
Org. Sint. Neftekhim., 1976, 5, 109-113
Liquid-Vapor Phase Equilibrium in the
System Methanol-Propanol-Propyl
acetate

Resa, J. M.; Gonzalez, C.; de Landaluce, S.


O.; Lanz, J. J. Chem. Eng. Data, 2001, 46,
1338-1343
Ethanol - Ethyl Formate Ethanol - propyl Formate
1 n-Ethanol 1 n-Ethanol
2 n-Ethyl Formate 2 Propyl Formate
Liquid Vapor Liquid
mole mole Total mole
Temperat Temperat
No. fraction fraction pressure No. fraction
ure (K) ure (K)
ETHAN- ETHAN- (N/sqm) ETHAN-
01 01 01

1 0 327.29 0 101320 1 0 353.79


2 0.019 327.23 0.022 101320 2 0.0533 351.65
3 0.065 327.19 0.061 101320 3 0.0567 351.47
4 0.083 327.24 0.074 101320 4 0.0732 350.87
5 0.102 327.27 0.088 101320 5 0.0785 350.68
6 0.125 327.34 0.104 101320 6 0.1392 348.7
7 0.161 327.48 0.123 101320 7 0.1653 348.1
8 0.176 327.58 0.131 101320 8 0.2426 346.75
9 0.206 327.71 0.146 101320 9 0.3272 345.9
10 0.225 327.84 0.155 101320 10 0.3675 345.63
11 0.26 328.11 0.171 101320 11 0.4185 345.36
12 0.286 328.27 0.182 101320 12 0.4604 345.24
13 0.323 328.56 0.198 101320 13 0.5016 345.15
14 0.349 328.81 0.209 101320 14 0.5464 345.13
15 0.379 329.08 0.218 101320 15 0.5832 345.17
16 0.406 329.36 0.23 101320 16 0.6418 345.31
17 0.429 329.63 0.238 101320 17 0.6921 345.49
18 0.459 329.96 0.249 101320 18 0.7165 345.65
19 0.482 330.25 0.259 101320 19 0.7634 345.97
20 0.505 330.53 0.269 101320 20 0.7891 346.23
21 0.529 330.89 0.28 101320 21 0.8131 346.45
22 0.558 331.32 0.293 101320 22 0.8369 346.78
23 0.591 331.83 0.308 101320 23 0.8549 347.1
24 0.624 332.4 0.326 101320 24 0.8885 347.68
25 0.655 333.03 0.344 101320 25 0.9038 347.95
26 0.681 333.62 0.361 101320 26 0.9261 348.5
27 0.71 334.39 0.383 101320 27 0.9464 349.08
28 0.746 335.43 0.412 101320 28 0.9561 349.37
29 0.779 336.53 0.443 101320 29 0.9686 349.67
30 0.82 338.14 0.492 101320 30 Galvan, S.;
1 Ortega,
351.13
J.; Susial, P.; Pen
31 0.859 340.01 0.552 101320 J. Chem. Eng. Jpn., 1994, 27, 529
Isobaric vapor-liquid equilibria for p
32 0.886 341.69 0.608 101320 methanoate + (n-alkanes, C7, C8 , C
33 0.92 344.03 0.69 101320 n-alkanols (C2, C3, C4)
34 0.942 345.88 0.762 101320
35 0.962 347.66 0.831 101320
36 0.975 348.98 0.888 101320
37 0.989 350.48 0.954 101320
38 1 351.46 1 101320

Soto, A.; Hernandez, P.; Ortega, J. Fluid


Phase Equilib., 1998, 146, 351-370
mate Ethanol - Butyl Formate Ethanol - Methyl Acetate
1 n-Ethanol 1 n-Ethanol
2 Butyl Formate 2 Methyl Acetate
Vapor Liquid Vapor
mole Total mole mole Total
Temperat
fraction pressure No. fraction fraction pressure No.
ure (K)
ETHAN- (N/sqm) ETHAN- ETHAN- (N/sqm)
01 01 01

0 101320 1 0.0236 377.47 0.0889 101320 1


0.1079 101320 2 0.0345 375.67 0.1502 101320 2
0.114 101320 3 0.0678 372.57 0.2542 101320 3
0.1424 101320 4 0.0768 371.25 0.2929 101320 4
0.1512 101320 5 0.0886 369.93 0.3267 101320 5
0.2458 101320 6 0.1065 367.82 0.3725 101320 6
0.275 101320 7 0.1397 365.1 0.4445 101320 7
0.3516 101320 8 0.1538 364.07 0.4714 101320 8
0.4113 101320 9 0.1909 362.27 0.5171 101320 1
0.4361 101320 10 0.2107 361.01 0.5462 101320 2
0.4647 101320 11 0.2811 358.55 0.6047 101320 3
0.4879 101320 12 0.3097 357.45 0.6302 101320 4
0.5096 101320 13 0.3563 356.6 0.6517 101320 5
0.5331 101320 14 0.3733 356.24 0.6621 101320 6
0.5533 101320 15 0.3859 355.52 0.6708 101320 7
0.5839 101320 16 0.4155 354.85 0.6903 101320 8
0.6152 101320 17 0.4565 354.27 0.7069 101320 9
0.6317 101320 18 0.4772 353.87 0.7205 101320 1
0.6662 101320 19 0.494 353.53 0.7314 101320 2
0.6862 101320 20 0.5657 352.69 0.7604 101320 3
0.7081 101320 21 0.6043 352.3 0.7765 101320 4
0.7333 101320 22 0.7016 351.57 0.8179 101320 5
0.752 101320 23 0.7251 351.45 0.8275 101320 6
0.7917 101320 24 0.7956 351.14 0.8545 101320 7
0.8129 101320 25 0.8105 351.09 0.8688 101320 8
0.8485 101320 26 0.868 351.05 0.8829 101320 9
0.8858 101320 27 0.9025 351 0.9055 101320 10
0.9027 101320 28 0.9357 350.97 0.933 101320 11
0.9221 101320 29 0.9578 351 0.9495 101320 12
.; Ortega, J.; Susial, P.;1 Pena,
101320
J. A. 30 0.9892 351.07 0.9815 101320 13
m. Eng. Jpn., 1994, 27, 529-34 Gonzalez, E.; Ortega, J. J. Chem. Eng. Data, 14
vapor-liquid equilibria for propyl 1995, 40, 1178-83 Densities and Isobaric
oate + (n-alkanes, C7, C8 , C9) or 15
Vapor-Liquid Equilibria of Butyl Esters
n-alkanols (C2, C3, C4) (Methanoate to Butanoate) with Ethanol 16
at 101.32 kPa 17
18
19
20
21
22
23
24
25
26
27
28
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
Ethanol - Methyl Acetate Ethanol - Ethyl Acetate
1 n-Ethanol
Methyl Acetate 2 n-Ethyl Acetate
Liquid Vapor Liquid Vapor
mole mole Total mole mole Total
Temperat Temperat
fraction fraction pressure No. fraction fraction pressure
ure (K) ure (K)
ETHAN- ETHAN- (N/sqm) ETHAN- ETHAN- (N/sqm)
01 01 01 01

0.0783 330.4349 0.0505 101325 1 0.128 347.2236 0.17 101320


0.2908 330.7349 0.1785 101325 2 0.128 347.4236 0.208 101320
0.467 333.6343 0.273 101325 3 0.225 345.9237 0.262 101320
0.6241 336.2338 0.3897 101325 4 0.305 345.1238 0.315 101320
0.7678 340.033 0.5259 101325 5 0.497 345.2238 0.383 101320
0.8747 344.3317 0.6865 101325 6 0.55 345.3238 0.407 101320
0.9446 349.0303 0.8379 101325 7 0.7 346.3237 0.514 101320
0.9731 349.6301 0.9115 101325 8 0.715 345.7237 0.45 101320
0.1 331.4347 0.071 101000 9 0.735 346.1237 0.468 101320
0.2 333.3343 0.1405 101000 10 0.77 346.8236 0.547 101320
0.3 335.134 0.197 101000 11 0.831 348.3235 0.614 101320
0.4 336.9336 0.2503 101000 12 0.882 348.6235 0.746 101320
0.5 338.7333 0.3087 101000 13 0.901 349.1234 0.798 101320
0.6 340.5328 0.354 101000 14 0.944 349.8233 0.748 101320
0.7 342.5322 0.4169 101000 15 0.975 350.6233 0.873 101320
0.8 344.6316 0.5428 101000 16 0.984 351.3232 0.948 101320
0.9 347.6307 0.7325 101000 1 0 350.2233 0 101320
0 329.82 0 101320 2 0.091 349.0234 0.159 101320
0.012 329.85 0.0133 101320 3 0.175 347.9235 0.274 101320
0.0204 329.82 0.0216 101320 4 0.252 346.8236 0.351 101320
0.03 329.81 0.0308 101320 5 0.324 345.9237 0.402 101320
0.0376 329.79 0.0379 101320 6 0.389 345.2238 0.439 101320
0.0459 329.8 0.0456 101320 7 0.45 344.9238 0.467 101320
0.0568 329.82 0.055 101320 8 0.507 344.9238 0.479 101320
0.0763 329.85 0.0712 101320 9 0.56 344.9238 0.496 101320
0.1141 329.98 0.1003 101320 10 0.61 345.0238 0.513 101320
0.1544 330.15 0.1273 101320 11 0.657 345.1238 0.533 101320
0.1931 330.55 0.1612 101320 12 0.7 345.2238 0.555 101320
0.2326 330.85 0.1877 101320 13 0.742 345.5238 0.581 101320
0.2752 331.15 0.2085 101320 14 0.78 345.7237 0.61 101320
0.3708 332.05 0.257 101320 15 0.817 346.0237 0.643 101320
0.4331 332.55 0.2777 101320 16 0.852 346.6237 0.679 101320
0.4771 333.05 0.2998 101320 17 0.884 347.2236 0.725 101320
0.5267 333.55 0.3208 101320 18 0.916 348.1235 0.773 101320
0.5661 334.15 0.3414 101320 19 0.945 349.0234 0.824 101320
0.591 334.45 0.3537 101320 20 0.973 350.1233 0.878 101320
0.6279 335.15 0.3757 101320 21 1 351.4232 1 101320
0.6568 335.85 0.3957 101320 1 0.025 349.8233 0.07 101320
0.6945 336.75 0.423 101320 2 0.08 348.6235 0.126 101320
0.791 339.55 0.5202 101320 3 0.1 348.1235 0.164 101320
0.8094 340.15 0.544 101320 4 0.13 347.5236 0.2 101320
0.8224 340.75 0.5618 101320 5 0.24 345.7237 0.295 101320
0.8457 341.75 0.5968 101320 6 0.36 344.9238 0.398 101320
0.9312 345.75 0.7517 101320 7 0.563 345.1238 0.507 101320
1 351.46 1 101320 8 0.653 345.5238 0.56 101320
0.076 329.79 0.07 101300 9 0.71 345.9237 0.6 101320
0.118 329.9 0.102 101300 10 0.735 346.2237 0.627 101320
0.138 329.98 0.116 101300 11 0.776 346.6237 0.665 101320
0.139 329.99 0.116 101300 12 0.785 346.7236 0.675 101320
0.184 330.19 0.144 101300 13 0.833 347.3236 0.735 101320
0.192 330.24 0.149 101300 14 0.873 348.0235 0.773 101320
0.232 330.47 0.17 101300 15 0.878 348.1235 0.783 101320
0.235 330.49 0.172 101300 16 0.908 348.7234 0.823 101320
0.24 330.52 0.175 101300 17 0.932 349.2234 0.868 101320
0.248 330.57 0.179 101300 18 0.942 349.5234 0.88 101320
0.301 330.94 0.204 101300 19 0.984 350.8232 0.965 101320
0.308 330.99 0.208 101300 1 0.259703 347.0236 0.360951 101000
0.339 331.24 0.222 101300 2 0.416757 345.8237 0.487315 101000
0.363 331.44 0.233 101300 3 0.46098 345.5238 0.518251 101000
0.364 331.45 0.233 101300 4 0.680595 345.0238 0.657551 101000
0.424 332 0.26 101300 5 0.707122 345.1238 0.67182 101000
0.449 332.25 0.27 101300 6 0.763515 345.4238 0.710473 101000
0.466 332.43 0.278 101300 7 0.842066 346.4237 0.763515 101000
0.563 333.63 0.324 101300 8 0.906968 347.7235 0.840009 101000
0.626 334.61 0.358 101300 9 0.957074 349.2234 0.912481 101000
0.631 334.7 0.361 101300 1 0.05 349.1234 0.086 101320
0.664 335.32 0.381 101300 2 0.1 347.8235 0.163 101320
0.675 335.54 0.389 101300 3 0.2 346.1237 0.274 101320
0.684 335.73 0.395 101300 4 0.3 345.3238 0.356 101320
0.708 336.26 0.413 101300 5 0.4 345.0238 0.424 101320
0.733 336.9 0.434 101300 6 0.5 344.9238 0.484 101320
0.743 337.17 0.442 101300 7 0.6 345.2238 0.543 101320
0.826 339.92 0.535 101300 8 0.7 345.9237 0.611 101320
0.879 342.34 0.622 101300 9 0.8 347.0236 0.695 101320
0.911 344.12 0.69 101300 10 0.9 348.6235 0.813 101320
0.961 347.62 0.835 101300 11 0.95 349.7233 0.898 101320
0.989 350.12 0.95 101300 1 0 350.2233 0 101320
0 330.05 0 100000 2 0.0505 348.6734 0.1036 101320
0.041 329.95 0.041 100000 3 0.126 346.9436 0.2146 101320
0.089 330.15 0.079 100000 4 0.1343 346.9036 0.2146 101320
0.098 330.15 0.089 100000 5 0.2271 346.1637 0.296 101320
0.126 330.25 0.108 100000 6 0.3128 345.6238 0.3634 101320
0.145 330.45 0.126 100000 7 0.3358 345.4038 0.3643 101320
0.28 331.15 0.191 100000 8 0.5052 345.3038 0.4803 101320
0.314 331.55 0.209 100000 9 0.5441 345.4738 0.5074 101320
0.357 331.95 0.227 100000 10 0.6442 345.8237 0.5618 101320
0.431 332.95 0.262 100000 11 0.6828 346.0237 0.6092 101320
0.512 333.75 0.297 100000 12 0.786 347.2636 0.6819 101320
0.559 334.45 0.314 100000 13 0.8774 348.6235 0.7908 101320
0.628 336.05 0.365 100000 14 0.9482 349.8233 0.8924 101320
0.665 336.75 0.398 100000 15 1 351.4232 1 101320
0.709 337.25 0.423 100000 1 0.0947 347.8306 0.155 101320
0.789 339.75 0.504 100000 2 0.1753 346.2311 0.2496 101320
0.832 341.35 0.582 100000 3 0.3233 344.9315 0.3835 101320
0.921 345.95 0.746 100000 4 0.4502 345.2314 0.4782 101320
0.962 349.05 0.873 100000 5 0.5605 345.6313 0.5396 101320
1 351.35 1 100000 6 0.6566 346.2311 0.6082 101320
VAPOR-LIQUID EQUILIBRIUM 7 0.7413 346.9309 0.6656 101320
MEASUREMENTS FOR THE BINARY
SYSTEM METHYL ACETATE+ETHANOL AT 8 0.8213 347.6307 0.7351 101320
0.3 AND 0.7 MPa 9 0.8843 348.8303 0.803 101320
Chem. Liq., 2011, 49, 52-71 Phase 10 0.945 349.93 0.8885 101320
equilibria of binary mixtures containing
methyl acetate, water, methanol or 11 0.9732 350.5298 0.9405 101320
ethanol at 101.3 kPa 12 0.9868 350.9297 0.9695 101320
Chem. Eng. Data, 1990, 35, 350-352 1 0.05 348.8303 0.093 101000
Vapor-liquid equilibrium measurements at
101.32 kPa for binary mixtures of methyl 2 0.1 347.7307 0.163 101000
acetate + ethanol or 1-propanol 3 0.2 346.1312 0.265 101000
4 0.3 345.2314 0.349 101000
Nishi, Y. J. Chem. Eng. Jpn., 1972, 5, 334-9
Vapor-liquid equilibria accompanied by 5 0.4 344.9315 0.42 101000
hypothetical chemical reaction 6 0.459 344.8315 0.459 101000
Uchebn. Zaved., Pishch. Tekhnol., 1970, , 7 0.5 344.9315 0.484 101000
124-6 Liquid-vapor phase equilibrium in
ethanol - methyl acetate and water - 8 0.6 345.2314 0.544 101000
methyl acetate systems 9 0.7 345.9312 0.613 101000
10 0.8 347.1309 0.7 101000
11 0.9 348.8303 0.817 101000
12 0.95 350.13 0.894 101000
1 0.05 348.6304 0.101 101000
2 0.131 346.8309 0.215 101000
3 0.21 346.0812 0.291 101000
4 0.306 345.5313 0.368 101000
5 0.436 345.3314 0.452 101000
6 0.551 345.3814 0.501 101000
7 0.6 345.5313 0.526 101000
8 0.66 345.9312 0.569 101000
9 0.772 347.0809 0.676 101000
10 0.857 348.4805 0.768 101000
11 0.915 349.6301 0.863 101000
1 0 350.2299 0 101330
2 0.064 348.4305 0.1 101330
3 0.083 347.7307 0.135 101330
4 0.11 347.5307 0.162 101330
5 0.168 346.731 0.237 101330
6 0.173 346.531 0.272 101330
7 0.256 345.8312 0.319 101330
8 0.319 345.5313 0.465 101330
9 0.372 345.3314 0.408 101330
10 0.538 345.3314 0.505 101330
11 0.64 345.7313 0.578 101330
12 0.668 345.9312 0.596 101330
13 0.669 345.8312 0.59 101330
14 0.743 346.531 0.649 101330
15 0.85 347.5307 0.751 101330
16 0.864 348.2305 0.768 101330
17 0.865 348.3305 0.77 101330
18 0.903 349.1303 0.825 101330
19 0.905 349.2302 0.824 101330
20 0.929 349.83 0.866 101330
21 0.97 350.9297 0.934 101330
22 0.978 351.1297 0.95 101330
23 0.987 351.4296 0.97 101330
24 1 351.4296 1 101330
1 0.0097 349.5301 0.0314 101325
2 0.0152 349.3302 0.0474 101325
3 0.0252 349.1303 0.0652 101325
4 0.0366 348.8303 0.0792 101325
5 0.0474 348.6304 0.0962 101325
6 0.0555 348.4305 0.1081 101325
7 0.0633 348.2305 0.1202 101325
8 0.0846 347.8306 0.1496 101325
9 0.1084 347.4308 0.1784 101325
10 0.121 347.2308 0.1926 101325
11 0.1366 347.0309 0.2086 101325
12 0.1497 346.8309 0.2227 101325
13 0.1602 346.631 0.2339 101325
14 0.1806 346.3311 0.2551 101325
15 0.2027 346.1312 0.2773 101325
16 0.2233 345.9312 0.298 101325
17 0.2549 345.6313 0.3275 101325
18 0.2808 345.4314 0.3525 101325
19 0.3146 345.2314 0.3831 101325
20 0.3305 345.1315 0.396 101325
21 0.3575 345.0315 0.4169 101325
22 0.3789 344.9315 0.4348 101325
23 0.4035 344.9115 0.4548 101325
24 0.4331 344.8315 0.4688 101325
25 0.49 344.8315 0.4891 101325
26 0.5245 344.8815 0.5005 101325
27 0.5349 344.9315 0.5066 101325
28 0.553 344.9815 0.5163 101325
29 0.5756 345.0315 0.527 101325
30 0.5816 345.0815 0.5309 101325
31 0.5981 345.1315 0.5389 101325
32 0.6446 345.4314 0.5669 101325
33 0.6623 345.5313 0.5779 101325
34 0.6912 345.8312 0.5998 101325
35 0.7214 346.1312 0.6219 101325
36 0.7503 346.4311 0.6483 101325
37 0.7812 346.8309 0.6676 101325
38 0.7902 346.9309 0.6857 101325
39 0.8008 347.1309 0.6964 101325
40 0.8204 347.2308 0.7164 101325
41 0.8259 347.3308 0.722 101325
42 0.8312 347.4308 0.7288 101325
43 0.8392 347.6307 0.738 101325
44 0.8532 347.8306 0.7553 101325
45 0.8563 347.9306 0.7598 101325
46 0.8709 348.1306 0.7766 101325
47 0.8784 348.2305 0.7862 101325
48 0.8907 348.5304 0.8029 101325
49 0.8995 348.7304 0.8132 101325
50 0.9152 349.0303 0.8337 101325
51 0.9266 349.2302 0.8553 101325
52 0.9309 349.3302 0.8609 101325
53 0.9385 349.5301 0.8755 101325
54 0.9465 349.7301 0.8886 101325
55 0.9532 349.93 0.8993 101325
56 0.9692 349.3302 0.9292 101325
57 0.9752 350.5298 0.9423 101325
1 0 350.27 0 101300
2 0.077 348.48 0.132 101300
3 0.144 347.39 0.215 101300
4 0.246 346.3 0.311 101300
5 0.344 345.51 0.383 101300
6 0.445 345.21 0.448 101300
7 0.512 345.31 0.489 101300
8 0.631 345.9 0.565 101300
9 0.745 346.9 0.651 101300
10 0.843 348.19 0.749 101300
11 0.929 349.77 0.866 101300
12 1 351.36 1 101300
1 0 350.16 0 101300
2 0.0503 348.77 0.0934 101300
3 0.1498 346.82 0.2273 101300
4 0.2606 345.6 0.3463 101300
5 0.3502 345.14 0.3937 101300
6 0.4526 344.96 0.4511 101300
7 0.5498 345.09 0.4997 101300
8 0.6505 345.48 0.5568 101300
9 0.7502 346.24 0.628 101300
10 0.8498 347.43 0.7548 101300
11 0.9251 349.12 0.8487 101300
12 1 351.45 1 101300
1 0.1008 347.91 0.1643 101325
2 0.158 346.99 0.2301 101325
3 0.2081 346.33 0.2836 101325
4 0.2553 345.89 0.3238 101325
5 0.2998 345.61 0.3562 101325
6 0.3406 345.43 0.3835 101325
7 0.3759 345.29 0.407 101325
8 0.4208 345.21 0.4343 101325
9 0.4631 345.19 0.459 101325
10 0.501 345.22 0.4822 101325
11 0.5357 345.27 0.5019 101325
12 0.5658 345.35 0.5156 101325
13 0.585 345.41 0.5271 101325
14 0.6084 345.51 0.5414 101325
15 0.6303 345.61 0.5593 101325
16 0.6594 345.7 0.5704 101325
17 0.7095 346.07 0.6101 101325
18 0.778 346.74 0.6611 101325
19 0.8114 347.16 0.6934 101325
20 0.8367 347.53 0.7222 101325
21 0.8995 348.76 0.8064 101325
22 0.9349 349.52 0.8633 101325
23 0.9563 350.08 0.8976 101325
24 0.9761 350.77 0.9398 101325
1 0 349.89 0 100000
2 0.025 349.1 0.049 100000
3 0.063 348.13 0.112 100000
4 0.1 347.36 0.167 100000
5 0.125 346.88 0.197 100000
6 0.149 346.51 0.226 100000
7 0.165 346.27 0.241 100000
8 0.182 346.05 0.26 100000
9 0.21 345.8 0.28 100000
10 0.233 345.57 0.301 100000
11 0.256 345.37 0.321 100000
12 0.283 345.18 0.343 100000
13 0.31 345.04 0.363 100000
14 0.334 344.91 0.379 100000
15 0.376 344.8 0.407 100000
16 0.416 344.73 0.432 100000
17 0.46 344.71 0.458 100000
18 0.507 344.73 0.486 100000
19 0.552 344.82 0.514 100000
20 0.598 344.98 0.542 100000
21 0.645 345.18 0.572 100000
22 0.697 345.53 0.608 100000
23 0.74 345.89 0.642 100000
24 0.783 346.39 0.683 100000
25 0.832 347.02 0.728 100000
26 0.879 347.82 0.788 100000
27 0.926 348.85 0.853 100000
28 0.957 349.74 0.909 100000
29 0.979 350.45 0.952 100000
30 1 351.21 1 100000
1 0 350.25 0 101320
2 0.038 348.86 0.076 101320
3 0.087 347.55 0.164 101320
4 0.195 345.94 0.27 101320
5 0.291 345.36 0.346 101320
6 0.39 345 0.408 101320
7 0.483 345.06 0.47 101320
8 0.582 345.46 0.532 101320
9 0.677 346.13 0.611 101320
10 0.805 347.04 0.701 101320
11 0.893 348.85 0.808 101320
12 0.951 350.13 0.894 101320
13 1 351.46 1 101320
1 0.0216 349.35 0.0412 101325
2 0.0626 348.25 0.117 101325
3 0.0776 348.25 0.1209 101325
4 0.1211 347.45 0.1643 101325
5 0.1321 346.75 0.2036 101325
6 0.1506 346.65 0.2005 101325
7 0.2228 345.85 0.2693 101325
8 0.3098 345.35 0.3437 101325
9 0.3692 345.35 0.3706 101325
10 0.6434 345.55 0.5404 101325
11 0.734 346.25 0.6021 101325
12 0.8632 348.05 0.7399 101325
13 0.918 348.65 0.7941 101325
14 0.9391 349.25 0.8361 101325
15 0.9555 349.75 0.8797 101325
16 0.9763 350.35 0.9273 101325
17 0.9842 350.85 0.9509 101325
18 0.9989 351.35 0.9923 101325
19 1 351.55 1 101325
1 0 350.15 0 100000
2 0.028 349.25 0.056 100000
3 0.056 348.55 0.096 100000
4 0.096 347.85 0.148 100000
5 0.198 346.15 0.269 100000
6 0.257 345.65 0.326 100000
7 0.281 345.55 0.348 100000
8 0.326 345.35 0.381 100000
9 0.434 345.15 0.444 100000
10 0.484 345.15 0.474 100000
11 0.58 345.35 0.533 100000
12 0.598 345.45 0.542 100000
13 0.616 345.55 0.552 100000
14 0.701 346.05 0.616 100000
15 0.771 346.65 0.668 100000
16 0.822 347.35 0.717 100000
17 0.857 347.95 0.756 100000
18 0.89 348.45 0.794 100000
19 0.953 349.95 0.897 100000
20 0.983 350.75 0.953 100000
21 1 351.45 1 100000
1 0 350.45 0 101000
2 0.1808 348.05 0.2846 101000
3 0.2962 346.75 0.3904 101000
4 0.4 346.45 0.4183 101000
5 0.5038 346.35 0.4683 101000
6 0.6087 346.65 0.525 101000
7 0.7077 347.25 0.5712 101000
8 0.801 347.45 0.6687 101000
9 0.9032 349.35 0.7929 101000
10 0.9498 350.25 0.8827 101000
11 1 352.75 1 101000
Balakrishnan, A. R. J. Chem. Eng. Data,
2013, 58, 560-569 Effect of Inorganic Salts
on the Isobaric Vapor Liquid Equilibrium
of the Ethyl Acetate Ethanol System
Eng. Jpn., 2011, 44, 155-163 Vapor
Pressure and VLE Data Measurements on
Ethyl Acetate/Ethanol Binary system at
0.1, 0.5, and 0.7 MPa
Chem. Eng. Data, 2009, 54, 194-197
Isobaric Vapor-Liquid Equilibrium for Ethyl
Acetate + Ethanol + 1-Ethyl-3-
methylimidazolium Tetrafluoroborate
2007, 52, 2325-2330 Isobaric Vapor-Liquid
Equilibria for Ethyl Acetate + Ethanol + 1-
Ethyl-3-methylimidazolium
Trifluoromethanesulfonate at 100 kPa
liquid equilibria for the quaternary
reactive system ethyl acetate + ethanol
+water + acetic acid and some of the
constituent binary systems at 101.3 kPa

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Chem. Eng. Data, 2001, 46, 1333
Equilib., 1997, 130, 243-252 Effect of 1 ,2-
propanediol on the vapor-liquid equilibria
of the ethyl acetate + ethanol system at
101.3 kPa
Ortega, J.; Pena, J. A.; de Alfonso, C. J.
Chem. Eng. Data, 1986, 31, 339 Isobaric
Vapor-Liquid Equilibria of Ethyl Acetate +
Ethanol Mixtures at 760 +- 0.5mmHg
80, 338 Vapor-liquid equilibrium of binary
mixtures of alcohols and acetic acid
esters. I. Systems with methanol, ethanol,
n-propanol and isopropanol at 760 mmHg
Chem. Biotechnol., 1974, 24, 709-29 The
vapor-liquid equilibrium of ternary
systems with limited miscibility at
atmospheric pressure
for isobaric dew and bubble point method
methanol + water, ethyl acetate +
ethanol, water + 1-butanol, and ethyl
acetate + water systems
G. Izv. Vyssh. Uchebn. Zaved., Pishch.
Tekhnol., 1968, , 136-9 Liquid-vapor phase
equilibrium in ethanol - ethyl acetate and
water - ethyl acetate systems
Eng., 1958, 3, 72-81 Vapor-Liquid
Equilibria for Binary Systems of Methanol,
Ethyl Alcohol, 1-Propanol, and 2-Propanol
with Ethyl Acetate and 1-Propanol-Water

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1950, Reinhold: New York
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Ind. Eng. Chem., 1949, 41, 2352 Phase
equilibria in ethyl alcohol - ethyl acetate -
water system
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Chem., 1937, 29, 709 Ethyl alcohol - ethyl
acetate and acetic acid - ethyl acetate
systems
Kireev, V. A.; Klinov, I. Ya.; Grigorovich, A.
N. Khim. Mashinostr. (Moscow), 1936, 5,
34-9 Distillation of a pure component
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N. Zh. Khim. Prom-sti, 1935, 12, 936-40
Boiling points and the vapor composition
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Phase Equilib., 2010, 290, 68 (-74)
Ethanol - Propyl Acetate Ethanol - Butyl Acetate
1 n-Ethanol 1 n-Ethanol
2 n-Propyl Acetate 2 n-Butyl Acetate
Liquid Vapor Liquid
mole mole Total mole
Temperat Temperat
No. fraction fraction pressure No. fraction
ure (K) ure (K)
ETHAN- ETHAN- (N/sqm) ETHAN-
01 01 01

1 0.0842 366.6757 0.2885 101320 1 0.032 391.2208


2 0.1016 365.8758 0.3143 101320 2 0.073 384.4221
3 0.1239 364.876 0.3444 101320 3 0.102 380.4229
4 0.1452 363.9762 0.3726 101320 4 0.152 374.5241
5 0.1626 363.1764 0.3947 101320 5 0.265 367.4255
6 0.1892 362.1766 0.4269 101320 6 0.355 362.7265
7 0.227 360.5769 0.471 101320 7 0.508 358.5274
8 0.2499 359.6771 0.495 101320 8 0.559 358.0276
9 0.2938 358.2775 0.534 101320 9 0.622 356.728
10 0.3506 356.778 0.5772 101320 10 0.685 355.4284
11 0.3854 355.9782 0.6017 101320 11 0.757 354.6286
12 0.4061 355.5783 0.6158 101320 12 0.8 354.0288
13 0.4274 355.1784 0.6297 101320 13 0.876 352.8291
14 0.453 354.7786 0.645 101320 14 0.898 352.8291
15 0.4983 354.1787 0.6699 101320 15 0.954 352.2293
16 0.5294 353.7789 0.6869 101320 1 0.0297 394.31
17 0.5479 353.5789 0.6959 101320 2 0.057 389.68
18 0.5717 353.279 0.7102 101320 3 0.0795 386.12
19 0.5984 353.0791 0.7239 101320 4 0.1013 383.05
20 0.6184 352.7792 0.734 101320 5 0.1373 378.76
21 0.6497 352.5792 0.7499 101320 6 0.1647 376.04
22 0.6771 352.3793 0.7623 101320 7 0.2043 372.77
23 0.6963 352.2793 0.7723 101320 8 0.2369 370.52
24 0.7292 352.0794 0.7909 101320 9 0.2756 368.25
25 0.7505 351.9794 0.8043 101320 10 0.3037 366.82
26 0.7845 350.9797 0.8244 101320 11 0.3284 365.7
27 0.8235 351.7795 0.8486 101320 12 0.3676 364.12
28 0.8502 351.6795 0.8665 101320 13 0.399 362.97
29 0.8839 351.6795 0.8907 101320 14 0.4187 362.32
30 0.8986 351.5795 0.9017 101320 15 0.4411 361.62
31 0.9228 351.4796 0.9224 101320 16 0.4769 360.58
1 0 374.55 0 101320 17 0.508 359.76
2 0.011 372.79 0.036 101320 18 0.5374 359.04
3 0.058 369.29 0.174 101320 19 0.566 358.37
4 0.111 365.92 0.303 101320 20 0.6103 357.42
5 0.166 363.05 0.396 101320 21 0.6561 356.52
6 0.214 360.59 0.464 101320 22 0.7336 355.12
7 0.279 358.89 0.532 101320 23 0.7879 354.21
8 0.315 357.65 0.568 101320 24 0.8563 353.16
9 0.357 356.41 0.602 101320 25 0.9144 352.32
10 0.425 355.3 0.638 101320 1995, 40, 1178-83 Densities and Iso
Vapor-Liquid Equilibria of Butyl Es
11 0.487 354.03 0.674 101320 (Methanoate to Butanoate) with Et
12 0.52 353.6 0.691 101320 at 101.32N.;
Shono, H.; Kanazawa, kPaHashitan
13 0.561 353.15 0.711 101320 Komatsu, H.; Hirata, M. Kogyo Ka
Zasshi, 1969, 72, 815-9 Vapor-liq
14 0.599 352.75 0.728 101320 equilibrium in extractive distillatio
15 0.634 352.41 0.746 101320 ethyl acetate + ethanol system
16 0.663 352.16 0.76 101320
17 0.694 351.93 0.776 101320
18 0.726 351.7 0.793 101320
19 0.777 351.41 0.82 101320
20 0.827 351.21 0.848 101320
21 0.847 351.12 0.864 101320
22 0.878 351.06 0.885 101320
23 0.904 351.02 0.906 101320
24 0.924 351.02 0.923 101320
25 0.951 351.04 0.947 101320
26 0.978 351.08 0.974 101320
27 1 351.33 1 101320
J. Chem. Eng., 1987, 65, 982-990 Vapor-
Liquid Equilibrium of the Binary Mixtures
CnH2n+2(OH) (n=2,3,4) + Propyl
Ethanoate and + Ethyl Propanoate
Thermodynamic study on binary mixtures
of propyl ehtanoate and an alkan-1-ol (C2-
C4). Isobaric vapor-liquid equilibria and
excess properties
ate Methanol - Pentane Methanol - Heptane
1 Methanol 1 Methanol
2 n-Pentane 2 n-Heptane
Vapor Liquid Vapor
mole Total mole mole Total
Temperat
fraction pressure No. fraction fraction pressure No.
ure (K)
ETHAN- (N/sqm) METHA- METHA- (N/sqm)
01 01 01

0.286 101325 1 0.001 307.6522 0.02 99990 1


0.386 101325 2 0.003 306.6126 0.05 99990 2
0.487 101325 3 0.009 305.0932 0.102 99990 3
0.616 101325 4 0.011 304.1136 0.139 99990 4
0.73 101325 5 0.021 303.6738 0.16 99990 5
0.795 101325 6 0.037 303.5138 0.167 99990 6
0.85 101325 7 0.05 303.4939 0.171 99990 7
0.851 101325 8 0.119 303.234 0.186 99990 8
0.864 101325 9 0.197 303.214 0.188 99990 9
0.887 101325 10 0.385 303.2939 0.194 99990 1
0.904 101325 11 0.603 303.3139 0.217 99990 2
0.915 101325 12 0.75 303.5938 0.244 99990 3
0.943 101325 13 0.865 305.1132 0.304 99990 4
0.953 101325 14 0.924 308.8917 0.385 99990 5
0.978 101325 15 0.961 315.1694 0.5 99990 6
0.1721 101320 16 0.968 317.6486 0.532 99990 7
0.3002 101320 17 0.974 319.1682 0.553 99990 8
0.3829 101320 18 0.98 322.1473 0.597 99990 9
0.4484 101320 19 0.987 325.8862 0.682 99990 10
0.5329 101320 20 0.991 329.2052 0.751 99990 11
0.5817 101320 21 0.993 332.1243 0.836 99990 12
0.6355 101320 22 0.999 335.344 0.95 99990 13
0.6698 101320 Tenn, F. G.; Missen, R. W. Can. J. Chem.
Eng., 1963, 41, 12 A Study of the
0.7029 101320 Condensation of Binary Vapors of Miscible
0.723 101320 Liquids equilibrium relations.
0.7378 101320
0.7592 101320
0.7746 101320
0.7833 101320
0.7937 101320
0.8088 101320
0.8199 101320
0.8299 101320
0.8392 101320
0.8538 101320
0.869 101320
0.8909 101320
0.9064 101320
0.9315 101320
0.9508 101320
, 1178-83 Densities and Isobaric
Liquid Equilibria of Butyl Esters
oate to Butanoate) with Ethanol
at 101.32N.;
H.; Kanazawa, kPaHashitani, M.;
u, H.; Hirata, M. Kogyo Kagaku
, 1969, 72, 815-9 Vapor-liquid
ium in extractive distillation of
yl acetate + ethanol system
Methanol - Heptane Methanol - Octane
1 Methanol
n-Heptane 2 n-Octane
Liquid Vapor Liquid Vapor
mole mole Total mole mole Total
Temperat Temperat
fraction fraction pressure No. fraction fraction pressure
ure (K) ure (K)
METHA- METHA- (N/sqm) METHA- METHA- (N/sqm)
01 01 01 01

0 371.5538 0 101320 1 0 398.7193 0 101320


0.138 333.724 0.72 101320 2 0.05 345.1315 0.83 101320
0.178 332.5942 0.733 101320 3 0.1 339.3331 0.865 101320
0.39 332.0543 0.739 101320 4 0.2 336.7836 0.884 101320
0.668 331.9444 0.746 101320 5 0.3 336.1838 0.893 101320
0.81 331.9344 0.748 101320 6 0.4 336.0838 0.895 101320
0.885 332.1343 0.765 101320 7 0.5 335.9838 0.895 101320
0.946 333.024 0.809 101320 8 0.6 335.8838 0.895 101320
1 337.634 1 101320 9 0.7 335.8338 0.895 101320
0 371.5247 0 101320 10 0.8 335.8838 0.895 101320
0.05 339.1332 0.67 101320 11 0.9 336.0838 0.896 101320
0.1 334.0342 0.721 101320 12 0.95 336.4837 0.914 101320
0.2 332.4345 0.734 101320 13 1 337.8334 1 101320
0.3 332.2346 0.736 101320
Budantseva, L. S.; Lesteva, T. M.;
0.4 332.0346 0.739 101320 Nemtsov, M. S. Zh. Fiz. Khim., 1975, 49,
0.5 331.9346 0.741 101320 1844
0.6 331.9346 0.743 101320
0.7 331.9346 0.746 101320
0.8 331.9346 0.748 101320
0.9 331.9846 0.771 101320
Benedict, M.; Johnson, C. 0.815
0.95 333.5343 101320
A.; Solomon, E.;
Rubin, L.1 C.337.8334 1 101320
Trans. Am. Inst. Chem. Eng.,
1945, 41, 371 Extractive and azeotropic
distillation II separation of toluene from
paraffins by azeotropic distillation with
methanol

Budantseva, L. S.; Lesteva, T. M.;


Nemtsov, M. S. Zh. Fiz. Khim., 1975, 49,
1844
Ethanol - Hexane Ethanol - Heptane
1 n-Ethanol 1 n-Ethanol
2 n-Hexane 2 n-Heptane
Liquid Vapor Liquid
mole mole Total mole
Temperat Temperat
No. fraction fraction pressure No. fraction
ure (K) ure (K)
ETHAN- ETHAN- (N/sqm) ETHAN-
01 01 01

1 0 341.824 0 101320 1 0.005 351.6232


2 0.006 339.824 0.065 101320 2 0.013 361.223
3 0.01 336.624 0.16 101320 3 0.017 363.7231
4 0.045 333.324 0.255 101320 4 0.04 353.523
5 0.102 332.2743 0.29 101320 5 0.065 348.5235
6 0.235 331.5745 0.325 101320 6 0.094 347.6236
7 0.275 331.3745 0.33 101320 7 0.1005 346.1237
8 0.33 331.1246 0.34 101320 8 0.148 346.3237
9 0.412 331.2246 0.35 101320 9 0.24 345.3238
10 0.548 331.4745 0.36 101320 10 0.388 344.3239
11 0.667 331.8244 0.37 101320 11 0.482 344.1239
12 0.755 332.5242 0.395 101320 12 0.487 344.3239
13 0.848 334.924 0.468 101320 13 0.553 344.1239
14 0.92 339.024 0.58 101320 14 0.669 344.1239
15 0.94 340.524 0.635 101320 15 0.78 344.1239
16 0.98 346.3237 0.807 101320 16 0.791 344.1239
17 0.99 349.1234 0.905 101320 17 0.876 344.9238
18 1 351.4232 1 101320 18 0.948 345.3238
1 0 341.874 0 101325 19 0.973 347.5236
2 0.0916 332.5342 0.285 101325 20 0.997 350.0233
3 0.1979 331.6544 0.324 101325 1 0 371.1238
4 0.307 331.5145 0.329 101325 2 0.01 365.1932
5 0.4012 331.6444 0.343 101325 3 0.025 358.163
6 0.5001 331.8044 0.354 101325 4 0.05 351.9331
7 0.6115 332.1443 0.365 101325 5 0.075 349.4234
8 0.7035 332.8641 0.386 101325 6 0.1 348.1335
9 0.8102 334.134 0.41 101325 7 0.2 345.7437
10 0.9007 338.184 0.526 101325 8 0.3 344.9638
11 1 351.4232 1 101325
Sinor, J. E.; Weber, J. H. J. Chem. Eng. 9 0.4 344.6139
Data, 1960, 5, 243 Vapor-Liquid Equilibria 10 0.5 344.4039
at Atmospheric Pressure. Systems
Containing Ethyl Alcohol, n-Hexane, 11 0.6 344.3439
Benzene, andL.Methylcyclopentane
Kudryavtseva, S.; Susarev, M. P. Zh. 12 0.7 344.3739
Prikl. Khim. (Leningrad), 1963, 36, 1471 13 0.8 344.6938
Liquid-vapor equilibrium in the systems
acetone-hexane and hexane-ethyl alcohol 14 0.9 345.7737
at 35, 45, and 55 deg. and 760 mm of Hg. 15 0.95 347.4336
16 0.975 348.9034
17 1 351.4232
1 0.0047 368.95
2 0.0108 365.72
3 0.0291 358.49
4 0.0492 354.3
5 0.1215 347.74
6 0.2621 345.34
7 0.3358 344.92
8 0.4059 344.66
9 0.5416 344.39
10 0.6188 344.35
11 0.7288 344.39
12 0.8248 344.71
13 0.9346 346.5
14 0.9748 348.81
15 0.9936 350.87
Katz, K.; Newman, M. Ind. Eng. Ch
1956, 48, 137-41 Vapor-liquid equ
for ethyl alcohol - n-heptane at l
pressure
Van Ness, H. C.; Soczek, C. A.; Koch
K. J. Chem. Eng. Data, 1967, 12, 34
Thermodynamic excess propertie
ethanol - n-heptane

Wang, Q.; Chen, G.; Han, S. Ranti


Hwaxue Xuebae - Journal of Fu
Chemistry and Technology, 1990,
Ethanol - Octane Methanol - Benzene
1 n-Ethanol 1 Methanol
2 n-Octane 2 n-Benzene
Vapor Liquid Vapor
mole Total mole mole Total
Temperat
fraction pressure No. fraction fraction pressure No.
ure (K)
ETHAN- (N/sqm) ETHAN- ETHAN- (N/sqm)
01 01 01

0.515 101325 1 0.087 372.5245 0.65 101320 1


0.33 101325 2 0.25 355.7283 0.8 101320 2
0.19 101325 3 0.508 351.4296 0.805 101320 3
0.475 101325 4 0.571 350.9297 0.808 101320 4
0.543 101325 5 0.606 349.3302 0.819 101320 5
0.557 101325 6 0.805 349.83 0.82 101320 6
0.572 101325 7 0.833 349.7301 0.83 101320 7
0.587 101325 8 0.925 350.03 0.881 101320 8
0.612 101325 9 0.988 351.2296 0.966 101320 9
0.629 101325 1 0.0716 359.28 0.7141 101300 10
0.636 101325 2 0.1087 355.599 0.7517 101300 11
0.632 101325 3 0.2013 352.433 0.7842 101300 12
0.638 101325 4 0.2219 352.222 0.788 101300 13
0.655 101325 5 0.2738 351.537 0.7952 101300 14
0.66 101325 6 0.3527 351.424 0.7985 101300 15
0.668 101325 7 0.4385 350.753 0.8098 101300 16
0.706 101325 8 0.4665 350.73 0.8108 101300 17
0.793 101325 9 0.5001 350.452 0.8142 101300 1
0.865 101325 10 0.5378 350.47 0.8216 101300 2
0.967 101325 11 0.6229 350.194 0.8287 101300 3
0 101320 12 0.6939 349.981 0.8295 101300 4
0.1669 101320 13 0.712 350.002 0.83 101300 5
0.3371 101320 14 0.7717 349.869 0.8396 101300 6
0.4667 101320 15 0.8148 349.792 0.8486 101300 7
0.511 101320 16 0.8506 349.773 0.8577 101300 8
0.5396 101320 17 0.8822 349.811 0.8661 101300 9
0.5853 101320 18 0.9105 349.918 0.884 101300 10
0.6029 101320 19 0.9497 350.16
Koshel'kov, 0.9159 T. G.;
V. A.; Pavlenko, 101300 11
0.614 101320 20 Timofeev,
0.9557 V.350.233
S.; Serafimov, L. A. Tr.101300
0.9216 Altai. 12
0.625 101320 Politekh. Inst. im. I. I. Polzunova, 1974, , 13
74-83 Phase equilibriums in the water +
0.6302 101320 aliphatic alcolhols (c(1)-c(3)) paraffinic 14
0.6495 101320 hydrocarbons
Hiaki, (c(6)-c(10))
T.; Takahashi, K.; Tsuji,systems.
T.; Hongo, 15
0.6834 101320 M.; Kojima, K. J. Chem. Eng. Data, 1994, 16
39, 720-722 Vapor-Liquid Equilibria of
0.7449 101320 Ethanol with 2,2,4-Trimethylpentane or 17
0.8214 101320 Octane at 101.3 kPa 18
0.8869 101320 19
1 101320 20
0.0623 101000 21
0.1528 101000 1
0.3188 101000 2
0.4059 101000 3
0.5323 101000 4
0.5899 101000 5
0.605 101000 6
0.6188 101000 7
0.6398 101000 8
0.6504 101000 9
0.6703 101000 10
0.7003 101000 11
0.7882 101000 12
0.8931 101000 13
0.9772 101000 14
; Newman, M. Ind. Eng. Chem., 15
8, 137-41 Vapor-liquid equilibria
hyl alcohol - n-heptane at low 16
pressure 17
s, H. C.; Soczek, C. A.; Kochar, N. 18
m. Eng. Data, 1967, 12, 346-51
odynamic excess properties for 19
ethanol - n-heptane 20
21
, Q.; Chen, G.; Han, S. Rantiae
xue Xuebae - Journal of Fuel 22
ry and Technology, 1990, 18, 2 23
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Methanol - Benzene Methanol - Toluene
1 Methanol
n-Benzene 2 n-Toluene
Liquid Vapor Liquid Vapor
mole mole Total mole mole Total
Temperat Temperat
fraction fraction pressure No. fraction fraction pressure
ure (K) ure (K)
METHA- METHA- (N/sqm) METHAN METHAN (N/sqm)
01 01 OL OL

0 351.1232 0 101320 1 0.006 376.7247 0.172 101000


0.0001 350.7232 0.21 101320 2 0.037 357.523 0.557 101000
0.025 340.424 0.423 101320 3 0.097 344.6239 0.736 101000
0.05 333.924 0.495 101320 4 0.147 342.024 0.758 101000
0.07 331.7244 0.575 101320 5 0.299 339.524 0.794 101000
0.077 335.924 0.525 101320 6 0.34 338.824 0.795 101000
0.134 331.8244 0.557 101320 7 0.525 338.024 0.813 101000
0.17 331.4245 0.57 101320 8 0.637 337.624 0.818 101000
0.18 330.9247 0.572 101320 9 0.771 336.924 0.837 101000
0.34 331.1246 0.585 101320 10 0.842 336.824 0.859 101000
0.365 332.9241 0.57 101320 11 0.899 336.724 0.887 101000
0.625 330.6248 0.61 101320 12 0.914 337.324 0.958 101000
0.73 330.8247 0.639 101320 13 0.943 336.824 0.922 101000
0.776 332.4242 0.735 101320 14 0.966 337.124 0.949 101000
0.812 331.6245 0.685 101320 1 0.03 356.223 0.627 101320
0.86 332.3242 0.72 101320 2 0.08 347.6236 0.717 101320
0.977 335.974 0.92 101320 3 0.132 342.324 0.751 101320
0 353.223 0 101000 4 0.277 339.924 0.785 101320
0.0015 352.5231 0.0155 101000 5 0.427 337.724 0.808 101320
0.0075 347.2236 0.152 101000 6 0.56 338.224 0.818 101320
0.0175 347.4236 0.149 101000 7 0.635 337.924 0.827 101320
0.0623 335.824 0.4617 101000 8 0.677 337.724 0.833 101320
0.095 334.424 0.485 101000 9 0.77 337.424 0.849 101320
0.1565 333.024 0.516 101000 10 0.79 337.424 0.851 101320
0.222 332.7241 0.5395 101000 11 0.888 336.924 0.88 101320
0.3145 331.3245 0.5855 101000 12 0.953 336.924 0.93 101320
0.411 331.3245 0.5795 101000 13 0.965 337.624 0.948 101320
0.505 331.1246 0.5935 101000 14 0.973 337.824 0.955 101320
0.6375 331.2246 0.6135 101000 1 0 383.7261 0 101320
0.6565 331.2246 0.6175 101000 2 0.046 363.023 0.519 101320
0.756 331.3245 0.6555 101000 3 0.058 357.923 0.627 101320
0.8135 332.0243 0.6915 101000 4 0.07 353.523 0.704 101320
0.905 334.224 0.7995 101000 5 0.094 347.8735 0.777 101320
0.974 336.724 0.944 101000 6 0.114 344.4239 0.793 101320
0.9915 337.424 0.9735 101000 7 0.132 342.824 0.801 101320
0.992 337.424 0.977 101000 8 0.234 339.874 0.813 101320
0.9965 337.824 0.9935 101000 9 0.33 338.874 0.822 101320
1 337.824 1 101000 10 0.439 338.224 0.828 101320
0.002 350.9832 0.041 101000 11 0.675 337.274 0.842 101320
0.0028 350.7732 0.066 101000 12 0.83 336.824 0.866 101320
0.003 350.6432 0.0684 101000 13 0.87 336.724 0.878 101320
0.003 350.4033 0.0812 101000 14 0.93 336.824 0.912 101320
0.0041 350.3433 0.082 101000 15 0.974 337.224 0.957 101320
0.0055 349.1734 0.1172 101000 16 1 337.724 1 101320
0.0056 349.3934 0.106 101000 1 0.002 382.1226 0.034 101320
0.0058 348.4235 0.1386 101000 2 0.0038 381.0728 0.0573 101320
0.0134 346.9036 0.1924 101000 3 0.0062 380.053 0.08 101320
0.019 346.1837 0.206 101000 4 0.0078 379.1232 0.102 101320
0.02 346.2237 0.197 101000 5 0.01 376.9236 0.145 101320
0.0276 344.0839 0.2658 101000 6 0.01 377.2036 0.1427 101320
0.046 341.074 0.3392 101000 7 0.0109 376.2238 0.1656 101320
0.048 340.884 0.3436 101000 8 0.0128 375.124 0.1881 101320
0.048 340.874 0.344 101000 9 0.0144 374.1742 0.211 101320
0.083 337.144 0.43 101000 10 0.0159 373.1244 0.2312 101320
0.1437 334.204 0.4998 101000 11 0.018 370.2949 0.2512 101320
0.17 334.164 0.518 101000 12 0.0193 371.3147 0.268 101320
0.1858 333.044 0.5212 101000 13 0.0222 369.2252 0.307 101320
0.276 332.5242 0.5442 101000 14 0.0232 368.7253 0.3818 101320
0.364 331.5545 0.5736 101000 15 0.0254 367.2755 0.3443 101320
0.4558 331.2746 0.587 101000 16 0.0275 366.8956 0.365 101320
0.524 331.1646 0.5981 101000 17 0.0313 364.1262 0.405 101320
0.597 331.0946 0.6114 101000 18 0.0323 364.0762 0.4128 101320
0.637 331.0946 0.62 101000 19 0.0333 363.0264 0.426 101320
0.6739 331.1046 0.629 101000 20 0.0345 362.2266 0.44 101320
0.68 331.1146 0.6322 101000 21 0.036 362.0766 0.4406 101320
0.7024 331.1446 0.6408 101000 22 0.039 360.157 0.474 101320
0.7071 331.1846 0.6416 101000 23 0.0447 358.9473 0.495 101320
0.7298 331.2546 0.6509 101000 24 0.046 358.7274 0.4983 101320
0.744 331.3445 0.6531 101000 25 0.0468 358.4375 0.505 101320
0.7768 331.5745 0.6691 101000 26 0.05 357.2278 0.5218 101320
0.8031 331.7744 0.6838 101000 27 0.052 356.2781 0.53 101320
0.838 332.1143 0.708 101000 28 0.0528 356.1282 0.5358 101320
0.8754 332.7241 0.748 101000 29 0.06 354.4487 0.5615 101320
0.8998 333.304 0.7742 101000 30 0.07 352.2793 0.5915 101320
0.9178 333.724 0.8002 101000 31 0.077 351.3496 0.6135 101320
0.925 334.024 0.8118 101000 32 0.0775 351.1297 0.6158 101320
0.9424 334.724 0.851 101000 33 0.0808 350.2799 0.627 101320
0.9652 335.724 0.8998 101000 34 0.084 349.6301 0.637 101320
0.9849 336.694 0.9492 101000 35 0.086 348.6604 0.6384 101320
0.988 336.844 0.9572 101000 36 0.094 348.0506 0.66 101320
0.989 336.904 0.961 101000 37 0.094 348.2305 0.6593 101320
0.9918 337.074 0.9684 101000 38 0.1 347.2008 0.672 101320
0.9949 337.334 0.9799 101000 39 0.1008 346.9409 0.677 101320
0.026 343.8019 0.267 101000 40 0.103 346.601 0.68 101320
0.05 339.5731 0.371 101000 41 0.1082 346.1312 0.6868 101320
0.088 336.0038 0.457 101000 42 0.11 345.5813 0.6888 101320
0.164 333.3343 0.526 101000 43 0.1185 345.1514 0.7025 101320
0.333 331.7746 0.559 101000 44 0.1335 344.4117 0.718 101320
0.549 331.1548 0.595 101000 45 0.1335 344.4317 0.7179 101320
0.699 331.2348 0.633 101000 46 0.136 344.0518 0.7198 101320
0.782 331.6047 0.665 101000 47 0.14 343.6319 0.726 101320
0.898 333.0344 0.76 101000 48 0.15 343.1421 0.7341 101320
0.973 335.8438 0.907 101000 49 0.1501 342.9821 0.7351 101320
0.019 349.6301 0.128 101000 50 0.1622 342.1723 0.746 101320
0.028 344.2317 0.263 101000 51 0.1623 342.0324 0.7465 101320
0.088 335.8338 0.456 101000 52 0.165 341.5325 0.7482 101320
0.109 335.134 0.475 101000 53 0.1738 341.1327 0.7541 101320
0.179 333.0344 0.53 101000 54 0.1858 341.0227 0.762 101320
0.226 332.4345 0.538 101000 55 0.193 340.8327 0.7662 101320
0.311 332.2346 0.554 101000 56 0.2161 340.1629 0.776 101320
0.399 331.7347 0.566 101000 57 0.228 339.963 0.78 101320
0.438 331.5347 0.573 101000 58 0.24 339.6431 0.7842 101320
0.529 331.5347 0.597 101000 59 0.26 339.2531 0.791 101320
0.575 331.4347 0.603 101000 60 0.2602 339.1332 0.7912 101320
0.634 331.5347 0.615 101000 61 0.2882 338.8032 0.7955 101320
0.715 331.5347 0.643 101000 62 0.29 338.6933 0.796 101320
0.811 332.0346 0.694 101000 63 0.295 338.1834 0.8028 101320
0.866 332.8344 0.737 101000 64 0.33 337.8334 0.8031 101320
0.912 333.8342 0.795 101000 65 0.44 337.4535 0.81 101320
0.939 334.834 0.831 101000 66 0.54 337.4335 0.8173 101320
0.97 336.0338 0.896 101000 67 0.66 337.1736 0.8255 101320
0 353.289 0 101000 68 0.664 337.1336 0.826 101320
0.055 346.1811 0.305 101000 69 0.7242 337.0336 0.8356 101320
0.0975 335.3839 0.415 101000 70 0.767 336.8836 0.845 101320
0.135 334.2941 0.4955 101000 71 0.795 336.9136 0.8494 101320
0.1975 332.5245 0.512 101000 72 0.8152 336.7736 0.8563 101320
0.3125 332.2945 0.5725 101000 73 0.849 336.7436 0.866 101320
0.5025 331.1648 0.615 101000 74 0.863 336.7237 0.8757 101320
0.5935 330.9048 0.6263 101000 75 0.878 336.7137 0.8795 101320
0.695 330.9148 0.64 101000 76 0.89 336.7237 0.8876 101320
0.7975 331.4647 0.6675 101000 77 0.901 336.7237 0.8935 101320
0.8445 332.1846 0.6975 101000 78 0.912 336.7337 0.9 101320
0.9113 333.5243 0.7775 101000 79 0.9248 336.8236 0.909 101320
0.95 335.5139 0.892 101000 80 0.935 336.8336 0.9175 101320
1 337.6335 1 101000 81 0.942 336.8836 0.9237 101320
0 353.229 0 101320 82 0.95 337.0236 0.935 101320
0.05 341.6325 0.344 101320 83 0.96 337.1136 0.9422 101320
0.1 336.4337 0.454 101320 84 0.9673 337.1436 0.951 101320
0.2 332.8344 0.522 101320 85 0.9732 337.2136 0.9584 101320
0.3 331.8346 0.544 101320 1 0 383.7223 0 101320
0.4 331.4347 0.566 101320 2 0.0098 372.6245 0.2329 101320
0.5 331.2348 0.587 101320 3 0.0112 370.025 0.2741 101320
0.6 331.0348 0.608 101320 4 0.0144 368.9252 0.3047 101320
0.7 331.1348 0.635 101320 5 0.0168 366.7257 0.3437 101320
0.8 331.8346 0.691 101320 6 0.0207 364.5261 0.3999 101320
0.9 333.2344 0.781 101320 7 0.0225 361.0268 0.4575 101320
0.95 334.834 0.858 101320 8 0.0228 362.8264 0.4342 101320
1 337.8334 1 101320 9 0.0234 363.1264 0.4232 101320
0.01 350.1599 0.11 101320 10 0.0261 360.4269 0.4703 101320
0.054 339.0732 0.39 101320 11 0.0286 358.9273 0.495 101320
0.102 334.874 0.485 101320 12 0.0303 358.6274 0.4976 101320
0.165 333.1544 0.525 101320 13 0.0358 357.3278 0.5174 101320
0.26 331.9946 0.556 101320 14 0.0388 356.628 0.5377 101320
0.346 331.6147 0.568 101320 15 0.0449 354.6286 0.5702 101320
0.408 331.4347 0.578 101320 16 0.0589 350.3299 0.6232 101320
0.474 331.2547 0.588 101320 17 0.0711 346.731 0.6652 101320
0.551 331.1848 0.602 101320 18 0.0823 345.9312 0.6808 101320
0.622 331.1048 0.612 101320 19 0.1094 344.4317 0.7116 101320
0.633 331.1248 0.619 101320 20 0.1264 343.232 0.7315 101320
0.706 331.2148 0.64 101320 21 0.192 341.1327 0.7566 101320
0.738 331.2847 0.65 101320 22 0.2941 339.5331 0.7817 101320
0.807 331.7247 0.685 101320 23 0.3244 338.5333 0.7959 101320
0.882 332.7544 0.748 101320 24 0.4592 338.4333 0.8073 101320
0.927 333.8342 0.806 101320 25 0.5038 338.1334 0.8 101320
0.956 334.994 0.868 101320 26 0.611 337.5335 0.8085 101320
0.01 347.1708 0.175 101000 27 0.6934 337.1336 0.8278 101320
0.01 347.1708 0.195 101000 28 0.7825 336.8336 0.8441 101320
0.01 347.1708 0.169 101000 29 0.8209 336.7337 0.8536 101320
0.046 339.853 0.354 101000 30 0.8589 336.6337 0.8755 101320
0.05 339.853 0.36 101000 31 0.9053 336.6337 0.8936 101320
0.052 339.853 0.352 101000 32 0.9343 336.7337 0.9173 101320
0.1 334.2941 0.482 101000 33 0.9534 336.8336 0.9366 101320
0.11 334.2941 0.484 101000 34 0.9712 336.8336 0.9541 101320
0.115 334.2941 0.476 101000 35 0.9862 336.9336 0.9769 101320
0.19 332.3645 0.534 101000 36 0.9867 337.0336 0.9765 101320
0.198 332.3645 0.534 101000 37 1 337.6335 1 101320
0.24 332.3645 0.555 101000 1 0 383.7223 0 101320
0.245 331.5847 0.558 101000 2 0.05 355.1285 0.608 101320
0.254 331.5847 0.553 101000 3 0.1 344.9315 0.723 101320
0.264 331.4647 0.56 101000 4 0.2 340.3829 0.771 101320
0.267 331.4647 0.558 101000 5 0.3 339.1832 0.791 101320
0.28 331.5847 0.559 101000 6 0.4 338.5333 0.802 101320
0.304 331.4647 0.564 101000 7 0.5 338.0334 0.812 101320
0.517 330.9848 0.598 101000 8 0.6 337.5835 0.82 101320
0.52 330.9848 0.598 101000 9 0.7 337.1836 0.827 101320
0.527 330.9848 0.607 101000 10 0.8 336.9336 0.847 101320
0.635 330.9048 0.62 101000 11 0.9 336.7337 0.888 101320
0.636 330.9048 0.622 101000 12 0.95 336.9336 0.93 101320
0.65 330.9048 0.628 101000 Lu, B. C.-Y. Can. J. Chem. Eng., 1957, 34,
468-472 Vapor-liquid equilibrium data for
0.714 331.0248 0.643 101000 systems methanol - toluene and n-
0.715 331.0248 0.643 101000 propanol - toluene
0.716 331.0248 0.644 101000
Kojima, K.; Hirata, M. Kagaku Kogaku,
0.743 331.2048 0.65 101000 1960, 24, 214-8 A modified equilibrium
0.75 331.2048 0.66 101000 still
0.75 331.2048 0.651 101000 Burke, D. E.; Williams, G. C.; Plank, C. A. J.
Chem. Eng. Data, 1964, 9, 212 Vapor-
0.768 331.3347 0.663 101000 liquid equilibria for the methanol -
0.769 331.3347 0.66 101000 toluene system
0.778 331.3347 0.664 101000
Ocon, J.; Tojo, G.; Espada, L. An. Quim.,
0.823 332.4645 0.747 101000 1969, 65, 641-8 Vapor-liquid equilibrium:
0.878 332.4645 0.742 101000 x methyl alcohol + toluene system
0.879 332.4645 0.734 101000 Kogaku, 1972, 36, 566-9 Vapor-liquid
equilibria of 1,2-dichloroethane + methyl
0.944 334.2841 0.84 101000 isobutyl ketone and methanol + toluene
0.945 334.2841 0.839 101000 systems at 760 mm hg
0.945 334.2841 0.845 101000
Budantseva, L. S.; Lesteva, T. M.;
0.055 336.5337 0.423 101000 Nemtsov, M. S. Zh. Fiz. Khim., 1975, 49,
0.089 334.0342 0.48 101000 1844
0.1285 332.8344 0.5145 101000
0.154 332.5345 0.525 101000
0.2725 331.9346 0.55 101000
0.34 331.7347 0.5635 101000
0.384 331.6347 0.573 101000
0.45 331.6347 0.5815 101000
0.5255 331.5347 0.5975 101000
0.612 331.4347 0.612 101000
0.676 331.5347 0.625 101000
0.745 331.6347 0.6465 101000
0.7615 331.7347 0.6525 101000
0.795 331.9346 0.6705 101000
0.83 332.3345 0.697 101000
0.861 332.7345 0.72 101000
0.8895 333.3343 0.7595 101000
0.932 334.4341 0.8205 101000
0.954 335.234 0.8665 101000
0.055 336.5337 0.423 101325
0.089 334.0342 0.48 101325
0.1285 332.8344 0.5145 101325
0.154 332.5345 0.525 101325
0.2725 331.9346 0.55 101325
0.34 331.7347 0.5635 101325
0.384 331.6347 0.573 101325
0.45 331.6347 0.5815 101325
0.5255 331.5347 0.5975 101325
0.676 331.5347 0.625 101325
0.745 331.6347 0.6465 101325
0.7615 331.7347 0.6525 101325
0.795 331.9346 0.6705 101325
0.83 332.3345 0.697 101325
0.861 332.7345 0.72 101325
0.8895 333.3343 0.7595 101325
0.932 334.4341 0.8205 101325
0.954 335.234 0.8665 101325
0.023 344.7016 0.256 101325
0.04 340.6128 0.378 101325
0.064 337.6735 0.432 101325
0.075 336.9036 0.443 101325
0.076 336.8536 0.446 101325
0.076 336.8736 0.439 101325
0.081 336.4737 0.472 101325
0.334 331.7946 0.565 101325
0.86 332.5445 0.727 101325
0.94 334.6241 0.833 101325
0.946 334.744 0.833 101325
0 353.229 0 101320
0.03 340.6328 0.344 101320
0.033 340.6328 0.341 101320
0.045 338.1334 0.408 101320
0.05 338.1334 0.406 101320
0.08 335.7339 0.461 101320
0.083 335.7339 0.46 101320
0.105 334.5841 0.495 101320
0.106 334.5841 0.487 101320
0.15 333.2843 0.526 101320
0.15 333.2843 0.521 101320
0.239 332.3345 0.554 101320
0.24 332.3345 0.561 101320
0.284 331.8346 0.568 101320
0.285 331.8346 0.572 101320
0.348 331.4847 0.575 101320
0.352 331.4847 0.569 101320
0.414 331.3347 0.582 101320
0.422 331.3347 0.586 101320
0.482 331.1348 0.592 101320
0.483 331.1348 0.596 101320
0.535 331.0348 0.598 101320
0.538 331.0348 0.6 101320
0.573 331.0348 0.606 101320
0.577 331.0348 0.614 101320
0.654 331.0348 0.621 101320
0.663 331.0348 0.63 101320
0.691 331.0848 0.632 101320
0.697 331.0848 0.636 101320
0.726 331.1348 0.645 101320
0.733 331.1348 0.653 101320
0.758 331.3347 0.659 101320
0.763 331.3347 0.664 101320
0.789 331.5347 0.671 101320
0.792 331.5347 0.677 101320
0.82 331.7846 0.687 101320
0.822 331.7846 0.69 101320
0.849 332.1346 0.716 101320
0.851 332.1346 0.723 101320
0.888 332.8344 0.756 101320
0.888 332.8344 0.754 101320
0.916 333.5843 0.792 101320
0.917 333.5843 0.795 101320
0.949 334.6341 0.855 101320
0.95 334.6341 0.853 101320
0.988 336.8336 0.96 101320
0.988 336.8336 0.959 101320
1 337.8334 1 101320
0.0493 339.5 0.385 101300
0.099 335.5 0.485 101300
0.147 332.9 0.551 101300
0.196 331.9 0.555 101300
0.249 331.2 0.575 101300
0.299 330.9 0.583 101300
0.396 330.6 0.595 101300
0.5 330.5 0.605 101300
0.598 330.5 0.62 101300
0.699 330.5 0.64 101300
0.746 330.4 0.65 101300
0.787 330.9 0.672 101300
0.912 332.1 0.74 101300
0.956 333.9 0.82 101300
0.075 336.31 0.449 101300
0.092 335.36 0.474 101300
0.129 333.9 0.503 101300
0.155 333.35 0.521 101300
0.221 332.41 0.541 101300
0.26 332.09 0.552 101300
0.308 331.82 0.565 101300
0.347 331.67 0.571 101300
0.381 331.54 0.575 101300
0.409 331.45 0.578 101300
0.458 331.3 0.586 101300
0.483 331.25 0.59 101300
0.54 331.17 0.602 101300
0.552 331.14 0.602 101300
0.564 331.12 0.605 101300
0.575 331.12 0.607 101300
0.58 331.11 0.607 101300
0.608 331.1 0.613 101300
0.615 331.11 0.615 101300
0.618 331.11 0.615 101300
0.636 331.12 0.62 101300
0.639 331.11 0.62 101300
0.642 331.12 0.622 101300
0.654 331.12 0.624 101300
0.655 331.14 0.624 101300
0.658 331.13 0.625 101300
0.669 331.13 0.629 101300
0.676 331.14 0.63 101300
0.684 331.16 0.634 101300
0.691 331.17 0.635 101300
0.695 331.18 0.638 101300
0.725 331.26 0.647 101300
0.803 331.71 0.684 101300
0.838 332.06 0.708 101300
0.877 332.67 0.745 101300
0.911 333.46 0.786 101300
0.932 334.07 0.818 101300
0.956 335.01 0.865 101300
0 353.25 0 101325
0.041 340.58 0.345 101325
0.067 337.5 0.418 101325
0.091 335.35 0.47 101325
0.119 334.24 0.493 101325
0.152 333.25 0.519 101325
0.177 332.88 0.528 101325
0.212 332.44 0.542 101325
0.243 332.13 0.548 101325
0.29 331.8 0.556 101325
0.327 331.63 0.563 101325
0.374 331.48 0.57 101325
0.416 331.34 0.577 101325
0.471 331.2 0.587 101325
0.52 331.11 0.595 101325
0.568 331.04 0.603 101325
0.574 331.04 0.603 101325
0.596 331.02 0.61 101325
0.613 331.03 0.615 101325
0.632 331.03 0.621 101325
0.652 331.05 0.624 101325
0.685 331.09 0.631 101325
0.762 331.29 0.661 101325
0.812 331.63 0.687 101325
0.852 332.07 0.72 101325
0.901 332.98 0.774 101325
0.951 334.6 0.853 101325
1 337.66 1 101325

Williams, G. C.; Rosenberg, S.; Rothenberg, H. A. Ind. Eng. Chem., 1948, 40, 1273 Physical Properties of Benzene-Methanol
Wehe, A. H.; Coates, J. AIChE J., 1955, 1, 241 Vapor-liquid equilibrium relations predicted by thermodynamic examinations
Ocon, J.; Espantoso, J. An. R. Soc. Esp. Fis. Quim., B, 1958, 54, 421-30 Vapor-liquid equilibrium: IV methanol + benzene and
Hudson, J. W.; Van Winkle, M. J. Chem. Eng. Data, 1969, 14, 310-318 Multicomponent vapor-liquid equilibriums in systems
Nagata, I. J. Chem. Eng. Data, 1969, 14, 418-20 Vapor-Liquid Equilibrium Data for the Binary Systems Methanol-Benzene an
Vilcu, R.; Cenuse, Z. Rev. Roum. Chim., 1971, 16, 1635 Vapour-liquid equilibrium still
Budantseva, L. S.; Lesteva, T. M.; Nemtsov, M. S. Zh. Fiz. Khim., 1975, 49, 260-1 Liquid-vapor equilibriums in methanol-C6 h
Triday, J. O.; Andrade, A.; Aguirre-Ode, F. Scientia (Valparaiso), 1978, 43, 1

Cabezas, J. L.; Arranz, J. C.; Berrueta, J. Rev. Roum. Chim., 1985, 30, 903 Binary vapor-liquid equilibria of benzene-alcohol s
Gabezas, J. I.; Arranz, J. C.; Berrueta, J. Rev. Roum. Chim., 1985, 30, 903
Luo, C. W.; Weber, J. H.; Tao, L. C. J. Chem. Thermodyn., 1985, 17, 1097 Vapor-liquid equilibria of (methanol + methylcyclo
Cabezas, J. L.; Beltran, S.; Coca, J. Unpublished data, (1987)
Dharmendira Kumar, M.; Rajendran, M. J. Chem. Eng. Jpn., 1998, 31, 749-757 Effect of Dissolved Salts on the Vapor-Liquid
Kurihara, K.; Hori, H.; Kojima, K. J. Chem. Eng. Data, 1998, 43, 264-268 Vapor-Liquid Equilibrium Data for Acetone + Methan
Hiaki, T.; Kawai, A. Fluid Phase Equilib., 1999, 158-60, 979-89 Vapor-liquid equilibria determination for a hydrofluoroether
Methanol - p-Xylene Methanol - m-Xylene
1 Methanol 1 Methanol
2 p-Xylene 2 m-Xylene
Liquid Vapor Liquid
mole mole Total mole
Temperat Temperat
No. fraction fraction pressure No. fraction
ure (K) ure (K)
METHAN METHAN (N/sqm) METHAN
OL OL OL

1 0 411.4167 0 101320 1 0 412.1166


2 0.05 362.7265 0.784 101320 2 0.05 364.1262
3 0.1 350.9297 0.865 101320 3 0.1 351.8294
4 0.2 344.6316 0.901 101320 4 0.2 344.8315
5 0.3 342.2823 0.907 101320 5 0.3 341.9324
6 0.4 340.7328 0.909 101320 6 0.4 340.3329
7 0.5 339.833 0.91 101320 7 0.5 339.7331
8 0.6 339.4331 0.914 101320 8 0.6 339.3331
9 0.7 338.9832 0.919 101320 9 0.7 338.9332
10 0.8 338.5333 0.928 101320 10 0.8 338.5333
11 0.9 338.1334 0.945 101320 11 0.9 338.0834
12 0.95 337.9334 0.965 101320 12 0.95 337.7834
13 1 337.8334 1 101320 13 1 337.8334

Budantseva, L. S.; Lesteva, T. M.; Budantseva, L. S.; Lesteva, T. M


Nemtsov, M. S. Zh. Fiz. Khim., 1975, 49, Nemtsov, M. S. Zh. Fiz. Khim., 197
1844 1844
ties of Benzene-Methanol Mixtures
rmodynamic examinations of activity coefficients
V methanol + benzene and carbon tetrachloride + toluene systems
uid equilibriums in systems of mixed positive and negative deviations
ems Methanol-Benzene and Methyl Acetate-Methanol
ilibriums in methanol-C6 hydrocarbons of different classes

ibria of benzene-alcohol systems

f (methanol + methylcyclopentane)

Salts on the Vapor-Liquid Equilibrium Relationships of Three Miscible Binary Systems at the Pressure of 101.3 kPa
Data for Acetone + Methanol + Benzene, Chloroform + Methanol + Benzene, and Constituent Binary Systems at 101.3 KPa
on for a hydrofluoroether with several alcohols
e Methanol - o-Xylene Ethanol - Benzene
1 Methanol 1 n-Ethanol
2 o-Xylene 2 n-Benzene
Vapor Liquid Vapor
mole Total mole mole Total
Temperat
fraction pressure No. fraction fraction pressure No.
ure (K)
METHAN (N/sqm) METHAN METHAN (N/sqm)
OL OL OL

0 101320 1 0.0249 375.25 0.8 101300 1


0.784 101320 2 0.2176 344.65 0.9384 101300 2
0.865 101320 3 0.4933 341.55 0.9452 101300 3
0.901 101320 4 0.7674 340.45 0.9497 101300 4
0.907 101320 5 0.833 339.85 0.9565 101300 5
0.909 101320 6 0.8424 339.45 0.9531 101300 6
0.91 101320 7 0.8684 338.85 0.9568 101300 7
0.914 101320 8 0.9334 338.45 0.9682 101300 1
0.922 101320 9 0.967 338.05 0.9796 101300 2
0.934 101320 10 0.9767 337.95 0.9845 101300 3
0.949 101320 11 0.9833 337.95 0.9881 101300 4
0.965 101320 12 Costa-Lopez,
0.9878 J.; 337.85
Garvin, A.;0.991
Espana.,101300
F. J. J. 5
1 101320 Chem. Eng. Data, 1995, 40, 1067-71 6
Vapor-Liquid Equilibrium Data for
Methanol, Ethanol, Methyl Acetate, Ethyl 7
antseva, L. S.; Lesteva, T. M.;
v, M. S. Zh. Fiz. Khim., 1975, 49, Acetate, and o-Xylene at 101.3 kPa 8
1844 9
10
11
12
13
14
15
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
1
2
3
4
5
6
7
8
9
10
11
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
1
2
3
4
5
6
7
8
9
10
11
12
13
1
2
3
4
5
6
7
1
2
3
4
5
6
7
8
1
2
3
4
5
6
7
8
9
10
11
12
13
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
1
2
3
4
5
6
7
s at 101.3 KPa
Ethanol - Benzene Ethanol - Toluene
1 n-Ethanol
n-Benzene 2 n-Toluene

Liquid Vapor Liquid Vapor


Total Total
mole Temperat mole mole Temperat mole
pressure No. pressure
fraction ure (K) fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
ETHANOL ETHANOL ETHANOL ETHANOL

0.14 343.124 0.34 101000 1 0 383.7261 0 100790


0.2 342.124 0.376 101000 2 0.0666 364.1831 0.4478 100790
0.328 341.124 0.424 101000 3 0.0908 361.323 0.5083 100790
0.606 341.124 0.506 101000 4 0.0985 360.573 0.5224 100790
0.72 342.124 0.558 101000 5 0.1191 358.723 0.557 100790
0.79 343.124 0.606 101000 6 0.1576 356.523 0.5991 100790
0.879 345.1238 0.705 101000 7 0.2523 353.723 0.6536 100790
0.015 349.9233 0.117 101000 8 0.3469 352.2231 0.683 100790
0.025 348.3735 0.163 101000 9 0.4283 351.5232 0.7018 100790
0.052 346.5237 0.217 101000 10 0.489 351.0732 0.7141 100790
0.078 344.7238 0.279 101000 11 0.633 350.4233 0.7444 100790
0.135 343.124 0.335 101000 12 0.731 350.1633 0.7751 100790
0.223 341.874 0.393 101000 13 0.8082 350.1233 0.8094 100790
0.3 341.324 0.417 101000 14 0.8794 350.2733 0.8554 100790
0.4 341.024 0.443 101000 15 0.9262 350.5233 0.8975 100790
0.603 341.074 0.482 101000 16 0.9382 350.5733 0.9099 100790
0.669 341.374 0.498 101000 17 0.9545 350.7232 0.9304 100790
0.843 343.624 0.633 101000 18 1 351.4232 1 100790
0.902 345.4238 0.714 101000 1 0.1646 356.3281 0.6509 101325
0.914 345.9737 0.743 101000 2 0.3122 353.6289 0.6882 101325
0.956 348.1735 0.842 101000 3 0.3607 351.9294 0.6906 101325
0.992 350.5233 0.958 101000 4 0.4314 350.9297 0.6997 101325
0.015 349.9233 0.117 101300 5 0.4732 350.6298 0.7055 101325
0.025 348.3735 0.163 101300 6 0.5611 350.13 0.7066 101325
0.052 346.5237 0.217 101300 7 0.6666 349.6301 0.7179 101325
0.078 344.7238 0.279 101300 8 0.6928 349.6301 0.7185 101325
0.135 343.124 0.335 101300 9 0.827 350.6298 0.7804 101325
0.223 341.874 0.393 101300 10 0.9583 351.6295 0.9361 101325
0.3 341.324 0.417 101300 1 0 383.8222 0 101320
0.4 341.024 0.443 101300 2 0.0001 383.8222 0.0004 101320
0.603 341.074 0.482 101300 3 0.001 383.8222 0.004 101320
0.669 341.374 0.498 101300 4 0.02 380.9228 0.0993 101320
0.843 343.624 0.633 101300 5 0.05 374.6241 0.2803 101320
0.902 345.4238 0.714 101300 6 0.1 364.4261 0.5082 101320
0.914 345.9737 0.743 101300 7 0.15 357.4778 0.632 101320
0.956 348.1735 0.842 101300 8 0.2 352.3293 0.7048 101320
0.992 350.5233 0.958 101300 9 0.3 351.5295 0.75 101320
0 353.223 0 101391.7 10 0.4 351.3296 0.7541 101320
0.0048 351.7231 0.04 101325 11 0.5 350.9297 0.759 101320
0.0085 350.2333 0.079 101391.7 12 0.6 350.6298 0.7633 101320
0.172 342.024 0.356 101325 13 0.7 350.2299 0.7656 101320
0.3085 341.104 0.404 101325 14 0.8 350.03 0.8016 101320
0.4855 340.794 0.449 101325 15 0.85 350.03 0.8292 101320
0.7545 342.304 0.572 101325 16 0.9 350.13 0.8695 101320
0.8815 344.9838 0.703 101325 17 0.95 350.6298 0.9248 101320
0.987 350.6332 0.9545 101325 18 0.98 351.0297 0.9671 101320
0.991 350.8732 0.9685 101325 19 0.999 351.5295 0.9982 101320
1 351.4432 1 101365 20 0.9999 351.5295 0.9998 101320
0 353.223 0 101320 21 1 351.5295 1 101320
0.03 348.6734 0.142 101320 1 0 382.6225 0 100930
0.065 345.4238 0.244 101320 2 0.087 354.3287 0.525 100930
0.114 343.524 0.309 101320 3 0.219 353.6289 0.643 100930
0.216 341.824 0.374 101320 4 0.39 350.9297 0.695 100930
0.317 341.274 0.41 101320 5 0.522 350.03 0.716 100930
0.406 341.124 0.435 101320 6 0.628 349.4302 0.749 100930
0.544 341.124 0.48 101320 7 0.737 349.2302 0.775 100930
0.639 341.574 0.515 101320 8 0.817 349.1303 0.815 100930
0.749 342.524 0.575 101320 9 0.882 349.3302 0.854 100930
0.828 343.7239 0.642 101320 10 0.961 349.83 0.943 100930
0.896 345.8237 0.74 101320 11 0.973 350.13 0.95 100930
0.943 347.9235 0.837 101320 12 1 350.6298 1 100930
0.968 349.2734 0.9 101320 1 0 383.55 0 101300
0.984 350.2733 0.948 101320 2 0.0331 372.25 0.3438 101300
1 351.4232 1 101320 3 0.1276 357.95 0.5753 101300
0.027 349.2234 0.137 101350 4 0.2291 353.95 0.6557 101300
0.063 345.8237 0.248 101350 5 0.3659 352.15 0.6796 101300
0.1 343.9239 0.307 101350 6 0.4819 351.25 0.7027 101300
0.167 342.324 0.36 101350 7 0.4994 350.75 0.7248 101300
0.245 341.524 0.39 101350 8 0.6676 350.35 0.7496 101300
0.341 341.124 0.422 101350 9 0.687 350.35 0.7659 101300
0.45 341.024 0.447 101350 10 0.7199 350.25 0.7738 101300
0.578 341.124 0.478 101350 11 0.7974 349.65 0.8027 101300
0.68 341.824 0.528 101350 12 0.8142 349.75 0.8126 101300
0.766 342.624 0.566 101350 13 0.8344 349.85 0.8274 101300
0.82 343.524 0.615 101350 14 0.84 350.25 0.8346 101300
0.905 345.8237 0.725 101350 15 0.8792 350.45 0.8433 101300
0.984 350.0233 0.937 101350 16 0.9586 351.25 0.9392 101300
0 353.193 0 101320 17 1 351.35 1 101300
0.155 342.714 0.359 101320 Landwehr, J. C.; Yerazunis, S.; Steinhauser,
H. H. Chem. Eng. Data Ser., 1958, 3, 231-4
0.3 341.384 0.415 101320 Vapor-liquid equilibria of toluene - ethyl
0.5 341.224 0.471 101320 alcohol and benzene - ethyl alcohol
0.7 342.234 0.554 101320 M. G. Indian J. Technol., 1975, 13, 345
Experimemtal determination and
0.845 344.7638 0.668 101320 prediction of vapour-liquid equilibrium
1 351.4232 1 101320 data for the system ethanol + toluene
0 353.329 0 101320 Khim. (Leningrad), 1980, 53, 2115 Liquid-
vapor equilibrium in tetrahydrofuran +
0.155 342.8321 0.334 101320 ethanol and ethanol + toluene binary
0.302 341.4326 0.407 101320 mixtures.
0.501 341.2326 0.464 101320 1988, 43, 91 Isobaric vapour-liquid
equilibria of ethanol-toluene-sodium
equilibria of ethanol-toluene-sodium
0.6 341.5325 0.502 101320 acetate mixtures at various system
0.7 342.1324 0.544 101320 pressures
0.842 344.6316 0.675 101320 Data, 2012, 1, 155-165 Isobaric Vapor-
Liquid Equilibrium for Binary Systems of
1 351.5295 1 101320 Toluene + Ethanol, Toluene + Isopropanol
0.086 343.8818 0.265 101000 at (101.3, 121.3, 161.3 and 201.3) kPa
0.112 342.8821 0.282 101000
0.12 342.6822 0.308 101000
0.158 342.1823 0.335 101000
0.2 341.5825 0.368 101000
0.308 340.7828 0.41 101000
0.442 340.7828 0.446 101000
0.604 341.1826 0.505 101000
0.77 342.6822 0.59 101000
0.815 343.482 0.628 101000
0.841 343.9818 0.665 101000
0.898 345.7813 0.744 101000
0.924 346.8809 0.782 101000
0.04 344.9315 0.259 101000
0.074 343.7319 0.3 101000
0.16 342.2323 0.3655 101000
0.2255 341.8324 0.3925 101000
0.371 341.5325 0.428 101000
0.442 341.4326 0.442 101000
0.5235 341.5325 0.4555 101000
0.544 341.6325 0.4605 101000
0.6385 341.8324 0.475 101000
0.6825 342.1324 0.498 101000
0.714 342.5322 0.5235 101000
0.7475 342.8321 0.5445 101000
0.8055 343.7319 0.6 101000
0.857 344.8315 0.665 101000
0.902 346.2311 0.727 101000
0.932 347.6307 0.7935 101000
0.964 349.5301 0.883 101000
0.04 344.9315 0.259 101325
0.074 343.7319 0.3 101325
0.16 342.2323 0.3655 101325
0.2255 341.8324 0.3925 101325
0.371 341.5325 0.428 101325
0.5235 341.4326 0.4555 101325
0.544 341.6325 0.4605 101325
0.6385 341.8324 0.475 101325
0.6825 342.1324 0.498 101325
0.714 342.5322 0.5235 101325
0.7475 342.8321 0.5445 101325
0.8055 343.7319 0.6 101325
0.857 344.8315 0.665 101325
0.902 346.2311 0.727 101325
0.932 347.6307 0.7935 101325
0.964 349.5301 0.883 101325
0 353.26 0 101300
0.0029 352.25 0.0256 101300
0.0177 349.79 0.107 101300
0.044 347.31 0.1837 101300
0.1061 343.65 0.2973 101300
0.2124 341.64 0.372 101300
0.3661 340.97 0.4252 101300
0.4641 340.92 0.4511 101300
0.5666 340.97 0.4836 101300
0.6394 341.26 0.5091 101300
0.7536 342.34 0.5753 101300
0.8095 343.52 0.6216 101300
0.9111 346.33 0.7555 101300
0.957 348.53 0.8639 101300
0.9729 349.42 0.9053 101300
0.9907 350.76 0.9714 101300
1 351.31 1 101300
0.261 341.3 0.41 100000
0.367 341 0.423 100000
0.466 340.9 0.436 100000
0.502 341 0.452 100000
0.56 341.1 0.466 100000
0.593 341.5 0.485 100000
0.733 342 0.548 100000

Ellis, S. R. M. Birmingham Univ. Chem.


Eng., 1952, 3, 34 A modified 100 cc
othmer equilibrium still

Ellis, S. R. M.; Thwaites, J. M. Chem.


Process Eng. (London), 1955, 36, 358 A
small-capacity equilibrium still

Ellis, S. R. M.; Thwaites, J. M. Birmingham


Univ. Chem. Eng., 1955, 6, 78 A small
capacity equilibrium still
Wehe, A. H.; Coates, J. AIChE J., 1955, 1,
241 Vapor-liquid equilibrium relations
predicted by thermodynamic
examinations of activity coefficients
Landwehr, J. C.; Yerazunis, S.; Steinhauser,
H. H. Chem. Eng. Data Ser., 1958, 3, 231-4
Vapor-liquid equilibria of toluene - ethyl
alcohol and benzene - ethyl alcohol

Ellis, S. R. M.; Clark, M. B. Chem. Age


India, 1961, 12, 377

Morachevskii, A. G.; Zharov, V. T. Zh. Prikl.


Khim. (Leningrad), 1963, 36, 2771
Khim. (Leningrad), 1968, 41, 2032 Certain
properties of lines of constant content of
properties of lines of constant content of
a component in the vapor in ternary
systems
Data, 1972, 17, 366-9 Measurement of
isothermal vapor-liquid equilibria for
acetone + n-heptane mixtures using
modified gillespie still
Cabezas, J. L.; Arranz, J. C.; Berrueta, J.
Rev. Roum. Chim., 1985, 30, 903 Binary
vapor-liquid equilibria of benzene-alcohol
systems

Gabezas, J. I.; Arranz, J. C.; Berrueta, J.


Rev. Roum. Chim., 1985, 30, 903

Wang, Q.; Chen, G.; Han, S. Rantiae


Hwaxue Xuebae - Journal of Fuel
Chemistry and Technology, 1990, 18, 2
Chen, W.-C.; Tsai, F. N. J. Chem. Eng. Data,
1995, 40, 1151-3 Isobaric Vapor-Liquid
Equilibria for Ethanol + Benzene +
Magnesium Chloride
Ethanol - p-Xylene Ethanol - o-Xylene
1 n-Ethanol 1 n-Ethanol
2 p-Xylene 2 o-Xylene

Liquid Vapor Liquid


Total
mole Temperat mole mole Temperat
No. pressure No.
fraction ure (K) fraction fraction ure (K)
(N/sqm)
ETHANOL ETHANOL ETHANOL

1 0 411.5017 0 101320 1 0.0065 410.45


2 0.057 373.7941 0.671 101320 2 0.0522 385.95
3 0.12 365.0132 0.77 101320 3 0.1094 370.45
4 0.211 359.413 0.825 101320 4 0.2511 361.25
5 0.306 357.233 0.841 101320 5 0.4866 356.95
6 0.668 353.493 0.881 101320 6 0.6769 355.15
7 0.78 352.643 0.898 101320 7 0.7677 353.45
8 0.861 352.0531 0.919 101320 8 0.8091 353.35
9 0.914 351.6931 0.94 101320 9 0.8501 353.15
10 0.942 351.5632 0.955 101320 10 0.8679 352.85
11 0.968 351.4632 0.973 101320 11 0.9059 352.45
12 0.986 351.4332 0.987 101320 12 0.9578 352.15
13 1 351.4232 1 101320 13 0.9773 351.85
1 0.008 404.93 0.189 101300 14 0.9859 351.85
2 0.031 391.42 0.479 101300 15 Costa-Lopez,
0.9952 J.; 351.45
Garvin, A.; Espana.,
3 0.082 372.38 0.734 101300 Chem. Eng. Data, 1995, 40, 1067
Vapor-Liquid Equilibrium Data f
4 0.123 366.03 0.795 101300 Methanol, Ethanol, Methyl Acetate
5 0.196 361.22 0.835 101300 Acetate, and o-Xylene at 101.3 k
6 0.255 359.31 0.847 101300
7 0.313 358.12 0.857 101300
8 0.349 357.3 0.863 101300
9 0.397 356.39 0.875 101300
10 0.464 355.72 0.881 101300
11 0.488 355.34 0.883 101300
12 0.553 354.74 0.887 101300
13 0.6 354.28 0.893 101300
14 0.65 353.89 0.898 101300
15 0.706 353.45 0.902 101300
16 0.75 353.09 0.906 101300
17 0.802 352.7 0.915 101300
18 0.85 352.32 0.927 101300
19 0.896 351.99 0.94 101300
20 0.949 351.63 0.962 101300
21 0.979 351.48 0.982 101300
Galska-Krajewska, A. Rocz. Chem., 1966,
40, 863 Vapor-liquid equilibriums in the
systems of ethanol alcohol with
ethylbenzene and p-xlylene
Loras, S. J. Chem. Eng. Data, 2004, 49,
1258-1262 Isobaric Vapor-Liquid Equilibria
for Binary and Ternary Mixtures of
Ethanol, Methylcyclohexane and p-Xylene
Methanol - diethyl ether Methanol - tetrahydrofu
1 Methanol 1 Methanol
2 Diethyl Ether 2 Tetrahydrofuran

Vapor Liquid Vapor


Total Total
mole mole Temperat mole
pressure No. pressure No.
fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
ETHANOL METH METH

0.229 101300 1 0.9803 333.8342 0.8012 101325 1


0.6591 101300 2 0.9602 329.7551 0.646 101325 2
0.8149 101300 3 0.939 326.496 0.5411 101325 3
0.8732 101300 4 0.8999 322.2773 0.4433 101325 4
0.8925 101300 5 0.7996 317.7187 0.3222 101325 5
0.9121 101300 6 0.7004 314.0898 0.272 101325 6
0.9236 101300 7 0.6004 312.3603 0.2318 101325 7
0.9291 101300 8 0.4997 310.7908 0.2175 101325 8
0.937 101300 9 0.4013 309.3712 0.1933 101325
0.9416 101300 10 0.3012 308.5614 0.1654 101325
0.9509 101300 11 0.1974 308.0516 0.1267 101325
0.974 101300 12 0.1033 307.7817 0.0833 101325
0.9852 101300 13 0.08 307.6717 0.0697 101325
0.9903 101300
Goloborodkina, R. V.; Beregovykh, V. V.;
0.9966
pez, J.; Garvin, A.; Espana.,101300
F. J. J. Babich, S. V.; Timoveev, V. S.; L'vov, S. V.
Eng. Data, 1995, 40, 1067-71 Khim. -Farm. Zh., 1981, 15, 79
r-Liquid Equilibrium Data for
l, Ethanol, Methyl Acetate, Ethyl
te, and o-Xylene at 101.3 kPa
Methanol - tetrahydrofuran Ethanol - diethyl ether
1 n-Ethanol
Tetrahydrofuran 2 Diethyl Ether
Liquid Vapor
Liquid Vapor
mole mole Total Total
Temperat mole Temperat mole
fraction fraction pressure No. pressure
ure (K) fraction ure (K) fraction
METHAN METHAN (N/sqm) (N/sqm)
ETH ETH
OL OL

0.173 333.724 0.28 99300 1 1 351.2232 1 101320


0.345 332.5242 0.409 99300 2 0.994 349.7233 0.952 101320
0.512 332.2243 0.5 99300 3 0.987 348.2235 0.901 101320
0.654 332.5242 0.595 99300 4 0.981 346.8236 0.847 101320
0.767 333.124 0.691 99300 5 0.975 345.3238 0.79 101320
0.849 334.024 0.76 99300 6 0.968 343.9239 0.729 101320
0.897 334.824 0.829 99300 7 0.962 342.624 0.669 101320
0.943 335.724 0.896 99300 8 0.955 341.324 0.617 101320
Gause, E. M.; Ernsberger, F. M. Chem. 9 0.948 340.024 0.573 101320
Eng. Data Ser., 1957, 2, 28 Vapor-liquid
equilibria in tetrahydrofuran + methanol + 10 0.942 338.824 0.541 101320
methyl borate system 11 0.935 337.624 0.502 101320
12 0.901 332.5242 0.379 101320
13 0.865 328.9253 0.296 101320
14 0.828 326.2261 0.241 101320
15 0.79 323.7268 0.203 101320
16 0.749 322.0273 0.177 101320
17 0.707 320.5278 0.159 101320
18 0.663 319.0282 0.143 101320
19 0.617 317.7286 0.128 101320
20 0.568 316.629 0.114 101320
21 0.518 315.4293 0.101 101320
22 0.464 314.2297 0.089 101320
23 0.408 313.13 0.076 101320
24 0.349 312.3303 0.064 101320
25 0.287 311.5306 0.052 101320
26 0.221 310.8309 0.04 101320
27 0.151 310.1312 0.027 101320
28 0.078 309.5314 0.014 101320
29 0 308.8317 0 101320
1 0.9977 350.7698 0.975 101325
2 0.9913 348.5904 0.8996 101325
3 0.9762 343.5119 0.7385 101325
4 0.9585 339.763 0.6374 101325
5 0.9234 332.5645 0.5065 101325
6 0.9037 328.2155 0.4433 101325
7 0.8999 328.1356 0.4398 101325
8 0.85 323.5369 0.367 101325
9 0.8073 319.938 0.2862 101325
10 0.701 316.539 0.2031 101325
11 0.6015 315.2394 0.1587 101325
12 0.425 312.3403 0.1128 101325
13 0.3311 311.7905 0.0811 101325
14 0.209 310.9407 0.062 101325
15 0.0871 308.6614 0.0305 101325
16 0.0556 308.4215 0.0247 101325
17 0.0483 308.3215 0.0207 101325
18 0.0366 308.3115 0.0148 101325
19 0.0223 308.2715 0.0091 101325
20 0.0075 307.8916 0.0031 101325
Kireev, V. A.; Khachadurova, E. M. Zh.
Prikl. Khim. (Leningrad), 1934, 7, 495-6
Boiling Points and the Vapor Composition
of the System Ethyl Alcohol and Ether

Borisova, I. A.; Erlykina, M. E. Deposited


Doc., VINITI, 1982, 308, 308-82
Ethanol - Diisopropyl ether Ethanol - Dipropyl ether
1 n-Ethanol 1 n-Ethanol
2 Diisopropyl Ether 2 Dipropyl Ether

Liquid Vapor Liquid


Total
mole Temperat mole mole Temperat
No. pressure No.
fraction ure (K) fraction fraction ure (K)
(N/sqm)
ETHANOL ETHANOL ETHANOL

1 0.1 338.45 0.162 101000 1 0.05 356.8779


2 0.143 337.8 0.209 101000 2 0.1971 350.2399
3 0.255 337.2 0.288 101000 3 0.37 347.4408
4 0.318 337.15 0.318 101000 4 0.4899 346.8209
5 0.37 337.25 0.335 101000 5 0.5144 346.691
6 0.398 337.35 0.343 101000 6 0.5275 346.631
7 0.45 337.45 0.36 101000 7 0.577 346.501
8 0.578 338.05 0.41 101000 8 0.6328 346.4511
9 0.635 338.55 0.44 101000 9 0.6867 346.531
10 0.703 339.35 0.475 101000 10 0.7456 346.721
11 0.799 341.15 0.555 101000 11 0.8176 347.1708
12 0.875 343.15 0.649 101000 12 0.8618 347.4907
13 0.908 344.45 0.707 101000 13 0.9068 348.2205
14 0.94 346.15 0.781 101000 14 0.9424 349.0903
1 0.046 339.92 0.085 101300 15 0.968 350.02
2 0.093 338.73 0.152 101300
3 0.141 337.97 0.205 101300 Ernst, P. Thesis, Technical Univer
4 0.191 337.58 0.24 101300 Dortmund, Dortmund, Germany (1
5 0.243 337.37 0.27 101300
6 0.295 337.31 0.297 101300
7 0.351 337.35 0.325 101300
8 0.402 337.47 0.349 101300
9 0.463 337.67 0.369 101300
10 0.511 337.97 0.396 101300
11 0.56 338.34 0.422 101300
12 0.611 338.8 0.448 101300
13 0.662 339.34 0.477 101300
14 0.713 340.08 0.51 101300
15 0.76 341 0.548 101300
16 0.807 342.15 0.597 101300
17 0.857 343.73 0.661 101300
18 0.911 345.76 0.744 101300
19 0.956 348.29 0.846 101300

Gonzalez-Benito, G. G.; Lopez, A. C. Rev.


Ku, H.Roum.
-C.; Tu,Chim.,
C. -H. 1992, 37, 973
Fluid Phase Equilib.,
2006, 248, 197-205 Vapor liquid equilibria
for binary and ternary mixtures of
diisopropyl ether, ethanol, and 2,2,4-
trimethylpentane at 101.3 kPa
ther Ethanol - tetrahydrofuran Methanol - Acetone
1 n-Ethanol 1 n-Methanol
2 Tetrahydrofuran 2 n-Acetone

Vapor Liquid Vapor


Total Total
mole mole Temperat mole
pressure No. pressure No.
fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
ETHANOL ETHANOL ETHANOL

0.2271 101320 1 0 338.6333 0 101320 1


0.4204 101320 2 0.0001 338.6333 0.0001 101320 2
0.5357 101320 3 0.001 338.6333 0.0009 101320 3
0.5743 101320 4 0.02 338.6533 0.019 101320 4
0.5854 101320 5 0.05 338.6833 0.0473 101320 5
0.5915 101320 6 0.1 338.7333 0.091 101320 6
0.6066 101320 7 0.15 338.8332 0.133 101320 7
0.6291 101320 8 0.2 338.9332 0.1724 101320 8
0.654 101320 9 0.25 339.2332 0.2105 101320 9
0.6837 101320 10 0.3 339.5331 0.2479 101320 1
0.7263 101320 11 0.4 340.3329 0.3195 101320 2
0.766 101320 12 0.45 340.8327 0.3499 101320 3
0.8119 101320 13 0.5 341.2326 0.3876 101320 4
0.8712 101320 14 0.6 342.4323 0.4545 101320 5
0.9292 101320 15 0.65 343.232 0.4943 101320 6
16 0.7 343.9318 0.5335 101320 7
P. Thesis, Technical University 17 0.75 344.8315 0.5769 101320 8
nd, Dortmund, Germany (1975) 18 0.8 345.8312 0.6369 101320 1
19 0.85 347.0309 0.7069 101320 2
20 0.9 348.3305 0.793 101320 3
21 0.95 349.83 0.8983 101320 4
22 0.98 350.8297 0.9617 101320 5
23 0.999 351.5295 0.9981 101320 6
24 0.9999 351.5295 0.9998 101320 7
25 1 351.5295 1 101320 8
1 0 338.7333 0 100000 1
2 0.0185 338.6333 0.021 100000 2
3 0.0501 338.5333 0.0554 100000 3
4 0.082 338.5333 0.0852 100000 4
5 0.149 338.5333 0.135 100000 5
6 0.285 339.0332 0.238 100000 6
7 0.457 340.3329 0.346 100000 7
8 0.503 340.8327 0.372 100000 8
9 0.737 344.1318 0.572 100000 9
10 0.861 346.9309 0.736 100000 10
11 0.9464 349.3302 0.885 100000 11
12 0.9828 350.5298 0.9631 100000 12
13 1 351.1297 1 100000 13
1 0.028 339.65 0.032 101300 14
2 0.064 339.35 0.069 101300 15
3 0.144 339.55 0.133 101300 16
4 0.207 339.65 0.186 101300 17
5 0.28 339.85 0.229 101300 18
6 0.356 340.55 0.28 101300 19
7 0.445 341.15 0.339 101300 20
8 0.517 341.85 0.394 101300 21
9 0.574 342.55 0.432 101300 22
10 0.653 343.55 0.496 101300 23
11 0.725 344.75 0.566 101300 24
12 0.8 346.35 0.655 101300 25
13 0.865 347.75 0.745 101300 1
14 0.94 349.85 0.869 101300 2
Khim. (Leningrad), 1980, 53, 2115 Liquid- 3
vapor equilibrium in tetrahydrofuran +
ethanol and ethanol + toluene binary 4
mixtures. 5
Data, 1984, 29, 28 - 31 Isobaric Vapor- 6
Liquid Equilibria of the
Tetrahydrofuran/Ethanol System at 25, 7
50, and 100 kPa 8
Wang, S. Lanzhou Daxue Xuebao, Ziran 9
Kexueban, 1994, 30, 68-72 Vapor-Liquid
Equilibrium Data for Tetrahyofuran- 10
Ethanol-Lithium Chloride Systems 11
12
13
14
1
2
3
4
5
6
7
8
9
10
11
12
13
1
2
3
4
5
6
7
8
9
10
11
12
13
1
2
3
4
5
1
2
3
4
5
6
7
8
9
10
11
12
1
2
3
4
5
6
7
8
1
2
3
4
5
6
7
8
9
10
11
12
1
2
3
4
5
6
7
8
9
10
11
12
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
1
2
3
4
5
6
7
8
9
10
11
12
13
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
1
2
3
4
5
6
7
8
9
10
11
12
13
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
1
2
3
4
5
1
2
3
4
5
6
7
8
9
10
11
1
2
3
4
5
6
7
8
9
10
11
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
Methanol - Acetone Methanol - 2-Butanone
n-Methanol 1 n-Methanol
n-Acetone 2 2-Butanone
Liquid Vapor Liquid Vapor
mole mole Total mole mole Total
Temperat Temperat
fraction fraction pressure No. fraction fraction pressure
ure (K) ure (K)
METHAN METHAN (N/sqm) METHAN METHAN (N/sqm)
OL OL OL OL

0.073618 328.3254 0.070222 101000 1 0.106 340.294 0.284 101320


0.121676 328.1255 0.134559 101000 2 0.2 339.344 0.392 101320
0.169189 327.8256 0.1876 101000 3 0.36 338.684 0.53 101320
0.292879 328.0255 0.266537 101000 4 0.491 338.014 0.616 101320
0.471678 328.5254 0.395233 101000 5 0.6 335.064 0.682 101320
0.559485 328.7253 0.456902 101000 6 0.692 336.734 0.736 101320
0.687266 329.925 0.526282 101000 7 0.771 335.904 0.891 101320
0.795394 331.4245 0.627789 101000 8 0.9 335.904 0.986 101320
0.944656 335.024 0.855775 101000 9 0.953 336.844 0.944 101320
0.108 329.0252 0.125 101000 1 0.076 348.4235 0.193 101320
0.2 328.8253 0.2 101000 2 0.147 345.3238 0.308 101320
0.268 328.9253 0.246 101000 3 0.197 343.8239 0.377 101320
0.475 329.4251 0.375 101000 4 0.265 341.924 0.453 101320
0.602 330.3248 0.483 101000 5 0.356 340.624 0.528 101320
0.705 331.7244 0.58 101000 6 0.498 339.024 0.622 101320
0.85 333.924 0.75 101000 7 0.622 338.224 0.695 101320
0.94 335.924 0.903 101000 8 0.747 337.524 0.777 101320
0.018 329.2252 0.024 101320 9 0.829 337.424 0.832 101320
0.05 328.7253 0.06 101320 10 0.841 337.424 0.842 101320
0.324 328.2255 0.29 101320 11 0.873 337.424 0.869 101320
0.4 329.2252 0.344 101320 12 0.936 337.524 0.926 101320
0.6 330.3248 0.484 101320 1 0.0465 348.1306 0.1585 101000
0.72 331.4245 0.58 101320 2 0.1 346.1312 0.252 101000
0.824 333.224 0.683 101320 3 0.1525 344.5316 0.3275 101000
0.952 336.024 0.86 101320 4 0.2005 343.0321 0.3855 101000
0.0009 329.2252 0.0013 101000 5 0.3095 340.4329 0.4863 101000
0.0106 329.1252 0.0119 101000 6 0.4195 338.8332 0.5724 101000
0.0539 329.0252 0.0562 101000 7 0.61 337.1336 0.6886 101000
0.0581 329.0252 0.0636 101000 8 0.6142 337.1336 0.6932 101000
0.0709 328.9253 0.0793 101000 9 0.7126 336.7337 0.7512 101000
0.0971 328.7253 0.1143 101000 10 0.8088 336.6337 0.8174 101000
0.1053 328.7253 0.1247 101000 11 0.8566 336.7337 0.856 101000
0.1323 328.6254 0.1423 101000 12 0.903 336.9336 0.8951 101000
Hill, W. D.; Van Winkle, M. Ind. Eng.
0.179 328.6254 0.188 101000 13 0.94751952,
Chem., 337.3335 0.9385
44, 208-10 101000
Vapor-liquid
0.1992 328.5254 0.1992 101000 equilibria in methanol binary systems
methanol + methyl ethyl ketone,
0.2131 328.5254 0.2082 101000 methanol + methyl propyl ketone,
0.2807 328.6254 0.2573 101000 methanol + methyl isobutyl ketone
0.3558 328.8253 0.3169 101000 Schoenborn, E. M. J. Chem. Eng. Data,
1966, 11, 331-3 Vapor-liquid equilibria of
0.4036 328.9253 0.3489 101000 methanol + methyl ethyl ketone in the
0.5198 329.5251 0.4334 101000 presence of diethyl ketone
0.5474 329.6251 0.4475 101000 Jpn., 1976, 9, 319 Vapor-liquid equilibrium
in methanol + methylethylketone and
0.5554 329.725 0.4573 101000 methanol + methylisobutylketone at 760
0.6359 330.3248 0.5118 101000 mm hg.
0.6433 330.4248 0.514 101000
0.7142 331.4245 0.581 101000
0.7945 332.6242 0.6582 101000
0.8556 333.624 0.7377 101000
0.8939 334.624 0.7931 101000
0.9168 335.124 0.8365 101000
0.9568 336.324 0.9069 101000
0 329.2252 0 101000
0.139 328.9253 0.157 101000
0.177 328.9253 0.194 101000
0.258 328.9253 0.255 101000
0.317 328.9253 0.295 101000
0.416 329.0252 0.361 101000
0.487 329.3251 0.42 101000
0.606 330.0249 0.5 101000
0.707 331.2246 0.577 101000
0.794 332.5242 0.664 101000
0.859 333.824 0.749 101000
0.919 335.324 0.839 101000
0.964 336.624 0.918 101000
1 337.724 1 101000
0.079 328.5154 0.087 100260
0.083 328.4954 0.093 100260
0.254 328.1955 0.241 100260
0.389 328.5754 0.334 100260
0.416 328.7353 0.347 100260
0.602 329.905 0.474 100260
0.637 330.2449 0.499 100260
0.771 331.7644 0.619 100260
0.799 332.4742 0.647 100260
0.833 332.994 0.705 100260
0.864 333.644 0.748 100260
0.922 335.054 0.847 100260
0.942 335.514 0.882 100260
0 329.3351 0 101000
0.046 329.0452 0.054 101000
0.105 328.6653 0.12 101000
0.16 328.4954 0.171 101000
0.244 328.4154 0.24 101000
0.313 328.5354 0.293 101000
0.421 328.9053 0.369 101000
0.499 329.3451 0.422 101000
0.599 330.0849 0.495 101000
0.712 331.2646 0.588 101000
0.81 332.7241 0.688 101000
0.909 334.904 0.823 101000
1 337.774 1 101000
0.1 328.9353 0.125 101320
0.4 329.1353 0.345 101320
0.599 330.5349 0.479 101320
0.715 332.1346 0.59 101320
0.92 335.234 0.84 101320
0 329.2152 0 101000
0.1 328.5354 0.114 101000
0.2 328.3355 0.2 101000
0.3 328.4555 0.278 101000
0.4 328.7054 0.35 101000
0.5 329.2352 0.421 101000
0.6 330.075 0.495 101000
0.7 331.0948 0.577 101000
0.8 332.5145 0.677 101000
0.9 334.6341 0.808 101000
0.95 335.9938 0.895 101000
1 337.6335 1 101000
0.092 329.4352 0.135 103330
0.34 328.8353 0.33 103330
0.54 329.5351 0.46 103330
0.655 330.7349 0.55 103330
0.738 332.0346 0.638 103330
0.794 332.8344 0.701 103330
0.89 334.834 0.826 103330
0.947 335.8338 0.901 103330
0.128 328.4954 0.145 101325
0.177 328.3855 0.194 101325
0.224 328.3555 0.23 101325
0.279 328.2955 0.273 101325
0.374 328.5454 0.337 101325
0.515 329.3552 0.439 101325
0.571 329.7651 0.478 101325
0.66 330.6249 0.535 101325
0.725 331.4847 0.595 101325
0.8 332.6645 0.672 101325
0.874 334.1542 0.778 101325
0.899 334.764 0.814 101325
0.023 329.5351 0.03 101060
0.09 329.0853 0.1 101060
0.28 328.7854 0.27 101060
0.372 328.9353 0.337 101060
0.485 329.4852 0.413 101060
0.618 330.5349 0.525 101060
0.718 331.5347 0.595 101060
0.835 333.4843 0.715 101060
0.87 334.0842 0.76 101060
0.903 334.934 0.813 101060
0.938 335.9338 0.868 101060
0.98 337.1336 0.858 101060
0 329.2152 0 101325
0.067 328.7654 0.078 101325
0.092 328.6554 0.104 101325
0.116 328.5654 0.128 101325
0.145 328.4954 0.155 101325
0.184 328.4555 0.19 101325
0.199 328.4455 0.203 101325
0.239 328.4455 0.235 101325
0.286 328.4954 0.271 101325
0.338 328.6254 0.309 101325
0.407 328.8753 0.358 101325
0.495 329.3452 0.417 101325
0.567 329.855 0.471 101325
0.64 330.4849 0.525 101325
0.708 331.2547 0.582 101325
0.768 332.0846 0.641 101325
0.839 333.2443 0.723 101325
0.887 334.3041 0.79 101325
0.93 335.4039 0.859 101325
0.97 336.5937 0.935 101325
1 337.6335 1 101325
0 329.2152 0 101000
0.067 328.7654 0.078 101000
0.092 328.6554 0.104 101000
0.116 328.5654 0.128 101000
0.145 328.4954 0.155 101000
0.184 328.4555 0.19 101000
0.199 328.4455 0.203 101000
0.22 328.4355 0.22 101000
0.239 328.4455 0.235 101000
0.286 328.4954 0.271 101000
0.338 328.6254 0.309 101000
0.407 328.8753 0.358 101000
0.495 329.3452 0.417 101000
0.567 329.855 0.471 101000
0.64 330.4849 0.525 101000
0.708 331.2547 0.582 101000
0.768 332.0846 0.641 101000
0.839 333.2443 0.723 101000
0.887 334.3041 0.79 101000
0.93 335.4039 0.859 101000
0.97 336.5937 0.935 101000
1 337.6335 1 101000
0.02 329.1353 0.023 101320
0.05 328.9353 0.059 101320
0.1 328.7354 0.115 101320
0.13 328.6354 0.147 101320
0.15 328.5354 0.164 101320
0.3 328.6354 0.274 101320
0.45 329.1353 0.379 101320
0.55 329.6351 0.451 101320
0.65 330.5349 0.524 101320
0.75 331.8346 0.612 101320
0.85 333.7343 0.73 101320
0.9 334.7341 0.804 101320
0.95 336.1338 0.892 101320
0.07 328.8054 0.082 101325
0.133 328.5654 0.144 101325
0.181 328.4455 0.188 101325
0.217 328.3755 0.218 101325
0.227 328.3855 0.226 101325
0.265 328.4355 0.255 101325
0.34 328.6254 0.311 101325
0.406 328.8753 0.356 101325
0.446 329.0953 0.382 101325
0.481 329.2852 0.406 101325
0.593 330.035 0.486 101325
0.606 330.185 0.496 101325
0.631 330.4249 0.515 101325
0.676 330.8248 0.55 101325
0.719 331.4547 0.59 101325
0.737 331.6247 0.608 101325
0.771 332.1046 0.643 101325
0.805 332.7045 0.681 101325
0.849 333.5443 0.735 101325
0.9 334.6641 0.809 101325
0.926 335.3439 0.852 101325
0.947 335.9238 0.89 101325
0.976 336.8236 0.947 101325
0 329.25 0 101000
0.1038 328.65 0.1172 101000
0.1309 328.55 0.1492 101000
0.2125 328.43 0.2125 101000
0.4044 328.83 0.3457 101000
0.4911 329.3 0.4183 101000
0.584 329.95 0.4602 101000
0.6685 330.65 0.5244 101000
0.7582 331.95 0.6274 101000
0.7978 332.65 0.6716 101000
0.8294 333.25 0.7093 101000
0.8518 333.7 0.7352 101000
0.8754 334.2 0.7567 101000
0.8887 334.5 0.7917 101000
0.9075 334.95 0.8187 101000
0.9213 335.3 0.8433 101000
0.9307 335.55 0.8456 101000
0.9716 336.75 0.9333 101000
0.9749 336.85 0.9439 101000
1 337.66 1 101000
0.325 328.8 0.294 101300
0.375 328.92 0.332 101300
0.406 329.05 0.354 101300
0.485 329.54 0.411 101300
0.576 330.21 0.479 101300
0.614 330.5 0.512 101300
0.668 331.02 0.556 101300
0.686 331.18 0.577 101300
0.743 332 0.626 101300
0.755 332.11 0.637 101300
0.794 332.71 0.678 101300
0.832 333.31 0.722 101300
0.865 333.92 0.766 101300
0.07 328.82 0.082 101300
0.133 328.58 0.144 101300
0.181 328.46 0.188 101300
0.217 328.39 0.218 101300
0.227 328.4 0.226 101300
0.265 328.45 0.255 101300
0.34 328.54 0.311 101300
0.406 328.89 0.356 101300
0.446 329.11 0.382 101300
0.481 329.3 0.406 101300
0.593 330.05 0.486 101300
0.606 330.2 0.496 101300
0.631 330.44 0.515 101300
0.676 330.84 0.55 101300
0.719 331.47 0.59 101300
0.737 331.64 0.608 101300
0.771 332.12 0.643 101300
0.805 332.72 0.681 101300
0.849 333.56 0.735 101300
0.9 334.68 0.809 101300
0.926 335.36 0.852 101300
0.947 335.94 0.89 101300
0.976 336.84 0.947 101300
0 329.35 0 101320
0.013 329.25 0.016 101320
0.035 329.1 0.043 101320
0.048 329 0.058 101320
0.057 328.95 0.067 101320
0.065 328.9 0.075 101320
0.085 328.8 0.097 101320
0.099 328.75 0.111 101320
0.113 328.7 0.124 101320
0.152 328.6 0.16 101320
0.168 328.6 0.176 101320
0.184 328.55 0.185 101320
0.197 328.55 0.2 101320
0.209 328.55 0.21 101320
0.219 328.55 0.216 101320
0.221 328.55 0.22 101320
0.223 328.55 0.221 101320
0.225 328.55 0.223 101320
0.232 328.55 0.225 101320
0.234 328.55 0.23 101320
0.249 328.55 0.24 101320
0.25 328.55 0.242 101320
0.264 328.6 0.253 101320
0.277 328.6 0.263 101320
0.3 328.65 0.281 101320
0.374 328.8 0.328 101320
0.399 328.9 0.351 101320
0.425 329 0.367 101320
0.453 329.15 0.387 101320
0.521 329.55 0.425 101320
0.6 330.15 0.487 101320
0.615 330.3 0.505 101320
0.681 330.95 0.555 101320
0.775 332.2 0.638 101320
0.803 332.65 0.667 101320
0.875 334.05 0.761 101320
1 337.65 1 101320
0.192 328.45 0.192 100200
0.225 328.45 0.219 100200
0.77 332.15 0.648 100200
0.87 333.95 0.768 100200
0.911 334.85 0.83 100200
0.1057 328.52 0.1221 101330
0.2539 328.31 0.2472 101330
0.3111 328.39 0.2861 101330
0.3964 328.68 0.3456 101330
0.5005 329.21 0.4114 101330
0.6 329.9 0.4874 101330
0.7069 331.02 0.5745 101330
0.8044 332.57 0.6746 101330
0.8527 333.48 0.7338 101330
0.9073 334.71 0.8077 101330
0.9662 336.39 0.9183 101330
0 329.35 0 101000
0.105 328.75 0.109 101000
0.241 328.55 0.238 101000
0.315 328.65 0.298 101000
0.43 329.05 0.354 101000
0.498 329.45 0.418 101000
0.595 330.05 0.498 101000
0.712 331.25 0.601 101000
0.812 332.75 0.672 101000
0.909 334.85 0.813 101000
1 337.75 1 101000
0 329.05 0 100000
0.028 328.75 0.036 100000
0.07 328.45 0.082 100000
0.117 328.25 0.13 100000
0.138 328.25 0.15 100000
0.159 328.15 0.17 100000
0.18 328.15 0.187 100000
0.2 328.15 0.203 100000
0.219 328.15 0.219 100000
0.24 328.15 0.235 100000
0.257 328.15 0.249 100000
0.273 328.15 0.261 100000
0.303 328.25 0.282 100000
0.341 328.35 0.31 100000
0.383 328.45 0.338 100000
0.426 328.65 0.37 100000
0.469 328.85 0.397 100000
0.509 329.15 0.424 100000
0.551 329.35 0.454 100000
0.588 329.75 0.482 100000
0.628 330.05 0.511 100000
0.669 330.45 0.544 100000
0.708 330.95 0.577 100000
0.746 331.45 0.612 100000
0.786 332.05 0.652 100000
0.824 332.75 0.697 100000
0.863 333.55 0.753 100000
0.903 334.55 0.812 100000
0.943 335.65 0.881 100000
0.971 336.45 0.937 100000
0.985 336.95 0.966 100000
1 337.45 1 100000
0 329.01 0 100000
0.028 328.75 0.036 100000
0.07 328.49 0.082 100000
0.117 328.29 0.13 100000
0.138 328.23 0.15 100000
0.159 328.18 0.17 100000
0.18 328.15 0.187 100000
0.2 328.14 0.203 100000
0.219 328.13 0.219 100000
0.24 328.13 0.235 100000
0.257 328.13 0.249 100000
0.273 328.15 0.261 100000
0.303 328.2 0.282 100000
0.341 328.31 0.31 100000
0.383 328.43 0.338 100000
0.426 328.66 0.37 100000
0.469 328.86 0.397 100000
0.509 329.1 0.424 100000
0.551 329.39 0.454 100000
0.588 329.7 0.482 100000
0.628 330.06 0.511 100000
0.669 330.48 0.544 100000
0.708 330.95 0.577 100000
0.746 331.45 0.612 100000
0.786 332.05 0.652 100000
0.824 332.72 0.697 100000
0.863 333.58 0.753 100000
0.903 334.52 0.812 100000
0.943 335.6 0.881 100000
0.971 336.45 0.937 100000
0.985 336.9 0.966 100000
1 337.41 1 100000

Othmer, D. F. Ind. Eng. Chem., 1928, 20, 743-6 Composition of vapors from boiling binary solutions
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Methanol - 2-Pentanone Ethanol - Acetone
1 n-Methanol 1 n-Ethanol
2 2-Pentanone 2 n-Acetone
Liquid Vapor
Liquid
mole mole Total
Temperat mole Temperat
No. fraction fraction pressure No.
ure (K) fraction ure (K)
METHAN METHAN (N/sqm)
ETHANOL
OL OL

1 0 375.3244 0 101320 1 0.1 329.9749


2 0.124 351.0632 0.421 101320 2 0.2 330.9746
3 0.23 346.9036 0.576 101320 3 0.3 331.9743
4 0.402 345.4038 0.705 101320 4 0.4 333.974
5 0.535 342.404 0.77 101320 5 0.5 334.974
6 0.642 342.404 0.819 101320 6 0.6 336.974
7 0.729 339.234 0.859 101320 7 0.65 337.974
8 0.802 337.684 0.891 101320 8 0.7 338.974
9 0.856 337.014 0.92 101320 9 0.75 339.974
10 0.915
Hill, W. D.;337.064
Van Winkle,0.947 101320
M. Ind. Eng. 10 0.8 341.974
11 Chem.,11952,337.824 1 101320
44, 208-10 Vapor-liquid 11 0.85 343.9739
equilibria in methanol binary systems 12 0.9 345.9737
methanol + methyl ethyl ketone,
methanol + methyl propyl ketone, 13 0.95 348.9734
methanol + methyl isobutyl ketone 1 0 329.3751
2 0.125 330.2749
3 0.264 331.7744
4 0.42 333.774
5 0.556 335.974
6 0.661 338.374
7 0.724 339.874
8 0.825 343.274
9 0.879 345.3738
10 0.942 348.1735
11 1 351.5732
1 0 329.2252
2 0.148 330.4248
3 0.309 332.1243
4 0.468 334.424
5 0.586 336.524
6 0.684 338.724
7 0.805 342.224
8 0.851 343.9239
9 0.922 347.1236
10 0.967 349.5234
11 1 351.4232
1 0 329.3251
2 0.1 330.0749
3 0.2 331.0746
4 0.3 332.2243
5 0.4 333.474
6 0.5 335.074
7 0.6 336.924
8 0.7 339.174
9 0.8 342.174
10 0.9 346.2237
11 1 351.4232
1 0 329.3351
2 0.125 330.4348
3 0.25 331.5545
4 0.375 333.654
5 0.5 335.304
6 0.625 337.944
7 0.75 340.934
8 0.875 345.3238
9 0.938 347.8535
10 1 351.4232
1 0 329.26
2 0.049 329.69
3 0.099 330.17
4 0.151 330.66
5 0.204 331.2
6 0.255 331.81
7 0.312 332.43
8 0.361 333.06
9 0.414 333.78
10 0.462 334.51
11 0.519 335.37
12 0.567 336.24
13 0.62 337.32
14 0.672 338.39
15 0.724 339.81
16 0.773 341.17
17 0.825 342.69
18 0.868 344.53
19 0.915 346.65
20 0.956 348.91
21 1 351.44

Chu, J. C. ; Getty, R. J.; Brennecke,


Paul, R. Distillation Equilibrium D
1950, Reinhold: New York

Hellwig, L. R.; Van Winkle, M. Ind.


Chem., 1953, 45, 624 Vapour-liq
equilibria for ethyl alcohol binary sy
Amer, H. H.; Paxton, R. R.; Van Wink
Ind. Eng. Chem., 1956, 48, 142-1
Methanol-Ethanol-Acetone Vapor-
Equilibria

Morachevskii, A. G.; Leont'ev, N. P.


Khim., 1960, 34, 2347
Morachevskii, A. G.; Leont'ev, N. P.
Khim., 1960, 34, 2347

Vinichenko, I. G.; Susarev, M. P. Zh


Khim. (Leningrad), 1966, 39, 158
2005, 231, 99-108 Isobaric vapor l
equilibria for mixtures of aceton
ethanol, and 2,2,4-trimethylpenta
101.3 kPa
nary solutions
tures vapor-liquid equilibria of acetone - methanol - water
inhold: New York
n distillation.
nol-Ethanol-Acetone Vapor-Liquid Equilibria
ew still and method for determining vapor-liquid equilibrium
liquid-vapor equilibrium in the acetone-methanol and acetone- cyclohexane systems at temperatures of 25, 45, and 55 degrees and a

od for measuring ternary vapor-liquid equilibria dew, bubble and condensation point method
tem acetone + methanol + water
and Other Properties of Methanol + Acetone, Carbon Disulphide + Acetone, Carbon Disulphide + Methanol, and Carbon Disulphide + M
ur-liquid equilibria of the binary, ternary and quaternary systems formed by acetone, methanol, propan-2-ol, and water
sobaric Vapor-Liquid Equilibria of Acetone-Methanol System system

tion of Binary Vapor-Liquid Equilibrium Data

uring VLE Data--Coupling Method with Two-Leaned-Ebulliometer


rnary and Quarternary Systems Composed of Acetone, Methanol, 2-Propanol, and 1-Propanol
quilibria for Acetone + Chloroform + Methanol and Constituent Binary Systems at 101.3 kPa
rium for the acetone-methanol-inorganic salt system
uilibria of the binary systems formed by methanol, acetone and methyl vinyl ketone at 100.0 1 0.2 kPa

Equilibrium of Acetone + Methanol System in the Presence of Calcium Bromide


Phase Equilib., 2006, 250, 131-137 Isobaric vapor liquid equilibria for acetone + methanol + lithium nitrate at 100 kPa
7, 52, 141-147
Ethanol - 2-Butanone Ethanol - 2-Pentanone
1 n-Ethanol 1 n-Ethanol
2 2-Butanone 2 2-Pentanone

Vapor Liquid Vapor


Total Total
mole mole Temperat mole
pressure No. pressure No.
fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
ETHANOL ETHANOL ETHANOL

0.071 101320 1 0 352.4731 0 101320 1


0.135 101320 2 0.04 351.051 0.0864 101320 2
0.198 101320 3 0.151 348.8845 0.208 101320 3
0.261 101320 4 0.223 348.2735 0.279 101320 4
0.326 101320 5 0.485 347.4458 0.492 101320 5
0.395 101320 6 0.521 347.1847 0.513 101320 6
0.434 101320 7 0.695 347.8346 0.642 101320 7
0.476 101320 8 0.808 348.7123 0.743 101320 8
0.522 101320 9 0.956 350.601 0.932 101320 9
0.583 101320 10 1 351.6731 1 101320 10
0.652 101320 1 0.144 349.4302 0.19 101000 11
0.738 101320 2 0.238 348.1306 0.305 101000 12
0.845 101320 3 0.324 347.7307 0.374 101000 13
0 101320 4 0.397 347.5307 0.427 101000 14
0.081 101320 5 0.508 347.4308 0.508 101000 15
0.173 101320 6 0.622 347.5307 0.587 101000
0.274 101320 7 0.727 347.9306 0.675 101000
0.364 101320 8 0.786 348.4305 0.717 101000
0.445 101320 9 0.862 349.1303 0.797 101000
0.506 101320 10 0.934 350.13 0.893 101000
0.624 101320 11 1 351.4296 1 101000
0.703 101320 1 0 352.72 0 101300
0.827 101320 2 0.036 351.69 0.06 101300
1 101320 3 0.07 351 0.112 101300
0 101000 4 0.106 350.36 0.161 101300
0.104 101000 5 0.142 349.71 0.205 101300
0.204 101000 6 0.197 348.9 0.27 101300
0.303 101000 7 0.258 348.32 0.332 101300
0.386 101000 8 0.305 347.95 0.368 101300
0.466 101000 9 0.374 347.69 0.42 101300
0.59 101000 10 0.432 347.55 0.454 101300
0.655 101000 11 0.491 347.48 0.495 101300
0.784 101000 12 0.543 347.5 0.534 101300
0.889 101000 13 0.597 347.56 0.565 101300
1 101000 14 0.644 347.7 0.604 101300
0 101320 15 0.695 347.91 0.642 101300
0.07 101320 16 0.752 348.21 0.692 101300
0.13 101320 17 0.787 348.58 0.729 101300
0.197 101320 18 0.842 349.06 0.781 101300
0.265 101320 19 0.898 349.7 0.841 101300
0.33 101320 20 0.958 350.45 0.914 101300
0.405 101320 21 1 351.44 1 101300
0.49 101320 1 0 352.68 0 101300
0.59 101320 2 0.04 351.34 0.083 101300
0.745 101320 3 0.087 350.44 0.148 101300
1 101320 4 0.14 349.68 0.215 101300
0 101320 5 0.199 348.99 0.266 101300
0.083 101320 6 0.245 348.56 0.312 101300
0.161 101320 7 0.296 348.1 0.36 101300
0.238 101320 8 0.345 347.87 0.396 101300
0.312 101320 9 0.392 347.66 0.43 101300
0.414 101320 10 0.446 347.54 0.467 101300
0.526 101320 11 0.501 347.5 0.506 101300
0.706 101320 12 0.559 347.51 0.545 101300
0.802 101320 13 0.608 347.58 0.582 101300
1 101320 14 0.657 347.72 0.617 101300
0 101320 15 0.709 347.94 0.656 101300
0.035 101320 16 0.764 348.29 0.7 101300
0.071 101320 17 0.821 348.73 0.755 101300
0.102 101320 18 0.866 349.19 0.802 101300
0.133 101320 19 0.912 349.78 0.859 101300
0.165 101320 20 0.957 350.53 0.926 101300
0.197 101320 21 1 351.46 1 101300
0.223 101320
Hellwig, L. R.; Van Winkle, M. Ind. Eng.
0.251 101320 Chem., 1953, 45, 624 Vapour-liquid
0.281 101320 equilibria for ethyl alcohol binary systems.
0.315 101320 (Leningrad), 1968, 41, 589 Liquid - vapor
phase equilibrium in the system ethyl
0.349 101320 acetate - ethanol - methyl ethyl ketone
0.391 101320 under atmospheric pressure
0.429 101320 2007, 258, 131-139 Vapor liquid equilibria
for binary and ternary mixtures of
0.483 101320 ethanol,
Martinez, 2-butanone,
N. F.; Lladosa, E.;and 2,2,4- M.;
Burguet,
0.537 101320 trimethylpentane
Monton, at 101.3
J. B. Fluid Phase kPa2008,
Equilib.,
0.597 101320 270, 62-68 Isobaric vapour liquid
equilibria for binary systems of 2-
0.675 101320 butanone with ethanol, 1-propanol, and
0.768 101320 2-propanol at 20 and 101.3 kPa
0.871 101320
1 101320

C. ; Getty, R. J.; Brennecke, L. F.;


. Distillation Equilibrium Data,
950, Reinhold: New York

, L. R.; Van Winkle, M. Ind. Eng.


, 1953, 45, 624 Vapour-liquid
for ethyl alcohol binary systems.
H.; Paxton, R. R.; Van Winkle, M.
ng. Chem., 1956, 48, 142-146
ol-Ethanol-Acetone Vapor-Liquid
Equilibria

vskii, A. G.; Leont'ev, N. P. Zh. Fiz.


Khim., 1960, 34, 2347
ko, I. G.; Susarev, M. P. Zh. Prikl.
(Leningrad), 1966, 39, 1583
31, 99-108 Isobaric vapor liquid
bria for mixtures of acetone,
, and 2,2,4-trimethylpentane at
101.3 kPa
, 45, and 55 degrees and a pressure of 760mm Hg.

and Carbon Disulphide + Methanol + Acetone


, and water
Ethanol - 2-Pentanone Methanol - Acetonitrile
1 n-Methanol
2-Pentanone 2 Acetonitrile
Liquid Vapor
Liquid Vapor
Total mole mole Total
mole Temperat mole Temperat
pressure No. fraction fraction pressure
fraction ure (K) fraction ure (K)
(N/sqm) METHAN METHAN (N/sqm)
ETHANOL ETHANOL
OL OL

0 376.0746 0 101320 1 0.075 349.1303 0.227 101000


0.0652 361.1619 0.237 101320 2 0.094 348.3305 0.266 101000
0.13 359.273 0.347 101320 3 0.205 343.7319 0.426 101000
0.301 356.273 0.518 101320 4 0.282 341.8324 0.512 101000
0.534 354.1008 0.683 101320 5 0.378 340.133 0.58 101000
0.613 353.0508 0.732 101320 6 0.465 338.9832 0.63 101000
0.624 352.9952 0.738 101320 7 0.512 338.3333 0.657 101000
0.789 352.0509 0.838 101320 8 0.639 337.3335 0.719 101000
0.854 351.712 0.885 101320 9 0.694 337.0336 0.744 101000
0.867 351.7731 0.892 101320 10 0.711 336.9836 0.757 101000
0.919 351.6009 0.93 101320 11 0.817 336.7836 0.817 101000
0.959 351.4954 0.953 101320 12 0.86 336.8336 0.847 101000
0.969 351.2954 0.967 101320 13 0.913 336.9336 0.889 101000
0.985 351.6009 0.983 101320 14 0.945 337.1336 0.925 101000
1 351.6731 1 101320 1 0 354.7286 0 101330
2 0.075 349.1303 0.227 101330
Hellwig, L. R.; Van Winkle, M. Ind. Eng.
Chem., 1953, 45, 624 Vapour-liquid 3 0.094 348.3305 0.266 101330
equilibria for ethyl alcohol binary systems. 4 0.205 343.7319 0.429 101330
5 0.282 341.8324 0.512 101330
6 0.378 340.133 0.58 101330
7 0.465 338.9832 0.63 101330
8 0.512 338.3333 0.657 101330
9 0.639 337.3335 0.719 101330
10 0.694 337.0336 0.744 101330
11 0.711 336.9836 0.757 101330
12 0.86 336.8336 0.847 101330
13 0.913 336.9336 0.889 101330
14 0.945 337.1336 0.925 101330
15 1 337.8334 1 101330
1 0.025 352.3293 0.095 101325
2 0.04 351.0797 0.135 101325
3 0.055 349.9 0.175 101325
4 0.097 348.2505 0.265 101325
5 0.14 346.2511 0.33 101325
6 0.17 345.2014 0.375 101325
7 0.2 344.0918 0.42 101325
8 0.247 341.9824 0.455 101325
9 0.289 341.5225 0.505 101325
10 0.415 339.1332 0.596 101325
11 0.47 338.4833 0.625 101325
12 0.545 337.8834 0.655 101325
13 0.63 337.4735 0.715 101325
14 0.69 337.1636 0.745 101325
15 0.745 336.9336 0.78 101325
16 0.825 336.9036 0.825 101325
17 0.86 336.8936 0.86 101325
18 0.9 337.0036 0.88 101325
19 0.93 337.1836 0.915 101325
20 0.95 337.3135 0.93 101325
21 0.97 337.5335 0.955 101325
1 0 355.66 0 101300
2 0.054 350.19 0.189 101300
3 0.171 344.6 0.38 101300
4 0.31 340.55 0.529 101300
5 0.437 339.38 0.6 101300
6 0.602 338.09 0.687 101300
7 0.646 337.71 0.706 101300
8 0.766 337.09 0.785 101300
9 0.805 337.02 0.814 101300
10 0.866 336.96 0.86 101300
11 0.962 338.04 0.945 101300
12 1 338.41 1 101300

Mato, F.; Benito, G. G. An. Quim., A, 1985,


81, 116 Liquid-Vapor Equilibrium of Binary
Mixtures of Nitriles and Alcohols. I.

Mato, F.; Gonzalez Benito, G. An. Quim.,


A, 1985, 81, 116
1986, 31, 363 Liquid-Vapor Equilibria at
760 mmHg in the Systems Methanol-
Aceto- nitrile and Acetonitrile-Propyl
Bromide
Li, Y.; Bai, P.; Zhuang, Q. Fluid Phase
Equilib., 2013, 340, 42-45 Isobaric vapor
liquid equilibrium for binary system of
methanol and acetonitrile
Methanol - Propionitrile Methanol - Butyronitrile
1 n-Methanol 1 n-Methanol
2 Propionitrile 2 Butyronitrile
Liquid Vapor Liquid
mole mole Total mole
Temperat Temperat
No. fraction fraction pressure No. fraction
ure (K) ure (K)
METHAN METHAN (N/sqm) METHAN
OL OL OL

1 0.104 354.5786 0.447 101000 1 0.074 367.9254


2 0.167 350.4299 0.546 101000 2 0.101 363.6263
3 0.226 348.0306 0.597 101000 3 0.128 360.4269
4 0.33 344.9315 0.66 101000 4 0.198 354.4287
5 0.374 344.2817 0.683 101000 5 0.25 351.7295
6 0.43 343.232 0.71 101000 6 0.3 349.6301
7 0.501 342.4323 0.732 101000 7 0.353 347.7307
8 0.53 341.8324 0.749 101000 8 0.448 345.5813
9 0.597 341.0327 0.78 101000 9 0.505 344.6316
10 0.711 339.833 0.827 101000 10 0.632 342.6322
11 0.743 339.6331 0.842 101000 11 0.725 341.2826
12 0.765 339.3331 0.852 101000 12 0.795 340.4329
13 0.835 338.8332 0.887 101000 13 0.852 339.6331
14 0.905 338.3333 0.931 101000 14 0.887 339.2831
15 0.936 338.1834 0.952 101000 15 0.941 338.6333
1 0 370.4749 0 101330 1 0 391.0608
2 0.104 354.5786 0.447 101330 2 0.074 367.9254
3 0.167 350.4299 0.546 101330 3 0.101 363.6263
4 0.226 348.0306 0.597 101330 4 0.128 360.4269
5 0.33 344.9315 0.66 101330 5 0.198 354.4287
6 0.374 344.2817 0.683 101330 6 0.25 351.7295
7 0.43 343.232 0.71 101330 7 0.3 349.6301
8 0.501 342.4323 0.732 101330 8 0.353 347.7307
9 0.53 341.8324 0.749 101330 9 0.448 345.5813
10 0.597 341.0327 0.78 101330 10 0.505 344.6316
11 0.711 339.833 0.827 101330 11 0.632 342.6322
12 0.743 339.6331 0.842 101330 12 0.725 341.2826
13 0.765 339.3331 0.852 101330 13 0.795 340.4329
14 0.835 338.8332 0.887 101330 14 0.852 339.6331
15 0.905 338.3333 0.931 101330 15 0.887 339.2831
16 0.936 338.1834 0.952 101330 16 0.941 338.6333
17 1 337.8334 1 101330 17 1 337.8334

Mato, F.; Benito, G. G. An. Quim., A, 1985, Mato, F.; Benito, G. G. An. Quim., A
81, 116 Liquid-Vapor Equilibrium of Binary 81, 116 Liquid-Vapor Equilibrium of
Mixtures of Nitriles and Alcohols. I Mixtures of Nitriles and Alcohols

Mato, F.; Gonzalez Benito, G. An. Quim., Mato, F.; Gonzalez Benito, G. An. Q
A, 1985, 81, 116 A, 1985, 81, 116
trile Ethanol - Acetonitrile Ethanol - Propionitrile
1 n-Ethanol 1 n-Ethanol
2 Acetonitrile 2 Propionitrile
Vapor
Liquid Vapor
mole Total Total
mole Temperat mole
fraction pressure No. pressure No.
fraction ure (K) fraction
METHAN (N/sqm) (N/sqm)
ETHANOL ETHANOL
OL

0.536 101000 1 0.07 351.5295 0.153 101000 1


0.613 101000 2 0.093 350.5298 0.194 101000 2
0.656 101000 3 0.199 348.4305 0.324 101000 3
0.739 101000 4 0.264 347.4308 0.378 101000 4
0.775 101000 5 0.304 347.0809 0.405 101000 5
0.8 101000 6 0.357 346.631 0.443 101000 6
0.817 101000 7 0.421 346.3311 0.476 101000 7
0.851 101000 8 0.49 346.1312 0.515 101000 8
0.865 101000 9 0.547 345.9312 0.547 101000 9
0.888 101000 10 0.624 346.2311 0.59 101000 10
0.91 101000 11 0.696 346.4311 0.627 101000 11
0.927 101000 12 0.749 346.781 0.67 101000 12
0.942 101000 13 0.84 347.7307 0.75 101000 13
0.956 101000 14 0.889 348.6304 0.806 101000 14
0.97 101000 1 0 354.7286 0 101330 15
0 101330 2 0.07 351.5295 0.153 101330 1
0.536 101330 3 0.093 350.5298 0.194 101330 2
0.613 101330 4 0.199 348.4305 0.324 101330 3
0.656 101330 5 0.264 347.4308 0.378 101330 4
0.739 101330 6 0.304 347.0809 0.405 101330 5
0.775 101330 7 0.357 346.631 0.443 101330 6
0.8 101330 8 0.421 346.3311 0.476 101330 7
0.817 101330 9 0.49 346.1312 0.515 101330 8
0.851 101330 10 0.624 346.2311 0.59 101330 9
0.865 101330 11 0.696 346.4311 0.627 101330 10
0.888 101330 12 0.749 346.781 0.67 101330 11
0.91 101330 13 0.84 347.7307 0.75 101330 12
0.927 101330 14 0.889 348.6304 0.806 101330 13
0.942 101330 15 1 351.4196 1 101330 14
0.956 101330 15
Mato, F.; Benito, G. G. An. Quim., A, 1985,
0.97 101330 81, 116 Liquid-Vapor Equilibrium of Binary 16
1 101330 Mixtures of Nitriles and Alcohols. I.

Benito, G. G. An. Quim., A, 1985,


quid-Vapor Equilibrium of Binary Mato, F.; Gonzalez Benito, G. An. Quim.,
res of Nitriles and Alcohols. I. A, 1985, 81, 116

; Gonzalez Benito, G. An. Quim.,


A, 1985, 81, 116
Ethanol - Propionitrile Ethanol - Butyronitrile
1 n-Ethanol
Propionitrile 2 Butyronitrile

Liquid Vapor Liquid Vapor


Total Total
mole Temperat mole mole Temperat mole
pressure No. pressure
fraction ure (K) fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
ETHANOL ETHANOL ETHANOL ETHANOL

0.071 364.0262 0.234 101000 1 0.083 376.8236 0.399 101000


0.09 362.8764 0.278 101000 2 0.12 372.9244 0.488 101000
0.15 360.127 0.372 101000 3 0.16 369.6251 0.558 101000
0.215 357.5277 0.462 101000 4 0.19 367.6255 0.594 101000
0.272 355.8282 0.522 101000 5 0.233 365.176 0.644 101000
0.393 353.7289 0.593 101000 6 0.27 363.2264 0.68 101000
0.478 352.7292 0.642 101000 7 0.321 361.4267 0.715 101000
0.555 351.9294 0.683 101000 8 0.378 359.7271 0.744 101000
0.609 351.4796 0.705 101000 9 0.431 358.2775 0.772 101000
0.666 351.1796 0.733 101000 10 0.478 357.2778 0.791 101000
0.721 350.9297 0.777 101000 11 0.596 355.2284 0.835 101000
0.777 350.8297 0.794 101000 12 0.655 354.4787 0.853 101000
0.817 350.7798 0.817 101000 13 0.728 353.5789 0.874 101000
0.871 350.8297 0.86 101000 14 0.8 352.9291 0.898 101000
0.923 350.9797 0.901 101000 15 0.9 352.1294 0.945 101000
0 370.4749 0 101330 1 0 391.0608 0 101330
0.071 364.0262 0.234 101330 2 0.083 376.8236 0.399 101330
0.09 362.8764 0.278 101330 3 0.12 372.9244 0.488 101330
0.15 360.127 0.372 101330 4 0.16 369.6251 0.558 101330
0.215 357.5277 0.462 101330 5 0.19 367.6255 0.594 101330
0.272 355.8282 0.522 101330 6 0.233 365.176 0.644 101330
0.393 353.7289 0.593 101330 7 0.27 363.2264 0.68 101330
0.478 352.7292 0.642 101330 8 0.321 361.4267 0.715 101330
0.555 351.9294 0.683 101330 9 0.378 359.7271 0.744 101330
0.609 351.4796 0.705 101330 10 0.431 358.2775 0.772 101330
0.666 351.1796 0.733 101330 11 0.478 357.2778 0.791 101330
0.721 350.9297 0.777 101330 12 0.596 355.2284 0.835 101330
0.777 350.8297 0.794 101330 13 0.655 354.4787 0.853 101330
0.871 350.8297 0.86 101330 14 0.728 353.5789 0.874 101330
0.923 350.9797 0.901 101330 15 0.8 352.9291 0.898 101330
1 351.4196 1 101330 16 0.9 352.1294 0.945 101330
17 1 351.4196 1 101330
Mato, F.; Benito, G. G. An. Quim., A, 1985,
81, 116 Liquid-Vapor Equilibrium of Binary Mato, F.; Benito, G. G. An. Quim., A, 1985,
Mixtures of Nitriles and Alcohols. I. 81, 116 Liquid-Vapor Equilibrium of Binary
Mixtures of Nitriles and Alcohols. I.
Mato, F.; Gonzalez Benito, G. An. Quim.,
A, 1985, 81, 116 Mato, F.; Gonzalez Benito, G. An. Quim.,
A, 1985, 81, 116
Methanol - Ethanol Methanol - 1-Propanol
1 n-Methanol 1 n-Methanol
2 n-Ethanol 2 n-Propanol
Liquid Vapor Liquid
mole mole Total mole
Temperat Temperat
No. fraction fraction pressure No. fraction
ure (K) ure (K)
METHAN METHAN (N/sqm) METHAN
OL OL OL

1 1 337.724 1 101000 1 0 370.2449


2 0.91 338.724 0.937 101000 2 0.05 367.3855
3 0.873 338.924 0.919 101000 3 0.1 364.5861
4 0.814 339.724 0.875 101000 4 0.15 362.1366
5 0.79 340.024 0.858 101000 5 0.2 359.907
6 0.728 340.824 0.813 101000 6 0.25 357.7977
7 0.652 341.724 0.759 101000 7 0.3 355.8482
8 0.542 343.124 0.676 101000 8 0.35 353.9888
9 0.435 344.8238 0.566 101000 9 0.4 352.3193
10 0.401 345.4238 0.529 101000 10 0.45 350.6898
11 0.32 346.7236 0.428 101000 11 0.5 349.1403
12 0.242 348.1235 0.326 101000 12 0.55 347.7107
13 0.134 349.7233 0.183 101000 13 0.6 346.3711
14 0 351.4232 0 101000 14 0.65 345.0615
1 0.888 338.924 0.932 101320 15 0.7 343.8618
2 0.725 340.724 0.82 101320 16 0.75 342.7622
3 0.6 342.324 0.725 101320 17 0.8 341.6825
4 0.47 344.0239 0.6 101320 18 0.85 340.6228
5 0.375 345.4238 0.505 101320 19 0.9 339.5531
6 0.248 347.1236 0.362 101320 20 0.95 338.5833
7 0.142 348.9234 0.222 101320 21 1 337.6335
8 0.073 350.1233 0.12 101320 1 0 370.3249
1 1 337.824 1 101000 2 0.155 361.4267
2 0.91 338.724 0.95 101000 3 0.265 356.628
3 0.788 339.524 0.87 101000 4 0.31 354.7286
4 0.745 340.424 0.818 101000 5 0.386 351.9294
5 0.731 340.224 0.826 101000 6 0.61 345.7313
6 0.715 340.624 0.805 101000 7 0.86 340.3329
7 0.683 340.724 0.791 101000 8 0.895 339.6331
8 0.645 341.224 0.763 101000 9 1 337.7335
9 0.63 341.424 0.751 101000 1 0.15 363.1264
10 0.61 341.724 0.735 101000 2 0.34 354.3287
11 0.587 342.124 0.716 101000 3 0.425 351.5295
12 0.567 342.424 0.685 101000 4 0.485 349.4302
13 0.497 343.124 0.637 101000 5 0.63 345.8312
14 0.48 343.7239 0.6 101000 6 0.665 344.3317
15 0.434 344.1239 0.56 101000 7 0.74 342.8321
16 0.38 345.4238 0.492 101000 8 0.82 341.0327
17 0.345 345.6238 0.47 101000 9 0.885 339.7331
18 0.311 346.1237 0.445 101000 10 0.95 338.4333
19 0.287 346.6237 0.386 101000 1 0.113 364.5261
20 0.26 347.0236 0.357 101000 2 0.226 359.827
21 0.24 347.4236 0.327 101000 3 0.362 354.6286
22 0.214 347.8235 0.293 101000 4 0.494 350.2299
23 0.19 348.3235 0.261 101000 5 0.616 346.631
24 0.162 348.6235 0.228 101000 6 0.741 343.332
25 0.142 348.9234 0.194 101000 7 0.871 340.6328
26 0.116 349.8233 0.162 101000 1 0 370.2749
27 0.056 350.4233 0.089 101000 2 0.3795 353.479
28 0.012 351.3232 0.026 101000 3 0.5808 347.5807
29 0 351.5232 0 101000 4 0.6803 344.4117
1 0.935 338.41 0.963 101300 5 0.6873 344.4117
2 0.717 341.06 0.818 101300 6 0.7622 342.5322
3 0.682 341.47 0.792 101300 7 0.764 342.5322
4 0.581 342.83 0.709 101300 8 1 337.5835
5 0.529 343.5 0.663 101300 1 0.092 365.45
6 0.424 344.98 0.561 101300 2 0.18 362.03
7 0.329 346.35 0.459 101300 3 0.28 357.05
8 0.238 347.68 0.349 101300 4 0.32 355.68
9 0.195 348.36 0.292 101300 5 0.38 353.4
10 0.113 349.63 0.177 101300 6 0.459 351.3
11 0.074 350.26 0.119 101300 7 0.581 347.61
1 0.9793 337.83 0.9832 101320 8 0.583 347.42
2 0.9421 338.22 0.965 101320 9 0.68 344.43
3 0.9007 338.78 0.9378 101320 10 0.764 342.55
4 0.8619 339.27 0.9162 101320 11 0.822 341.45
5 0.7964 340.05 0.8735 101320 12 0.862 340.23
6 0.742 340.66 0.8358 101320 Kojima, K.; Tochigi, K.; Seki, H.; Wat
Kagaku Kogaku, 1968, 32, 149-5
7 0.7072 341.19 0.8089 101320 Determination of vapor-liquid equil
8 0.6512 341.86 0.7683 101320 from boiling point curve
9 0.6075 342.43 0.7288 101320 Ochi, K.; Kojima, K. Kagaku Kogaku,
33, 352 Vapor-liquid equilibrium
10 0.5501 343.21 0.6767 101320 ternary system consisting of alcoho
11 0.4938 343.96 0.6193 101320 water
12 0.4453 344.65 0.5716 101320 Pavlenko, T. G.; Timofeev, V. S
Serafimov, L. A. Tr. Inst. - Mosk. I
13 0.392 345.4 0.516 101320 Tonkoi Khim. Tekhnol. im. M. V
14 0.344 346.09 0.4617 101320 Lomonosova, 1971, 1, 44-8
15 0.2981 346.78 0.4089 101320 Patlasov, V. P.; Grishunin, A. V.; Bal
M. I.; Rudakovskaya, T. S.; Serafimo
16 0.251 347.57 0.3544 101320 Osnovn. Org. Sint. Neftekhim., 19
17 0.2026 348.21 0.2911 101320 (Yaroslavl), 8, 103
18 0.1564 348.98 0.2326 101320
19 0.0923 349.88 0.1446 101320 Gultekin, N. Chim. Acta Turc., 1985
20 0.0418 350.71 0.0673 101320 369
1 0.941 338.19 0.959 101300 132 Vapor-Liquid Equilibria at 1 atm
Ternary and Quarternary System
2 0.876 338.72 0.916 101300 Composed of Acetone, Methano
3 0.763 339.76 0.839 101300 Propanol, and 1-Propanol
4 0.761 339.78 0.838 101300
5 0.726 340.13 0.813 101300
6 0.682 340.57 0.782 101300
7 0.599 341.49 0.72 101300
8 0.598 341.5 0.719 101300
9 0.58 341.71 0.705 101300
10 0.569 341.84 0.696 101300
11 0.534 342.27 0.667 101300
12 0.459 343.24 0.602 101300
13 0.442 343.46 0.587 101300
14 0.423 343.72 0.569 101300
15 0.4 344.05 0.547 101300
16 0.326 345.16 0.469 101300
17 0.312 345.37 0.455 101300
18 0.294 345.66 0.434 101300
19 0.287 345.77 0.426 101300
20 0.275 345.98 0.411 101300
21 0.246 346.46 0.376 101300
22 0.182 347.59 0.293 101300
23 0.179 347.64 0.289 101300
24 0.171 347.8 0.277 101300
25 0.096 349.23 0.167 101300
26 0.018 350.86 0.034 101300
Amer, H. H.; Paxton, R. R.; Van Winkle, M.
Ind. Eng. Chem., 1956, 48, 142-146
Methanol-Ethanol-Acetone Vapor-Liquid
Equilibria
Delzenne, A. O. Chem. Eng. Data Ser.,
1958, 3, 224 Vapor-liquid equilibrium data
for ternary system methanol - ethanol -
water
Slobodyanik, I. P.; Babushkina, E. M. Zh.
Prikl. Khim. (Leningrad), 1966, 39, 1899-
901 Liquid-vapor equilibrium in the
system methanol + ethanol
Chem. Eng. Data, 1993, 38, 446-449
Isobaric vapor-liquid equilibria for
methanol + ethanol + water and the three
constituent binary systems
139-153 Measurement and prediction of
isobaric vapour-liquid equilibrium data of
the system ethanol + methanol + 2-
methoxy-2-methylpropane
Chem. Liq., 2011, 49, 52-71 Phase
equilibria of binary mixtures containing
methyl acetate, water, methanol or
ethanol at 101.3 kPa
nol Methanol - 2-Propanol Methanol - 1-Butanol
1 n-Methanol 1 n-Methanol
2 2-propanol 2 n-Butanol
Vapor Liquid Vapor
mole Total mole mole Total
Temperat
fraction pressure No. fraction fraction pressure No.
ure (K)
METHAN (N/sqm) METHAN METHAN (N/sqm)
OL OL OL

0 101320 1 0.068 352.3231 0.146 101320 1


0.1487 101320 2 0.106 351.6232 0.206 101320 2
0.2785 101320 3 0.141 351.6232 0.268 101320 3
0.3809 101320 4 0.184 349.6234 0.336 101320 4
0.4664 101320 5 0.31 347.2236 0.501 101320 5
0.5408 101320 6 0.425 345.3238 0.612 101320 6
0.6043 101320 7 0.524 343.624 0.684 101320 7
0.6602 101320 8 0.652 341.924 0.785 101320 8
0.7069 101320 9 0.811 340.224 0.886 101320 9
0.7494 101320 10 0.824 339.624 0.889 101320 1
0.7871 101320 11 0.878 339.024 0.924 101320 2
0.8196 101320 12 0.947 338.424 0.967 101320 3
0.8483 101320 1 0 355.453 0 101320 4
0.8747 101320 2 0.081 354.123 0.132 101320 5
0.8975 101320 3 0.195 352.0631 0.296 101320 6
0.9176 101320 4 0.293 350.1833 0.4285 101320 7
0.9366 101320 5 0.408 347.9035 0.57 101320 8
0.9545 101320 6 0.522 345.7937 0.685 101320 9
0.9715 101320 7 0.6605 343.344 0.8 101320 10
0.9861 101320 8 0.79 341.064 0.891 101320 11
1 101320 9 0.901 339.344 0.9535 101320 12
0 101320 10 1 337.794 1 101320 13
0.437 101320 1 0 355.5283 0 101320 14
0.595 101320 2 0.135 353.0291 0.205 101320 15
0.66 101320 3 0.14 352.8291 0.21 101320 1
0.725 101320 4 0.165 352.5292 0.255 101320 2
0.872 101320 5 0.215 351.4296 0.315 101320 3
0.965 101320 6 0.22 351.1297 0.327 101320 4
0.975 101320 7 0.255 350.7298 0.38 101320 5
1 101320 8 0.467 346.8309 0.637 101320 6
0.455 101325 9 0.49 346.2311 0.665 101320 7
0.75 101325 10 0.597 344.3317 0.755 101320 8
0.89 101325 11 0.665 343.332 0.808 101320 9
0.86 101325 12 0.7 342.6322 0.835 101320 10
0.91 101325 13 0.91 339.5331 0.958 101320 1
0.92 101325 14 1 337.7335 1 101320 2
0.945 101325 1 0.157 352.5092 0.255 101325 3
0.96 101325 2 0.229 351.1996 0.347 101325 4
0.97 101325 3 0.292 350.05 0.427 101325 5
0.985 101325 4 0.338 349.1802 0.482 101325 6
0.31 101325 5 0.399 347.9306 0.557 101325 7
0.496 101325 6 0.475 346.4311 0.647 101325 8
0.651 101325 7 0.502 346.0712 0.667 101325 9
0.797 101325 8 0.555 345.0315 0.713 101325 10
0.862 101325 9 0.601 344.1817 0.752 101325 11
0.926 101325 10 0.65 343.312 0.792 101325 12
0.959 101325 11 0.747 341.5625 0.862 101325 13
0 101330 12 0.805 340.5828 0.9 101325 14
0.6777 101330 1 0.045 354.8285 0.074 101000 15
0.835 101330 2 0.12 353.429 0.191 101000 16
0.8894 101330 3 0.16 352.5292 0.264 101000 17
0.8925 101330 4 0.343 349.2302 0.503 101000 18
0.925 101330 5 0.489 346.631 0.653 101000
0.9258 101330 6 0.525 346.0312 0.685 101000
1 101330 7 0.63 344.1318 0.784 101000
0.235 101300 8 0.668 343.6319 0.807 101000
0.412 101300 9 0.737 342.5322 0.855 101000
0.562 101300 10 0.765 342.1324 0.871 101000
0.61 101300 11 0.807 341.4326 0.898 101000
0.675 101300 12 0.879 340.3329 0.939 101000
0.753 101300 13 0.905 339.833 0.955 101000
0.832 101300 14 0.927 339.4331 0.968 101000
0.835 101300 1 0.195 349.6 0.351 101300
0.888 101300 2 0.254 348.22 0.432 101300
0.928 101300 3 0.32 346.81 0.506 101300
0.94 101300 4 0.385 345.63 0.576 101300
0.955 101300 5 0.486 343.74 0.664 101300
.; Tochigi, K.; Seki, H.; Watase, K. 6 0.515 343.33 0.688 101300
ku Kogaku, 1968, 32, 149-53
ation of vapor-liquid equilibrium 7 0.585 342.39 0.741 101300
rom boiling point curve 8 0.624 341.64 0.768 101300
Kojima, K. Kagaku Kogaku, 1969, 9 0.665 341.26 0.796 101300
2 Vapor-liquid equilibrium for
ystem consisting of alcohols and 10 0.714 340.52 0.828 101300
water 11 0.775 339.8 0.865 101300
enko, T. G.; Timofeev, V. S.; 12 0.824 339.22 0.892 101300
mov, L. A. Tr. Inst. - Mosk. Inst.
koi Khim. Tekhnol. im. M. V. 13 0.896 338.48 0.934 101300
omonosova, 1971, 1, 44-8 14 0.915 338.2 0.947 101300
V. P.; Grishunin, A. V.; Balashov, 1 0 355.35 0 101325
akovskaya, T. S.; Serafimov, L. A.
n. Org. Sint. Neftekhim., 1977, 2 0.0843 353.97 0.1243 101325
(Yaroslavl), 8, 103 3 0.093 353.72 0.1466 101325
4 0.123 353.19 0.1956 101325
n, N. Chim. Acta Turc., 1985, 13, 5 0.1545 352.6 0.244 101325
369 6 0.1949 351.82 0.3022 101325
or-Liquid Equilibria at 1 atm. for 7 0.2379 351.08 0.3598 101325
ary and Quarternary Systems
osed of Acetone, Methanol, 2- 8 0.3171 349.51 0.4691 101325
ropanol, and 1-Propanol 9 0.355 348.8 0.5162 101325
10 0.3975 348 0.5621 101325
11 0.4634 346.8 0.6308 101325
12 0.5103 345.93 0.6778 101325
13 0.5596 345.03 0.7176 101325
14 0.6172 343.92 0.7652 101325
15 0.6864 342.69 0.8173 101325
16 0.7945 340.79 0.891 101325
17 0.8126 340.49 0.9032 101325
18 1 337.52 1 101325
1 0 355.5 0 101300
2 0.036 354.22 0.084 101300
3 0.057 353.54 0.127 101300
4 0.093 352.42 0.196 101300
5 0.113 351.85 0.231 101300
6 0.131 351.32 0.262 101300
7 0.173 350.2 0.328 101300
8 0.206 349.4 0.373 101300
9 0.24 348.6 0.417 101300
10 0.289 347.52 0.476 101300
11 0.329 346.72 0.519 101300
12 0.393 345.52 0.582 101300
13 0.464 344.32 0.643 101300
14 0.535 343.22 0.7 101300
15 0.564 342.8 0.721 101300
16 0.614 342.1 0.757 101300
17 0.695 341.05 0.812 101300
18 0.778 340.05 0.864 101300
19 0.854 339.2 0.911 101300
20 1 337.68 1 101300
1 0.0427 354.69 0.071 101000
2 0.0677 354.27 0.1109 101000
3 0.1221 353.43 0.194 101000
4 0.1506 352.82 0.2386 101000
5 0.2174 351.73 0.3315 101000
6 0.2679 350.78 0.3987 101000
7 0.3131 349.85 0.4575 101000
8 0.3723 348.65 0.5315 101000
9 0.4053 348.01 0.5675 101000
10 0.443 347.57 0.6035 101000
11 0.4917 346.45 0.658 101000
12 0.5827 344.93 0.7377 101000
13 0.6825 343.25 0.8209 101000
14 0.8039 341.34 0.9001 101000
15 0.8888 340.15 0.9509 101000
16 0.9576 339.07 0.9832 101000

Dunlop, J. G. Thesis, Brooklyn


Polytechnical Institute, Brooklyn, NY
(1948)
equilibria at 760 mm pressure 2-propanol
- methanol, 2- propanol - ethyl alcohol, 2-
propanol - propanol, and 2-propanol - 2-
butyl alcohol systems
Ochi, K.; Kojima, K. Kagaku Kogaku, 1969,
33, 352 Vapor-liquid equilibrium for
ternary system consisting of alcohols and
water
vapour-liquid equilibria of the binary,
ternary and quaternary systems formed
by acetone, methanol, propan-2-ol, and
water
Wisniak, J.; Tamir, A. J. Chem. Eng. Data,
1985, 30, 339 Vapor-Liquid Equilibria at
760 mmHg in the Sys. Methanol-2-
Propanol-Propyl Bromide and Its Binaries
132 Vapor-Liquid Equilibria at 1 atm. for
Ternary and Quarternary Systems
Composed of Acetone, Methanol, 2-
Propanol, and 1-Propanol

Lencka, M.; Persson, O.; Rasmussen, P. J.


Chem. Thermodyn., 1991, 23, 851-58
Eng. Data, 2007, 52, 878-883 Vapor-Liquid
Equilibria Data for Methanol + 2-
Propanol+ 2-Methyl-2-butanol and
Constituent Binary Systems at 101.3 kPa
Equilibrium Data for Methanol + tert-
Butylamine + N,N-Dimethylformamide
and Constituent Binary Systems at
Atmospheric Pressure
Methanol - 1-Butanol Ethanol - 1-Propanol
n-Methanol 1 n-Ethanol
2 n-Propanol
Liquid Vapor
Liquid Vapor
mole mole Total Total
Temperat mole Temperat mole
fraction fraction pressure No. pressure
ure (K) fraction ure (K) fraction
METHAN METHAN (N/sqm) (N/sqm)
ETHANOL ETHANOL
OL OL

0.108 375.6245 0.596 101000 1 0 369.9737 0 101320


0.205 368.4568 0.75 101000 2 0.0815 367.9735 0.153 101320
0.366 362.123 0.86 101000 3 0.1835 365.9733 0.316 101320
0.498 357.3452 0.909 101000 4 0.296 362.973 0.465 101320
0.607 354.2897 0.938 101000 5 0.416 360.973 0.5965 101320
0.698 354.123 0.957 101000 6 0.549 357.973 0.718 101320
0.776 352.5675 0.97 101000 7 0.696 355.973 0.8275 101320
0.844 347.9568 0.979 101000 8 0.8605 352.973 0.9285 101320
0.902 344.5128 0.987 101000 9 1 350.9732 1 101320
0.125 377.5235 0.635 101325 1 0 370.2849 0 101320
0.195 370.8248 0.795 101325 2 0.126 366.9756 0.24 101320
0.27 364.826 0.875 101325 3 0.188 365.7858 0.318 101320
0.36 360.4269 0.92 101325 4 0.21 364.7261 0.339 101320
0.425 357.4278 0.94 101325 5 0.358 361.4467 0.55 101320
0.46 354.6286 0.95 101325 6 0.461 359.3772 0.65 101320
0.61 349.1303 0.96 101325 7 0.546 358.1076 0.711 101320
0.65 347.3308 0.965 101325 8 0.6 357.2578 0.76 101320
0.7 345.6313 0.97 101325 9 0.663 356.1881 0.799 101320
0.75 344.3317 0.975 101325 10 0.844 353.7189 0.914 101320
0.81 342.8321 0.98 101325 11 1 351.5095 1 101320
0.85 341.6325 0.985 101325
0.885 340.5328 0.99 101325
0.93 339.4331 0.995 101325 Gay, L. Chim. Ind. (Paris), 1927, 18, 187
0.97 338.4333 0.998 101325 Ochi, K.; Kojima, K. Kagaku Kogaku, 1969,
33, 352 Vapor-liquid equilibrium for
0 390.9708 0 101320 ternary system consisting of alcohols and
0.035 386.9716 0.224 101320 water
0.088 380.9728 0.456 101320
0.168 372.9744 0.642 101320
0.272 364.976 0.788 101320
0.359 359.977 0.865 101320
0.468 354.9785 0.917 101320
0.628 347.9806 0.961 101320
0.792 342.9821 0.98 101320
1 337.9834 1 101320
0.0271 386.44 0.148 101320
0.0419 384.73 0.2139 101320
0.1002 379.21 0.3855 101320
0.1741 372.22 0.5549 101320
0.2298 367 0.6604 101320
0.2785 363.33 0.7297 101320
0.3227 361.05 0.7771 101320
0.3729 357.91 0.8199 101320
0.4282 355.76 0.8526 101320
0.4912 353.06 0.8873 101320
0.565 349.94 0.9173 101320
0.6422 347.06 0.9397 101320
0.7086 345.09 0.9553 101320
0.7819 342.96 0.9705 101320
0.8418 341.42 0.9795 101320
0.8907 340.23 0.9854 101320
0.9333 339.23 0.9913 101320
0.9736 338.26 0.9971 101320
Chem., 1952, 44, 205-8 Vapor-liquid
equilibria in methanol binary systems
methanol + propanol, methanol + butanol,
and methanol + pentanol
Pavlenko, T. G.; Timofeev, V. S.;
Serafimov, L. A. Tr. Inst. - Mosk. Inst.
Tonkoi Khim. Tekhnol. im. M. V.
Lomonosova, 1971, 1, 44-8
Patlasov, V. P.; Naumova, T. B.;
Sergacheva, N. I.; Balashov, M. I. Tr. Inst. -
Mosk. Inst. Tonkoi Khim. Tekhnol. im. M.
V. Lomonosova, 1977, 7, 179
207-218 Phase equilibria involved in
extractive distillation of 2-methoxy-2-
methylpropane + methanol using 1-
butanol as entrainer
Ethanol - 2-Propanol Ethanol - 1-Butanol
1 n-Ethanol 1 n-Ethanol
2 2-propanol 2 n-Butanol

Liquid Vapor Liquid


Total
mole Temperat mole mole Temperat
No. pressure No.
fraction ure (K) fraction fraction ure (K)
(N/sqm)
ETHANOL ETHANOL ETHANOL

1 0 355.453 0 101320 1 0 390.7268


2 0.124 355.013 0.141 101320 2 0.0345 388.1265
3 0.24 354.563 0.2665 101320 3 0.0685 385.6263
4 0.2425 354.513 0.273 101320 4 0.1055 383.126
5 0.348 354.123 0.3845 101320 5 0.145 380.6255
6 0.4555 353.683 0.485 101320 6 0.188 378.125
7 0.457 353.683 0.4955 101320 7 0.284 373.124
8 0.552 353.343 0.5895 101320 8 0.399 368.1235
9 0.559 353.293 0.597 101320 9 0.5365 363.123
10 0.6135 353.063 0.646 101320 10 0.616 360.623
11 0.7425 352.5631 0.77 101320 11 0.703 358.123
12 0.8295 352.2331 0.8545 101320 12 0.7995 355.623
13 0.8335 352.2331 0.858 101320 13 0.908 353.123
14 0.915 351.9531 0.9295 101320 14 1 351.4232
15 1 351.6232 1 101320 1 0.062 387.4264
1 0 355.5183 0 101320 2 0.113 384.2261
2 0.18 354.6286 0.1935 101320 3 0.178 379.0252
3 0.302 354.2787 0.3235 101320 4 0.252 374.4243
4 0.3655 354.0088 0.414 101320 5 0.323 369.5236
5 0.401 353.8089 0.4275 101320 6 0.427 366.6234
6 0.514 353.399 0.56 101320 7 0.488 363.7231
7 0.541 353.229 0.5725 101320 8 0.555 361.223
8 0.629 353.0291 0.662 101320 9 0.574 361.423
9 0.7182 352.6992 0.7536 101320 10 0.601 359.523
10 0.7916 352.1593 0.825 101320 11 0.666 358.823
11 0.8606 352.0794 0.8705 101320 12 0.738 356.423
12 1 351.5895 1 101320 13 0.743 357.023
1 0 355.65 0 101300 14 0.845 354.123
2 0.1108 355.1 0.1247 101300 15 0.887 353.423
3 0.1757 354.75 0.1998 101300 16 0.938 352.2231
4 0.2645 354.5 0.2983 101300 1 0 390.2378
5 0.3497 354.2 0.3871 101300 2 0.129 380.7366
6 0.4054 353.95 0.4458 101300 3 0.233 375.2355
7 0.4726 353.7 0.5149 101300 4 0.282 372.7351
8 0.5461 353.45 0.5915 101300 5 0.357 368.9014
9 0.6123 353.2 0.6564 101300 6 0.453 366.0677
10 0.7182 352.75 0.7538 101300 7 0.468 365.5121
11 0.8067 352.4 0.8336 101300 8 0.61 360.7897
12 0.8937 351.95 0.9094 101300 9 0.709 357.9563
13 1 351.45 1 101300 10 0.88 353.9008
equilibria at 760 mm pressure 2-propanol 11 1 351.5121
- methanol, 2- propanol - ethyl alcohol, 2-
propanol - propanol, and 2-propanol - 2- 1 0.078 384.0722
butyl alcohol systems 2 0.1516 379.4231
Kojima, K.; Ochi, K.; Nakazawa, Y. Kagaku 3 0.349 369.825
Kogaku, 1968, 32, 441-6 Relation between
the liquid activity coefficient and 4 0.5168 363.6263
composition for a ternary system 5 0.6626 359.2272
equilibrium data and their correlation for 6 0.7895 355.9282
binary systems consisting of ethanol, 2-
propanol, 1,2-ethanediol and methyl 7 0.9011 353.4889
benzoate 8 0.9683 352.3093
1 0 390.88
2 0.0297 387.65
3 0.0444 386.44
4 0.057 385.7
5 0.0804 384.14
6 0.1292 381.17
7 0.1505 380.08
8 0.1696 378.71
9 0.2087 376.71
10 0.2594 374.03
11 0.3139 371.68
12 0.3661 369.48
13 0.4266 367.25
14 0.4895 364.9
15 0.554 362.68
16 0.6142 360.9
17 0.6548 359.74
18 0.685 358.88
19 0.7466 357.05
20 0.7971 355.84
21 0.8342 354.89
22 0.8805 353.93
23 0.9373 352.58
24 1 351.44

Gay, L. Chim. Ind. (Paris), 1927, 18


equilibria for commercially impor
systems of organic solvents: the b
systems ethanol - n-butanol; aceto
water, and isopropanol - wate

Hellwig, L. R.; Van Winkle, M. Ind.


Chem., 1953, 45, 624 Vapour-liq
equilibria for ethyl alcohol binary sy
P. Izv. Vyssh. Uchebn. Zaved., Khim.
Tekhnol., 1969, 12, 424-8 Liquid-v
Phase Equilibriums in Ethanol-n-bu
and Water - n-butanol system

Arce, A.; Rodil, E.; Soto, A. Can. J. C


Eng., 1999, 77, 1135
Ethanol - 2-Butanol Butylamine - Hexane
1 n-Ethanol 1 n-Butylamine
2 2-Butanol 2 n-Hexane

Vapor Liquid Vapor


Total Total
mole mole Temperat mole
pressure No. pressure No.
fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
ETHANOL ETHANOL ETHANOL

0 101320 1 0 372.4017 0 101320 1


0.125 101320 2 0.0552 370.6238 0.126 101320 2
0.2285 101320 3 0.321 363.7898 0.505 101320 3
0.327 101320 4 0.442 361.0119 0.636 101320 4
0.416 101320 5 0.57 358.5674 0.743 101320 5
0.496 101320 6 0.753 355.1786 0.87 101320 6
0.6345 101320 7 0.817 354.0674 0.9 101320 7
0.7495 101320 8 0.825 353.9008 0.912 101320 8
0.843 101320 9 0.924 352.012 0.966 101320 9
0.883 101320 10 1 351.5121 1 101320 10
0.9169 101320 11
Hellwig, L. R.; Van Winkle, M. Ind. Eng.
0.9508 101320 Chem., 1953, 45, 624 Vapour-liquid 12
0.9798 101320 equilibria for ethyl alcohol binary systems. 13
1 101320
0.181 101000
0.316 101000
0.496 101000
0.597 101000
0.708 101000
0.784 101000
0.828 101000
0.881 101000
0.885 101000
0.9 101000
0.927 101000
0.946 101000
0.976 101000
0.982 101000
0.987 101000
0.997 101000
0 101320
0.384 101320
0.563 101320
0.602 101320
0.696 101320
0.779 101320
0.786 101320
0.871 101320
0.912 101320
0.968 101320
1 101320
0.276 101320
0.4451 101320
0.7104 101320
0.8308 101320
0.9 101320
0.945 101320
0.9761 101320
0.9923 101320
0 101320
0.1178 101320
0.1719 101320
0.2 101320
0.2614 101320
0.3734 101320
0.4157 101320
0.4622 101320
0.5261 101320
0.602 101320
0.6657 101320
0.7168 101320
0.7697 101320
0.8178 101320
0.8577 101320
0.8847 101320
0.9016 101320
0.9126 101320
0.938 101320
0.9522 101320
0.9644 101320
0.973 101320
0.9883 101320
1 101320

him. Ind. (Paris), 1927, 18, 187


ria for commercially important
of organic solvents: the binary
ethanol - n-butanol; acetone -
er, and isopropanol - water

, L. R.; Van Winkle, M. Ind. Eng.


, 1953, 45, 624 Vapour-liquid
for ethyl alcohol binary systems.
ssh. Uchebn. Zaved., Khim. Khim.
l., 1969, 12, 424-8 Liquid-vapor
quilibriums in Ethanol-n-butanol
Water - n-butanol systems

Rodil, E.; Soto, A. Can. J. Chem.


Eng., 1999, 77, 1135
Butylamine - Hexane Butylamine - p-Xylene
n-Butylamine 1 n-Butylamine
2 p-Xylene

Liquid Vapor Liquid Vapor


Total Total
mole Temperat mole mole Temperat mole
pressure No. pressure
fraction ure (K) fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
N-BUT-01 N-BUT-01 N-BUT-01 N-BUT-01

0.0405 341.5 0.053 101300 1 0.95 351.6295 0.986 101000


0.1262 340.81 0.1494 101300 2 0.928 352.1294 0.984 101000
0.2037 340.52 0.2195 101300 3 0.894 353.329 0.968 101000
0.2963 340.49 0.2905 101300 4 0.812 354.8285 0.95 101000
0.3886 340.72 0.3551 101300 5 0.804 355.6283 0.945 101000
0.4704 341.13 0.415 101300 6 0.758 356.628 0.931 101000
0.547 341.65 0.4631 101300 7 0.681 358.7274 0.903 101000
0.6318 342.43 0.5259 101300 8 0.614 361.6267 0.87 101000
0.7349 343.42 0.6121 101300 9 0.546 363.6263 0.842 101000
0.7962 344.67 0.6733 101300 10 0.518 365.4259 0.816 101000
0.8506 345.81 0.7393 101300 11 0.468 367.6255 0.792 101000
0.9108 M.;
Dominguez, 347.33
Mainar, A. 0.8269 101300
M.; Artigas, H.; 12 0.431 369.4251 0.787 101000
0.955 348.67 0.9046 101300
Royo, F. M.; Urieta, J. S. J. Chem. Eng. Jpn., 13 0.397 371.0248 0.75 101000
1997, 30, 484-490 Isobaric VLE Data of the 14 0.302 377.5235 0.654 101000
Ternary System (1-Butanol + n-Hexane +
1-Butylamine) and the Three Constituent 15 0.25 380.6229 0.585 101000
Binary Mixtures at 101.3kPa 16 0.165 389.0212 0.465 101000
17 0.129 392.7205 0.408 101000
18 0.052 401.6187 0.228 101000
19 0.033 405.5179 0.145 101000
20 0.012 407.6175 0.104 101000
21 0.005 409.917 0.081 101000
22 0.001 410.8168 0.028 101000

Bagga, O. P.; Raju, K. S. N.


Indian Chem. Eng., 1975, 17, 45
Butylamine - Ethylbenzene Hexane - Heptane
1 n-Butylamine 1 n-Hexane
2 Ethylbenzene 2 n-Heptane

Liquid Vapor Liquid


Total
mole Temperat mole mole
No. pressure No.
fraction ure (K) fraction fraction
(N/sqm)
N-BUT-01 N-BUT-01 HEXANE

1 0.9725 351.0297 0.988 101000 1 0


2 0.943 351.9294 0.98 101000 2 0.0383
3 0.9 352.8291 0.96 101000 3 0.0964
4 0.8425 353.9288 0.94 101000 4 0.1363
5 0.82 354.8285 0.93 101000 5 0.1904
6 0.77 356.1282 0.9175 101000 6 0.2459
7 0.65 359.3272 0.874 101000 7 0.3146
8 0.555 362.5265 0.8275 101000 8 0.3953
9 0.48 366.2258 0.7825 101000 9 0.4321
10 0.4425 367.9254 0.7825 101000 10 0.4853
11 0.27 377.7235 0.619 101000 11 0.5123
12 0.208 383.4223 0.53 101000 12 0.5571
13 0.1375 389.3211 0.365 101000 13 0.6187
14 0.095 392.4205 0.267 101000 14 0.6824
15 0.085 394.1202 0.254 101000 15 0.7012
16 0.0575 397.7195 0.1835 101000 16 0.7679
17 0.0425 399.3191 0.1275 101000 17 0.816
18 0.0125 407.1176 0.0325 101000 18 0.8991
19 1
Jan, D. S.; Shiau, H. -Y.; Tsai, F. N
Bagga, O. P.; Raju, K. S. N. Indian Chem. Data, 1994, 39, 438-440 Vapor-Liq
Eng., 1975, 17, 45 n-Hexane + Cyclohexane + n-Hepta
Constituent Binary Systems a
eptane Hexane - Benzene
1 n-Hexane
2 n-Benzene

Vapor Liquid Vapor


Total
Temperature mole Total pressure mole Temperat mole
No. pressure
(K) fraction (N/sqm) fraction ure (K) fraction
(N/sqm)
HEXANE HEXANE HEXANE

371.47 0 101000 1 1 341.474 1 101000


369.45 0.0852 101000 2 0.96 341.874 0.961 101000
367.18 0.1986 101000 3 0.92 341.924 0.921 101000
365.5 0.2731 101000 4 0.872 341.974 0.878 101000
363.52 0.36 101000 5 0.795 342.124 0.815 101000
361.41 0.4407 101000 6 0.743 342.274 0.77 101000
359.11 0.5258 101000 7 0.6875 342.524 0.725 101000
356.37 0.6236 101000 8 0.65 342.674 0.692 101000
355.56 0.6534 101000 9 0.608 342.974 0.661 101000
353.95 0.703 101000 10 0.566 343.274 0.629 101000
352.93 0.727 101000 11 0.532 343.424 0.603 101000
351.94 0.7622 101000 12 0.5105 343.624 0.5855 101000
350.27 0.8074 101000 13 0.451 344.0739 0.539 101000
348.72 0.8495 101000 14 0.39 344.6738 0.486 101000
348.13 0.8615 101000 15 0.352 345.1238 0.454 101000
346.66 0.8993 101000 16 0.3375 345.3738 0.439 101000
345.55 0.924 101000 17 0.31 345.7237 0.418 101000
343.74 0.9637 101000 18 0.308 345.7737 0.416 101000
341.81 1 101000 19 0.274 346.3237 0.3845 101000
Jan, D. S.; Shiau, H. -Y.; Tsai, F. N. J. Chem. Eng. 20 0.268 346.4237 0.392 101000
Data, 1994, 39, 438-440 Vapor-Liquid Equilibria of
n-Hexane + Cyclohexane + n-Heptane and the Three 21 0.241 346.9236 0.3535 101000
Constituent Binary Systems at 101.0 kPa 22 0.2155 347.2736 0.33 101000
23 0.198 347.6735 0.3085 101000
24 0.177 348.0235 0.288 101000
25 0.141 348.8234 0.2425 101000
26 0.123 349.1734 0.223 101000
27 0.112 349.4234 0.205 101000
28 0.1075 349.6234 0.1975 101000
29 0.102 349.7733 0.1905 101000
30 0.098 349.8233 0.184 101000
31 0.088 350.1233 0.168 101000
32 0.082 350.3233 0.156 101000
33 0.0785 350.3733 0.1525 101000
34 0.048 351.3732 0.1 101000
35 0.0225 352.3231 0.0515 101000
36 0.015 352.673 0.0335 101000
37 0.0055 352.923 0.016 101000
38 0 353.273 0 101000
1 0.984 341.894 0.983 101320
2 0.982 341.824 0.981 101320
3 0.98 341.824 0.979 101320
4 0.975 341.824 0.973 101320
5 0.971 341.874 0.969 101320
6 0.925 341.934 0.927 101320
7 0.921 341.974 0.923 101320
8 0.825 342.024 0.835 101320
9 0.825 342.024 0.836 101320
10 0.638 342.924 0.697 101320
11 0.638 342.014 0.695 101320
12 0.51 344.0239 0.608 101320
13 0.499 344.5439 0.589 101320
14 0.499 344.6239 0.594 101320
15 0.402 345.0238 0.512 101320
16 0.168 348.5735 0.28 101320
17 0.168 348.6235 0.275 101320
18 0.163 348.7234 0.272 101320
19 0.113 349.6234 0.2 101320
20 0.11 349.7233 0.2 101320
21 0.108 349.7233 0.2 101320
22 0.108 350.6233 0.2 101320
23 0.08 350.6233 0.154 101320
24 0.04 351.9231 0.08 101320
25 0.031 352.4231 0.061 101320
26 0.03 352.4231 0.062 101320
27 0.028 352.5231 0.055 101320
28 0.027 352.3231 0.062 101320
29 0.024 352.6231 0.051 101320
1 0.984 341.894 0.983 101320
2 0.982 341.824 0.981 101320
3 0.98 341.824 0.979 101320
4 0.975 341.824 0.973 101320
5 0.971 341.874 0.969 101320
6 0.925 341.934 0.927 101320
7 0.921 341.974 0.923 101320
8 0.825 342.024 0.836 101320
9 0.825 342.024 0.835 101320
10 0.638 342.014 0.695 101320
11 0.638 342.924 0.697 101320
12 0.51 344.0239 0.608 101320
13 0.499 344.6239 0.594 101320
14 0.499 344.5439 0.589 101320
15 0.402 345.0238 0.512 101320
16 0.168 348.6235 0.275 101320
17 0.168 348.5735 0.28 101320
18 0.163 348.7234 0.272 101320
19 0.113 349.6234 0.2 101320
20 0.11 349.7233 0.2 101320
21 0.108 350.6233 0.2 101320
22 0.108 349.7233 0.2 101320
23 0.08 350.6233 0.154 101320
24 0.04 351.9231 0.08 101320
25 0.031 352.4231 0.062 101320
26 0.03 352.4231 0.061 101320
27 0.028 352.5231 0.055 101320
28 0.027 352.3231 0.062 101320
29 0.024 352.6231 0.051 101320
1 0.9988 341.864 0.9984 101320
2 0.9982 341.864 0.9979 101320
3 0.998 341.864 0.9979 101320
4 0.9892 341.874 0.9897 101320
5 0.9803 341.874 0.9816 101320
6 0.9679 341.884 0.9705 101320
7 0.9608 341.894 0.964 101320
8 0.9451 341.914 0.95 101320
9 0.93 341.934 0.9371 101320
10 0.841 342.134 0.861 101320
11 0.598 343.104 0.67 101320
12 0.42 344.4639 0.529 101320
13 0.296 345.9737 0.42 101320
14 0.248 346.7536 0.373 101320
15 0.207 347.4636 0.328 101320
16 0.102 349.7733 0.192 101320
17 0.03 352.1031 0.06 101320
1 1 341.994 1 101325
2 0.99 341.884 0.98969 101325
3 0.98 341.824 0.9795 101325
4 0.97 341.784 0.96943 101325
5 0.96 341.764 0.95958 101325
6 0.95 341.764 0.94979 101325
7 0.94 341.804 0.94027 101325
1 0.92 341.824 0.922 101000
2 0.918 341.874 0.92 101000
3 0.915 341.874 0.918 101000
4 0.912 341.924 0.915 101000
5 0.909 341.924 0.912 101000
6 0.905 341.924 0.909 101000
7 0.856 341.974 0.863 101000
8 0.848 342.024 0.856 101000
9 0.84 342.074 0.848 101000
10 0.83 342.074 0.84 101000
11 0.817 342.124 0.83 101000
12 0.801 342.124 0.817 101000
13 0.748 342.124 0.774 101000
14 0.719 342.274 0.748 101000
15 0.682 342.474 0.719 101000
16 0.634 342.774 0.682 101000
17 0.57 343.174 0.634 101000
18 0.488 343.7739 0.57 101000
19 0.417 344.4739 0.511 101000
20 0.31 345.8237 0.417 101000
21 0.203 347.6735 0.31 101000
22 0.119 349.7733 0.203 101000
23 0.06 351.2232 0.119 101000
24 0.028 352.2231 0.06 101000
1 0.94 341.724 0.942 101320
2 0.937 341.724 0.939 101320
3 0.898 341.824 0.902 101320
4 0.897 341.824 0.902 101320
5 0.798 341.924 0.814 101320
6 0.793 342.024 0.809 101320
7 0.72 342.224 0.749 101320
8 0.717 342.224 0.746 101320
9 0.606 342.824 0.659 101320
10 0.603 342.824 0.657 101320
11 0.503 343.524 0.579 101320
12 0.499 343.524 0.577 101320
13 0.387 344.6239 0.487 101320
14 0.381 344.6239 0.483 101320
15 0.323 345.3238 0.432 101320
16 0.32 345.4238 0.43 101320
17 0.312 345.5238 0.424 101320
18 0.312 345.5238 0.422 101320
19 0.311 345.5238 0.422 101320
20 0.234 346.7236 0.347 101320
21 0.219 346.9236 0.334 101320
22 0.128 348.9234 0.222 101320
23 0.125 348.9234 0.22 101320
24 0.122 349.0234 0.216 101320
25 0.055 351.0232 0.112 101320
26 0.052 351.0232 0.108 101320
1 0.92 341.824 0.922 101000
2 0.918 341.874 0.92 101000
3 0.915 341.874 0.918 101000
4 0.912 341.924 0.915 101000
5 0.909 341.924 0.912 101000
6 0.905 341.924 0.909 101000
7 0.856 341.974 0.863 101000
8 0.848 342.024 0.856 101000
9 0.84 342.074 0.848 101000
10 0.83 342.074 0.84 101000
11 0.817 342.124 0.83 101000
12 0.801 342.124 0.817 101000
13 0.748 342.124 0.774 101000
14 0.719 342.274 0.748 101000
15 0.682 342.474 0.719 101000
16 0.634 342.774 0.682 101000
17 0.57 343.174 0.634 101000
18 0.488 343.7739 0.57 101000
19 0.417 344.4739 0.511 101000
20 0.31 345.8237 0.417 101000
21 0.203 347.6735 0.31 101000
22 0.119 349.7733 0.203 101000
23 0.06 351.2232 0.119 101000
24 0.028 352.2231 0.06 101000
1 0.92 342.3323 0.919 101300
2 0.772 342.5322 0.791 101300
3 0.666 342.8321 0.696 101300
4 0.589 343.432 0.644 101300
5 0.484 344.1318 0.561 101300
6 0.414 344.8315 0.507 101300
7 0.305 346.0312 0.412 101300
8 0.226 347.1309 0.338 101300
9 0.151 348.7304 0.251 101300
10 0.079 350.8297 0.149 101300
1 1 341.95 1 101325
2 0.82 341.95 0.83 101325
3 0.807 341.85 0.817 101325
4 0.747 342.05 0.764 101325
5 0.704 342.2 0.734 101325
6 0.64 342.55 0.687 101325
7 0.6 342.85 0.657 101325
8 0.524 343.45 0.587 101325
9 0.434 344.25 0.53 101325
10 0.397 344.75 0.504 101325
11 0.357 345.15 0.464 101325
12 0.244 346.65 0.367 101325
13 0.157 348.55 0.284 101325
14 0.03 351.95 0.077 101325
15 0.014 352.55 0.04 101325
16 0 353.05 0 101325
Myers, H. S. Ind. Eng. Chem., 1955, 47,
2215 Vapor-liquid equilibrium data for
binary mixtures of paraffins and
aromatics.

Gotthard, F.; Minea, I. Rev. Chim.


(Bucharest), 1960, 11, 642

Gothard, F.; Minea, I.; Grigoras, C. Rev.


Chim. (Bucharest), 1960, 11, 705
Brzostowski, W. Bull. Acad. Pol. Sci.-Chim.,
1961, 9, 471 Vapour-liquid equilibria in
the benzene + hexane system containing
carbon 1 4-labelled benzene
Gotthard, F.; Minea, I. Rev. Chim.
(Bucharest), 1961, 12, 489 Rectification of
n-hexane + benzene mixtures and the
liquid-vapor equilibrium of these mixtures

Butler, P. A.; Ridgway, K. J. Appl. Chem.,


1967, 17, 191-197 Ternary Vapour-Liquid
Equilibrium: The Use of A Multi-Stage Still
Hanson, D. O.; Van Winle, M. J. Chem.
Eng. Data, 1967, 12, 319 Alteration of the
Relative Volatility of n-Hexane-1-Hexene
by Oxygenated and Chlorinated Solvents
Ridgway, K.; Butler, P. A. J. Chem. Eng.
Data, 1967, 12, 509-515 Some Physical
Properties of the Ternary System
Benzene-Cyclohexane-n-Hexane
Michishita, T.; Arai, Y.; Saito, S. Kagaku
Kogaku, 1971, 35, 111-116 Vapor-liquid
equilibria of hydrocarbons at atmospheric
pressure
I. Rev. Roum. Chim., 1992, 37, 27-40
Liquid-vapor equilibria in binary mixtures
of 2-chlorotoluene + 4- chlorotoluene and
toluene + 2-chlorotoluene
Hexane - Toluene Hexane - p-xylene
1 n-Hexane 1 n-Hexane
2 n-Toluene 2 p-Xylene

Liquid Vapor Liquid


Total
mole Temperat mole mole Temperat
alpha No. pressure No.
fraction ure (K) fraction fraction ure (K)
(N/sqm)
HEXANE HEXANE HEXANE

1 1 341.874 1 101000 1 0.953 343.1321


2 0.869 344.2739 0.948 101000 2 0.868 345.7313
3 0.862 344.6239 0.946 101000 3 0.797 347.9306
4 0.822 345.2738 0.93 101000 4 0.701 351.3296
5 0.813 345.3738 0.927 101000 5 0.578 356.0282
6 0.77 346.6237 0.907 101000 6 0.497 359.7271
7 0.73 347.3236 0.89 101000 7 0.409 364.4261
8 0.707 347.9735 0.88 101000 8 0.338 369.4251
9 0.64 349.8733 0.848 101000 9 0.192 382.8224
10 0.605 350.9232 0.832 101000 10 0.165 385.222
11 0.579 351.6232 0.822 101000 11 0.123 391.4207
12 0.508 354.123 0.777 101000 12 0.042 403.1184
13 0.491 353.973 0.769 101000 13 0.011 409.2172
14 0.473 355.073 0.757 101000
15 0.464 355.523 0.751 101000 Michishita, T.; Arai, Y.; Saito, S. Ka
Kogaku, 1971, 35, 111-116 Vapor-
16 0.443 355.623 0.742 101000 equilibria of hydrocarbons at atmos
17 0.392 358.473 0.697 101000 pressure
18 0.352 359.473 0.664 101000
19 0.339 359.973 0.657 101000
20 0.28 362.923 0.593 101000
21 0.254 363.9731 0.563 101000
22 0.217 366.1233 0.518 101000
23 0.196 367.5234 0.484 101000
24 0.18 369.1736 0.459 101000
25 0.1 374.0742 0.31 101000
26 0.09 375.2244 0.282 101000
27 0 383.6861 0 101000
1 1 341.674 1 101325
2 0.962 342.374 0.986 101325
3 0.928 343.124 0.973 101325
4 0.882 343.9739 0.955 101325
5 0.837 344.9738 0.934 101325
6 0.794 345.8737 0.917 101325
7 0.752 347.0736 0.898 101325
8 0.713 348.1235 0.883 101325
9 0.677 349.0234 0.866 101325
10 0.655 349.5234 0.853 101325
11 0.628 350.2733 0.84 101325
12 0.567 351.9231 0.81 101325
13 0.501 353.823 0.772 101325
14 0.437 355.923 0.733 101325
15 0.376 358.173 0.689 101325
16 0.369 358.673 0.682 101325
17 0.324 360.273 0.645 101325
18 0.317 360.773 0.635 101325
19 0.279 362.573 0.594 101325
20 0.272 363.073 0.589 101325
21 0.239 364.5231 0.555 101325
22 0.224 365.5232 0.534 101325
23 0.203 366.7734 0.5 101325
24 0.169 368.8236 0.447 101325
25 0.134 371.0738 0.392 101325
26 0.125 371.7239 0.378 101325
27 0.084 375.0244 0.28 101325
28 0.075 375.7745 0.248 101325
29 0.06 377.1748 0.213 101325
30 0.04 379.1752 0.15 101325
31 0.02 381.3256 0.077 101325
32 0.001 383.476 0.004 101325
33 0 383.7761 0 101325
1 0.938 343.332 0.975 101320
2 0.885 344.5316 0.954 101320
3 0.822 345.8312 0.921 101320
4 0.754 348.0306 0.886 101320
5 0.659 349.4302 0.851 101320
6 0.639 350.13 0.833 101320
7 0.582 351.4296 0.812 101320
8 0.516 353.1291 0.766 101320
9 0.439 355.9282 0.717 101320
10 0.379 358.1276 0.667 101320
11 0.29 362.3265 0.592 101320
12 0.24 364.7261 0.531 101320
13 0.224 365.5259 0.512 101320
14 0.201 366.7257 0.471 101320
15 0.172 368.9252 0.424 101320
16 0.141 370.9248 0.364 101320
17 0.125 371.1248 0.331 101320
18 0.104 373.4243 0.301 101320
19 0.087 374.824 0.251 101320
20 0.071 376.2238 0.212 101320
21 0.057 377.5235 0.176 101320
22 0.047 378.5233 0.154 101320
1 0.884 344.0318 0.935 101300
2 0.834 345.2314 0.935 101300
3 0.82 345.6313 0.927 101300
4 0.796 346.2311 0.918 101300
5 0.658 349.7301 0.852 101300
6 0.652 349.83 0.852 101300
7 0.578 351.8294 0.809 101300
8 0.568 352.1294 0.806 101300
9 0.51 353.8288 0.776 101300
10 0.503 354.0288 0.768 101300
11 0.499 354.2287 0.763 101300
12 0.441 356.1282 0.733 101300
13 0.434 356.2281 0.724 101300
14 0.429 356.528 0.721 101300
15 0.356 359.2272 0.659 101300
16 0.345 359.7271 0.651 101300
17 0.309 361.1268 0.621 101300
18 0.293 362.1266 0.609 101300
19 0.26 363.6263 0.571 101300
20 0.254 363.9262 0.565 101300
21 0.246 364.2262 0.553 101300
22 0.182 367.9254 0.462 101300
23 0.181 368.0254 0.463 101300
24 0.177 368.2254 0.459 101300
25 0.142 370.6249 0.388 101300
26 0.14 370.7249 0.391 101300
27 0.137 371.0248 0.38 101300
28 0.12 372.3245 0.345 101300
29 0.116 372.5245 0.346 101300
30 0.104 373.6243 0.314 101300
31 0.072 376.2238 0.253 101300
32 0.07 376.4237 0.229 101300
33 0.069 376.6237 0.228 101300
1 1 341.8224 1 101320
2 0.9822 342.1224 0.9937 101320
3 0.938 343.0321 0.9776 101320
4 0.8603 344.6916 0.9495 101320
5 0.7595 346.9009 0.9122 101320
6 0.6698 349.1702 0.8732 101320
7 0.5387 352.7292 0.8113 101320
8 0.4686 354.9385 0.7754 101320
9 0.3501 359.3872 0.6923 101320
10 0.2213 365.3859 0.5618 101320
11 0.1713 368.2853 0.4882 101320
12 0.1115 373.0444 0.3562 101320
13 0.0756 375.9338 0.2622 101320
14 0.0628 376.9136 0.233 101320
15 0.0416 379.1032 0.1586 101320
16 0.0214 381.1128 0.0918 101320
17 0.0096 382.5425 0.0398 101320
18 0 383.6823 0 101320

Sieg, L. Chem.-Ing.-Tech., 1950, 22, 322-


326 Liquid-vapor equilibria in binary
systems of hydrocarbons of various types
Myers, H. S. Ind. Eng. Chem., 1955, 47,
2215 Vapor-liquid equilibrium data for
binary mixtures of paraffins and
aromatics.
Kogyo Gijutsu Shoreikai, 1969, 15, 397-
407 Separation of hydrocarbons. 2.
Vapor-liquid equilibriums of normal
paraffin aromatic systems
Michishita, T.; Arai, Y.; Saito, S. Kagaku
Kogaku, 1971, 35, 111-116 Vapor-liquid
equilibria of hydrocarbons at atmospheric
pressure

Klon-Palczewska, M.; Cholinski, J.;


Wyrzykowska-Stankiewicz, D. Chem.
Stosow., 1980, 24, 197
Hexane - m-Xylene Hexane - o-Xylene
1 n-Hexane 1 n-Hexane
2 m-Xylene 2 o-Xylene

Vapor Liquid Vapor


Total Total
mole mole Temperat mole
pressure No. pressure No.
fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
HEXANE HEXANE HEXANE

0.993 101300 1 1 341.9 1 101300 1


0.978 101300 2 0.9 344.5 0.983 101300 2
0.966 101300 3 0.812 346.9 0.974 101300 3
0.941 101300 4 0.74 348.9 0.963 101300 4
0.898 101300 5 0.673 351.1 0.952 101300 5
0.867 101300 6 0.557 355.3 0.932 101300 6
0.831 101300 7 0.352 366.3 0.846 101300 7
0.785 101300 8 0.296 371.2 0.798 101300 8
0.625 101300 9 0.249 375.8 0.744 101300 9
0.587 101300 10 0.148 388.3 0.566 101300 10
0.486 101300 11 0.095 396.4 0.413 101300 11
0.224 101300 12 0.063 401.7 0.295 101300 12
0.069 101300 13 0 412.2 0 101300 13
Gupta, B. S.; Lee, M. J. J. Chem. Eng. Data, 14
ita, T.; Arai, Y.; Saito, S. Kagaku 2012, 57, 1237-1243 Isobaric Vapor Liquid
1971, 35, 111-116 Vapor-liquid Equilibrium of Binary Systems of Hexane
of hydrocarbons at atmospheric or Octane with 1,2-Dimethylbenzene or
pressure 1,3-Dimethylbenzene at 101.3 kPa
Hexane - o-Xylene Hexane - n,n-dimethylformamide
1 n-Hexane
2 n,n-dimethylformamide

Liquid Vapor Liquid Vapor


Total Total
mole Temperat mole mole Temperat mole
pressure No. pressure
fraction ure (K) fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
HEXANE HEXANE HEXANE HEXANE

1 341.5 1 101300 1 1 341.8 1 101330


0.936 344.4 0.99 101300 2 0.995 341.9 0.996 101330
0.819 347.8 0.973 101300 3 0.989 341.95 0.992 101330
0.725 351.4 0.956 101300 4 0.975 342.1 0.983 101330
0.625 355.7 0.935 101300 5 0.963 342.3 0.977 101330
0.515 359.6 0.91 101300 6 0.951 342.5 0.972 101330
0.429 364.6 0.875 101300 7 0.926 342.95 0.962 101330
0.343 369.5 0.836 101300 8 0.882 343.75 0.948 101330
0.231 379.9 0.737 101300 9 0.006 417.35 0.125 101330
0.187 385.5 0.667 101300 10 0 426.15 0 101330
0.122 394 0.534 101300
0.074 402.6 0.393 101300 Blanco, B.; Beltran, S.; Cabezas, J. L.; Coca,
0.018 414.6 0.113 101300 J. J. Chem. Eng. Data, 1997, 42, 938-942
0 417.3 0 101300
Gupta, B. S.; Lee, M. J. J. Chem. Eng. Data,
2012, 57, 1237-1243 Isobaric Vapor Liquid
Equilibrium of Binary Systems of Hexane
or Octane with 1,2-Dimethylbenzene or
1,3-Dimethylbenzene at 101.3 kPa
Heptane - n,n-dimethylformamide Hexane - Dichloromethane
1 n-Heptane 1 n-Hexane
2 n,n-dimethylformamide 2 Dichloromethane

Liquid Vapor Liquid


Total
mole Temperat mole mole Temperat
No. pressure No.
fraction ure (K) fraction fraction ure (K)
(N/sqm)
HEPT HEPT HEX

1 0.938 370.225 0.92 101000 1 0.975 338.1834


2 0.868 370.125 0.905 101000 2 0.9 330.4849
3 0.744 369.825 0.9 101000 3 0.875 328.2855
4 0.6334 370.3249 0.8826 101000 4 0.84 326.4861
5 0.423 370.9248 0.863 101000 5 0.721 322.7872
6 0.3297 371.7247 0.852 101000 6 0.492 318.2885
7 0.2463 374.7241 0.8412 101000 7 0.438 317.4888
8 0.1748 377.4235 0.8127 101000 8 0.345 316.689
9 0.04 402.1186 0.65 101000 9 0.3 315.9892
10 0.292 315.8892
Zemlyanskaya, T. A.; Komarova, L. F.;
Kormina, L. A.; Garber, Yu. N. Zh. Prikl. 11 0.163 314.7896
Khim. (Leningrad), 1977, 50, 1159 12 0.115 314.4897
13 0.077 314.2897
14 0.072 314.2897

Luchkina, R. I.; Golubkov, Y. V.


Zhvanetskii, I. B.; Avdoshin, S. V. Zh
Khim. (Leningrad), 1984, 57, 186
Hexane - Chloroform Hexane - tetrachloromet
1 n-Hexane 1 n-Hexane
2 Chloroform 2 Tetrachloromethane

Vapor Liquid Vapor


Total Total
mole mole Temperat mole
pressure No. pressure No.
fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
HEX HEX HEX

0.868 101320 1 1 341.874 1 101320 1


0.627 101320 2 0.8945 339.654 0.841 101320 2
0.568 101320 3 0.7945 337.904 0.708 101320 3
0.517 101320 4 0.7085 336.624 0.617 101320 4
0.399 101320 5 0.6031 335.444 0.516 101320 5
0.2745 101320 6 0.5003 334.524 0.434 101320 6
0.2505 101320 7 0.4063 333.994 0.359 101320 7
0.216 101320 8 0.3002 333.594 0.28 101320 8
0.193 101320 9 0.2 333.534 0.204 101320 9
0.192 101320 10 0.0999 333.774 0.116 101320 10
0.124 101320 11 0 334.394
Kudryavtseva, 101320
L. S.; Susarev,0M. P. Zh. 11
0.0935 101320 Prikl. Khim. (Leningrad), 1963, 36, 1231- 12
1237 Liquid-vapor equilibrium in
0.07 101320 chloroform-hexane and acetone- 13
0.066 101320 chloroform systems. 14
15
16
hkina, R. I.; Golubkov, Y. V.;
kii, I. B.; Avdoshin, S. V. Zh. Prikl. 17
(Leningrad), 1984, 57, 1867 18
Hexane - tetrachloromethane Heptane - Chloroform
1 n-Heptane
Tetrachloromethane 2 Chloroform

Liquid Vapor Liquid Vapor


Total Total
mole Temperat mole mole Temperat mole
pressure No. pressure
fraction ure (K) fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
HEX HEX HEPT HEPT

0.974 341.9324 0.977 101000 1 0.9235 364.4761 0.7705 101325


0.919 342.0324 0.929 101000 2 0.826 357.2278 0.5625 101325
0.86 342.1324 0.875 101000 3 0.765 353.6789 0.475 101325
0.797 342.3323 0.821 101000 4 0.6395 348.3805 0.3405 101325
0.736 342.5322 0.767 101000 5 0.595 346.8809 0.308 101325
0.675 342.7322 0.714 101000 6 0.5515 345.3814 0.275 101325
0.615 343.0321 0.662 101000 7 0.459 342.8821 0.2155 101325
0.552 343.432 0.606 101000 8 0.2765 338.1834 0.118 101325
0.491 343.8318 0.552 101000 9 0.2395 337.4335 0.1 101325
0.484 343.8318 0.545 101000 10 0.102 334.884 0.041 101325
0.43 344.2317 0.495 101000
0.369 344.7316 0.438 101000 Loiseleur, B.; Clechet, P.; Merlin, J. C. Bull.
0.309 345.3314 0.378 101000 Soc. Chim. Fr., 1968, 11, 4390-8
0.252 346.0312 0.319 101000
0.193 346.731 0.255 101000
0.135 347.5307 0.188 101000
0.075 348.5304 0.112 101000
0.018 349.5301 0.028 101000
Rodger, A. J.; Hsu, C. C.; Furter, W. F. J.
Chem. Eng. Data, 1969, 14, 362 Vapor-
Liquid Equilibria for 23 Carbon
Tetrachloride-Hydrocarbon Syst.
Heptane - tetrachloromethane heptane - Propionic acid
1 n-Heptane 1 n-Heptane
2 Tetrachloromethane 2 Propionic acid

Liquid Vapor Liquid


Total
mole Temperat mole mole Temperat
No. pressure No.
fraction ure (K) fraction fraction ure (K)
(N/sqm)
HEPT HEPT HEPT

1 0.979 370.9248 0.963 101000 1 1 371.5147


2 0.918 369.0252 0.858 101000 2 0.994 370.9848
3 0.858 367.2256 0.764 101000 3 0.986 370.7448
4 0.791 365.3259 0.672 101000 4 0.927 371.2747
5 0.739 363.9262 0.604 101000 5 0.861 371.5347
6 0.678 362.4265 0.532 101000 6 0.624 373.5843
7 0.622 361.0268 0.469 101000 7 0.592 373.9842
8 0.562 359.6271 0.409 101000 8 0.535 375.064
9 0.503 358.3275 0.355 101000 9 0.332 378.6733
10 0.499 358.2275 0.35 101000 10 0.201 383.8622
11 0.436 356.9279 0.294 101000 11 0.103 391.8306
12 0.369 355.6283 0.242 101000 12 0.081 394.5301
13 0.304 354.4287 0.194 101000 13 0.061 397.8694
14 0.24 353.329 0.151 101000 14 0.034 403.9082
15 0.179 352.3293 0.111 101000 15 0.032 404.3081
16 0.119 351.4296 0.074 101000 16 0.022 406.9776
17 0.06 350.6298 0.037 101000 17 0.014 409.4671
18 0.024 350.13 0.013 101000 18 0.011 410.4569
Rodger, A. J.; Hsu, C. C.; Furter, W. F. J. 19 Malijevska,
0 414.4661
I.; Vlckova, D. Collect. C
Chem. Eng. Data, 1969, 14, 362 Vapor- Chem. Commun., 1985, 50, 2101 Va
Liquid Equilibria for 23 Carbon Liquid Equilibrium in Strongly Assoc
Tetrachloride-Hydrocarbon Syst. Systems. The Propionic Acid-n-Hep
System
acid Octane - Acetic acid Octane - Propionic acid
1 n-Octane 1 n-Octane
2 Acetic Acid 2 Propionic acid

Vapor Liquid Vapor


Total Total
mole mole Temperat mole
pressure No. pressure No.
fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
HEPT OCT OCT

1 101325 1 0.961 392.4969 0.77 101325 1


0.989 101325 2 0.864 386.3363 0.546 101325 2
0.984 101325 3 0.735 382.3558 0.429 101325 3
0.944 101325 4 0.58 380.0654 0.365 101325 4
0.913 101325 5 0.405 378.9052 0.324 101325 5
0.834 101325 6 0.226 379.0652 0.296 101325 6
0.817 101325 7 0.162 379.3753 0.282 101325 7
0.797 101325 8 0.125 379.7753 0.268 101325 8
0.723 101325 9 0.046 382.926 0.192 101325 9
0.629 101325 10 0.019 386.2663 0.11 101325 10
0.49 101325 11
Zieborak, K.; Brzostowski, W. Bull. Acad.
0.446 101325 Pol. Sci., Ser. Sci., Chim., Geol. Geogr., 12
0.372 101325 1958, 6, 169 13
0.253 101325 14
0.244 101325 15
0.187 101325 1
0.124 101325 2
0.102 101325 3
101325
0 Czech.
ka, I.; Vlckova, D. Collect. 4
ommun., 1985, 50, 2101 Vapour- 5
quilibrium in Strongly Associated
. The Propionic Acid-n-Heptane 6
System 7
8
9
10
11
12
Octane - Propionic acid Octane - Butyric acid
1 n-Octane
Propionic acid 2 n-Butyric acid

Liquid Vapor Liquid Vapor


Total Total
mole Temperat mole mole Temperat mole
pressure No. pressure
fraction ure (K) fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
OCT OCT OCT OCT

1 398.9287 1 101000 1 1 398.7193 1 101300


0.996 398.2285 0.987 101000 2 0.962441 397.9194 0.951433 101300
0.983 397.1282 0.948 101000 3 0.921429 397.8194 0.924282 101300
0.948 396.0279 0.889 101000 4 0.898125 397.7694 0.898669 101300
0.935 395.7278 0.875 101000 5 0.842015 398.1194 0.89695 101300
0.79 394.4274 0.756 101000 6 0.729571 398.8292 0.874803 101300
0.584 394.7275 0.651 101000 7 0.56646 400.3189 0.831945 101300
0.315 396.7281 0.529 101000 8 0.399401 403.4183 0.762005 101300
0.193 400.4292 0.439 101000 9 0.342875 404.7181 0.732118 101300
0.109 404.0302 0.335 101000 10 0.284876 406.8176 0.68891 101300
0.038 409.2312 0.169 101000 11 0.216504 409.6171 0.630466 101300
0.038 410.6315 0.118 101000 12 0.150322 413.6163 0.541349 101300
0.026 411.3316 0.084 101000 13 0.128925 415.8158 0.505417 101300
0.012 412.932 0.045 101000 14 0.080769 420.215 0.392929 101300
0 414.2322 0 101000 15 0.044695 426.6137 0.245466 101300
0.967 397.9284 0.918 99990 16 0.040408 428.3133 0.205827 101300
0.938 396.8281 0.878 99990 17 0.026006 430.313 0.151602 101300
0.888 396.0279 0.827 99990 18 0.007196 434.7125 0.037181 101300
0.766 395.1276 0.731 99990 19 0 437.6122 0 101300
0.701 394.9275 0.69 99990
Radwan, M. H.; Hanna, A. A. J. Chem. Eng.
0.649 392.927 0.66 99990 Data, 1976, 21, 285-8 Binary Azeotropes
0.595 394.5274 0.648 99990 Containing Butyric Acid
0.461 395.0276 0.566 99990
0.361 395.7278 0.512 99990
0.135 402.3298 0.337 99990
0.082 406.3306 0.234 99990
0.051 409.9314 0.12 99990
Johnson, A. I.; Furter, W. F.; Barry, T. W.
Can. J. Technol., 1954, 32, 179-86 A phase
equilibrium study of the system n-octane -
water - propionic acid
Johnson, A. I.; Ward, D. M.; Furter, W. F.
Can. J. Chem. Eng., 1957, 34, 514-8 Vapor-
liquid equilibrium data for system: n-
octane + propionic acid, with salt effect
Octane - isoButyric acid Hexane - Methyl formate
1 n-Octane 1 n-Hexane
2 n-Isobutyric acid 2 Methyl Formate

Liquid Vapor Liquid


Total
mole Temperat mole mole Temperat
No. pressure No.
fraction ure (K) fraction fraction ure (K)
(N/sqm)
OCT OCT HEX

1 1 398.7193 1 101300 1 1 341.76


2 0.956472 397.7294 0.935932 101300 2 0.978 333.45
3 0.905471 397.4195 0.895183 101300 3 0.9675 331
4 0.867914 397.2695 0.869183 101300 4 0.9366 325.36
5 0.842027 397.4195 0.860392 101300 5 0.8782 315.65
6 0.782766 397.6195 0.847829 101300 6 0.8191 311.55
7 0.68948 398.1194 0.819503 101300 7 0.758 308.2
8 0.545592 399.4291 0.765381 101300 8 0.711 306.72
9 0.409355 401.2188 0.702625 101300 9 0.6658 305.93
10 0.343109 402.5385 0.66214 101300 10 0.5992 304.76
11 0.235136 406.4377 0.574336 101300 11 0.5301 303.99
12 0.186207 408.5273 0.50501 101300 12 0.4596 303.53
13 0.140243 409.927 0.456481 101300 13 0.4055 303.3
14 0.13068 410.2969 0.446742 101300 14 0.3408 303.08
15 0.098914 412.5065 0.382382 101300 15 0.2747 302.91
16 0.09273 414.6361 0.342472 101300 16 0.2031 302.77
17 0.079815 415.6659 0.313315 101300 17 0.1571 302.73
18 0.079742 416.7157 0.297346 101300 18 0.1189 302.75
19 0.046129 419.5951 0.191884 101300 19 0.084 302.88
20 0 427.0136 0 101300 20 0.0633 303.07
21 0.0415 303.36
Radwan, M. H.; Hanna, A. A. J. Chem. Eng.
Data, 1976, 21, 285-8 Binary Azeotropes 22 0.0219 303.85
Containing Butyric Acid 23 0.0128 304.11
24 Ortega, 304.55 G.; de la Nue
0.0021 J.; Sabater,
25 Quintana,0 J. J. 304.7
J. Chem. Eng. Data,
52, 215-225 Isobaric Vapor-Liqu
Equilibrium Data and Excess Proper
Binary Systems Comprised of Al
Methanoates + Hexane
mate Hexane - Ethyl formate Hexane - propyl formate
1 n-Hexane 1 n-Hexane
2 n-Ethyl Formate 2 Propyl Formate

Vapor Liquid Vapor


Total Total
mole mole Temperat mole
pressure No. pressure No.
fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
HEX HEX HEX

1 101320 1 0.9927 340.89 0.9614 101300 1


0.7337 101320 2 0.9827 339.55 0.9136 101300 2
0.6653 101320 3 0.9719 338.35 0.8686 101300 3
0.5229 101320 4 0.9618 337.08 0.8308 101300 4
0.3714 101320 5 0.9426 335.65 0.7805 101300 5
0.3029 101320 6 0.9213 334.3 0.7308 101300 6
0.262 101320 7 0.8918 333.02 0.6835 101300 7
0.2385 101320 8 0.8548 331.16 0.6291 101300 8
0.2289 101320 9 0.8346 330.23 0.6029 101300 9
0.209 101320 10 0.8131 329.36 0.5771 101300 10
0.198 101320 11 0.7645 327.77 0.5252 101300 11
0.1905 101320 12 0.7444 327.11 0.5091 101300 12
0.1854 101320 13 0.7243 326.64 0.4946 101300 13
0.1796 101320 14 0.7221 326.62 0.4911 101300 14
0.1743 101320 15 0.7009 326.11 0.4757 101300 15
0.1631 101320 16 0.6768 325.66 0.4593 101300 16
0.1527 101320 17 0.6444 325.21 0.4414 101300 17
0.1403 101320 18 0.6194 324.86 0.4284 101300 18
0.1237 101320 19 0.5866 324.62 0.4192 101300 19
0.1097 101320 20 0.5534 324.28 0.3999 101300 20
0.0828 101320 21 0.522 324.01 0.3868 101300 21
0.0499 101320 22 0.4901 323.79 0.3728 101300 22
0.0343 101320 23 0.4513 323.6 0.3595 101300 23
, J.; Sabater, G.;0.0079 101320
de la Nuez, I.; 24 0.426 323.47 0.3479 101300 24
0 101320
a, J. J. J. Chem. Eng. Data, 2007, 25 0.3916 323.33 0.3345 101300 25
15-225 Isobaric Vapor-Liquid 26 0.358 323.25 0.3213 101300 26
m Data and Excess Properties of
y Systems Comprised of Alkyl 27 0.3222 323.23 0.3074 101300
Methanoates + Hexane 28 0.2908 323.21 0.2913 101300
29 0.2558 323.25 0.2745 101300
30 0.2256 323.34 0.2577 101300
31 0.1952 323.5 0.2374 101300
32 0.1655 323.71 0.2167 101300
33 0.1371 324.02 0.1923 101300
34 0.11 324.38 0.1649 101300
35 0.0814 324.82 0.1346 101300
36 0.0558 325.35 0.0976 101300
37 0.028 325.94 0.0527 101300
38 0.0096 326.84 0.0191 101300
39 0.0045 327.08 0.0097 101300
1 1 341.76 1 101320
2 0.9972 341.41 0.9866 101320
3 0.9569 337.13 0.8204 101320
4 0.9431 335.9 0.7942 101320
5 0.9253 334.85 0.738 101320
6 0.918 334.37 0.7237 101320
7 0.9151 334.12 0.7133 101320
8 0.8967 332.97 0.6822 101320
9 0.874 331.63 0.6392 101320
10 0.8503 330.46 0.6036 101320
11 0.8201 329.3 0.5639 101320
12 0.8041 328.72 0.5465 101320
13 0.7978 328.48 0.5397 101320
14 0.7519 327.17 0.5009 101320
15 0.6887 326.06 0.4635 101320
16 0.6676 325.85 0.4545 101320
17 0.6405 325.6 0.4434 101320
18 0.5952 324.84 0.4177 101320
19 0.5306 324.22 0.3886 101320
20 0.4692 323.81 0.3634 101320
21 0.4105 323.53 0.342 101320
22 0.3522 323.38 0.3202 101320
23 0.2946 323.31 0.2962 101320
24 0.2344 323.39 0.2677 101320
25 0.1764 323.66 0.2333 101320
26 0.1251 324.11 0.1922 101320
27 0.0866 324.67 0.1517 101320
28 0.0537 325.38 0.108 101320
29 0.0343 325.93 0.0729 101320
30 0.0165 326.56 0.0381 101320
31 0.0062 326.94 0.0153 101320
32 0 327.33 0 101320
Measurement and correlation of isobaric
vapour?liquid equilibrium data and excess
properties of ethyl methanoate with
alkanes (hexane to decane)
52, 215-225 Isobaric Vapor-Liquid
Equilibrium Data and Excess Properties of
Binary Systems Comprised of Alkyl
Methanoates + Hexane
Hexane - propyl formate Hexane - Butyl formate
1 n-Hexane
Propyl Formate 2 Butyl Formate

Liquid Vapor Liquid Vapor


Total Total
mole Temperat mole mole Temperat mole
pressure No. pressure
fraction ure (K) fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
HEXANE HEXANE HEXANE HEXANE

0 353.92 0 101320 1 0 380.13 0 101320


0.0187 352.6 0.063 101320 2 0.0049 378.49 0.0282 101320
0.0467 350.67 0.1455 101320 3 0.0131 377.36 0.0701 101320
0.0653 349.55 0.1885 101320 4 0.023 376.08 0.1176 101320
0.0884 348.45 0.2359 101320 5 0.0395 374.24 0.1831 101320
0.1156 347.25 0.2837 101320 6 0.0643 371.76 0.2678 101320
0.1451 346.01 0.3302 101320 7 0.102 368.22 0.3742 101320
0.173 345.05 0.3676 101320 8 0.1369 365.52 0.4502 101320
0.2106 344 0.4125 101320 9 0.1774 362.78 0.5199 101320
0.2771 342.56 0.472 101320 10 0.2112 360.6 0.566 101320
0.3077 341.82 0.4993 101320 11 0.2431 358.87 0.6059 101320
0.3579 341.25 0.5275 101320 12 0.2731 357.4 0.6351 101320
0.3959 340.85 0.551 101320 13 0.3193 355.27 0.6782 101320
0.434 340.42 0.57 101320 14 0.377 353.35 0.7128 101320
0.4714 340.07 0.5916 101320 15 0.4172 351.93 0.7391 101320
0.5357 339.64 0.6223 101320 16 0.4818 349.97 0.7784 101320
0.5861 339.37 0.6476 101320 17 0.5444 348.83 0.8014 101320
0.6402 339.2 0.6757 101320 18 0.6137 347.23 0.8339 101320
0.699 339.1 0.7076 101320 19 0.7005 345.84 0.8627 101320
0.7629 339.12 0.7468 101320 20 0.7806 344.42 0.8929 101320
0.8247 339.35 0.7915 101320 21 0.863 343.43 0.9264 101320
0.8757 339.74 0.8377 101320 22 0.9052 342.84 0.9469 101320
0.919 340.25 0.8841 101320 23 0.9519 342.36 0.9712 101320
0.9477 340.72 0.9204 101320 24 Ortega,
0.9802 J.; Sabater,
342.03 G.;0.9867 101320
de la Nuez, I.;
Ortega, J.; Sabater, G.;0.9587
0.9739 341.25 101320
de la Nuez, I.; 25 Quintana,1 J. J.341.76
J. Chem. Eng. Data, 101320
1 2007,
1 J. J.341.76
Quintana, 1 101320
J. Chem. Eng. Data, 2007, 52, 215-225 Isobaric Vapor-Liquid
52, 215-225 Isobaric Vapor-Liquid Equilibrium Data and Excess Properties of
Equilibrium Data and Excess Properties of Binary Systems Comprised of Alkyl
Binary Systems Comprised of Alkyl Methanoates + Hexane
Methanoates + Hexane
Hexane - diethyl ether Hexane - tetrahydrofuran
1 n-Hexane 1 n-Hexane
2 Diethyl Ether 2 Tetrahydrofuran

Liquid Vapor Liquid


Total
mole Temperat mole mole Temperat
No. pressure No.
fraction ure (K) fraction fraction ure (K)
(N/sqm)
HEX-01 HEX-01 HEX-01

1 1 341.8224 1 101320 1 1 341.8224


2 0.9572 337.8034 0.847 101320 2 0.9857 341.0427
3 0.9161 335.3439 0.7495 101320 3 0.9667 340.5128
4 0.8364 330.9148 0.6182 101320 4 0.9361 339.5831
5 0.7379 326.4761 0.4577 101320 5 0.8656 338.4833
6 0.6171 321.6975 0.3383 101320 6 0.8123 337.8834
7 0.5044 318.3285 0.2447 101320 7 0.5865 336.4137
8 0.4033 315.6693 0.1804 101320 8 0.4795 336.3137
9 0.3241 313.6099 0.1421 101320 9 0.3792 336.2338
10 0.2247 311.7305 0.0947 101320 10 0.293 336.3137
11 0.139 309.941 0.0608 101320 11 0.2501 336.4037
12 0.074 308.7814 0.0357 101320 12 0.181 336.6337
13 0.0468 308.2715 0.0218 101320 13 0.1131 337.0836
14 0.0298 307.9816 0.0149 101320 14 0.055 337.9934
15 0.0164 307.7317 0.0088 101320 15 0.0286 338.4233
16 0 307.6217 0 101320 16 0.0084 338.9532
1 1 341.8324 1 101325 17 0 339.1532
2 0.982 340.123 0.9071 101325 1 0.927 340.3429
3 0.9393 337.8134 0.7852 101325 2 0.906 339.973
4 0.9191 335.5639 0.7346 101325 3 0.881 339.5031
5 0.8991 334.944 0.6917 101325 4 0.848 339.0032
6 0.8006 329.6851 0.5623 101325 5 0.827 338.7033
7 0.6962 326.2461 0.45 101325 6 0.771 338.1034
8 0.5757 322.5372 0.3153 101325 7 0.725 337.5735
9 0.4998 319.5981 0.2577 101325 8 0.648 337.0036
10 0.4008 316.4791 0.1702 101325 9 0.561 336.4937
11 0.306 314.3597 0.1222 101325 10 0.472 336.2038
12 0.2011 311.9704 0.0621 101325 11 0.407 336.1538
13 0.1006 309.2112 0.0321 101325 12 0.269 336.3737
14 0.0808 308.9213 0.0237 101325 13 0.218 336.6237
15 0.0633 308.8014 0.0194 101325 14 0.158 337.0036
16 0.0448 308.5214 0.014 101325 15 0.106 337.3335
17 0.0244 308.1016 0.0067 101325 16 0.077 337.7534
18 0 307.7417 0 101325 17 0.055 338.0634
18 0.034 338.4233
Klon-Palczewska, M.; Cholinski, J.;
Wyrzykowska-Stankiewicz, D. Chem. 1 0.9164 340
Stosow., 1980, 24, 197 2 0.7876 338.25
3 0.6725 337.3
Goloborodkina, R. V.; Beregovykh, V. V.;
Babich, S. V.; Timoveev, V. S.; L'vov, S. V. 4 0.6218 336.88
Khim. -Farm. Zh., 1981, 15, 79 5 0.5801 336.47
6 0.519 336.42
7 0.4869 336.3
8 0.4472 336.2
9 0.3879 336.17
10 0.3518 336.26
11 0.2862 336.36
12 0.2454 336.65
13 0.1896 336.75
14 0.1604 336.87
15 0.1279 337.05
16 0.1076 337.2
17 0.0906 337.55
18 0.0755 337.86
19 0.0585 338.17
20 0.0431 338.36
21 0.0387 338.47
22 0.0251 338.57

Klon-Palczewska, M.; Cholinski,


Wyrzykowska-Stankiewicz, D. Ch
Stosow., 1980, 24, 197
Collect. Czech. Chem. Commun., 19
1159 Liquid-vapour and liquid-liq
equilibria in the tetrahydrofuran(1
hexane(2) + water(3) system
Xie, Q.; Guan, G. H. Huaxue Gongc
2010, 38(4), 61-64,72 Isobaric
vapor2liquid equilibrium for
tetrahydrofuran2water2n2hexane s
furan Heptane - Diisopropyl ether Heptane - tetrahydrofura
1 n-Heptane 1 n-Heptane
2 Diisopropyl Ether 2 Tetrahydrofuran

Vapor Liquid Vapor


Total Total
mole mole Temperat mole
pressure No. pressure No.
fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
HEX-01 HEPT-01 HEPT-01

1 101320 1 0.813 363.423 0.64 101320 1


0.9715 101320 2 0.697 358.923 0.49 101320 2
0.9569 101320 3 0.646 357.423 0.433 101320 3
0.9006 101320 4 0.584 355.323 0.368 101320 4
0.8048 101320 5 0.502 352.823 0.29 101320 5
0.7051 101320 6 0.455 351.5232 0.251 101320 6
0.5593 101320 7 0.366 349.3234 0.188 101320 7
0.4629 101320 8 0.287 347.3236 0.141 101320 Chart Title8
0.3976 101320 9 Vijayaraghavan,
0.146 344.1239
S.1.2 0.068 101320
V.; Deshpande, P. K.; 9
0.3449 101320 10 Kuloor, N. R. 342.324
0.068 J. Chem. Eng.0.028 101320
Data, 1967, 12, 10
0.2863 101320 15 Vapor-Liquid Equilibrium
1 Data for the 11
System Diisopropyl Ether- n-Heptane and
0.2124 101320 Diisopropyl Ether-Carbon Tetrachloride at 12
101320 0.8 13
0.1604 Medium Press.
0.0721 101320 14
0.6
0.042 101320 15
0.009 101320 0.4 16
0 101320 17
0.892 101320 0.2 18
0.865 101320 19
101320 0
0.828 0 0.2 0.4 0.6 20 0.8
0.788 101320 21
0.764 101320 22
0.708 101320 23
0.659 101320 24
0.592 101320 25
0.52 101320 26
0.454 101320 27
0.405 101320
0.3 101320
0.266 101320
0.202 101320
0.146 101320
0.112 101320
0.083 101320
0.056 101320
0.8372 100000
0.7217 100000
0.618 100000
0.5735 100000
0.5363 100000
0.488 100000
0.4611 100000
0.4316 100000
0.388 100000
0.3604 100000
0.3006 100000
0.2687 100000
0.2252 100000
0.1993 100000
0.1668 100000
0.1434 100000
0.1232 100000
0.1049 100000
0.0834 100000
0.0697 100000
0.0589 100000
0.0446 100000

Palczewska, M.; Cholinski, J.;


kowska-Stankiewicz, D. Chem.
Stosow., 1980, 24, 197
zech. Chem. Commun., 1980, 45,
iquid-vapour and liquid-liquid
a in the tetrahydrofuran(1) + n-
xane(2) + water(3) system
Guan, G. H. Huaxue Gongcheng,
10, 38(4), 61-64,72 Isobaric
por2liquid equilibrium for
ofuran2water2n2hexane system
Heptane - tetrahydrofuran Hexane - Acetone
n-Heptane 1 n-Hexane
Tetrahydrofuran 2 n-Acetone

Liquid Vapor Liquid Vapor


Total Total
mole Temperat mole mole Temperat mole
pressure No. pressure
fraction ure (K) fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
HEPT-01 HEPT-01 HEX-01 HEX-01

1 371.51 1 101300 1 0.924 331.2945 0.657 101320


0.9864 370.16 0.9497 101300 2 0.9 328.9253 0.621 101320
0.9669 368.46 0.8869 101300 3 0.803 325.5763 0.528 101320
0.9278 365.56 0.7801 101300 4 0.753 324.4766 0.5 101320
0.8999 363.73 0.7157 101300 5 0.735 324.0567 0.478 101320
0.8721 361.95 0.6565 101300 6 0.731 324.0367 0.477 101320
0.8366 360.07 0.5971 101300 7 0.569 322.8471 0.417 101320
hart Title 0.8051 358.41 0.5462 101300 8 0.564 322.977 0.423 101320
0.7782 357 0.5084 101300 9 0.479 322.8471 0.403 101320
0.7403 355.41 0.4632 101300 10 0.441 322.7571 0.39 101320
0.7034 353.95 0.425 101300 11 0.318 322.7271 0.345 101320
0.6612 352.39 0.3852 101300 12 0.247 322.8171 0.316 101320
0.6227 351.2 0.3513 101300 1 1 341.874 1 101325
0.5803 349.74 0.3142 101300 2 0.9058 332.0343 0.665 101325
0.5441 348.53 0.2829 101300 3 0.8014 326.6359 0.517 101325
0.5059 347.54 0.2593 101300 4 0.7011 324.6965 0.46 101325
0.4557 346.37 0.2296 101300 5 0.6017 323.6668 0.416 101325
0.413 345.4 0.2058 101300 6 0.5005 323.127 0.39 101325
0.3338 343.82 0.1656 101300 7 0.4001 322.9071 0.384 101325
0.6 0.2908
0.8 343.06
1 0.1451
1.2 101300 8 0.3001 322.967 0.346 101325
0.2258 342.09 0.1167 101300 9 0.1993 323.4369 0.3 101325
0.1784 341.37 0.0941 101300 10 0.0985 324.8865 0.205 101325
0.1409 340.83 0.0759 101300 11 0 329.3751 0 101325
0.1076 340.39 0.0593 101300 1 0.9894 340.07 0.9425 101320
0.0751 339.97 0.0426 101300 2 0.9868 338.78 0.9006 101320
T.-B.; Tang,339.5
Du,0.0366 Y. P. Fluid101300
M.; Chen,0.0194 Phase 3 0.9705 336.35 0.8189 101320
339.12
Equilib.,0 2001, 0 101300
192, 71-83 Vapor-liquid 4 0.9369 333.36 0.7251 101320
equilibria of the binary mixtures of 5 0.8968 330 0.6236 101320
tetrahydrofuran with 2,2,4-
trimethylpentane, methylcyclohexane and 6 0.8204 326.82 0.5334 101320
n-heptane at 101.3 kPa 7 0.7549 325.08 0.4827 101320
8 0.695 324.16 0.4554 101320
9 0.6254 323.43 0.4227 101320
10 0.5166 322.88 0.3958 101320
11 0.4869 322.78 0.3898 101320
12 0.455 322.69 0.3828 101320
13 0.4058 322.67 0.3706 101320
14 0.3514 322.67 0.3562 101320
15 0.3069 322.69 0.343 101320
16 0.2685 322.82 0.3294 101320
17 0.2408 322.93 0.3171 101320
18 0.2047 323.16 0.2988 101320
19 0.142 323.83 0.2572 101320
20 0.1001 324.6 0.216 101320
21 0.0622 325.73 0.1614 101320
22 0.0319 327.02 0.1001 101320
23 0.0174 327.84 0.0617 101320
24 0.005 328.67 0.0237 101320
M. S. Zh. Prikl. Khim. (Leningrad), 1961,
34, 323-331 Liquid-vapor equilibrium in
binary systems of hydrocarbons with
acetone
Prikl. Khim. (Leningrad), 1963, 36, 1471
Liquid-vapor equilibrium in the systems
acetone-hexane and hexane-ethyl alcohol
at 35, 45, and 55 deg. and 760 mm of Hg.
Rodil, E.; Soto, A. J. Chem. Eng. Data,
2002, 47, 849-854 Vapor-Liquid
Equilibrium of the Ternary System Ethyl
Acetate + Hexane + Acetone at 101.32 kPa
Hexane - 2-Butanone Heptane - Acetone
1 n-Hexane 1 n-Heptane
2 2-Butanone 2 n-Acetone

Liquid Vapor Liquid


Total
mole Temperat mole mole Temperat
No. pressure No.
fraction ure (K) fraction fraction ure (K)
(N/sqm)
HEX-01 HEX-01 HEPT-01

1 1 341.79 1 101300 1 0.9578 360.127


2 0.933 339.6 0.876 101300 2 0.8098 344.6316
3 0.86 338.3 0.792 101300 3 0.7392 337.6335
4 0.783 337.64 0.735 101300 4 0.7129 337.1336
5 0.706 337.42 0.691 101300 5 0.5752 334.1342
6 0.628 337.38 0.652 101300 6 0.4347 331.3347
7 0.553 337.59 0.619 101300 7 0.3859 331.1348
8 0.474 337.95 0.584 101300 8 0.2381 329.935
9 0.399 338.54 0.55 101300 9 Zacharias, 329.4352
0.1063 A.; Srinivasan, D.; Rau, M
10 0.328 339.36 0.511 101300 Indian J. Technol., 1976, 14, 162 Iso
vapor-liquid equilibria for the syst
11 0.262 340.45 0.465 101300 acetone + n-heptane and n- hexa
12 0.197 341.97 0.412 101300 trichloroethylene.
13 0.132 344.15 0.333 101300
14 0.071 347.18 0.221 101300
15 Lladosa,
0.002 352.4 N. F.;0.009
E.; Martinez, Monton,101300
J. B. ;
16 Torre, J.0 d. l. 352.68 101300
0 2011,
Fluid Phase Equilib.,
307, 24-29 Measurements and correlation
of vapour liquid equilibria of 2-butanone
and hydrocarbons binary systems at two
different pressures
Heptane - 2-butanone Benzene - Toluene
1 n-Heptane 1 n-Benzene
2 2-Butanone 2 n-Toluene

Vapor Liquid Vapor


Total Total
mole mole Temperat mole
pressure No. pressure No.
fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
HEPT-01 HEPT-01 HEPT-01

0.6755 101000 1 1 371.4238 1 101000 1


0.3221 101000 2 0.9967 369.2236 0.94 101000 2
0.263 101000 3 0.973 366.8234 0.859 101000 3
0.2546 101000 4 0.926 362.523 0.715 101000 4
0.193 101000 5 0.878 359.523 0.6245 101000 5
0.1769 101000 6 0.77 355.373 0.505 101000 6
0.1689 101000 7 0.646 353.073 0.428 101000 7
0.1408 101000 8 0.631 353.173 0.422 101000 8
s, A.; Srinivasan,0.0926 101000
D.; Rau, M. G. S. 9 0.525 351.4732 0.368 101000 9
Technol., 1976, 14, 162 Isobaric 10 0.493 351.3232 0.355 101000 10
quid equilibria for the systems
e + n-heptane and n- hexane + 11 0.3885 350.5733 0.309 101000 11
trichloroethylene. 12 0.307 350.1233 0.273 101000 12
13 0.294 350.2733 0.264 101000 1
14 0.235 350.1233 0.2315 101000 2
15 0.136 350.3733 0.168 101000 3
16 0.068 351.2232 0.092 101000 4
17 0.027 351.8231 0.046 101000 5
18 0.006 352.1731 0.013 101000 6
19 0 352.5731 0 101000 7
1 0.982 369.05 0.919 101300 8
2 0.944 365.25 0.787 101300 9
3 0.864 359.31 0.623 101300 10
4 0.825 357.61 0.581 101300 11
5 0.749 354.99 0.502 101300 12
6 0.67 353.43 0.443 101300 13
7 0.587 352.29 0.401 101300 1
8 0.508 351.45 0.361 101300 2
9 0.422 350.75 0.325 101300 3
10 0.317 350.68 0.273 101300 4
11 0.129 350.85 0.16 101300 5
12 0.044 351.72 0.072 101300 6
Steinhauser, H. H.; White, R. R. Ind. Eng. 7
Chem., 1949, 41, 2912-20 Vapor-Liquid
Equilibria
Lladosa, Data for Ternary
E.; Martinez, Mixtures
N. F.; Monton, J. B. ; 8
heptane
Torre, J. - toluene
d. l. Fluid system 2011,
Phase Equilib., 9
307, 24-29 Measurements and correlation 10
of vapour liquid equilibria of 2-butanone
and hydrocarbons binary systems at two 11
different pressures 1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
1
2
3
4
5
1
2
3
4
5
6
7
8
9
10
11
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
1
2
3
4
5
6
7
8
9
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
1
2
3
4
5
6
7
8
9
10
11
12
13
1
2
3
4
5
6
7
8
9
10
11
12
13
14
Benzene - Toluene Benzene - Ethylbenzene
n-Benzene 1 n-Benzene
2 Ethylbenzene

Liquid Vapor Liquid Vapor


Total Total
mole Temperat mole mole Temperat mole
pressure No. pressure
fraction ure (K) fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
BENZE-01 BENZE-01 BENZE-01 BENZE-01

0 383.7261 0 101320 1 0 409.2971 0 101320


0.088 379.2252 0.212 101320 2 0.009 408.4273 0.033 101320
0.2 375.3244 0.37 101320 3 0.017 407.6575 0.059 101320
0.3 371.7239 0.5 101320 4 0.03 406.0478 0.106 101320
0.397 368.3235 0.618 101320 5 0.165 393.1104 0.458 101320
0.489 365.2232 0.71 101320 6 0.302 382.7724 0.664 101320
0.592 362.523 0.789 101320 7 0.438 374.984 0.785 101320
0.7 359.923 0.853 101320 8 0.601 367.0756 0.879 101320
0.803 357.523 0.914 101320 9 0.753 361.1368 0.937 101320
0.903 355.423 0.957 101320 10 0.902 356.0782 0.979 101320
0.95 354.323 0.979 101320 11 0.945 354.7486 0.989 101320
1 353.323 1 101320 12 0.966 354.2187 0.993 101320
0 383.7361 0 101320 13 1 353.209 1 101320
0.05 381.4857 0.1084 101320 1 0.0767 404.05 0.2044 101592
0.1 379.3452 0.2057 101320 2 0.1153 401.4 0.2932 101592
0.2 375.3644 0.3723 101320 3 0.1671 397.85 0.4051 101592
0.3 371.7439 0.5084 101320 4 0.2372 392.7 0.5291 101592
0.4 368.4235 0.6206 101320 5 0.2845 390 0.6017 101592
0.5 365.3732 0.7137 101320 6 0.3435 386 0.6778 101592
0.6 362.563 0.7916 101320 7 0.3845 383.25 0.7247 101592
0.7 359.963 0.8571 101320 8 0.42 381.25 0.763 101592
0.8 357.553 0.9125 101320 9 0.4951 376.65 0.8257 101592
0.9 355.313 0.9597 101320 10 0.6138 370.05 0.9034 101592
0.95 354.253 0.9806 101320 11 0.7787 361.7 0.9627 101592
1 353.223 1 101320 12 0.8468 358.85 0.9783 101592
0 383.7261 0 101320 13 0.8974 356.85 0.9891 101592
0.107 378.9252 0.219 101320 14 0.9101
Kesselman, 356.4
W. 0.991 G.101592
D.; Hollenbach, E.;
0.207 374.9244 0.381 101320 Myers, A. L.; Humphreys, A. E. J. Chem.
Eng. Data, 1968, 13, 34-6 Vapor-Liquid
0.303 371.4238 0.509 101320 Equilibrium Datsa for Benzene-
0.393 368.4235 0.609 101320 Alkylbenzene Systems
0.486 365.6233 0.696 101320 Kutsarov, R.; Ralev, N.; Sharlopov, V. Zh.
Prikl. Khim. (S.-Peterburg), 1993, 66, 567-
0.578 363.023 0.769 101320 73 Liquid-vapor phase equilibria of binary
0.673 360.523 0.835 101320 systems from C6-8 aromatic hydrocarbons
0.773 358.123 0.893 101320
0.875 355.823 0.945 101320
1 353.223 1 101320
0 383.7461 0 101000
0.042 381.8758 0.089 101000
0.047 381.5457 0.104 101000
0.132 377.995 0.257 101000
0.183 376.1246 0.334 101000
0.219 374.6443 0.395 101000
0.325 370.8838 0.53 101000
0.407 368.1335 0.619 101000
0.483 365.8833 0.688 101000
0.551 363.8831 0.742 101000
0.628 361.753 0.8 101000
0.712 359.533 0.853 101000
0.81 357.223 0.911 101000
0.9 355.113 0.958 101000
0.904 355.043 0.96 101000
0.941 354.303 0.973 101000
1 353.223 1 101000
0 383.7422 0 101320
0.081 380.163 0.17 101320
0.268 372.9644 0.455 101320
0.505 365.086 0.71 101320
1 353.209 1 101320
0 383.7223 0 101320
0.1 379.3231 0.208 101320
0.2 375.3239 0.372 101320
0.3 371.7247 0.507 101320
0.4 368.4253 0.619 101320
0.5 365.4259 0.713 101320
0.6 362.5265 0.791 101320
0.7 359.927 0.857 101320
0.8 357.5277 0.912 101320
0.9 355.3284 0.959 101320
1 353.229 1 101320
0.052 381.8226 0.11 101300
0.083 380.3229 0.172 101300
0.119 379.0232 0.238 101300
0.141 378.2234 0.274 101300
0.173 377.0236 0.322 101300
0.194 375.9238 0.36 101300
0.224 374.6241 0.402 101300
0.253 373.7243 0.434 101300
0.299 372.1246 0.501 101300
0.314 371.4247 0.523 101300
0.366 369.7251 0.581 101300
0.433 367.8254 0.643 101300
0.502 365.8258 0.706 101300
0.571 363.8262 0.761 101300
0.621 362.2266 0.801 101300
0.705 360.227 0.853 101300
0.769 358.4275 0.889 101300
0.82 357.3278 0.919 101300
0.879 356.2281 0.946 101300
0.931 354.9285 0.968 101300
0.961 354.4287 0.983 101300
0.008 383.9 0.018 101300
0.022 383.17 0.051 101300
0.077 380.45 0.17 101300
0.088 379.95 0.191 101300
0.23 373.94 0.424 101300
0.352 369.53 0.573 101300
0.449 366.44 0.668 101300
0.519 364.37 0.727 101300
0.599 362.2 0.786 101300
0 383.76 0 101330
0.0333 382.65 0.0714 101330
0.078 380.58 0.1625 101330
0.1136 379.05 0.2323 101330
0.2056 375.25 0.3757 101330
0.2588 373.35 0.4511 101330
0.3179 371.34 0.524 101330
0.3731 369.59 0.5858 101330
0.3952 368.88 0.6049 101330
0.4616 366.64 0.6761 101330
0.5326 364.4 0.7375 101330
0.6125 362.28 0.7935 101330
0.6742 360.62 0.8353 101330
0.7193 359.65 0.8622 101330
0.7832 358 0.9002 101330
0.8732 355.97 0.943 101330
0.9315 354.68 0.97 101330
0.9767 353.67 0.99 101330
1 353.25 1 101330
0.0374 382.25 0.0821 101300
0.0703 380.85 0.149 101300
0.1061 379.35 0.2167 101300
0.1347 378.15 0.2678 101300
0.185 376.18 0.3495 101300
0.2047 375.45 0.3795 101300
0.229 374.55 0.4148 101300
0.2935 372.2 0.5007 101300
0.3763 369.41 0.5959 101300
0.3841 369.16 0.6042 101300
0.4553 366.95 0.6739 101300
0.5432 364.35 0.7486 101300
0.6391 361.75 0.8181 101300
0.731 359.45 0.8749 101300
0.8149 357.45 0.9197 101300
0.9148 355.25 0.9658 101300
0 383.8 0 101300
0.087 380.2 0.175 101300
0.131 378.4 0.242 101300
0.265 373.5 0.462 101300
0.362 369.8 0.568 101300
0.483 366.3 0.69 101300
0.489 366.3 0.69 101300
0.598 362.9 0.792 101300
0.633 362.1 0.798 101300
0.778 358.5 0.893 101300
0.783 358.5 0.893 101300
0.901 355.8 0.957 101300
1 353.3 1 101300
0 383.82 0 101300
0.071 380.67 0.148 101300
0.134 377.99 0.265 101300
0.205 375.24 0.376 101300
0.293 372 0.497 101300
0.375 369.18 0.593 101300
0.456 366.67 0.672 101300
0.543 364.05 0.747 101300
0.639 361.41 0.817 101300
0.731 359.07 0.873 101300
0.804 357.37 0.91 101300
0.903 355.2 0.957 101300
0.951 354.25 0.979 101300
1 353.27 1 101300

Kirschbaum, E.; Gerstner, F. Z. Ver. Deut. Ing., Verfahrenstech., 1939, 10, 2460
Rollet, A.-P.; Elkaim, G.; Toledano, P.; Senez, M. C. R. Hebd. Seances Acad. Sci., 1956, 242, 2560-3 Vapor-liquid e
Schuberth, H. J. Prakt. Chem., 1958, 6, 129-38 Prediction of vapor-liquid equilibrium data for ideal binary system
Heertjes, P. M. Chem. Process Eng. (London), 1960, 41, 385-7 Determination of Vapor-Liquid Equilibria of Binary
Kesselman, W. D.; Hollenbach, G. E.; Myers, A. L.; Humphreys, A. E. J. Chem. Eng. Data, 1968, 13, 34-6 Vapor-Liq
Meeboer, B. Recommended Test Mixtures for Distillation Columns, 1969, Eur- op. Fed. Chem. Eng., Zuiderweg,
Michishita, T.; Arai, Y.; Saito, S. Kagaku Kogaku, 1971, 35, 111-116 Vapor-liquid equilibria of hydrocarbons at atm
Gultekin, N. J. Chem. Eng. Data, 1990, 35, 130 Vapor-Liquid Equilibria at 1 atm. for Binary and Ternary Systems C
Jin, Z.; Hu, A.; Liu, K. Chin. J. Chem. Eng., 1993, 1, 47-51 Vapor-liquid equilibrium for ternary mixtures of benzen
Huang, X.; Xia, S.; Ma, P.; Song, S.; Ma, B. J. Chem. Eng. Data, 2008, 53, 252-255 Vapor Liquid Equilibrium of N-F
Gupta, B. S.; Lee, M. J. Fluid Phase Equilib., 2011, 313, 190-195 Isobaric vapor-liquid equilibrium for the binary m
Yang, S.; Wang, Y.; Wang, X.; Zhu, Y.; Chen, N. Fluid Phase Equilib., 2013, 337, 109-114 Isobaric vapor-liquid equ
Toluene - Ethylbenzene Benzene - n,n-dimethylformamide
1 n-Toluene 1 n-Benzene
2 Ethylbenzene 2 n,n-dimethylformamide

Liquid Vapor Liquid


Total
mole Temperat mole mole Temperat
No. pressure No.
fraction ure (K) fraction fraction ure (K)
(N/sqm)
TOL-01 TOL-01 BENZ-01

1 0.9755 383.85 0.9785 101325 1 1 353.223


2 0.9474 384.05 0.9591 101325 2 0.8 358.123
3 0.8791 384.8 0.9215 101325 3 0.655 364.1231
4 0.8122 385.6 0.8855 101325 4 0.56 368.3235
5 0.7657 386 0.8615 101325 5 0.35 379.1252
6 0.704 386 0.8615 101325 6 0.2 392.1269
7 0.6231 388.45 0.7788 101325 7 0.1 404.6303
8 0.553 389.85 0.7333 101325 8 0.055 413.132
9 0.5084 391.2 0.6992 101325 9 0 426.5354
10 0.4516 392.6 0.6531 101325 1 0.82 357.5277
11 0.3979 394.25 0.6026 101325 2 0.647 362.1266
12 0.3141 396.55 0.5161 101325 3 0.465 368.7253
13 0.2704 398.25 0.4626 101325 4 0.385 373.6243
14 0.2287 399.7 0.4092 101325 5 0.31 378.0234
15 0.1909 400.85 0.3547 101325 6 0.238 384.5221
16 0.1466 402.95 0.2872 101325 7 0.154 391.8206
17 0.112 404.3 0.2265 101325 1 1 353.25
18 0.0738 405.9 0.1576 101325 2 0.961 354.1
19 0.0387 407.45 0.0854 101325 3 0.892 356.35
20 0.0114 408.65 0.0264 101325 4 0.74 360.35
21 0.006 408.9 0.0139 101325 5 0.605 365.75
6 0.508 368.4
Kutsarov, R.; Ralev, N.; Sharlopov, V. Zh. 7 0.395 374.3
Prikl. Khim. (S.-Peterburg), 1993, 66, 567-
73 Liquid-vapor phase equilibria of binary 8 0.314 381.25
systems from C6-8 aromatic hydrocarbons 9 0.222 389.75
10 0.105 405.8
11 Delzenne, 421.25Eng. Sci., 1953,
0.023 A. Chem.
12 Liquid-vapor
0 426.15
equilibrium: 2 a benz
dimethylformamide system under
atmosphere
Zaretskii, M. absolute
I.; Kogan,bV.methyl alco
B.; Konon
dimethylformamide
F.; Podolyak, V. G.system under
Zh. Prikl. Khi
atmosphere
(Leningrad), 1971, 44,absolute
579 Liquid-v
equilibrium in systems formed
thiophene and benzene with n,
dimethylformamide and n-
methylpyrrolidone

Blanco, B.; Beltran, S.; Cabezas, J. L.


J. J. Chem. Eng. Data, 1997, 42, 938
242, 2560-3 Vapor-liquid equilibrium for the benzene + toluene system
data for ideal binary systems and testing with a new equilibrium apparatus
-Liquid Equilibria of Binary Mixtur
a, 1968, 13, 34-6 Vapor-Liquid Equilibrium Datsa for Benzene-Alkylbenzene Systems
d. Chem. Eng., Zuiderweg, F. J., Ed., Inst. Chem. Eng.: London,
bria of hydrocarbons at atmospheric pressure
nary and Ternary Systems Composed of Benzene, Toluene, and m-Xylene
ernary mixtures of benzene, toluene, and p- xylene
r Liquid Equilibrium of N-Formylmorpholine with Toluene and Xylene at 101.33 kPa
quilibrium for the binary mixtures of nonane with cyclohexane, toluene, m-xylene, or p-xylene at 101.3 kPa
4 Isobaric vapor-liquid equilibrium of binary systems of decane with p-, o-, m-xylene at 20 kPa
hylformamide Toluene - n,n-dimethylformamide Benzene - Chloroform
1 n-Toluene 1 n-Benzene
2 n,n-dimethylformamide 2 Chloroform

Vapor Liquid Vapor


Total Total
mole mole Temperat mole
pressure No. pressure No.
fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
BENZ-01 TOL-01 TOL-01

1 101320 1 0.905 384.0222 0.947 101325 1


0.975 101320 2 0.835 385.122 0.923 101325 2
0.945 101320 3 0.752 386.1218 0.887 101325 3
0.925 101320 4 0.696 387.3215 0.846 101325 4
0.835 101320 5 0.644 388.1214 0.835 101325 5
0.69 101320 6 0.487 391.9206 0.746 101325 6
0.49 101320 7 0.357 399.919 0.634 101325 7
0.355 101320 8 0.29 405.6179 0.57 101325 8
0 101320 9 0.155 417.5155 0.402 101325 9
0.9675 101000 10 0.092 422.4145 0.268 101325 10
0.95 101000 1 0.837 384.2222 0.916 101320 11
0.8825 101000 2 0.785 384.6221 0.89 101320 12
0.8785 101000 3 0.693 385.3219 0.87 101320 13
0.835 101000 4 0.585 387.7215 0.836 101320 1
0.755 101000 5 0.455 389.4211 0.754 101320 2
0.66 101000 6 0.209 401.1188 0.512 101320 3
1 101330 1 0.936 384.1222 0.976 101000 4
0.995 101330 2 0.762 386.9216 0.881 101000 5
0.986 101330 3 0.667 388.7213 0.806 101000 6
0.964 101330 4 0.6 390.021 0.781 101000 7
0.934 101330 5 0.548 391.2208 0.7579 101000 8
0.91 101330 6 0.4721 392.7205 0.7267 101000 9
0.863 101330 7 0.364 395.5199 0.6626 101000 10
0.812 101330 8 0.067 412.7165 0.298 101000 11
0.716 101330 1 0.9129 386.4 0.9412 100920 12
0.503 101330 2 0.7899 387.8 0.8763 100920 13
1953,101330
0.142
, A. Chem. Eng. Sci., 2, 220 3 0.684 389.4 0.8402 100920 14
apor equilibrium: 2 a 0benzene 101330
+ 4 0.6004 390.6 0.8015 100920 15
ylformamide system under one 5 0.5133 392.6 0.7701 100920 16
ere
M. absolute
I.; Kogan,bV.methyl alcoholN.
B.; Kononov, +
ylformamide
odolyak, V. G.system under
Zh. Prikl. Khim.one 6 0.4195 394.6 0.7417 100920 17
atmosphere
ad), 1971, 44,absolute
579 Liquid-vapor 7 0.3428 397.8 0.7109 100920 18
ibrium in systems formed by 8 0.2689 402.4 0.6584 100920 19
hene and benzene with n, n-
methylformamide and n- 9 0.185 408.9 0.5723 100920 1
methylpyrrolidone 10 0.1211 414.2 0.4795 100920 2
11 0.05897 418.2 0.3152 100920 3
.; Beltran, S.; Cabezas, J. L.; Coca, 12 0.04206 420.3 0.2134 100920 4
m. Eng. Data, 1997, 42, 938-942 Ababi, V.; Bilba, N. An. Stiint. Univ. "A. I. 5
Cuza" Iasi, Sect. IC, 1968, 14, 155 Liquid-
vapor equilibriums in systems with 6
dimethylformamide: I. 7
Zaretskii, M. I.; Kogan, V. B.; Kononov, N. 8
F.; Miroshnichenko, A. A.; Usyshkina, I. V.;
F.; Miroshnichenko, A. A.; Usyshkina, I. V.;
Podolyak, V. G. Zh. Prikl. Khim. 9
(Leningrad), 1974, 47, 2087-91 10
11
Zemlyanskaya, T. A.; Komarova, L. F.;
Kormina, L. A.; Garber, Yu. N. Zh. Prikl. 1
Khim. (Leningrad), 1977, 50, 1159 2
Chem. Eng., 2006, 14, 4;825 The Isobaric 3
Vapor-Liquid Equilibrium of Butanone-
DMF and Toluene-DMF at Reduced 4
Pressures 5
6
7
8
9
10
11
12
13
14
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
Benzene - Chloroform Benzene - tetrachloromethane
n-Benzene 1 n-Benzene
Chloroform 2 Tetrachloromethane

Liquid Vapor Liquid Vapor


Total Total
mole Temperat mole mole Temperat mole
pressure No. pressure
fraction ure (K) fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
BENZ BENZ BENZ BENZ

1 353.623 1 101325 1 1 353.243 1 101000


0.95 353.123 0.94 101325 2 0.9928 353.173 0.9915 101000
0.92 352.923 0.9 101325 3 0.9713 353.003 0.9655 101000
0.88 352.3231 0.85 101325 4 0.9092 352.6031 0.8884 101000
0.8 351.6232 0.73 101325 5 0.8296 352.1831 0.8059 101000
0.68 350.1233 0.555 101325 6 0.7307 351.7031 0.7037 101000
0.62 349.4234 0.48 101325 7 0.6198 351.2132 0.5916 101000
0.55 348.4235 0.39 101325 8 0.3556 350.3833 0.3401 101000
0.44 346.6237 0.29 101325 9 0.26 350.1433 0.2501 101000
0.36 345.4238 0.22 101325 10 0.1762 349.9933 0.169 101000
0.22 342.124 0.11 101325 11 0.0602 349.8833 0.0593 101000
0.18 341.124 0.09 101325 12 0.0505 349.9033 0.0497 101000
0 334.424 0 101325 13 0.0467 349.8933 0.0462 101000
0.94 352.3231 0.911 101000 14 0.036 349.8933 0.0358 101000
0.932 352.1231 0.9 101000 15 0.0339 349.9333 0.0335 101000
0.884 351.5232 0.833 101000 16 0.0247 349.9233 0.0241 101000
0.867 351.0232 0.81 101000 17 0.0154 349.9633 0.0154 101000
0.807 350.0233 0.73 101000 18 0.0065 349.9333 0.0065 101000
0.771 349.3234 0.684 101000 19 0 349.9133 0 101000
0.734 348.8234 0.639 101000 1 1 353.273 1 101000
0.682 347.8235 0.571 101000 2 0.9117 352.6231 0.8944 101000
0.667 347.5236 0.557 101000 3 0.7957 351.9231 0.7692 101000
0.612 346.4237 0.492 101000 4 0.6712 351.3232 0.6423 101000
0.557 345.3238 0.43 101000 5 0.5817 350.9232 0.5561 101000
0.533 344.7238 0.399 101000 6 0.4793 350.5733 0.4575 101000
0.483 343.9239 0.348 101000 7 0.3769 350.2733 0.3603 101000
0.43 342.824 0.298 101000 8 0.2716 350.0233 0.2601 101000
0.363 341.424 0.238 101000 9 0.1804 349.8233 0.1746 101000
0.3 340.124 0.186 101000 10 0.0908 349.7733 0.0881 101000
0.217 338.524 0.125 101000 11 0.0421 349.7733 0.0413 101000
0.147 337.224 0.078 101000 12 0 349.7733 0 101000
0.066 335.724 0.032 101000 1 1 353.223 1 101000
0.901 350.7798 0.8505 101325 2 0.95 352.893 0.9413 101000
0.784 348.8303 0.693 101325 3 0.9 352.5531 0.8842 101000
0.7105 347.5307 0.608 101325 4 0.85 352.2331 0.8288 101000
0.5745 344.8815 0.449 101325 5 0.8 351.9531 0.7748 101000
0.4995 343.332 0.3685 101325 6 0.75 351.6931 0.7217 101000
0.409 341.4826 0.2765 101325 7 0.7 351.4432 0.67 101000
0.3505 340.2829 0.2255 101325 8 0.65 351.2232 0.6195 101000
0.299 339.4331 0.186 101325 9 0.6 351.1132 0.5699 101000
0.19 337.3335 0.115 101325 10 0.55 350.8232 0.5212 101000
0.128 336.0838 0.0685 101325 11 0.5 350.6932 0.4732 101000
0.0905 335.3339 0.048 101325 12 0.45 350.5133 0.426 101000
0.858 350.92 0.797 101300 13 0.4 350.3533 0.379 101000
0.815 350.15 0.738 101300 14 0.35 350.2133 0.3325 101000
0.731 348.64 0.627 101300 15 0.3 350.0933 0.286 101000
0.653 347.21 0.532 101300 16 0.25 349.9933 0.2397 101000
0.616 346.42 0.487 101300 17 0.2 349.9233 0.1931 101000
0.551 345.31 0.417 101300 18 0.15 349.8833 0.1461 101000
0.504 344.28 0.366 101300 19 0.1 349.8633 0.0984 101000
0.476 343.75 0.334 101300 20 0.05 349.8433 0.0499 101000
0.41 342.43 0.27 101300 21 0 349.8433 0 101000
0.341 340.93 0.209 101300 1 0.936 352.923 0.924 101320
0.307 340.33 0.183 101300 2 0.866 352.3231 0.844 101320
0.232 338.82 0.128 101300 3 0.866 352.4231 0.846 101320
0.143 337.05 0.072 101300 4 0.865 352.3231 0.84 101320
0.065 335.53 0.031 101300 5 0.57 351.0232 0.544 101320
1 353.26 1 101300 6 0.492 350.7232 0.469 101320
0.9731 352.67 0.9563 101300 7 0.488 350.7232 0.466 101320
0.9583 352.36 0.9308 101300 8 0.318 350.3233 0.308 101320
0.8668 350.87 0.8151 101300 9 0.214 350.1233 0.207 101320
0.8145 349.8 0.7419 101300 10 0.153 350.0233 0.15 101320
0.7628 348.85 0.6684 101300 1 0.991 353.423 0.989 101000
0.7052 347.87 0.602 101300 2 0.966 353.223 0.958 101000
0.6494 347.04 0.5251 101300 3 0.926 352.923 0.912 101000
0.6079 346.51 0.4755 101300 4 0.889 352.723 0.869 101000
0.5573 345.58 0.4286 101300 5 0.7 351.7231 0.671 101000
0.5103 344.57 0.3743 101300 6 0.598 351.4232 0.568 101000
0.4653 343.78 0.3258 101300 7 0.516 351.0232 0.488 101000
0.4219 342.77 0.2836 101300 8 0.435 350.7232 0.415 101000
0.3791 341.95 0.2447 101300 9 0.348 350.7232 0.332 101000
0.3346 341.07 0.2064 101300 10 0.272 350.5233 0.261 101000
0.2819 340.02 0.1743 101300 11 0.228 350.3233 0.221 101000
0.2421 338.87 0.1405 101300 12 0.094 350.2233 0.093 101000
0.2046 338.13 0.1149 101300 13 0.055 350.1233 0.055 101000
0.1722 337.49 0.0943 101300 1 0.9593 352.8891 0.95 101320
0.1397 336.86 0.0738 101300 2 0.9166 352.5892 0.9 101320
0.1108 336.31 0.0573 101300 3 0.8723 352.2993 0.85 101320
0.0692 335.53 0.0352 101300 4 0.8266 352.0294 0.8 101320
0.0429 335.07 0.0208 101300 5 0.7797 351.7695 0.75 101320
0 334.28 0 101300 6 0.7317 351.5195 0.7 101320
apparatus for the determination of the 7 0.6827 351.2896 0.65 101320
equilibrium state of liquid-vapor systems
for normal and reduced pressure tests on 8 0.5816 350.8697 0.55 101320
chloroform and benzene 9 0.5295 350.6698 0.5 101320
Nagata, I. J. Chem. Eng. Data, 1962, 7, 360 10 0.4767 350.4998 0.45 101320
Vapor-Liquid Equilibriumat Atmospheric
Pressure for the Ternary System Methyl 11 0.423 350.3399 0.4 101320
Acetate-Chloroform-Benzene 12 0.3686 350.1999 0.35 101320
13 0.3122 350.08 0.3 101320
Loiseleur, B.; Clechet, P.; Merlin, J. C. Bull.
Soc. Chim. Fr., 1968, 11, 4390-8
Loiseleur, B.; Clechet, P.; Merlin, J. C. Bull. 14 0.2586 350 0.25 101320
Soc. Chim. Fr., 1968, 11, 4390-8 15 0.2052 349.94 0.2 101320
Nakamichi, M. J. Chem. Eng. Data, 1991, 16 0.1531 349.9 0.15 101320
36, 343 Isobaric vapor-liquid equilibria for
acetone + chloroform + benzene and the 17 0.1017 349.87 0.1 101320
three constituent binary systems 18 0.0507 349.84 0.05 101320
361-6 Phase equilibria at 1 0.979 353.0291 0.975 101000
superatmospheric pressures for systems
containing halohydrocarbon, aromatic 2 0.939 352.8291 0.928 101000
hydrocarbon, and alcohol 3 0.876 352.3293 0.856 101000
4 0.812 351.9294 0.787 101000
5 0.749 351.6295 0.719 101000
6 0.687 351.2296 0.656 101000
7 0.624 350.9297 0.593 101000
8 0.561 350.7298 0.533 101000
9 0.505 350.4299 0.48 101000
10 0.499 350.4299 0.475 101000
11 0.441 350.2299 0.418 101000
12 0.378 350.13 0.359 101000
13 0.314 349.93 0.299 101000
14 0.249 349.83 0.24 101000
15 0.185 349.83 0.18 101000
16 0.122 349.83 0.119 101000
17 0.061 349.83 0.059 101000
18 0.022 349.83 0.021 101000
1 1 353.159 1 101000
2 0.945 352.7492 0.928 101000
3 0.906 352.4892 0.883 101000
4 0.856 352.1893 0.833 101000
5 0.826 352.0194 0.803 101000
6 0.75 351.5595 0.723 101000
7 0.673 351.1996 0.646 101000
8 0.567 350.7798 0.541 101000
9 0.446 350.2999 0.42 101000
10 0.36 350.12 0.343 101000
11 0.273 349.92 0.263 101000
12 0.205 349.85 0.2 101000
13 0.162 349.7801 0.159 101000
14 0.12 349.7301 0.118 101000
15 0.067 349.6801 0.066 101000
16 0 349.6601 0 101000
1 1 353.229 1 101325
2 0.9851 353.1191 0.9822 101325
3 0.9589 352.9291 0.9508 101325
4 0.8954 352.4992 0.8771 101325
5 0.844 352.1793 0.8192 101325
6 0.7975 351.9294 0.769 101325
7 0.75 351.6695 0.7197 101325
8 0.6941 351.3996 0.662 101325
9 0.664 351.2696 0.632 101325
10 0.6283 351.0997 0.5963 101325
11 0.565 350.8597 0.5356 101325
12 0.5126 350.6898 0.4847 101325
13 0.4623 350.4998 0.4373 101325
14 0.3965 350.3399 0.3763 101325
15 0.3476 350.1699 0.33 101325
16 0.32 350.09 0.3047 101325
17 0.2856 350.03 0.273 101325
18 0.2772 350.02 0.26 101325
19 0.175 349.87 0.166 101325
20 0.0673 349.7701 0.0656 101325
21 0.0066 349.7601 0.0067 101325
22 0 349.7701 0 101325

Campbell, A. N.; Dulmage, W. J. J. Am.


Chem. Soc., 1948, 70, 1723
Fowler, R. T.; Lim, S. C. J. Appl. Chem.,
1956, 6, 74 Azeotropism in binary
solutions: carbon tetrachloride-benzene
system.
Quim., B, 1958, 54, 401-11 Vapor-liquid
equilibrium: II method of fitting the
experimental data to a curve the system
benzene + carbon tetrachloride

Gotthard, F.; Minea, I. Rev. Chim.


(Bucharest), 1960, 11, 642

Haughton, C. O. Br. Chem. Eng., 1965, 10,


237 New Benzene-CCl4 Equilibrium Data
for Testing Fractionating Columns

Kojima, K.; Sunaga, H.; Hashimoto, S.


Kagaku Kogaku, 1968, 32, 480
Rodger, A. J.; Hsu, C. C.; Furter, W. F. J.
Chem. Eng. Data, 1969, 14, 362 Vapor-
Liquid Equilibria for 23 Carbon
Tetrachloride-Hydrocarbon Syst.
Simonovic, D. M. Glas. Hem. Drus.
Beograd, 1971, 36, 109-18 Isobaric vapor-
liquid equilibria for the system acetone +
carbon tetrachloride + benzene
Gongcheng Xuebao, 1989, 3, 32;40
Application of Method of Boiling Point
Analysis in the VLE Determination of
Binary and Ternary Systems
Toluene - Chloroform Toluene - tetrachloromethane
1 n-Toluene 1 n-Toluene
2 Chloroform 2 Tetrachloromethane

Liquid Vapor Liquid


Total
mole Temperat mole mole Temperat
No. pressure No.
fraction ure (K) fraction fraction ure (K)
(N/sqm)
TOL TOL TOL

1 0.987 382.3258 0.963 101000 1 0.9529 382.1658


2 0.976 381.6257 0.92 101000 2 0.92 381.0256
3 0.941 379.3252 0.81 101000 3 0.9038 380.5355
4 0.912 377.6249 0.724 101000 4 0.8955 379.6253
5 0.858 373.9242 0.58 101000 5 0.8638 378.6251
6 0.825 372.624 0.526 101000 6 0.8558 378.125
7 0.812 371.1238 0.508 101000 7 0.8277 377.6449
8 0.8 370.0237 0.485 101000 8 0.795 375.5145
9 0.77 368.1235 0.425 101000 9 0.7432 373.084
10 0.75 367.1234 0.4 101000 10 0.7375 372.874
11 0.719 365.4232 0.36 101000 11 0.737 373.174
12 0.67 362.623 0.296 101000 12 0.711 371.8439
13 0.641 360.623 0.258 101000 13 0.7075 371.7239
14 0.611 358.923 0.225 101000 14 0.6735 370.6037
15 0.575 357.123 0.191 101000 15 0.618 368.6636
16 0.545 355.423 0.169 101000 16 0.6155 368.2935
17 0.506 353.723 0.146 101000 17 0.606 368.0135
18 0.484 352.0231 0.125 101000 18 0.5832 367.7035
19 0.45 350.4233 0.11 101000 19 0.5772 366.6734
20 0.415 348.8234 0.09 101000 20 0.55 365.0832
21 0.36 346.6237 0.076 101000 21 0.5175 364.9732
22 0.335 345.7237 0.07 101000 22 0.5018 363.9831
23 0.294 343.7239 0.053 101000 23 0.4481 362.093
24 0.255 342.224 0.045 101000 24 0.412 360.573
25 0.21 340.724 0.034 101000 25 0.399 360.323
26 0.152 338.924 0.027 101000 26 0.3642 359.163
27 0.106 337.724 0.015 101000 27 0.3441 358.683
28 0.068 336.224 0.01 101000 28 0.3184 357.983
29 0.025 334.924 0.005 101000 29 0.2808 357.073
30 0.2442 356.043
Rao, M. R.; Sitapathy, R.; Anjaneyulu, N. S.
R.; Raju, G. J. V. J.; Rao, C. V. J. Sci. Ind. 31 0.215 355.073
Res., Sect. B, 1956, 15, 556 32 0.1922 354.343
33 0.17 353.863
34 0.1633 353.073
35 0.121 352.5531
36 0.095 352.3231
37 0.053 351.0732
38 0.0206 350.5533
39 0.005 350.1533
1 0.984 382.9224
2 0.94 380.7229
3 0.891 378.4233
4 0.841 376.2238
5 0.793 374.1242
6 0.742 372.0246
7 0.692 370.125
8 0.639 368.1254
9 0.599 366.6257
10 0.586 366.2258
11 0.532 364.3261
12 0.46 362.0266
13 0.39 359.927
14 0.317 357.8276
15 0.243 355.8282
16 0.172 354.0288
17 0.095 352.1294
18 0.022 350.4299
1 1 383.7123
2 0.9539 381.2927
3 0.9184 379.5931
4 0.8634 376.9636
5 0.8359 375.7338
6 0.7945 373.9542
7 0.7455 371.9246
8 0.696 369.965
9 0.6199 367.0756
10 0.5443 364.4761
11 0.4197 360.5169
12 0.3556 358.6374
13 0.2776 356.4781
14 0.1843 354.0788
15 0.0743 351.4796
16 0 349.7701
Ocon, J.; Espantoso, J. An. R. Soc. Es
Quim., B, 1958, 54, 421-30 Vapor-
equilibrium: IV methanol + benzen
carbon tetrachloride + toluene sys
Rodger, A. J.; Hsu, C. C.; Furter, W
Chem. Eng. Data, 1969, 14, 362 Va
Liquid Equilibria for 23 Carbon
Tetrachloride-Hydrocarbon Sys
Gongcheng Xuebao, 1989, 3, 32
Application of Method of Boiling P
Analysis in the VLE Determinatio
Binary and Ternary Systems
omethane Benzene - Acetic acid Benzene - Propionic acid
1 n-Benzene 1 n-Benzene
2 Acetic Acid 2 Propionic acid

Vapor Liquid Vapor


Total Total
mole mole Temperat mole
pressure No. pressure No.
fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
TOL BENZ BENZ

0.8995 101000 1 1 353.363 1 101320 1


0.835 101000 2 0.6451 357.843 0.8504 101320 2
0.8082 101000 3 0.4539 362.083 0.7752 101320 3
0.7858 101000 4 0.3804 363.9731 0.7421 101320 4
0.7178 101000 5 0.2993 367.1134 0.6859 101320 5
0.704 101000 6 0.2497 369.3536 0.6443 101320 6
0.6775 101000 7 0.1923 372.5639 0.5776 101320 7
0.6259 101000 8 0.1272 376.8347 0.4782 101320 8
0.5315 101000 9 0.0891 379.9454 0.3882 101320 9
0.5235 101000 10 0.0647 382.6359 0.3149 101320 10
0.5282 101000 1 1 353.363 1 101320 11
0.5018 101000 2 0.6451 357.843 0.8504 101320 12
0.496 101000 3 0.4539 362.083 0.7752 101320 13
0.4602 101000 4 0.3804 363.9731 0.7421 101320 14
0.4075 101000 5 0.2993 367.1134 0.6859 101320
0.4 101000 6 0.2497 369.3536 0.6443 101320
0.3955 101000 7 0.1923 372.5639 0.5776 101320
0.3718 101000 8 0.1272 376.8347 0.4782 101320
0.3572 101000 9 0.0891 379.9454 0.3882 101320
0.3341 101000 10 0.0647 382.6359 0.3149 101320
0.3035 101000 1 0.949858 352.923 0.961326 101000
0.289 101000 2 0.88232 353.123 0.930881 101000
0.2448 101000 3 0.53246 355.923 0.79316 101000
0.219 101000 4 0.340718 358.923 0.703183 101000
0.2122 101000 5 0.173082 364.6232 0.592355 101000
0.1948 101000 6 0.07387 373.124 0.394765 101000
0.182 101000 7 0.027908 382.1258 0.240736 101000
0.16 101000 8 0.009251 388.2265 0.060269 101000
0.131 101000 1 0.929 353.023 0.9473 101330
0.1235 101000 2 0.884 353.123 0.924 101330
0.1015 101000 3 0.835 353.523 0.895 101330
0.095 101000 4 0.707 354.423 0.872 101330
0.082 101000 5 0.65 354.823 0.85 101330
0.0815 101000 6 0.602 355.323 0.818 101330
0.066 101000 7 0.543 356.323 0.796 101330
0.044 101000 8 0.448 357.923 0.75 101330
0.019 101000 9 0.297 361.623 0.643 101330
0.0079 101000 10 0.165 367.8235 0.503 101330
0.003 101000 11 0.118 371.7239 0.426 101330
0.964 101000 12 0.0805 375.6245 0.342 101330
0.868 101000 13 0.067 378.9252 0.275 101330
0.772 101000 14 0.016 387.3264 0.076 101330
0.687 101000 1 0.95 353.1291 0.96 101330
0.613 101000 2 0.919 353.229 0.936 101330
0.542 101000 3 0.914 353.229 0.934 101330
0.479 101000 4 0.835 353.5289 0.9 101330
0.417 101000 5 0.811 353.7289 0.889 101330
0.374 101000 6 0.716 354.5286 0.842 101330
0.36 101000 1 0.8927 353.65 0.9169 101300
0.312 101000 2 0.7832 354.65 0.8438 101300
0.251 101000 3 0.6426 355.85 0.8013 101300
0.199 101000 4 0.5009 357.05 0.7681 101300
0.151 101000 5 0.4293 358.85 0.7297 101300
0.11 101000 6 0.3712 359.95 0.6955 101300
0.073 101000 7 0.3084 361.95 0.6356 101300
0.039 101000 8 0.2417 364.05 0.5859 101300
0.009 101000 9 0.2138 365.35 0.5533 101300
1 101325 10 0.1804 367.35 0.5102 101300
0.8865 101325 11 0.1455 369.95 0.4507 101300
0.8094 101325 12 0.0994 372.85 0.3798 101300
0.7115 101325 13 0.0684 375.85 0.2973 101300
0.661 101325 14 0.0501 378.65 0.225 101300
0.5948 101325 15 0.0318 380.95 0.1653 101300
0.5217 101325 16 0.0119 383.95 0.0835 101300
0.4565 101325
0.3682 101325 Rosanoff, M. A.; Easley, C. W. Z. Phys.
0.2976 101325 Chem. (Leipzig), 1909, 68, 641
0.1964 101325
Rosanoff, M. A.; Easley, C. W. J. Am.
0.1547 101325 Chem. Soc., 1909, 31, 953-87 On the
0.1123 101325 partial vapor pressures of binary mixtures
0.0677 101325
Othmer, D. F. Ind. Eng. Chem., 1928, 20,
0.0252 101325 743-6 Composition of vapors from boiling
0 101325 binary solutions
Espantoso, J. An. R. Soc. Esp. Fis.
B, 1958, 54, 421-30 Vapor-liquid Haughton, C. O. Br. Chem. Eng., 1967, 12,
um: IV methanol + benzene and 1102 Vapor-liquid equilibria of benzene
etrachloride + toluene systems and acetic acid
A. J.; Hsu, C. C.; Furter, W. F. J. Molochnikov, M. L.; Kudryavtseva, T. S.;
Eng. Data, 1969, 14, 362 Vapor- Kogan, V. B. Zh. Prikl. Khim. (Leningrad),
uid Equilibria for 23 Carbon 1969, 42, 1916-8 Vapor-liquid equilibirum
achloride-Hydrocarbon Syst. in the benzene - acetic aicd system
cheng Xuebao, 1989, 3, 32;40 Eng. Data, 1979, 24, 100 Activity
tion of Method of Boiling Point coefficients from solid-liquid and vapor-
is in the VLE Determination of liquid equilibria of some associated
nary and Ternary Systems solutions
Equilibria for Binary Systems of Acetic
Acid + Benzene, Chloroacetic Acid +
Benzene, and Dichloroacetic Acid +
Benzene at 101.33 kPa
Benzene - Propionic acid Toluene - Acetic acid
n-Benzene 1 n-Toluene
Propionic acid 2 Acetic Acid

Liquid Vapor Liquid Vapor


Total Total
mole Temperat mole mole Temperat mole
pressure No. pressure
fraction ure (K) fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
BENZENE BENZENE TOL TOL

0.003 413.9162 0.018 101300 1 1 383.9261 1 101320


0.059 401.8686 0.296 101300 2 0.95 378.025 0.885 101320
0.1 394.92 0.445 101300 3 0.9 375.7245 0.81 101320
0.128 390.7209 0.521 101300 4 0.85 374.5243 0.758 101320
0.164 386.2218 0.609 101300 5 0.8 374.0242 0.718 101320
0.217 380.4729 0.673 101300 6 0.7 373.7241 0.666 101320
0.277 375.8238 0.761 101300 7 0.6 373.7241 0.615 101320
0.327 372.2246 0.804 101300 8 0.5 373.9242 0.57 101320
0.432 366.7257 0.864 101300 9 0.4 374.8243 0.541 101320
0.538 362.4765 0.904 101300 10 0.3 376.4247 0.46 101320
0.649 359.2272 0.935 101300 11 0.2 378.7251 0.372 101320
0.725 357.4278 0.951 101300 12 0.1 382.0258 0.255 101320
0.766 356.728 0.961 101300 13 0.05 384.4261 0.155 101320
0.977 353.279
Malijevska, 0.994 Czech.
I.; Pick, J. Collect. 101300 14 0 391.2268 0 101320
Chem. Commun., 1978, 43, 2096-104 1 1 383.6261 1 101000
Liquid-vapor equilibrium in strongly
associating binary systems aliphatic acid + 2 0.951578 380.6255 0.86643 101000
benzene 3 0.924551 379.6253 0.818867 101000
4 0.885109 378.9252 0.763463 101000
5 0.790877 378.225 0.680865 101000
6 0.744225 377.925 0.65923 101000
7 0.689379 377.7249 0.630947 101000
8 0.571784 377.5249 0.56293 101000
9 0.524934 377.8249 0.544326 101000
10 0.472667 377.6249 0.51854 101000
11 0.432467 377.8249 0.501652 101000
12 0.370939 378.025 0.474714 101000
13 0.312611 378.025 0.457429 101000
14 0.253033 378.7251 0.416771 101000
15 0.195823 379.7253 0.371875 101000
16 0.13485 380.7255 0.293255 101000
17 0.100251 381.9258 0.253033 101000
18 0.070328 383.6261 0.195823 101000
19 0.052255 385.1262 0.158342 101000
20 0.03249 386.5263 0.131111 101000
21 0.007854 388.6266 0.07103 101000
22 0.001304 391.1268 0.001304 101000
1 1 383.6223 1 101330
2 0.95 380.9228 0.865 101330
3 0.88 379.4231 0.765 101330
4 0.75 378.4233 0.67 101330
5 0.685 378.1234 0.625 101330
6 0.6 378.0234 0.575 101330
7 0.545 377.8234 0.547 101330
8 0.45 378.1234 0.515 101330
9 0.345 378.5233 0.465 101330
10 0.29 378.9232 0.43 101330
11 0.18 379.5231 0.34 101330
12 0.117 382.4225 0.255 101330
13 0.06 384.6221 0.165 101330
14 0.03 386.3217 0.115 101330
15 0 391.3207 0 101330
1 0.9614 383.55 0.9347 101300
2 0.9164 380.35 0.8576 101300
3 0.8697 379.1 0.7863 101300
4 0.7838 375.95 0.7117 101300
5 0.6466 374.15 0.6271 101300
6 0.5817 375.15 0.5917 101300
7 0.4979 376.55 0.5478 101300
8 0.4404 376.75 0.5331 101300
9 0.3788 376.65 0.5046 101300
10 0.3125 378.15 0.4536 101300
11 0.2744 378.55 0.4375 101300
12 0.2351 379.15 0.4173 101300
13 0.1912 379.4 0.3872 101300
14 0.1493 380.65 0.3538 101300
15 0.1416 381.65 0.3216 101300
16 0.0972 382.65 0.2477 101300
17 0.0708 383.35 0.1639 101300

Othmer, D. F. Ind. Eng. Chem., 1943, 35,


614-20 Composition of vapors from
boiling binary solutions

Haughton, C. O. Chem. Eng. Sci., 1961, 16,


82 Liquid-vapour equilibria and azeotropic
data for acetic acid and toluene

Murthy, D. P.; Achary, M. V. R. Trans.


Indian Inst. Chem. Eng., 1968, , 26-9
Vapor-Liquid Equilibria
(vapour-liquid) equilibria data for the
binary systems (tolueneYacetic acid) and
(tolueneYmethyl ethyl ketone) at
atmospheric pressure
Benzene - Methyl Acetate Benzene - Ethyl Acetate
1 n-Benzene 1 n-Benzene
2 Methyl Acetate 2 n-Ethyl Acetate

Liquid Vapor Liquid


Total
mole Temperat mole mole Temperat
No. pressure No.
fraction ure (K) fraction fraction ure (K)
(N/sqm)
BENZENE BENZENE BENZENE

1 0.105 331.0246 0.067 101000 1 0.086 350.4233


2 0.137 331.5245 0.086 101000 2 0.16 350.4233
3 0.265 333.224 0.168 101000 3 0.242 350.5233
4 0.38 334.924 0.251 101000 4 0.322 350.6233
5 0.495 336.924 0.335 101000 5 0.385 350.7232
6 0.638 339.924 0.455 101000 6 0.45 350.8232
7 0.662 340.624 0.472 101000 7 0.527 351.0232
8 0.788 344.1239 0.613 101000 8 0.598 351.3232
9 0.811 344.9238 0.644 101000 9 0.675 351.6232
10 0.861 346.6237 0.718 101000 10 0.755 352.0231
11 0.924 349.0234 0.825 101000 11 0.81 352.2231
12 0.945 350.0233 0.867 101000 12 0.884 352.6231
1 0.289 334.4441 0.173 101000 13 0.928 352.823
2 0.384 336.1638 0.233 101000 1 0.05 350.3133
3 0.478 337.9434 0.303 101000 2 0.088 350.3533
4 0.573 340.003 0.38 101000 3 0.143 350.4133
5 0.672 342.4123 0.468 101000 4 0.159 350.4333
6 0.745 344.3017 0.544 101000 5 0.166 350.4433
7 0.786 345.5313 0.597 101000 6 0.226 350.5033
8 0.808 346.2511 0.631 101000 7 0.303 350.6133
9 0.916 349.89 0.807 101000 8 0.413 350.7932
10 0.948 350.9397 0.87 101000 9 0.472 350.9632
1 0.0261 330.22 0.0154 101310 10 0.559 351.2432
2 0.0498 330.48 0.0305 101310 11 0.578 351.3132
3 0.0785 330.84 0.0496 101310 12 0.641 351.5532
4 0.1202 331.44 0.0771 101310 13 0.7 351.7831
5 0.1598 331.98 0.1017 101310 14 0.77 352.0831
6 0.2059 332.45 0.1272 101310 15 0.84 352.4031
7 0.254 333.07 0.1596 101310 16 0.864 352.5231
8 0.3057 333.9 0.1961 101310 17 0.94 352.893
9 0.4357 336.03 0.2853 101310 18 0.973 353.073
10 0.507 337.38 0.3402 101310 19 0.984 353.133
11 0.6275 339.76 0.4362 101310 Chao, K.-C.; Hougen, O. A. Chem. En
1958, 7, 246 Vapour-liquid equilib
12 0.731 342.56 0.55 101310 the ternary system ethyl acetate
13 0.7971 344.46 0.6272 101310 benzene
Carr, A. D.; + cyclohexane.
Kropholler, H. W. J. Chem
14 0.8196 345.23 0.656 101310 Data, 1962, 7, 26 Vapor Liquid Equil
Atmospheric Pressure. Binary Syste
15 0.8702 347.18 0.7396 101310 Ethyl Acetate-Benzene, Ethyl Acet
16 0.9471 350.35 0.8839 101310 Toluene, and Ethyl Acetate-p-Xy
17 0.9769 351.75 0.9495 101310
Nagata, I. J. Chem. Eng. Data, 1962, 7, 360
Vapor-Liquid Equilibriumat Atmospheric
Vapor-Liquid Equilibriumat Atmospheric
Pressure for the Ternary System Methyl
Acetate-Chloroform-Benzene
Hudson, J. W.; Van Winkle, M. J. Chem.
Eng. Data, 1969, 14, 310-318
Multicomponent vapor-liquid equilibriums
in systems of mixed positive and negative
deviations

Postigo, M. A.; Mariano, A.; Zurakoski, N.;


Jara, A. F. J. Chem. Eng. Data, 2009, 54,
1575-1579
tate Benzene - Propyl Acetate Benzene - Butyl Acetate
1 n-Benzene 1 n-Benzene
2 n-Propyl Acetate 2 n-Butyl Acetate

Vapor Liquid Vapor


Total Total
mole mole Temperat mole
pressure No. pressure No.
fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
BENZENE BENZENE BENZENE

0.084 101000 1 0.044 373.5243 0.072 101320 1


0.155 101000 2 0.105 371.9746 0.174 101320 2
0.233 101000 3 0.176 370.4249 0.265 101320 3
0.309 101000 4 0.243 368.7253 0.378 101320 4
0.369 101000 5 0.317 366.9756 0.474 101320 5
0.431 101000 6 0.369 365.5759 0.527 101320 6
0.503 101000 7 0.419 364.6261 0.583 101320 7
0.572 101000 8 0.521 362.4265 0.694 101320 8
0.649 101000 9 0.601 360.6269 0.765 101320 9
0.729 101000 10 0.648 359.7271 0.795 101320 10
0.787 101000 11 0.739 357.8276 0.857 101320 11
0.866 101000 12 0.801 356.778 0.889 101320 12
0.915 101000 13 0.834 356.0782 0.916 101320 13
0.049 101320 14 0.89 354.9785 0.946 101320 14
0.086 101320 15 0.932 354.3287 0.961 101320 15
0.14 101320 16 Fahmy, A.1 F. M.;
353.229
El-Ghannam, N.1 I. M.
101320
Bull. 16
0.155 101320 Acad. Pol. Sci.-Chim., 1972, 20, 157 Vapor- 17
Liquid Equilibrium in n-Amyl Acetate-
0.162 101320 Toluene, n-Butyl Acetate-Toluene and n- 1
0.22 101320 Propyl Acetate-Benzene Mixtures 2
0.293 101320 3
0.395 101320 4
0.453 101320 5
0.535 101320 6
0.552 101320 7
0.613 101320 8
0.671 101320 9
0.744 101320 10
0.816 101320 11
0.843 101320 1
0.929 101320 2
0.967 101320 3
0.98 101320 4
C.; Hougen, O. A. Chem. Eng. Sci., 5
246 Vapour-liquid equilibria in
ernary system ethyl acetate + 6
benzene + cyclohexane.
.; Kropholler, H. W. J. Chem. Eng. 7
2, 7, 26 Vapor Liquid Equilibria at 8
eric Pressure. Binary Systems of
cetate-Benzene, Ethyl Acetate- 9
ne, and Ethyl Acetate-p-Xyle 10
11
12
13
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
Benzene - Butyl Acetate Toluene - Methyl Acetate
n-Benzene 1 n-Toluene
n-Butyl Acetate 2 Methyl Acetate

Liquid Vapor Liquid Vapor


Total Total
mole Temperat mole mole Temperat mole
pressure No. pressure
fraction ure (K) fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
BENZENE BENZENE TOL TOL

0.044 395.7278 0.138 101330 1 0.982 379.6831 0.885 101000


0.078 393.5271 0.225 101330 2 0.976 378.5033 0.851 101000
0.114 391.5268 0.298 101330 3 0.97 377.5535 0.822 101000
0.159 388.8266 0.384 101330 4 0.956 374.904 0.759 101000
0.206 385.9263 0.473 101330 5 0.949 373.9642 0.731 101000
0.238 383.8261 0.522 101330 6 0.94 372.4445 0.696 101000
0.331 378.8251 0.653 101330 7 0.922 370.3049 0.635 101000
0.361 377.5249 0.682 101330 8 0.887 366.1258 0.541 101000
0.441 373.4241 0.766 101330 9 0.851 362.5365 0.466 101000
0.536 369.0236 0.833 101330 10 0.815 359.917 0.409 101000
0.598 366.4233 0.87 101330 11 0.763 356.3681 0.342 101000
0.655 364.1231 0.892 101330 12 0.699 352.1493 0.274 101000
0.704 362.223 0.915 101330 13 0.687 351.6695 0.269 101000
0.757 360.323 0.934 101330 14 0.582 346.681 0.197 101000
0.835 357.723 0.959 101330 15 0.438 341.2526 0.131 101000
0.88 356.623 0.971 101330 16 0.368 338.8832 0.1 101000
0.911 355.723 0.98 101330 17 0.33 337.9534 0.09 101000
0.05 395.12 0.165 101320 18 0.287 336.3737 0.076 101000
0.1 391.7207 0.3 101320 19 0.248 335.6039 0.065 101000
0.2 385.9218 0.503 101320 20 0.192 334.4641 0.053 101000
0.3 380.6229 0.643 101320 21 0.147 333.4143 0.041 101000
0.4 375.7239 0.743 101320 22 0.123 332.8544 0.033 101000
0.5 370.9248 0.817 101320 23 Wisniak,
0.112J.;332.5045 0.031Eng.101000
Tamir, A. J. Chem. Data,
0.6 366.6257 0.877 101320 24 1989,0.05 330.9848
34, 16-19 Vapor-Liquid0.014 101000
Equilibria at
0.7 362.9264 0.923 101320 760 mmHg in the Systems Methyl
Acetate-Propyl Bromide, Methyl Acetate-
0.8 359.3272 0.958 101320 Toluene and Methyl Methacrylate-
0.9 356.1282 0.982 101320 Toluene
0.95 354.6286 0.99 101320
0 399.2192 0 101330
0.05 395.12 0.165 101330
0.1 391.7207 0.3 101330
0.2 385.9218 0.503 101330
0.3 380.6229 0.643 101330
0.4 375.7239 0.743 101330
0.5 370.9248 0.817 101330
0.6 366.6257 0.877 101330
0.7 362.9264 0.923 101330
0.8 359.3272 0.958 101330
0.9 356.1282 0.982 101330
0.95 354.6286 0.99 101330
1 353.229 1 101330
0.0189 397.19 0.0617 101310
0.0437 395.18 0.1361 101310
0.0884 391.75 0.2533 101310
0.1168 389.71 0.3181 101310
0.1979 384.15 0.4765 101310
0.2712 379.77 0.5846 101310
0.36 375.27 0.6814 101310
0.4351 372.14 0.741 101310
0.4894 369.75 0.783 101310
0.5565 367.22 0.8238 101310
0.6005 365.52 0.8495 101310
0.6821 362.54 0.8914 101310
0.7651 359.71 0.9276 101310
0.7999 358.58 0.941 101310
0.8599 356.81 0.9608 101310
0.9077 355.47 0.9751 101310
0.9501 354.25 0.9875 101310
equilibrium data for binary systems,
acetone - methyl acetate, methyl acetate
- carbon tetrachloride, benzene - butyl
acetate, and cyclohexane - butyl acetate
Anton, N. J.; Zheleznova, N. I.; Tikhonova,
N. K.; Timofeev, V. S.; Serafimov, L. A. Tr.
Inst. - Mosk. Inst. Tonkoi Khim. Tekhnol.
im. M. V. Lomonosova, 1973, 3, 115
Inst. - Mosk. Inst. Tonkoi Khim. Tekhnol.
im. M. V. Lomonosova, 1973, 3, 115-20
Physicochemical properties of the system
benzene + butyl acetate + water

Postigo, M. A.; Mariano, A.; Zurakoski, N.;


Jara, A. F. J. Chem. Eng. Data, 2009, 54,
1575-1579
Toluene - Ethyl Acetate Benzene - Diisopropyl ether
1 n-Toluene 1 n-Benzene
2 n-Ethyl Acetate 2 Diisopropyl Ether

Liquid Vapor Liquid


Total
mole Temperat mole mole Temperat
No. pressure No.
fraction ure (K) fraction fraction ure (K)
(N/sqm)
TOLUENE TOLUENE BENZENE

1 0.03 350.7232 0.013 101320 1 0 341.5325


2 0.046 350.9332 0.02 101320 2 0.11 341.7325
3 0.078 351.5132 0.033 101320 3 0.27 342.1324
4 0.109 351.9231 0.047 101320 4 0.46 343.1321
5 0.165 353.033 0.072 101320 5 0.59 344.1318
6 0.227 354.263 0.101 101320 6 0.7 345.1315
7 0.285 355.373 0.133 101320 7 0.8 346.531
8 0.344 356.673 0.163 101320 8 0.895 348.4305
9 0.402 358.283 0.2 101320 9 0.965 351.1297
10 0.548 362.343 0.297 101320 10 0.98 351.6295
11 0.635 365.2132 0.371 101320 11 1 353.229
12 0.715 368.1435 0.455 101320 Ramachandran, S.; Baradarajan,
Satyanarayana, M. Indian J. Tech
13 0.73 368.6336 0.472 101320 1970, 8, 323-5 Vapor-liquid equilib
14 0.825 372.924 0.609 101320 of benzene + diisopropyl ether sys
15 0.893 376.5847 0.735 101320
16 0.952 380.0654 0.863 101320
17 0.968 380.9956 0.903 101320
18 0.979 381.9458 0.936 101320
1 0 350.3299 0 101325
2 0.04 350.7298 0.019 101325
3 0.078 351.2296 0.037 101325
4 0.123 351.8294 0.059 101325
5 0.16 352.2293 0.071 101325
6 0.199 353.0291 0.096 101325
7 0.241 353.9288 0.118 101325
8 0.294 355.0285 0.146 101325
9 0.3 355.2284 0.152 101325
10 0.341 356.2281 0.176 101325
11 0.375 357.0279 0.196 101325
12 0.394 357.4278 0.209 101325
13 0.422 358.1276 0.228 101325
14 0.427 358.4275 0.231 101325
15 0.502 360.127 0.277 101325
16 0.562 362.1266 0.329 101325
17 0.581 362.6265 0.341 101325
18 0.634 364.4261 0.385 101325
19 0.664 365.6259 0.419 101325
20 0.697 366.7257 0.449 101325
21 0.738 368.4253 0.5 101325
22 0.763 369.7251 0.529 101325
23 0.774 370.225 0.549 101325
24 0.777 370.5249 0.555 101325
25 0.79 371.1248 0.573 101325
26 0.824 372.6245 0.619 101325
27 0.834 373.2244 0.641 101325
28 0.872 375.224 0.71 101325
29 0.907 376.8236 0.763 101325
30 0.926 378.5233 0.815 101325
31 0.941 379.6231 0.854 101325
32 0.949 379.923 0.869 101325
33 0.963 381.0228 0.902 101325
34 0.984 382.5225 0.957 101325
35 1 383.7223 1 101325
Data, 1962, 7, 26 Vapor Liquid Equilibria at
Atmospheric Pressure. Binary Systems of
Ethyl Acetate-Benzene, Ethyl Acetate-
Toluene, and Ethyl Acetate-p-Xyle

Rivenq, F. Bull. Soc. Chim. Fr., 1970, ,


3833-4 Ebullioscopy of ethyl acetate +
toluene mixtures
yl ether Toluene - Tetrahydrofuran Benzene - Acetone
1 n-Toluene 1 n-Benzene
2 Tetrahydrofuran 2 n-Acetone

Vapor Liquid Vapor


Total Total
mole mole Temperat mole
pressure No. pressure No.
fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
BENZENE TOLUENE TOLUENE

0 101000 1 0 338.8332 0 101325 1


0.085 101000 2 0.044 339.933 0.009 101325 2
0.22 101000 3 0.071 340.7328 0.013 101325 3
0.39 101000 4 0.121 342.1324 0.024 101325 4
0.525 101000 5 0.172 343.6319 0.035 101325 5
0.63 101000 6 0.237 345.9312 0.059 101325 6
0.74 101000 7 0.299 347.9306 0.078 101325 7
0.885 101000 8 0.348 349.7301 0.106 101325 8
0.95 101000 9 0.392 351.2296 0.116 101325 9
0.965 101000 10 0.445 353.329 0.152 101325 10
1 101000 11 0.521 356.2281 0.194 101325 11
chandran, S.; Baradarajan, A.; 12 0.525 356.628 0.204 101325 12
arayana, M. Indian J. Technol.,
323-5 Vapor-liquid equilibriums 13 0.559 357.9276 0.241 101325 13
ene + diisopropyl ether system 14 0.619 360.9268 0.304 101325 1
15 0.627 361.3267 0.316 101325 2
16 0.684 364.1262 0.375 101325 3
17 0.695 364.926 0.388 101325 4
18 0.731 366.7257 0.434 101325 5
19 0.755 367.9254 0.472 101325 6
20 0.789 369.925 0.525 101325 7
21 0.825 372.2246 0.587 101325 8
22 0.833 372.5245 0.608 101325 9
23 0.904 377.2236 0.749 101325 10
24 0.917 377.7235 0.779 101325 11
25 0.968 381.3227 0.904 101325 12
26 0.975 381.5227 0.922 101325 13
27 1 383.7223 1 101325 14
1 0.0007 338.8332 1.00E-04 101000 15
2 0.02 339.3331 0.004 101000 1
3 0.04 339.7331 0.0083 101000 2
4 0.06 340.2329 0.0127 101000 3
5 0.08 340.7328 0.0174 101000 4
6 0.1 341.2326 0.0224 101000 5
7 0.15 342.5322 0.036 101000 6
8 0.2 343.8318 0.051 101000 7
9 0.25 345.3314 0.069 101000 8
10 0.3 346.731 0.089 101000 9
11 0.35 348.2305 0.111 101000 10
12 0.4 349.93 0.137 101000 11
13 0.45 351.7295 0.166 101000 12
14 0.5 353.6289 0.2 101000 13
15 0.55 355.6283 0.239 101000 14
16 0.6 357.8276 0.283 101000 15
17 0.65 360.3269 0.334 101000 1
18 0.7 363.0264 0.393 101000 2
19 0.75 365.8258 0.462 101000 3
20 0.8 368.9252 0.542 101000 4
21 0.85 372.1246 0.632 101000 5
22 0.9 375.6239 0.738 101000 6
23 0.92 377.1236 0.785 101000 7
24 0.94 378.7233 0.834 101000 8
25 0.96 380.3229 0.886 101000 9
26 0.98 381.9226 0.941 101000 10
27 0.99 382.8224 0.97 101000 11
28 0.9999 383.8222 0.9998 101000 12
1 0 339.1532 0 101320 1
2 0.0141 339.5431 0.0042 101320 2
3 0.0403 339.973 0.0081 101320 3
4 0.113 341.8424 0.0272 101320 4
5 0.1722 343.5219 0.0425 101320 5
6 0.2547 345.5313 0.062 101320 6
7 0.3214 347.2308 0.0828 101320 7
8 0.4889 352.9391 0.2006 101320 8
9 0.5959 356.688 0.2821 101320 9
10 0.8042 366.6457 0.5661 101320 10
11 0.8552 370.4749 0.63 101320 11
12 0.9457 378.0334 0.8593 101320 12
13 0.9708 380.4329 0.9025 101320 13
14 1 383.6823 1 101320 1
1 0 339.15 0 101300 2
2 0.116 342.84 0.026 101300 3
3 0.13 343.42 0.03 101300 4
4 0.282 348.32 0.081 101300 5
5 0.478 355.17 0.186 101300 6
6 0.514 356.6 0.212 101300 7
7 0.553 358.5 0.243 101300 8
8 0.579 359.25 0.266 101300 9
9 0.618 360.94 0.303 101300 10
10 0.703 365.1 0.4 101300 11
11 0.74 367.03 0.451 101300 12
12 0.763 368.27 0.484 101300 13
13 0.871 374.7 0.676 101300 14
14 0.89 376.1 0.716 101300 15
15 0.906 377.13 0.753 101300 16
16 0.916 378.1 0.776 101300 17
17 0.931 379.06 0.819 101300 1
18 0.931 378.94 0.817 101300 2
3
Rivenq, F. Bull. Soc. Chim. Fr., 1975, ,
2433-4 Ebulliometry of the binary system
tetrahydrofuran + toluene
Rivenq, F. Bull. Soc. Chim. Fr., 1975, ,
2433-4 Ebulliometry of the binary system 4
tetrahydrofuran + toluene 5
(Leningrad), 1978, 51, 1198-9 Liquid-vapor 6
equilibrium in the systems diethyl ether +
tetrahydrofuran and tetrahydrofuran + 7
toluene 8
9
Klon-Palczewska, M.; Cholinski, J.;
Wyrzykowska-Stankiewicz, D. Chem. 10
Stosow., 1980, 24, 197 11
Wisniak, J. J. Chem. Eng. Data, 1996, 41, 12
1079-1082 Isobaric Vapor-Liquid Equilibria
in the Systems Methyl Ethanoate + 13
Oxolane and Oxolane + Toluene 14
15
16
17
18
19
20
21
Benzene - Acetone Benzene - 2-Butanone
n-Benzene 1 n-Benzene
n-Acetone 2 2-Butanone

Liquid Vapor Liquid Vapor


Total Total
mole Temperat mole mole Temperat mole
pressure No. pressure
fraction ure (K) fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
BENZ BENZ BENZENE BENZENE

1 353.223 1 101320 1 0 352.5731 0 101000


0.98 352.6231 0.937 101320 2 0.014 352.5231 0.015 101000
0.95 351.4232 0.86 101320 3 0.057 352.4731 0.063 101000
0.9 349.5234 0.757 101320 4 0.123 352.1031 0.135 101000
0.8 345.9237 0.6 101320 5 0.247 351.6731 0.26 101000
0.7 342.724 0.488 101320 6 0.365 351.4232 0.377 101000
0.6 339.824 0.406 101320 7 0.394 351.4532 0.405 101000
0.5 337.424 0.335 101320 8 0.45 351.4232 0.457 101000
0.4 335.524 0.27 101320 9 0.489 351.4532 0.493 101000
0.3 333.824 0.205 101320 10 0.537 351.4732 0.538 101000
0.2 332.7241 0.137 101320 11 0.584 351.4732 0.581 101000
0.1 331.9244 0.068 101320 12 0.674 351.6731 0.662 101000
0 329.2252 0 101320 13 0.726 351.5732 0.71 101000
1 353.223 1 101320 14 0.798 351.9231 0.778 101000
0.99 352.3231 0.9648 101320 15 0.843 352.1731 0.823 101000
0.95 349.4734 0.8504 101320 16 0.869 352.2731 0.849 101000
0.9 346.7236 0.7469 101320 17 0.888 352.3731 0.869 101000
0.8 342.824 0.597 101320 18 0.912 352.5731 0.895 101000
0.7 339.874 0.4853 101320 19 0.912 352.5731 0.894 101000
0.6 337.624 0.397 101320 20 0.935 352.773 0.921 101000
0.5 335.774 0.3215 101320 21 0.963 352.973 0.951 101000
0.4 334.124 0.2536 101320 22 0.988 353.323 0.985 101000
0.3 332.7241 0.19 101320 23 0.994 353.323 0.993 101000
0.2 331.4745 0.1263 101320 24 1 353.323 1 101000
0.1 330.3748 0.0629 101320 1 0 352.723 0 101353
0.05 329.825 0.0313 101320 2 0.186 351.1232 0.201 101353
0.01 329.3951 0.0063 101320 3 0.47 350.8232 0.48 101353
0 329.3051 0 101320 4 0.682 351.6232 0.672 101353
1 353.223 1 101000 5 0.874 352.3231 0.856 101353
0.9368 349.0634 0.8245 101000 6 1 353.223 1 101353
0.8259 343.404 0.6607 101000 1 0.14 351.9831 0.152 101000
0.7286 339.764 0.5516 101000 2 0.227 351.7131 0.241 101000
0.6617 338.024 0.4886 101000 3 0.296 351.5132 0.308 101000
0.5963 336.604 0.4269 101000 4 0.336 351.4832 0.349 101000
0.5528 335.794 0.3921 101000 5 0.503 351.2232 0.504 101000
0.5032 334.944 0.3507 101000 6 0.622 351.3032 0.61 101000
0.4785 334.544 0.3306 101000 7 0.709 351.5432 0.695 101000
0.4255 333.714 0.2888 101000 8 0.813 351.8831 0.789 101000
0.3169 332.3542 0.2082 101000 9 0.876 352.3231 0.856 101000
0.205 331.0146 0.1308 101000 10 0.95 352.923 0.938 101000
0.1366 330.3648 0.0858 101000 1 0 352.673 0 101320
0.0593 329.655 0.0369 101000 2 0.155 352.0931 0.17 101320
0 329.2352 0 101000 3 0.3 351.7131 0.31 101320
0.946 349.6234 0.845 101000 4 0.5 351.4632 0.505 101320
0.916 348.0235 0.782 101000 5 0.7 351.6631 0.685 101320
0.844 344.9238 0.662 101000 6 0.845 352.1331 0.823 101320
0.763 342.224 0.56 101000 7 1 353.213 1 101320
0.76 341.924 0.556 101000 1 0 352.7292 0 101320
0.665 339.524 0.459 101000 2 0.154 352.2293 0.159 101320
0.568 337.324 0.377 101000 3 0.287 351.8294 0.305 101320
0.468 335.524 0.302 101000 4 0.498 351.5295 0.502 101320
0.353 333.724 0.226 101000 5 0.689 351.7295 0.686 101320
0.291 332.7241 0.187 101000 6 0.843 352.2293 0.831 101320
0.242 332.2243 0.155 101000 7 1 353.329 1 101320
0.131 330.8247 0.085 101000 1 0.1 351.8294 0.11 101320
0.931 346.9309 0.803 100000 2 0.185 351.5295 0.197 101320
0.91 345.9312 0.76 100000 3 0.238 351.4296 0.247 101320
0.824 342.1324 0.625 100000 4 0.293 351.2796 0.306 101320
0.796 341.1327 0.596 100000 5 0.376 351.2296 0.386 101320
0.705 338.6333 0.53 100000 6 0.463 351.1297 0.467 101320
0.587 335.9338 0.392 100000 7 0.525 351.1297 0.525 101320
0.534 334.834 0.354 100000 8 0.583 351.1297 0.578 101320
0.534 334.834 0.351 100000 9 0.629 351.2296 0.619 101320
0.446 333.3343 0.289 100000 10 0.737 351.4796 0.725 101320
0.402 332.7345 0.266 100000 11 0.858 352.0294 0.842 101320
0.187 330.4349 0.125 100000 12 0.928 352.5292 0.915 101320
0.094 329.7351 0.062 100000 Steinhauser, H. H.; White, R. R. Ind. Eng.
Chem., 1949, 41, 2912-20 Vapor-Liquid
0.053 329.4352 0.035 100000 Equilibria Data for Ternary Mixtures
0.861 345.38 0.679 101300 heptane - toluene system
0.807 343.36 0.601 101300 Narasinga Rao, N. J. Sci. Ind. Res., Sect. B,
1957, 16, 233-240 High-pressure Vapor-
0.73 341.03 0.512 101300 liquid Equilibriums of Nonideal Solutions
0.613 338.14 0.399 101300 II. Benzene- methyl Ethyl Ketone System
0.572 337.31 0.37 101300 Donald, M. B.; Ridgway, K. J. Appl. Chem.,
1958, 8, 403 The binary systems benzene-
0.554 336.94 0.353 101300 ethyl methyl ketone and benzene-
0.534 336.54 0.339 101300 cyclohexane
0.502 335.97 0.317 101300 Morachevskii, A. G. Zh. Prikl. Khim.
(Leningrad), 1965, 38, 2132 Liquid-Vapor
0.45 335.06 0.279 101300 equilibrium in the ternary system methyl
0.398 334.2 0.247 101300 ethyl ketone- Benzene - isopropyl alcohol
0.373 333.86 0.231 101300 Khim. (Leningrad), 1968, 41, 2032 Certain
properties of lines of constant content of
0.327 333.16 0.202 101300 a component in the vapor in ternary
0.27 332.39 0.167 101300 systems
0.267 332.36 0.166 101300 Verhoeye, L. A. J.; Qazi, S. A. Ind. Chim.
Belge, 1971, 36, 109 The vapour-liquid
0.151 330.9 0.095 101300 equilibrium of the system methyl ethyl
0.128 330.63 0.081 101300 ketone + benzene + water
0.117 330.49 0.074 101300
0.924 348.3 0.802 101300
0.899 347.01 0.75 101300
0.876 346.03 0.713 101300
0.851 344.98 0.671 101300
0.793 342.88 0.592 101300
0.774 342.28 0.57 101300
0.738 341.22 0.528 101300
0.719 340.66 0.507 101300
0.675 339.56 0.466 101300
0.633 338.54 0.427 101300
0.602 337.93 0.403 101300
0.538 336.64 0.35 101300
0.499 335.9 0.32 101300
0.435 334.84 0.278 101300
0.371 333.74 0.232 101300
0.331 333.17 0.207 101300
0.291 332.62 0.182 101300
0.228 331.86 0.144 101300
0.184 331.32 0.117 101300
0.155 330.97 0.099 101300
0.078 330.08 0.051 101300

Othmer, D. F. Ind. Eng. Chem., 1943, 35,


614-20 Composition of vapors from
boiling binary solutions

Mueller, E.; Stage, H. J. Am. Oil Chem.


Soc., 1946, 23, 177
Canjar, L. N.; Horni, E. C.; Rothfus, R. R.
Ind. Eng. Chem., 1956, 48, 427 Vapor-
Liquid Equil. in the Acetone-Benzene-
Ethylene Dichloride System
Free, K. W.; Hutchison, H. P. J. Chem. Eng.
Data, 1959, 4, 193 Isobaric Vapor-Liquid
Equilibria for the Ternary System Acetone-
Benzene-Chlorobenzene
Khim. (Leningrad), 1974, 47, 2492-5
Determination of phase equilibria in an
apparatus with reversed flow and phase
circulation
Nakamichi, M. J. Chem. Eng. Data, 1991,
36, 343 Isobaric vapor-liquid equilibria for
acetone + chloroform + benzene and the
three constituent binary systems
Equilibrium Data for Acetone + Methanol
+ Benzene, Chloroform + Methanol +
Benzene, and Constituent Binary Systems
at 101.3 KPa
Toluene - Acetone Toluene- 2-Butanone
1 n-Toluene 1 n-Toluene
2 n-Acetone 2 2-Butanone

Liquid Vapor Liquid


Total
mole Temperat mole mole Temperat
No. pressure No.
fraction ure (K) fraction fraction ure (K)
(N/sqm)
TOL TOL TOL

1 0.99 381.1256 0.92 101000 1 1 383.7261


2 0.978 378.5251 0.823 101000 2 0.9955 383.326
3 0.965 376.1246 0.74 101000 3 0.9915 383.006
4 0.955 374.2242 0.7 101000 4 0.9825 382.3759
5 0.941 372.5239 0.655 101000 5 0.9595 380.3254
6 0.932 370.8238 0.625 101000 6 0.915 377.3248
7 0.922 369.5236 0.602 101000 7 0.881 375.4045
8 0.897 366.4233 0.525 101000 8 0.82 372.674
9 0.885 364.4231 0.485 101000 9 0.8019 371.8239
10 0.865 362.323 0.45 101000 10 0.7641 370.2237
11 0.845 359.623 0.392 101000 11 0.6873 367.4234
12 0.825 357.923 0.37 101000 12 0.6018 364.9732
13 0.8 355.923 0.33 101000 13 0.5318 363.023
14 0.765 353.423 0.3 101000 14 0.4521 360.973
15 0.725 351.1232 0.255 101000 15 0.4142 359.873
16 0.67 348.5235 0.22 101000 16 0.358 358.923
17 0.622 346.2237 0.19 101000 17 0.3076 357.973
18 0.582 344.3239 0.166 101000 18 0.2988 357.523
19 0.515 342.124 0.14 101000 19 0.2154 356.223
20 0.45 339.924 0.118 101000 20 0.1985 355.773
21 0.36 337.324 0.088 101000 21 0.1389 354.923
22 0.284 335.924 0.068 101000 22 0.065 353.623
23 0.218 334.124 0.05 101000 23 0.0226 352.973
24 0.17 333.024 0.038 101000 24 0.0061 352.6231
25 0.122 331.9244 0.028 101000 25 0 352.5731
26 0.075 331.0246 0.02 101000 1 0.964 379.8053
27 0.05 330.4248 0.012 101000 2 0.958 379.1552
28 0.019 329.825 0.005 101000 3 0.921 378.4951
Rao, M. R.; Sitapathy, R.; 4 0.907 377.1948
Anjaneyulu, N. S. R.; Raju, G. J.
V. J.; Rao, C. V. J. Sci. Ind. Res., 5 0.902 375.6145
Sect. B, 1956, 15, 556 6 0.859 374.8243
7 0.836 373.6241
8 0.804 371.8239
9 0.766 370.1337
10 0.646 365.6333
11 0.591 364.3931
12 0.545 363.293
13 0.501 361.893
14 0.469 360.653
15 0.344 358.193
16 0.304 357.403
17 0.273 357.003
18 0.248 356.403
19 0.227 356.003
1 1 383.7223
2 0.974 382.0226
3 0.967 381.3227
4 0.911 378.1234
5 0.898 377.3235
6 0.888 376.5237
7 0.848 374.7241
8 0.841 374.2242
9 0.8 372.3245
10 0.787 371.8246
11 0.738 369.825
12 0.732 369.4251
13 0.691 367.8254
14 0.685 367.6255
15 0.645 366.3257
16 0.64 366.1258
17 0.602 364.826
18 0.588 364.5261
19 0.568 363.9262
20 0.531 362.9264
21 0.528 362.7265
22 0.517 362.3265
23 0.447 360.6269
24 0.422 359.827
25 0.39 359.1273
26 0.38 359.0273
27 0.344 358.4275
28 0.329 357.9276
29 0.297 357.4278
30 0.265 356.628
31 0.249 356.4281
32 0.215 355.9282
33 0.194 355.4284
34 0.17 354.9285
35 0.137 354.4287
36 0.11 353.9288
37 0.071 353.429
38 0.016 352.6292
39 0 352.4293
1 0.9075 378.65
2 0.8978 378.35
3 0.8716 377.05
4 0.8612 375.25
5 0.8233 374.05
6 0.8108 373.05
7 0.7444 371.35
8 0.6504 368.15
9 0.572 366.15
10 0.4916 362.85
11 0.4656 362.35
12 0.4442 361.45
13 0.3733 360.05
14 0.3237 358.65
15 0.2699 357.55
16 0.2291 356.17
17 0.1949 355.95
18 0.1501 355
19 0.1117 354.2
20 0.0377 352.75
Steinhauser, H. H.; White, R. R. Ind
Chem., 1949, 41, 2912-20 Vapor-L
Equilibria Data for Ternary Mixtu
heptane - toluene system

Kojima, K.; Hirata, M. Kagaku Kog


1960, 24, 214-8 A modified equilib
still

Rivenq, F. Bull. Soc. Chim. Fr., 197


3782-3 Ebulliometry of methylet
ketone and toluene mixtures
(vapour-liquid) equilibria data for
binary systems (tolueneYacetic acid
(tolueneYmethyl ethyl ketone)
atmospheric pressure
e Benzene - Acetonitrile Toluene - Acetonitrile
1 n-Benzene 1 n-Toluene
2 Acetonitrile 2 Acetonitrile

Vapor Liquid Vapor


Total Total
mole mole Temperat mole
pressure No. pressure No.
fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
TOL BENZENE BENZENE

1 101000 1 0.015 354.223 0.039 101000 1


0.986 101000 2 0.03 353.523 0.073 101000 2
0.971 101000 3 0.051 352.5231 0.119 101000 3
0.9445 101000 4 0.083 351.4232 0.177 101000 4
0.8719 101000 5 0.105 350.8232 0.209 101000 5
0.765 101000 6 0.137 349.9233 0.251 101000 6
0.6957 101000 7 0.181 349.1234 0.296 101000 7
0.605 101000 8 0.206 348.7234 0.325 101000 8
0.58 101000 9 0.235 348.3235 0.349 101000 9
0.5291 101000 10 0.265 348.0235 0.372 101000 10
0.4479 101000 11 0.302 347.6236 0.397 101000 11
0.372 101000 12 0.343 347.3236 0.429 101000 12
0.3146 101000 13 0.383 347.1236 0.447 101000 13
0.2572 101000 14 0.428 347.0236 0.474 101000 14
0.2292 101000 15 0.44 346.9236 0.482 101000 15
0.1973 101000 16 0.466 346.9236 0.496 101000 16
0.1658 101000 17 0.479 346.9236 0.502 101000 17
0.1604 101000 18 0.506 346.8236 0.516 101000 18
0.1142 101000 19 0.513 346.8236 0.52 101000 19
0.1045 101000 20 0.521 346.8236 0.524 101000 20
0.0719 101000 21 0.546 346.8236 0.537 101000 21
0.0371 101000 22 0.579 346.9236 0.555 101000 22
0.0122 101000 23 0.616 347.0236 0.573 101000 23
0.0046 101000 24 0.658 347.1236 0.596 101000 24
0 101000 25 0.687 347.2236 0.616 101000 25
0.866 101320 26 0.701 347.3236 0.624 101000 26
0.84 101320 27 0.737 347.3236 0.648 101000 27
0.813 101320 28 0.78 347.8235 0.68 101000 1
0.773 101320 29 0.822 348.3235 0.715 101000 2
0.729 101320 30 0.876 349.2234 0.77 101000 3
0.667 101320 31 0.928 350.4233 0.84 101000 4
0.631 101320 32 0.962 351.6232 0.904 101000 5
0.58 101320 33 0.989 352.6231 0.96 101000 6
0.528 101320 1 0.02 353.7289 0.048 101000 7
0.393 101320 2 0.027 353.5289 0.062 101000 8
0.351 101320 3 0.056 352.1294 0.125 101000 9
0.32 101320 4 0.065 351.6295 0.147 101000 10
0.288 101320 5 0.077 351.1297 0.165 101000 11
0.264 101320 6 0.176 349.1303 0.293 101000 12
0.184 101320 7 0.242 348.0306 0.355 101000 13
0.16 101320 8 0.299 347.5307 0.393 101000 14
0.148 101320 9 0.371 346.9309 0.438 101000 15
0.131 101320 10 0.38 346.8309 0.449 101000 1
0.125 101320 11 0.44 346.531 0.485 101000 2
1 101320 12 0.513 346.3311 0.519 101000 3
0.921 101320 13 0.5294 346.1312 0.5294 101000 4
0.906 101320 14 0.581 346.3311 0.545 101000 5
0.769 101320 15 0.665 346.531 0.6 101000 6
0.743 101320 16 0.713 346.9309 0.626 101000 7
0.72 101320 17 0.767 347.1309 0.657 101000 8
0.649 101320 18 0.79 347.5307 0.68 101000 9
0.638 101320 19 0.92 349.4302 0.801 101000 10
0.578 101320 1 0 354.75 0 101300 11
0.556 101320 2 0.017 353.85 0.039 101300 12
0.495 101320 3 0.027 353.45 0.065 101300 13
0.488 101320 4 0.048 352.65 0.102 101300 14
0.442 101320 5 0.058 352.15 0.129 101300 15
0.433 101320 6 0.123 350.25 0.22 101300 16
0.4 101320 7 0.148 349.55 0.253 101300 1
0.391 101320 8 0.195 348.85 0.296 101300 2
0.354 101320 9 0.218 348.35 0.323 101300 3
0.345 101320 10 0.268 347.75 0.366 101300 4
0.333 101320 11 0.34 347.15 0.41 101300 5
0.306 101320 12 0.384 346.95 0.437 101300 6
0.298 101320 13 0.541 346.75 0.538 101300 7
0.286 101320 14 0.608 346.85 0.582 101300 8
0.244 101320 15 0.627 346.85 0.588 101300 9
0.22 101320 16 0.663 347.05 0.623 101300 10
0.204 101320 17 0.712 347.25 0.643 101300 11
0.198 101320 18 0.787 347.95 0.717 101300 12
0.173 101320 19 0.83 348.45 0.737 101300 13
0.169 101320 20 0.867 349.25 0.789 101300 14
0.153 101320 21 0.869 349.25 0.787 101300 15
0.129 101320 22 0.915 350.25 0.842 101300 16
0.121 101320 23 0.929 350.65 0.858 101300 17
0.1 101320 24 0.961 351.55 0.91 101300 18
0.091 101320 25 1 353.25 1 101300 19
0.08 101320 Mato, F.; Sanchez, M. An. R. Soc. Esp. Fis. 20
Quim., B, 1967, 63, 1-11 Liquid-vapor
0.062 101320 equilibrium of binary mixtures of 21
0.045 101320 acetonitrile: I 22
0.035 101320 Chem. Eng. Data, 1980, 25, 11-3 Isobaric 23
Vapor-Liquid Equilibria of Binary Systems
0.008 101320 of Acetonitrile with Benzene, Toluene, 24
0 101320 and Methylcyclohexane 25
0.7273 101300 Data, 1991, 36, 293 Isobaric Vapor-Liquid 26
Equilibria for the Binary Systems Formed
0.7895 101300 by Acetonitrile and Aromatic 27
0.7257 101300 Hydrocarbons 28
0.6407 101300 29
0.618 101300 30
0.5801 101300
0.5244 101300
0.3833 101300
0.3259 101300
0.2865 101300
0.2624 101300
0.2305 101300
0.21 101300
0.1632 101300
0.1374 101300
0.1195 101300
0.0925 101300
0.0679 101300
0.0509 101300
0.0182 101300
ser, H. H.; White, R. R. Ind. Eng.
1949, 41, 2912-20 Vapor-Liquid
bria Data for Ternary Mixtures
eptane - toluene system

, K.; Hirata, M. Kagaku Kogaku,


4, 214-8 A modified equilibrium
still

, F. Bull. Soc. Chim. Fr., 1972, ,


3 Ebulliometry of methylethyl
one and toluene mixtures
r-liquid) equilibria data for the
stems (tolueneYacetic acid) and
eneYmethyl ethyl ketone) at
atmospheric pressure
Toluene - Acetonitrile Diethylamine - Dipropylamine
1 Diethylamine
Acetonitrile 2 Dipropylamine

Liquid Vapor Liquid Vapor


Total Total
mole Temperat mole mole Temperat mole
pressure No. pressure
fraction ure (K) fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
Tol TOL DIETH-01 DIETH-01

0.994 381.4257 0.913 101000 1 0 382.3 0 101300


0.974 378.6251 0.827 101000 2 0.013 380.5 0.067 101300
0.946 374.9244 0.709 101000 3 0.082 372.6 0.32 101300
0.904 370.3237 0.596 101000 4 0.104 370.4 0.381 101300
0.846 366.1233 0.488 101000 5 0.151 366.2 0.488 101300
0.785 363.023 0.42 101000 6 0.184 363.9 0.545 101300
0.716 360.823 0.365 101000 7 0.221 360.9 0.606 101300
0.662 359.323 0.334 101000 8 0.252 359.1 0.646 101300
0.601 358.423 0.307 101000 9 0.286 356.9 0.688 101300
0.531 357.323 0.277 101000 10 0.313 355.1 0.717 101300
0.458 356.523 0.253 101000 11 0.346 353 0.75 101300
0.37 355.823 0.223 101000 12 0.397 350.2 0.796 101300
0.297 355.323 0.198 101000 13 0.454 346.5 0.822 101300
0.243 355.023 0.177 101000 14 0.518 343.9 0.857 101300
0.209 354.823 0.163 101000 15 0.577 341.4 0.882 101300
0.168 354.723 0.142 101000 16 0.671 337.8 0.911 101300
0.139 354.623 0.125 101000 17 0.785 334.5 0.946 101300
0.122 354.623 0.116 101000 18 0.842 333 0.96 101300
0.108 354.523 0.106 101000 19 Resa,0.898 331.6 C.; de
J. M.; Gonzalez, 0.975 101300
Landaluce, S.
0.1 354.523 0.1 101000 20 O.; Lanz,1J. J. Chem.
328.5 Eng. Data,1 2000,
101300
45,
0.095 354.523 0.097 101000 867-871 Vapor-liquid equilibrium of
binary mixtures containing diethylamine +
0.088 354.523 0.092 101000 diisopropylamine at 101.3 kPa, and vapor
0.078 354.623 0.084 101000 pressures of dipropylamine
0.076 354.623 0.081 101000
0.073 354.623 0.08 101000
0.057 354.623 0.065 101000
0.021 354.723 0.028 101000
0.982 378.1234 0.865 101325
0.961 373.1244 0.7748 101325
0.8939 365.126 0.56 101325
0.859 363.9262 0.482 101325
0.7948 362.0266 0.404 101325
0.7348 360.3269 0.348 101325
0.6707 358.9273 0.2988 101325
0.5526 357.0279 0.2478 101325
0.5019 356.3281 0.231 101325
0.3928 354.6286 0.2028 101325
0.258 354.4287 0.178 101325
0.2117 354.0288 0.16 101325
0.083 353.9288 0.09 101325
0.049 354.1288 0.058 101325
0.024 354.3287 0.032 101325
0.982 380.6229 0.854 101000
0.977 379.823 0.836 101000
0.956 376.7237 0.738 101000
0.929 374.3241 0.665 101000
0.876 368.7253 0.526 101000
0.84 366.5257 0.473 101000
0.785 364.2262 0.417 101000
0.605 358.7274 0.315 101000
0.533 357.5277 0.284 101000
0.375 355.8282 0.23 101000
0.284 354.9285 0.195 101000
0.221 354.5286 0.172 101000
0.182 354.4287 0.154 101000
0.1218 354.2287 0.1218 101000
0.069 354.5286 0.081 101000
0.033 354.6286 0.051 101000
1 383.75 1 101300
0.976 381.15 0.91 101300
0.973 380.25 0.885 101300
0.963 379.35 0.855 101300
0.95 378.15 0.817 101300
0.94 376.95 0.785 101300
0.937 375.55 0.76 101300
0.92 374.75 0.725 101300
0.917 373.85 0.713 101300
0.897 372.45 0.647 101300
0.88 370.65 0.622 101300
0.867 370.15 0.613 101300
0.844 368.35 0.566 101300
0.837 367.75 0.546 101300
0.786 365.15 0.474 101300
0.772 364.45 0.468 101300
0.703 361.55 0.393 101300
0.623 359.35 0.351 101300
0.585 358.45 0.323 101300
0.505 357.05 0.283 101300
0.466 356.55 0.267 101300
0.393 355.65 0.233 101300
0.292 354.75 0.205 101300
0.153 354.05 0.135 101300
0.117 353.85 0.113 101300
0.09 353.85 0.092 101300
0.088 353.95 0.091 101300
0.07 354.05 0.076 101300
0.048 354.15 0.057 101300
0 354.75 0 101300
Mato, F.; Sanchez, M. An. R. Soc. Esp. Fis.
Quim., B, 1967, 63, 1-11 Liquid-vapor
equilibrium of binary mixtures of
acetonitrile: I

Kesarwani, V. S.; Chandak, B. S.; Kher, M.


G. Chem. Petro-Chem. J., 1979, 10, 3
Chem. Eng. Data, 1980, 25, 11-3 Isobaric
Vapor-Liquid Equilibria of Binary Systems
of Acetonitrile with Benzene, Toluene,
and Methylcyclohexane
Data, 1991, 36, 293 Isobaric Vapor-Liquid
Equilibria for the Binary Systems Formed
by Acetonitrile and Aromatic
Hydrocarbons
Diethylamine - Diisopropylamine Diethylamine - Triethylamine
1 Diethylamine 1 Diethylamine
2 Diisopropylamine 2 Triethylamine

Liquid Vapor Liquid


Total
mole Temperat mole mole Temperat
No. pressure No.
fraction ure (K) fraction fraction ure (K)
(N/sqm)
DIETH-01 DIETH-01 DIETH-01

1 1 328.5 1 101300 1 0 363.6731


2 0.964 328.8 0.978 101300 2 0.025 362.223
3 0.938 329.2 0.962 101300 3 0.05 360.373
4 0.889 329.8 0.935 101300 4 0.09 358.123
5 0.84 330.7 0.91 101300 5 0.169 353.923
6 0.763 332.1 0.871 101300 6 0.305 348.4235
7 0.68 333.5 0.827 101300 7 0.437 343.8239
8 0.635 334.4 0.802 101300 8 0.497 341.924
9 0.554 336 0.757 101300 9 0.664 337.374
10 0.469 337.8 0.681 101300 10 0.748 335.324
11 0.439 338.8 0.668 101300 11 0.863 332.8241
12 0.367 340.8 0.601 101300 12 0.946 331.0746
13 0.282 343.4 0.519 101300 13 0.972 330.5748
14 0.258 344.3 0.485 101300 14 1 330.1749
15 0.172 347.9 0.357 101300 1 0 361.973
16 0.143 349.6 0.31 101300 2 0.02 360.473
17 0.126 350.4 0.284 101300 3 0.039 359.173
18 0.112 351 0.249 101300 4 0.052 358.323
19 0.089 351.9 0.209 101300 5 0.065 357.523
20 Resa,0.07 353.6 C.; de
J. M.; Gonzalez, 0.168 101300
Landaluce, S. 6 0.09 356.293
21 O.; Lanz,0 J. J. Chem.
357.1 Eng. Data,0 2000,
101300
45, 7 0.092 355.973
867-871 Vapor-liquid equilibrium of 8 0.14 353.623
binary mixtures containing diethylamine +
diisopropylamine at 101.3 kPa, and vapor 9 0.215 350.2733
pressures of dipropylamine 10 0.43 342.424
11 0.601 337.424
12 0.782 332.974
13 0.853 331.3245
14 0.932 329.825
15 0.985 328.8753
16 1 328.6753
1 0 361.973
2 0.02 360.473
3 0.039 359.173
4 0.052 358.323
5 0.065 357.523
6 0.09 356.293
7 0.092 355.973
8 0.14 353.623
9 0.215 350.2733
10 0.43 342.424
11 0.601 337.424
12 0.782 332.974
13 0.853 331.3245
14 0.932 329.825
15 0.985 328.8753
16 1 328.6753
1 0 363.6731
2 0.025 362.223
3 0.05 360.373
4 0.09 358.123
5 0.169 353.923
6 0.305 348.4235
7 0.437 343.8239
8 0.497 341.924
9 0.664 337.374
10 0.748 335.324
11 0.863 332.8241
12 0.946 331.0746
13 0.972 330.5748
14 1 330.1749
Bittrich, H.-J.; Kauer, E.; Kraft, M
Schoppe, G.; Soll, W.; Ullrich, A. J. P
Chem., 1962, 17, 250 The Vapor Pre
of the Ethylamines
(Leipzig), 1962, 219, 224 The
thermodynamics of the system
diethylamine + triethylamine: I liq
vapour equilibrium
hylamine Diethylamine - Chloroform Diisopropylamine - Chlor
1 Diethylamine 1 Diisopropylamine
2 Chloroform 2 Chloroform

Vapor Liquid Vapor


Total Total
mole mole Temperat mole
pressure No. pressure No.
fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
DIETH-01 DIETHYL DIETHYL

0 106650 1 1 329.25 1 101300 1


0.046 106650 2 0.9882 329.25 0.9973 101300 2
0.12 106650 3 0.9652 330.15 0.9892 101300 3
0.197 106650 4 0.9126 331.75 0.9686 101300 4
0.372 106650 5 0.8761 333.15 0.9546 101300 5
0.552 106650 6 0.818 334.55 0.9336 101300 6
0.637 106650 7 0.7821 335.85 0.9058 101300 7
0.738 106650 8 0.7098 337.85 0.8483 101300 8
0.846 106650 9 0.672 338.75 0.8084 101300 9
0.889 106650 10 0.6167 339.75 0.7361 101300 10
0.946 106650 11 0.5866 340.25 0.6973 101300 11
0.979 106650 12 0.4757 341.55 0.5199 101300 12
0.988 106650 13 0.468 341.55 0.4911 101300 13
1 106650 14 0.4487 341.55 0.4545 101300 14
0 101320 15 0.4468 341.55 0.4487 101300 15
0.042 101320 16 0.4294 341.55 0.4333 101300 16
0.085 101320 17 0.4111 341.45 0.4044 101300 17
0.124 101320 18 0.3939 341.45 0.3852 101300 18
0.153 101320 19 0.3518 341.05 0.3149 101300 19
0.225 101320 20 0.3262 340.85 0.2776 101300 20
0.243 101320 21 0.2738 340.05 0.2031 101300 21
0.316 101320 22 0.2066 338.75 0.1358 101300
0.449 101320 23 0.1391 337.35 0.0799 101300
0.678 101320 24 0.1005 336.25 0.0472 101300
0.802 101320 25 0.0917 336.15 0.0442 101300
0.91 101320 26 0.0591 335.45 0.0311 101300
0.948 101320 27 0.0546 334.55 0.0211 101300
0.97 101320 28 0 334.45 0 101300
0.993 101320 Ninov, J. I.; Stefanova, T. K.; Petrov, P. S. J.
Chem. Eng. Data, 1995, 40, 199-201
1 101320 Vapor-Liquid Equilibria at 101.3 kPa for
0 101320 Diethylamine + Chloroform
0.042 101320
0.085 101320
0.124 101320
0.153 101320
0.225 101320
0.243 101320
0.316 101320
0.449 101320
0.678 101320
0.802 101320
0.91 101320
0.948 101320
0.97 101320
0.993 101320
1 101320
0 106650
0.046 106650
0.12 106650
0.197 106650
0.372 106650
0.552 106650
0.637 106650
0.738 106650
0.846 106650
0.889 106650
0.946 106650
0.979 106650
0.988 106650
1 106650
ch, H.-J.; Kauer, E.; Kraft, M.;
, G.; Soll, W.; Ullrich, A. J. Prakt.
962, 17, 250 The Vapor Pressures
of the Ethylamines
ipzig), 1962, 219, 224 The
modynamics of the system
amine + triethylamine: I liquid-
vapour equilibrium
Diisopropylamine - Chloroform Diethylamine - Ethyl Acetate
Diisopropylamine 1 Diethylamine
Chloroform 2 n-Ethyl Acetate

Liquid Vapor Liquid Vapor


Total Total
mole Temperat mole mole Temperat mole
pressure No. pressure
fraction ure (K) fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
DIIP DIIP DIETH-01 DIETH-01

1 357.1 1 101300 1 0 350.2233 0 101320


0.993 357.1 0.993 101300 2 0.045 348.2235 0.108 101320
0.983 357.1 0.983 101300 3 0.088 346.1737 0.192 101320
0.958 357.1 0.956 101300 4 0.118 345.2238 0.242 101320
0.941 357 0.937 101300 5 0.138 344.5739 0.281 101320
0.896 356.9 0.884 101300 6 0.162 343.7239 0.312 101320
0.818 356.5 0.79 101300 7 0.217 342.174 0.382 101320
0.769 356 0.723 101300 8 0.281 340.574 0.465 101320
0.688 355 0.609 101300 9 0.303 339.774 0.496 101320
0.613 353.7 0.497 101300 10 0.327 339.274 0.521 101320
0.567 352.6 0.431 101300 11 0.333 339.324 0.53 101320
0.481 350.3 0.333 101300 12 0.346 338.924 0.541 101320
0.428 348.7 0.268 101300 13 0.367 338.424 0.56 101320
0.39 347.1 0.225 101300 14 0.413 337.374 0.609 101320
0.35 345.6 0.185 101300 15 0.44 336.824 0.63 101320
0.278 343 0.123 101300 16 0.471 336.174 0.659 101320
0.211 340.5 0.064 101300 17 0.504 335.774 0.678 101320
0.139 338.1 0.035 101300 18 0.538 335.224 0.703 101320
0.102 336.9 0.024 101300 19 0.573 334.524 0.723 101320
Resa,0.067 335.8 C.; de
J. M.; Gonzalez, 0.015 101300
Landaluce, S. 20 0.618 334.024 0.755 101320
334.1 101300
O.; Lanz,0J. J. Chem. Eng. Data,0 2000, 45, 21 0.629 333.574 0.76 101320
867-871 Vapor-liquid equilibrium of 22 0.688 332.7741 0.8 101320
binary mixtures containing diethylamine +
diisopropylamine at 101.3 kPa, and vapor 23 0.713 332.3242 0.821 101320
pressures of dipropylamine 24 0.736 331.9743 0.833 101320
25 0.777 331.3245 0.864 101320
26 0.811 330.9746 0.883 101320
27 0.846 330.3248 0.905 101320
28 0.871 330.1749 0.923 101320
29 0.915 329.5751 0.949 101320
30 0.949 329.1252 0.968 101320
31 0.962 328.8253 0.975 101320
32 1 328.4254 1 101320

Engelmann, K.; Bittrich, H.-J. Wiss. Z. Tech.


Hochsch. Chem. "Carl Schorlemmer"
Leuna-Merseburg, 1966, 8, 148-53
methylamine - dimethylamine methylformamide - methylacetamide
1 n-methylamine 1 n-methylformamide
2 dimethylamine 2 n-methylacetamide
Liquid Vapor
Liquid
mole mole Total
Temperat mole Temperat
No. fraction fraction pressure No.
ure (K) fraction ure (K)
METHY- METHY- (N/sqm)
METF
01 01

1 0.07 350.2233 0.13 101320 1 0.92 469.61


2 0.265 345.1238 0.38 101320 2 0.82 470.21
3 0.46 340.924 0.58 101320 3 0.747 470.81
4 0.505 340.124 0.62 101320 4 0.676 471.61
5 Delzenne,
0.73 A.336.124 0.815 101320
O. Chem. Eng. Sci., 1952, 1, 5 0.623 472.71
241 Liquid-vapor equilibrium studies: a 6 0.556 474.31
dichloroethane + 1,4-dioxane system at 1
atmosphere b monomethylamine + 7 0.491 475.11
dimethylamine system at 10 atmospheres 8 0.395 476.61
9 0.31 477.31
10 0.26 477.61
Kortuem, G.; Biedersee, H. Chem.-
Tech., 1970, 42, 552-560 Vapor-li
equilibria (boiling diagrams) of bi
systems of high relative volatili
methylacetamide dimethylformamide - chloroform dimethylformamide - ace
1 n,n-dimethylformamide 1 n,n-dimethylformamide
2 Chloroform 2 Acetic Acid

Vapor Liquid Vapor


Total Total
mole mole Temperat mole
pressure No. pressure No.
fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
METF DMF DMF

0.925 101325 1 0.9588 408.9 0.6449 101325 1


0.845 101325 2 0.923 401.4 0.4824 101325 2
0.78 101325 3 0.8891 393.9 0.338 101325 3
0.72 101325 4 0.8427 384.2 0.2297 101325 4
0.675 101325 5 0.8032 376.4 0.1852 101325 5
0.608 101325 6 0.7504 371.4 0.1118 101325 6
0.545 101325 7 0.7496 372.1 0.1111 101325 7
0.44 101325 8 0.6545 359.8 0.0929 101325 8
0.36 101325 9 0.5973 356.9 0.0529 101325 9
0.305 101325 10 0.583 354 0.0505 101325 10
m, G.; Biedersee, H. Chem.-Ing.- 11 0.4972 350.7 0.0458 101325 11
1970, 42, 552-560 Vapor-liquid
ria (boiling diagrams) of binary 12 0.4643 348.4 0.0397 101325 12
ms of high relative volatility 13 0.218 337.8 0.0159 101325 13
14 0.0842
Ye, 335.4
C.-s.; Lin, C.; 0.0159
Fang, X.-l. 101325
Fluid Phase 14
Equilib., 2009, 278, 85-89 Experimental 15
measurements and correlations of vapor
16
liquid equilibrium data for the binary
system of chloroform +N,N- 17
dimethylformamide at 101.3 kPa 18
19
20
dimethylformamide - acetic acid methylacetamide - acetic acid
n,n-dimethylformamide 1 n-methylacetamide
Acetic Acid 2 Acetic Acid

Liquid Vapor Liquid Vapor


Total Total
mole Temperat mole mole Temperat mole
pressure No. pressure
fraction ure (K) fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
DMF DMF MA MA

0.952 426.01 0.9729 101330 1 0.9221 475.6 0.8445 101330


0.9124 426.57 0.9436 101330 2 0.8665 472.95 0.7198 101330
0.8289 427.79 0.8757 101330 3 0.832 470.85 0.6404 101330
0.7528 428.26 0.7917 101330 4 0.8002 468.26 0.5652 101330
0.7087 428.54 0.7316 101330 5 0.7797 465.68 0.5141 101330
0.6323 427.71 0.5954 101330 6 0.7488 463.02 0.4419 101330
0.584 426.69 0.5067 101330 7 0.717 460.69 0.3744 101330
0.541 425.49 0.3638 101330 8 0.7011 458.1 0.3344 101330
0.4789 422.91 0.2827 101330 9 0.666 455.35 0.2853 101330
0.407 418.88 0.1794 101330 10 0.649 452.52 0.2528 101330
0.3461 415.1 0.13 101330 11 0.6248 449.88 0.2244 101330
0.3135 412.76 0.0908 101330 12 0.5857 444.8 0.1709 101330
0.2774 410.27 0.0659 101330 13 0.5543 442.56 0.1399 101330
0.2302 406.71 0.0399 101330 14 0.5283 439.7 0.1101 101330
0.2092 405.19 0.0374 101330 15 0.5128 437.44 0.0963 101330
0.1861 403.36 0.0296 101330 16 0.4943 434.8 0.0829 101330
0.1655 401.83 0.0249 101330 17 0.4438 429.55 0.0596 101330
0.1475 400.49 0.019 101330 18 0.4022 424.45 0.0477 101330
0.1083 397.85 0.0167 101330 19 0.3859 423.01 0.0431 101330
0.0646 395.01
Li, X.; Chang, 0.0038
W.; Guan, 101330
G. Huaxue 20 0.3687 420.31 0.0349 101330
Gongcheng, 2006, 34, 4;36 Isobar ic 21 0.3393 417.47 0.0269 101330
vapor-liquid equilibr ia for the binary
system of acetic ac id + dimethylformam 22 0.3173 414.75 0.0209 101330
ide 23 0.2926 412.03 0.0104 101330
24 0.2666 409.36 0.0089 101330
25 0.2395 407 0.0068 101330
26 0.1736 402.93 0.0052 101330
27 0.0954 397.6 0.0045 101330
28 0.0663 395.62 0.0034 101330
29 Chang, 393.16
0.0387W.; Wan, H.; Guan,
0.0022 101330
G.; Yao, H.
Fluid Phase Equilib., 2006, 242, 204-209
Isobaric vapor liquid equilibria for water +
acetic acid + (N-methyl pyrrolidone or N-
methyl acetamide)
dimethylacetamide - acetic acid dimethylformamide - Methylformate
1 n,n-dimethylacetamide 1 n,n-dimethylformamide
2 Acetic Acid 2 Methyl Formate

Liquid Vapor Liquid


Total
mole Temperat mole mole Temperat
No. pressure No.
fraction ure (K) fraction fraction ure (K)
(N/sqm)
DMA DMA N:N-D-01

1 0.95 440.112 0.97 101325 1 0 304.8333


2 0.855 442.1118 0.908 101325 2 0.0624 306.6326
3 0.775 443.4117 0.81 101325 3 0.185 310.0312
4 0.713 443.9116 0.713 101325 4 0.1908 310.731
5 0.675 443.7116 0.645 101325 5 0.2928 313.8298
6 0.608 442.6117 0.508 101325 6 0.3197 315.2294
7 0.52 438.1122 0.325 101325 7 0.371 317.0288
8 0.485 434.6125 0.263 101325 8 0.5109 324.6266
9 0.425 431.1129 0.18 101325 9 0.5652 328.7253
10 0.4 427.4135 0.143 101325 10 0.5788 329.1252
11 0.36 422.6145 0.085 101325 11 0.6446 335.024
12 0.325 419.6151 0.062 101325 12 0.6913 339.324
13 0.268 412.1166 0.027 101325 13 0.7434 345.4238
14 0.225 411.1168 0.025 101325 14 0.774 350.6233
15 0.198 406.8176 0.009 101325 15 0.7843 352.0231
16 0.183 404.4181 0.012 101325 16 0.858 367.0234
17 0.16 402.6185 0.007 101325 17 0.8825 372.924
18 0.125 400.119 0.004 101325 18 0.9 377.4249
19 Carli, A.; Di398.6193
0.098 0.003 E. 101325
Cave, S.; Sebastiani, Chem. 19 0.9352 388.3265
20 Eng.0.063 394.6201
Sci., 1972, 0.002 101325
27, 993 Thermodynamic 20 0.9485 394.5274
characterization of vapor-liquid equilibria 21 0.9487 394.7275
of mixtures acetic acid -
dimethylacetamide and water - 22 0.9674 404.6303
dimethylacetamide 23 0.9757 409.7313
24 0.9771 411.2316
25 0.9875 416.6327
26 0.9927 420.3334
27 0.9958 422.3338
28 1 425.735
Rother, M.; Steinbrecher, M.; Bittric
Z. Phys. Chem. (Leipzig), 1962, 220
104 Vapor-liquid equilibrium me
formate + dimethyl formamid
- Methylformate dimethylformamide - Ethyl acetate dimethylformamide - dip
1 n,n-dimethylformamide 1 n,n-dimethylformamide
2 n-Ethyl Acetate 2 Dipropyl Ether

Vapor Liquid Vapor


Total Total
mole mole Temperat mole
pressure No. pressure No.
fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
N:N-D-01 N:N-D-01 N:N-D-01

0 101320 1 0 350.24 0 101300 1


0.0013 101320 2 0.0049 351.15 0.0006 101300 2
0.0029 101320 3 0.0189 351.69 0.001 101300 3
0.003 101320 4 0.0465 352.45 0.0042 101300 4
0.0048 101320 5 0.0693 353.26 0.0049 101300 5
0.0047 101320 6 0.1863 356.06 0.0162 101300 6
0.0058 101320 7 0.2459 360.95 0.025 101300 7
0.0117 101320 8 0.3069 363.65 0.0299 101300 8
0.0168 101320 9 0.4056 366.3 0.0565 101300 9
0.0174 101320 10 0.4874 367.67 0.0601 101300 10
0.0239 101320 11 0.5689 371.69 0.0687 101300 11
0.0315 101320 12 0.6134 374.95 0.1001 101300 12
0.0476 101320 13 0.6501 379.26 0.1258 101300 13
0.0626 101320 14 0.7402 383.17 0.1836 101300 14
0.0673 101320 15 0.8473 394.98 0.292 101300 15
0.1362 101320 16 0.8789 399.39 0.4191 101300 16
0.175 101320 17 0.9012 402.66 0.5989 101300 17
0.2062 101320 18 0.9221 407.65 0.7256 101300 18
0.31 101320 19 0.9403 413.06 0.8025 101300 19
0.38 101320 20 0.9707 418.04 0.9119 101300 20
0.379 101320 21 0.9954
Hua, C.; Bai, P.; Li,0.9832
424.26 X.; Ma, P.101300 21
0.5344 101320 22 Petrochemical
1 426.3
Technology, 2005,1 101300
34(6), 22
0.6268 101320 4;547 Atmospheric Vapor-Liquid 23
Equilibrium of Ethanol-N,N-Dimethyl
0.6547 101320 Formamide and Ethyl Acetate-N,N-
0.767 101320 Dimethyl Formamide Systems
0.8566 101320
0.9102 101320
1 101320
M.; Steinbrecher, M.; Bittrich, H.-J.
Chem. (Leipzig), 1962, 220, 89-
apor-liquid equilibrium methyl
mate + dimethyl formamide
dimethylformamide - dipropyl ether dimethylacetamide - diisopropyl ether
n,n-dimethylformamide 1 n,n-dimethylacetamide
Dipropyl Ether 2 Diisopropyl Ether

Liquid Vapor Liquid Vapor


Total Total
mole Temperat mole mole Temperat mole
pressure No. pressure
fraction ure (K) fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
N:N-D-01 N:N-D-01 DMA DMA

0 363.16 0 101300 1 1 440.31 1 101300


0.061 363.77 0.032 101300 2 0.998 437.04 0.898 101300
0.129 364.57 0.055 101300 3 0.996 435.32 0.865 101300
0.2 365.43 0.071 101300 4 0.991 429.41 0.744 101300
0.262 366.18 0.081 101300 5 0.978 421.68 0.574 101300
0.318 366.87 0.089 101300 6 0.939 401.27 0.305 101300
0.375 367.65 0.096 101300 7 0.898 388.26 0.202 101300
0.46 368.76 0.101 101300 8 0.842 375.56 0.121 101300
0.511 369.55 0.105 101300 9 0.805 368.99 0.094 101300
0.561 370.62 0.116 101300 10 0.775 364.66 0.087 101300
0.609 371.77 0.124 101300 11 0.712 355.89 0.065 101300
0.66 373.08 0.135 101300 12 0.658 351.54 0.061 101300
0.704 374.67 0.146 101300 13 0.607 348.94 0.06 101300
0.778 378.87 0.18 101300 14 0.554 346.82 0.055 101300
0.842 384.08 0.225 101300 15 0.498 345.69 0.048 101300
0.895 391.86 0.313 101300 16 0.431 344.57 0.039 101300
0.949 405.08 0.505 101300 17 0.378 343.99 0.034 101300
0.966 410.79 0.62 101300 18 0.314 343.61 0.029 101300
0.975 413.81 0.697 101300 19 0.266 343.13 0.028 101300
0.984 417.24 0.772 101300 20 0.168 342.43 0.017 101300
0.991 420.79 0.852 101300 21 0.084 342.34 0.009 101300
0.998E.; Monton,
Lladosa, 423.99 J. B. ;0.962
Burguet,101300
M. C.; 22 Zhang,
0.051 342.08
Z.; Yang, Li, W. J.101300
L.; Xing, Y.;0.006 Chem.
Munoz,1R. J. Chem.
425.63Eng. Data,12007, 101300
52, 23 Eng. Data, 341.51
0 2013, 58, 357-363 Vapor 0 101300
Liquid
532-537 Phase Equilibria Involved in Equilibrium for Ternary and Binary
Extractive Distillation of Dipropyl Ether + Mixtures of 2-Isopropoxypropane, 2-
1-Propyl Alcohol Using N,N- Propanol, and N,N-Dimethylacetamide at
Dimethylformamide as Entrainer 101.3 kPa
dimethylformamide - 2-propanone dimethylformamide - 2-butanone
1 n,n-dimethylformamide 1 n,n-dimethylformamide
2 n-Acetone 2 2-Butanone

Liquid Vapor Liquid


Total
mole Temperat mole mole Temperat
No. pressure No.
fraction ure (K) fraction fraction ure (K)
(N/sqm)
DMF DMF N:N-D-01

1 0.925 398.1194 0.5247 101000 1 0 352.6292


2 0.84 380.3229 0.2994 101000 2 0.05 353.9288
3 0.5832 351.9294 0.0909 101000 3 0.1 355.2284
4 0.4843 345.8312 0.06 101000 4 0.2 358.1276
5 0.3384 338.9332 0.0272 101000 5 0.3 361.5267
6 0.286 335.6339 0.012 101000 6 0.4 365.226
7 0.1529 332.4345 0.0116 101000 7 0.5 369.875
8 0.0685 329.4352 0.008 101000 8 0.6 375.5239
1 1 426.0138 1 101320 9 0.7 382.4225
2 0.95 404.918 0.5225 101320 10 0.8 391.5207
3 0.9 390.9208 0.321 101320 11 0.9 404.3181
4 0.8 373.4243 0.158 101320 12 0.95 413.4163
5 0.7 362.3265 0.0923 101320 13 1 426.0138
6 0.6 354.2287 0.0583 101320 1 0.1259 361.8
7 0.5 348.0306 0.0384 101320 2 0.2203 368
8 0.4 343.1321 0.0255 101320 3 0.2947 373.4
9 0.3 338.9332 0.0164 101320 4 0.472 385.4
10 0.2 335.3339 0.0097 101320 5 0.6002 394.6
11 0.1 332.1346 0.0045 101320 6 0.7059 402.5
12 0.05 330.6349 0.0022 101320 7 0.7938 408
13 0 329.3352 0 101320 8 0.8392 411.4
1 0.935 405.2 0.495 101300 9 0.9386 419.9
2 0.918 397.2 0.47 101300 10 0.9595 422.4
3 0.905 396.7 0.384 101300 11 0.9746 422.9
4 0.899 392.2 0.411 101300 12 0.9779 423.4
5 0.881 389.7 0.339 101300 13 0.9832 423.7
6 0.874 390.2 0.343 101300 14 0.9872 424.2
7 0.86 386.7 0.222 101300 15 0.9891 424.4
8 0.835 383.2 0.238 101300 16 0.9924 424.7
9 0.808 378.7 0.139 101300 17 0.9945 425
10 0.784 375.2 0.136 101300
Misheneva, I. N.; Smirnov, V. V.; Sar
11 0.754 370.7 0.108 101300 A.; Pavlov, S. Yu. Prom-st Sint. Kau
12 0.707 365.7 0.085 101300 Liu, C.; Wang,1980, 11,C.;2 Ye, X. Ch
L.; He,
13 0.67 362.5 0.073 101300 Chem. Eng., 2006, 14, 4;825 The Iso
Vapor-Liquid Equilibrium of Butan
14 0.642 359.7 0.072 101300 DMF and Toluene-DMF at Reduc
15 0.598 356.2 0.048 101300 Pressures
16 0.503 348.8 0.051 101300
17 0.466 347.8 0.026 101300

Zemlyanskaya, T. A.; Komarova, L. F.;


Kormina, L. A.; Garber, Yu. N. Zh. Prikl.
Khim. (Leningrad), 1977, 50, 1159
Zemlyanskaya, T. A.; Komarova, L. F.;
Kormina, L. A.; Garber, Yu. N. Zh. Prikl.
Khim. (Leningrad), 1977, 50, 1159

Misheneva, I. N.; Smirnov, V. V.; Saraev, B.


A.; Pavlov, S. Yu. Prom-st Sint. Kauch.,
1980, 11, 2
ethanol-N,N-dimethyl formanide(DMF),
ethyl acetate-water-DMF and acetone-
chloroform-ethyl acetate at atmospheric
pressure
- 2-butanone dimethylacetamide - 2-propanone Dichloromethane - Chlor
1 n,n-dimethylacetamide 1 Dichloromethane
2 n-Acetone 2 Chloroform

Vapor Liquid Vapor


Total Total
mole mole Temperat mole
pressure No. pressure No.
fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
N:N-D-01 DMA DMA

0 101320 1 0.7519 382.1226 0.0667 101000 1


0.0063 101320 2 0.7214 378.1234 0.0571 101000 2
0.0125 101320 3 0.5356 359.1273 0.0267 101000 3
0.0262 101320 4 0.4733 343.6319 0.0181 101000 4
0.0428 101320 5 0.3685 345.6313 0.0146 101000 5
0.0634 101320 6 0.2347 337.1336 0.009 101000 6
0.092 101320 7 0.1858 335.5339
Deizenrot, 0.0073 E.101000
I. V.; Vinogradova, V.; 7
0.1312 101320 Sadchikova, N. A.; Kogan, V. B. Zh. Prikl. 8
Khim. (Leningrad), 1980, 53, 2551 Liquid-
0.191 101320 vapor equilibrium in systems formed by 9
0.292 101320 acetone, water, and dimethylacetamide. 10
0.488 101320 11
0.671 101320 12
1 101320 13
0.0211 100920 14
0.0487 100920 15
0.0672 100920 16
0.1239 100920 17
0.1688 100920 18
0.1987 100920 19
0.2405 100920 20
0.2688 100920 21
0.4697 100920 22
0.5812 100920 23
0.6918 100920 24
0.7346 100920
0.7924 100920
0.8456 100920
0.8672 100920
0.9076 100920
0.9349 100920

a, I. N.; Smirnov, V. V.; Saraev, B.


ov, S. Yu. Prom-st Sint. Kauch.,
Wang,1980, 11,C.;2 Ye, X. Chin. J.
L.; He,
ng., 2006, 14, 4;825 The Isobaric
iquid Equilibrium of Butanone-
and Toluene-DMF at Reduced
Pressures
Dichloromethane - Chloroform Dichloromethane - Tetrachloromethane
Dichloromethane 1 Dichloromethane
Chloroform 2 Tetrachloromethane

Liquid Vapor Liquid Vapor


Total Total
mole Temperat mole mole Temperat mole
pressure No. pressure
fraction ure (K) fraction fraction ure (K) fraction
(N/sqm) (N/sqm)
DCM DCM DCM DCM

1 312.8601 1 101320 1 1 312.8601 1 101320


0.9 314.2297 0.9675 101320 2 0.92 317.4787 0.968 101320
0.865 314.8895 0.965 101320 3 0.9 317.7286 0.9675 101320
0.805 315.9392 0.9 101320 4 0.8 319.728 0.92 101320
0.8 316.0791 0.92 101320 5 0.8 319.3881 0.925 101320
0.7 317.8786 0.86 101320 6 0.7 320.9776 0.88 101320
0.64 319.898 0.795 101320 7 0.655 319.3281 0.865 101320
0.6 320.8277 0.79 101320 8 0.6 322.2273 0.8425 101320
0.568 321.5075 0.715 101320 9 0.53 321.3475 0.8025 101320
0.5 321.9274 0.7025 101320 10 0.5 323.9268 0.785 101320
0.4725 322.2473 0.641 101320 11 0.4215 325.3963 0.7225 101320
0.4 324.2267 0.6 101320 12 0.4 325.9262 0.715 101320
0.385 324.0967 0.57 101320 13 0.335 327.6556 0.635 101320
0.32 326.1161 0.51 101320 14 0.3 328.9253 0.62 101320
0.3 326.526 0.4775 101320 15 0.2475 331.3045 0.55 101320
0.26 327.7256 0.425 101320 16 0.2 334.524 0.46 101320
0.225 328.4754 0.36 101320 17 0.155 337.594 0.375 101320
0.2 329.0052 0.335 101320 18 0.13 341.974 0.2225 101320
0.2 328.9253 0.345 101320 19 0.11 342.924 0.205 101320
0.17 329.5751 0.305 101320 20 0.1 342.724 0.22 101320
0.105 331.3245 0.195 101320 21 0.08 344.1039 0.18 101320
0.1 331.5745 0.1975 101320 22 0.065 345.8237 0.11 101320
0.083 332.2443
Kaplan, S. I.; Monakhova, Z. D. 101320
0.17 Zh. 23 0 349.9233 0 101320
Obshch. 333.924
0 Khim., 0 101320
1937, 7, 2499-2512 1 1 313.04 1 101325
Equilibrium in solutions: IV boiling point at 2 0.912 314.4296 0.972 101325
atmospheric pressure and composition of
vapor of binary mixtures consisting of 3 0.85 315.5593 0.944 101325
chlorides of methane and ethane 4 0.761 317.1288 0.908 101325
5 0.667 318.8783
Kaplan, 0.882
S. I.; Monakhova, 101325
Z. D. Zh.
6 320.0279
0.619 Khim., 1937, 7,0.857
Obshch. 2499-2512101325
Equilibrium in solutions: IV boiling point at
atmospheric pressure and composition of
vapor of binary mixtures consisting of
chlorides
Maass, of methaneG.;and
G.; Schneider, ethaneG.
Wilhelm,
Naturwissenschaften, 1960, 47, 228
Isobaric equilibrium measurements in the
system methylchloride + carbon
tetrachloride
Chloroform - Tetrachloromethane Dichloromethane - Acetic acid
1 Chloroform 1 Dichloromethane
2 Tetrachloromethane 2 Acetic Acid

Liquid Vapor Liquid


Total
mole Temperat mole mole Temperat
No. pressure No.
fraction ure (K) fraction fraction ure (K)
(N/sqm)
CHLORO CHLORO DICHL-01

1 1 333.924 1 101320 1 1 312.6902


2 0.9 334.624 0.95 101320 2 0.861 315.4094
3 0.875 334.924 0.92 101320 3 0.6769 320.3979
4 0.8 335.724 0.885 101320 4 0.5145 325.1365
5 0.7 337.024 0.81 101320 5 0.3881 333.2543
6 0.68 337.334 0.79 101320 6 0.2304 346.751
7 0.6 338.424 0.725 101320 7 0.1095 365.7259
8 0.55 339.104 0.665 101320 8 0.0359 373.5043
9 0.515 339.604 0.655 101320 9 0 390.9308
10 0.5 340.024 0.635 101320
Sadovnikova, L. V.; Belobokova, N
11 0.4 341.724 0.52 101320 Aleksandrova, M. N. Sb. Nauch.
12 0.377 342.084 0.495 101320 Ivanov. Energ. Inst., 1974, 14, 22
13 0.3 343.7239 0.395 101320
14 0.2 345.7237 0.265 101320
15 0.16 346.4237 0.225 101320
16 0.1 347.8235
Kaplan, Z. D. 101320
0.135
S. I.; Monakhova, Zh.
17 Obshch. 349.9233 0 101320
0 Khim., 1937, 7, 2499-2512
Equilibrium in solutions: IV boiling point at
atmospheric pressure and composition of
vapor of binary mixtures consisting of
chlorides of methane and ethane
Acetic acid Dichloromethane - Butyric acid
1 Dichloromethane
2 n-Butyric acid

Vapor Liquid
Total
mole mole Temperat
pressure No.
fraction fraction ure (K)
(N/sqm)
DICHL-01 DICHL-01

1 101330 1 0 435.6224
0.9831 101330 2 0.051 423.1744
0.9514 101330 3 0.1578 394.77
0.931 101330 4 0.313 354.7486
0.8836 101330 5 0.4655 334.5141
0.7698 101330 6 0.6207 324.1967
0.4927 101330 7 0.7586 318.9583
0.1329 101330 8 Sadovnikova,
0.8974 315.1495
L. V.;
0 101330 9 Belobokova,
1 312.6902
N. V.;
Aleksandrova, M. N.
ikova, L. V.; Belobokova, N. V.; Sb. Nauch. Tr.,
androva, M. N. Sb. Nauch. Tr., Ivanov. Energ. Inst.,
v. Energ. Inst., 1974, 14, 221 1974, 14, 221

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