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Mole Mole
Excess
fraction Temperat Pressure fraction Temperat
No. enthalpy No.
ETHAN- ure (K) (N/sqm) ETHAN- ure (K)
(J/kmol)
01 01
101300 99860
101300 186270
101300 244020
101300 308250
101300 336550
101300 352950
101300 350730
101300 302900
101300 239780
101300 156210
101300 80960
101300 44620
101300 23020
101300 10840
ies of (an alkanol + a
ylic acid) at 298.15 K
ured with a Picker
calorimeter
Methanol - dipropylamine Methanol - butylamine
Liquid Vapor
Mole
mole mole Total Excess
Temperat fraction Temperat Pressure
fraction fraction pressure No. enthalpy
ure (K) METHAN ure (K) (N/sqm)
METHA- METHA- (N/sqm) (J/kmol)
OL
01 01
Mole Mole
Excess
fraction Temperat Pressure fraction Temperat
No. enthalpy No.
METHA- ure (K) (N/sqm) METHA- ure (K)
(J/kmol)
01 01
Mole
Excess Excess
Pressure fraction Temperat Pressure
enthalpy No. enthalpy No.
(N/sqm) METHA- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01
7
8
9
10
11
12
13
14
15
16
17
18
19
1
2
3
4
5
6
7
8
9
10
11
12
13
14
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
1
2
3
4
5
6
7
8
9
10
11
12
Methanol - n,n-dimethylformamide Ethanol - n,n-dimethylformamide
Mole Mole
Excess Excess
fraction Temperat Pressure fraction Temperat Pressure
enthalpy No. enthalpy
METHA- ure (K) (N/sqm) ETHAN- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01 01
Mole
Excess Excess
Pressure fraction Temperat Pressure
enthalpy No. enthalpy No.
(N/sqm) METHA- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01
Mole
Excess Mole
fraction Temperat Pressure Temperat
No. enthalpy No. fraction
ETHAN- ure (K) (N/sqm) ure (K)
(J/kmol) PROP
01
Mole
Excess Excess
Pressure fraction Temperat Pressure
enthalpy No. enthalpy No.
(N/sqm) METHA- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01
Mole Mole
Excess Excess
fraction Temperat Pressure fraction Temperat Pressure
enthalpy No. enthalpy
METHA- ure (K) (N/sqm) ETHAN- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01 01
Mole
Excess Mole
fraction Temperat Pressure Temperat
No. enthalpy No. fraction
ETHAN- ure (K) (N/sqm) ure (K)
(J/kmol) 1-PRO-01
01
Mole Mole
Excess
fraction Temperat Pressure fraction Temperat
No. enthalpy No.
METHA- ure (K) (N/sqm) METHA- ure (K)
(J/kmol)
01 01
Mole
Excess Excess
Pressure fraction Temperat Pressure
enthalpy No. enthalpy No.
(N/sqm) METHA- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01
Mole Mole
Excess Excess
fraction Temperat Pressure fraction Temperat Pressure
enthalpy No. enthalpy
METHA- ure (K) (N/sqm) METHA- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01 01
Mole Mole
Excess
fraction Temperat Pressure fraction Temperat
No. enthalpy No.
ETHAN- ure (K) (N/sqm) ETHAN- ure (K)
(J/kmol)
01 01
Mole
Excess Excess
Pressure fraction Temperat Pressure
enthalpy No. enthalpy No.
(N/sqm) ETHAN- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01
Mole Mole
Excess Excess
fraction Temperat Pressure fraction Temperat Pressure
enthalpy No. enthalpy
ETHAN- ure (K) (N/sqm) ETHAN- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01 01
Mole Mole
Excess
fraction Temperat Pressure fraction Temperat
No. enthalpy No.
ETHAN- ure (K) (N/sqm) ETHAN- ure (K)
(J/kmol)
01 01
101325 1217600
101325 1133200
101325 1030700
101325 921000
101325 793400
101325 660700
101325 516400
101325 380600
101325 260300
101325 126100
101000 0
101000 441400
101000 772900
101000 1033700
101000 1210500
101000 1306100
101000 1311700
101000 1184000
101000 936100
101000 566900
101000 0
Mole Mole
Excess Excess
fraction Temperat Pressure fraction Temperat Pressure
enthalpy No. enthalpy
METHA- ure (K) (N/sqm) METHA- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01 01
Mole Mole
Excess
fraction Temperat Pressure fraction Temperat
No. enthalpy No.
METHA- ure (K) (N/sqm) METHA- ure (K)
(J/kmol)
01 01
Mole
Excess Excess
Pressure fraction Temperat Pressure
enthalpy No. enthalpy No.
(N/sqm) METHA- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01
Washburn, E. R.; Lightbody, A. J. Phys. Chem., 1930, 34, 2701 The changes in volume and temperature that accompany the
Brown, I.; Fock, W. Aust. J. Chem., 1955, 8, 361 Heats of mixing of alcohol solutions
Schnaible, H. W.; Van Ness, H. C.; Smith, J. M. AIChE J., 1957, 3, 147-52 Heats of mixing of liquids
Williamson, A. G.; Scott, R. L. J. Phys. Chem., 1960, 64, 440 Heats of mixing of nonelectrolyte solutions: I ethanol + benzene
Brown, I.; Fock, W. Aust. J. Chem., 1961, 14, 387 Heats of mixing IV solutions of n-alcohols with benzene at 25, 35, and 45
Goates, J. R.; Snow, R. L.; James, M. R. J. Phys. Chem., 1961, 65, 335 Application of quasi-lattice theory to heats of mixing in
Mrazek, R. V.; Van Ness, H. C. AIChE J., 1961, 7, 190-5 Heats of mixing: alcohol - aromatic binary systems at 25, 35 and 45 c
Jones, H. K. D.; Lu, B. C.-Y. J. Chem. Eng. Data, 1966, 11, 488-492 Heats of Mixing of Liquids ifor the System Ethanol-Benzen
Stokes, R. H.; Burfitt, C. J. Chem. Thermodyn., 1973, 5, 623-31 Enthalpies of dilution and transfer of ethanol in non-polar so
Yan, W.; Lin, R.; Yen, W. Thermochim. Acta, 1990, 169, 171-84 Excess enthalpies of seven binary liquid systems
Lien, P.-J.; Lin, H. M.; Lee, M. J. Fluid Phase Equilib., 2004, 215, 187-193 Excess molar enthalpies for binary mixtures of etha
Missopolinou, D.; Tsivintzelis, I.; Panayiotou, C. Fluid Phase Equilib., 2006, 245, 89-101 Excess enthalpies of binary mixture
Ethanol - p-Xylene Ethanol - o-Xylene
Liquid Vapor
Total Mole
mole Temperat mole Temperat
No. pressure No. fraction
fraction ure (K) fraction ure (K)
(N/sqm) ETHANOL
ETHANOL ETHANOL
7 0.4007 298.2
8 0.3565 298.2
9 0.3046 298.2
10 0.2212 298.2
11 0.1488 298.2
12 0.1148 298.2
F. E. Z.; Mercer-Chalmers, J. J. Ch
Thermodyn., 1990, 22, 765-70 Ex
enthalpies of (a xylene + an alkano
298.2 K
rature that accompany the mixing of organic liquids I
Mole
Excess Excess
Pressure fraction Temperat Pressure
enthalpy No. enthalpy No.
(N/sqm) METHA- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01
Mole
Excess Mole Excess
fraction Temperat Pressure Temperat Pressure
enthalpy No. fraction enthalpy
METHA- ure (K) (N/sqm) ure (K) (N/sqm)
(J/kmol) ETHANOL (J/kmol)
01
Mole Mole
Excess Excess
fraction Temperat Pressure fraction Temperat Pressure
enthalpy No. enthalpy
METHA- ure (K) (N/sqm) METHA- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01 01
Mole Mole
Excess
fraction Temperat Pressure fraction Temperat
No. enthalpy No.
METHA- ure (K) (N/sqm) ETHAN- ure (K)
(J/kmol)
01 01
Mole
Excess Excess
Pressure fraction Temperat Pressure
enthalpy No. enthalpy No.
(N/sqm) ETHAN- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01
Mole Mole
Excess Excess
fraction Temperat Pressure fraction Temperat Pressure
enthalpy No. enthalpy
ETHAN- ure (K) (N/sqm) METHA- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01 01
7 0.4596 298.15
8 0.4652 298.15
9 0.4795 298.15
10 0.486 298.15
11 0.492 298.15
12 0.5586 298.15
13 0.5796 298.15
14 0.7979 298.15
15 0.8403 298.15
16 0.9368 298.15
17 0.9851 298.15
Excess functions at T = 298.15 K
(butanenitrile + methanol, + pentan
+ heptan-1-ol, + nonan-1-ol, or + de
ol)
anol - Butyronitrile Ethanol - Acetonitrile Ethanol -
Mole
Excess Excess
Pressure fraction Temperat Pressure
enthalpy No. enthalpy No.
(N/sqm) ETHAN- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01
Mole Mole
Excess
fraction Temperat Pressure fraction Temperat
No. enthalpy No.
METHA- ure (K) (N/sqm) METHA- ure (K)
(J/kmol)
01 01
Mole
Excess Excess
Pressure fraction Temperat Pressure
enthalpy No. enthalpy No.
(N/sqm) METHA- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01
Mole Mole
Excess Excess
fraction Temperat Pressure fraction Temperat Pressure
enthalpy No. enthalpy
METHA- ure (K) (N/sqm) ETHAN- ure (K) (N/sqm)
(J/kmol) (J/kmol)
01 01
Mole Mole
Excess
fraction Temperat Pressure fraction Temperat
No. enthalpy No.
ETHAN- ure (K) (N/sqm) ETHAN- ure (K)
(J/kmol)
01 01
Liquid Vapor
Excess Total
Pressure mole Temperat mole
enthalpy No. pressure No.
(N/sqm) fraction ure (K) fraction
(J/kmol) (N/sqm)
ETHANOL ETHANOL
101000 7000 1
101000 21800 2
101000 36400 3
101000 45300 4
101000 46300 5
101000 47700 6
101000 48900 7
101000 48700 8
101000 49300 9
101000 48400 10
101000 47500 1
101000 46200 2
101000 43000 3
101000 34700 4
101000 24200 5
101000 14100 6
E.; Pflug, H. D.; Dacre, B.; Benson, 7
an. J. Chem., 1967, 45, 2665-74
excess enthalpies of binary n- 8
alcohol systems at 25 C 9
10
11
12
13
14
Butylamine - Hexane Butylamine - p-Xylene
nzene-Cyclohexane-n-Hexane
panoate + hexane + benzene at 298.15 and 308.15 K
Bissell, T. G.; Okafor, G. E.; Williamson, A. G. J. Chem. Thermodyn., 1971, 3, 393 Enthalpies and volumes of mixing of alkanes with carb
Jain, D. V. S.; Yadav, O. P.; Gill, S. S. Indian J. Chem., 1971, 9, 339-41 Thermodynamics of alkane solutions: II excess heats of mixing of
Berryman, J. M. ; Heric, E. L. Can. J. Chem., 1972, 50, 3799 Some mixtures of carbon tetrachloride with several n-alkanes: enthalpies a
Recko, W.; Sadowska, K. W. Bull. Acad. Pol. Sci.-Chim., 1972, 20, 73
Harsted, B. S.; Thomsen, E. S. J. Chem. Thermodyn., 1974, 6, 557-63
Grolier, J. -P. E.; Benson, G. C.; Picker, P. Int. DATA Ser., Sel. Data Mixtures, Ser. A, 1975, 3(1), 1
Parsa, J. B.; Yazdi, M. J. Chem. Eng. Data, 2008, 53(4), 995-997 Excess Enthalpies and Thermal Conductivity Coefficients for Binary Mix
Heptane - tetrachloromethane heptane - Propionic acid
Bykov, V. T. Zh. Fiz. Khim., 1939, 13, 1013 Heats of mixing of liquids
Vilcu, R.; Stanciu, F. An. Univ. "C.I. Parhon" Bucuresti, Ser. Stiint. Nat., 1963, 12, 87 Heats of Mixing in Binary Sys
Bissell, T. G.; Okafor, G. E.; Williamson, A. G. J. Chem. Thermodyn., 1971, 3, 393 Enthalpies and volumes of mixin
Jain, D. V. S.; Yadav, O. P.; Gill, S. S. Indian J. Chem., 1971, 9, 339-41 Thermodynamics of alkane solutions: II exce
Kehiaian, H. V. J. Chim. Phys. Phys.-Chim. Biol., 1971, 68, 935-40 Analysis of the enthalpy of mixing of normal-ch
Harsted, B. S.; Thomsen, E. S. J. Chem. Thermodyn., 1974, 6, 557-63
Grolier, J.-P. E.; Inglese, A. Can. J. Chem., 1976, 54, 1952 Enthalpies of mixing of carbon tetrachloride with hydro
Inglese, A.; Grolier, J.-P. E. Thermochim. Acta, 1977, 18, 257-64 Measurement of heats of a mixture of two liquid
Parsa, J. B.; Yazdi, M. J. Chem. Eng. Data, 2008, 53(4), 995-997 Excess Enthalpies and Thermal Conductivity Coeffi
mixing of alkanes with carbon tetrachloride, chloroform, and methylene chloride at 25.deg.
excess heats of mixing of n-alkanes in carbon tetrachloride
ral n-alkanes: enthalpies and energies of mixing
Coefficients for Binary Mixtures of Carbon Tetrachloride and Four Alkanes (C5 to C8) at a Temperature of 298.15 K
Octane - Acetic acid Octane - Propionic acid
Liquid Vapor
Total Mole
mole Temperat mole Temperat
No. pressure No. fraction
fraction ure (K) fraction ure (K)
(N/sqm) N-OCT-01
OCT OCT
1 0.9166 313.15
2 0.8461 313.15
3 0.7856 313.15
4 0.7332 313.15
5 0.6469 313.15
6 0.5788 313.15
7 0.4781 313.15
8 0.4072 313.15
9 0.3141 313.15
10 0.2339 313.15
11 0.1863 313.15
12 0.1324 313.15
13 0.1027 313.15
14 Comelli,
0.0709F.; Francesconi,
313.15 R. J. Chem
Data, 1996, 41, 101-104 Excess M
Enthalpies and Excess Molar Volum
Propionic Acid + Octane, + Cyclohex
1,3,5-Trimethylbenzene, + Oxane,
1,4-Dioxane at 313.15 K
a, M.; Kazuma, K.; Nakagawa, S. J. Chem. Eng. Jpn., 1975, 8, 261-5 Heats of mixing for binary systems and data reduction based on a tr
nowska, B. Bull. Acad. Pol. Sci.-Chim., 1978, 26, 371 Excess enthalpies and heat capacities of diluted propionic acid solutions in n-hepta
. S. Thermochim. Acta, 1985, 91, 141 Excess enthalpies and excess volumes of some carboxilic acid mixtures with n-heptane.
A.; Grolier, J.-P. E. J. Chem. Thermodyn., 1999, 31, 1165-1174 Excess molar enthalpies of (an alkanoic acid + n-heptane, or cyclohexane
ats of Mixing in Binary Systems
lpies and volumes of mixing of alkanes with carbon tetrachloride, chloroform, and methylene chloride at 25.deg.
of alkane solutions: II excess heats of mixing of n-alkanes in carbon tetrachloride
lpy of mixing of normal-chain ethers with carbon tetrachloride at 25c in terms of molecular surface interactions in the zeroth approxim
n tetrachloride with hydrocarbons using the picker dynamic-flow microcalorimeter equipped with separators
s of a mixture of two liquids without programmation of the flow rates using at picker microcalorimeter
Thermal Conductivity Coefficients for Binary Mixtures of Carbon Tetrachloride and Four Alkanes (C5 to C8) at a Temperature of 298.15
ne - Propionic acid Octane - Butyric acid Octane - is
Liquid Vapor
Excess Total
Pressure mole Temperat mole
enthalpy No. pressure No.
(N/sqm) fraction ure (K) fraction
(J/kmol) (N/sqm)
OCT OCT
101320 150000
101320 272000
101320 358000
101320 435000
101320 528000
101320 579000
101320 612000
101320 612000
101320 545000
101320 460000
101320 390000
101320 299000
101320 237000
F.; Francesconi,101320 170000
R. J. Chem. Eng.
996, 41, 101-104 Excess Molar
es and Excess Molar Volumes of
Acid + Octane, + Cyclohexane, +
imethylbenzene, + Oxane, or +
1,4-Dioxane at 313.15 K
ta reduction based on a triplet model of guggenheim.
ic acid solutions in n-heptane.
with n-heptane.
n-heptane, or cyclohexane, or benzene) at T=298.15K
ons in the zeroth approximation
a Temperature of 298.15 K
Octane - isoButyric acid Hexane - Methyl formate
Liquid Vapor
Total Mole Excess
mole Temperat mole Temperat Pressure
pressure No. fraction enthalpy
fraction ure (K) fraction ure (K) (N/sqm)
(N/sqm) N-HEX-01 (J/kmol)
OCT OCT
Nagata, I.; Nagashima, M.; Kazuma, K.; Nakagawa, S. J. Chem. Eng. Jpn., 1975, 8, 261-5 He
Ortega, J.; Legido, J. L.; Fernandez, J.; Lopez, M.; Pias, L.; Paz Andrade, M. I. Fluid Phase Eq
Ortega, J.; Espiau, F.; Dieppa, R. Fluid Phase Equilib., 2004, 215, 175-186 Measurement an
Ortega, J.; Sabater, G.; de la Nuez, I.; Quintana, J. J. J. Chem. Eng. Data, 2007, 52(1), 215-22
e - propyl formate Hexane - Butyl formate Hexane -
ng. Jpn., 1975, 8, 261-5 Heats of mixing for binary systems and data reduction based on a triplet model of guggenheim.
drade, M. I. Fluid Phase Equilib., 1990, 56, 219-34 Analysis of excess enthalpies of ethyl formate + n-alkane or 1-alkanol with two group
175-186 Measurement and correlation of isobaric vapour?liquid equilibrium data and excess properties of ethyl methanoate with alka
. Data, 2007, 52(1), 215-225 Isobaric Vapor-Liquid Equilibrium Data and Excess Properties of Binary Systems Comprised of Alkyl Metha
Hexane - diethyl ether Hexane - tetrahydrofuran
Liquid Vapor
Total Mole Excess
mole Temperat mole Temperat Pressure
pressure No. fraction enthalpy
fraction ure (K) fraction ure (K) (N/sqm)
(N/sqm) HEXANE (J/kmol)
HEX-01 HEX-01
Chem. Soc. Jpn., 1964, 37, 1776-80 Heats of mixing for binary mixtures the energy of hydrogen bonding between alcohol and ketone
esan, T. E.; Laddha, G. S. Indian Chem. Manuf., 1973, 11(2), 23-8 Enthalpy-composition diagram for the acetone + n-hexane system.
W. E.; Tucker, S. A. Thermochim. Acta, 1990, 162, 291
Heptane - 2-butanone Benzene - Toluene
Baud, E. Bull. Soc. Chim. Fr., 1915, 17, 329-45 Thermodynamic Analysis of Binary Mixtures
Trew, V. C. G.; Spencer, J. F. Trans. Faraday Soc., 1936, 32, 701 Magnetic susceptibility and other properties of binary mixtures of orga
Canning, J.; Cheesman, G. H. J. Chem. Soc., 1955, 1230 Heats of mixing of liquids
Cheesman, G. H.; Ladner, W. R. Proc. R. Soc. London, Ser. A, 1955, 229, 387 The variation of the heat of mixing with temperature
Mathieson, A. R.; Thynne, J. C. J. J. Chem. Soc., 1956, 3708 Thermodynamics of Hydrocarbon Mixtures. II. The Heats of Mixing of the B
Paz Andrade, M. I. Acta Cient. Compostelana, 1964, 1, 117
Rastogi, R. P.; Nath, J.; Misra, J. J. Phys. Chem., 1967, 71, 1277 Thermodynamics of Weak Interactions in Liquid Mixtures I. Mixtures o
Murakami, S.; Lam, V. T.; Benson, G. C. J. Chem. Thermodyn., 1969, 1, 397-407 The thermodynamic properties of binary aromatic syst
Sturtevant, J. M.; Lyons, P. A. J. Chem. Thermodyn., 1969, 1, 201-9 Application of flow calorimetry to the determination of the enthal
Diaz Pena, M.; Menduina, C. An. Quim., 1973, 69, 857 Semicontinuous calorimeter for measuring heats of mixing
Hsu, K.-Y.; Clever, H. L. J. Chem. Thermodyn., 1975, 7, 435-442 The Excess Enthalpies of the 15 Binary Mixtures Formed from Cyclohe
Sharma, S. C.; Lakhanpal, M. L.; Rampaul, M. L. Indian J. Chem., Sect. A: Inorg., Bio-inorg., Phys., Theor. Anal. Chem., 1981, 20, 770-2
Diez, D.; Ruiz, B.; Royo, R. M.; Gutierrez Losa, C. J. Chem. Thermodyn., 1985, 17, 371-7
Toluene - Ethylbenzene Benzene - n,n-dimethylformamide
Baud, E. Bull. Soc. Chim. Fr., 1915, 17, 329-45 Thermodynamic Analy
Hirobe, H. J. Faculty Sci. Imp. Univ. Tokyo, 1926, 1, 155-222 Thermoc
Kireev, V. A.; Bykov, V. T.; Khodorchenko, V. V. Zh. Fiz. Khim., 1937, 1
Vold, R. D. J. Am. Chem. Soc., 1937, 59, 1515 A calorimetric test of th
Boissonnas, C. G.; Cruchaud, M. Helv. Chim. Acta, 1944, 27, 994 Influ
Schulze, W. Z. Phys. Chem. (Leipzig), 1951, 197, 105-15 Binary liquid
Scatchard, G.; Ticknor, L. B.; Goates, J. R.; McCartney, E. R. J. Am. Ch
Andrade, M. I. P.; Casanova, J.; Ocon, J. An. R. Soc. Esp. Fis. Quim., 19
Toluene - Chloroform Toluene - tetrachloromethane
achloride-Benzene
lcohol +toluene systems
ne - Propionic acid Toluene - Acetic acid Benzene - M
Liquid Vapor
Total Mole
mole Temperat mole Temperat
No. pressure No. fraction
fraction ure (K) fraction ure (K)
(N/sqm) BENZENE
BENZENE BENZENE
1 0.8731 308.15
2 0.7477 308.15
3 0.5971 308.15
4 0.5425 308.15
5 0.5042 308.15
6 0.4381 308.15
7 0.3401 308.15
8 0.2721 308.15
9 0.2286 308.15
10 0.1286 308.15
Liquid Vapor
Excess Total
Pressure mole Temperat mole
enthalpy No. pressure No.
(N/sqm) fraction ure (K) fraction
(J/kmol) (N/sqm)
TOL TOL
101300 -7500 1
101300 -14000 2
101300 -20900 3
101300 -22700 4
101300 -24500 5
101300 -26400 6
101300 -27400 7
101300 -26000 Chart8 Title
101300 -24500 180000 9
101300 -20400 160000 10
11
S.; Deshwal, B. R.; Chadha, R.; 140000
h, K. C.; Kim, H.; Park, J.-W. Fluid 12
120000
se Equilib., 2005, 235, 42-49 13
100000 14
80000 15
60000 16
40000
17
18
20000
1
0
0 0.1 0.2 0.3 0.4 2 0.5 0.6 0
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
Toluene - Ethyl Acetate Benzene - Diisopropyl ether
Moebius, H. H. J. Prakt. C
Brown, I.; Fock, W. Aust.
Campbell, A. N.; Kartzma
Mattingley, B. I.; Fenby, D
Akamatsu, Y.; Ogawa, H.;
Marongiu, B.; Dernini, S.;
nzene - Acetone Benzene - 2-Butanone Toluene
of mixing, dipole moments, densities, and boiling points of the system acetone-chloroform-benzene.
zene and of acetone + benzene
Excess Volumes and Molar Isentropic Compressibilities of Mixtures of 2-Propanone with Heptane, Benzene and Trichloromethane a
olecular interactions in mixtures of substances containing carbonyl groups
Benzene - Acetonitrile Toluene - Acetonitrile
Brown, I.; Fock, W. Aust. J. Chem., 1956, 9, 180-183 Heats of mixing II. Acetonitrile and nit
Anderson, R.; Prausnitz, J. M. Rev. Sci. Instrum., 1961, 32, 1224 High precision, semimicro,
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ene - Acetonitrile Diethylamine - Dipropylamine Diethylamine -
Liquid Vapor
Excess Total
Pressure mole Temperat mole
enthalpy No. pressure No.
(N/sqm) fraction ure (K) fraction
(J/kmol) (N/sqm)
DIETH-01 DIETH-01
101325 422166
101325 495386
101325 507519
101325 501243
101325 487018
101325 456893
101325 420492
101325 383673
101000 53470
101000 216400
101000 338100
101000 414800
101000 502920
101000 493080
101000 452580
101000 371000
101000 211400
100000 151461
100000 283675
100000 394133
100000 447688
100000 490365
100000 512540
100000 521326
100000 531368
100000 535552
100000 543083
100000 541828
100000 527184
100000 451872
100000 303340
100000 62342
100000 285349
100000 398317
100000 484507
100000 527184
100000 547267
100000 568187
100000 577392
100000 590781
100000 598730
100000 597475
100000 588270
100000 569024
100000 468608
100000 282838
101325 306400
101325 393300
101325 403100
101325 487800
101325 586000
101325 569500
101325 347300
101325 257900
101000 83200
101000 162300
101000 156200
101000 217900
101000 218700
101000 268700
101000 272300
101000 394100
101000 432600
101000 449900
101000 508100
101000 537600
101000 522300
101000 457700
101000 382000
101000 274800
101000 145600
101000 143500
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xing II. Acetonitrile and nitromethane systems
High precision, semimicro, hydrostatic calorimeter for heats of mixing of liquids
ermodynamic Excess Property Measurements for Acetonitrile-Benzene-n- Heptane System at 45 C
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Data, 2010, 55(12), 5406-5412 Calorimetric Study of Nitrile Group-Solvent Interactions and Comparison with Dispersive Quasi-Chemic
Diethylamine - Diisopropylamine Diethylamine - Triethylamine
Liquid Vapor
Total Mole Excess
mole Temperat mole Temperat Pressure
pressure No. fraction enthalpy
fraction ure (K) fraction ure (K) (N/sqm)
(N/sqm) DIETH-01 (J/kmol)
DIETH-01 DIETH-01
1
2
3
4
5
6
7
8
9
dimethylacetamide - acetic acid dimethylformamide - Methylformate
Liquid Vapor
Mole Excess Total
Temperat Pressure mole Temperat mole
fraction enthalpy No. pressure
ure (K) (N/sqm) fraction ure (K) fraction
N:N-D-02 (J/kmol) (N/sqm)
N:N-D-01 N:N-D-01
Liquid
Mole Excess
Temperat Pressure mole Temperat
No. fraction enthalpy No.
ure (K) (N/sqm) fraction ure (K)
N:N-D-01 (J/kmol)
N:N-D-01
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
dimethylformamide - 2-propanone dimethylformamide - 2-butanone
Liquid Vapor
Total Mole
mole Temperat mole Temperat
No. pressure No. fraction
fraction ure (K) fraction ure (K)
(N/sqm) CH2CL2
DMA DMA
1 0.784 297.8361
2 0.76 297.8361
3 0.588 297.8361
4 0.524 297.8361
5 0.524 297.8361
6 0.479 297.8361
7 0.475 297.8361
8 0.474 297.8361
9 0.445 297.8361
10 0.444 297.8361
11 0.444 297.8361
12 0.332 297.8361
13 0.301 297.8361
Liquid Vapor
Mole Excess Total
Temperat Pressure mole Temperat mole
fraction enthalpy No. pressure
ure (K) (N/sqm) fraction ure (K) fraction
CHCL3 (J/kmol) (N/sqm)
DICHL-01 DICHL-01
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Dichloromethane - Butyric acid
Liquid
mole Temperat
No.
fraction ure (K)
DICHL-01
al and partial heats of mixing of normal liquids
ermination of heats of mixing,
stem chloroform + carbon tetrachloride and a thermo
Ethanol - Acetone Ethanol - Acetic acid
1 n-Ethanol 1 n-Ethanol
2 n-Acetone 2 Acetic acid
Liquid Vapor Liquid
mole mole Total mole
Temperat Temperat
No. fraction fraction pressure No. fraction
ure (K) ure (K)
ETHAN- ETHAN- (N/sqm) ETHAN-
01 01 01
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1 n-Ethanol 1 Methanol
2 Dipropylamine 2 Dipropylamine
Vapor Liquid Vapor
mole Total mole mole Total
Temperat
fraction pressure No. fraction fraction pressure No.
ure (K)
ETHAN- (N/sqm) ETHAN- ETHAN- (N/sqm)
01 01 01
iquid equilibria for mixtures of acetone, ethanol, and 2,2,4-trimethylpentane at 101.3 kPa
Methanol - dipropylamine Methanol - butylamine
1 Methanol
Dipropylamine 2 n-Butylamine
Liquid Vapor Liquid Vapor
mole mole Total mole mole Total
Temperat Temperat
fraction fraction pressure No. fraction fraction pressure
ure (K) ure (K)
METHA- METHA- (N/sqm) METHA- METHA- (N/sqm)
01 01 01 01
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Ebulliometer for Six Binary Systems Made Containing Alcohols (Methanol with
of Alcohol and Amine Aliphatic Amines)
Methanol - tert-butylamine Methanol - diethylamine
1 Methanol 1 Methanol
2 tert-butylamine 2 Diethylamine
Liquid Vapor Liquid
mole mole Total mole
Temperat Temperat
No. fraction fraction pressure No. fraction
ure (K) ure (K)
METHAN METHAN (N/sqm) METHAN
OL OL OL
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Methanol - p-Xylene Methanol - m-Xylene
1 Methanol 1 Methanol
2 p-Xylene 2 m-Xylene
Liquid Vapor Liquid
mole mole Total mole
Temperat Temperat
No. fraction fraction pressure No. fraction
ure (K) ure (K)
METHAN METHAN (N/sqm) METHAN
OL OL OL
f (methanol + methylcyclopentane)
Salts on the Vapor-Liquid Equilibrium Relationships of Three Miscible Binary Systems at the Pressure of 101.3 kPa
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e Methanol - o-Xylene Ethanol - Benzene
1 Methanol 1 n-Ethanol
2 o-Xylene 2 n-Benzene
Vapor Liquid Vapor
mole Total mole mole Total
Temperat
fraction pressure No. fraction fraction pressure No.
ure (K)
METHAN (N/sqm) METHAN METHAN (N/sqm)
OL OL OL
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Methanol - 2-Pentanone Ethanol - Acetone
1 n-Methanol 1 n-Ethanol
2 2-Pentanone 2 n-Acetone
Liquid Vapor
Liquid
mole mole Total
Temperat mole Temperat
No. fraction fraction pressure No.
ure (K) fraction ure (K)
METHAN METHAN (N/sqm)
ETHANOL
OL OL
od for measuring ternary vapor-liquid equilibria dew, bubble and condensation point method
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1 n-Ethanol 1 n-Ethanol
2 Acetonitrile 2 Propionitrile
Vapor
Liquid Vapor
mole Total Total
mole Temperat mole
fraction pressure No. pressure No.
fraction ure (K) fraction
METHAN (N/sqm) (N/sqm)
ETHANOL ETHANOL
OL
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Toluene - Ethylbenzene Benzene - n,n-dimethylformamide
1 n-Toluene 1 n-Benzene
2 Ethylbenzene 2 n,n-dimethylformamide
Vapor Liquid
Total
mole mole Temperat
pressure No.
fraction fraction ure (K)
(N/sqm)
DICHL-01 DICHL-01
1 101330 1 0 435.6224
0.9831 101330 2 0.051 423.1744
0.9514 101330 3 0.1578 394.77
0.931 101330 4 0.313 354.7486
0.8836 101330 5 0.4655 334.5141
0.7698 101330 6 0.6207 324.1967
0.4927 101330 7 0.7586 318.9583
0.1329 101330 8 Sadovnikova,
0.8974 315.1495
L. V.;
0 101330 9 Belobokova,
1 312.6902
N. V.;
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