Si n=0

−r A =k C 0A=k
−d C A
−r A = =k
dt
CA t
− ∫ d C A =∫ kdt
C A0 0

C A 0−C A =kt

C A 0 −C A
k=
t

Si n= 1
−r A =k C 1A
−d C A
−r A = =k C A
dt
CA
dCA t
−∫ = kdt
C A0
CA ∫0

C A0
ln ( )
CA
=kt

1 C A0
k = ln
t ( )
CA

Si n=2
−r A =k C 2A
−d C A 2
−r A = =k C A
dt
CA t
dCA
−∫ =∫ kdt
C A0 CA2 0

1 1
− =kt
CA C A0

1 1 1
k=
[
−
t C A C A0 ]
Si n=3
−r A =k C 3A
−d C A 3
−r A = =k C A
dt
CA t
dCA
−∫ =∫ kdt
C A0 CA3 0

1 1
− =kt
2C A 2C A2
2

1 1 1
k=
[ −
t 2C A2 2C A2 ]