Material Safety Data Sheet

Matex according to 1907/2006/EC (REACH),

1272/2008/EC (CLP), and GHS
Bangladesh Limited
Print date: 07/02/2017 Revision date: 07/02/2017
Matacid® AS Liquid
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifiers
Product name: Matacid® AS Liquid
Product Code:
Brand/Trademark: Matacid®

1.2 Relevant identified uses of the substance or mixture and uses advised against:
Identified uses: Industrial uses only

1.3 Details of the supplier of the Safety Data Sheet Manufacturer/Supplier:

Company: Matex Bangladesh Limited
Head Office: Rupayan Golden Age, 5th & 6th Floor,
99,Gulshan Avenue, Dhaka. Bangladesh.
Telephone: 880-2-9883358
Fax: 880-2-88010850
Factory: East Chandora, Shafipur, Kaliakoir,
Gazipur. Bangladesh.
Tel & Fax: 88-06822-51166, Cell: 88-017-11684530
E-mail address: researchdevelopment@matexbd.com
Web: www.matexbd.com

1.4 Emergency telephone number:

Emergency Phone: 88-06822-51166, 88-017-13425868

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture:
Classification according to Regulation (EC) No 1272/2008:
Flam Liq 3 Flammable liquids
Skin Corr./Irrit. 1B Skin corrosion/Irritation
H314, H226
For the full text of the H-Statements mentioned in this Section, see Section 16.

2.2 Label elements

Labelling according to Regulation (EC) No 1272/2008
Pictogram:

Signal word: Danger

Hazard statement(s):
H226 Falmmable liquid & vapour
H314 Causes serious skin burn & eye damage

Precautionary statement(s):
P273: Avoid release to the environment.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection.
P261: Avoid breathing vapours
P260: Do not breath mist or vapour
 Material Safety Data Sheet
Matex according to 1907/2006/EC (REACH),
1272/2008/EC (CLP), and GHS
Bangladesh Limited
P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/ physician.

2.3 Other hazards:

According to Regulation (EC) No 1272/2008 [CLP]
See section 12 - Results of PBT and vPvB assessment.
If applicable information is provided in this section on other hazards which do not result in
classification but which may contribute to the overall hazards of the substance or mixture.

SECTION 3: Composition/information on ingredients

3.1 Substances:
Hazardous ingredients according to Regulation (EC) No 1272/2008:
Not Applicable

3.2 Chemical characterization: Mixture

Hazardous ingredients according to Regulation (EC) No 1272/2008
Component Classification Concentration
Skin Corr./Irrit. 1B
Organic aliphatic acids
Eye Dam./Irrit. 1 15-20%
CAS No. 64-19-7
Flam Liq. 3
There are no aditional ingridients present which, within the current knowledge of supplier and in the
concentrations applicable , are classified as hazardous to health or environment and hence require
reporting to this section.

For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16

SECTION 4: First aid measures

4.1 Description of first aid measures
General information:
Take off immediately all contaminated clothing. Self-protection of the first aider
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration.
Consult a physician.
In case of skin contact
Wash with plenty of water. Consult a physician immediately.
In case of eye contact
In case of contact with eyes flush immediately with plenty of water for 10-15 min holding eyelids
apart and consult an opthalmologist. Protect Uninjured eye.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse
mouth with water. Consult a physician.

4.2 Most important symptoms and effects, both acute and delayed:
Causes irritation, all routes of exposure. May cause eye damage.

4.3 Indication of any immediate medical attention and special treatment needed:
No additional information available.
 Material Safety Data Sheet
Matex according to 1907/2006/EC (REACH),
1272/2008/EC (CLP), and GHS
Bangladesh Limited

SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing media:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Unsuitable extinguishing media:
No Data Available

5.2 Special hazards arising from the substance or mixture

No Data Available

5.3 Advice for firefighters

Protective equipment:
Use self-contained breathing apparatus to avoid exposure to smoke and vapor.
Wear self-contained respiratory protective device.
Wear fully protective suit.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures:
Wear respiratory protection. Avoid breathing vapours, mist or gas. Ensure adequate ventilation.
Evacuate personnel to safe areas.
For personal protection see section 8.

6.2 Environmental precautions:

Keep away from drains, surface and ground water.

6.3 Methods and material for containment and cleaning up:

Absorb with liquid-binding material (sand, diatomite, sawdust).
Clean the affected area carefully; suitable cleaners are: Warm water
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.

6.4 Reference to other sections:

See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information

SECTION 7: Handling and storage

7.1 Precautions for safe handling:
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
Ensure good ventilation/exhaustion at the workplace.
Do not to eat, drink and smoke in work areas;
Wash hands after use; and
Remove contaminated clothing and protective equipment before entering eating areas.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Segregate from bases, segregate form oxidising agent
7.3 Specific end use(s)
 Material Safety Data Sheet
Matex according to 1907/2006/EC (REACH),
1272/2008/EC (CLP), and GHS
Bangladesh Limited
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
Occupational Exposure limits:
No exposure limit value known
Recommended Monitoring procedures:
None assigned
Derived effect levels:
No DELs available
Predicted effect concentrations:
No PECs available
8.2 Exposure controls:
Respiratory protection:
Wear a NIOSH certified organic vapour/particulate respirator.

Hand protection:
Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact
(Recommended: Protective index 6, corresponding > 480 minutes of permeation time according
to EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) etc.
Eye protection:
Tightly fitting safety goggles and face shield .
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron,
protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or
EN ISO 13982 in case of dust).
General safety and hygiene measures
The statements on personal protective equipment in the instructions for use apply when handling
crop-protection agents in final-consumer packing. Wearing of closed work clothing is recommended.
Store work clothing separately. Keep away from food, drink and animal feeding stuffs.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
a) Appearance Colorless liquid
b) Odour Pungent
c) Odour threshold No data available
d) pH (1.0% Soln. ) 2.5
e) Melting point / freezing point -13°C
f) Initial boiling point and boiling range
g) Flash point No data available
h) Evaporation rate No data available
i) Flammability (solid, gas) Not applicable.
j) Upper/lower flammability or explosive limits Not applicable.
k) Vapour pressure Not volatile
l) Vapour density Not applicable.
m) Relative density 1.135
n) Solubility(ies) Soluble in water
o) Partition coefficient: n-octanol/water No data available
p) Auto-ignition temperature No data available
 Material Safety Data Sheet
Matex according to 1907/2006/EC (REACH),
1272/2008/EC (CLP), and GHS
Bangladesh Limited
q) Decomposition temperature No data available
r) Viscosity Not applicable.
s) Explosive properties No data available
t) Oxidising properties No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity:
No applicable information available .
10.2 Chemical stability:
No applicable information available
10.3 Possibility of hazardous reactions:
product is chemically stable
10.4 Conditions to avoid:
Keep away from heat, sparks, open flame and other ignition sources.
10.5 Incompatible materials:
oxidizers & bases
10.6 Hazardous decomposition products:
carbon dioxide, carbon monoxide, nitrous oxides

SECTION 11: Toxicological information

11.1 Information on toxicological effects:
(a) acute toxicity; Oral/LD50/rat : > 2030 mg/kg
(b) skin corrosion/irritation; corrosive
(c) serious eye damage/irritation; it may damage eye
(d) respiratory or skin sensitisation; No data available
(e) germ cell mutagenicity; No data available
(f) carcinogenicity; NTP carcinogen not known and not anticipated
(g) reproductive toxicity; No data available
(h) STOT-single exposure; No data available
(i) STOT-repeated exposure; No data available
(j) aspiration hazard. No data available
Additional Information

SECTION 12: Ecological information

12.1 Toxicity:
Toxicity to Fish:
LC50 (96h) 46-100 mg/l Leuciscus indus (Static). Slightly toxic.
Toxicity to aquatic invertibrates:
EC50 (48h) 34.2 mg/l, Daphinia manga (Static). Slightly toxic.
IC 50 (3 hours) >50000 mg/l , Bacteria
12.2 Persistence and degradability:
74% biodegradable as per OECD 301 E; 84/449/EEC, C.3 , 98% biodegradable after 2 d as per DIN EN ISO 9888
12.3 Bioaccumulative potential:
Not worth-mentioning accumulating in organisms.
12.4 Mobility in soil:
No additional information available.
12.5 Results of PBT and vPvB assessment:
 Material Safety Data Sheet
Matex according to 1907/2006/EC (REACH),
1272/2008/EC (CLP), and GHS
Bangladesh Limited
Not applicable
12.6 Other adverse effects:
No additional information available.

SECTION 13: Disposal considerations

13.1 Waste treatment methods:
Product
Methods of disposal
Hazardous Waste
:Dispose of in accordance with national, state and local regulations.
It is the waste generators responsibility to determine if a particular
waste is hazardous under RCRA.
: The classification of the product may meet the criteria .

Empty Containers : Empty container contains product residue and can be dangeorous.
Do not pressurize, cut, weld, braze, solder, drill, grind or expose
such container to heat, flame, spark and any other source of ignition.
They may explode and cause injury or death. Empty drums should be
completely drained, tripple rinsed, properly bunged and promptly
returned to a drum reconditioner or properly disposed.

SECTION 14: Transport information

14.1 UN-Number:
Not Available
14.2 UN proper shipping name:
Not Available
14.3 Transport hazard class(es):
Not classified as transport hazard
14.4 Packing group:
Not Available
14.5 Environmental hazards:
See corresponding entries for “Environmental hazards” for the respecOve regulaOons in above.
the tables
14.6 Special precautions for user:
See corresponding entries for “Special precautions for user” for the respective regulations in
the tables above.
14.7 Transport in bulk according to Annex II of Marpol¹¹² and the IBC Code:
Regulation: Not evaluated
Shipment approved: Not evaluated
Pollution name: Not evaluated
Pollution category: Not evaluated
Ship Type: Not evaluated

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Restrictions relating to the product or contained substances pursuant to Annex XVII to EC
Regulation 1907/2006: None.
Substances in Candidate List (Art. 59 REACH):None.
Substances subject to authorisarion (Annex XIV REACH):None.
15.2 Chemical safety assessment:
No Chemical Safety Assessment has been carried out for this product.
 Material Safety Data Sheet
Matex according to 1907/2006/EC (REACH),
1272/2008/EC (CLP), and GHS
Bangladesh Limited

SECTION 16: Other information

This information is based on our present knowledge. However, this shall not constitute a
guarantee for any specific product features and shall not establish a legally valid
contractual relationship.
Relevant phrases:
H226 Falmmable liquid & vapour
H314 Causes serious skin burn & eye damage

The above information is believed to be correct but does not purport to be all inclusive and shall be
used only as a guide. The information in this document is based on the present state of our knowledge
and is applicable to the product with regard to appropriate safety precautions. It does not represent
any guarantee of the properties of the product. Matex Bangladesh Limited shall not be held liable
for any damage resulting from handling or from contact with the above product.