David Keffer, Department of Chemical Engineering, University of Tennessee

Bridgman Tables
Convenient for Single-component Pressure Explicit Equations of State
and Constant Volume Heat Capacity

I. Volume

 ∂p 
1. (∂p)V = −(∂V )p =  
 ∂T  V

2. (∂T )V = −(∂V )T = 1

CV
3. (∂S )V = −(∂V )S =
T

4. (∂U)V = −(∂V )U = C V

 ∂p 
5. (∂H)V = −(∂V )H = C V + V  
 ∂T  V

6. (∂A )V = −(∂V )A = −S

 ∂p 
7. (∂G)V = −(∂V )G = −S + V  
 ∂T  V

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 David Keffer, Department of Chemical Engineering, University of Tennessee

II. Temperature

1. (∂V )T = −(∂T )V = −1

 ∂p 
2. (∂p)T = −(∂T)p = − 
 ∂V T

 ∂p 
3. (∂S )T = −(∂T )S = − 
 ∂T  V

 ∂p 
4. (∂U)T = −(∂T )U = p − T 
 ∂T  V

 ∂p   ∂p 
5. (∂H)T = −(∂T)H = −T  − V  
 ∂T  V  ∂V T

6. (∂A )T = −(∂T )A = p

 ∂p 
7. (∂G)T = −(∂T )G = − V  
 ∂V T

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 David Keffer, Department of Chemical Engineering, University of Tennessee

III. Pressure

 ∂p 
1. (∂V )p = −(∂p)V = − 
 ∂T  V

 ∂p 
2. (∂T )p = −(∂p)T =  
 ∂V T

2
CV  ∂p   ∂P 
3. (∂S)p = −(∂p)S =   − 
T  ∂V T  ∂T  V

2
 ∂p   ∂P   ∂p 
4. (∂U)p = −(∂p)U = C V   − T   + p 
 ∂V T  ∂T  V  ∂T  V

2
 ∂p   ∂P 
5. (∂H)p = −(∂p)H = C V   − T 
 ∂V T  ∂T  V

 ∂p   ∂p 
6. (∂A )p = −(∂p)A = p  − S 
 ∂T  V  ∂V  T

 ∂p 
7. (∂G)p = −(∂p)G = −S 
 ∂V T

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 David Keffer, Department of Chemical Engineering, University of Tennessee

IV. Entropy

2
C  ∂p   ∂P 
1. (∂p)S = −(∂S )p = − V   + 
T  ∂V T  ∂T  V

 ∂p 
2. (∂T )S = −(∂S )T =  
 ∂T  V

C
3. (∂V )S = −(∂S )V = − V
T

C
4. (∂U)S = −(∂S)U = p V
T

V   ∂p   ∂P  
2
5. (∂H)S = −(∂S)H = − C V   − T  
T   ∂V T  ∂T  V 


C  ∂p 
6. (∂A )S = −(∂S)A = p V − S 
T  ∂T  V

V   ∂p   ∂P  
2
 ∂p 
7. (∂G)S = −(∂S)G = − C V   − T   − S 
T   ∂V T  ∂T  V   ∂T  V


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 David Keffer, Department of Chemical Engineering, University of Tennessee

V. Internal Energy

2
 ∂p   ∂P   ∂p 
1. (∂p)U = −(∂U)p = −C V   + T   − p 
 ∂V T  ∂T  V  ∂T  V

 ∂p 
2. (∂T )U = −(∂U)T = −p + T 
 ∂T  V

3. (∂V )U = −(∂U)V = −C V

C
4. (∂S)U = −(∂U)S = −p V
T

 2
 ∂p    ∂p   ∂P 
5. (∂H)U = −(∂U)H = −p C V + V    − VC V   + VT 
  ∂T  V   ∂V  T  ∂T  V

 ∂p 
6. (∂A )U = −(∂U)A = p[C v + S] − ST 
 ∂T  V

2
 ∂p   ∂p   ∂P 
7. (∂G)U = −(∂U)G = pS − [pV + ST ]  − VC V   + VT 
 ∂T  V  ∂V T  ∂T  V

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 David Keffer, Department of Chemical Engineering, University of Tennessee

VI. Enthalpy

2
 ∂p   ∂P 
1. (∂p)H = −(∂H)p = −C V   + T 
 ∂V T  ∂T  V

 ∂p   ∂p 
2. (∂T )H = −(∂H)T = T  + V  
 ∂T  V  ∂V T

 ∂p 
3. (∂V )H = −(∂H)V = −C V − V  
 ∂T  V

V   ∂p   ∂P  
2
4. (∂S )H = −(∂H)S = CV   − T   
T   ∂V  T  ∂T  V 
 

 2
 ∂p    ∂p   ∂P 
5. (∂U)H = −(∂H)U = p CV + V    + VC V   − VT 
  ∂T  V   ∂V T  ∂T  V

 ∂p   ∂p 
6. (∂A )H = −(∂H)A = pC V + [pV − ST ]  − SV  
 ∂T  V  ∂V T

  ∂P 
2 
 T  
  ∂T  V   ∂p   ∂p 
7. (∂G)H = −(∂H)G = − V C V − + S   − ST 
 ∂P  ∂V T  ∂T  V
   
  ∂V  T 

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 David Keffer, Department of Chemical Engineering, University of Tennessee

VII. Helmholtz Free Energy

 ∂p   ∂p 
1. (∂p)A = −(∂A )p = −p  + S 
 ∂T  V  ∂V  T

2. (∂T )A = −(∂A )T = −p

3. (∂V )A = −(∂A )V = S

C  ∂p 
4. (∂S )A = −(∂A )S = −p V + S 
T  ∂T  V

 ∂p 
5. (∂U)A = −(∂A )U = −p[CV + S] + ST 
 ∂T  V

 ∂p   ∂p 
6. (∂H)A = −(∂A )H = −pC V + [ST − pV ]  + SV  
 ∂T  V  ∂V  T

  ∂p    ∂p 
7. (∂G)A = −(∂A )G = S p + V    − pV  
  ∂V T   ∂T  V

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 David Keffer, Department of Chemical Engineering, University of Tennessee

VIII. Gibbs Free Energy

 ∂p 
1. (∂p)G = −(∂G)p = S 
 ∂V  T

 ∂p 
2. (∂T )G = −(∂G)T = V  
 ∂V T

 ∂p 
3. (∂V )G = −(∂G)V = S − V  
 ∂T  V

V   ∂p   ∂P  
2
 ∂p 
4. (∂S )G = −(∂G)S = C V   − T    + S 
T   ∂V T  ∂T  V   ∂T  V


2
 ∂p   ∂p   ∂P 
5. (∂U)G = −(∂G)U = −pS + [pV + ST ]  + VC V   − VT 
 ∂T  V  ∂V T  ∂T  V

  ∂P 
2 
 T  
  ∂T  V  ∂p   ∂p 
6. (∂H)G = −(∂G)H = V C V − + S   + ST 
 ∂P  ∂V  T  ∂T  V
   
  ∂V  T 

  ∂p    ∂p 
7. (∂A )G = −(∂G)A = −S p + V    + pV  
  ∂V T   ∂T  V