CLASS TUTORIAL: CT 10 1) Fora system methanol (I)/methyl acetate (2), the following equations provide a reasonable correlation for the activity coefficients: Inf, = Ax? In Y= Ax? where A=2.771- 0.005237 where T is in Kelvins and the vapor pressures are in kPa, Assuming the validity of Modified Raoult’s law. Plot a graph of P vs xi,y1_ at constant temperature 60 °C. (Construct a table with a set of x1 data, calculated Prespieand y1) Pe Kite meee dr OE (10 marks) Ya = losaes~ 363609 aap xe) exp BRAS IHS La [a PP = 44: fa Catan] | Who = [rkG-_ 266298 fe t3is | pegs : aos SUE [ee ral 5 Pe = agar Ps (ieet | aes] 0420, 1431s) I 24TH | 2) Find T tattle and vapor composition yi of acetonitrile (1)/nitromethane (2) for a given pressure 65 kPa and x: = 0.62 (assume Raoult’s law) marks) Guess: for Thubble to gt X, 2062 fom Rel ak bubble pomt , sob IX) = KOE KP co Sn = YstsD- 3413-10 =f P7627 Pete Rls dyrgsts— 338190 given BeOS Ceatst) vane T e ae me a Tod se doare TH! pom Aatrne OP Ty = 34/80 pa 2627 J489D-lalt vt. 240099 k 52 3605S aa | cee TMM Pre Baess Th m roe Cree eae oe awe The 345K yt Poa pit eo = TH — te pe 2 3753 = OS= 34S? Me une FSB Xe = Oe THEpss foe BU Th = 350K | Xe Gut by mrfepaabm | aT x 350 | O42 Te? | Oba BES \ que Ya (or BJ’) es C14, x07. Po = (BRAT ee BS = YS tba ¢ OL2-O4F2 = Th-350 \ OFER-O'FID yc 350 Th > 347-32 KO THz We Odapan = vole wha ==