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    4 views7 pages

    Annonacin

    Uploaded by

    softpoison

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    of 7

    Data File E:\DATA\2017-05-22\17920.

    Peak RetTime Type Width Area Height Area


    # [min] [min] [mAU*s] [mAU] %
    ----|-------|----|-------|----------|----------|--------|
    13 12.702 MM R 0.3753 22.56622 1.00212 0.2832
    14 15.875 MM R 0.3988 16.81207 7.02626e-1 0.2110
    15 18.209 MM R 0.7513 26.63624 5.90923e-1 0.3343

    Totals : 7967.82438 505.04183

    =====================================================================
    *** End of Report ***

    Agilent LC-1260_2 5/22/2017 4:49:53 PM DY Page 2 of 2


    Print of window 80: MS Spectrum

    MS Spectrum
    *MSD1 SPC, time=0.649 of D:\DATA\05-22-2017\TEST 2017-05-22 13-20-17\54.D ES-API, Pos, Scan, Frag: 100, "Pos ES"
    Norm.

    597.4
    100 Max: 46083

    80

    60
    598.4

    40
    619.4

    20
    620.5
    621.5
    579.4

    0
    200 400 600 800 m/z
    Instrument 1 5/22/2017 1:46:56 PM Page 1 of 1
    1H NMR in CDCl3

    7.26
    7.19
    7.18
    5.07
    5.07
    5.06
    5.05
    3.87
    3.85
    3.84
    3.83
    3.82
    3.82
    3.81
    3.79
    3.77
    3.60
    3.60
    3.41
    3.40
    2.55
    2.54
    2.51
    2.43
    2.41
    2.39
    2.39
    2.38
    2.37
    2.36
    2.00
    1.99
    1.98
    1.97
    1.96
    1.71
    1.69
    1.68
    1.66
    1.64
    1.58
    1.55
    1.49
    1.47
    1.44
    1.43
    1.41
    1.40
    1.38
    1.37
    1.34
    Current Data Parameters
    NAME 2017-05-22
    EXPNO 78
    PROCNO 1

    F2 - Acquisition Parameters
    Date_ 20170522
    Time 17.03 h
    INSTRUM spect
    PROBHD Z116098_0293 (
    PULPROG zg30
    TD 65536
    SOLVENT CDCl3
    NS 8
    DS 0
    SWH 8802.817 Hz
    FIDRES 0.268641 Hz
    AQ 3.7224448 sec
    RG 161.57
    DW 56.800 usec
    DE 6.50 usec
    TE 298.0 K
    D1 1.00000000 sec
    TD0 1
    SFO1 400.1332010 MHz
    NUC1 1H
    P1 9.70 usec
    PLW1 16.00000000 W

    F2 - Processing parameters
    SI 65536
    SF 400.1300086 MHz
    WDW no
    SSB 0
    LB 0 Hz
    GB 0
    PC 1.00

    9 8 7 6 5 4 3 2 1 0 ppm
    1.04

    1.00

    3.19
    1.09
    2.18

    1.27
    3.64
    0.08
    2.20
    2.48

    3.52
    29.43
    19.15
    Data File D:\DATE\05-24-2017\2017-05-24 16-43-52.D

    Poroshell HPH-C18 (2.1*100mm,2.7um); F=0.3ml/min; T=30 degree;


    CH3CN/H2O=60/40
    =====================================================================
    Acq. Operator : LTT
    Sample Operator : LTT
    Acq. Instrument : 6120B Location : P1-B1
    Injection Date : 5/24/2017 4:44:44 PM Inj : 1
    Inj Volume : 2.000 µl
    Acq. Method : C:\CHEM32\1\METHODS\3.M
    Last changed : 5/24/2017 4:13:55 PM by LTT
    (modified after loading)
    Analysis Method : C:\CHEM32\1\METHODS\3.M
    Last changed : 5/24/2017 5:43:56 PM by LTT
    (modified after loading)
    Sample Info : Poroshell HPH-C18 (2.1*100mm,2.7um); F=0.3ml/min; T=30 degree;
    CH3CN/H2O=60/40

    Additional Info : Peak(s) manually integrated


    DAD1 A, Sig=210,4 Ref=off (D:\DATE\05-24-2017\2017-05-24 16-43-52.D)
    mAU

    12.206

    13.021
    300
    250
    200
    150

    LC-MS

    13.899
    100
    50
    0
    2 4 6 8 10 12 14 16 18 min
    MSD2 TIC, MS File (D:\DATE\05-24-2017\2017-05-24 16-43-52.D) ES-API, Neg, Scan, Frag: 100
    12.314

    13.137

    110000
    100000
    90000
    80000
    14.094

    70000
    60000
    50000
    40000
    30000
    2 4 6 8 10 12 14 16 18 min

    6120B 5/24/2017 5:44:17 PM LTT Page 1 of 3


    Data File D:\DATE\05-24-2017\2017-05-24 16-43-52.D

    MS Signal: MSD2 TIC, MS File, ES-API, Neg, Scan, Frag: 100


    Spectra averaged over upper half of peaks.
    Noise Cutoff: 1000 counts.
    Reportable Ion Abundance: > 10%.
    LC Signal: DAD1 A, Sig=210,4 Ref=off
    Peak matching window: 0.1 min

    Retention Retention Mol. Weight


    Time (LC) LC Area Time (MS) MS Area or Ion
    12.206 6945 - -

    - - 12.314 2023799 658.40 I


    641.40 I
    631.35 I
    596.40 I
    595.45 I

    13.021 7657 - -

    - - 13.137 2301217 659.35 I


    658.40 I
    641.40 I
    631.40 I
    596.40 I
    595.40 I

    13.899 1086 - -

    - - 14.094 391171 658.35 I


    631.35 I
    597.40 I
    596.35 I
    595.30 I

    *MSD2 SPC, time=12.003:12.448 of D:\DATE\05-24-2017\2017-05-24 16-43-52.D ES-API, Neg, Scan, Frag: 100
    595.5

    100 Max: 34171

    80

    60
    596.4

    40
    659.3

    20
    632.3

    100 200 300 400 500 600 700 800 900 m/z

    6120B 5/24/2017 5:44:17 PM LTT Page 2 of 3


    Data File D:\DATE\05-24-2017\2017-05-24 16-43-52.D

    *MSD2 SPC, time=12.804:13.315 of D:\DATE\05-24-2017\2017-05-24 16-43-52.D ES-API, Neg, Scan, Frag: 100

    595.4
    80

    60

    596.4
    40

    658.4
    597.4
    20

    642.5
    0

    100 200 300 400 500 600 700 800 900 m/z

    *MSD2 SPC, time=13.893:14.182 of D:\DATE\05-24-2017\2017-05-24 16-43-52.D ES-API, Neg, Scan, Frag: 100

    595.3
    35

    30

    25

    596.3
    20

    15

    10
    597.4

    659.4
    632.4
    5

    100 200 300 400 500 600 700 800 900 m/z

    *** End of Report ***

    6120B 5/24/2017 5:44:17 PM LTT Page 3 of 3

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