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Relative Permeability For Gas-Condensate Fluid A General Correlation PDF
Relative Permeability For Gas-Condensate Fluid A General Correlation PDF
the following equation for capillary number15 used in this gas and condensate relative permeabilities. The upstream
work: back-pressure regulator was set at a pressure above the dew
point pressure of the fluid and the downstream back-pressure
kΔP
Nc = (4) regulator was set at a pressure below the dew point pressure
σL corresponding to the bottom hole flowing well pressure.
The pressure drop is the only variable in Eq. 4 for two-phase, Therefore, the single-phase gas mixture flashes into two
steady state flow of gas and oil at connate water saturation at phases (gas and condensate) as it flows past the upstream
fixed temperature and pressure. There is no advantage to back-pressure regulator. This dynamic flashing method is
expressing the capillary number in terms of velocity since the similar to the condensate accumulation process around
pressure drop is measured. The endpoint relative permeability production wells. The mixture is injected until steady state is
of each phase is calculated as a function of the residual phase reached at a given flow rate and the pressure drop measured.
saturations (and thus indirectly the capillary number) as The flow rate is then increased and the measurements repeated
follows: at each flow rate to determine the dependence of the relative
permeability on capillary number.
(k )
low − S
S1'r
o low l'r o high o low
k orl = k rl + rl − k rl (5) Results and Discussion
low − Shigh
S1'r 1'r The steady state gas and condensate (oil) relative
permeabilities have been correlated as a function of the krg/kro
ratio and the capillary number. The steady state krg/kro ratio
Experimental Apparatus and Procedure can be calculated directly from the PVT properties of the fluid
Coreflood Apparatus. A laboratory was setup for steady state and for a particular fluid is dependent only on the pressure and
gas-condensate relative permeability measurements at temperature. Chopra et al.16 showed that the krg/kro ratio can be
reservoir conditions. Figure 1 shows a schematic of the calculated using only PVT data using the following equation:
experimental setup. A positive displacement Ruska pump was
used to inject fluid at a constant rate. Multiple pressure ports k rg Vg μg
were used to measure the pressure drop and see condensate = (6)
k ro Vo μo
buildup along the length of the core. Two back-pressure
regulators were used to control the flowing pressure upstream where, Vg and Vo are the volumes of gas and liquid obtained
(BPR-1) and downstream (BPR-2) of the core. The flow is from constant composition expansion measurements expressed
downward through a vertical core. A high-pressure Phoenix as a fraction of the total hydrocarbon volume. Fevanq and
core holder, Temco back-pressure regulators and high- Whitson17 used an equivalent equation as the basis for their
pressure Temco accumulators are placed inside a temperature pseudo steady state method of calculating the flow rates from
controlled oven. wells with a condensate bank. At steady state the volume
fractions correspond to the fractional flow of each phase so
Synthetic Gas-Condensate Mixtures. Five different fluid Eq. 6 can also be written as follows:18
mixtures were used to perform coreflood experiments. The
k rg f g μg
compositions of the gas mixtures are given in Table 1. The = (7)
fluid PVT properties were calculated using the Peng-Robinson k ro fo μo
equation of state with Peneloux volume corrections. Figure 2
and Table 2 give key fluid property data for fluids 1, 2 and 3. where, fg and fo represent the steady state fractional flow of
Fluids 3, 4 and 5 were used for reservoir cores C, A and B, gas and liquid respectively.
respectively. Whitson et al.,13 Mott et al.,12 Cable et al.,7
Ayyalasomayajula et al.4 and Kumar et al.11 have all shown
Rocks. Berea sandstone and reservoir sandstone plugs from that steady state gas and condensate relative permeability data
three different gas-condensate fields and Texas cream can be correlated with the ratio given in Eq. 6. The data
limestone were used in the coreflood experiments. Table 3 presented in this paper confirm and extend this correlation to a
gives the rock properties for the new core flood experiments wider range of conditions and higher capillary numbers.
as well as those from the literature. The cores were wrapped
with a layer of Teflon tape followed by aluminum foil and Results for Sandstones. Figures 3 through 12 show gas and
Teflon heat shrink tube. The Teflon tape was used to prevent oil relative permeability data as a function of capillary number
contact of brine with the aluminum foil. Aluminum foil and for different krg/kro ratios. The new data presented in this paper
Teflon heat shrink tube prevent diffusion of gasses and extend the range of the capillary numbers to the high values
interaction of fluids with the Viton rubber sleeve. representative of flow near high-rate wells.
Figures 3 and 4 show the measured gas and oil relative
Coreflood Procedure. The single-phase gas permeability for permeability data for a krg/kro ratio of 2.1 for capillary
each dry core was first measured using methane or nitrogen. numbers up to 10-3. Under some conditions non-Darcy flow
Initial water saturation was then established and gas relative can complicate the measurement of relative permeability at
permeability at initial water saturation was measured. A such high capillary numbers. Non-Darcy flow was avoided in
dynamic flashing method (also called pseudo-steady state these experiments by lowering the IFT between the gas and oil
method in the literature) was used to measure the steady-state to 0.049 dyne/cm. With this low IFT, the flow rates required
SPE 102741 3
to give the desired capillary numbers are not high enough to permeability data as a function of capillary number. The data
cause non-Darcy flow. for a krg/kro ratio of 1.6 are for capillary numbers on the order
The data show that the gas and oil relative permeabilities of 10-5. The data at a ratio of 2.1 was measured over a
do not increase significantly up to a capillary number of about capillary number range of 10-4 to 10-3 and show a significant
10-4, but for capillary numbers greater than 10-4 there is a increase in both gas and oil relative permeabilities with
significant increase in both gas and oil relative permeabilities. capillary number. This is the first set of limestone data
Similar results are observed for other krg/kro ratios. Figures 5 reported for such high capillary numbers. Figures 13 and 14
and 6 show the measured gas and oil relative permeability data also compare the new data with some of the data reported in
as well as the data from the literature as a function of capillary literature, which show a similar behavior.
number for a krg/kro ratio of 1. This set of data shows a similar The gas and oil relative permeabilities are higher for this
trend i.e. low and almost constant values of gas and oil relative limestone than for the sandstones at low capillary numbers.
permeabilities for capillary numbers up to 10-4 and a steep However, gas and oil relative permeabilites are almost the
increase in both the gas and oil relative permeability values for same at high capillary numbers. The data for capillary
capillary numbers greater than 10-4, which corresponds to the numbers in the range of 10-5 to 10-3 were compared with the
critical capillary number and is typical for a non-wetting phase model curves using the same set of parameters used for
in sandstones.14 The data of Cable and Mott7 using reservoir sandstones (Table 3). Figures 13 and 14 show that the model
gas-condensate fluids and the data of Kumar et al.11 using curve is close to the data at high capillary numbers, but is
synthetic gas-condensate fluids are in good agreement. This is somewhat lower than most of the data at low capillary
an important observation since almost all of the data in the numbers.
literature are for synthetic fluids.
Figures 7 and 8 show the dependence of gas and oil Illustration of Relative Permeability Model. Figure 15
relative permeability on capillary number for reservoir shows gas relative permeability model curves as a function of
sandstone with a krg/kro ratio of 3 to 5. Figures 9 and 10 show capillary number for different krg/kro ratios. Figure 16 shows
the measured relative permeability data for lean gas- the model curves as a function of krg/kro for different capillary
condensate fluids corresponding to a krg/kro ratio in the range numbers. Figure 17 shows gas relative permeability model
of 8 to 12. Relative permeability data for even leaner fluids curves as a function of oil saturation for different capillary
corresponding to a krg/kro ratio in the range of 20 to 60 are numbers. Figure 18 shows that the oil saturation predicted by
shown in Figs. 11 and 12. The data for krg/kro ratios of 8 to 12 the model varies over a very narrow range of about 0.35 to
and 20 to 60 were measured on two different reservoir 0.40 when the krg/kro ratio is 1, which corresponds to a liquid
sandstone cores (Reservoir A and Reservoir B). The low drop out from a constant composition expansion on the order
values of gas relative permeability show that for even for such of 10%. All curves were calculated using the same set of
lean fluids (high krg/kro ratios) condensate blocking can be a parameters given in Table 3. These curves can be used to get a
serious problem. quick first estimate of the steady state gas and oil relative
The new sandstone data and the sandstone data reported in permeability values in a condensate bank using nothing but
the literature for both reservoir and synthetic fluids was used PVT data to calculate the krg/kro ratio and the capillary
to tune the UT relative permeability model.14 An attempt was number. The well productivity index can then be estimated
made to fit all of the gas and oil relative permeability using from one of several simple models.13,18 The UT relative
only one set of model parameters for all rocks and fluids over permeability model can also be used to fit experimental data
the entire range of capillary numbers. Table 3 gives the model following chemical treatment of the rock to increase the gas
parameters obtained after tuning the model to fit all of the and oil relative permeabilities.11 The increase in the gas and
data. oil flow rates can then be estimated from numerical simulation
Figures 3 to 12 show the comparison of the measured gas or in special cases from an analytical well model.19
and oil relative permeability data with the model curves. The
comparison shows that the model curves fit the data over Conclusions
krg/kro ratios ranging from 1 to 60 and capillary numbers 1. Steady state gas and oil relative permeabilities have been
ranging from 10-7 to 10-3 reasonably well within experimental measured at high capillary numbers corresponding to the
uncertainty. The model predicts low and almost constant gas near well region of high-rate gas-condensate wells.
and oil relative permeabilities for capillary numbers less than 2. Gas and oil relative permeabilities show strong dependence
10-4 as observed from the data. The match is equally good for on capillary numbers at high capillary number for both
low and high krg/kro ratios. The most significant observation of sandstones and limestones.
this work is that the model is able to capture the sharply 3. The UT relative permeability model was used to fit the gas
increasing relative permeability in the capillary number range and oil relative permeability data for sandstones and
of 10-4 to 10-3, which represents the capillary numbers limestones over a wide range of capillary numbers, krg/kro
expected near high-rate gas-condensate wells. ratios, rock type, fluids, temperatures, permeability and
initial water saturation using just one set of parameters for
Results for Limestone. The steady state relative permeability all the data.
measurements for Texas Cream Limestone were done using 4. The model captures the gas and oil relative permeability
fluid 1 at 145 °F. The experiments were done at 1200 psig and dependence on capillary numbers for both limestones and
2600 psig corresponding to krg/kro ratios of 1.6 and 2.1. sandstones.
Figures 13 and 14 show the measured gas and oil relative
4 SPE 102741
Table 1—Fluid Composition of Synthetic Gas Mixtures Table 2—Properties of Synthetic Gas Mixtures 1, 2 and 3
Fluid Component Mole % Fluid Temperature, Dew-Point Core Krg/kro
°F Pressure, Pressure,
Fluid 1 Methane 80
psi psi
n-Butane 15
n-Heptane 3.8 Fluid 1 145 2792 1200 1.6
n-Decane 1.2 Fluid 1 145 2792 2600 2.1
Fluid 2 Methane 83 Fluid 2 250 3850 1500 0.9
n-Butane 4 Fluid 3 275 4153 1500 2.9
n-Heptane 7.2
n-Decane 4
n-Dodecane 1.8
Fluid 3 Methane 93
n-Butane 4
n-Decane 2
n-Pentadecane 1
Fluid 4 Methane 94.5
n-Decane 5.95
n-C20 0.05
Fluid 5 Methane 98.7
n-Decane 0.98
n-C20 0.32
Ayyalasomayajula et al.
Cap illary Kumar et al.
Viscom eter 0.3 Berea
krg/kro=2
Core BPR-2
Holder 0.2
RUSKA
Pump 0.1
Effluent
0.0 -7
Fig. 1—A schematic of experimental setup for coreflood 10 10-6 10-5 10-4 10-3 10-2
1E-7 1E-6 1E-5 1E-4 1E-3 1E-2
experiments.
Capillary Number
35 Fig. 4—Comparison of measured oil relative permeability for
krg/kro=2 with the relative permability model.
30 Fluid 2
250°F 1.0
Liquid Dropout, %
25
Henderson et al.
0 0.2
0 1000 2000 3000 4000 5000
Pressure, psig
0.0 -7
Fig. 2—Liquid dropout of the fluid mixtures for constant 10 10-6 10-5 10-4 10-3 10-2
1E-7 1E-6 1E-5 1E-4 1E-3 1E-2
composition expansion.
Capillary Number
1.0 Fig. 5—Comparison of measured gas relative permeability for
Henderson et al. krg/kro=1 with the relative permability model.
Cable et al.
Gas Relative Permeability
0.2 0.4
0.0 -7 0.2
10 10-6 10-5 10-4 10-3 10-2
Capillary Number
0.0 -7 -6 -5 -4 -3 -2
Fig. 3—Comparison of measured gas relative permeability for 10 10 10 10 10 10
1E-7 1E-6 1E-5 1E-4 1E-3 1E-2
krg/kro=2 with the relative permability model.
Capillary Number
Fig. 6—Comparison of measured oil relative permeability for
krg/kro=1 with the relative permability model.
SPE 102741 7
0.7 0.10
Henderson et al.
Reservoir A Cable et al.
0.6
Gas Relative Permeability
Reservoir B
0.1 0.02
0.0 -7
10 10-6 10-5 10-4 10-3
1E-7 1E-6 1E-5 1E-4 1E-3 0.00 -7 -6 -5 -4 -3
Capillary Number 10 10 10 10 10
Capillary Number
Fig. 7—Comparison of measured gas relative permeability for
krg/kro=3 and 4 with the relative permability model. Fig. 10—Comparison of measured oil relative permeability for
krg/kro=8 to 12 with the relative permability model.
0.20
1.0
Reservoir A
Reservoir B Reservoir B
Oil Relative Permeability
0.04
0.2
0.00 -7 -6 -5 -4 -3
10 10 10 10 10 0.0 -7
1E-7 1E-6 1E-5 1E-4 1E-3 10 10-6 10-5 10-4 10-3
Capillary Number 1E-7 1E-6 1E-5 1E-4 1E-3
Capillary Number
Fig. 8—Comparison of measured oil relative permeability for
krg/kro=3 and 4 with the relative permability model. Fig. 11—Comparison of measured gas relative permeability for
krg/kro=20 to 60 with the relative permability model.
1.0
Henderson et al. 0.10
Cable et al. Reservoir B
Gas Relative Permeability
0.4
0.04
0.2
0.02
0.0 -7
10 10-6 10-5 10-4 10-3 0.00 -7
1E-7 1E-6 1E-5 1E-4 1E-3 -6 -5 -4 -3
Capillary Number 10 10 10 10 10
1E-7 1E-6 1E-5 1E-4 1E-3
Capillary Number
Fig. 9—Comparison of measured gas relative permeability for
krg/kro=8 to 12 with the relative permability model. Fig. 12—Comparison of measured oil relative permeability for
krg/kro=20 to 60 with the relative permability model.
8 SPE 102741
0.5 1.0
Capillary Number
Al-Anazi et al.
Du et al. 1.00E-03
0.4 krg/kro=1
0.8 3.00E-04
krg/kro=1.6 2.00E-04
krg/kro=2 1.00E-04
0.3 krg/kro=2.1 0.6
1.00E-05
1.00E-06
0.2 0.4 1.00E-07
0.1 0.2
0.0 -7 0.0
10 10-6 10-5 10-4 10-3 0.001 0.01 0.1 1 10 100 1000
1E-7 1E-6 1E-5 1E-4 1E-3
Capillary Number Ratio of Gas to Oil Relative Permeability
Fig. 13—Comparison of gas relative permeability measured on Fig. 16—Gas relative permeability as a function of krg/kro ratio.
limestone for krg/kro=1 and 2 with the relative permability model.
1
0.5
Al-Anazi et al.
0.4 krg/kro=1
krg/kro=1.6 0.1
krg/kro=2 Caillary
0.3 krg/kro=2.1 Number
1.00E-02
1.00E-03
0.2 0.01 3.00E-04
1.00E-04
1.00E-05
0.1 1.00E-07
0.001
0.0 -7 -6 -5 -4 -3 0.0 0.2 0.4 0.6 0.8 1.0
10 10 10 10 10 Oil Saturation
1E-7 1E-6 1E-5 1E-4 1E-3
Capillary Number
Fig. 17—Gas relative permeability as a function of oil saturation
Fig. 14—Comparison of oil relative permeability measured on and capillary number.
limestone for krg/kro=1 and 2 with the relative permability model.
Ratio of Gas to Oil Relative Permeability
100
1.0
Caillary
krg/kro=100 Number
krg/kro=10 1.00E-02
Gas Relative Permeability
0.8 10
krg/kro=5 1.00E-03
krg/kro=2 3.00E-04
krg/kro=1.0 1.00E-04
0.6 krg/kro=0.1 1 1.00E-05
1.00E-07
0.4
0.1
0.2
0.01
0.0 0.2 0.4 0.6 0.8 1.0
0.0 -7 -6 -5 -4 -3
10 10 10 10 10 Oil Saturation
Capillary Number Fig. 18—Oil saturation as a function of krg/kro ratio and capillary
Fig. 15—Gas relative permeability as a function of capillary number.
number.