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CONSTRUCTION
MATERIAL
9.1. Bitumen
9.2. Rubber
9.3. Plastic
9.4. Polymer
9.5. Gypsum
9.6. Glass
9.7. Fiber Reinforced Polymer
The range of materials available to the engineer is vast and these materials
may possess widely differing properties. Concrete, timber, steel, bitumen,
glass, rubber and polymer are all used by engineers, but in character and
properties they are completely different from one another. Every engineer is
concerned with materials and has to select the most suitable material for the
job in hand, be it for some civil engineering structure, or some power plant,
or perhaps for an electronic component. An engineer has to consider many
factors when making the selection because within one group of materials,
properties may range from soft and easily deformed to tool steels which are
hard and tough.
9.1 Bitumen
Properties of Bitumen
Bitumen Application
Bitumen is primarily used for paving roads. Its other uses are for bituminous
waterproofing products, including the use of bitumen in the production of
roofing felt and for sealing flat roofs.
Bitumen alternatives
Methods of Testing
Most present day standard were developed in the early 1900s. Equipment
has change becoming electric and better control can be accomplished during
the testing period of the product.
2. Sampling Bituminous (ASTM
D140)
- cover the method used to
sample bituminous material at
1. Specific Gravity (ASTM D70)
points of manufacture,
- use of a pycnometer
storage or delivery
- can be expressed as the ratio
- is to determine the true nature
of the weight of a given
and condition of the material
volume of the material at
250C or at 15.60C to that of an
equal volume of water at the
same temperature
3. Ductility (ASTM D113)
- is measured by the distance
to which it will elongate before
breaking when 2 ends of
specimen are pulled apart at
a specified speed and
Method of Testing
temperature
- to measure the adhesive and
elasticity of the asphalt.
4. Viscosity
- ASTM D2170 : Kinematic
Viscosity of asphalt (Bitumen)
- Covers determination of the
kinematic viscosity of liquid
asphalt (bitumen), road oils
and distillation residue of
liquid asphalt (bitumen), all at
600C and for asphalt cement
at 1350C in the range of 6 to
100,000 centistokes.
- Meadure the resistance to
5. Penetration of Bituminous flow of a liquid under gravity.
Materials (ASTM D5) - ASTM D2171 : Viscosity of
- measure the hardness and asphalt by Vacuum Capillary
softness of the material Viscometer
- test are taken at least 3 - Determination of viscosity of
determination on the surface of the asphalt (bitumen) by vacuum
sample at points not less than 10 capillary viscometer at 600C.
mm from the side of the container - It is applicable to material
and not less than 10 mm apart. having viscosities in the range
- However, the test is empirical and from 0.036 to over 200,000
many engineers would like to poiss (P).
replace it with ASTM D2171
(Viscosity of Asphalts by Vacuum
Capillary Viscometer) 6. Float Test (ASTM D139)
- is a consistency test used for
material that are too soft to
undergo the standard
penetration test and too hard
for use with viscosity test
Pithces
is the name for any of a number of highly viscous liquids
which appear solid. Pitch can be made from petroleum
products or plants
Molasses
is a viscous by-product from the processing of the sugar
beet or sugar cane into sugar
Fractional distillation
is the separation of a mixture into its component parts, or
fractions, such as in separating chemical compounds by
their boiling point by heating them to a temperature at
which several fractions of the compound will evaporate.
9.2 Rubber
Christopher Columbus has been the first Europeans to handle natural rubber
since it was reported that some tribes of South American Indians played ball
games well before the days of Pele!. Rubber is a very important material
used in a wide range variety of product. It is an elastomer. This is a
substance in which the arrangement of the polymer molecules allows
considerable reversible extension to take place at normal temperatures.
Elastomer exists as long chain molecules which are irregularly coiled, bent
and generally entangled when in the unstressed state.
Elastomer is used in Civil Engineering for some good reason such as:
- Long lasting
- Good in impact absorption
- Good bonding with metal
- Good resistance to ageing
- Good tearing properties
- Good physical properties
- Good resistance to oil and chemicals
- Suitable for hot and cool temperature.
However, elastomer rubber is expensive especially for rubber with high
resistance to ageing. It also can be attack by ester, ketone, hydrocarbon
with nitrogen and aromatic. Table 9.1 shows physical properties of the
elastomer.
Resilience or
E F-G G F-G VG
Rebound
Impact Resistance E E G F G
Abrasion Resistance E G-E G-E G-E G-E
Tear Resistance E F F-G F-G F-G
Cut Growth E G G G G
Physical Natural
SBR EPDM NBR Neoprene
Properties Rubber
Flame Resistance P P P P G
Impermeability, Gas F F F-G G F-G
Weathering
P-F F E F-G VG
Resistance
-30°
Low Temperature -10° TO - 0° TO - -20° TO -10° TO -
TO -40
Limit* 50°F 50°F -60°F 50°F
°F
High Temperature 158° TO 158° TO 300° TO 275°F 225°F
Limit* 225°F 225°F 350°F
P = Poor, F = Fair, G = Good, VG = Very Good, E = Excellent
9.3 Plastic
Organic plastic can be classified into three general classifications which are;
(iii) Chemically Setting Plastic: are those that harden by the addition
of a suitable chemical to the composition just before molding or by
subsequent chemical treatment following fabrication.
Properties of Plastic
The strength of plastics materials is generally much lower than that of other
constructional material. Nevertheless, plastics are light material with relative
density between 0.9 and 2.0. Table 9.2 shows the strength-weight
relationships for plastic and some common structural elements.
Application of Plastic
9.4 Polymer
Polymer Materials
Acetal resin
is an engineering plastic, a polymer with the
chemical formula -(-O-CH2-)n-. It is often
marketed and used as a metal substitute
PET
is a thermoplastic polymer resin of the polyester
family and is used in synthetic fibers; beverage,
food and other liquid containers; thermoforming
applications; and engineering resins often in
combination with glass fiber.
composite materials when reinforced with stiff fibres such as fibreglass and
aramids. Since crosslinking stabilises the thermosetting matrix of these
materials, they have physical properties more similar to traditional
engineering materials like steel. However, their very much lower densities
compared with metals makes them ideal for lightweight structures. In
addition, they suffer less from fatigue, so are ideal for safety-critical parts
which are stressed regularly in service.
Thermoplastics have relatively low tensile moduli, but also have low densities
and properties such as transparency which make them ideal for consumer
products and medical products. They include polyethylene, polypropylene,
nylon, acetal resin, polycarbonate and PET, all of which are widely used
materials.
Elastomers are polymers which have very low moduli and show reversible
extension when strained, a valuable property for vibration absorption and
damping. They may either be thermoplastic (in which case they are known as
Thermoplastic elastomers) or crosslinked, as in most conventional rubber
products such as tyres. Typical rubbers used conventionally include natural
rubber, nitrile rubber, polychloroprene, polybutadiene, styrene-butadiene and
fluorinated rubbers such as Viton.
Applications of Polymer
Monocoque
is a construction technique that supports structural
load by using an object's external skin as opposed to
using an internal frame or truss that is then covered
with a non-load-bearing skin
Stealth bomber
is an American heavy bomber with "low observable"
stealth technology designed to penetrate dense anti-
aircraft defenses and deploy both conventional and
nuclear weapons.
9.5 Gypsum Board
Hydrous
containing water as a constituent
Plasticizer
are additives that increase the plasticity or fluidity of the material to which they
are added, these include plastics, cement, concrete, wallboard and clay bodies
Foaming agent
is a surfactant, which when present in small amounts, facilitates the formation
of a foam, or enhances its colloidal stability by inhibiting the coalescence of
bubbles
Potash
is the common name given to potassium carbonate and various mined and
manufactured salts that contain the element potassium in water-soluble form.
EDTA
Ethylenediamine tetra-acetic acid, a crystalline acid with a strong tendency to
form chelates with metal ions.
Starch
an odourless, tasteless white substance occurring widely in plant tissue and
obtained chiefly from cereals and potatoes. It is a polysaccharide which
functions as a carbohydrate store and is an important constituent of the human
diet.
Chelate
a compound containing a ligand (typically organic) bonded to a central metal
atom at two or more point.
Mildew
a thin whitish coating consisting of minute fungal hyphae, growing on plants or
damp organic material such as paper.
Vermiculite
is a natural mineral that expands with the application of heat.
9.6 Glass
The principle ingredients of common soda glass
are silica sand, lime (from limestone) and soda
ash (crude sodium carbonate). Since glass can
be recycle, large amount of scrap glass (cullet)
are used in glass manufactured. At 15900C
temperature in gas-fired furnaces which hold up
to 250 tonnes of molten glass, acidic silicate will reacts with basic lime and
soda to form the mixed silicates known as glass. Glass can be rolled, blown,
cast or pressed for a variety of uses. From engineering point of view, glass is
extremely weak and codes and standard have been established to deal with
the utilization of glass in engineering project which is American National
Standards Institute (ANSI) Z97.1 Safety Glazing Material Used In Buildings –
Performance Specification and Methods of Test.
Properties of Glass
Glasses are plastic at high temperatures and rigid at low temperatures but
under normal manufacturing conditions glasses do not crystallize. When,
glasses have no crystal structure making molecules are unable to move
significant distance relatively at one another making glass extremely brittle at
ambient temperature. The rate of viscous flow is dependent mainly upon the
prevailing temperature but is also dependent upon the composition and
structure of the glass. Small applied stresses will cause the more highly
strained bonds within the structure to be ruptured. When glass is drawn to a
fine fiber and cooled quickly, a high tensile strength is produced. Glass is
extremely stable and will not deteriorate. Special glasses used in fiber-
reinforced composites can
reach strength of up to 15 000
MPa (under ideal condition),
but in practice a lower
strength of about 3500 MPa
would be obtained since
surface damage of the fiber is
caused by contact with other
material. These microscopic
surface scratches act as
stress-raisers.
Application of Glass
The coefficient of thermal expansion of ordinary soda glass is relatively high,
whilst its thermal conductivity is low, and this combination of properties makes
it unsuitable for use in the majority of domestic situation involving sudden
contact with boiling water. Table 9.4 shows other applications of glass in
wide range of use.
Advanced FRP composites are made from different constituent materials, i.e.
fiber, resins, interface, fillers, and additives. Higher modulus fibers contribute
to the mechanical strength of the FRP, whereas the matrix helps to transfer
or distribute the stress from one fiber to another, through interface shear
resistance, and to improve the durability of the fiber against environmental
and mechanical damage. The fiber generally occupies 30–70% of the matrix
volume of the composite (Figure 9.8). The interface between the fiber and the
matrix is known to significantly affect the performance of FRP composites. In
addition to these three basic components (fibers, resins, and interface), the
fillers serve to reduce cost and shrinkage. The additives help to improve the
mechanical and physical properties of the composites as well as the
workability.
Applications of Fiber Reinforced Polymer
1. Briefly define:
a. Bitumen
b. Plastic
c. Polymer
d. Gypsum Board
e. Glass
f. Fiber Reinforced Polymer