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•Review•
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Magnetic levitation using diamagnetism: Mechanism, applications


and prospects
GAO QiuHua, YAN Han, ZOU HongXiang, LI WenBo, PENG ZhiKe,
*
MENG Guang & ZHANG WenMing

State Key Laboratory of Mechanical System and Vibration, School of Mechanical Engineering,
Shanghai Jiao Tong University, Shanghai 200240, China

Received January 15, 2020; accepted February 25, 2020; published online May 13, 2020

As a typical contact-free manipulation technique that removes friction and contamination risk, levitation has gradually become a
preferred candidate for various applications. Magnetic levitation using diamagnetism, beyond Earnshaw’s theorem, is a kind of
passive stable levitation that can be achieved at normal temperatures with no energy input. Appealingly, most seemingly
nonmagnetic materials can be levitated in a magnetic field and can stabilize free levitation of magnetic materials. This review
focuses on the fundamental principles of magnetic levitation using diamagnetism, with emphasis on its burgeoning applications.
The theoretical basis associated with the magnetic levitation using diamagnetism is discussed by elucidating the characteristics
of diamagnetic materials, and the key levitation mechanisms are clarified. Afterwards, state-of-the-art applications in various
aspects, including sensing and measurement, actuating and micromanipulation, energy harvesting and magnetic gravity com-
pensation, are summarized and compared. Finally, the review concludes with a brief outlook on future perspectives.
magnetic levitation, diamagnetism, sensors, actuators, energy harvesters

Citation: Gao Q H, Yan H, Zou H X, et al. Magnetic levitation using diamagnetism: Mechanism, applications and prospects. Sci China Tech Sci, 2020, 63,
https://doi.org/10.1007/s11431-020-1550-1

1 Introduction erties but also clear limitations. Aerodynamic levitation lifts


a sample by aerodynamic forces in a gas stream flowing from
Contactless levitation and controlled motion of matter are of a jet nozzle. Stability in the vertical direction can be realized
fundamental importance to many branches of modern sci- by the divergence of the jet, and the stability in the transverse
ence. In recent years, levitation techniques have been direction can be guaranteed via the centering force produced
adopted in a wealth of applications ranging from materials by the increased Bernoulli force where the flow is faster [13].
science to biophysics [1,2], such as containerless processing However, this technique cannot levitate a sample in a va-
for high-purity materials [3,4], physical properties mea- cuum. Acoustic levitation suspends a sample via the acoustic
surement [5,6], manipulation of particles and biological radiation force at the point where the force converges [14].
materials [2,7–9], and so forth [10–12]. Substances may be The commonest acoustic levitators are single-axis types,
levitated by a jet of airflow, a beam of laser light, intense which generally consist of a circular ultrasonic transducer
waves of sound, alternative electric field and strong radio- and a reflector or another transducer. Between the two ele-
frequency field. Each of these methods has intriguing prop- ments, the acoustic radiation force generated by the standing
wave pushes the sample to a pressure node [15]. In this
technique, the sample must be levitated in a medium. Optical
*Corresponding author (email: wenmingz@sjtu.edu.cn)

© Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature 2020 tech.scichina.com link.springer.com
2 Gao Q H, et al. Sci China Tech Sci

levitation suspends the sample against gravity using the ra- underlying the research subarea. Advances in applications
diation pressure from a focused laser in air or vacuum [16]. such as acceleration sensors, viscosity and density sensors,
Based on the optical levitation, optical manipulations have force sensors, rotating actuators, micro-robots, energy har-
significantly advanced in scientific fields ranging from vesters, are summarized and compared (Figure 1). Finally,
atoms to biological materials [9], but are disadvantaged by we discuss current challenges and limitations in an outlook
bulky and sophisticated instruments [17], heating at the focal with future perspectives.
point due to optical absorption [2]. Samples that are elec-
trically charged can be levitated in an electrostatic field. This
method, known as electrostatic levitation, can be applied to 2 Fundamentals
conductors, semi-conductors and insulators in a vacuum
environment [3]. One drawback is the complexity and high 2.1 Diamagnetic materials
cost of electrostatic levitators, which require tricky operation The magnetic property of a material depends on two main
and active feed-back system [18]. Magnetic levitation can be atomistic effects, specifically, the orbital motion of electrons
realized in several different ways. One or a combination of around nucleus and the intrinsic spin of the electrons, which
permanent magnets, electromagnets, diamagnets or super- are associated with its atomic structure and temperature
conductors may be involved under the action of attractive [36,37]. Magnetic materials can be generally classified into
and repulsive fields, such as levitation by repulsive perma- ferromagnets (the most familiar type), paramagnets and
nent magnets with guidance [13,19], radio-frequency elec- diamagnets [38]. An externally applied magnetic field aligns
tromagnetic levitation [3,20] and superconducting levitation the moments of all the magnetic domains, and the vector sum
[21]. Interestingly, most seemingly nonmagnetic materials of each domain manifests as the magnetization of the fer-
can be levitated in a magnetic field and can stabilize the free romagnetic material. Due to the dimensions as well as
levitation of permanent magnets at normal temperatures, structures of the domains and their interactions, ferromag-
namely magnetic levitation by diamagnetism [13,22]. netic materials exhibit nonlinear magnetization behavior that
The demonstration of magnetic levitation using dia- depends on the history of the applied magnetic field, which is
magnetism dates back to the year of 1939, in which Braun- described by B-H curves. The induction Br remains after the
bek et al. [23] levitated tiny pieces of strongly diamagnetic external magnetic field is removed. Different from the fer-
materials (bismuth and graphite) under a strong in- romagnetic materials, the magnetizations of feeble magnetic
homogeneous magnetic field of an electromagnet. Later in materials can be regarded as a dynamic process in some
1991, various diamagnetic materials such as water, ethanol, extent [22,39], that is, the magnetizations are linear with the
acetone, antimony, bismuth, graphite, wood and plastic, were externally applied magnetic field and return to zero when the
levitated in a high static magnetic field of 27 T [24]. Berry external magnetic field is removed. Paramagnetic materials,
and Geim [25] levitated a living frog in a strong magnetic with positive magnetic susceptibilities, align along the ex-
field from a bitter magnet, which have drawn wide attention. ternal magnetic field and are attracted to magnetic field
The levitation of creatures has demonstrated that all dia- maximum (Figure 2(a)). In contrast, diamagnetic material
magnetic materials could be levitated with a sufficiently high manifests itself as a negative susceptibility, which can be
magnetic field [26]. Stable levitation of diamagnetic mate- also characterized as an induced magnetic moment opposite
rials can be achieved in the magnetic field, and vice versa, to the external magnetic field. Hence, they are repelled by the
diamagnetic materials can stabilize free levitation of a per- external magnetic field and move toward the field minimum
manent magnet. Geim et al. [27] demonstrated the stable (Figure 2(b)).
levitation of one permanent magnet by the diamagnetism of Diamagnetism is a quantum mechanical effect inherent in
human fingertips at room temperature. Levitating a water each atom and molecule [40]. However, the diamagnetic
droplet containing CuSO4 in a pressurized oxygen atmo- effect remains unnoticed generally in the paramagnetic or
sphere demonstrated that paramagnetic substance could be ferromagnetic materials because it is weaker and can be
levitated as well using the magneto-Archimedes effect [28]. overwhelmed by paramagnetism or ferromagnetism. Table 1
Cryogenic liquid and gaseous oxygen were also employed to lists the net volumetric magnetic susceptibilities of some
levitate a range of diamagnetic materials [29]. diamagnetic materials. Superconductors are perfect dia-
Nowadays, magnetic levitation using diamagnetism has magnets because the interior magnetic field of the super-
boosted the recent growth of contactless devices and appli- conductor can be cancelled by appropriate surface currents
cations. This article systematically reviews the latest pro- [21].
gress on fundamentals and applications of magnetic
levitation using diamagnetism. After introducing state-of- 2.2 Magnetic levitation using diamagnetism
the-art levitation techniques, we illustrate the characteristics
of diamagnetic materials and elucidate the key mechanisms Earnshaw’s theorem proved that particles could have no
Gao Q H, et al. Sci China Tech Sci 3

Figure 1 (Color online) Summary of magnetic levitation using diamagnetism: diamagnetic levitation (reprinted from ref. [22], with the permission of AIP
Publishing) and diamagnetically stabilized magnet levitation (reprinted by permission from ref. [27], copyright 1999 Springer Nature). (a) Diamagnetic
levitation-based rotor, reprinted from ref. [30], copyright 2019, with permission from Elsevier; (b) diamagnetic levitation-based sensor, © 2018 IEEE,
reprinted, with permission, from ref. [31]; (c) magnetic gravity compensation, reprinted by permission from ref. [32], copyright 2015 Springer Nature; (d)
diamagnetically stabilized energy harvester, © 2017 IEEE, reprinted, with permission, from ref. [33]; (e) diamagnetically stabilized microrobot, reprinted by
permission from ref. [34], copyright 2018 Springer Nature; (f) diamagnetically stabilized force sensor, reprinted from ref. [35], copyright 2016, with
permission from Elsevier.

Figure 2 (Color online) Magnetic effects under an external magnetic field. (a) Paramagnetic materials, with the magnetization direction parallel to that of
the external magnetic field, experience an attractive force; (b) diamagnetic materials, with the magnetization direction antiparallel to the external magnetic
field, experience a repulsive force.

stable equilibrium position if they are exerted by any type or given as


2
combination of 1/r forces, such as gravity, electrostatic M= p H, (1)
forces and magnetic forces [44]. Substances with positive
where H represents the magnetic field strength. χp is the
susceptibilities under an externally applied magnetic field
dimensionless magnetic susceptibility. It is weak (|χp|<<1)
move to a location featured as maximized field and cannot be
and negative (χp<0) for diamagnetic matter. For an object
stably levitated in free space. While the Earnshaw’s theorem
with volume Vp, the induced magnetic moment m can be
only applies to ferromagnetic or paramagnetic materials [45].
given by
Pushed towards an area of the field minimum, diamagnetic
materials can be stably levitated because local field minima m = p BVp / µ 0 . (2)
can exist in free space. The magnetizations of diamagnetic Here we ignore the distortion of the ambient field by the
materials vary with an applied magnetic field which can be object and the self-demagnetization in the object [25,46].
4 Gao Q H, et al. Sci China Tech Sci

Table 1 Net volumetric magnetic susceptibilities of some diamagnetic sultant force can be calculated as
materials [41–43]
( p m)
Net volumetric magnetic susceptibility F= B2Vp ( p m )gVp e z, (6)
Materials –6
(×10 )
2µ 0
V

Superconductors –10
6 where ez is the upwards unit vector. When stably levitated in
Pyrolytic graphite⊥ –450 the magnetic medium, the total force acted on the object
Pyrolytic graphite∥ –85 needs to be zero to keep static equilibrium. At the same time,
Diamond –21.8 remaining dynamic force balance requires a minimum of the
Silicon –3.25 potential at the levitation point, that is
Silicon nitride –9.0 2 ( p m) 2 2
E= B > 0, (7)
Glass –13.9 2µ 0
2
H2O –9.04 where B 2 can be calculated by
D2O –8.82 2
B2 = 2
(Bx2 + B y2 + B z2)
Bismuth –170
2 2 2
Copper –9.65 = 2( Bx + By + Bz ) 0. (8)
Gol –34.5
Then the necessary condition for stability can be simplified
Silver –23.8
as
Lead –15.6
p m < 0. (9)
Mercury –28
Hemoglobin –3.38 Based on the necessary condition for stable levitation,
Fibrinogen –6.12 magnetic levitation using diamagnetism comes in two fla-
DNA –4.99 vors: diamagnetic levitation and diamagnetically stabilized
Cholesterol –7.61 magnet levitation. Diamagnetic levitation refers to the stable
Benzene –7.68 levitation of diamagnetic substances (χp < 0) in an in-
Methanol –6.66 homogeneous magnetic field. The most representative ex-
Ethanol –7.23 ample is the levitation of a living frog [25]. Furthermore,
paramagnetic materials can be levitated like diamagnets by
immersing in a stronger paramagnetic medium (χm >χp >0),
The magnetic energy of the object can be expressed as [47] which is called magneto-Archimedes levitation [28]. Mag-
1 p neto-Archimedes levitation is considered as a variant of
Um = M BVp = B2Vp . (3)
2 2µ 0 diamagnetic levitation. The stable levitation of one magnet
As force and energy are related by Fm = Um, the by another in free space can be obtained with the aid of
magnetic force acting on the object can be derived by diamagnetic materials (such as fingertips) at special loca-
p tions [27], which is known as diamagnetically stabilized
Fm = B2Vp . (4) magnet levitation, or abbreviated as diamagnetically stabi-
2µ 0
Supposing that an object with the density ρp levitates in a lized levitation. The comparison of levitation mechanisms at
medium with the density ρm and magnetic susceptibility χm, room temperature is listed in Table 2.
the total energy of the object, including the magnetic energy
and gravitational energy, can be given by 3 Diamagnetic levitation: Methods and appli-
( p m) 2 cations
E= B Vp +( p m )Vp gz , (5)
2µ 0
where g represents the gravity acceleration. Then the re- In recent years, diamagnetic levitation has proved its worth

Table 2 Summary and comparison of magnetic levitation using diamagnetism: Diamagnetic levitation and diamagnetically stabilized magnet levitation
Levitation mechanism Diamagnetic levitation Diamagnetically stabilized levitation

Regime ( p m
) 2
B Vp ( )gVpe z = 0
2µ 0 p m

Diamagnets Diamagnets or paramagnets


Levitating objects Magnets
( p < 0) ( p < 0 or 0 < p < m )
Air or vacuum Paramagnetic medium Air or vacuum
Medium
( m 0) ( m > 0) ( m 0)
Gao Q H, et al. Sci China Tech Sci 5

due to no mechanical friction, wear and thermal dilatations producing a local magnetic field minimum with a steep
exist. Meanwhile, passive levitation needs no active control gradient. This magnet pattern is inherently stable and needs
and power supply, which improves reliability and offers a no gluing for assembly. The linear Halbach array, assembled
long service life. from magnets with spatially rotating pattern of magnetiza-
tions (Figure 3(b)), concentrates the flux on the one side and
3.1 Levitation mechanism and configurations cancels it on the other side [49]. This array cannot constrain
the motion of the levitating object along the width of the
To levitate a diamagnetic material, the construction must not magnets. With 2D pattern repetitions (Figure 3(c)), Halbach-
only support the object against gravity, but must also ensure 2D magnet array harnesses a higher thrust force density by
levitation stability to resist certain disturbance [48]. To cal- concentrating the magnetic field on the one side and
culate the whole diamagnetic force acting on the levitated shielding the stray field on the other side using a reduced
materials, each single dipole of the diamagnetic material has number of magnets [50]. However, the Halbach arrays need
to be considered. The diamagnetic force for the entire vo- gluing for assembly [51]. The above-mentioned magnet ar-
lume can be expressed as rays can be also constructed from ring-shaped magnets
p (Figure 3(d)–(f)), which generate a rotationally symmetrical
Fd = B2dv. (10) magnetic field and stabilize all degrees of freedom except the
2µ 0 V
rotation around the main axis [52].
Thus, the diamagnetic force in the three directions can be
According to eq. (10), the diamagnetic repulsion force is
derived as
proportional to the magnetic susceptibility of diamagnetic
p Bx By Bz materials. To counteract gravity in the magnetic field, ma-
Fdx = µ Bx + By + Bz dv,
0 V x x x terials with strong diamagnetism and lightweight properties
are preferred. Pyrolytic graphite and highly-oriented pyr-
p Bx By Bz
Fdy = µ Bx + By + Bz dv, olytic graphite (HOPG), formed by accurately aligning car-
0 V y y y bon atoms on a solid substrate by high-temperature
Bx By Bz decomposition [53], are usually chosen as the levitating
p
Fdz = µ Bx + By + Bz dv. (11) parts. Both materials exhibit strongly anisotropic magnetic
0 V z z z
and thermal properties, because the atomic bonding is strong
The magnetic field distribution is vitally important for within each layer but weak between layers [54]. High-quality
stable levitation. A spatially varying high magnetic field can graphite and HOPG are considered to have the strongest
be produced by Bitter magnet, superconducting magnets, or magnetic susceptibilities among bulk materials, and their
hybrid magnets. A weaker magnetic field can be produced by susceptibility depends on the heat treatment process [55].
electromagnets, magnets in configured arrangements, or a
combination of both. For the diamagnetic levitation using 3.2 Sensing and Measurement
permanent magnets, the key is to construct a local magnetic
field minimum with a steep gradient. The commonly used In an inertial sensing system based on diamagnetic levitation,
magnet configurations are schematized in Figure 3. The the typical seismic mass (which is displaced under external
opposite-2D magnet array (Figure 3(a)), consisting of acceleration) is levitating pyrolytic graphite. Barrot et al.
neighboring magnets with different polarities, is effective in [50] developed a 2D acceleration sensor that combined

Figure 3 (Color online) Schematics of commonly used magnet arrays for diamagnetic levitation. (a) Opposite-2D magnet array; (b) linear Halbach magnet
array; (c) Halbach-2D magnet array; (d) and (e) opposite-ring magnet array; (f) Halbach ring magnet array.
6 Gao Q H, et al. Sci China Tech Sci

Figure 4 (Color online) Prototypes and schematics of measurement devices using diamagnetic levitation. (a) 2D-acceleration sensor by combining
diamagnetic levitation and electrostatic actuation, reprinted by permission from ref. [50], copyright 2005 Springer Nature; (b) inertial sensor exploiting an
inductive readout strategy for displacement and acceleration measurement, © 2018 IEEE, reprinted, with permission, from ref. [31]; (c) microscope photo of a
levitated MEMS acceleration sensor for low-frequency measurement, © 2007 IEEE, reprinted, with permission, from ref. [56]; (d) laser power measurement
based on the levitation height of the pyrolytic carbon [54]; (e) mass change recorded after applying temperature correction over 120 s for three optical powers
generated by the laser of wavelength 532 nm, republished with permission of IOP Publishing, Ltd, from ref. [57], 2018 of copyright, permission conveyed
through Copyright Clearance Center, Inc.; (f) schematic of a gas viscometer using electromagnetically spinning method [58]; (g) experimentally obtained
magnetic field display of multilayer graphene suspension, reproduced with permission from ref. [59], copyright 2016 John Wiley and Sons.

diamagnetic levitation and electrostatic actuation (Figure 4 of pyrolytic graphite placed on a balance pan and irradiated
(a)). The seismic mass to be levitated was pyrolytic graphite by a laser beam. A plot of mass change with respect to the
surrounded by an aluminum ring. The relative position in- exposure time after applying temperature correction over
formation of the seismic mass was input to a feedback 120 s is shown in Figure 4(e). It was demonstrated that the
control loop that maintained the diamagnetic part at a pre- wave-lengths of irradiating light beams affected the photo-
defined position. Furthermore, they presented the design of a response of the pyrolytic graphite.
3D-acceleration sensor prototype that could measure the Shimokawa et al. [58] proposed a viscosity measurement
vertical motion with a differential control system. Ando et al. method using diamagnetic levitation. Free from mechanical
[31] developed an inertial sensor that could measure both friction, the levitating graphite was rotated by an electro-
displacement and acceleration (Figure 4(b)). The resolution magnetically induced torque as shown in Figure 4(f). The
–4 2
in two operating modes reached as low as 1×10 m/s and measurement results demonstrated that the measurement
–4
1.9×10 mm, respectively. Garmire et al. [56] presented a accuracy of this method was the order of μPa·s. With the aid
proof-of-concept design for MEMS based accelerator (Fig- of high diamagnetism of exfoliated graphene, Lin et al. [59]
ure 4(c)). The accelerator measured low-frequency vibration reported that graphene flakes could be aligned in the mag-
(below 5 Hz) with a measurement sensitivity of 34 μg at a netic field generated by one permanent magnet. When the
0.1 V sense signal. magnetic field and flakes were oriented horizontally, the
Pinot and Silvestri [54] preliminarily studied a laser power reflection was relatively high. When the magnetic field and
sensor that exploited the photothermal effect of pyrolytic flakes were oriented vertically, the reflection was low be-
carbon. Direct irradiation with a laser beam photothermally cause the light was transmitted among the flakes. Based on
induced changes in the magnetic susceptibility of the pyr- this phenomenon, the sensitivity of graphene to the magnetic
olytic graphite. Consequently, the irradiating laser power field could be exploited in magnetic field sensors that re-
could be measured by relating the levitation height of pyr- flected the actual distribution of the magnetic field (Figure 4
olytic carbon to the optical power as shown in Figure 4(d). (g)). Later, levitation and orientation of graphene using
More recently, the same working group developed a second magnetic field were theoretically and experimentally in-
configuration for laser power measurement [57]. Unlike the vestigated, which provided potential for the use of graphene
first configuration, the new system detected the mass change magnetic writing board [60].
Gao Q H, et al. Sci China Tech Sci 7

3.3 Actuating and micromanipulation to a height of 132 μm above the opposite-ring magnet array,
and the maximum rotating speed was 500 r/min. Kobayashi
Magnetic interactions provide improved performances for and Abe [65] demonstrated that photothermally induced
integrated MEMS systems due to the scale reduction effect changes in magnetic susceptibility could control the motions
[61]. Schemes for diamagnetic bearings range from simple of the graphite (Figure 5(c)). The magnetic susceptibility was
arrangements to sophisticated designs. The most straight- changed at the irradiated side, leading to a variation in the
forward structure consists of a ring-shaped magnet array magnetic force. The light energy then could be converted
stator and a diamagnetic rotor. Chen et al. [62] theoretically into rotational kinetic energy. Intriguingly, the maximum
evaluated the dynamic stability and rotational properties of a rotating speed reached over 200 r/min under sunlight. Later,
diamagnetic bearing. The vertical, lateral and inclination the physics mechanism and thermal driven motion of gra-
damping as well as rotational losses caused by eddy current phite on a checkerboard magnet array was investigated the-
effect were evaluated based on the thin-sheet model and the oretically and experimentally [66].
image method [63]. Utilizing MEMES processing methods Suzuki et al. [67] experimentally studied a contact-free
and the axial variable-capacitance motor principle, Liu et al. linear drive system using diamagnetic levitation. Levitated
[30] designed an electrostatic micromotor based on open- above the linear Halbach magnet array, the graphite plate
loop and closed-loop control (Figure 5(a)). When levitated, could be motivated by a small piece of approaching magnet.
the gear-shaped pyrolytic graphite rotor reached a rotating The acceleration was found to depend on the edge shape of
speed of 70.0 r/min above the magnets. Xu et al. [52] com- the pyrolytic graphite plate and the magnetic pole relation
bined frictionless diamagnetic levitation with an electrostatic between the magnet piece and the Halbach array. Kang et al.
glass motor. A piece of pyrolytic graphite adhered to a glass [68] developed a frictionless trajectory-control method op-
flake was levitated at a height of about 100 μm and actuated erated by adjusting magnetic field distribution. To guide the
by a three-phase rotary electrostatic field generated by motions of the graphite levitated above the linear Halbach
electrodes fixed on the stator. The maximum rotating speed magnet array, they modified the magnet rails with spacers
was limited to 140 r/min by the instability caused by the high because diamagnetic materials were pulled into the weak
voltage or small levitation gap. Su et al. [64] developed a magnetic field region. The experiments confirmed linear,
micromachined rotator actuated by a continuous nitrogen pendulum and curved motions of the pyrolytic graphite
flow (Figure 5(b)). The four-blade HOPG rotor was levitated (Figure 5(d)).

Figure 5 (Color online) Representatives of actuating devices using diamagnetic levitation. (a) Photo of a levitated pyrolytic graphite rotor driven by the
electrostatic field, reprinted from ref. [30], copyright 2019, with permission from Elsevier; (b) a micromachined diamagnetic rotator actuated by a gas flow, ©
2015 IEEE, reprinted, with permission, from ref. [64]; (c) photographic frames of the rotatory motion of a levitated pyrolytic graphite by a laser beam,
reprinted with permission from ref. [65], copyright 2012 American Chemical Society; (d) trajectory control of a levitated diamagnetic graphite by adjusting
the magnetic field distribution, reprinted by permission from ref. [68], copyright 2018 Springer Nature; (e) using the microrobot to carry a microparticle over
1000 μm, reprinted from ref. [69], with the permission of AIP Publishing.
8 Gao Q H, et al. Sci China Tech Sci

Feng et al. [69] investigated the relationship between [72,88]. More applications of magnetic gravity compensa-
passive levitation stability and the shape of pyrolytic gra- tion in the biological sciences were detailed in the refs. [89–
phite by finite element analysis. Based on the theoretical 91].
analysis, they optimized a star-shaped pyrolytic graphite and
employed it in the microrobot. By adjusting the relative
position between the magnets and the pyrolytic graphite, the 4 Diamagnetically stabilized levitation: Meth-
microrobot was able to convey a microparticle at a relatively ods and applications
high speed (up to 20 mm/s) over a long distance (1000 μm)
(Figure 5(e)). The experiments demonstrated the feasibility Diamagnetically stabilized levitation means the passive le-
of microrobots and their potential in wide practical manip- vitation of a permanent magnet via the diamagnetic materi-
ulations. als. Notably, diamagnetic levitation and diamagnetically
stabilized levitation refer to two different kinds of levitation
3.4 Magnetic gravity compensation mechanisms. The former refers to the levitation of diamag-
netic materials as opposed to a levitated magnet in the latter.
Magnetic gravity compensation refers to the controlled re- Diamagnetically stabilized levitation can be regarded as a
duction of gravity force inside the object, which is not further variant of diamagnetic levitation [51].
equivalent to the definition of levitation [70]. The vertical
diamagnetic force is proportional to the product of the 4.1 Levitation mechanism and configurations
magnitude of the magnetic field B and vertical gradient
δB/δz. One example of the magnetic levitation positions with Several configurations of diamagnetically stabilized levita-
respect to magnetic field B and the field-gradient product tion are illustrated in Figure 6. The basic structure is a
was introduced in ref. [71]. The magnitude and direction of magnet array with alternative poles (opposite-2D magnet
the effective gravity vary continuously, flexibly mimicking array) placed above the diamagnetic material (Figure 6(a)).
hypergravity, hypogravity and inverted gravity environments Besides direct levitation of the permanent magnets, dia-
[72,73]. magnetically stabilized levitation can be realized by in-
With the development of superconductive solenoids and troducing another fixed magnet called the biasing magnet.
high field magnets, magnetic gravity compensation using When the lifting force of the biasing magnet matches the
diamagnetism has paved the way for low-gravity environ- weight of the permanent magnet, a stable levitation can be
ment [70]. Magnetic gravity-compensation technology has obtained within a hollow diamagnetic cylinder (Figure 6(b))
been widely applied in physical and biological sciences. In [45]. As shown in Figure 6(c) and mentioned by Boukallel
the physical sciences, containerless processing technology et al. [92], the levitated magnet can be stabilized by placing
based on magnetic gravity compensation has provided an the diamagnetic material closely below it. Similarly, the le-
alternative for obtaining high-quality products with no con- vitated magnet can be stabilized by placing the diamagnetic
tainer contact [74,75]. Fluid behaviors such as vibrations and materials closely above it (Figure 6(d)). The levitated magnet
oscillations of droplets [76–78], shapes and fissility of dro- receives an upward force from the lifting magnet and a
plets [79,80], influence of hydrodynamic flow on suspended downward force from the diamagnetic material. Equilibrium
particles [81], have also been investigated under the can be achieved when the vector sum of the lifting force,
weightless conditions. Additionally, the investigations on gravity and diamagnetic force is zero. The stable levitation
surface effects in two-phase systems have caught attention interval can be extended by applying double pieces of the
[82,83]. diamagnetic material (Figure 6(e) and (f)). For consistency
In the biological sciences, magnetic gravity compensation with the literature on diamagnetically stabilized levitation,
has been mainly applied in molecular level, cellular level and the two configurations are differentiated by the terms vertical
organism-level studies of microgravity. Biological materials and horizontal [93].
and organisms are levitated by the interaction between the Diamagnetic levitation and diamagnetically stabilized le-
magnetic field and the molecular components, which de- vitation can be combined to produce weight compensated
pends on the average diamagnetic susceptibility of the ma- diamagnetic levitation (Figure 6(g)) [51]. The weight of the
terial or organism [32]. Molecular level researches under floating specimen, including a compensation magnet, a rod,
weightless conditions have mainly focused on gene and and a piece of diamagnetic material, is mainly counter-
protein expressions [84,85]. The altered gene or protein ex- balanced by an attraction of a lift magnet or a ferromagnet.
pressions under reduced-gravity conditions inevitably affect Such a configuration enhances the levitation gap. In addition,
the structures and functions of cells [32,86,87]. Meanwhile, Küstler developed an inline triple-levitation configuration
for living organisms under weightless conditions, the most based on weight-compensated diamagnetic levitation, which
straightforward impact goes to the gravikinetic response simultaneously levitated the magnet and diamagnetic mate-
Gao Q H, et al. Sci China Tech Sci 9

Figure 6 (Color online) Configurations to achieve diamagnetically stabilized levitation of permanent magnets. (a) Levitation of a magnet array over a piece
of diamagnetic material; (b) levitation of a permanent magnet via the stable effect of a hollow diamagnetic cylinder [45]. (c) and (d) Stable levitation of one
magnet by another with one piece of diamagnetic material [92]. (e) and (f) Vertical and horizontal levitation of one magnet with double pieces of diamagnetic
material [93]. (g) Weight compensated diamagnetic levitation [51]; (h) inline triple levitation in diamagnetic levitation [94].

rial as shown in Figure 6(h) [94]. measured the levitation height of the floating magnet. Im-
mersed in the liquid, the floating magnet experienced a
4.2 Sensing and measurement buoyance force. When the lifting magnet was adjusted to
maintain the levitation height of the floating magnet, the
Boukallel et al. [92] designed a force sensor with variable density of the fluid could be obtained. For the viscosity
stiffness based on diamagnetically stabilized horizontal le- measurements, a series of periodic vibrations were exerted
vitation. The sensing part was a levitated cylindrical magnet on the floating magnet in the vertical direction by the ac-
that allowed force measurement in two directions. Abadie tuation coil. The damping effect induced by the surrounding
et al. [95] experimentally investigated a low-frequency na- fluid indicated the feasibility of this setup for viscosity
noforce sensor with two levitating magnets joined by a 10- measurement. They concluded that the viscosity measure-
cm long macroscopic thin capillary as the sensing part, al- ment was strongly affected by squeezing film damping as the
lowing the force measurement along one direction. Within floating magnet was actuated linearly perpendicular to the
certain limits, the displacement of this capillary tube was bottom. To improve the viscosity measurement performance,
proportional to the force. Over the measurement range –50– Clara et al. [97] optimized the viscosity measurement
+50 µN, the mechanical stiffness could be adjusted from method by actuating a spherical floating magnet in rotatory
0.01 to 0.03 N/m. More recently, Billot et al. [35] proposed a oscillations as shown in Figure 7(c). The generated shearing
passive strategy that compensated the low-frequency en- wave could obtain a higher penetration depth than that of the
vironmental disturbance. A protype of the force sensor is traditional resonant sensor.
shown in Figure 7(a). This strategy utilized two force sensors Zhang et al. [98] presented a gas flowmeter that measured
simultaneously, realizing a differential measurement princi- the rotating speed of a diamagnetically levitated magnet
ple that decreased the force estimation error without in- rotor (Figure 7(d)). To decrease the levitating weight and
troducing new types of sensors. enable rotation under a weak gas flow, a round hole was
Clara et al. [96] measured the density and viscosity of fluid formed in the center and three teeth were evenly distributed
using a magnet floated above pyrolytic graphite (Figure 7 along the circumference of the rotor. The measuring range of
(b)). The sensor mainly consisted of an actuation coil, a this prototype was 0.13–1.0 L/min with the linearity of 3.4%.
lifting magnet, a measurement chamber, a floating magnet, a Aydemir et al. [99] developed a passive microflow sensor
piece of pyrolytic graphite plate, and a Hall sensor that based on diamagnetically stabilized magnet levitation as
10 Gao Q H, et al. Sci China Tech Sci

Figure 7 (Color online) Prototypes and schematics of sensors based on diamagnetically stabilized levitation. (a) Nanoforce sensor based on diamagnetically
stabilized horizontal levitation and a differential measurement principle using two force sensors, reprinted from ref. [35], copyright 2016, with permission
from Elsevier; (b) scheme of fluid viscosity and density measurement sensor using a floating magnet actuated linearly above the pyrolytic graphite [96]; (c)
image of a floating magnet excited in rotatory oscillations in an optimized measurement sensor, reprinted from ref. [97], copyright 2016, with permission
from Elsevier; (d) schematic of a flowmeter using a floating magnet with three teeth distributed evenly along the circumference [98]; (e) schematic of a
passive microflow sensor with the measurement range of 1000–7000 μL/min, reprinted from ref. [99], copyright 2019, with permission from Elsevier.

shown in Figure 7(e). The measurement range was between haviour of a diamagnetically levitated bearing, including its
1000–7000 μL/min. transitional and angular vibrations. A dynamic model in-
tegrated with vertical and lateral forces was constructed, and
4.3 Actuating and micromanipulation the governing equation of the motion was simplified by using
the diamagnetic-mirror-image model. Ho and Wang [104]
Hilber and Jakoby [100] exploited diamagnetically stabilized designed an in-plane rotary microgenerator based on dia-
levitation in a miniaturized magnetic membrane actuator magnetically stabilized vertical levitation (Figure 8(b)). Le-
(Figure 8(a)). The floating magnet, integrated in a composite vitated between two plates of pyrolytic graphite, a triangular
membrane of PDMS and NdFeB powder, was levitated configuration of magnets generated voltage by passing
above a piece of pyrolytic graphite. The interaction between through coils placed below the rotor. Their experiments in-
the floating magnet and pyrolytic graphite stabilized the dicated that the induced voltage could be 1.7 mV at a radial
moveable membrane in the vertical direction. The neutral frequency of 21.8 rad/s.
position of the actuating membrane could be tuned by ad- In the absence of friction, wear and surface adhesions,
justing the diamagnetically stabilized levitation. The mem- diamagnetically stabilized levitation has been attractive for
brane was actuated by an integrated coil driven by AC- small and micro-robotic systems. A series of researches on
signal. diamagnetically levitated robots have been carried out. Fig-
Moser and Bleuler [101] presented a rotative positioning ure 8(c) shows the basic schematic of the microrobot [105].
device based on diamagnetically stabilized levitation in The main components included a plate of pyrolytic graphite,
combination with the electrostatic glass actuators. They de- an opposite-2D magnet array and a printed circuit board
monstrated slow and synchronous rotation in the sub-arc (PCB). The magnet array (forming the main part of the mi-
second range. Cansiz and Hull [102] developed a bearing crorobot) was levitated above the pyrolytic graphite and
driven by a tangential jet of nitrogen gas. The rotor weight, actuated by magnetic fields generated by traces in the PCB.
compensated by a ferrite ring-shaped lift magnet, was levi- Figure 8(d) plots the simulated forces generated by the ser-
tated between two pieces of bismuth plates. Their spin-down pentine traces, manifesting that the robot could be approxi-
measurement experiments attested that the rotational losses mated as sitting in a parabolic potential well [34]. The planar
varied with the frequency due to eddy currents. Later, Cansiz motion of the microrobot was driven by a magnetic wave
[103] investigated the static characteristic and dynamic be- pattern generated by two-layer phasing of the currents, while
Gao Q H, et al. Sci China Tech Sci 11

Figure 8 (Color online) Representatives of actuating devices based on diamagnetically stabilized levitation. (a) Schematic of a membrane actuator along
with each layer of the device prior to the adhesive bonding step [100]; (b) photograph of an electric generator with the enlarged images of a triangular
configuration magnets rotor, reprinted from ref. [104], with the permission of AIP Publishing. (c)–(e) Microrobots using diamagnetically stabilized levitation.
(c) Schematic of the diamagnetically levitated microrobot actuated by the magnetic field generated by PCB [105]; (d) simulated forces (Fx, Fy, Fz) generated
by the serpentine traces, reprinted by permission from ref. [106], copyright 2018 Springer Nature; (e) multi-agent systems using diamagnetically levitated
robots: one microrobot carried the syringe and the other microrobot actuated the plunger, © 2017 IEEE, reprinted, with permission, from ref. [107].

the vertical motion was excited by the current amplitude in-plane rotation of 3500 deg/s.
[105]. Pelrine conceptualized a massively parallel robotic
system that simultaneously levitated 130 microrobots as 4.4 Energy harvesting
2
small as 1.7 mm with the density up to 12.5 robots/cm
[106]. More recently, the same research team developed Diamagnetically stabilized levitation has provided a platform
multi-agent systems using diamagnetically levitated micro- for the design of energy harvesters in low-frequency
robots [107]. Several levitated microrobots cooperated in broadband spectra. Liu and Yuan [112,113] presented a
partial completion of complex tasks, such as controlling the nonlinear vibration energy harvester based on diamagneti-
plunger for a syringe tube (Figure 8(e)). The basic dia- cally stabilized vertical levitation, and performed a series of
magnetically levitated robots were also employed in 2D and theoretical analyses. This system harvested electricity and
3D micro-assembly [34,108]. Various types of parts could be stabilized the levitation of a permanent magnet by two spiral
transferred with high precision, including silicon-on- bismuth coils. Later, Wang et al. [114] designed and fabri-
insulators wafers with surface coatings or individual carbon cated a nonlinear electromagnetic vibration energy harvester.
fibers, and biochemical nanoliter fluid [109,110]. Light- The schematic of this harvester is shown in Figure 9(a). The
weight end effectors combined with force-compatible micro- weight of the floating magnet was balanced by a lifting
processes were integrated into diamagnetically levitated ro- magnet, and the levitation was stabilized by two pieces of
bots for 3D micro-assembly tasks such as assembling mi- pyrolytic graphite plates. Mechanical energy was converted
crospheres, grasping and liquid deposition [34]. More into electrical energy by two thick cylindrical coils placed in
recently, additional rotational rather than translational de- grooves engraved in the pyrolytic plates. Palagummi and
grees-of-freedom were imparted by applying repulsive for- Yuan [115] parametrically optimized the design based on the
ces on the multipole magnetic robots and changing the center thin-coil model for magnetic forces analysis, and calculated
of rotation [111]. Experimental results confirmed a dynamic the diamagnetic force by the discrete volume method. The
12 Gao Q H, et al. Sci China Tech Sci

Figure 9 (Color online) Schematics of energy harvesters based on diamagnetically stabilized levitation. (a) Vibration energy harvester based on dia-
magnetically stabilized vertical levitation [114]; (b) monostable vibration energy harvester using diamagnetically stabilized horizontal levitation [116]; (c)
bistable vibration energy harvester using diamagnetically stabilized horizontal levitation [33].

levitating magnet vibrated along the vertical direction when corporated into sensor and actuator designs, such as optically
the base was subjected to a harmonic excitation. A root mean driven actuator using the photothermal effect [118], elec-
square (RMS) power output of 1.72 μW could be harvested trostatic-field driven rotor [52], and gas flowmeter [98].
at a frequency of 2.1 Hz under a peak acceleration of Frenkel et al. [119] demonstrated that diamagnetic particles
2
0.081 m/s . Theoretical analysis and experimental results floating on diamagnetic fluids could be actuated by a per-
confirmed the suitability of the device for energy harvesting manent magnet, which was induced by interfacial phenom-
in a low-frequency ambient environment. Nevertheless, in ena related to the hysteresis of the contact angle. Actuating
energy harvesters based on the diamagnetically stabilized diamagnetic materials by this approach is potentially useful
vertical levitation, the motion of the floating magnet in the for exploiting the properties of fluid [120,121]. Potential
vertical direction may be restricted by the structure. To avoid applications could be further diversified but not limited to the
this limitation, energy harvesters based on diamagnetically optimization of existing techniques. For example, a fully
stabilized horizontal levitation were presented, and the biocompatible transporting method was tested in the mag-
schematic is illustrated in Figure 9(b) [93,116]. The weight netic transport of lipid-coated HOPG in NaCl aqueous so-
of the floating magnet was counteracted by the attractive lution, which demonstrated the potential applicability in the
forces from the lifting magnets at right and left sides. The biomedical domain [122]. Moreover, the strong diamagnet-
levitation was stabilized by symmetrically arranged pyrolytic ism and unique anisotropic optical property of graphene
graphite. To broaden the operating bandwidth and enhance flakes could be combined in many other applications, such as
the amplitude of the floating magnet, a bistable system was 3D patterning techniques [59] and the control and alignment
incorporated into the design of the vibration energy har- of other low-dimensional nanomaterials [123].
vesters [33,117]. The bistable magnetic potential well could Diamagnetically stabilized levitation has offered a unique
be constructed from strategically placed multiple magnets, capability of multiple magnets simultaneous levitation in the
increasing the vertical range of the floating-magnet vibra- vertical and horizontal configurations [106,124]. Future di-
tions (Figure 9(c)). rections for diamagnetically stabilized levitation might in-
volve multi-agent operations, which are being increasingly
enriched with multi-functionality. Combined with machine
5 Summary and outlook vision or optimized end effectors, multi-agent operations
with adaptability and self-repair ability could be utilized in
Magnetic levitation using diamagnetism is a rising and sensing, scanning, surface topography inspection, or micro-
powerful tool that has inspired multiple research endeavors. manipulations [108].
In this work, we focus on the recent advancements in mag- One of the most important technical challenges of mag-
netic levitation using diamagnetism and elucidate the key netic levitation using diamagnetism is the electromagnetic
mechanisms underlying each research subarea. A systema- eddy current damping, as the most commonly used dia-
tical review is presented with the emphasis on the burgeon- magnetic materials (pyrolytic graphite or HOPG) are not
ing applications, ranging from sensing and measurement, only strongly diamagnetic, but also good conductors. Eddy
actuating and micromanipulation to magnetic gravity com- current damping, generated by the relative motion between
pensation and energy harvesting. the permanent magnet and the conductor, may have an im-
Future directions for diamagnetic levitation could involve pact on the precision and trajectory repeatability.
the optimization of existing magnetic field arrangement and
levitation mechanism for improving the carrying capacity This work was supported by the Innovation Program of Shanghai Municipal
and levitation height. More explored stimuli could be in- Education Commission (Grant No. 2019-01-07-00-02-E00030), the Na-
Gao Q H, et al. Sci China Tech Sci 13

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