Professional Documents
Culture Documents
net/publication/280095184
CITATIONS READS
0 1,976
3 authors:
Farshad Barzegar
University of Pretoria
45 PUBLICATIONS 842 CITATIONS
SEE PROFILE
Some of the authors of this publication are also working on these related projects:
Hybrid asymmetric capacitor based on cobalt phosphate-graphene foam composite with enhanced capacity and long-life cycle View project
Synthesis and characterization of Ni(OH)2 carbon-based nanomaterials for supercapacitor application View project
All content following this page was uploaded by Morteza Ranjbar on 31 March 2016.
Abstract Introduction
The discovery of high temperature Superconductivity is a striking and fascinating
superconductor YBCO (Yttrium barium field of physics. Scientists and engineers
copper oxide) opened up a new class of throughout the world have been determined to
applications in technology. To name one, these develop an understanding of this interesting
technologies, the levitating train operating at phenomenon for many years. This
speeds exceeding 500 km/h. To study the phenomenon occurs in certain materials
efficiency and improvement of magnetic generally at low temperatures, characterized
levitation train, high temperature by exactly zero electrical resistance and the
superconductor YBCO samples were prepared expulsion of the interior magnetic field. The
by using the standard solid state reaction latter property which makes the
method. The critical parameters such as TC, JC, superconductor exhibit perfect diamagnetism,
and HC were measured in our samples. The is called Meissner effect [ 1], Ashcroft and
1
resistivity and critical temperature (TC) Mermin have a nice, not too technical
measurements were undertaken using the discussion of this property in one of the last
standard four-point probe method with an AC chapters in their textbook [ 2].The zero 2
lock-in technique and a PC data acquisition electrical resistance property which deals with
system. To measure critical current density the flow of charged particles (electron pairs)
(JC), a Vibrating Sample Magnetometer without dissipation, combined with the
(VSM) was used, and critical magnetic field discovery of high-temperature
(HC) was calculated by theoretical work. The superconductors (HTS) in and after 1986 [ 3], 3
induced between the magnets are used to the vehicle itself but rather in the guide way. It
propel the vehicle (superconducting magnet). functions on the same principal as a tradition
The propulsion coils located on the sidewalls rotating electrical motor who stated has been
on both sides of the guideway are energized by cut open unrolled and stretched lengthwise
a three-phase alternating current from a along both sides of the guideway. But instead
substation, creating a shifting magnetic field of a rotating magnetic field a travelling magnet
on the guideway. The on board field is generated in the windings one that
superconducting magnets are attracted and paused the vehicle along the guide way
pushed by the shifting field, propelling the without contact. Although not part of the
Maglev vehicle figure 3. present Transrapid design, superconducting
magnets can be incorporated in attraction-type
maglev systems [ 21-23] figure 4.
13
transrapid guideway can therefore be adapted on sample processing for the fabrication of
to the landscape instead of the other way high quality superconductors [ 24-29]. Most
14
around. The operation control system controls attention in this arena has been on the (YBCO)
and safe guards the vehicles, switches, superconductor in order to optimize the purity
guideway and stations along the maglev rout. of the superconducting phase.
The vehicles location is monitored by means Among the three most common methods for
of a location reference system integrated into the preparation of YBCO samples involved the
the guide way. The only motor section in fabrication of a pressed polycrystalline disc,
operation along the guideway is the one in flux growth of single crystals [28, 30] and 15
which the vehicle correctly travelling. When melt-textured growth (MTG) crystal [ 31-33], 16
the vehicle passes from one section to the next the pressed disc polycrystalline YBa2Cu3O7-
the new motor section is automatically (Y123) and Y2BaCuO5 (Y211) samples were
switched on. Non contact technology makes chosen and prepared by using the standard
the transrapid very fast. It is designed for solid state reaction method [ 34]. This method
17
operating speed at between three hundred and allows off-the-shelf high purity chemicals to
five hundred kilometers per hour. This enables be processed into ceramic, polycrystalline
trip times on a media along distances which materials. The phase diagram of YBCO using
have until now only that achieved by aircraft. the base compounds Y2O3, BaO and CuO is
For obtaining higher efficiency and shown by the work of Taylor et al [ 35], where
18
The samples are mounted on a sample holder stainless steel dewar. A computer records data
which is a 16 pin DIL package supplied by from the lock-in amplifier (Stanford SR 530)
SPECTRUM Semiconductor Material, INC. and magnet hall probe. A reference voltage is
This type of sample holder is very useful as it normally taken from the vibrator supply,
allows the sample wires to be connected with although, it can be taken from the reference
the aid of a standard binocular microscope. To coil. Sweep rates regarding applied field can
make sure that there is no electrical contact be varied from 0.0004 T/min. to 2 T/min.
between sample and sample holder, a very thin Calibration of the magnetic moment as a
layer of mica, which is a good thermal function of sensor voltage was performed at
conductor and electrical insulator, is used. room temperature and 77 K using a pure nickel
Thermal paste (zinc oxide) is used to attach the sphere of known magnetic saturation. A nickel
sample to the sample holder. Utilizing the sphere of weight 0.310g was attached to the
thermal paste reduces the time delay for fiberglass rod by superglue and vibrated at 27
thermal equilibrium of the system. Current and Hz. The applied field (magnetising field) was
voltage wires are connected directly onto the ramped to 1 Tesla at 0.4 T/min. then ramped
sample surface, or onto evaporated silver pads, down again to zero. This procedure was
using colloidal silver. Contact resistance is repeated after reversing the current polarity to
estimated to be less than 0.1 ohm. The sample the magnet. The resulting pick-up coil voltages
holder is then gently pushed into the DIL were used for the calibration constants, after
socket attached to the base (cold finger). correcting for the variation of the saturation
Measurements were performed from 10 to 300 magnetisation of nickel with temperature, (5%
K with an accuracy of 0.1 K at a frequency of increase at 77 K) [ 39].
22
magnetic field is related to the vector equation 43]. However, additional information on
B = 0 (H + M) (1) calibration and design of Vibrating Sample
where H is the magnetic field strength in A/m, Magnetometers which we used in this
0 is the permeability of free space (4 10-7 investigation can be found in references [ 44- 25
boundaries associated with the different 2212 were broken more easily than the Cu–O
crystallographic orientations. chains because the bond energy of Bi–O
chains is lower than that of Cu–O [ 58]. 30
0.0006
Since the resistivities depend on the electron
0.0005
contribution only, and the thermal
conductivities may be separated into phonon
and electron contributions ph and e an
0.0004 Polycrystalline (Y123)
Oxygen 6.96
Resistivity (Ohm-cm)
Temperature (K)
The use of the VSM allows samples to be
Fig. 5 Resistivity curve for the polycrystalline Y (123) sample measured under different applied field
containing oxygen contents 6.96 orientations. Samples measured using the
VSM equipment were secured to the sample
According to the Figure 3.1 the rod by „superglue‟. Measurements can be
superconducting transition temperature Tc, for made for two sample orientations, Ha c-axis
polycrystalline Y123 sample is sharp enough and Ha ab-plane for single and melt-texture
and clear. Tc value is taken from where an crystals, but only data for polycrystalline
extrapolation of the superconducting transition independent of axis are reported due to the
intercept the zero axis, the foot of curve is not requirements of our concentration on magnetic
considered. This value is 91.0K from levitation train. M-H hysteresis loops were
resistivity and 87.5 K from thermoelectric performed at 77 K in applied fields to 1.1 T
power [ 56] for sample with oxygen content
28
oxygen content 6.96. The present VSM system Table 1 The value of constant parameters with the errors
related to the fit curve of critical current density for
is only suitable for relatively high oxygen polycrystalline YBCO.
content samples. Therefore, in the case of the Parameters Constants Absolute Relative
polycrystalline samples only the over doped Errors Error (%)
y 0 0 0
sample with oxygen content of 6.96 is 0
reported. All the measurements were X0
0 0 0
performed under zero field cooling (ZFC) 552.25113 22.45971 4.06694
conditions at the same sweep rate. The zero A1
t1 0.05182 0.00518 9.99614
field Jc value for polycrystalline YBCO 202.21156 20.93632 10.35367
sample is very low (754.5A/cm2) in A2
t2 0.53116 0.05962 11.22449
comparison with the other samples due to the
large number of grain boundaries. For MTG
(Nd/Y)BCO (Neodymium/Yttrium barium The shape of critical current density Jc versus
the applied magnetic field and its fit curves
copper oxide) crystal are 2 larger than those
related YBCO polycrystalline are consistent
obtained for the YBCO single crystal, but
with the data reported for thin film single
almost 2 smaller than the MTG (Y123)
crystal YBCO when the field was oriented
value, the last result being affected by the
perpendicular to c axis at 77K [ 61,62]. It is
33
POLY
2
400 Fit
[ 63, 64]
34
0
200 BP 1.84TC (4)
2 B
Here, B is the Bohr magneton. This limitation
0
-0.1 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1
of the superconducting state is also referred to
Applied field (T )
as the “Clogston-Chandrasekhar limit” or the
Fig. 6 VSM data for polycrystalline (Y123) sample, showing “paramagnetic limit”. In the case of strong
critical current density JC and its fit versus applied magnetic coupling between the electron spin and the
field Ha.
orbital angular momentum, this limit can even
be strongly increased. Due to our
The fit curve of Jc values is related to an
superconductor with a transition temperature
exponential decay with the following formula;
91K, we obtain a value of ≈167.5T for critical
field Bp from Eq. (4).
J C y0 A1e[ ( X X 0 ) / t1 ] A2e[ ( X X 0 ) / t2 ] (3) On the other hand from a reversible Meissner
effect it turns out that superconductivity will
The value of constant parameters with the be destroyed by a critical magnetic field Hc
errors for this fit equation (3) is given by the which is related thermodynamically to the
next table (table 1). free-energy difference between the normal and
superconducting states in zero field. This is
called the condensation energy of the
superconducting state. The critical field is
related to temperature and the relationship
National Conference on Mechanical Engineering
between Hc and T is given by the following Ha (magnetic field) at 77K are related to an
formula; exponential decay curve. However, the value
T of JC is low, and instead of polycrystalline,
H C (T ) H C 0 1 ( ) 2 (5) using high quality melt-texture and single
Tc
crystalline materials is needed to improve JC
Where HC0 is the critical field at zero and consequently superconducting state in
temperature and HC (T) is the critical field at maglev train systems.
temperature T. Therefore, not only it is
possible to convert a material from the Suggestions
superconducting state to the normal state by New applications of superconductors will
raising its temperature but also by applying a increase with critical temperature. Liquid
certain strength of magnetic field to it. Welp et nitrogen based superconductors has provided
al. [ 65] reported H C 2 (0) ≈130T for YBCO
35
6- V´elez, M., Mart´ın, J.I., Villegas, J.E., Hoffmann, A., 24-Xiao, G., Streitz. F. H., Gavrin. A., DU, Y.W. and
Gonzalez, E.M., Vicente, J.L., and Schuller, Ivan K., Chien. C.L., Phys. Rev. B 38 (1987) 8782.
2008 J. Magn. Mater. 320, 2547–62. 25-Frank, J. P., Jung, J. and Mohamed, M. A. K., Phys.
7- Aladyshkin, A., Silhanek, A.V., Gillijns, W., and Rev. B. 36(1987) 2308.
Moshchalkov, V.V., 2009. Supercond. Sci. Technol. 26-Matthews, D. N., Bailey, A., Vaile, R. A., Russell, G.
22, 053001. J. and Taylor, K. N. R., Nature 328 (1987) 786.
8- H¨anggi, P., and Marchesoni, F., 2009 Rev. Mod. 27-Jorgenson, J. D., Beno, M. A., Hinks, D. G.,
Phys. 81, 387. Soderholm, L., Volin, K. J., Hitterman, R. L., Grace,
9-Schrieffer, John Robert. “Theory of J. D., Schuller, I. K., Segra, C.U., Zang, K. and
Superconductivity”. New York, Benjamin/Cummings, Kleefisch, M.S., Phys. Rev. B 36 (1987) 3608.
(first edition 1964), 332 pgs., 1983 ISBN: 0-8053- 28-Hunter, B. A., Town, S. L., Matthews, D. N., Russell,
8502-9. G. J. and Taylor, K. N. R., Aust. J. Phys. 44 (1991)
10-Kresin, Vladimir., and Wolf, Stuart., “Fundamentals 421.
of Superconductivity”. New York and London 29-Ito, T., Takenaka, K. and Uchida, S., Phys. Rev. Lett.
Plenum Press. 1990. 70 (1993) 3995.
11-Cyrot, Michel., and Davor Pavuna., “Introduction to 30-Balestrino, G., Barbanera, S. and Parolia, P., J.
Superconductivity and High-Tc Materials”. Crystal Growth 85 (1987) 585.
Singapore, World Scientific, 1992. 31-Matthews, D. M., Cochrane, J. W. and Russell, G. J.,
12-Bourdillon, A., and Bourdillon, Tan. N. X., “High Physica C 249 (1995) 255.
Temperature Superconductors: Processing and 32-Mahmoud, A. S., and Russell, G. J., Supercond. Sci.
Science”. San Diego, Academic Press, Inc., 1994. Technol. 11, (1998) 1036.
13-Chu, C. W., Chu, W. K., Hor, P.H., and Salama, K., 33-Mahmoud, A. S., and Russell, G. J., presented at the
“HTS Materials, Bulk Processing, Bulk 23th meeting of Condensed Matter Physics Meeting,
Applications”. Proceedings of the 1992 TCSUH Wagga-Wagga NSW, Australia, and 3-5 Feb., 1999.
Workshop, Houston, Texas, World Scientific 34-Costa, C. A., Ferretti, M., Olcese, C. L., Cimberle, M.
Publishing Company, 1992. R., Ferdeghini, C., Nicchiotti, G. L., Siri, A. S. and
14-“Nature” (1995) 373, 319. Rizzuto, C., J. Cryst. Growth 85 (1987) 623.
15-Consortium of European Companies for 35-Taylor, K. N. R., Russell, G. J., Harris, L. B., Vaile,
18
Superconductivity Use, (Conectus, 2007). R. A., Cochrane, J., Matthews, D. N., Puzzer, T., Sun,
16-Brandt, E. H., “Rigid levitation and suspension of H. B., Bailey, A., Bosi, S. and Larobina, M., J. Mod.
high-temperature superconductors by magnets” 1990 Phys. B1 (1987) 196.
Am. J. Phys. 58 43. 36-Cochrane, J. W., Ph.D. Thesis, School of Physics, The
17-Weh, H., Pahl, H., Hupe, H., Steingaver, A., and May, University of New South Wales, Australia (1997).
H., “High Tc superconductor‟s calculation model and 37-Smith, D. O., Rev. Sci. Inst. 27 5 (1956) 261.
possible Maglev applications”. 1995, 14th 38-Foner, S., Rev. Sci. Inst. 30 7 (1959) 548.
International Conference on Magnetically Levitated 39-“American Institute of Physics Handbook”, 2nd ed.
Systems and Liner Drives (Maglev .95), pp 217-222. Pub. McGraw-Hill, New York (1963).
18-Ohsaki, H., Kitahara, H., and Masada, E., “Magnetic 40-Hattori, K., Saito, A., Takano, Y., Suzuki, T.,
levitation systems using a high-Tc superconducting Yamada, H., Takayama, T., Kamitani, A., and
bulk magnet”. 1995 Ibid, (Maglev. 95), pp 203-208. Ohshima, S., “Detection of smaller Jc region and
19-Wang, S. Y., Wang, J. S., and Lian, J.S., “High damage in YBCO coated conductors by using
temperature superconducting Maglev”. February permanent magnet method”, 2011 Physica C,
1997, Cryogenics and Superconductivity, vol. 25 (1), doi:10.1016/j.physc.2011.05.117.
pp. 17-22. 41-Nguyen, D.N., Sastry, P.V.P.S.S., Knoll, D.C., and
20-Randy, Simon., and Smith, Andrew., Schwartz, J., IEEE Trans. Appl. Supercond. 19 (4)
“Superconductors Conquering Technology‟s New (2009) 3637.
Frontier”, chapter 8. 42-Jiang, Z., Staines, M., Badcock, R.A., Long, N.J., and
21-Nakashima, H., and Isoura. K., “Superconducting Amemiya, N., Supercond. Sci. Technol. 22 (2009)
Maglev Development in Japan”. 1998, Proceedings of 095002.
the 15th International Conference on Magnetically 43-Thakur, K.P., Jiang, Z., Staines, M.P., Long, N.J.,
Levitated Systems. (Maglev .98), pp 25-28. Badcock, R.A., and Ashish Raj “Current carrying
22-Terai, M., Inadama, S., Tsuchishima, H., Suzuki, E, capability of HTS Roebel cable” Physica C 471
and Okai, T., “Development of New Superconducting (2011) 42–47.
Magnets of the Yamanashi Test Line”. 1995, 44-Zieba, A. and Foner, S., Rev. Sci. Inst. 53 9 (1982)
Proceedings of the 14th International Conference on 1344.
Magnetically Levitated Systems (Maglev .95), pp. 45-Case, W. E. and Harrington, R. D., J. Research of
267-273. National Bureau of Stand. C 70 4 (1966) 255.
23-Shudo, T. et al., “Study on Vibration Phenomena of 46-Dwight, K., Menyuk, N. and Smith, D., J. Appl. Phys,
Superconducting Magnets for Maglev”. June 1997 29 3 (1958) 491.
IEEE Trans. On Applied Superconductivity, vol. 7, 47-Bowden, G. J., J. Phys. E: Sci. Inst. 5 (1972) 1115.
No. 2, pp. 932-935. 48-Gurvitch, M. and Fiory, A. T., Phys. Rev. Lett. 59
(1987) 1337.
National Conference on Mechanical Engineering