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Eion M. Cameron
Introduction
The principal consumers of exploration geochemistry data are the project geologists
who run exploration programs worldwide. Some of these geologists have been discour-
aged from interpreting data employed in the search for deep deposits by explanations
for the upward migration of elements that verge on the mystical. Or by approaches to
interpreting geochemical plots that appear to derive from the precepts of Hermann Ror-
schach. However, many of the anomalies studied during this project have a clear struc-
tural connection. Of all the persons likely to be involved in the interpretation of data, it is
the project geologist who is best informed on the local structural setting, and he or she
is the person who must take the lead role in placing the data in geological context.
The following pages give most attention to the porphyry belt of northern Chile, where
anomalies are being formed at the present day, as a result of neotectonics and active
seismicity. At Mike, Nevada, there is also a correlation between anomalies and late
structures. In the Abitibi clay belt, structure does not appear to play an important part in
the formation of surface anomalies.
RR
R
n ce
Sp e
R RR
Figure 2. Satellite image of the area of the Spence deposit, north to the top. The white area of the salar can be seen. The high-
way (R) between Antofagasta and Calama passes over the southeast quadrant of the deposit. Other similarly-orientated lines
nearby are aqueducts. The railway (RR) is to the east. The sampling traverse across the deposit is shown by the red line.
Figure 3. Typical west-east section across the northern part of the Spence deposit, this one at 7481500N. Modified from a
section provided by RioChilex.
Page 4
Conductivity of soil-water slurry, µs 8000
6000 Eastern
Deposit
Fracture Fracture
Zone Zone
4000
2000
0
473500 474000 474500 475000 475500 476000
East, m
Figure 4. Conductivity of soil-water slurries from samples collected at 10-20 cm depth on the west-east traverse at
7480500N. The conductivity measures the quantity of water-soluble salts, mainly NaCl, present in the samples. Area
underlain by the deposit shown by the yellow rectangle in this and following figures.
14000
12000
10000
Cu MMI, ppb
8000
6000
4000
2000
0
473500 474000 474500 475000 475500 476000
East, m
Figure 5. Copper by MMI for soil samples collected at 10-20 cm depth on the west-east traverse at 7480500N.
Page 5
160
120
Mo Enzyme Leach, ppb
80
40
0
473500 474000 474500 475000 475500 476000
East, m
Figure 6. Molybdenum by Enzyme Leach for soil samples collected at 10-20 cm depth on the west-east traverse at
7480500N.
Figure 7. Location of trenches dug along Line 7480500, with frequency of vertical fractures in gravel.
Page 6
Figure 8. Vertical fracture in gravel, Spence deposit. Rucksack and GPS meter for scale.
west (Figure 7). In this there were no east-west fractures and only one north-south frac-
ture in 5 m of east-west trench. The final set of trenches was dug in the soils over the
Eastern Fracture Zone. These showed the highest frequency of north-south fractures, at
two per horizontal meter. The frequency of east-west fractures is less, at 0.5 per hori-
zontal meter. In summary, the trenching showed evenly-spaced east-west and north-
south fractures in the gravels of the Deposit Fracture Zone, a high frequency of north-
south fracturing in the Eastern Fracture Zone and only one fracture in a area of back-
ground geochemical values. There is a correlation between fracturing and geochemical
anomalies.
Figure 9. Gaby Sur, looking west. The deposit lies under the flat, gravel pampa in the foreground and middle ground.
Photo courtesy N. O’Brien.
In 1999 soils were sampled along a west-east traverse across the deposit. Samples
were taken at 50 m intervals over the deposit and 100 m intervals on the peripheries.
Over both boundary faults there are sharp “spikes” for Na (Figure 10), indicative of seis-
mic pumping of saline groundwater up these basement faults and through the gravels.
Given the presence of calcrete in the upper 20 m of gravel there was a need for re-
peated recent movements along these faults to fracture the calcrete-indurated gravels to
permit upward movement of groundwater. Fractured gravels can be observed in soil pits
and bulldozer trenches. The samples that show anomalous “spikes” of Na also contain
high contents of Cl, Se, I, Cu, Mo, Re and As. The data for Cu are also shown in Figure
10, which shows “spikes” coincident with those for Na.
80
Cu Enzyme Leach, ppb
60
40
20
0
10000
8000
Na Enzyme Leach, ppm
6000
4000
2000
Gravel
lt
au
au
Porphyry
yF
yF
ar
ar
nd
d
un
ou
Bo
tB
st
s
We
Ea
Figure 10. East-west cross section of the Gaby Sur deposit along line 7412500N showing the
relationship between anomalies for Na and Cu by Enzyme Leach to the underlying geology.
Page 9
of these being 50 m on the west side of the West fault, but several
hundred meters on the east side of the fault.
This is a disturbed area, and the extent of the sampling traverse is
limited. Strongly anomalous “spikes” for a variety of elements (Na,
Cl, Se, I, Br, Re, Mg, K, Rb, Tl, Ni, Cs, Ba, Tl and Mg) occur in soils
directly above the fault, or close by (Mo, Mn, Zn, Cd, W and Sb).
For many elements, soil anomalies are one to two orders of magni-
tude greater than those at Spence or Gaby Sur. The factors by
which anomaly maxima at Mansa Mina are greater than maxima at
Spence for Enzyme Leach analyses include: Re (77), Mo (61), Tl
(20), K (16), Se (15) and Rb (8). These are elements that are char-
acteristic of molybdenite-rich ore associated with quartz-sericite al-
teration, which is well developed at Chuquicamata and possibly
also at Mansa Mina. All are highly mobile anions or cations that can
travel long distances in groundwater. It is possible that they derive
mainly from Chuquicamata, 5 km up gradient. Given the size of
Chuquicamata, dissolved elements from this up-gradient source
may have overwhelmed the flux from Mansa Mina. Copper, which
has a restricted range for migration, and is thus a better indicator of
a proximal source of oxidizing porphyry mineralization, is less
strongly enriched in the soils above the deposit and West fault than
Re, Mo and Se, with a ratio of maxima 2.3 times greater than that
at Spence.
Figure 12 shows the strong spike for Cl, directly above the West
fault. Despite the hyperaridity, it does rain in the Atacama Desert,
there being a heavy rainfall in the Calama area, including Mansa
Mina, in the early part of 2001, which washed out bridges. Soluble
salts, such as NaCl, are removed from the upper soil horizons by
successive heavy rains, so that the strong spike for Cl shown in
Figure 12 must represent recent movement of saline groundwater
to the surface. The spike for Mo by aqua regia (Figure 13) is dis-
placed about 65 m east from the Na spike. As shown for the
Figure 11. The Chuquicamata cluster of Spence deposit (Hall and Cameron, 2001), Mo accumulates in the
porphyry copper deposits immediately upper part of soil profiles in a form that dissolves only in aqua regia.
north of Calama. This form is stable to rainfall and the different locations for the Mo
and Na spikes may represent a shift over time in the near-surface
fracture patterns for the West fault, that for Na being most recent.
Page 10
16000
Cl Enzyme Leach, ppm
12000
8000
4000
Figure 12. Chloride by Enzyme Leach along a soil traverse across the Mansa Mina deposit and West fault.
Page 11
30
Mo Aqua Regia, ppm
20
10
0
508600 508700 508800 508900 509000 509100 509200 509300
Figure 13. Molybdenum by aqua regia along a soil traverse across the Mansa Mina deposit and West fault.
Page 12
2.0
1.6
Channel B
1.2
Channel A
0.8
0.4
0.0
Figure 18. Plot of cadmium by aqua regia in soil samples along Line 3 at Mike. Horizontal scale in feet.
18
15
Au Aqua Regia, ppb
12
Figure 19. Plot of gold by aqua regia in soil samples along Line 3 at Mike. Horizontal scale in feet.
Page 16
60
50
Cu Aqua Regia, ppm
40
30
20
10
Figure 20. Plot of copper by aqua regia in soil samples along Line 3 at Mike. Horizontal scale in feet.
Average Flow
SEISMIC PUMPING
Interseismic Period:
Fractures Open,
Drawing In Water
21), the increases continuing for several weeks through dry weather (Muir-Wood, 1994).
The Kern County, California, magnitude 7.5 earthquake of July 1952 involved left lateral
reverse slip. It occurred in the summer and was followed by two months with negligible
precipitation. There were outpourings of groundwater in the vicinity of the rupture and
increases in spring flow and well water level, which continued for two months, up to 130
km from the epicentre (Briggs and Troxell, 1955).
Seismic pumping is a repetitive phenomenon, involving strain cycling. During inter-
seismic crustal extension, fractures, which are ubiquitous through the brittle crust, dilate,
drawing in fluid. During an earthquake, the stress field changes to compression and the
fractures collapse, expelling water (Figure 22). The water migrates to the nearest fault
that provides access to an area of lower pressure, usually the surface. Basement rocks
are usually of low permeability, thus it takes time for water to reach the fault, hence the
continuous effusion of water at the surface for periods of weeks or months following the
earthquake. The volumes of rock that undergo dilational collapse are centred around the
earthquake focus, usually several kilometers deep. At these depths, waters expelled are
generally saline, but may mix near-surface with waters of lower salinity.
A conceptual model for the development of surface anomalies at Spence by seismic
pumping is shown in Figure 23. It needs to be emphasised that it is a phenomenon re-
lated to faults that penetrate several kilometers into the basement; near-surface waters
are only incidentally involved. Waters in the gravel aquifer upflow (east) of the deposit
are relatively fresh (Leybourne and Cameron, 2000a); the salinity of the soils above the
fracture zones derives from waters moving up from the basement. During this upward
movement waters in contact with the mineralization and waters in the gravel aquifer will
mix with the deeper waters and be carried to the surface.
If the Atacama Desert were not hyperarid, there would not be even temporary preserva-
tion of NaCl at the surface; heavier rainfall and recharge would return the NaCl to the
groundwater. Thus connecting the anomalies to seismic pumping would be less appar-
ent. There is no evidence to suggest that the anomalies at Mike are due to seismic
pumping. In part this is because NaCl would not be retained at the surface in the semi-
arid climate of Nevada. But also, structural geology studies would have to show that the
Page 19
Figure 23 Conceptual model of the Spence area showing the development of surface anomalies by seismic pumping.
faulting of the Carlin Formation identified by Dohrenwend and Moring (1991) are con-
tinuous into the basement.
References
• Briggs, R.C. and Troxell, H.C., 1955. Effect of Arvin-Techapi earthquake on spring and stream flow.
In: Earthquakes in Kern County, California, During 1952. Calif. Div. Mines Bull. 171: 81-98.
• Cameron, E.M., 1998. Deep-Penetrating Geochemistry. CAMIRO Report. 117 pp.
• Cuadra, P.C. and Rojas, G.S., 2001. Oxide mineralization at the Radomiro Tomic porphyry copper
deposit, Northern Chile. Econ. Geol. 96: 387-400.
• Dohrenwend, J.C. and Moring, B.C., 1991. Reconnaissance photogeological map of young faults in
the Winnemucca 1o by 2o quadrangle, Nevada. United States Geological Survey. Miscellaneous
Field Studies Map MF-2175.
• Hall, G.E.M. and Cameron, E.M., 2001. Comparison of selective extractions in soils over the Spence
deposit, Chile. Part A: Sequential extractions of a soil profile. CAMIRO Deep-Penetrating Geochem-
istry, 15 pp.
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Part A—Major elements and stable isotopes. CAMIRO Deep-Penetrating Geochemistry, Phase II,
18 pp.
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Part B—Metals associated with supergene copper mineralization. CAMIRO Deep-Penetrating Geo-
chemistry, Phase II, 14 pp.
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