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Combustion:
If there are several gases are mixed in a chamber, we can calculation the
some characterize composition as:
Ni N
i n i ,
N1 N 2 ....... N n
Ni i 1
(2.1)
where , N : number of moles
mi m
Yi n i (2.2)
m1 m2 ....... mn
mi i 1
Note : the sum of all the constituent mole or mass fractions must be unity,
or :
n n
i 1
i 1 , Y 1
i 1
i (2.3)
Then, the relationship between mass fraction and mole fraction as:
MWmix MWi
i Yi & Yi i (2.4)
MWi MWmix
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Chapter Two Fundamental of combustion Fuel & Energy Department
or
(2.5)
1
MWmix n
Yi
i 1 MWi
Pi i . PTotal
and (2.6)
R
Pi i Ti
MWi
i Yi mix
or (2.7)
n
mix Yi i
i 1
Note: for ideal gases mixture, many mass (or molar) specific mixture
properties are calculated as:
n
hmix Yi hi (2.7)
i 1
The enthalpy to be formed from two parts : sensible and chemical parte
as:
T
hi Cpi dT h of ,i (2.8)
To
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Chapter Two Fundamental of combustion Fuel & Energy Department
n
Cpmix Yi .Cp i (2.9)
i 1
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Chapter Two Fundamental of combustion Fuel & Energy Department
In a premixed combustor, fuel and oxidizer are mixed before they enter
' '
the combustion chamber. If vF and vO are the coefficients
corresponding to fuel and oxidizer when considering an overall unique
reaction of the type
'
vF F vO
'
O2 products (2.10)
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Chapter Two Fundamental of combustion Fuel & Energy Department
Ch. Two |5
Chapter Two Fundamental of combustion Fuel & Energy Department
To calculate the equivalence ratio for any reaction same reaction shown
in equation 2.16, we will be written as:
mair
m
f stoic A / F stoic
mair A / F act (2.15)
m
fuel act
x y/4
a (2.19)
To find the mole fraction of all of the product species, we will study as :
bx (2.20)
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Chapter Two Fundamental of combustion Fuel & Energy Department
c0 (2.21)
d y/2 (2.22)
e0 (2.23)
1
f ( )( x y / 4) (2.24)
The total number of moles of products (per mole of fuel burned) can be
found by summing the above coefficient together with 3.76a moles of N2.
x y/4
N Total x y / 2 ( )(1 3.76) (2.25)
The mole fractions are then determine by divided each of the coefficient
above by N Total :
co 0 (2.26b)
H 2 O ( y / 2) / NTotal (2.26c)
H 2 0 (2.26d)
1
O2 ( )( x y / 4) / N Total (2.26e)
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Chapter Two Fundamental of combustion Fuel & Energy Department
these, we employ the three element balances (C, H, and O) and the water-
gas shift equilibrium,
The use of equation (3.11) causes the system of equation for b, c, d and e
to be nonlinear (quadratic). Solving the element balance in terms of the
unknown coefficient b results in
c x b (2.28a)
d 2a b x (2.28b)
e 2a b x y / 2 (2.28c)
1/ 2
2a( K p 1) x y / 2 1 (2a( K p 1) x y / 2) 2
b (2.29)
2( K p 1) 2( K p 1) 4 K p ( K p 1)(2ax x 2)
Ch. Two |8
Chapter Two Fundamental of combustion Fuel & Energy Department
O2 0 (2.31e)
After that, we can calculated the mass fraction of fuel in the fresh
gases(air-fuel mixture) as [ ]:
1
Yf (2.32)
s MWN 2
1 (1 3.76 )
MWO2
And, the mole fraction of species for fresh gases (unburnt mixture) by
known the type of fuel and the equivalence ratio as below:
From equation (3.1) the total number moles of reactant species(NTotal) is:
Ch. Two |9
Chapter Two Fundamental of combustion Fuel & Energy Department
Exercises:
Q1: For the reaction( vF' F vO' (O2 3.76 N2 ) products )find the mass
fractions for fuel, O2 and N2 ?
Q2: For the reaction shown in Q1, if the equivalence ratio equal to 1.3,
determine the mass fraction for fuel, O2 and N2?
Q5: Calculate the equivalence ratio and the mole fractions of the
products of the complete combustion of isooctane (C8H18) with
200% theoretical air.
Q6: In a vessel of volume 1m3 there are 2 g of molecular H2, 6 g of
molecular O2 and 30 g of N2. What are the mole fractions, mass
fraction and concentrations of the hydrogen, oxygen and nitrogen?
Q7: A steady flow 1 mol/s of CH4 and 2 mol/s of O2 enters a reactor
and become H2O and CO2. Write equation of the reaction. What is
the concentration of CO2 and H2O vapor density at the exit if the
density of gas exiting the reactor is 1 kg/m3?
Q8: Calculate (1) partial pressures, (2) mole fractions, (3)
Concentrations, (4) densities of the gaseous components in a
vessel, which contains 0.2 kg of H2, 3 mol of CO, amount of H2O
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Chapter Two Fundamental of combustion Fuel & Energy Department
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