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Marks Scored : 47.

Question no 1
All of the following are isoelectronic with hydrogen except
 
                                                                                                                              

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Option A :
1+
He            

Option B :
2+  
Li                             

Option C :
Be3+            

Option D :
+2
Be

Question no 2
 Which one of the following electronic species has more electrons than neutrons:
 
                                                                                                                      
 
 

Option A :
-2
 O           

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Option B :
  F-1              

Option C :
+1  
Na     

Option D :
+2
 Mg

Question no 3
  Which pair of the following is iso-electronic
 
                                          
 
 

Option A :
  CO2, NO2           

Option B :
NO, CO2                                                 

Option C :
-
   CN , CO     

Option D :
SO2, CO2

 
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Question no 4
Unknown element having 212 nucleon number and 90 atomic number, the number of electrons, protons
and neutrons in that element is
 
 
 

Option A :
 e = 90 p = 90   n = 110   

Option B :
e = 90 p = 122  n = 90                 

Option C :
 e = 90p = 90   n = 122

                                                    

Option D :
e = 90 p = 100 n = 120

Question no 5
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nd
An element forms M+2 ion and belongs to 2 period, the number of protons are
 
 
 

Option A :
 12       

Option B :
2                               

Option C :
      4    

Option D :
10

Question no 6
The nucleus of the atom (Z > 1) consists of
 
 

Option A :
Proton and neutron             

Option B :
  Proton and electron           

 
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Option C :
 Neutron and electron

Option D :
Proton, neutron and electrons

Question no 7
If an isotope of hydrogen has two neutrons in its atom, its atomic number and mass number will be
 
 

Option A :
2and 1             

Option B :
1 and 1                

Option C :
 3 and 1    

Option D :
1 and 3

Question no 8
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40 -
The number of electrons in [19K ] is
 
 

Option A :
19           

Option B :
18                         

Option C :
 20   

Option D :
40

Question no 9
According to quantum mechanics, the size of electronic shell is told by the quantum number
 
 

Option A :
 Spin quantum number       

Option B :
Magnetic quantum number               

Option C :
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Azimuthal quantum number

Option D :
Principal quantum number

Question no 10
th +2
The number of shells in 5 period element after formation of stable cation (M ) that belongs to II-A
group are
 
 

Option A :
 4       

Option B :
3               

Option C :
       5      

Option D :
 6

© 2020 All rights reserved

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Question no 11
N-Shell can accommodate maximum number of electrons
 
                                          
 

Option A :
 2         

Option B :
 8                 

Option C :
18         

Option D :
32

Question no 12
How many electrons can t into sub-shell for which n = 3, = 2:
 

Option A :
  2        

Option B :
10                      

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Option C :
    6    

Option D :
18

Question no 13
If the value of n = 4 what is probable value of ℓ:
        
                                                                                            
 

Option A :
      0,1               

Option B :
  0,1,2,3          

Option C :
    0,1,2                 

Option D :
None of above

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Question no 14
Which Quantum number describes about the number of orientations in sub-shell
 
 

Option A :
Spin      

Option B :
Azimuthal          

Option C :
Magnetic   

Option D :
  Principal

Question no 15
Magnetic quantum number for the last electron in sodium atom is equal to
 
                                    
 

Option A :
 3            

Option B :
  1                        

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Option C :
  2         

Option D :
0

Question no 16
In the absence of magnetic eld, the orbitals of f-subshell are
 
 
 

Option A :
 

 Three fold degenerate      

Option B :
Seven fold degenerate             

Option C :
 Five fold degenerate     

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Option D :
One fold degenerate

Question no 17
The electron density between 1s and 2 s orbital is
 
                
 

Option A :
high         

Option B :
Low              

Option C :
      zero        

Option D :
 unpredictable

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Question no 18
Three unpaired electrons in the ground state of nitrogen atom can be explained by
 
 

Option A :
 Pauli’s exclusion principle       

Option B :
uncertainty principle         

Option C :
 Hund’s rule   

Option D :
Aufbau principle

Question no 19
Which of following vaiolates Hund’s rule
 
 

Option A :
2 2 1 1 0
1s , 2s , 2px2 , 2py2 , 2pz        

Option B :
2 2 2 2 2   
1s , 2s , 2px , 2py , 2pz               

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Option C :
2 2 2 o 0
1s , 2s , 2px , 2py 2pz

Option D :
2 1
 1s , 2s

Question no 20
Electronic con guration is the distribution of electrons in
 
 

Option A :
  Sub-shells in their decreasing energy order               

Option B :
 Outermost shells only                 

Option C :
shells in their decreasing energy order                             

Option D :
 Shells and sub shells with increasing energy order

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Question no 21
Among the following the electron de cient compound is
 
 

Option A :
 BCl3               

Option B :
 CCl4             

Option C :
   PCl5             

Option D :
CH4

Question no 22
During the formation of a chemical bond the potential energy of the system
 
 

Option A :
 Decreases                 

Option B :
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Increases            

Option C :
Does not change            

Option D :
   None of these

Question no 23
The arrangement of Sodium, Oxygen, Flourine and Strontium on the basis of increasing rst ionization
energy is
 
 

Option A :
 Na <Sr< O < F           

Option B :
   Sr< Na < F < O            

Option C :
   Sr< Na < O < F          

Option D :
   Na <Sr< F < O

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Question no 24
Which of the following group have the greater ionization energy?
 
 

Option A :
 Metals                   

Option B :
Transitional Metals              

Option C :
Nonmetals     

Option D :
 Inert gases

Question no 25
 The rst ionization energy of the alkali metals decreases with increasing atomic number. which one of the
following factors is mainly responsible for this?
 
 

Option A :
increasing nuclear charge        

Option B :
increasing atomic radius             

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Option C :
    decreasing net nuclear charge

                                            

Option D :
   increasing atomic mass

Question no 26
 Which of following pair of groups show abnormal trend of ionization energy
 
 

Option A :
 II, III     

Option B :
  II, V                    

Option C :
     III, V     

Option D :
 III, VI

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Question no 27
In determining the ionization energy, the atom must be
 
 

Option A :
In solid state          

Option B :
  In liquid state         

Option C :
 In gaseous state   

Option D :
 In any state

Question no 28
An atom with high electronegativity generally has
 
 

Option A :
 Tendency to form positive ions         

Option B :

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    Large atomic size                                     

Option C :
 High ionization energy

Option D :
Oxide of amphoteric nature

Question no 29
Ionic compound shows all of the following properties except:
 
 

Option A :
  High melting and boiling point           

Option B :
Resonance               

Option C :
  Conduct electricity in molten state      

Option D :
Non-directional bond

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Question no 30
Ionic compounds are mostly obtained by the combination of atoms of elements of groups
 
 

Option A :
  3 and 5              

Option B :
 4 and 8             

Option C :
  2 and 5   

Option D :
 1 and 7

Question no 31
+2
When a calcium atom becomes a calcium ion (Ca )
 
 

Option A :
 It loses an electron       

Option B :
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  it gains two electrons                     

Option C :
it loses two electrons

                                                

Option D :
   its proton number increases

Question no 32
Which of the following is a favourable factor for cation formation?
 
 

Option A :
High electron a nity       

Option B :
High electronegativity                   

Option C :
Small atomic size   

Option D :
 Low ionization potential

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Question no 33
In the given structure NaBH4 the co-ordinate covalent bond is present in between
 
 

Option A :
 BH3 and Na               

Option B :
-
BH3 and H                

Option C :
+     
BH3 and H  

Option D :
No co-ordinate covalent bond in present

Question no 34
Which of the following does not have linear geometry?
 
                                                                                
 

Option A :
  CdCl2           

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Option B :
SnCl2       

Option C :
 HgCl2                                

Option D :
BeCl2

Question no 35
The compound which has minimum bond angle is
 
 

Option A :
 H2O               

Option B :
   H2S             

Option C :
   NH3       

Option D :
 CH4

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Question no 36
All are AB3 type molecules except
 
 

Option A :
SO3           

Option B :
 SO2               

Option C :
  BF3      

Option D :
 H2S

Question no 37
If two Ione pairs are present then bond angle of tetrahedral compound reduce to
 
 

Option A :
o
 109.5                

Option B :
107.5o                   

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Option C :
o             
104.5  

Option D :
None of these

Question no 38
The bond angle depends upon the
 
 

Option A :
Types of bonds                 

Option B :
Numbers of bonds                   

Option C :
  Non bonding electron pairs       

Option D :
 All of the above

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Question no 39
Which of the following pairs of structures are same
 
 

Option A :
 BeCl2 and CO2        

Option B :
SO2 and SO3       

Option C :
 H2S and BeH2

Option D :
H2SO4 and H2SO3

Question no 40
A hybrid orbital is formed by the intermixing of two or more orbitals of different shape and energy and can
form __________ bond.
 
 

Option A :
Sigma bond             

Option B :
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Both A and c         

Option C :
 Pi bond

                 

Option D :
  None of these

Question no 41
In ethyne molecule the sigma bond is formed by __________ overlapping.
 
 

Option A :
 sp-sp               

Option B :
3 3
sp -sp                          

Option C :
    sp2-sp2          

Option D :
    s-s

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Question no 42
Bond length between two atoms is the shortest in:
 
 

Option A :

Option B :

Option C :

Option D :

Question no 43
Both BF3 and NF3 are covalent but BF3 molecule is non-polar while NF3 is polar because
 
 
 

Option A :
 atomic size of boron is smaller than nitrogen                                                           

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Option B :
 boron is a metal while nitrogen is gas 

Option C :
 BF3 is planner but NF3 is pyramidal

Option D :
 BF bond has no dipole moment while NF bondhas dipole

Question no 44
Which of the following molecules is polar in nature
 
 

Option A :
CCl4                  

Option B :
    NH3             

Option C :
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 CO2              

Option D :
    CH4

Question no 45
Py and Pz atomic orbitals always give
 
 

Option A :
Sigma bond       

Option B :
   Pi-bond                 

Option C :
   Pi*-bonds      

Option D :
   Both B and A

Question no 46
Which of the following pairs resembles in shape
 

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Option A :
 AlCl3 and PCl3                 

Option B :
  AlCl3 and BCl3                

Option C :
BF3 and NH3

Option D :
 CO2 and SO2

Question no 47
7
If the nitrogen atom had electronic con guration 1s , it would have energy lower than that of the normal
2 2 3 7
ground state con guration 1s , 2s , 2p , because the electrons would be closer to the nucleus. Yet 1s
is not observed because it violates
 

Option A :
 Heisenberg's uncertainty principle                  bits

Option B :
          

 Hund's rule                                                                

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Option C :
 Pauli's exclusion principle

Option D :
Bohr postulate of stationary or

Question no 48
Two electrons in the same atomic orbital can be distinguished by their
 
 

Option A :
 Principal quantum number         

Option B :
   Azimuthal quantum number         

Option C :
 Magnetic quantum number

                     

Option D :
  Spin quantum number

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Question no 49
The electronic con guration of the element which is just above the element with atomic number 43 in the
same particular group is
 
 

Option A :
 1s2, 2s2 2p6, 3s2 3p6 3d10 4sl 4p6

Option B :
2 2 6 2 6 5 2
1s , 2s 2p , 3s 3p 3d , 4s

Option C :
1s2, 2s2 2p6, 3s2 3p6 3d6, 4s1

Option D :
1s2, 2s2 2p6, 3s2 3p6 3d10, 4s1 4p5

Question no 50
Which set of quantum number represents permissible values?
 
 

Option A :
 n = 3, l = 1, m = 1, s = 1/2     

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Option B :
n = 3, l =1, m = 4, s = + 1 

Option C :
n = 3, l = 2, m = 4, s = + 1/2

Option D :
n = 1, l  = - 1, m = - 1, s = - 1/2

Question no 51
Which set of quantum number represents the electron of the lowest energy?
 
 

Option A :
  n = 2, l = 0, m = 0, s = - 1/2

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Option B :
 

  n = 2, l =1, m = 0, s = +1/2 

Option C :
  n = 4, l = 0, m = 0, s = +1/2

Option D :
  n = 4, l  =0, m = 0, s = - 1/2

Question no 52
If n = 6, the correct sequence of lling of electron will be:
 
 

Option A :
ns→ np →(n – 1)d→  (n – 2)f     

Option B :
 ns →(n – 2)f→ (n – 1)d → np                 

Option C :
 ns → (n – 1)d→  (n – 2) f→  np

                 

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Option D :
ns → (n – 2)f → np → (n – 1)d

Question no 53
Which is not correct for electron distribution in the ground state?
 
 

Option A :
Co : [Ar] 3d7, 4s2         

Option B :
  Cu : [Ar] 3d9, 4s2                      

Option C :
 Ni : [Ar] 3d8, 4s2

Option D :
Zn : [Ar] 3d10, 4s2

Question no 54
An ion which has 18 electrons in the outermost shell is
 
 

Option A :

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+
Cu            

Option B :
Cs+                               

Option C :
4+
   Th

                        
 

Option D :
    +
 K

Question no 55
The values of quantum numbers for the outermost electron in scandium (Sc = 21) are
 
 

Option A :
 n = 3, l = 2         

Option B :
 n = 4, l = 0                   

Option C :

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  n = 3, l = 3

                                

Option D :
  n = 2, l = 2

Question no 56
Which of the following molecules is not planer?
 
 

Option A :
benzene               

Option B :
  boron tri uoride                         

Option C :
  Ethene

Option D :
 Phosphorus trichloride

Question no 57
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Which molecule is linear?

 
 
 

Option A :
 C2H2

Option B :
C2Cl4                    

Option C :
 C3H6    

Option D :
  C3H8  

Question no 58
Why is the molecule of BCl3 planar, whereas the molecule of PH3 is pyramidal?
 
 

Option A :
 The boron atom has no d orbitals available for bonding

Option B :
The boron atom in BCl3 has six electrons in its valency shell, whereas the phosphorus atom in PH3
has eight

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Option C :
The repulsion between chlorine atoms is greater than that between hydrogen atoms

Option D :
 The covalent radius of phosphorus is greater than that of boron

Question no 59
Most polar bond among following is

Option A :
C-H      

Option B :
N-H                   

Option C :
S-H 

Option D :
O-H

Question no 60
Minimum electronic repulsions are present in the compound
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Option A :
H2O

Option B :
H2S

Option C :
NH3 

Option D :
CH4

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