Professional Documents
Culture Documents
60 60
31. The half-life of 27 Co is 5.3 years. How much of 20 g of 27 Co will remain radioactive after 21.2 years ?
32. The element which reacts both with acids and bases to produce a salt and hydrogen gas is -
(A) Zn (B) Mg (C) Li (D) S
36. Among HCl, HBr, HF, and HI the weakest acid in water is -
(A) HCl (B) HF (C) HBr (D) HI
38. When a few drops of concentrated sulphuric acid are added to a few drops of a clear sugar (sucrose)
solution in a test tube, the solution
(A) remains colorless (B) turns black (C) turns blue (D) turns white
66. A 3 N solution of H2SO4 in water is prepared from Conc. H2SO4 (36 N) by diluting -
(A) 20 ml of the conc. H2SO4 to 240 ml (B) 10 ml of the conc. H2SO4 to 240 ml
(C) 1 ml of the conc. H2SO4 to 36 ml (D) 20 ml of the conc. H2SO4 to 36 ml
67. The gas responsible for under water corrosion of iron and the product of corrosion, respectively, are -
(A) Dissolved oxygen and Fe2O3 (B) Dissolved hydrogen and Fe2O3
(C) Dissolved oxygen and Fe(OH)3 (D) Dissolved nitrogen and Fe(OH)3
250
Solubility (g/100 ml water)
200
150
100
50
0 20 40 60 80 100
Temperature (°C)
The amount of KNO3 that will crystallize when a saturated solution of KNO3 in 100 ml of water is cooled
from 90°C to 30 °C, is
(A) 16 g (B) 100 g (C) 56 g (D)160 g
70. A sample of water was checked for suitability for drinking and was subjected to a chemical test. Pure zinc
granules and sulphuric acid were added to the water sample. The effervescence that resulted from the
reaction was bubbled through a tube containing lead acetate solution. A black precipitate appeared. The
outgoing gas was subsequently passed through a heated copper tube, a black mirror appeared on the
wall of the tube. The first and second black substances, respectively, are :
(A) HgS and CuS (B) PbS and CuS (C) As and Hg (D) PbS and As
CHEMISTRY
31. The volume of 0.5 M aqueous NaOH solution required to neutralize 10 ml of 2 M aqueous HCl solution is:
(A) 20ml (B) 40ml (C) 80ml (D) 120ml
34. Among butane,1-butene,1-butanol and butanal, the compound which is most polar is
(A) butane (B) 1-butene (C) 1-butanol (D) butanal
35. Among ethanol, dimethyl ether, methanol, and propanal, the isomers are :
(A) ethanol, dimethyl ether, methanol and propanal
(B) ethanol and methanol
(C) ethanol, dimethyl ether, and methanol
(D) ethanol and dimethyl ether
36. Among Li, Be, N and F, the element having the largest atomic radius, is :
(A) Li (B) Be (C) N (D) F
37. The proof of oxidizing action of hydrogen peroxide in acid solution is in the formation of :
(A) O2 (B) H2O
(C) both H2O and O2 (D) both H3O+ and O2
39. 3.01×1023 molecules of elemental Sulphur will react with 0.5 mole of oxygen gas completely to produce
(A) 6.02 × 1023 molecules of SO3 (B) 6.02 × 1023 molecules of SO2
(C) 3.01 × 1023 molecules of SO3 (D) 3.01 x 1023 molecules of SO2
40. The pair of metals which will produce hydrogen gas in reaction with acid is :
(A) Mg, Cu (B) Mg, Ag (C) Zn, Pb (D) Cu, Zn
gas gas
gas
(A) a > b > c (B) a < b < c (C) a = b = c (D) a >b < c
CHEMISTRY
71. The density of a salt solution is1.13 g cm–3 and it contains 18% of NaCI by weight. The volume of the
solution containing 36.0 g of the salt will be :
(A) 200 cm3 (B) 217 cm3 (C) 177 cm3 (D) 157cm3
72. Esterification of a compound ‘’X’’ with molecular formula C3H6O2 with an alcohol ‘’Y’’ produces a com-
pound with molecular formula C5H10O2. X and Y, respectively, are :
(A) propanoic acid and methanol (B) propanoic acid and ethanol
(C) acetic acid and ethanol (D) butyric acid and methanol
73. 10 g of a crystalline metal sulphate salt when heated generates approximately 6.4 g of an anhydrous salt
of the same metal. The molecular weight of the anhydrous salt is 160 g. The number of water molecules
present in the crystal is :
(A) 1 (B) 2 (C) 3 (D) 5
74. In the reaction of FeSO4 with K2Cr2O7 in the presence of an acid, the changes in the formal oxidation
numbers of Cr and Fe, respectively, are :
(A) 1 and 5 (B) 3 and 1 (C) 5 and 1 (D) 1 and 3
75. An aqueous solution of a metal salt (X) reacts with carbon dioxide to give a water soluble compound (Y)
which on heating gives the starting metal salt back. Y when present in water does not produce lather with
soap. The compounds X and Y, respectively are
(A) CaCO3 and Ca(HCO3)2 (B) Mg (HCO3)2 and MgCO3
(C) Ca(HCO3)2 and CaCO3 (D) MgCO3 and Mg (HCO3)2
CHEMISTRY
31. The element X which forms a stable product of the type XCI4 is -
(A) AI (B) Na (C) Ca (D) Si
33. The pair in which the first compound is ionic and the second compound is covalent, is -
(A) Fe(OH)2,CH3OH (B) CH3OH, CH3CH2OH (C) Fe(OH)2, Cu(OH)2 (D) Ca(OH)2, Cu(OH)2
34. In the reaction SO2 + 2H2S 3S + 2H2O, the substance that is oxidized is -
(A) SO2 (B) H2O (C) S (D) H2S
35. Sodium oxide dissolves in water to give sodium hydroxide which indicates its -
(A) acidic character (B) basic character
(C) amphoteric character (D) ionic character
P P P P
T V V T
37. The pH values of
(i) 0.1 M HCl aq (ii) 0.1 M KOH
(iii) tomato juice and (iv) pure water
follow the order -
(A) (i) < (iii) < (iv) < (ii) (B) (iii) < (i) < (iv) < (ii) (C) (i) < (ii) < (iii) < (iv) (D) (iv) < (iii) < (ii) < (i)
38. When calcium carbide is added to water, the gas that is evolved is -
(A) carbon dioxide (B) hydrogen (C) acetylene (D) methane
41. Among the four compounds (i) acetone, (ii) propanol, (iii) methyl acetate and (iv) propionic acid, the two
that are isomeric are -
(A) methyl acetate and acetone (B) methyl acetate and propanol
(C) propionic acid and methyl acetate (D) propionic acid and acetone
42. One mole of nitrogen gas on reaction with 3.01 x 1023 molecules of hydrogen gas produces -
(A) one mole of ammonia (B) 2.0 x 1023 molecules of ammonia
(C) 2 moles of ammonia (D) 3.01 × 1023 molecules of ammonia
43. Saponification is -
(A) hydrolysis of an ester (B) hydrolysis of an amide
(C) hydrolysis of an ether (D) hydrolysis of an acid chloride
45. Solubility
g/I
250
KNO3
200
150
KCl
100
50
20 40 60 80 100
Temperature (ºC)
Given the solubility curves of KNO3 and KCl, which of the following statements is not true?
(A) At room temperature the solubility of KNO3 and KCI are not equal.
(B) The solubilities of both KNO3 and KCI increase with temperature.
(C) The solubility of KCI decreases with temperature.
(D) The solubility of KNO3 increases much more as compared to that of KCl with increase in temperature.
CHEMISTRY
71. Reaction of NaCl with conc. H2SO4 liberates a gas X that turns moist blue litmus paper red. When gas X
is passed into a test tube containing egg shell powder suspended in water another gas, Y is generated
which when passed through lime water makes it milky. The gases X and Y respectively, are -
(A) HCl and CO2 (B) Cl2 and CO2 (C) SO2 and CO2 (D) SO2 and HCl
72. 10 ml of an aqeuous solution containing 222 mg of calcium chloride (mol. wt. = 111) is diluted to 100 ml.
The concentration of chloride ion in the resulting solution is -
(A) 0.02 mol/lit. (B) 0.01 mol/lit. (C) 0.04 mol/lit (D) 2.0 mol/lit.
73. Aluminium reduces maganese dioxide to manganese at high temperature. The amount of aluminium
required to reduce one gram mole of manganese dioxide is -
(A) 1/2 gram mole (B) 1 gram mole (C) 3/4 gram mole (D) 4/3 gram mole
74. Ethanol on reaction with alkaline KMnO4 gives X which when reacted with methanol in the presence of an
acid gives a sweet smelling compound. Y. X and Y respectively, are -
(A) acetaldehyde and acetone (B) acetic acid and methyl acetate
(C) formic acid and methyl formate (D) ethylene and ethyl methyl ether
75. The pH of a 10 ml aqueous solution of HCl is 4. The amount of water to be added to this solution in order
to change its pH from 4 to 5 is -
(A) 30 ml (B) 60 ml (C) 90ml (D) 120 ml
CHEMISTRY
21. The boiling points of 0.01 M aqueous solutions of sucrose,NaCl and CaCl2 would be :
(A) the same (B) highest for sucrose solution
(C) highest for NaCl solution (D) highest for CaCl2 solution
22. The correct electronic configuration for the ground state of silicon (atomic number 14) is :
(A) 1s2 2s2 2p6 3s2 3p2 (B) 1s2 2s2 2p6 3p4 (C) 1s2 2s2 2p4 3s2 3p4 (D) 1s2 2s2 2p6 3s1 3p3
23. The molar mass of CaCO3 is 100 g. The maximum amount of carbon dioxide that can be liberated on
heating 25 g of CaCO3 is :
(A) 11 g (B) 5.5 g (C) 22 g (D) 2.2 g
24. The atomic radii of the elements across the second period of the periodic table.
(A) decrease due to increase in atomic number
(B) decrease due to increase in effective nuclear charge
(C) decrease due to increase in atomic weights
(D) increase due to increase in the effective nuclear charge
25. Among NH3, BCl3, Cl2 and N2, the compound that does not satisfy the octet rule is :
(A) NH3 (B) BCl3 (C) Cl2 (D) N2
29. Consider two sealed jars of equal volume. One contains 2 g of hydrogen at 200 K and the other contains
28 g of nitrogen at 400 K. The gases in the two jars will have :
(A) the same pressure. (B) the same average kinetic energy.
(C) the same number of molecules. (D) the same average molecular speed.
ANSWER KEY
Ques. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. B C D C B D D B A B D C D D B
Ques. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans. B C B C C B C C A C A C B A C
Ques. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
Ans. B A C C D B A B B D A C C A D
Ques. 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans. A A A D B A D A B D D D D B B
Ques. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75
Ans. C A B A C A A D A B D D A C C
ANSWER KEY
Ques. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. A B D A C C C A C D B B D B A
Ques. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans. D D A A B C A D A B C B D C A
Ques. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
Ans. B A A C D A C A D C A B B C D
Ques. 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans. B B B B A C A&C C A D C A D B D
Ques. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75
Ans. B A D A C D A B A A C B D B A
Ques. 76 77 78 79 80
Ans. B C C A D
Ques. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. C D B A B B A D D D B A C D C
Ques. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans. D A D B A D A A B B A A D C C
Ques. 31 32 33 34 35 36 37 38 39 40
Ans. D C A D D A C B C B
CHEMISTRY
n
1
31. Using the formula, N = N0
2
where, No = initial amount of radioactive substance
N = Amount of substance left after ‘n’ half lives
21.2 years
n=
5.3 years
n=4
4
1 20
so, N = 20 = = 1.25g
2
16
35. KMnO4 being strong oxidising agent will oxidise Cl– ion present in HCl to form chlorine gas.
2KMnO4 + 16 HCl 2KCl + 2MnCl2 + 8H2O + 5Cl2
36. Order of strength for halogen acids is HI > HBr > HCl > HF
38. Concentrated sulphuric acid is a dehydrating agent and it burns the organic compounds like sucrose so
the colour of the solution turns black.
Conc .H2SO 4
C12H22O11(s) 12C + 11H2O(g)
Sucrose Carbon Water vapour
(Black)
Oxidation
39. ZnO+C Zn + CO
Reduction
35. Ethanol (C2H5OH) and dimethyl ether (CH3 –O – CH3) have same molecular formula but different functional
groups, so they are isomers.
36. For the elements belonging to one period, increase in atomic number results in decrease in atomic
radius. So Li has the largest atomic radius.
40. Zn and Pb are placed above hydrogen in the metal activity series, so they will produce hydrogen gas with
dilute acids.
41. Milk of magnesia is basic, water is neutral and lemon juice is acidic in nature.
Conc. H2SO4
45. CH3 – CH –CH2 – CH2 – CH3 CH3 – CH = CH – CH2 – CH3 + CH2 = CH – CH2 – CH2 – CH3
–H 2O
2-Pentene (Major) 1-Pentene (minor)
OH
2-Pentanol
CHEMISTRY
71. Consider the volume of the solution = x cm3
Then the mass of the solution will be = 1.13x
(mass = density × volume)
The solution contains 18% of NaCl by weight
18
× 1.13x = 36
100
3600
x= = 177 cm3
18 1.13
+
H
72. CH3 – CH2 – COOH + CH2 – OH CH3 – CH2 – COOCH2CH3 + H2O
Propanoic Ethyl propanoate
acid CH3
Ethanol
Oxidation
39. As we move downwards in a group, atomic radii increases. So the order will be Li < Na < K < Cs.
40. CH3 – C CH (Propyne) and (cyclo propene) are two possible structural isomers of C3H4 .
41. Propionic acid and methyl acetate both have same molecular formula (C3H6O2) but different functional
groups, so they are isomers.
42 N2 + 3H2 2NH3
Initial
no. of
moles 1 0.5 0
After
reaction 1 – 0.167 0.5 – 0.5 0.334 mole
222 10 –3
= = 0.2M
111 10 10 – 3
Alkaline
74. CH3 – CH2 – OH CH3COOH
KMnO 4
Ethanol Acetic acid
(X)
H
CH3COOH + CH3OH CH3COOCH3 + H2O
Acetic acid Methanol Methyl acetate
(Y)
21. Aqueous solution containing more number of particles have more elevation in boiling point.
22. 14
Si : 1s2 2s2 2p6 3s2 3p2
23. CaCO3 (s) CaO (s) + CO2 (g)
25 25
Number of mole
100 100
25
Amount of CO2 = × 44 = 11 gram.
100
24. As we move ‘left to right’ in 2nd period, atomic radii decreases due to increase in effective nuclear charge.
27. C4H7Br
CH2 = CH – CH2 – CH2 – Br
H H H H
| | | |
H – C C – C – C – Br
| |
H H
[H ] f 10 5 1
= =
[H ]i 10 2 1000
2
Number of moles of H2 (g) = =1 mole.
2
Number of molecules of H2 (g) = 6.02 × 1023.
For 2nd jar :
28
Number of moles of N2 (g) = =1 mole.
28
Number of molecules of N2 (g) = 6.02 × 1023.
So, both jar have same number of molecules.
30. and
(cis) (trans)