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How do I
chose the
best phone? ▪ Even when you buy a phone, lots of options
available and we need to chose from them
based on our requirements
▪ Think about how many decisions one need to
make to build a large-scale chemical plant
3
In almost every case encountered by a chemical engineer there are several alternative
4
methods which can be used for any given process or operation.
Questions we have to ask before project implementation
▪ What to produce?
Requires an extensive foresight and market knowledge
▪ How much to produce?
Depends on market analysis and economic plant capacity
▪ How to produce?
Selection of technology, optimal flowsheet, safety compliance, energy
conservation, project cost, working capital
Novel
To help you understand Idea
9
Optimal Economic Design
12
General Overall Design Considerations
13
Hierarchical Approach: “Divide-and-Conquer”
PLANT LEVEL
SUBSYSTEM
LEVEL
14
Syllabus for the course
Reference Books
1. T. Beiger, I.E Grossman, A.W. Westerberg Systematic methods of chemical process design, Prentice Hall,
International series 1997
2. Douglas, Conceptual Design of Chemical Process, McGraw Hill 1989
3. E. Ludwig, Applied Project Engineering, 2nd Edition, Gulf publishing company, 1988.
Shanmugam V shanmugam.v@iitg.ac.in
Abhishek Bansal abhishek.bansal@iitg.ac.in
Durlov Pait d.pait@iitg.ac.in
Aakash Rajpoot arajpoot@iitg.ac.in
Class Hours
Day Time
Monday 4-4:55 PM
Tuesday 4-4:55 PM
Friday 3-3:55 PM
17
Thanks!
Any questions?
You can find me at:
▪ resmis@iitg.ac.in
18
Lecture 2: Introduction to typical design
steps and input information
Resmi Suresh
1
Design steps
8-Jan-2021 2
Design Steps of Chemical Process
Example
◦ Electric vehicle
We have been using IC engine vehicles for a long time. It resulted in huge amount of
pollution.
There was a need for alternate technology. This resulted in electric vehicles.
◦ Haber-Bosch process
Nitrogen plays a crucial role in the biochemistry of our lives.
Due to low reactivity of nitrogen, plants and animals were not able to extract
nitrogen from air. This was a major limiting factor in agriculture.
In 1910, German chemists Fritz Haber and Carl Bosch changed all this when they
combined atmospheric nitrogen and hydrogen into ammonia. This in turn can be
used as crop fertiliser, eventually filtering up the food chain to us.
8-Jan-2021 3
Design Steps of Chemical Process
o Involves synthesis or various configurations of processing operations with the help of prior knowledge and simulation studies
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Design Steps of Chemical Process
5. Refine required design data
o Establish property data with appropriate software
o Prepare flowsheet
o Size equipment
8. Revisit the process again for environment factors and provide a written process design report
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Design Steps of Chemical Process
11. Installation
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Levels of Design Accuracy
Depending on the accuracy and detail required, design engineers classify
process designs in the following 5 levels
Increasing accuracy and detail
8-Jan-2021 8
Input information
1. Reaction Information
➢The stoichiometry of all reactions that take place
If catalyst is used,
Maximum Yield
▪ Many processes are designed to operate at maximum yield, but this
operation need not give optimal economic conversion
▪ Conversion of A to C is selectivity loss. Normally raw material costs and selectivity losses are the dominant factors in the design of
petrochemical process.
▪ The optimum economic conversion is normally fixed by an economic trade off between large
selectivity losses and large reactor costs at high conversions balanced against larger recycle
costs at low conversions.
▪ The graph shows that the optimum economic conversion is less than the conversion
corresponding to the maximum yield.
8-Jan-2021 11
Input information
2. Production rate
Production rate is directly proportional to the plant capacity and it is fixed by maximum size of one or more pieces of
equipment
The production rate specified for the plant might change during a design as the market condition are constantly
changing we must be responsive to these changes.
3. Product purity
The product purity is fixed by the marketing considerations, it might be possible to produce a range of product purities
at different prices. It is essential that designer inform the marketing department about the cost associated with
producing high purity products, that does not raise customer expectations to unrealistic levels.
4. Raw Materials
During purchasing of raw materials need to gather information from marketing team about raw material price versus
purity. This will help to decide whether to include purification facility as a part of the design.
We must work with chemist to see whether the impurities in the raw materials are inert or will affect the reaction.
Particular trace amount of impurities can build up to large values in recycle loops
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Input information
5. Catalyst Deactivation
Life time of catalyst is one of the major pre-requisite of early stages in design which enable us to determine
the deactivation period, hence it will put into regeneration or replacement after its appropriate usage.
6. Constraints
➢ There have been large number of serious plant explosion throughout the history chemical industry hence
safety precautions against ignitions must be incorporated.
➢ Some materials might polymerise and foul heat exchanger surface and also in the process of coking it will
form coke and deactivate catalysts. Toxic or highly corrosive materials also affect the way in which we
approach a design problem.
8-Jan-2021 13
Input information
7. Physical property
The information we normally need are molecular weights, boiling points, vapour pressures, heat capacities, heat of
vaporisation, liquid densities, fugacity coefficients etc.
For new compounds, these properties may not be available and so, we will have to rely up on experimental studies or
simulation tools like ASPEN
8. Other plant and site data
If we are going to build our new process on an existing site, then we must design the process compatible with the
facilities that already exist on that site.
1. Utilities
a. Feed supply b. Levels of steam pressure c. Cooling water inlet and outlet temperature
8-Jan-2021 14
Input information for the Haber process of Ammonia
To understand the basic input information, let us consider the case study of ammonia production in Madras Fertilizer Limited.
This plant was commissioned in the year 1966 producing ammonia, urea and NPK complex located in North Chennai, Tamil nadu.
a. Reaction
N2 + 3H2 ֞ 2NH3
Reaction condition:
Reactants are gas phase and catalyst is solid, hence it is heterogeneous reaction
b. Production rate
Plant has the daily rated capacity of 750 Metric tonnes
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Input information for the Haber process of Ammonia
c. Raw materials
Naphtha from Chennai petroleum corporation limited (CPCL) was initially the feedstock for producing hydrogen in the reforming
unit. Later regularised to meet environmental standard requirements, there was a shift from naphtha to Natural gas. Hydrogen
produced from secondary reforming unit from natural gas along with air will be the feedstock to produce ammonia.
d. Catalyst deactivation
Iron is the catalyst and the active life period would be 5-10 years, further the catalyst will be taken for either regeneration or
replacement.
e. Processing Constraints
This is highly reversible reaction and it is thermodynamically favourable with high pressure as the number of moles decreases in the
product side and also requires decreasing temperature profile as it highly exothermic reaction. Failure of cooling water supply will
disturb the equilibrium production.
This fertilizer plant commissioned with the agreement between Government of India and American chemical and oil company in the
year 1966 located at Chennai, Tamil nadu
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Input information for the Haber process of Ammonia
➢ Effluent treatment systems and hydrolyser stripper for treating ammonia in place as a part of environment
protection.
➢ Cooling water blow down has been commissioned for recycling water
➢ Carbon dioxide evolved during burning of natural gas will be absorbed using ethanolamine in the column,
will be utilized for urea production which saves considerable cost for further production
➢ Water treatment plants and Reverse osmosis plant are functioning effectively to meet the water demand.
Also receives secondary treated sewage water from Chennai metropolitan water supply and sewerage
board.
8-Jan-2021 17
References
◦ Conceptual design of chemical process by James Douglas
8-Jan-2021 18
CL 306
Process Engineering and Economics
Flowsheet Synthesis
Lecture-03
Flow Diagrams
Mass & Energy Balances
✓ The sequence of the equipment and unit operations involved in the process.
✓ The stream connections, stream flow rates and compositions
✓ Energy flow in the process
✓ The operating conditions
✓ All necessary auxiliary equipment such as pumps, compressors, turbines, etc.
▪ Depending on the information contained, flow diagrams may be divided into three general types:
❖ Depending on the level of detail required several types of flow diagrams are used:
❑ Piping and instrumentation diagram is very important for control system design and safety analysis.
❑ Commonly known as P&ID diagram also known as Engineering flow-sheet or Mechanical flow sheet.
➢ Block flow process diagram will concentrate on a particular sector/area of a chemical plant
➢ Each block can represent a single piece of equipment or a complete stage in a process or even the complete
process
➢ The simplest form of BFD, the input/output diagram provides the material streams entering and exiting the
process
Input Output
Process
➢ Block flow plant diagram is used to explain the general material flows throughout an entire plant and would
help orient workers to the products and important operation zones of a chemical facility
➢ Limited use for complex processes as it will be very difficult to use a large number of blocks to represent the
process
➢ We can use a single block for several units combined, but we will lose the detail of the process
➢ Graphical representation of a chemical engineering process that shows the preliminary process flow
path
➢ It does not show the minor details of the process rather it focus on the equipment used, control valves
and other instruments that are present.
➢ It helps to illustrate how the major components of a process plant interact with each other to bring the
desired effect
➢ It is also effectively used in other sectors such as business administration to understand how different
sections of a company can work efficiently in order to achieve their specific targets
➢ Process flow diagrams may not show the working of the whole plant. It may be used to represent different
sections of a plant
➢ This would help us to understand in detail about each specific operation that is being carried out such as raw
material storage, reaction, separation, purification, recovery and product storage
➢ Sequence of the equipment and unit operation involved in the process, the stream connections and stream flow
rates, operating conditions and all necessary auxiliary equipment
➢ PFD symbols are a set of diagram that show how different parts of the process are interconnected to each other
➢ The symbols also depict the instrumentation devices that are used in the process. Examples of symbols include
valves, pumps, compressor etc.
➢ Major process streams and major instruments and controls are only shown
➢ Process streams are numbered and their flow directions will be represented.
➢ Equipment tag numbers are shown with their rated capacity, overall dimensions, design pressures and
design temperatures
➢ Legend of all equipment’s and instruments are shown either on same sheet or on a separate common sheet
depending on the size and complexity of the project.
➢ PFD forms the basis for developing the plot plans as piping studies for all major lines can be carried out on
its basis.
➢ Diamond symbol located on the lines represents the stream number, any number of streams can enter and go
out of the process that will be identified by unique numerical value.
Area code
400
▪ P101A/B
P – Pump
100 – Process area in the plant
01 – Pump number
A/B – Running and back up pump
4
V – Pressure control valve
Stream Number 100 – Process area in the plant
01 – Control valve number
January 11, 2021 | Slide 20
Piping and Instrumentation Diagram
➢ PID shows all of piping including the physical sequences of branches, reducers, valves, equipment,
instrumentation and control interlocks.
➢ It is used for design, installation and day to day maintenance of the control system and also crucial for plant
operator to go through how the valves are used in the control of the process.
➢ Valves Cv, stream trap with hot and cold insulation are marked.
➢ There are two methods to illustrate when pipes cross on drawings but are not physically connected. Either a small
hump to show one going over the other or break one of the lines very near the other to show it going under it.
➢ This is not a physical representation of the actual pipes. It is merely a method to keep the lines separate when they
must cross in the drawing
Electrical signal
Pneumatic signal
• Typical functions are display, record, transmit and control. These instruments are identified by up to five
letter and minimum of two
➢ There are standard symbols used to represent the component in these diagrams. It is important to note that
these symbols are NOT to scale and are NOT dimensionally accurate.
➢ These symbols are also labelled with words, letters and numbers to further identify and specify the
components that they are representing.
➢ Symbols used could vary from company to company
➢ PID do not represent the physical locations and proximity of the each component
➢ The purpose is not to serve as a floor plan or map of the system, it is to illustrate the process of the system
End connection
Examples:
• Example 1: 3’’-P-12007-A11A-H30
3 inch, fluid service, unit/facility no 12, serial no. 007, piping service class A11A, Hot insulation of thickness 30 units
• Example 1: 2”AARX-304S/S-1”F
2” dia., Type 304 stainless steel pipe in acetic acid reactor discharge service, insulated with 1” of fiberglass insulation