Professional Documents
Culture Documents
Plastics Engineering
September 2016
CONTENTS
VOLUME 72 ■ NUMBER 8 ■ SEPTEMBER 2016
FROM SPE
DESIGN NOTES
12 Power Drive
By Patrick Toensmeier
The desire to reduce vehicle weight is accelerating the development
and use of high-performance thermoplastics for underhood
applications
12
28
K 2016 Preview
Gearing Up for the World’s Largest Plastics Show
By Jon Evans
To whet your appetite, we offer up a small sampling of the vast
array of innovative products and technologies that await the
200,000 visitors to K 2016 in Düsseldorf from Oct. 19-26
왔 Air bags
Powertrain 왔 왗 Safety systems
왗 Tire cord
Eco
왖 Clips & Fasteners For
R86
왖 Exterior PA6
Cooling systems 왖 recy
betw
1010 Travis Street, Suite 900, Houston, TX 77002, United States +1 888 927 2363
© 2016. ASCEND PERFORMANCE MATERIALS and VYDYNE are trademarks of Ascend Performance Materials Operations LLC.
These trademarks have been registered in jurisdictions throughout the world, including the United States of America and the European Community.
01-05 contents_editorial 8/19/16 8:51 AM Page 3
Ascend Performance Materials is the world’s largest fully integrated producer of nylon/PA66 resin and a global
leading supplier of nylon 66 fiber to the airbag and tire cord industries. With more than 60 years of PA66 materials
expertise, Ascend is strategically focused to help automotive manufacturers innovate and optimize their designs
to meet future regulatory, technical and cost requirements.
A Global Leader in
uto Global Performance PA66 Solutions for
Automotive
Global OEMs and Tier suppliers trust Ascend Applications Emission systems 왔
왗 Safety systems
CONTENTS
CONTENTS
38
Technical Paper: Joining Technologies
How to Select the Right Process for Joining Your Underhood Parts
By Craig Birrittella
A variety of technologies exist to execute the welding and joining of
plastics parts. In this article, Branson Ultrasonics helps you to
determine which one is right for you.
CONSULTANT’S CORNER
INSIDE SPI
38
58 The Dawn of Commercial Thermoforming
By Stanley R. Rosen
Industry veteran Stan Rosen reflects on how the thermoforming
industry got its start some 80 years ago, and what developments
have helped shaped the modern-day thermoforming sector.
DEPARTMENTS
64 Industry News
80 Market Place
72 Industry Patents
By Dr. Roger Corneliussen 82 Editorial Index
76 Upcoming Industry
Events 84 Advertisers Index
64 78 Energy-Saving Tip
By Dr. Robin Kent
FROM SPE
Preparing to reflect,
and to forge ahead
T
By Wim de Vos
ime flies by. The pace of innovation quickens. Product careers 20-30 years ago as
cycles shorten. Time to market accelerates. And every chemical or mechanical
day our plastics industry helps to advance these evo- engineers. In the future,
lutions. more of our industry’s lead-
The digitalization of processes continues and even virtual tech- ers are likely to come from
nologies can help us to speed up or skip certain steps in the old an information technology
product development processes. Time indeed goes so fast that background. The key
it seems as if NPE 2015 was only yesterday and the K 2013 show aspects of Industry 4.0 are
only last month, but K 2016 is already upon us. information, knowledge
No wonder the theme of this year’s K Show is Plastics Indus- transfer and networking.
try 4.0. Whilst information technology emerged at first to help Not surprisingly, SPE pro-
support some of our industry’s functions, IT now is taking over vides these same aspects —
some of our key functions, and playing a central role in both our although SPE’s knowledge
manufacturing and business processes. transfer and networking currently have a different perspective.
This also has and will continue to impact the types of people This brings us to how SPE will support the plastics industry
we need to run the processes in our factories. We used to need of tomorrow. And tomorrow = next year. In 2017 SPE will cel-
chemists, polymer engineers and mechanical engineers to ebrate its 75th anniversary — marking three-quarters of a
start up new machines, do new trials and run our operations. century of excellence in supporting the plastics and polymer
Human interpretation and manual adjustments always made industry and its individuals. The Oct. 19-26 K Show in Düssel-
a difference. This, for sure will not be the case tomorrow. dorf is a starting point for us to begin our reflection of the past
Our industry will need IT people to run our processes — 75 years and to assess what lies ahead.
whether to simulate product or mold design, calculate prop- This offers us an opportunity to reflect on those volunteers
erties, set up machine and leaders who made what SPE is today. We will acknowledge
parameters or such. All but not dwell on the past. We mostly want to reflect what our
this knowledge will be organisation should be in the next 75 years!
supplied by intelligent We want to have a dialog with you about our common
databases and software, future, how our industry will evolve, what resources it will
which will adapt and require, what kinds of knowledge will be needed and how it will
update our systems and be transferred. Most of all, we want to learn how can SPE con-
processes on a continu- tinue to be your go-to resource for finding whatever you need
ous, 24/7 basis. The in the polymer and plastics industry. From the K Show onward,
search for talent will shift we will be featuring our SPE logo in a Futuristic 75, which will
from finding the best remind us that SPE needs to remain the vehicle for this indus-
chemist or engineer to try for at least another 75 years.
employing the cleverest SPE — our past, our present, your future.
IT process person. _________________________________________________________
This is a paradigm shift. Please help us to reflect and to prepare for the future. Share your
Today, many of our plas- thoughts about the association, its history, and our industry’s
tics companies are led by future, in the Industry Exchange section of SPE’s online forum The
SPE CEO Wim de Vos CEOs who started their Chain: http://bit.ly/SPE_at_75
DESIGN NOTES
J
By Robert Grace
ack Piper and his colleagues at Dresden Optics Pty. Ltd. The company’s co-founders – Bruce Jeffreys and Jason
in Australia want to put a new face on the business of McDermott – describe themselves as frustrated glasses-
eyeglasses. At the same time, they believe strongly in wearers. Because, they note, glasses are annoying. “You lose
environmental stewardship and a circular economy. And so them, you break them. You scratch them. You forget them.
they’re doing their modest bit to drive that concept forward They’re fragile, expensive and hopelessly inconvenient.”
– one set of recyclable glasses at a time. Jeffreys and McDermott decided to do something about
it. They conceived the idea for a new type of eyewear com-
pany in late 2013 and opened their first shop in July 2015.
They were attracted to a craft excellence and to the German
approach to both design and manufacturing. “We admire
how Germany has maintained its traditions, yet has a hyper-
modern, progressive edge,” they said. Hence, the adoption
of the name Dresden Optics (after the German city of Dres-
den) for a startup company in the Sydney suburb of
Newtown.
The founders’ one rule when first assembling its new team,
explained Piper, the firm’s head of research and development,
was that no one was allowed to be from the optics industry.
Piper – the Canberra-born son of United Nations officials –
has lived all over the world, earned a structural engineering
degree from the University of Sydney and did his honors
research in water storage solutions for drought-stricken vil-
lages in the mountains of Nepal.
“Despite having no experience in manufacturing or plas-
tics,” he said recently, “we were determined to do it our
ourselves. The more we learnt about various methods of
manufacturing, the more we realized how much fun we could
have with injection molding. In our ignorance we assumed
that once you had a mold you could just throw anything you
liked in there so we started mucking around with recycled
Dresden Optics offers a single style of eyeglass frame, with
interchangeable parts. It prides itself on its vast array of col- plastics and bioplastics and realized that though anything
ors – some are one-of-a-kind because they choose not to might be a bit strong, there was a lot out there that we could
fully purge the injection press between runs. get away with.”
The Dresden team’s vision was to create simple yet stylish glasses cases.” instead of a classic screw hinge, the frustrating
eyeglasses that were very durable, lightweight, inexpensive weak point on most glasses, Dresden frames have a plastic
and made locally. The injection molded plastic frames – made hinge ‘pin’ that allows one to interchange any parts without
from Swiss compounder EMS-grivory’s grilamid TR90 nylon the need for tools, and the arms and frames can be pieced
– are fully recyclable. together in any combination. The firm currently makes its
Dresden also has been experimenting with making eyeglass hinge system from a bio-based copolyester called Ecozen,
frames from recycled waste plastics recovered from the fol- which it sources from SK chemicals in South Korea.
lowing diverse sources: low-density polyethylene milk bottle The firm already is selling glasses made from the above-
lids, high-density polyethylene keg caps, and polypropylene noted types of recycled plastics and, by working with
takeaway containers – all from newtown cafés and brewers; companies such as compounder Duromer Products Pty. ltd.,
recycled PET (rPET) from a local recycler; and recycled nylon- they continue to work to achieve 100 percent recycled content.
6 ghost fishing nets from a Byron Bay marine debris collector. Separately, Dresden is thrilled with its recent success with
They’ve also explored using a castor-oil-based bioplastic from using discarded fishing nets, washed up on the beach in arn-
Evonik. hem land on the country’s northern coast. “Our ghost net
The company trusts that when consumers who buy a pair nylon-6 frames are fantastically strong at the weld lines,” said
of their low-cost, recycled-plastic frames will be willing to trade Piper, “despite [the waste plastic] having floated around the
off a little in product durability to be part of the environmental Pacific for years on end.”
solution. Over the coming year, Piper said, the firm plans to launch
“Taking out the technical jargon,” Piper said, “our durability a number of “ranges,” but unlike others in the eyeglass industry,
standards are all about that unfortunate basketball to the all will be of the same style. “What’s new with each range is
face in the school yard.” He noted that playing with many recy- instead the material and story behind them. … There is so
cled materials brings a few challenges, and that Dresden is much to be recycled with so many stories to tell,” Piper notes.
still searching for the right additive to increase the strength He explained that his company’s eyeglass system is built
of the weld lines in the frames made from recycled lDPE milk around a single frame style in four sizes in a vast array of col-
bottles and HDPE keg caps. it has partly addressed the strength ors. customers find the best fit in the color combos that they
problem by blending polypropylene with the polyethylene, choose. all parts are interchangeable.
but that makes end-of-life recycling a bigger challenge. The project began with Dresden asking Sydney-based indus-
So Dresden has set up a closed-loop system with Melbourne- trial design firm Vert to research australians’ face shapes and
based Replas australia, which can successfully recycle such sizes and test frame styles via 3D-printed prototypes. One
mixed plastics into useful products such as outdoor furniture classic favorite has become Dresden’s universal frame. From
and decking. Over the past 20 years, Replas has grown from there, they realized that frame sets could easily be customized
a waste collector and mixed-plastics recycler into one of the with interchangeable parts. The result was four frame
country’s leading plastic product manufacturers in its own sizes and four lengths of arm, to accommodate different fits.
right. The system allows customers to customize their look by
Piper says that, “So far we’ve produced fully recyclable changing out frame and arm colors and materials. as for the
glasses, even replacing the hinge with a plastic pin, so that interchangeable lenses – supplied by Zeiss Vision care, a local
with our take-back program all our glasses at the end of their arm of the century-old german optics pioneer – Dresden
life – along with our industrial waste – will be turned into cuts them in-store to allow for additional flexibility, function-
Dresden sources its used plastics from many sources – from LDPE milk bottle lids (above left) and HDPE beer keg caps, to PP
takeaway food containers and nylon 6 fishing nets (above right). Sydney-based automotive supplier Astor Industries molds the
frames (above middle).
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COVER STORY
Power Drive
Weight-reduction goals accelerate the development and use of
high-performance thermoplastics for underhood applications
By Pat Toensmeier
Ford used materials substitution to trim 800 lbs off this Focus, in a project co-funded by the U.S. Department of Energy.
Photo credit: Ford
M
aterials substitution is gaining traction in an increasing num-
ber of critical automotive areas, as OEMs take advantage of
evolving thermoplastic technologies to achieve ever-higher
levels of component performance.
Many advances are focused on groundbreaking applications in
engines and powertrains. OEMs are tapping the properties of a new
generation of high-performance engineering resins to replace met-
al and some polymers in engines, transmissions and other powertrain
components with thermoplastics that withstand harsh end-use con-
ditions, notably heat.
An important factor influencing this is ongoing efforts to Regulatory initiatives and global sales also narrow differ-
reduce vehicle weight. Regulatory initiatives such as the ences in automotive development and, in a manner of
CAFE (Corporate Average Fuel Economy) program in the U.S. speaking, level the playing field when it comes to material
and the Euro 6 exhaust gas standard in the European Union requirements.
are pushing OEMs to design vehicles for greater fuel effi- “Traditionally, European automakers have held a lead in
ciency, with the ultimate aim of reducing carbon emissions. innovation due to the regulations they deal with, but U.S.
As a result, automakers in North America, Europe and Asia automakers are catching up,” says Scott Schlicker, power-
are refining designs to comply with these and other man- train market segment manager at BASF. The result is that
dates by reducing component weight, sometimes only by a most high-performance automotive thermoplastics, no mat-
few grams or ounces. ter where they are developed, have broad global applicability
CAFE standards call for 54.5-mpg fuel ratings in cars and for auto OEMs whose needs are increasingly the same.
light-duty trucks by model year 2025. This figure is an aver- In addition to the properties of lightweighting, heat resist-
age for a carmaker’s fleet rather than a goal for each model, ance, and acoustic and vibration management, OEMs are
and is based on mileage tests under ideal conditions. The specifying new-generation thermoplastics with other prop-
actual figure most vehicles achieve, analysts say, will be erties in mind. These include:
around 36 mpg. • Part consolidation. While a traditional benefit of plas-
Predictably, weight reduction creates tradeoffs in per- tics, in underhood and powertrain applications it
formance, especially under the hood. Small engines, for potentially eliminates bolt-on components—usually of
example, are fuel efficient, but have less power, and con- metal—that add weight to a vehicle, as well as costly
sumers do not want underpowered cars. OEMs, notably in secondary finishing and installation steps during fabri-
Europe, get around this by turbocharging small engines to cation.
boost horsepower. This increases engine compartment heat, • Rapid process cycles. Since many thermoplastics are
along with noise and vibration. As a result, for passenger injection or blow molded, parts can be made faster,
comfort resin suppliers are formulating thermoplastics to more precisely and, importantly, more economically
resist high underhood heat, as well as control NVH (noise, than if cast in metal and finished to spec.
vibration and harshness) acoustics generated by tur- • Sustainability. Most thermoplastics, even those with
bocharging. glass or carbon fiber reinforcements, are recyclable and
The ability of thermoplastics to meet such multiple require- can be reused in lower-performing parts, whether in
ments is especially important as automakers add universal automotive or other industries.
engines and powertrains that are designed for use around • Standardization. Major resin producers with global
the world, rather than particular countries or regions. operations maintain they can supply materials any-
COVER STORY
Power Drive
where in the world with consistent specifications and Polimotor, the concept has been around since the early
costs for universal engines, powertrains and other com- 1980s. The brainchild of Matti Holtzberg, president of Com-
ponents. posite Castings LLC of West Palm Beach, Fla., Polimotor 2, as
The ongoing developments in high-performance ther- the current design is called, seeks to develop a polymer-rich,
moplastics—many of which will be on display in October at 2,000cc (122-cu.-in.) engine that weighs 138 to 148 lbs, or
K 2016 in Germany—are giving automakers the tools they some 90 lbs less than a standard metal production engine
need to rethink ways in which engine and powertrain com- of the same size.
ponents can be designed for diverse needs. The fuel-injected Polimotor 2 is a four-cylinder, 16-valve,
double-overhead-cam engine. Holtzberg says it will gener-
ate 280 hp in a racing version and 180 hp in a street model.
Resurgent Polymer Engine He plans to install the racing engine later this year in a Stohr
Resin supplier DuPont has said that eliminating 110 lbs of WF1 Sports Racer, which is manufactured by Dauntless Rac-
vehicle weight would reduce CO2 emissions 5 grams/km ing Cars of Vacaville, Calif., and test performance in races
(0.6 mi.) and raise fuel efficiency by up to 2%. sanctioned by the Sports Car Club of America.
In the U.S., this would generate major benefits in lower Holtzberg selected the Stohr WF1 because it is lightweight
carbon emissions and fuel consumption, based on car and and configured for four-cylinder engines. Making extensive
light-duty truck sales. Figures developed by the Automotive use of carbon fiber in its construction, the car weighs just
News Data Center show the tally for vehicle sales in 2015 at 780 lbs and has a 97-in. wheelbase.
just under 17.5 million, up 5.7% from 2014, and a 15-year The Polimotor engine, despite some reports, is not entire-
high. ly made of plastics. Metal parts include the crankcase,
So imagine the environmental impact if another 90 lbs camshaft, pistons, cylinder sleeves and cylinder bores.
was extracted from the engine alone. However, the engine block, cam block and oil pan are fab-
This is one goal of an ongoing project to develop a com- ricated with an undisclosed thermoset resin in a special
mercially feasibly polymer-rich automotive engine. Called process Holtzberg developed. He declines to provide details
COVER STORY
Power Drive
The sintered PA6 plenum chamber can be used with tur- Ecoboost engine. The LCF components save 4 lbs per engine,
bocharged metal engines and resists 250°F, though the he reports, and provide a per-component mass savings of
Polimotor 2 engine will generate heat in the 150 to 200°F 23% for the front cover and 33% for the oil pan.
range. The value of the composite parts can be enhanced by
Solvay is also looking to apply its expertise in high-heat component integration during molding and reduced man-
plastics to electric vehicles. “High-temperature materials will ufacturing steps compared with aluminum.
allow electric cars to operate at higher temperatures, which Among grades BASF has developed for high-heat auto-
means they can get greater power density in batteries and motive applications is Ultramid Advanced N polyphthalamide,
extend their range,” Baleno says. a line of reinforced (short- or long-glass fibers) and unrein-
forced compounds including flame-retardant grades.
During a pre-K conference in June in Germany, BASF offi-
New Materials Save Weight cials said the Advanced N line of PPA exceeds the properties
Several years ago the U.S. Department of Energy (DOE) of conventional PPA—glass-transition temperature is 125°C,
launched and co-funded the Multi-Material Lightweight Vehi- double that of standard grades, and constant mechanical
cle (MMLV) project with Ford and engineering and prototype properties are maintained up to 100°C. The grades are
specialist Vehma International. The goal was to develop a reportedly easier to mold, with short cycle times and wide
vehicle that achieves significant weight reduction by mate- processing windows.
rials substitution. The heat-resistant properties of the PPAs meet the needs
The result was a Ford Fusion modified with substitute mate- of such turbocharged engine parts as integrated charge air
rials including thermoplastics that trimmed more than 800 coolers, air intake manifolds and turbo ducts, where air input
lbs from the car’s original curb weight of almost 3,500 lbs. and output temperatures range from 170 to 210°F.
The latest MMLV initiative involves DOE working with BASF BASF noted at the conference that Ultramid Advanced N
and molder Montaplast of North America Inc. to develop resins could be used “to design lighter, smaller and stronger
advanced composite powertrain components. components for challenging environments where other
BASF, says Schlicker, formulated a long-carbon-fiber (LCF) materials reach their limits.” These include “structural parts
PA66 composite called Ultramid XA-3370 to replace a cast alu- near [an] engine and gearbox in contact with hot, aggres-
minum front cover and structural oil pan on Ford’s 1.0L GTDI sive media and different fuels.”
BASF’s Endure PA66 is used in an air-intake spacer to replace A charged air cooler inlet uses heat-stabilized Vydyne
aluminum (left). The spacer has molded-in holes that create PA66 from Ascend to withstand high operating
turbulence for better mixing and temperature control. temperature and pressure.
Photo credit: BASF Photo credit: Ascend Performance Materials
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12-21 Cover Story Toensmeier_046854 IndustryNews.QXD 8/19/16 9:12 AM Page 18
COVER STORY
Power Drive
Schlicker says that BASF has developed injection moldable In development is a PA66 grade that withstands 3,000
PA6, PA66 and PA66/6 grades for the high pressure and tem- hours of aging exposure at 210°C. A patent search is under
perature that turbocharger components must withstand. way, Jeszke says, and the material is “on the horizon for us.”
Depending on the base polymer and stabilization system, grades Ascend’s expertise in polyamide formulations extends to
resist heat aging to 220°C and have high burst pressure and related requirements for underhood parts. Vydyne R533H
weld strength. Ultramid Endure PA, for example, withstands is a PA66 grade tailored to resist calcium chloride, a road
constant-use temperature of 220°C and peaks to 240°C. salt used in some countries including northern parts of the
In one application an OEM used a grade of Endure PA66 U.S. and Canada in place of sodium chloride. Calcium chlo-
to redesign an air-intake spacer on a turbocharger. The new ride can cause premature cracking in PA parts under load or
part, which replaces aluminum, has molded-in holes that pressure.
create air turbulence for better mixing and temperature The company also supplies a highly filled grade of PA66
control. called R550H to replace metal in engine mounts. Jeszke says
BASF also supplies Endure PA blow molding grades. this has a 40 to 65% loading of barium sulfate, dense filler
Notable among these, Schlicker says, is D5G3BM, a heat- that prevents underhood noise from being transmitted to a
stabilized, 15% glass fiber-reinforced PA66 with continuous- passenger compartment. It can also be used in transmis-
use temperature of 220°C and peak to 240°C. Intended for sions to dampen the noise of shifting gears, and even in
engine pipes and ducts, benefits include high melt stability, power seats to silence the inflation of a lumbar support. The
which maintains parison length and wall thickness during material isn’t less heavy than metal, he remarks, but is qui-
blow molding, and acoustic properties. eter, and so appeals to high-end car manufacturers.
The first use of grade D5G3BM, Schlicker notes, is on an DSM Engineering Plastics, meanwhile, commercialized
engine with a heat-resistance requirement of 200°C. He Arnitel HT copolyester elastomer for flexible blow molded
declines to identify the part or OEM but says the applica- charge air ducts. The material allows cost-efficient, one-step
tion will be at the K show. production of parts with a single resin, rather than the mate-
Tailoring PA Properties
Polyamides, of course, are dominant in underhood appli-
cations. Phil Jeszke, automotive segment leader at Ascend
Performance Materials, a global nylon supplier, says 1.3 bil-
lion lbs of PA66 is used worldwide in 80% of underhood,
engine-cooling and powertrain components. Since 2009, he
adds, demand has more than doubled.
These applications are, consequently, major R&D areas
for Ascend, especially as they pertain to turbocharged
engines. “As we map this space and identify performance
requirements, we develop different property retention char-
acteristics,” Jeszke says.
Recent developments include glass fiber-reinforced Vydyne
PA66 grades heat stabilized for such parts as radiator end
tanks that withstand 1,000 hours of aging exposure at 125
to 130°C, or resist 2,000 or 3,000 hours at 115 to 125°C.
Other critical materials include H series Vydyne resins for
air ducts on charge air coolers, a turbocharger component
that reintroduces cooled exhaust gas to an engine. Jeszke
says these grades, R530, R535 and R550 (the last two num- A new grade of Arnitel HT copolyester elastomer from DSM
bers indicate glass-fiber loading), resist 190 to 210°C exposure allows one-piece blow molding of charge air ducts, with
on the inlet side of a charge air cooler and 170 to 190°C on improved parison control.
the outlet side. Photo credit: DSM Engineering Plastics
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12-21 Cover Story Toensmeier_046854 IndustryNews.QXD 8/19/16 9:12 AM Page 20
COVER STORY
Power Drive
Noise Abatement
Turbocharged engines and smaller engine compartments
mean effective management of NVH acoustics plays a grow-
ing role in design.
Dow Automotive Plastics is addressing this with a
polyurethane foam hood liner material that combines low
density—15 grams/liter—and low weight with sound-damp- Specflex PUR foam from Dow is designed for NVH acoustic
ening properties. Called Specflex, the system is designed management in hood liners and engine parts.
for a range of acoustic needs, says Esther Quintanilla, Euro- Photo credit: Dow Automotive Plastics
pean marketing manager for interior and underhood.
Specflex foam can be applied to the underside of a hood,
typically as a part of a multilayer thermoformed structure,
on top of an engine, on the back wall of the engine com-
partment, applied to a transmission tunnel as an insulator, Specflex, which can be foamed into 1-meter-sq. (3.3-ft.-
or used in carpet and dashboard systems. sq.) blocks, offers consistent properties no matter where
The material replaces melamine and polyolefin foams and sections are cut—from the top, middle, bottom or sides of
other options. In addition to acoustic properties, the PUR foam a block. “Since every cut can constitute a different part of a
has reduced amine content and thus lower emissions than hood liner, it’s important that performance be the same
most conventional foams, as well as good flow and fast cure. throughout,” Quintanilla says.
Specflex is a three-component, water-blown system con- Foam formulations are customizable to end-use specifi-
sisting of Dow’s Voranol 4701 polyether polyol, isocyanate cations.
and catalyst. The polyol is tailored for semi-flexible molded Dow is working with OEMs to qualify Specflex foam for
foam and consistent properties. global use.
a pure solution
A revolutionary new liquid polymeric phosphite stabilizer
· Contains no alkylphenols
· TNPP alternative
AUTOMOTIVE COMPOSITES
Automotive Composites:
Mass Reduction for Mass Production
Reinforced plastics lower weight, improve handling and performance,
and boost safety on passenger cars
By Peggy Malnati
L
“ ightweighting” is the mantra du jour in the automotive of design, material and process technologies that reduce
industry these days, especially for those designing and mass on anything from wiring harnesses to seat structures
producing parts. As the industry passes the midpoint to chassis components is growing. It’s a good time to be
phase-in of the much stricter fuel-efficiency and tailpipe involved in automotive plastics and composites.
emissions standards of 2025, OEM interest in and support As is so often the case, replacing heavier materials with com-
posites to reduce mass isn’t the only benefit that automakers
and their tier suppliers gain. Generally, they also benefit from
far greater design freedom (including parts consolidation
with reduced assembly time and costs, and carryover savings
in inventory storage/tracking and warranty claims); elimination
of corrosion (and occasionally the paint and primer that pro-
tect against it); increased damage resistance (and often
improved crashworthiness); lower noise/vibration/harshness
(nVH) for a quieter ride; and lower tooling and part-produc- a typical SMc recipe involves use of resin – in this case,
tion costs. unsaturated polyester supplied by aOc llc of collierville,
another indirect benefit is so-called “mass decompounding.” Tenn. – as well as additives, chopped fiberglass, and mineral
By reducing the weight of a hood or decklid/liftgate, for exam- fillers (usually calcium carbonate, or cacO3). lower-density
ple, other mass can be removed from the assembly by going grades of SMc often have some portion of cacO3 replaced by
to lighter hinges, latches and struts, helping cut mass and costs hollow glass microspheres, which are more costly and require
further. The applications that follow are good examples of the more care during compounding and molding because they are
many benefits that come from mass reduction by using com- sensitive to process conditions and can crush. cSP researchers
posites. Each part was a finalist, category winner, or grand believed that if they could reach a density of 1.2 Sg with their
award winner in the 2015 SPE automotive innovation awards SMc, they could directly compete cost wise against aluminum,
competition. while offering the benefits of much lower mass, elimination of
rust/corrosion, better energy absorption in low- and high-
speed crashes, and far greater design freedom ― a boon to
Improved adhesion while saving mass designers on cars sporting the kinds of compound-curve
With all the pressure to cut weight from vehicles, much time styling that epitomizes corvettes.
and effort are focused on finding ways to trim a few grams to given the sensitivity of the microspheres, cSP researchers
a kilogram of mass from auto parts. However, a reformulated, sought a tougher, higher performance product (which they
lower-density grade of sheet-molding compound (SMc), eventually sourced from 3M co. of St. Paul, Minn.), and they
formulated and compression molded by continental Structural also set out to improve interfacial adhesion with the matrix.
Plastics (cSP) of auburn Hills, Mich., has reduced mass an after much trial and error with a scanning electron microscope
average of 9 kg (20 lbs.) on a total of 21 exterior body-panel and different sizing chemistries, cSP developed a formulation
assemblies for 2016 model year chevrolet corvette sports cars in-house that not only greatly improved part performance, but
from Detroit-based general Motors co. Reportedly, this was also offered visibly better matrix adhesion under the
accomplished without lowering mechanical performance or microscope.
necessitating process or tooling changes.
The new tough class a grade, which cSP calls Tca Ultra lite,
has a specific gravity (Sg) of 1.2, a value the company says is
28% lighter than its Tca lite 1.6-Sg, mid-density grade, and 43%
lighter than conventional 1.9-Sg SMc. cSP also reports that the
formulation is equally appropriate for painted, class a
applications such as the corvette painted body panels, as
well as for non-visible structural applications.
AUTOMOTIVE COMPOSITES
As an added bonus, that work helped researchers better are required. Better still, CSP claims its numbers show that
understand long-standing issues with paint adhesion on TCA Ultra Lite saves money vs. aluminum even at production
certain SMC parts. The problem, it turned out, wasn’t the volumes as high as 350,000-400,000 vehicles per year.
strength of the bond between paint and part surface, but
rather between the matrix and microsphere surface. By
strengthening the latter, the former was improved as well, Damping sound at lower weight
leading to better part bonding with paint and adhesive. Still Engine-compartment partition walls help keep engine noise
another formulation change that helped reduce mass without out of the passenger compartment for a more comfortable
loss of mechanicals was switching to ME1975 fiberglass, a ride. In addition to good NVH values, such parts also need
new multi-end glass roving from Toledo, Ohio-based Owens stiffness and strength, the durability to last 161,000 km
Corning that is specifically formulated for use in unsaturated (100,000 miles), and thermal stability to 160°C (320°F), since
polyester SMC where high strength and corrosion resistance they are mounted near the exhaust system. A composite
engine-compartment partition wall has replaced stamped
steel on 2015 model year Hyundai Genesis luxury sedans
from South Korea’s Hyundai Motor Group. The steel part
offered good stiffness, strength, dimensional stability and
sound insulation, but was heavy and needed paint to prevent
corrosion. Injection molded neat plastic was cost effective,
but had poor NVH values, dimensional stability, stiffness, and
strength.
Researchers experimented with combinations of polymer
(Kopla KDX 1065 PA 6/6 resin from South Korea’s Kopla Co.
Ltd.), reinforcements and fillers to improve performance of
the plastic option. They compounded combinations of short sold with full warranty coverage. The single-piece, painted
and long glass fiber with several mineral fillers (barium wheel is made by infusing a dry carbon fiber preform with a
sulfate (BaSO4), iron oxide (FeO), and wollastonite (calcium proprietary resin system via the resin transfer molding (RTM)
inosilicate/caSiO3). The formulation with the best balance of process.
mechanicals, nVH, and weight featured 15% long-glass fiber System supplier, material processor, and tooling supplier
and 50% BaSO4. The patent-pending application is supplied carbon Revolution Pty. ltd. of Waurn Ponds, australia, does
by nVH Korea using tools supplied by Hyundai. not only does say it uses a high-Tg resin to meet extreme track performance
the new part reduce mass by 20% without increasing costs, where brake-rotor temps can reach 900°c (1,652°F). This
but it also improves sound damping by 8 dB while reducing necessitated use of a novel ceramic thermal barrier applied
part count and assembly time, and eliminating the cost and via plasma arc to the inner barrel surface and back of the
environmental issues of paint. spokes. The polymer also provides high yield stress and
elongation, and abrasion and weathering resistance. carbon
Revolution designed the closed-cell, foam-filled spokes for
Reduced mass, improved handling maximum stiffness at low weight, while aluminum lug seats
if you’ve been around the automotive industry for a while, and backer plates are slip-fit (via c-clips) around the
you’ve seen many attempts to make composite wheels on composite for a robust joint after machining bores into the
passenger cars work ― with lots of development effort and wheel. The manufacturer even embeds a radio-frequency
marketing promise, but few commercial successes. However, identification chip in each wheel to record and track
that’s changing with a new wheel introduced last year by manufacturing and quality history. Replacing aluminum
Dearborn, Mich.-based Ford Motor co. as standard equipment with a composite reduced wheel weight by 27 kg (59.5 lbs)
on its 2016 model year Ford Shelby gT350R Mustang. The per car and lowered rotational inertia by 40%, thereby pro-
product is said to be the first high-volume, original-equipment, viding faster, more responsive steering, and improved
carbon fiber-reinforced composite wheel designed to meet all acceleration and braking.
OEM requirements and quality standards, and produced and
AUTOMOTIVE COMPOSITES
K 2016 preview:
Gearing up for the
world’s largest
plastics show
I
By Jon Evans
nnovation will be the word on everyone’s lips at this year’s K 2016 trade
fair, taking place in Düsseldorf, Germany, from Oct. 19-26.
“Innovative products are the most important asset in a competitive
environment,” says Werner Matthias Dornscheidt, president and CEO of
Messe Düsseldorf, which organizes and manages the K fair. “Only those
who can offer new technologies that bring real benefits to their customers
will be able to hold their own against strong competition.”
K 2016 — the world’s largest plastics fair — will feature 3,200 exhibitors from 60 nations and more than 200,000 visitors over 8 days
Covestro expert Roland Wagner observes the manufacture of a small component in Covestro´s new 3D printing laboratory at
its headquarters in Leverkusen, Germany. Photo courtesy of Covestro LLC.
Meanwhile, speaking at the company’s recent K 2016 pre- In its first K fair since being spun-off from Bayer AG and
view, Covestro LLC CEO Patrick Thomas said, “Our main changing its name, Covestro will be presenting a whole host
objective is to drive energy efficiency, improve people’s lives of new plastic materials, including materials for three-dimen-
and create value, while at the same time reducing our own sional (3D) printing. These will include various types of plastic
use of fossil resources. But developments of this kind are filament for a form of 3D printing known as fused filament
impossible without intensive and targeted innovation.” fabrication, in which the plastic filaments are melted before
As the premier trade fair for the plastics and rubber indus- being laid down in a desired pattern. The filaments range
try, the triennial K fair has always been a prime venue for from flexible thermoplastic polyurethanes (TPU) to high-
companies to unveil their latest innovations. But K 2016 strength polycarbonate.
will place a major focus on four innovative themes of par- In addition, Covestro is able to offer TPU powders for
ticular importance for the future development of the global another form of 3D printing known as laser sintering, in
plastics industry – new materials; lightweight solutions; which the powders are laid down in a desired pattern before
resource efficiency; and industry 4.0. being solidified with a laser. Laser sintering is conventionally
These themes will feature heavily in both the Innovation used with metal powders, but TPU allows it to produce
Compass, which will bring together some of the innovative more flexible products, such as soles for shoes.
technologies being developed by the plastics industry, and The company also is actively developing a whole range of
the Science Campus, which will showcase the latest plastic new materials for 3D printing, with the aim of expanding
research being conducted by universities and research insti- beyond the around 30 or so materials that are currently avail-
tutes. The four themes will also feature in a special show able. To this end, the company recently opened a new 3D
called ‘Plastics shape the future”, which through panel dis- printing laboratory at its headquarters in Leverkusen, Ger-
cussions and multiple media will explore how plastic many. “We want to work with leading partners in the process
innovations will help to solve tomorrow’s challenges in func- chain to further advance these developments,” said Julien
tional, aesthetic and sustainable ways. Other issues such as Guiu, who leads the company’s global 3D printing activities.
marine litter will also be addressed during the show. “These include formulators, 3D printer manufacturers, soft-
As usual, however, the more than 3,000 exhibitors from five ware companies, service providers and of course OEMs.”
continents, spread over the 19 halls of the Düsseldorf exhi- Other companies will be presenting alternative approach-
bition center, will be the main draw of K 2016. But here, too, es for expanding the range of materials available for 3D
the four themes will feature heavily, as revealed in the K printing. For example, Wacker Chemie AG will debut the
2016 preview information that several companies have first ever industrial 3D printer specifically designed for sili-
already put out. cones, which are widely used for medical applications.
Preview
Known as the ACEO Imagine Series K, it employs a drop-on- materials is a solution to some of the biggest challenges of our
demand printing method developed by Wacker, in which time – finding a replacement for finite fossil resources such as
objects are built up by depositing individual droplets of sil- oil and gas and closing material cycles.” Covestro will market
icone on a surface and then hardening them with UV light. these polyols under the name Cardyon and already is work-
Producing medical devices is currently one of the fastest- ing on ways to produce other plastic materials from carbon
growing applications for 3D printing. “In these types of dioxide. Its ultimate aim is to dispense with crude oil as a feed-
applications, silicones can display their favorable properties stock in plastics production almost entirely.
particularly well,” said Bernd Pachaly, head of Wacker’s sili-
cones research and responsible for the ACEO team. “Silicones
are heat resistant, flexible at low temperatures, transparent
and biocompatible.”
In addition to offering this printer for sale, Wacker also is
allowing customers to order 3D-printed silicone parts, by
uploading their own designs in a web shop. These parts
will then be produced in Wacker’s new 3D printing technol-
ogy center, known as the ACEO campus, at its main site in
Burghausen, Germany.
Engel’s novel injection molding technology uses fiber-rein- Covestro is now making polyols for polyurethane foams
forced thermoplastics to produce plastic components with using carbon dioxide as one of the feedstocks at its plant in
walls that are just 0.6mm. Photo courtesy of Engel. Dormagen, Germany. Photo courtesy of Covestro LLC.
easier to process, whether by extrusion, injection molding or energy-efficient technologies. The plastics industry already
even 3D printing. For example, Vinnex 2526 can optimize melt has made great strides in energy efficiency, with modern
and bubble stability during extrusion, while Vinnex 8880 can plastic processing machinery now using 20% to 50% less
enhance the flow properties of melted PLA during injection energy than 10 years ago. To their credit, however, com-
molding and 3D printing. panies are still finding room for improvement.
The primary role of Wacker’s new Genioplast additives is Battenfeld-Cincinnati, which recently adopted the motto
lubrication, thereby allowing the wood fibers that make up to ‘driven by innovation’, will be showcasing several new
75% of WPCs to bond with plastics such as polyethylene, extruders at K 2016, all of which are designed to maximize
polypropylene or polyvinyl chloride during extrusion molding. energy efficiency. For example, the company’s new single-
But Wacker’s novel additives can also enhance the WPCs’ screw extruder solEX NG 75 for the production of polyolefin
physical properties, conferring higher impact strength and flex- pipe offers a completely redesigned barrel-screw combi-
ural toughness and making them more resistant to weathering. nation that allows lower melt temperatures, reducing energy
This move to replace crude oil with carbon dioxide and bio- costs by about 15%.
logical material as feedstocks can be encompassed under “With the design of the new NG series we again prove our
the resource efficiency theme, but many exhibitors are tak- innovativeness,” says Grant Flaharty, Battenfeld-Cincin-
ing a more direct approach to this theme by introducing nati’s chief sales and marketing officer. “We have succeeded
Covestro’s prototype electric car includes holographic films that allow the headlamps and rear lights to be incorporated
directly into the chassis. Photo courtesy of Covestro LLC.
Preview
in developing an extremely powerful and energy-efficient ideal for producing tough but light cases for handheld
processing unit that has not yet been seen on the market electronic devices.
in this form.” Lightweight engineering is particularly in demand by the
Arburg will be presenting its new Allrounder Golden Elec- automotive and aerospace industries, and this need often is
tric injection molding machine, along with 26 others. The met by replacing metal with plastic materials. Royal DSM will
Allrounder Golden Electric is an entry-level electric machine be displaying its expanded range of ForTii high-performance
that employs several innovative technologies for reducing polyphthalamides (PPAs), which it is marketing to automotive
energy demand, including highly efficient servo motors and manufacturers as an alternative to the die-cast metal parts cur-
energy recovery during braking. The company also promis- rently used in the fuel system, chassis and suspension. The
es to unveil more new technologies at K 2016. company claims that replacing die-cast metal with its ForTii
TheAllrounder Golden Electric machine series made its PPAs, which can be reinforced with glass fiber and maintain
debut in March. “This was their mechanical strength at
http://bit.ly/K_Show_goals
to-use control systems, mid Advanced N, this portfolio
on-board sensors and wire- comprises unreinforced PPA,
less monitoring, these and together with PPA reinforced
many other machines presented at K 2016 also embody the with glass fibers and flame retardants. With outstanding
industry 4.0 theme. This theme reflects the manifold effects chemical and heat resistance and low friction and wear,
of digital technology on the plastics industry, and its name BASF says that its Ultramid Advanced N range can be used
refers to the fact that these effects have been likened to a for automotive components that are near the engine and the
fourth industrial revolution. gearbox and in contact with hot oil and fuel.
As well as being easier and more convenient to use, the lat- “Ultramid Advanced N is BASF’s response to the rising
est machines also generate a huge amount of data. In demands on plastics that are employed today under increas-
conjunction with advanced tools for analysis and model- ingly challenging operating conditions,” says Melanie
ling, these data can help to make the plastics industry even Maas-Brunner, senior vice president, performance materi-
more efficient, in terms of costs, time and energy. For exam- als Europe at BASF.
ple, BASF will be showcasing its Ultrasim simulation tool Novel plastic materials are not just being used to replace
for predicting the behavior of polyurethane systems during existing metal parts in conventional gas-powered vehicles,
foaming in both open and closed molds. This allows proces- though, they are also helping to usher in the next generation
sors to spot potential problems with the design and of motoring. At K 2016, Covestro will be displaying a proto-
manufacturing of a component before a mold is made, type electric car, developed in close collaboration with design
reducing development times and costs. students and partners in the automotive industry, that incor-
Many of these new machines also allow plastic prod- porates a range of advanced plastic technologies. These
ucts to be produced with less material than ever before, include: a seamless, homogenous front end to reduce drag;
fitting squarely within the lightweight solutions theme. holographic films that allow the headlamps and rear lights
Engel will be demonstrating an injection molding technol- to be incorporated directly into the chassis; and wrap-around
ogy that uses fiber-reinforced thermoplastics to produce glazing made from transparent polycarbonate to provide
plastic components with walls that are just 0.6mm thick and enhanced visibility.
yet can still sport sophisticated surface decorations. By The innovations on display at K 2016, which three years ago
integrating three processing technologies, this technology attracted 218,000 attendees, have the potential to transform
can transform, overmold and decorate fiber-reinforced much more than just the plastics industry. More event
thermoplastic preforms in a single step, and could prove details are available at http://www.k-online.com.
F
By Nancy D. Lamontagne
oam blow molding will be a trending topic at this year’s upcoming conference, Wolfgang Meyer, president of the
Annual Blow Molding Conference, which features a vari- company, will give a presentation aimed at helping attendees
ety of industry presentations on packaging, medical and understand the effects of foam blow molding on mechani-
industrial applications, machinery and design innovations, cal properties.
and materials and processing. At this SPE event, held in Meyer explains that companies already familiar with blow
Atlanta from Oct. 3-5, several speakers will discuss how molding can add foaming capability without much difficult-
foam blow molding technology has matured in the last few ly. “There is always a training or learning curve, but foam blow
years and how various approaches can help save money and molding is similar to other multilayer processes that are
materials. state-of-the-art today.”
Triple-layer foam
W. Müller USA Inc. supplies customized extrusion heads for
blow molding machines. One of the company’s retrofitting
packages allows converters to add triple-layer foaming capa-
bility to their existing blow molding machines. At the
At the conference, Wolfgang Meyer of W. Müller USA will Bottles produced with W. Müller’s triple-layer foaming tech-
compare the loading capability of foamed and non-foamed nology (right, and inset) retain many of the physical proper-
containers. Courtesy of W. Müller USA. ties of non-foamed bottles (left). Courtesy of W. Müller USA.
Meyer points out that consumer packaging companies that maybe we couldn’t in the past. I’m hoping that our talk
have the greatest interest in foam blow molding, but may not will create some interest in EBAs and help dispel the myth
always have an immediate project or a number of projects that using EBAs is highly complex.”
that would use a foam blow molding system continuously. Bobrov, who works with iD Additives as a consultant,
However, the industrial packaging sector, which is also show- explained that EBAs come as a pelletized masterbatch prod-
ing interest in this technology, may see even more benefits uct that any converter can add to its blending process
from foaming. without additional equipment or sophisticated process mod-
“The return on investment is faster if foaming will save ification. “It can be treated as a regular material because the
more weight per container,” explained Meyer. “Foaming a polymer vehicle is usually very friendly to the materials used
100-milliliter bottle does not produce as much weight savings as a matrix,” he said. “In addition, EBAs are Food & Drug
as foaming a 5-gallon container, but for the 5-gallon container Administration-compliant, and both the agents themselves
the issue of load carrying capability is much different than on and the decomposition products are very neutral. This
a 100-ml bottle.” makes EBAs very suitable for all kinds of food packaging,
During his talk, Meyer will discuss some of the company’s including hot-filled, deep-freeze and refrigerated containers.”
studies on the load properties of foamed blow molded During the presentation, Bobrov plans to discuss the
products. “Everyone seems to quickly get excited at the essentials of polymer selection and principals of formulating
material savings available with foaming, but they always EBAs for a given application. He points out the importance
want to know more about the load capacity,” said Meyer. “We of understanding the temperature of decomposition for
felt the need to investigate this and provide some informa- the foaming agent in order to match it to the temperature
tion about how foamed structures compare to solid profile of the polymer matrix used in the product. The
structures.” decomposition products of an EBA are another important fac-
He plans to talk about how wall density and other param- tor. Materials such as PET that are sensitive to higher
eters such as compression affect the load capacity of blow moisture content will work better with a metal bicarbonate
molded foamed products. While some load capacity is lost blowing agent because the alkyl salt decomposition products
with foaming, the amount that is lost depends on the degree will absorb the water vapor.
of compression and other parameters that are permissible In terms of blowing process parameters, the pressure of
in a specific product. the blowing agent and the timing for using it are key. “Hold-
To help companies better understand the benefits of ing the air back a little bit longer can give the opportunity for
foaming, W. Müller USA’s parent company in Germany is the cells to form before blowing starts, yielding additional
working with European and global companies to conduct improvements in lowering density,” said Bobrov.
sample runs with customer molds for different bottle weights,
etc. They are also working with resin suppliers to fine-tune
resins.
In addition, W. Müller has worked on improving the mix-
ing system in the extrusion head and the way that the
foaming gas is injected into it. “Since we can disperse the
nitrogen gas independently of screw speed, etc.,” Meyer
said, “we believe that this automatically produces better
dispersion and, thus, finer cell structure.”
Foaming agents
At the conference, Nick Sotos, president of iD Additives Inc.
and Sergey Bobrov, president of Poly-Werk LLC, will discuss
extrusion blow molding converting processes that use
endothermic blowing agents (EBA). EBAs are bicarbonates of
alkali, transitional and/or post transitional metals that decom-
pose at wide range of temperatures to yield metal salt,
carbon dioxide and water vapor. EBAs that produce fine, extra
fine, and microfine cells are available from iD Additives.
“The main hurdle to adoption of EBAs is that people think This cross section of a foamed container’s wall shows the
the process is too complicated,” said Sotos. “We’ve come a microfine cell structure that can be achieved using blowing
long way with our product mix, and we’re able to do things agents from iD Additives. Courtesy of iD Additives.
Bobrov said that more and more companies are exploring “One of the things we’re trying to get across during the
opportunities to reduce their carbon footprint, reduce aux- talk is that our clients from a few years ago were ground-
iliary cost of operations, and improve recyclability of their breaking because we didn’t have very much evidence to
products. “In addition to offering these benefits, using EBAs show the success of the technology,” said Dominey. “How-
also greatly improves manufacturability of blow molded ever, now MuCell foaming technology is becoming a more
containers, thus reducing cost of operations that improves mature technology that can be used in new application
profitability,” he said. “EBAs can be used to produce very light, areas.”
very strong articles in an environmentally friendly, very easy One of those groundbreaking clients was Unilever, which
to use way.” applied the MuCell technology to blow molding its Dove
body wash 250 ml bottle. “Unilever publicized its testing and
decision-making process, which has given the MuCell extru-
A maturing technology sion technology as applied to blow molding a great deal of
Simon Dominey, vice president of MuCell Extrusion LLC, creditability,” said Dominey.
will provide an update on foaming technology for blow Through testing, Unilever found that consumers could not
molding. MuCell’s foaming process is based on directly differentiate between foamed and non-foamed bottles
injecting atmospheric gas in its supercritical state. This very manufactured with blow molding. “Our technology can
stable process provides uniform and repeatable product reduce the quantity of material and provide the cost sav-
density and part weight that can increase stiffness at equiv- ings without any visible functional difference,” said Dominey.
alent part weight or decrease part weight at equivalent “With downgauging, a company might save 5% on materi-
stiffness. al but will still need to compensate for how a lighter,
thinner bottle feels when the consumer picks it up. With the
MuCell technology, a company can save 20% material, and
the bottle feels the same as one that is solid.”
Dominey will also talk about Kyoraku Co. Ltd. of Japan,
which incorporated MuCell technology into its own process
for making automotive ducts. “Kyoraku put a lot of effort
into duct design and maximizing the benefit they can get
from the foaming technology,” said Dominey. “They use the
fact that the foaming process makes the plastic thicker
and stiffer to make a very rigid duct that uses significant-
ly less polymer. For the automotive industry, it is a real
win-win because they want to save weight as much as pos-
sible to improve gas mileage.”
Kyoraku’s success is an example of how well the MuCell
technology works in automotive applications, he added.
Many approaches for making cars lighter, such as convert-
ing steel to aluminum, increase costs while foaming can
help make car parts lighter while also lowering cost. The
Kyoraku application also exemplifies how the MuCell foam-
Kyoraku Co. Ltd. of Japan, incorporated MuCell’s foaming
technology into its own process for making automotive
ing technology can be used as an enabling technology.
ducts. Because the foaming process makes the plastic thick- “Companies can get a straightforward savings by letting us
er and stiffer, they can make a very rigid duct that uses sig- guide them, or they can also apply their own knowledge and
nificantly less polymer. Courtesy of Kyoraku Co. Ltd. get even more out of the technology,” Dominey said.
Where P
Packaging & Innovation
vation Meet
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TECHNICAL PAPER
I
t has been more than 25 years since polyamide (nylon) We have seen, for example, high-performance polymers
was first used in place of cast aluminum to mass produce such as PPS and PPA replace metal in assemblies that are clos-
an air intake manifold in the United States. Since then, er than ever to the engine combustion area. Here again,
replacing metal components with plastics in automotive success has been the result of a team approach simultaneously
under-the-hood applications has become a continuing trend. evaluating materials with higher thermal resistance, the pro-
In recent years, key technology drivers, led by fuel efficien- cessing requirements of such materials, and part design.
cy and emissions reduction, have presented tougher challenges, Given such complex challenges, when considering plas-
demanding innovative design solutions that rely on advances tics joining solutions, it is important to understand the
in engineered polymers and processing (see Table 1). advantages and limitations of a wide range of joining tech-
Success so far has been a result of the industry redesigning nologies. Of equal importance, a “process neutral” approach
parts and assemblies for plastics, and not simply replacing met- should be adopted at the outset of the design phase and
al components one by one. Design teams have had to engage maintained while evaluating the many available technolo-
resin suppliers and processing equipment suppliers at early gies. Plastics joining solutions providers should be engaged
stages of development to optimize all aspects of part design, early to help determine the best fit for the application.
resin material and processing. This will dramatically improve the design, manufacturability
and functional perform-
ance of the application,
and will reduce the risk of
Ultrasonic Welder costly redesigns, rework
of prototypes, and sched-
uling delays caused by a
Automotive Under-The-Hood Technology Drivers Challenges
lack of information about
Technology Fuel plastics joining technolo-
gies.
Emissions Safety Environmental Cost
Drivers Efficiency
Following is an overview
Solution Light- Smaller Higher Power Global of certain plastics joining
technologies deployed in
Recyclability
Trends weighting Footprints “Density” Production
under-the-hood applica-
tions that involve
engineered and high-per-
Solution Metal to Part Complex Advanced New / Advanced
formance polymers. We
Needs Plastics Consolidation Geometries Resins / Fillers Processing
Vibration welding uses heat energy generated when one part Infrared welding uses energy that is radiated by gray body
is held stationary while the other part is moved in a linear, emitters mounted on a movable platen. It is a non-contact
back-and-forth motion. The heat generated initiates a con- process in which the parts to be joined are brought close to
trollable meltdown at the interface of the parts. Vibration the emitter platen (approximately 1 mm) as energy is
welding requires that the part interface accommodate the absorbed at the weld interface. The parts are then pressed
relative motion inherent in the process. Typical motion is 1 together, achieving a bond that is controlled during meltdown.
mm in each direction for 240 Hz welding and 2 mm in each Infrared emitters are typically either glass bulb or metal foil
direction for 100 Hz welding. (Fig. 4). To optimize energy absorption in the weld area, the
Figure 2 shows an air intake manifold made from PA6 emitters should have an output energy profile that accom-
GF30. While the geometry is complex, the parts are designed modates the absorption efficiency profiles of the many
so that there is a part-to-part orientation that will accommo- plastics used (Fig. 5). Medium wave emitters have this char-
date the linear motion required by the process. Jagged weld acteristic and are best for plastics joining.
flash and particulates are typical by-products of vibration
welding. “Flash traps” are designed into the parts (Fig. 3) to con-
tain the flash produced during the weld. However, in some
designs, part geometry does not always allow for this method
of flash containment.
Flash trap
captures
particulates
during weld
process
TECHNICAL PAPER
Clean vibration technology (CVT) combines IR preheating (Fig. Laser welding uses energy typically generated by one or
6) followed by a vibration weld cycle. The preheat step more 980 nm laser sources to heat the parts during the weld
enables the combined process to bypass the dry friction cycle. Several techniques exist that deliver the laser energy
phase in traditional vibration welding, which generates the from its source to the plastic parts, including simultaneous,
common particulate and jagged flash (Fig. 7). In CVT welding, quasi-simultaneous, and trace welding. All techniques
the flash produced is clean and compact, similar to that of deploy the concept of through transmission welding, in
IR welding. Figure 8 shows a fluid reservoir requiring a her- which the parts are clamped together as the laser energy is
metic seal, high strength and a clean weld joint. Geometry transmitted through one part and absorbed by the sec-
constraints did not allow for the option of flash traps so weld ond part at the mating interface. The absorbed heat is
aesthetics were also important. conducted across the part interface, thus achieving a con-
trolled melt in both parts.
Laser welding accommodates highly complex parts,
achieves high-strength welds, and in the case of simulta-
neous laser welding, has very fast cycle times. The resulting
weld joint has very little flash and virtually zero particulate.
No relative motion or high-temperature heat sources are
required during the weld process, so parts with delicate
internals are often candidates for this technology. Laser
welding requires parts with good dimensional tolerances and
also requires one part to have a higher transmission/absorp-
tion ratio (at 980 nm) relative to the other. This is usually
accomplished by using selective colorants in the parts.
Figure 9 shows a laser welded electronic control module
that has delicate internals and a very thin wall, creating
Figure 6: IR emitter for CVT application. Contoured metal
foil matches part shape.
very little room for a weld joint.
specimen.
Figure 8: Fluid
Reservoir. PA6 GF25.
Clean weld, hermetic
seal required. Figure 9: Control module PBT.
Other technologies are, of course, available for plastics join- an overall technology evaluation for any application.
ing that remain viable for a number of under-the-hood To illustrate the process of determining the most appro-
applications. These include hot plate welding, spin welding priate plastics joining solution for a particular application,
and ultrasonic welding. While these processes are not consider the coolant manifold shown in Figure 10. Assume
described in-depth here, they are also an important part of for a moment that the part shape has yet to be finalized and
Table 2.
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CONSULTANT’S CORNER
By Jeffrey A. Jansen
senior Managing Engineer & Partner, the Madison group
t
he characteristic properties exhibited by plastics are are formed through a process known as polymerization, in
the direct result of the unique molecular structure of which monomer molecules are bonded together through a
these materials. taking that a step further, the variation chemical reaction that results in a three-dimensional network
within the properties demonstrated by different plastics aris- of long individual polymer chains consisting of smaller repeat-
es from diversity in their structure. Plastics are polymers of ed units.
very high molecular mass. to enhance their properties, they there are two basic types of polymerization reactions —
often contain additives, such as fillers and reinforcements, addition and condensation. addition polymerization is the
anti-degradants and stabilizers, flame retardants and plas- formation of polymers from monomers containing a car-
ticizers. However, the underlying attributes of a plastic bon-carbon double bond through an exothermic addition
material are determined by the polymer. reaction. significantly, this reaction proceeds without the
loss of any atoms or molecules from the reacting monomers.
common materials produced through addition polymeriza-
Polymerization tion include polyethylene, polypropylene, poly(vinyl chloride),
Polymers are macromolecules that are based on a structure and polystyrene as represented in Figure 1.
built up, chiefly or completely, from a large number of similar in contrast, condensation polymers are formed by a step-
structural units bonded together. Often called chains, the wise reaction of molecules with different functional groups.
polymer consists of repeating units, similar to links. Polymers the reaction is endothermic and produces water, or other
Figure 1. Addition reaction mechanism showing styrene monomer polymerizing into polystyrene.
Figure 2. Condensation reaction mechanism showing the polymerization of a polyamide from a diacid and a diamine.
small molecules such as methanol, as a byproduct. Common condensation polymers. Comparing polymers produced via
polymers produced through condensation reactions include the two different mechanisms, addition polymers are gen-
thermoplastic polyesters, polyacetal, polycarbonate and erally chemically inert due to the relatively strong
polyamides as represented in Figure 2. carbon-carbon bonds that are formed. Condensation poly-
Addition polymers form high-molecular-weight chains rap- mers tend to be susceptible to hydrolytic molecular
idly, and tend to be higher in molecular weight than degradation through exposure to water at elevated temper-
atures, through a mechanism that resembles the reversion
of the initial liberalization reaction.
By using different starting materials and polymerization
processes and techniques, polymers having different molec-
ular structures can be produced (see Fig. 3).
The fundamental differences between the properties of
these different types of polymers are attributable to the
varying functional groups within the molecular structure.
These differences include mechanical, thermal and chemical
resistance properties. As such, it is important to select the
correct type of plastic based upon the requirements of the
application.
Intermolecular Bonding
As indicated, polymerization results in the formation of mul-
tiple individual polymer chains made up of repeating units.
A key aspect of polymeric materials is that the chains are
entangled within each other. The individual chains are not
covalently bonded to each other, but instead rely on inter-
molecular forces, such as Van der Waals forces, hydrogen
bonding, and dipole interactions, to keep the chains from
disentangling. This results in a structure that is similar to a
bowl of spaghetti noodles (Fig. 4).
Figure 3. Polymers contain a wide variety of functional Figure 4. Polymer chains consist of a high number of repeating
groups, responsible for the diversity in physical properties. units, and are entangled to form a spaghetti-like structure.
CONSULTANT’S CORNER
Crystalline/Amorphous Structure
Figure 5. The repeating unit of polyethylene consists of two another fundamental characteristic of polymeric materials
carbon atoms with pendant hydrogen atoms. is the organization of their molecular structure. Broadly,
CONSULTANT’S CORNER
Figure 7. DSC thermogram six showing a melting endotherm for a semicrystalline polymer and a glass transition for an
amorphous material.
Plastics continue to be used in increasingly diverse and of the plastic resin, it is essential that the correlation between
demanding applications. Given the cost of product failure, molecular structure and performance be understood. The
it is very important that the right material be chosen specif- difference between success and failure can hinge on the
ically for each situation. Because the base polymer implications of molecular weight, molecular weight distri-
determines many of the critical performance characteristics bution, and crystalline/amorphous structure.
Semicrystalline
• Distinct and sharp melting point ABOUT THE AUTHOR
• Opaque or translucent Jeffrey A. Jansen is senior
• Better organic chemical resistance managing engineer and a
• Higher tensile strength and modulus partner with The Madison
• Better creep and fatigue resistance Group, a Madison, Wis.-
• Higher density based provider of consulting
• Higher mold shrinkage services to the plastics indus-
try. He is an expert in failure
analysis; material analysis,
Amorphous
identification and selection;
• Soften over a wider range of temperature
and aging studies for plastic
• Transparent
and rubber components. A
• Lower organic chemical resistance
senior member of SPE,
• Higher ductility
Jansen also is a past chair-
• Better toughness
man of SPE’s Failure Analysis & Prevention Special
• Lower density Interest Group.
Table 1.
I
Engineering from Plastics Make it Possible®, an initiative spon-
sored by America’s Plastics Makers® through the American We already know that plastics are replacing traditional mate-
Chemistry Council (ACC). rials, due in large part to their favorable strength-to-weight
ratio that allows them to do more with less. We see that in
f a new material were found today that could reduce numerous previous studies and market sectors.
environmental costs compared to existing materials by
nearly four times, imagine what a positive, disruptive Packaging – A study in the U.S. shows that if we were to
force that would be. In the presence of such a force, tradi- replace plastic packaging with alternatives, we would dra-
tional materials would progressively be set aside in the name matically increase the amount of packaging material.
of corporate and planetary sustainability. Alternatives would require four and a half times as much
Well, a new study provides insights for corporate decision material by weight and increase the amount of packaging
makers, policy makers and environmentally minded people used by nearly 110 billion pounds yearly.
into just how disruptive plastics are from an environmen-
tal perspective. Building Materials – Plastics can help save a whole lot of
Disruptive, that is, in a good way. energy over the lives of our homes and buildings. The ener-
gy saved by using plastic materials compared to alternative
materials is approximately 467.2 trillion BTU of energy a
year – that’s enough to meet the average annual energy
needs of 4.6 million U.S. households.
New Study
To answer this question, the American Chemistry Council
commissioned an independent study by the environmen-
tal consulting firm Trucost PLC in London that looks at the
broad environmental costs of using plastics in consumer
goods compared to other materials.
This July 2016 study builds on a 2014 study, also by Tru-
cost, commissioned by the United Nations Environment
Programme (UNEP) called, “Valuing Plastics: The Business
Case for Measuring, Managing and Disclosing Plastic Use in
the Consumer Goods Industry.” That study found that the
“total natural capital cost of plastic used in the consumer
goods industry is estimated to be more than $75 billion per
year.” The cost comes from a range of environmental impacts
such as effects from marine litter and the loss of valuable ALL THE
resources when used plastics are sent to landfills rather
than recycled. RIGHT RESINS
RESINS..
What the 2014 study did not ask is: compared to what?
Trucost’s new study, “Plastics and Sustainability: A Valuation FOR ALL THE RIGHT REASONS.
of Environmental Benefits, Costs and Opportunities for Con-
tinuous Improvement,” provides that perspective. The A capacity for leadership.
report’s authors call it the largest natural capital cost study In what matters most to you.
ever conducted for the plastics manufacturing sector.
The new study expands upon the initial study by includ-
ing transportation as part of the life cycle of products and
When it comes to PET T Resin,, DAK
DAK Americas®
Disruptive Findings
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industr y. Today,
industry. Todaay, tomor row, and well
tomorrow, well into the
These results disrupt the commonly accepted narrative
around plastics—the assumption that traditional materials
future... DAK
future... DAK Americas.
have less environmental impact. In fact, these findings stand dakamericas.com | 1.888.738.2002
that assumption on its head.
One of the likely reasons for these findings, as mentioned
above, is the comparable strength-to-weight ratio of plas-
tics. Alternative materials such as glass, tin, aluminum and
paper can be viable alternatives to plastics in many con-
INSIDE SPI
T
he vote by 52 percent of the European Union to set the terms
United Kingdom to leave the of its withdrawal, a negotiation
European Union—the so-called which some expect may take two
British exit (Brexit)—has sent shock- years or more.
waves across global financial markets Until the U.K. officially withdraws
and ushered in a period of uncer- from the EU, it should be treated
tainty for manufacturers on both as an EU member state in trade for
sides of the Atlantic. The vote could purposes of tariffs and other tech-
further undermine growth within nical matters. Eventually, however,
Europe and potentially around the the U.S. trading relationship with
globe. Given the size of the U.S. economic relationship with the UK will experience increased costs and red tape after
Europe, the U.K. decision may have significant ramifications they have completely withdrawn from the EU. For U.K. man-
for the American plastics industry. ufacturers exporting into the European Union, EU standards
The U.S. commercial relationship with the U.K. and EU and regulations are expected to continue to apply for those
combined is the U.S.’ largest in the world, representing about goods to be eligible for sale, but much as they would nor-
40% of the global economy. Trade of U.S.–EU manufactured mally apply to U.S. exports, rather than to exports from EU
goods reached $836 billion in 2015, and cross-border invest- member companies.
ment equaled more than $5 trillion. Many U.S. companies Regarding the Transatlantic Trade and Investment Part-
with EU operations have headquarters in London, and about nership (TTIP), a major trade treaty currently being negotiated,
17% of U.S.-manufactured exports to the EU are destined it is clear that the Brexit vote will be a drag on the progress
for the U.K. of the deliberations. Prior to the vote, it was apparent that
The U.K. is the ninth largest export market for the U.S. plas- the differences separating the United States and EU in the
tics industry, representing more than $1.3 billion dollars in TTIP talks were larger than the areas of shared objectives
goods in 2015, and our eighth largest import market, with and perspectives. With the U.K. and EU now preparing to
more than $249 million dollars in goods in 2015. While the enter into a multi-year withdrawal negotiation, there are
day-to-day operations of businesses in the United Kingdom, serious questions as to whether the TTIP talks can result in
European Union or the United States may not be directly a truly meaningful and comprehensive agreement or even
impacted by the Brexit immediately, all businesses engaged any deal at all. In addition, the loss of the UK voice within
in the transatlantic market should prepare for the changes the EU will likely make it even more difficult for a deal to be
that are inevitably coming. struck. On a positive note, there is the possibility of a U.S.-
It’s expected that what the Brexit means for manufactur- U.K. free trade agreement, but this opportunity would still
ers in the United States and their partners in Europe won’t be years away at this point, and only be a fraction of the size
be fully known for years. Soon the United Kingdom will begin of an ideal TTIP agreement with the entire EU.
negotiations with the EU under Article 50 of the Treaty of the All this said, although it is a significant event with notable
economic consequences, the Brexit vote is unlikely to usher But the causal relationship between political and eco-
in a recession. It is very clear that all of the key players stand nomic uncertainty and negative market and trade
ready to intervene in the financial markets vigorously to buoy consequences is well established. The Brexit will most like-
their economies as required. Specifically, in the U.S., the Fed- ly have impacts akin to past Eurozone crises, at least in the
eral Reserve likely will cut interest rates rather than raise short term. It will shake financial markets and consumer
them, counterbalancing any negative investment conse- confidence, cause a majority of business decision-makers
quences the Brexit might have in the near-term for U.S. to hedge and serve as an unwelcome drag on economic
stakeholders. growth and demand.
4spe.org
The celebration starts in Booth 11 E21
54-57 Inside SPI_046854 IndustryNews.QXD 8/20/16 10:57 AM Page 57
INSIDE SPI
because it’s plastic, get the glass bottle because it’s more What’s one plastic product you couldn’t live without?
‘green’,” I know how to productively counteract that com- My contact lenses. I love my glasses too, but it’s crazy that
ment with facts like, “Well, plastics are recyclable and it took a curved piece of plastic you place on your eye can make
less energy to ship this plastic bottle to this location,” etc. the world beautiful and crisp.
People can easily be reminded that plas-
tics are needed in many facets of our
everyday lives and bring a lot of good.
THERMOFORMING
By Stanley R. Rosen
T
hermoforming is the process of heating a thermoplas- The firm first demonstrated its machine at the National
tic sheet and using vacuum or compressed air to form Plastics Exhibition in 1952 in Philadelphia (Fig. 1). Modern Plas-
the sheet to a mold and later trim to size each individual tics magazine in May 1952 noted: “This booth attracted more
cavity. Several firms during the 1930s and 1940s designed continuous attention than any other exhibit.” The process
and built proprietary machines that were used to thermo- appealed to many attendees due to the low cost of the equip-
form small quantities of plastics products. None of this ment and tooling when compared to injection molding.
equipment was ever sold to processors in the plastics indus- Within a very short time, machinery competition arose: J.E.
try. Kostur - Comet Corp. (Chicago), David Zelnick - Atlas Corp., now
The U.S. Army Relief Map Division, whose chief was E. Bow- the Zed Corp. (Rochester, N.Y.), and Bow Stratton’s Auto-Vac
man (Bow) Stratton, developed a practical method of vacuum Corp. (Bridgeport, Conn.) all built well-engineered vacuum
forming 3-D topographic maps during World War II. When formers. These machines used cut sheets and required a rel-
the war ended, the army vacuum former was upgraded and the atively long heating cycle as the oven contained only top
Industrial Radiant Heat Corp. of N.J. was created to promote and heating elements. The formed shot was trimmed using knife-
sell this equipment. like steel rule dies in presses adapted from the printing or
Figure 1: Industrial Radiant Heat Corp. of New Jersey introduced this thermoforming machine — the first such model to be
offered widely for sale — at the 1952 NPE trade fair in Philadelphia, where it attracted substantial attendee interest and
spurred a number of competitors to enter the market.
shoe-making industries.
Every new thermoformed component
required its own mold and this expense
was amortized over the total number of
parts purchased. Customers placing ini-
tial small orders to market-test this new
process needed to minimize the cost of
each mold. Molds were built using a
model or a wooden pattern to vacuum
form individual plastics cavities. Liquid
epoxy or plaster was poured into these
cavities and cured to create an inexpen-
sive mold. Both cavity materials are poor
heat conductors, resulting in a very slow
thermoforming cooling cycle.
Inefficient machines and molds when
combined with low volume orders tended
to restrict new machinery sales and reduce
technical innovation during this early peri-
od.
In 1954, retail merchandising started to
shift from traditional clerk assistance to Unma
Unmatched
tched exper
expertise
tise
consumer self-service. This trend intro-
duced a change in product packaging in pla
plastics-joining
stics-joining ttechnology
echnology
favoring heat-sealed plastic blisters on
cards mounted on peg board displays. Branson, a business of Emerson, is trusted worldwide for its unmatched
This package gave thermoforming sup- materials-joining exper tise. When you involve Branson early in the
pliers a huge new market. Newly designed development process, you have access to industr y -leading suppor t for
roll-fed thermoformers and heat-efficient design, materials testing, protot yping, applications development, DOE,
aluminum molds were quickly designed to 3D modeling, and production.
supply the rapid increase in volume for
blister packaging. For the next four to five
Our process-neutral approach, offering technology options that include
machine designs.
In fact, our range of technology options has allowed us to ser ve the
The industry was not yet ready to pay
automotive industr y in a wide variet y of applications, including :
the cost to solve the problem of trimming • Instrument panels and under the hood
parts in-line from a continuous thermo-
formed web. In the late 1950s, Dow
• Clean- welded headlight or tail light lenses
Mich., collaborated to mass produce plas- • High-speed production and automated systems
tic cups and lids. Their endeavor resulted
in successfully building a continuous sheet
In addition, Branson’s global resources offer you world-class qualit y,
Submit your innovative plastics nominations today to the oldest and largest
recognition event of its kind in the automotive plastics industry. Learn more at:
http://speautomotive.com/inno and http://speautomotive.com/awa.
58-63 Rosen Thermoforming_046854 IndustryNews.QXD 8/19/16 9:41 AM Page 61
THERMOFORMING
w w w. s i i g r o u p . c o m | 2 75 0 B a l l t o w n R o a d | S c h e n e c t a d y, N Y 1 2 3 0 1 | 51 8 . 3 47. 4 2 0 0
Formosa Plastics
®
ADVANCED MATERIALS
Chemro
C hemro
MRC Polymers
Engineered & Sustainable Resins
–– A D V E R T I S I N G ––
64-71 Industry News_046854 IndustryNews.QXD 8/20/16 11:30 AM Page 64
INDUSTRY NEWS
Having met with a positive response at K 2013, the Science resource efficiency; Plastics Industry 4.0; new materials and
Campus at K 2016 in Düsseldorf, Germany, Oct. 19-26 will lightweight engineering, as well as on scientific training in
further intensify the dialogue between research and indus- macromolecular chemistry and plastics technology. Scien-
try in an enlarged area and with an increased number of tists of K 2016’s Innovation Circle and teams from their
participating scientific organizations. Supplementing the pre- institutes will prepare the key themes and present them in
sentations of universities and colleges, institutes and different formats.
sponsoring organizations, the Science Campus will focus on Expected to have a lasting impact on market development
the four key themes defined by the K 2016 Innovation Circle of the sector in the coming years, these themes will not only
– a panel made up of experts from science and representa- be the focus of the Science Campus at K 2016 but will also be
tives of K’s Exhibitors Council. reflected in the presentations of the exhibitors, the special
The Science Campus enables exhibitors and visitors at K show “Plastics Shape the Future” and the Innovation Com-
2016 to gain a concentrated overview of scientific activities pass.
and findings in the plastics and rubber sector and promotes At K 2016, more than 3,200 exhibitors from 60 nations will
an exchange of experience between companies and univer- present their latest developments in the fields of machinery
sities. The participants at the Science Campus will be presenting and equipment for the plastics and rubber industry, raw
pioneering materials and technologies and responding to the materials and auxiliaries, semi-finished products, technical
central challenges of polymer technology. parts, and reinforced plastics products. The eight-day fair is
The discussion and communication will focus on the key expected to attract some 200,000 trade visitors from all over
themes: innovation drivers of global change focusing on the world. www.k-online.com.
PolymaxTPE introduces two styrenic TPE grades engineered 010 and P32-011, can replace TPV elastomers in a variety of
to deliver low-compression-set performance expressly for applications that require high resilience for seal integrity,
gasket and seals application. These two new grades, P32- including gaskets, seals, valves, home appliances, and food
packaging. What makes these new products stand out is their
low compression set at elevated temperatures. Compres-
sion set is the measure of a material’s ability to recover from
deformation. The lower the percentage, the better the mate-
rial resists permanent deformation under a given deflection
and temperature range.
“The development of new TPEs with low compression set
for the seal industry reflects the focus of PolymaxTPE on R&D
and its strategy of working proactively with customers”, not-
ed Dr. Martin Lu, chief technology officer of PolymaxTPE. The
two new grades score further points for their excellent tear
strength, cold temperature flexibility, low odor, stability at
high temperatures, and weather resistance. The raw mate-
rials used to manufacture these two grades are compliant
with food-contact regulations. These materials can be used
in stand-alone injection molding, extrusion applications, or
New styrenic grades target gaskets and seals. bonded with polypropylene substrates.
Graphic courtesy of PolymaxTPE www.polymaxtpe.com.
SABIC will showcase to K show visitors how “Chemistry that insulation. With its inherent high impact resistance, clarity
Matters™” is addressing global trends and the challenges in and durability, LEXAN™ sheet helps to maintain safety and a
key industries with solutions to help create a better future for clear view in indoor applications.
everyone. With a strong emphasis on sustainability, SABIC www.sabic.com.
says that at this year’s event it will high-
light its strong, collaborative approach
with customers to jointly develop and
produce global solutions, from con- W
Worldwide
orldwide Leader in Inject More value. More features.
cept to realization.
“Striving for a sustainable future
More productivity.
means looking at business practices
differently and being able to turn chal- HPM Model HST2 Full Line of Hybrid Machines
lenges into opportunities that add Toggle Clamp Machinery
Toggle M fr om 65 to 3500 U.S. T
from ons
Tons
lasting business value,” said Abdul-
rahman Al-Fageeh, Executive Vice
President - Polymers. “Our new organ-
ization brings us closer to customers,
enabling us to offer sustainable solu-
tions to the entire value chain and
Injection
INDUSTRY NEWS
INDUSTRY NEWS
SmartKem, UK-based developer of the truFLEX® semicon- strengthen our existing position within the Chinese display
ductor platform for the manufacture of flexible displays and sector with our ground-breaking semiconductor platform.”
electronics, has had notification of The primary target applications include new wear-
patent allowance for its able technologies, mobile devices, automotive,
semiconductor material in embedded, and transparent displays, but the tech-
China. This is a key market nology is a key enabler for the many products that
for the roll-out of its tech- are helping to build the Internet of Things, such as
nology platform with display gesture and touch control, fingerprint recog-
manufacturers across Asia. nition and wide range of sensor
Steve Kelly, CEO and applications.
founder of SmartKem, said: “The global market for OLED and
“Successful collaboration flexible OLED are set to
is crucial in helping China to grow rapidly in the
become a key stakeholder next two to three years
and competitor in the global and we are very much
OLED display industry. focused on the indus-
“As the Chinese trialization and
OLED industry matures, SmartKem's truFLEX® semiconductor platform commercialization of
China’s capabilities in both tra- helps to enable flexible displays and electronics. our truFLEX® organic
ditional and flexible OLED production will only Photo courtesy of SmartKem semiconductors to
increase as it turns its focus to designing and enhance and further
developing its own products rather than manu- strengthen our position
facturing someone else’s. There is a clear in this sector. Patent
commitment to encourage high-tech research and develop- allowance in key territories within Asia such as China is an
ment and there are benefits in place to incentivize innovation important milestone in achieving wide-scale market adop-
and high technological standards. Our new patent allowance tion of our technology platform,” Kelly continued.
places SmartKem in an excellent positon to consolidate and www.smartkem.com.
Clariant announces availability of new blow-molding tools and the broad, flat panels were not as representative of the
that can help customers evaluate how Clariant color and addi- shapes that producers of liquor bottles and other beverage
tive masterbatches perform in real-world applications. The containers are looking for today.”
new single-cavity tool, which is intended for reheat stretch The tooling can be used to evaluate not only color, but also
blow molding of clear or colored PET polyester resins, pro- performance-enhancing additives and barrier properties, as
duces a 12-oz (355-ml) round bottle with a long neck and curved well. Prusak says that the way plastic materials stretch to cre-
sides. The design is intended to reflect current design trends ate a bottle’s shape can vary depending on the color and other
for liquor bottles, but can also be used to evaluate wine, soft- ingredients in the compound. A resin/masterbatch combina-
drinks and other food and beverage containers, too. tion that works well in one shape can develop cosmetic flaws
“This new mold includes the details that customers told us or unacceptable physical properties in another. This is why it
they wanted in prototype tooling,” explains Peter Prusak, head is so important to produce shapes that more accurately mim-
of marketing for Clariant Masterbatches North America. “The ic the actual end-product containers.
tooling we’ve had in the past produced flask-shaped bottles, www.clariant.com.
CUSTOM-ENGINEERED
C
CUST
S TPE
Whether manufacturing products from the consumer, automotive or indus-
trial ma
markets: THERMOLAST® K TPE compounds provide optimal flexibility
andd adhesion
adhe i to vavarious substrates…why not create the difference with
KRAIBURG TPE?
INDUSTRY NEWS
INDUSTRY NEWS
INDUSTRY NEWS
INDUSTRY NEWS
• Injection Molding
• Thermoforming
• Composite Molding
Presented by: The SPE Product Design and Development Division (PD3)
Hosted by: The SPE Columbia River Section | Learn more: http://www.spe-pd3.org
Supported by: The SPE Thermoforming Division
Ed Probst, Conference Chair | ed.probst@probstplastics.com | 414-476-3096
72-75 Patents_046854 IndustryNews.QXD 8/19/16 10:53 AM Page 72
INDUSTRY PATENTS
By Roger Corneliussen
functional improvements. The foam is created as separate enhoefer and Lappe developed a storage and conditioner for
layers within the cavity formed by the inner and outer sol- preforms with a tempering space before molding. The pre-
id plastic skins. The foams layers are formed so as to leave forms can be treated and heating so that the condition,
a continuous, air-filled cavity within and throughout the body including temperature, is substantially constant for mold-
walls. The rotomolded body assembly consists of lower and ing. The preforms needs to be kept in storage at least 15
upper bodies that are joined or fixed together after mold- minutes and the final preform temperatures should not vary
ing. Candidate resins include polyethylene, polyamides, more than 2˚ C.
polypropylene and their copolymers or blends.
B
BLOWMOLDING
LOWMOLDING
INDUSTRY PATENTS
modulus, decreases the loss modulus and loss tangent. In stretch the film by 75% in the longitudinal direction. This
these cases, the applied stress rearranges the interphase. material is a two-layer, coextruded film from linear low den-
This stress can be mechanical dynamic, static or cyclical sity polyethylene (LLDPE) and low density polyethylene
stress. The nanofillers include carbon nanotubes, graphite, (LDPE) with ethylene vinyl acetate (EVA), ethylene butyl acry-
carbon black, nanofibers and nanoparticles. The polymers late (EBA) or ethyl methacrylate (EMA).
range from polyethylene to polyimides, as well as elastomers.
thechain.4spe.org
Materials
Data b a s e
Access ‘tons’ of materials in the world of plastics!
For more details: 4spe.org/materialsdatabase
#
67
Injection Molding: get the right motor Actions:
While the motors of hydraulic injection molding machines • Examine all the motors used in the injection molding
are the largest energy users in the complete system, much machines.
progress has been made in controlling this over the past 20 • Produce a list of the motor/pump types used and find out
years. These developments mainly concern slowing the what the options are for retrofitting new motors and
motor down when hydraulic oil is not needed or reducing the control systems to reduce energy use.
need for oil by other methods. In some cases, this means that • Consider retrofitting older machines with electric screw
new hydraulic machines are not far away from achieving all- drives (if available) to reduce the peak power needed and
electric standards of energy use. downgrading the main motor (if possible).
However, there are still many older machines in service that
• Consider retrofitting older machines with servomotor
pumps/fixed speed pumps
use old technology (fixed speed pump/fixed volume pump)
and these have very high energy demands. Fortunately, motor
and control system developers have produced a wide range
of solutions using variable-speed motors, variable-volume
pumps and now servo motors with fixed speed pumps. These Dr. Robin Kent — ©Tangram Technology Ltd.
are available for many older machines and can dramatically (www.tangram.co.uk)
reduce energy use if retrofitted to older machines.
Note: Dr. Robin Kent is the author of Energy Management in Plastics Processing, published by Plastics Information Direct, and managing director
of Tangram Technology Ltd., consulting engineers specializing in energy management in plastics processing. rkent@tangram.co.uk.
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EDITORIAL INDEX
Society of
Plastics Engineers
AOC LLC ..............................................23 iD Additives Inc. ..................................35 EDITORIAL STAFF
American Chemistry Council ......50, 51 Industrial Radiant Heat Corp. ..........58
Editor-in-Chief
Arburg ..................................................32 Kopla Co. Ltd.......................................24 Briana Gilmartin
Arizona Instrument ............................70 Krones AG............................................73 Managing Editor
Ascend Performance Materials....15, 18 Kyoraku Co. Ltd. ................................36 Robert Grace
Atlas Corp. ..........................................58 Madison Group ..................................44 Contributing Editors
Auto-Vac Corp. ....................................58 Maryland Cup......................................59 Dr. Roger Corneliussen
BASF ..................................13, 16, 29, 32 Messe Düsseldorf ........................28, 61 Jon Evans
Dr. Robin Kent
Battenfeld-Cincinnati ..................31, 32 MuCell Extrusion Inc. ........................36
Borealis AG ..........................................74 NVH Korea ..........................................25 Marketing & Communications
Sue Wojnicki
Branson Ultrasonics ..........................38 Owens Corning ..................................24
Brown Machine Co.......................59, 61 PolymaxTPE ........................................64 Branding & Design
Carbon Revolution Pty. Ltd. ..............24 Prent Corp. ..........................................59 Liz Martland & Kim Wakuluk
Chevron Philllips Co. LP ....................75 Replas Australia ....................................9 Art Director
Clariant ................................................66 Royal DSM ..........................................32 Gerry Mercieca
Coaster Pedicab..................................67 SABIC..............................................25, 65 Publisher
Combipac BV ......................................74 Sill Industries ......................................58 Steven Ottogalli
Comet Corp. ........................................58 SK Chemicals ........................................9
2016–2017 EXECUTIVE COMMITTEE
Composite Castings LLC ....................14 SmartKem............................................66
Conair Group ......................................70 Solvay Advanced Polymers ..............15 President
Scott Owens
Continental Structural Plastics..........23 Solvay Solexis SpA ..............................75
Covestro LLC ....................29, 31, 32, 67 Songwon ..............................................68 CEO, SPE
Dauntless Racing Cars ......................14 SPE ..........................6, 22-26, 34, 61, 76 Willem De Vos
Dow Automotive Plastics ..................20 SPI: The Plastics Industry President-elect
Dow Chemical ....................................59 Trade Assn. ................................54, 55 Raed Al-Zu’bi
Dresden Optics Pty. Ltd. ................8-10 Tangram Technology Ltd...................78
Senior Vice President
DSM Engineering Plastics ..................18 Tata Technologies Pte. Ltd. ..............72 Thierry d’Allard
DuPont ................................................14 Trucost PLC ........................................51
Vice President
Duromer Products Pty. Ltd. ................9 UT-Battelle LLC....................................72 Brian Landes
EMS-Grivory ..........................................9 Vert ........................................................9
Engel ....................................................31 Wacker Chemie AG ............................29 Vice President
Jaime Gómez
FCA US LLC ..........................................25 William Marsh Rice University ..........73
Flexopack SA ......................................72 Wittmann Battenfeld USA ................57 Vice President
Rodney Joslin
Ford Motor Co. ..........12, 16, 24, 25, 50 W. Müller USA Inc. ..............................34
General Motors Co. ............................22 YAGS LLC ............................................72 Vice President
Heraeus Noblelight ............................68 Zed Corp. ............................................58 Monika Verheij
Hyundai Motor Group ................23, 24 Zeiss Vision Care ..................................9 2015–2016 President
Dick Cameron
Plastics Engineering (ISSN 0091-9578) is published monthly, except bimonthly in July/August and November/December, by Wiley Subscription Services, Inc., a Wiley
Company, 111 River Street, Hoboken, NJ 07030 USA. The magazine is compiled and edited by the Society of Plastics Engineers, Editorial and Business Office, 6
Berkshire Blvd., Suite 306, Bethel, CT 06801 USA. Telephone +1 203-775-0471, Fax +1 203-775-8490. SPE Home Page: www.4spe.org. Communications should be
sent to the Editor. Send address changes and undeliverable copies to the Circulation Manager at the SPE address given above. Send subscription orders and
claims for non-receipt to Wiley Subscription Services at the Wiley address given above. SPE members receive the magazine as a
benefit of membership. Subscription rate for nonmembers is $151 for 1 year; add $100 per year for subscriptions outside North
America. Single-issue price is $20. Plastics Engineering is printed by Dartmouth Printing Co., a Sheridan Group Company. Copyright
2016 by the Society of Plastics Engineers, Inc. POSTMASTER: Send address changes to Plastics Engineering, 6 Berkshire Blvd., Suite
306, Bethel, CT 06801 USA. Reproduction in whole or in part without written permission is prohibited. Plastics Engineering is
indexed by Engineering Information Inc.
Neither Wiley Subscription Services, Inc., nor the Society of Plastics Engineers, nor Plastics Engineering is responsible for opinions
or statements of facts expressed by contributors or advertisers, either in the articles published in Plastics Engineering or in the
technical papers that are presented at the meetings of the Society. Editorials do not necessarily represent the official policy of
Wiley Subscription Services, Inc., or the Society. Display and classified advertisements are included as an educational service to
Printed in the U.S.A.
readers of Plastics Engineering. Advertising appearing in Plastics Engineering is not to be taken as an endorsement, expressed or
implied, of the respective company’s processes, products, or services represented in the ad.
AD INDEX
ADVERTISING SALES
Aaron Equipment Company www.aaronequipment.com/sniff ....................81
Allgrind Plastics www.allgrind.com ................................................................80
ANTEC 2017 antec.4spe.org ..............................................................................52 FOR PRINT AND ON LINE DIGITAL
Arizona Instruments www.azic.com/vpxi ......................................................27 ADVERTISING SALES in
Ascend Performance Materials www.ascendmaterials.com/pa66auto......2-3 Plastics Engineering magazine
Atlas atlas-mts.com ........................................................................................33 please contact:
Battenfeld-Cincinnati www.battenfeld-cincinnati.com/usa ..........................19
BASF construction.basf.us ................................................................................43
Global Sciences Sales Director
Branson www.bransonultrasonics.com ..........................................................59
Dan Nicholas
Conair www.conairgroup.com/support ..................................................Cover 4
Connect With SPE www.4spe.org ..............................................................20, 83 Tel: +1-716-587-2181
Coperion K-Tron www.coperionktron.com......................................................17 dnicholas@wiley.com
DAK Americas www.dakamericas.com ............................................................51
Dover Chemical Corporation www.Doverchem.com/LGP-11 ......................21 Sr. Account Manager
Entek www.entek.com ........................................................................................7 Print & E Media Advertising
HPM North America Corp. www.hpmmachinery.com ..................................65
Roland Espinosa
IMS Company www.imscompany.com/G4 ......................................................49
Tel: +1-201-748-6819
Instron www.instron.com..................................................................................57
J.P. Curilla Associates Email: jpcecl@aol.com ................................................80
E-mail: respinosa@wiley.com
Japan Steel Works www.jswcompounding-usa.com ......................Cover 2, 80
John Anderson & Associates www.plasticsjobsearch.com ............................80
Kraiburg TPE Corp. www.kraiburg-tpe.com ....................................................67 Product and news releases for
Perstorp www.perstorp.com/plasticizers ........................................................53 Plastics Engineering can be sent
Plastic Flow www.plasticflow.com....................................................................80 directly to PEreleases@wiley.com
Plastic Process Equipment, Inc. www.ppe.com ............................11, Cover 3
Polyhedron Laboratories, Inc. www.polyhedronlab.com ............................80
Process Design & Technologies www.processdesigntech.com ....................80
Rheo-Plast Associates, Inc. www.rheoplastusa.com......................................80
SAM North America www.sam-na.com • Email: info@sam-na.com ..............80
Shepherd Color www.shepherdcolor.com ......................................................47
SI Group www.siigroup.com..............................................................................61 111 River Street
SPE at K Show 4spe.org ....................................................................................56 Hoboken, NJ 07030 USA
SPE Auto TPO www.auto-tpo.com ................................................................62-63
SPE Blow Molding Conference www.blowmoldingdivision.org........................73
SPE Career Change www.4spe.org/careers ....................................................77
SPE FlexPackCon www.4spe.org/flexpackcon2016 ........................................37
SPE Got Membership? www.4spe.org ............................................................79
SPE Materials Database www.4spe.org/materialsdatabase ..........................75
SPE Medical Plastics Conference www.medicalplastics-conference.com ....69
SPE Technical Journals www.4spe.org ............................................................81
SPE The Chain thechain.4spe.org ........................................................................74 6 Berkshire Blvd., Suite 306
SPE Plastic Part Design Conference www.spe-pd3.org ................................71 Bethel, CT 06801 USA
SPE Innovation Awards www.speautomotive.com/inno ..................................60 www.4spe.org
Struktol www.4struktol.com ............................................................................25
Tangram Technology www.tangram.co.uk ....................................................80
Turkish Machinery www.turkishmachinery.org ..............................................5
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