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Abstract
Prediction of relative permeability is important to avoid dry spots or micro voids in the liquid composite molding
process. Most of previous studies focused on plain and twill, but few are about stain and none of them provide explicit
equation to calculate accurate values of unsaturated permeability. The main purpose of this work is to first propose a
new model which is proposed mainly based on fractal theory and has no empirical constant in the expression, to
calculate the permeability of satin fabric. And then we employ a new experimental method to calculate the unsaturated
permeability. Finally, a contrast experiment of 5-harness fabric and 8-harness fabric is designed at different injection
pressures, and the accurate values of permeability are obtained. The results show that unsaturated and saturated
permeabilities are in the same order of magnitude; furthermore, unsaturated permeability is 77% of saturated perme-
ability in 5-harness fabric and 73% in 8-harness fabric.
Keywords
Fractal Theory, minimum potential energy method, unsaturated permeability, explicit equation
for infusing by vacuum-assisted RTM (VARTM). Liu pores generated during the stacking and compression
and Dai13 studied the impregnation of a jute fiber mat of the layers of reinforcement. Kim et al.30 and Diallo
by a thermoplastic resin. They found that natural fab- et al.31 found that the saturated permeability was
rics’ permeability is an order of magnitude higher than always lower than the unsaturated permeability, while
the obtained for glass fiber mat. Due to the high vis- other authors obtained opposite results.32–34 These dis-
cosity melt used in their work, they did not observe crepancies are usually attributed to experimental issues
impregnation inside the fiber bundles. Rodriguez that could modify the saturated and unsaturated per-
et al.,14 Cosa,15 and Henderson et al.16 improved the meability ratio, such as mold deflection, capillary effect,
Kozeny–Carman equation from different points of microscopic flow, fiber channeling, and air bubbles.35
view. Chen and Ye17 raised the square and hexagonal However, most studies depend on plain twill, few on
arrangement permeability model on the basis theory of satin weave, and at the same time, many experiments
approximation lubrication. However, the model is employ the method of recording the position of the flow
restricted to those two kinds of arrangements and front rather than the pressure of the flow front.
only appropriate for porous media of a certain range In the present work, a new permeability model is put
of porosity. Amico and Lekakou,18 Dukkipati and forward based on textiles, fractal theory, principle of
Dukkipati,19 Golestanian20 and Feser et al.21 separately minimum potential energy and penetration theory, to
used the unidirectional flow method under constant calculate the permeability of satin fabrics. Traditional
pressure, the unidirectional flow method under con- permeability models have been based on empirical for-
stant flow rate, the radial flow method under constant mula and large amounts of experimental data. However,
pressure and the radial flow method under constant the structural parameters are rarely applied in empirical
flow rate to test the permeability of fabrics. Tan and formulas, which make the models hard to reflect the
Li22 have presented a fractal model for the permeability physical relationship and the seepage phenomenon.
of fractured reservoirs; however, the relation between Because of the employment of fractal theory, permeabil-
the transport exponent and fractal dimension in the ity can be expressed as an organic combination of the
proposed permeability model is unknown and needs structural parameters of porous structure, making each
to be determined by other methods. Simacek et al.23 parameter to have a clear meaning. No doubt these are
and Merotte et al.24 have studied the permeability the biggest advantages and the most attractive places of
through constructing constitutive equations of fiber fractal theory. In this study, we will use the new perme-
reinforcements. Homogenization theory was employed ability model to calculate both saturated and unsatur-
by Song and Youn25 and Fuhong et al.26 to calculate ated permeability. Unsaturated permeability will be the
the permeability of two-dimensional woven fabrics. focus of this study. In addition, permeability test results
Xiao et al.27 numerically simulated the transport pro- obtained under the injection pressure of 0.1 MPa and
cess in a fractal object by applying a percolation model 0.2 MPa, respectively, are compared in order to study
and concluded that the permeability in real porous the pressure effect on the permeability values. Finally,
media relates to porosity and fractal dimension. we briefly analyzed the main factors affecting the per-
Nevertheless, no quantitative expression for the perme- meability values, and proposed that in natural
ability was given in his work. Yu and Li28 proposed an fibers, unsaturated permeability is affected by fluid
analytical expression for the relative permeability of absorption and saturated permeability is affected by
unsaturated bi-dispersed porous media based on fractal the swelled fiber.
capillary bundle model, where each capillary tube was The rest of the paper is organized as follows: The
assumed to be partially filled with the wetting and no modeling process and the design of all parameters in
wetting phase fluids. the new fractal permeability model are presented in the
While large number of researches have been reported Modeling process section. The experimental procedure
for natural reinforcements, a detailed insight on the is shown in the Experimental section. The results and
analytical expression and unsaturated permeability is discussions can be found in the Results and discussion
still required. Therefore, it is very important is to iden- section. Finally, the conclusions are given in the
tify the main mechanisms presented in natural fibers Conclusion section.
infiltration. One key aspect that has been studied by
several authors in glass fibers is the difference between
saturated and unsaturated permeability. Pillai and Modeling process
Advani29 studied in detail the unsaturated flow in
Basic structures of satin fabrics
woven fibers preforms, taking into account the delayed
impregnation of fiber tows through the use of a sink In order to ensure the rationality of the new model, it is
function in the equation of continuity for the macro necessary to know more about the weaving structure of
flow. Micro flow can also occur through the micro satin fabrics. As shown in Figures 1(a) and 2(a), a
296 Journal of Reinforced Plastics and Composites 36(4)
Figure 1. Weaving structure of a 5-harness satin fabric. (a) the fractal theory is appropriate for this kind of porous
Photography of a 5-harness satin fabric. (b) Unit cell of a 5 medium.
harness satin fabric.
Df
min
ffi0 ð1Þ
max
Modeling assumptions
Suppose in-plane shear deformation will not happen,
then temperature and humidity have no influence on
fiber structures, satin fabrics will not wrinkle and
crimp, there is no energy exchange between fibers and
Figure 2. Weaving structure of an 8-harness satin fabric. (a) resin, pore channels are parallel to fibers, and yarn
Photography of an 8-harness satin fabric. (b) Unit cell of an 8 spaces are determined by the weaving machine only.
harness satin fabric.
() the number of channels whose diameters are greater Based on equation (3), the physical length of the
than . Df and DT have donated the structure fractal channel Lt can be expressed as
dimension of a fractal medium and the tortuosity frac-
tal dimension of a tortuous channel, respectively Lt ¼ Lt ðÞ ¼ LD T 1DT
0 ð7Þ
(1 < Df < 2 and 1 < DT < 2 in the two-dimensional
space). As a fractal medium, the quantity of flow (q) meets
Equation (2) implies that all the channels will be the Hagon–Poiseulle equation40
taken into account when is equal to min. Figure 4
illustrates that the minimum channel exists among three 4 P
mutually contacting filaments, and therefore min can qðÞ ¼ ð8Þ
128 Lt
be figured out according to equation (5).
where represents the fluid viscosity, and P is the
qffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
pffiffiffi differential pressure.
min ¼ 2r 3= 0:5 ð5Þ
Therefore, the total quantity of flow in the cross sec-
tion A is expressed as formula (9)
Z max
In this study, a 5-harness satin fabric and an 8-har-
Q¼ qðÞdNðÞ ð9Þ
ness satin fabric are taken as examples to illustrate how min
to calculate the permeability of satin fabrics using the
new model. The difference between warp yarns and Substituting equations (6) to (8) into equation (9),
weft yarns is their permeability. When solving the per- the formula can be further simplified as follow
meability in this paper, generally considered as weft
Z max
permeability, a weft cross section is ought to be used 4 P Df
for analysis (see Figures 5 and 6), and vice versa. Q¼ Df max ð1þDf Þ d
min 128 Lt ðÞ
According to equation (2), we can get the derivation 1D
P L0 T Df Df 3þD D 3þD D
of ‘‘’’ ¼ max max T f min T f
128 L0 3 þ DT Df
" #
min 3þDT Df
1D
f
dNðÞ ¼ Df max
D
ðDf þ1Þ d ð6Þ P L0 T Df DT
¼ 1
128 L0 3 þ DT Df max max
1D
P L0 T Df
¼ DT
128 L0 3 þ DT Df max
" #
min Df min 3þDT 2Df
1 ð10Þ
max max
Figure 5. Cross section of 5-harness satin fabric. Figure 6. Cross section of 8-harness satin fabric.
298 Journal of Reinforced Plastics and Composites 36(4)
5-Harness 8-Harness
K
Q¼ rP A ð12Þ composite composite
Average of the maximum 114.6 98.5
where K (m2) is the hydraulic conductivity, represents equivalent diameter
the viscosity of the liquid and rP is the total pressure of weft pores wmax
difference in the cross section A. Substituting equation
(11) into equation (12), the saturated permeability of
the fiber performance can be expressed as equation
(13) and unsaturated permeability can be derived as Table 2. The calculated values of all the parameters.
equation (14).
L0 (mm) A (mm2) max (mm) Df DT
Df ðmax ÞDT þ3 5-Harness fabric 2.78 0.7854 0.1146 1.7264 1.012
Kst ¼ 8-Harness fabric 3.568 0.8556 0.0985 1.6139 1.013
128AL0DT 1 DT Df þ 3
0 !DT Df þ3 1
@1 min A
ðmax ÞDT þ3
ln
DT þ3
Df ¼ 2 ð17Þ
Df ðmax Þ ln ðmin =max Þ
ð13Þ
128AL0DT 1 ðDT Df þ 3Þ
where Lt() means the actual length and L0 means the
DT þ3 representative length. In a unit cell, Lt () equals to
Df ðmax Þ
Kunst ¼ Kst DT 1
ð14Þ Lw.42
128AL0 ðDT Df þ 3ÞP The representative length and the cross-sectional
area are easy to calculate (L0 ¼ ndj, A ¼ ndwh); however,
There is no empirical constant in the expression, so the maximum equivalent diameter of capillaries is dif-
the warp permeability can be easily figured out only if ficult to compute. In the previous work, that problem
the porosity structure fractal dimension Df, the tortu- was easily addressed by help of using microscopic meas-
osity fractal dimension DT, the representative length of urement technique (as shown in Table 1). Now, Table 2
channels L0, the cross section area A, and the maximum shows the calculated values of all parameters in the
equivalent diameter of pore channels max are known. formula except for the pressure. As long as we get the
pressure of each test-point, the unsaturated permeabil-
ity of the fabric can be figured out by equation (14).
Parameters design Substituting the known parameters into equation (13),
Based on the literature mentioned before, we use the the saturated permeability of different glass fiber fabric
bending potential energy and the principle of fractal to can be shown in Table 6.
calculate the tortuosity fractal dimension DT, and along
with equation (4), the structure fractal dimension Df
can be figured out as equation (17). Experimental
According to equation (3), Lt ðÞ can be derived as Raw materials
equation (15).
Two kinds of glass fiber fabrics are used in this study,
Lt ðÞ ¼ LD T 1DT namely SW220-90a and EC9. In addition, the epoxy
0 ð15Þ
resin was used for injection, and the viscosity of the
Therefore, the tortuosity fractal dimension DT can epoxy resin is 0.08 Pa.s at room temperature. Table 3
be figured out as equation (16). shows the main structural parameter of the two kinds
of fabric.
ln Lt ðÞ ln ln Lj ln
DT ¼ ¼
ln L0 ln lnðndw Þ ln Experimental mold
qffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
12h2 pffiffiffi
ln ndw þ dw c ln 2r 3= 0:5 As shown in Figures 7 and 8, the injection mold con-
¼ qffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi ð16Þ sists of a lower mold, a middle mold, an upper mold
pffiffiffi
lnðndw Þ ln 2r 3= 0:5 and a binder plate. The middle plate and the lower plate
are steel mold, while the upper plate is a
Wang et al. 299
Number of harnesses 5 8
Thickness (mm) 0.22 0.23
Filament diameter (mm) 8 9
Warp density (yarns/cm) 18 22.4
Weft density (yarns/cm) 14 21.5
Linear density of the warp yarns (Tex) 72 66
Linear density of the weft yarns (Tex) 72 66
Filaments per warp yarn 500 400
Filaments per weft yarn 500 400
Areal weight (g/m2) 236 271
Width of fabric (mm) 100 100
480 mm 480 mm 12 mm tempered glass plate, which Figure 9. RTM injection machine.
has one injection gate, two spare injection gates and
four vents. The dimension of the cavity is 400 mm tank are still needed. In addition, 12 G-shaped clamps
400 mm 3 mm. With the help of the transparent were used to keep the mold closed. The resin flows into
upper plate, it is convenient for us to observe the flow the mold from the center gate and then permeates all
and record data, and the binder plate is used to ensure around with the flow front be circular or elliptical shape
the stiffness of the mold. as illustrated in Figures 10 and 11. And at the same
time, the sensor in the back of the mold (Figure 12)
records the pressure of flow front.
Permeability experiments
On account that the unidirectional flow is easily influ-
Results and discussion
enced by edge effect, radial flow was adopted in the
experiments. An RTM injection machine (as shown in The article studied the permeability of the two experi-
Figure 9), a pressure tank, a resin tank, and a recycling mental materials under different injection pressures and
300 Journal of Reinforced Plastics and Composites 36(4)
1. As illustrated in Table 6, the saturated permeability On the basis of comparison, it rises to the inequality
of 5-harness fabric and that of 8-harness fabric is in the representative length L0, the area of cross sec-
different. The densities of 5-harness fabric and tion A, the structure fractal dimension Df, the tortu-
8-harness fabric are different (as shown in Table 3). osity fractal dimension DT, and the maximum
equivalent diameter of pores max. This is why the
permeability of 5-harness and 8-harness are different.
2. From Tables 6, Table 7 and Figure 15, values of
unsaturated permeability are in the same order of
magnitude with saturated permeability. Further, no
matter the injection pressure is 0.1 MPa or 0.2 MPa,
unsaturated permeability is almost 77% of saturated
permeability in 5-harness fabric and 73% in 8-har-
ness fabric. Considering the unsaturated permeabil-
ity is complex to calculate than saturated
Values of Values of
Values of unsaturated unsaturated
saturated permeability permeability
permeability (106 mm2) (106 mm2)
(106 mm2) at 0.1 MPa at 0.2 MPa
Time (s) Test point1 (MPa) Test point2 (MPa) Test point3 (MPa) Test point1 (MPa) Test point2 (MPa) Test point3 (MPa)
10 0.0015 0 0 0.0011 0 0
30 0.0024 0 0 0.0017 0 0
60 0.0057 0 0 0.0035 0 0
90 0.0101 0.003 0.0002 0.0053 0.001 0
120 0.0206 0.009 0.0046 0.0095 0.003 0.0002
150 0.0307 0.018 0.0092 0.0166 0.009 0.0040
Time (s) Test point1 (MPa) Test point2 (MPa) Test point3 (MPa) Test point1 (MPa) Test point2 (MPa) Test point3 (MPa)
10 0.0033 0 0 0.0028 0 0
30 0.0057 0 0 0.0044 0 0
60 0.0098 0.001 0 0.0076 0.0007 0
90 0.0178 0.007 0.0003 0.0093 0.003 0.0001
120 0.0295 0.013 0.005 0.0143 0.008 0.0003
150 0.0411 0.025 0.0143 0.0178 0.011 0.006
302 Journal of Reinforced Plastics and Composites 36(4)
Table 7. Unsaturated permeability account for saturated only on the properties of the seepage material and
permeability. fluid characteristics.
6. In the theory, the pressure gradient is supposed to be
Unsaturated Unsaturated
permeability account permeability account the same with the increasing values of flow fronts,
for saturated for saturated and moreover upward tendency and downward ten-
permeability permeability dency are also observed in Figures 13 and 14, This is
at 0.1 MPa at 0.2 MPa because fiber agglomeration and fiber dispersion
may take place in some region of the actual fabrics.
5-Harness fabric 77.6796% 77.6819%
8-Harness fabric 73.1356% 73.1420%
Conclusion
We have proposed a new permeability model based on
the fractal theory and percolation theory to predict the
saturated and unsaturated permeability of satin fabrics
primarily. Like the other fractal models, there are no
empirical constants in the model. Furthermore, the
principle of minimum potential energy was used to cal-
culate the actual length of a tortuous channel Lt (),
and the fractal dimensions are expressed as the function
of yarn spaces but not the warp and weft density or
shrinkage any more, which makes our model differ
from the previous fractal permeability models dis-
tinctly. The saturated and unsaturated permeabilities
of a 5-harness and an 8-harness glass fiber fabrics
Figure 15. Unsaturated permeability account for saturated were measured in this study. From some aspects, we
permeability. can conclude that values of unsaturated permeability
are in the same order of magnitude with saturated per-
meability, and values of unsaturated permeability at
permeability, we can distinctly estimate it by using different injection pressures are almost equal. The
this conclusion in the future work. results show that unsaturated permeability is 77% of
3. When the mold is completely filled, and the saturated permeability in 5-harness fabric and 73% in
reinforcement is fully impregnated and saturated 8-harness fabric. Besides, the permeability coefficient
with fluid (no more micro pores impregnation or only depends on the properties of the seepage material
fluid absorption take place), and its sink nature and fluid characteristics. In this study, we roughly ana-
vanishes, and flow rate increases (for a given-per- lyzed the influence factors of saturated and unsaturated
form length), this means saturated permeability is permeabilities: unsaturated permeability is affected by
higher than unsaturated permeability. fluid absorption and saturated permeability is affected
4. From the whole experimental process, we can end by the swelled fiber (a consequence of fluid absorption).
up with a conclusion for fibers, that unsaturated As a future work, this question will be studied deeply
permeability is affected by fluid absorption and with other resin formulations.
saturated permeability is affected by the swelled
fiber (a consequence of fluid absorption). Both Acknowledgements
effects are leading to a decrease in the value of We would like to express our special gratitude and thanks to
the permeability. It can also be concluded all the respective personnels of the key technology research of
from another aspect that saturated permeability composite material aircraft manufacturing process lab. We
results are higher than those of unsaturated are also grateful to the teacher for giving us attention and
permeability. time during our experiment and who has also offered us
5. As illustrated in Table 6, values of unsaturated per- experimental devices.
meability at 0.1 MPa and 0.2 MPa are almost equal.
This conforms to the theory of Darcy’s Law, which Declaration of Conflicting Interests
describes that the seepage flow velocity is propor- The author(s) declared no potential conflicts of interest with
tional to the liquid pressure. At the same time, it respect to the research, authorship, and/or publication of this
also shows the permeability coefficient depends article.
Wang et al. 303
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