FLEETGUARD ES LIQUID

ChemWatch Material Safety Data Sheet CHEMWATCH 4508-92

Issue Date: Sat 28-Sep-2002 CD 2005/1 Page 1 of 10

Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME
FLEETGUARD ES LIQUID

SYNONYMS
engine coolant

PRODUCT USE
Engine coolant treatment.

SUPPLIER
Company: Fleetguard
Address:
31 Garden Street
Kilsyth
VIC, 3137
AUS
Telephone: (+61 3) 9721 9100
Emergency Tel: 1800 039 008 (24 hours)
Emergency Tel: +61 3 9573 3112
Fax: 03 9721 9148

HAZARD RATINGS

Flammability
Toxicity
Body Contact
Reactivity
Chronic

SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4

Section 2 - HAZARDS IDENTIFICATION

STATEMENT OF HAZARDOUS NATURE

HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
According to the Criteria of NOHSC, and the ADG Code.

POISONS SCHEDULE
S5

RISK
Harmful if swallowed.
Cumulative effects may result following exposure*.
Limited evidence of a carcinogenic effect*.
Possible skin sensitiser*.
* (limited evidence).

SAFETY
Do not breathe gas/fumes/vapour/spray.

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ChemWatch Material Safety Data Sheet CHEMWATCH 4508-92
Issue Date: Sat 28-Sep-2002 CD 2005/1 Page 2 of 10
Section 2 - HAZARDS IDENTIFICATION

Take off immediately all contaminated clothing.

If you feel unwell contact Doctor or Poisons Information Centre. (Show the label
if possible).

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS

NAME CAS RN %
potassium phosphate, monobasic 7778-77-0 2-10
organic corrosion inhibitors 2-10
scale inhibitors/surfactants 1-5
sodium nitrite 7632-00-0 <5
sodium molybdate 7631-95-0 <5
defoamer {1-3
stabiliser {
dyes {
sodium metasilicate, anhydrous 6834-92-0 0.5-2^
water 7732-18-5 75-85
NOTE: Manufacturer has supplied full ingredient
information to allow CHEMWATCH assessment.

Section 4 - FIRST AID MEASURES

SWALLOWED
Rinse mouth out with plenty of water.
• IF SWALLOWED, REFER FOR MEDICAL ATTENTION, WHERE POSSIBLE, WITHOUT DELAY.
• For advice, contact a Poisons Information Centre or a doctor.
• Where Medical attention is not immediately available or where the patient is
more than 15 minutes from a hospital or unless instructed otherwise:
• For advice, contact a Poisons Information Centre or a doctor.
• Urgent hospital treatment is likely to be needed.
• If conscious, give water to drink.
• INDUCE vomiting with fingers down the back of the throat, ONLY IF CONSCIOUS.
Lean patient forward or place on left side (head-down position, if possible) to
maintain open airway and prevent aspiration.
NOTE: Wear a protective glove when inducing vomiting by mechanical means.
• In the mean time, qualified first-aid personnel should treat the patient
following observation and employing supportive measures as indicated by the
patient's condition.
• If the services of a medical officer or medical doctor are readily available,
the patient should be placed in his/her care and a copy of the MSDS should be
provided. Further action will be the responsibility of the medical specialist.
• If medical attention is not available on the worksite or surroundings send the
patient to a hospital together with a copy of the MSDS.

EYE
If this product comes in contact with the eyes:
• Immediately hold eyelids apart and flush the eye continuously with running
water.
• Ensure complete irrigation of the eye by keeping eyelids apart and away from
eye and moving the eyelids by occasionally lifting the upper and lower lids.
• Continue flushing until advised to stop by the Poisons Information Centre or a
doctor, or for at least 15 minutes.
• Transport to hospital or doctor without delay.
• Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.

SKIN
If skin contact occurs:
• Immediately remove all contaminated clothing, including footwear
• Flush skin and hair with running water (and soap if available).
• Seek medical attention in event of irritation.

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ChemWatch Material Safety Data Sheet CHEMWATCH 4508-92
Issue Date: Sat 28-Sep-2002 CD 2005/1 Page 3 of 10
Section 4 - FIRST AID MEASURES

INHALED
• If fumes or combustion products are inhaled remove from contaminated area.
• Lay patient down. Keep warm and rested.
• Prostheses such as false teeth, which may block airway, should be removed,
where possible, prior to initiating first aid procedures.
• Apply artificial respiration if not breathing, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if
necessary.
• Transport to hospital, or doctor.

NOTES TO PHYSICIAN
Treat symptomatically.

Section 5 - FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA
• Water spray or fog.
• Foam.
• Dry chemical powder.
• BCF (where regulations permit).
• Carbon dioxide.

FIRE FIGHTING
• Alert Fire Brigade and tell them location and nature of hazard.
• Wear breathing apparatus plus protective gloves for fire only.
• Prevent, by any means available, spillage from entering drains or water
courses.
• Use fire fighting procedures suitable for surrounding area.
• DO NOT approach containers suspected to be hot.
• Cool fire exposed containers with water spray from a protected location.
• If safe to do so, remove containers from path of fire.
• Equipment should be thoroughly decontaminated after use.

FIRE/EXPLOSION HAZARD
• Non combustible.
• Not considered to be a significant fire risk.
• Expansion or decomposition on heating may lead to violent rupture of
containers.
• Decomposes on heating and may produce toxic fumes of carbon monoxide (CO).
• May emit acrid smoke.
Other decomposition products include nitrogen oxides (NOx) and sulfur oxides
(SOx)

FIRE INCOMPATIBILITY
Avoid reaction with oxidising agents and strong acids

HAZCHEM
None

Personal Protective Equipment

PERSONAL PROTECTION EQUIPMENT
Gas tight chemical resistant suit.
Limit exposure duration to 1 BA set - 30 mins.

Section 6 - ACCIDENTAL RELEASE MEASURES

EMERGENCY PROCEDURES

MINOR SPILLS
• Clean up all spills immediately.

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ChemWatch Material Safety Data Sheet CHEMWATCH 4508-92
Issue Date: Sat 28-Sep-2002 CD 2005/1 Page 4 of 10
Section 6 - ACCIDENTAL RELEASE MEASURES

• Avoid breathing vapours and contact with skin and eyes.

• Control personal contact by using protective equipment.
• Contain and absorb spill with sand, earth, inert material or vermiculite.
• Wipe up.
• Place in a suitable labelled container for waste disposal.

MAJOR SPILLS
Minor hazard.
• Clear area of personnel.
• Alert Fire Brigade and tell them location and nature of hazard.
• Control personal contact by using protective equipment as required.
• Prevent spillage from entering drains or water ways.
• Contain spill with sand, earth or vermiculite.
• Collect recoverable product into labelled containers for recycling.
• Absorb remaining product with sand, earth or vermiculite and place in
appropriate containers for disposal.
• Wash area and prevent runoff into drains or waterways.
• If contamination of drains or waterways occurs, advise emergency services.

Personal Protective Equipment advice is contained in Section 8 of the MSDS.

Section 7 - HANDLING AND STORAGE

PROCEDURE FOR HANDLING

• Limit all unnecessary personal contact.
• Wear protective clothing when risk of exposure occurs.
• Use in a well-ventilated area.
• Avoid contact with incompatible materials.
• When handling, DO NOT eat, drink or smoke.
• Keep containers securely sealed when not in use.
• Avoid physical damage to containers.
• Always wash hands with soap and water after handling.
• Work clothes should be laundered separately.
• Use good occupational work practice.
• Observe manufacturer's storing and handling recommendations.
• Atmosphere should be regularly checked against established exposure standards
to ensure safe working conditions are maintained.

SUITABLE CONTAINER
• Lined metal can, Lined metal pail/ can
• Plastic pail
• Polyliner drum
• Packing as recommended by manufacturer.
• Check all containers are clearly labelled and free from leaks.

STORAGE INCOMPATIBILITY
Avoid storage with oxidisers and strong acids

STORAGE REQUIREMENTS
• Store in original containers.
• Keep containers securely sealed.
• Store in a cool, dry, well-ventilated area.
• Store away from incompatible materials and foodstuff containers.
• Protect containers against physical damage and check regularly for leaks.
• Observe manufacturer's storing and handling recommendations.

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE CONTROLS
No data available for potassium phosphate, monobasic as (CAS: 7778-77-0) / (CAS:

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ChemWatch Material Safety Data Sheet CHEMWATCH 4508-92
Issue Date: Sat 28-Sep-2002 CD 2005/1 Page 5 of 10
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

7632-00-0) / (CAS: 7631-95-0) / (CAS: 10102-40-6) / (CAS: 7732-18-5)

None assigned. Refer to individual constituents.

EXPOSURE STANDARDS FOR MIXTURE

"Worst Case" computer-aided prediction of spray/ mist or fume/ dust components
and concentration:

Composite Exposure Standard for Mixture (TWA) :1.7391 mg/m³.

Operations which produce a spray/mist or fume/dust, introduce particulates to
the breathing zone.
If the breathing zone concentration of ANY of the components listed below is
exceeded, "Worst Case" considerations deem the individual to be overexposed.
Component Breathing Zone ppm Breathing Zone mg/m³ Mixture Conc (%)

Component Breathing Zone Mixture Conc

(mg/m³) (%)
sodium molybdate 0.4348 5.0
sodium nitrite 0.4348 5.0
potassium phosphate, monobasic 0.8696 10.0

INGREDIENT DATA
POTASSIUM PHOSPHATE, MONOBASIC:
TLV TWA: 10 mg/m³ (Value for particulate matter containing no asbestos and <1% crystalline
silica,Inhalable fraction) [ACGIH]
TLV TWA: 3 mg/m³ (Value for particulate matter containing no asbestos and <1% crystalline
silica,Respirable fraction) [ACGIH]
Dusts not otherwise classified, as inspirable dust;
ES TWA: 10 mg/m³

SODIUM NITRITE:
Dusts not otherwise classified, as inspirable dust;
ES TWA: 10 mg/m³

SODIUM MOLYBDATE:
TLV TWA: 0.5 mg/m³ (R) Soluble Compounds (A3) [ACGIH]
molybdenum, soluble compounds, as Mo (A.Wt: 95.95)
ES TWA: 5 mg/m³
TLV TWA: 0.5 mg/m³ respirable fraction A3
CAUTION: This substance has been classified by the ACGIH as A3 Animal Carcinogen
(at relatively high doses).
OES TWA: 5 mg/m³; STEL: 10 mg/m³
IDLH Level: 1000 mg/m³
An increased incidence of non-specific symptoms including headache, weakness,
fatigue, anorexia and joint and muscle weakness has been reported to occur in
mining and metallurgy workers exposed to 60-600 mg (as Mo). Some investigators
have attributed gout and elevated uric acid concentration found in some
Armenians to result from exposures to Armenian soils rich in molybdenum, whilst
exposure has been implicated as a cause of bone disease amongst Indians. "These
involvements are speculative". [US National Research Council]. As far as it is
known, the recommended TLV-TWA incorporates a large margin of safety against
potential pulmonary or systemic effects.

WATER:
No exposure limits set by NOHSC or ACGIH

PERSONAL PROTECTION

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ChemWatch Material Safety Data Sheet CHEMWATCH 4508-92
Issue Date: Sat 28-Sep-2002 CD 2005/1 Page 6 of 10
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

EYE
• Safety glasses with side shields
• Chemical goggles.
• Contact lenses pose a special hazard; soft lenses may absorb irritants and all
lenses concentrate them.

HANDS/FEET
No special equipment needed when handling small quantities.
OTHERWISE: Wear general protective gloves, eg. light weight rubber gloves. Or as
required: Wear chemical protective gloves, eg. PVC. Wear safety footwear.

OTHER
No special equipment needed when handling small quantities.
OTHERWISE:
• Overalls.
• Barrier cream.
• Eyewash unit.

GLOVE SELECTION INDEX

Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index".
The effect(s) of the following substance(s) are taken into account in the
computer-generated selection:
Substance
________________________________________
water
BUTYL A
NEOPRENE A
VITON A
PVA C
NATURAL RUBBER C

* CPI - Chemwatch Performance Index

A: Best Selection
B: Satisfactory; may degrade after 4 hours continuous immersion
C: Poor to Dangerous Choice for other than short term immersion
NOTE: As a series of factors will influence the actual performance of the glove,
a final selection must be based on detailed observation. -
* Where the glove is to be used on a short term, casual or infrequent basis,
factors such as "feel" or convenience (e.g. disposability), may dictate a choice
of gloves which might otherwise be unsuitable following long-term or frequent
use. A qualified practitioner should be consulted.

RESPIRATOR
Selection of the Class and Type of respirator will depend upon the level of
breathing zone contaminant and the chemical nature of the contaminant.
Protection Factors (defined as the ratio of contaminant outside and inside the
mask) may also be important.

Breathing Zone Maximum Protection Half-face Full-Face

Level ppm (volume) Factor Respirator Respirator
1000 10 -AUS P -
1000 50 - -AUS P
5000 50 Airline * -
5000 100 - -2 P
10000 100 - -3 P
100+ Airline**

* - Continuous Flow ** - Continuous-flow or positive pressure demand

The local concentration of material, quantity and conditions of use determine

the type of personal protective equipment required. For further information
consult site specific CHEMWATCH data (if available), or your Occupational

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ChemWatch Material Safety Data Sheet CHEMWATCH 4508-92
Issue Date: Sat 28-Sep-2002 CD 2005/1 Page 7 of 10
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

Health and Safety Advisor.

ENGINEERING CONTROLS
General exhaust is adequate under normal operating conditions. If risk of
overexposure exists, wear SAA approved respirator. Correct fit is essential to
obtain adequate protection. Provide adequate ventilation in warehouse or closed
storage areas. Air contaminants generated in the workplace possess varying
"escape" velocities which, in turn, determine the "capture velocities" of fresh
circulating air required to effectively remove the contaminant.

Type of Contaminant: Air Speed:

solvent, vapours, degreasing etc., 0.25-0.5 m/s (50-100 f/min)
evaporating from tank (in still air)
aerosols, fumes from pouring 0.5-1 m/s (100-200 f/min.)
operations, intermittent container
filling, low speed conveyer transfers,
welding, spray drift, plating acid
fumes, pickling (released at low
velocity into zone of active
generation)
direct spray, spray painting in shallow 1-2.5 m/s (200-500 f/min)
booths, drum filling, conveyer loading,
crusher dusts, gas discharge (active
generation into zone of rapid air
motion)
grinding, abrasive blasting, tumbling, 2.5-10 m/s (500-2000 f/min.)
high speed wheel generated dusts
(released at high initial velocity into
zone of very high rapid air motion).

Within each range the appropriate value depends on:

Lower end of the range Upper end of the range

1: Room air currents minimal or 1: Disturbing room air currents
favourable to capture
2: Contaminants of low toxicity or of 2: Contaminants of high toxicity
nuisance value only
3: Intermittent, low production. 3: High production, heavy use
4: Large hood or large air mass in 4: Small hood - local control only
motion

Simple theory shows that air velocity falls rapidly with distance away from the
opening of a simple extraction pipe. Velocity generally decreases with the
square of distance from the extraction point (in simple cases). Therefore the
air speed at the extraction point should be adjusted, accordingly, after
reference to distance from the contaminating source. The air velocity at the
extraction fan, for example, should be a minimum of 1-2 m/s (200-400 f/min.) for
extraction of solvents generated in a tank 2 meters distant from the extraction
point. Other mechanical considerations, producing performance deficits within
the extraction apparatus, make it essential that theoretical air velocities are
multiplied by factors of 10 or more when extraction systems are installed or
used.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE
Purple alkaline liquid with a mild odour; mixes with water.

PHYSICAL PROPERTIES
Liquid.

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ChemWatch Material Safety Data Sheet CHEMWATCH 4508-92
Issue Date: Sat 28-Sep-2002 CD 2005/1 Page 8 of 10
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Mixes with water.

Molecular Weight: Not available. Boiling Range (°C): 104

Melting Range (°C): -9
Solubility in water (g/L): Miscible
pH (1% solution): 10.2-10.8 @ 2%
Volatile Component (%vol): 90
Relative Vapour Density (air=1): >1
Lower Explosive Limit (%): Not applicable
Autoignition Temp (°C): Not available.
State: Liquid
Specific Gravity (water=1): 1.112
pH (as supplied): Not available
Vapour Pressure (kPa): Not available.
Evaporation Rate: Not available
Flash Point (°C): Not applicable
Upper Explosive Limit (%): Not applicable
Decomposition Temp (°C): Not available.

Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION

CONDITIONS CONTRIBUTING TO INSTABILITY

• Presence of incompatible materials.
• Product is considered stable.
• Hazardous polymerisation will not occur.

Section 11 - TOXICOLOGICAL INFORMATION

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS

SWALLOWED
Considered an unlikely route of entry in commercial/industrial environments
The liquid is discomforting to the gastro-intestinal tract
Ingestion may result in nausea, abdominal irritation, pain and vomiting

EYE
The liquid is discomforting to the eyes and capable of causing pain and severe
conjunctivitis. Corneal injury may develop, with possible permanent impairment
of vision, if not promptly and adequately treated

SKIN
The liquid is discomforting to the skin and is capable of causing allergic skin
reactions which may lead to dermatitis from repeated exposures over long periods
Sensitisation may result in allergic dermatitis responses including rash,
itching, hives or swelling of extremities.

INHALED
Not normally a hazard due to non-volatile nature of product
The mist is discomforting to the upper respiratory tract

CHRONIC HEALTH EFFECTS

Principal routes of exposure are usually by skin contact / eye contact with the material
As with any chemical product, contact with unprotected bare skin; inhalation of vapour,
mist or dust in work place atmosphere; or ingestion in any form, should be avoided by
observing good occupational work practice.

Fleetguard ES Liquid
Not available. Refer to individual constituents.
unless otherwise specified data extracted from RTECS - Register of Toxic Effects
of Chemical Substances

POTASSIUM PHOSPHATE, MONOBASIC:

No data of toxicological significance identified in literature search.

SODIUM NITRITE:

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ChemWatch Material Safety Data Sheet CHEMWATCH 4508-92
Issue Date: Sat 28-Sep-2002 CD 2005/1 Page 9 of 10
Section 11 - TOXICOLOGICAL INFORMATION

TOXICITY IRRITATION
Oral (human) LDLo: 71 mg/kg Eye (rabbit): 500 mg/24hr - mild
Oral (human) TDLo: 14 mg/kg
Oral (man) TDLo: 1.71 mg/kg/70M
Oral (rat) LD50: 180 mg/kg
Inhalation (rat) LC50: 5.5 mg/m3/4H
Tumorigenic - Carcinogenic by RTECS criteria.

SODIUM MOLYBDATE:
TOXICITY IRRITATION
Oral rat LD50: 4000 mg/kg
Inhalation rat LC50: >2080 mg/m3/4 hours

WATER:
No significant acute toxicological data identified in literature search.

Section 12 - ECOLOGICAL INFORMATION

No data for Fleetguard ES Liquid.

Refer to data for ingredients, which follows:

POTASSIUM PHOSPHATE, MONOBASIC:

The principal problems of phosphate contamination of the environment relates to

eutrophication processes in lakes and ponds. Phosphorus is an essential plant
nutrient and is usually the limiting nutrient for blue-green algae. A lake
undergoing eutrophication shows a rapid growth of algae in surface waters.
Planktonic algae cause turbidity and flotation films. Shore algae cause ugly
muddying, films and damage to reeds. Decay of these algae causes oxygen
depletion in the deep water and shallow water near the shore. The process is
self-perpetuating because anoxic conditions at the sediment/water interface
causes the release of more adsorbed phosphates from the sediment. The growth of
algae produces undesirable effects on the treatment of water for drinking
purposes, on fisheries, and on the use of lakes for recreational purposes.

SODIUM NITRITE:
Hazardous Air Pollutant: No
Hazardous Air Pollutant: No

The material is classified as an ecotoxin* because the Fish LC50 (96 hours) is
less than or equal to 0.1 mg/l

* Classification of Substances as Ecotoxic (Dangerous to the Environment)

Appendix 8, Table 1
Compiler's Guide for the Preparation of International Chemical Safety Cards:
1993 Commission of the European Communities
Toxicity invertebrate: LC50(48)33-100mg/L

SODIUM MOLYBDATE:

No data for sodium molybdate.

WATER:

No data for water.

Section 13 - DISPOSAL CONSIDERATIONS

• Recycle wherever possible or consult manufacturer for recycling options.

• Consult State Land Waste Management Authority for disposal.
• Treat and neutralise with dilute acid at an effluent treatment plant.
• Recycle containers, otherwise dispose of in an authorised landfill.

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ChemWatch Material Safety Data Sheet CHEMWATCH 4508-92
Issue Date: Sat 28-Sep-2002 CD 2005/1 Page 10 of 10

Section 14 - TRANSPORTATION INFORMATION

Shipping Name:
NONE
Dangerous Goods Class: None
UN/NA Number: None
ADR Number: None
Packing Group: None
Labels Required:
Additional Shipping Information:
International Transport Regulations:
IMO: None

HAZCHEM
None

Section 15 - REGULATORY INFORMATION

POISONS SCHEDULE
S5

REGULATIONS
potassium phosphate, monobasic (CAS: 7778-77-0) is found on the following regulatory lists:
Australian Inventory of Chemical Substances (AICS)

sodium nitrite (CAS: 7632-00-0) is found on the following regulatory lists:

Australian Inventory of Chemical Substances (AICS)
Australian Poisons Schedule

sodium molybdate (CAS: 7631-95-0) is found on the following regulatory lists:

Australian Inventory of Chemical Substances (AICS)

sodium molybdate (CAS: 10102-40-6) is found on the following regulatory lists:

Australian Inventory of Chemical Substances (AICS)

water (CAS: 7732-18-5) is found on the following regulatory lists:

Australian Inventory of Chemical Substances (AICS)

Section 16 - OTHER INFORMATION

This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.

Issue Date: Sat 28-Sep-2002

Print Date: Wed 23-Mar-2005