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Cobalt was discovered by Georg Brandt in 1735 interestingly the name Cobalt
originates form the German word “Kobald” which means goblin or evil spirit. The
original use of cobalt was value to early civilisation of Egypt for colouring glass blue.
Alfred Werner was a pioneer in coordination Chemistry determined the isomer cobalt
(III) hexamine chloride.
Experimental
A portion of this product (???g) was dissolved in Dilute ammonia (10cm3), water
(40cm3) was added. The solution was heated (15 mins) forming a clear red solution.
Concentrate Hydrochloric acid ( 10cm3) was added followed by Ammonium chloride
(1.00g) forming a orange solution. The resulting solution was heated for a further
25mins. COLOURS ??. Solution was cooled in ice and the product filtered off and
washed with hydrochloric acid (5cm3) ethanol (5cm3) and acetone (5.5cm3). Forming
0.??g ??%)
Ammonium Chloride (1.0g) was dissolved in Boling water (3.5cm3). Cobalt(II) chloride
hexahydrate (1.548g) was added producing a deep royal blue solution. Charcoal (?
0.75g) was added turning the solution grey black. The solution was cooled in an ice
bath to 5oC and Concentrate Ammonia (4.5cm3) was added in small portions over 3
mins. Hydrogen peroxide (23% vol) (4cm3) was added in portions over 5 mins. The
solution was then heated to 60oC for 1 min. The solution was re cooled to 3oC in an
ice bath. The black oily precipitate was filtered under suction before being added to
Boiling water (12cm3). Concentrate Hydrochloric acid (0.5cm3) was added and then
the solution filtered. Concentrate Hydrochloric acid (2cm3) was added to the filtrate
(liquid) and the solution cooled in ice. The resulting orange precipitate was filtered
and washed with acetone (10cm3) producing (0.444g ??%)
Equations
n=M/Mr
n= Moles
Mr = Molecular weight
n= C x V
n = moles
V= Volume (L)
100cm3= 0.1L
n=M/Mr
M= 0.1100g
n = 0.1100/267.4762
n= 4.1125431×10-4
n=CV
S m2 mol L-1
n=M/Mr
M= 0.0934g
n = 0.0934/341.90
n= 2.73179 x10-4
n=CV
2.73179×10-4= C x 0.1
C= 2.7317929 x10-3mol L-1 à 0.27317929 mol m3
S m2 mol L-1
n=M/Mr
M= 0.1010g
n = 0.1010/267.4762
n= 3.776036896 x10-4
n=CV
S m2 mol L-1