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Elemental Spectroscopy Results: A Guide To Understanding
Elemental Spectroscopy Results: A Guide To Understanding
Elemental Spectroscopy is one the most fundamental oil analysis tests. It is used to determine the
concentrations of elements ranging from wear metals and contaminants to oil additives. The method
used to perform the measurement is properly termed Inductively Coupled Plasma Atomic Emission
Spectroscopy (ICP-AES) and the results are commonly referred to as ICP or spec results.
Silver
Silver is a wear metal used as on overlay on
some bearings, such as journal bearing for gas
turbines or wrist pin bearings on EMD
locomotive engines. Silver from these parts will
increase disproportionately with iron. Zinc
additized oils will accelerate the corrosion of
silver in these applications, therefore the use of
tricresyl phosphate (TCP) additives is
warranted.
TYPE OF EQUIPMENT
Element Hydraulic Transmission Turbine
Airborne dirt Airborne dirt Airborne dirt
Cylinder gland Bushings Alumina media
Aluminum Pump housing Clutch/Friction disc contamination
Pumps Bearings
Thrust washers Oil cooler
Rods Roller/Taper bearings Bearings
Chromium Roller/Taper bearings Shaft coating
Spools
Bushings Bearings Bearings
Cylinder glands Bushings Oil cooler
Guides Clutch/Friction disc
Copper
Oil cooler Oil cooler
Pump pistons Steering discs
Pump thrust plates Thrust washers
Bearings Bearings Bearings
Cylinder bores Brake bands Reduction gear
Gears Clutch/Friction disc Shafts
Pistons Gears
Iron
Pump housing Housings
Pump vanes Power Take-Off (PTO)
Rods Pumps
Valves Shift spools
Bearings Bearings Bearings
Lead
Clutch/Friction disc
Pumps Bearings Bearings
Nickel
Gear plating
Bearing cage Bearing cage Roller bearings
Silver
Solder from coolers Solder from coolers Thrust bearings
Bearings Bearings Bearings
Polyol ester catalyst Clutch Solder from coolers
Tin Pump thrust plates Solder from coolers
Solder from coolers Thrust washers
Zinc may appear due as a wear, but generally With normal and expected additive depletion
any application where it may exist as a wear due to usage, the additives are still present in
metal will employ an AW oil, therefore the zinc the fluid, and will still be measured at their
content would be masked by the presence of normal levels. Once they do not appear in the
the additive. Brass wear can be differentiated fluid, they have dropped out completely, which
from bronze wear, as only brass contains zinc, indicates a more severe degradation
and both contain copper, lead and tin. Solders mechanism or additive drop-out.
contain zinc, as well as lead and tin; galvanized
steel (from piping or tanks) contains iron and Molybdenum may appear as a wear, as some
zinc; and some coating contain zinc, as well as piston rings and certain alloys of steel use
chromium and nickel. molybdenum. Molybdenum will increase
disproportionally with iron in a reciprocating
application, but will remain proportional with
Barium iron with wear of an alloyed part.
Barium was a detergent additive metal found in
natural gas engine oils, but is no longer allowed
in products manufactured in North America due
to toxicity concerns
Molybdenum
Molybdenum is an additive metal commonly
used in friction modifier additives. Only when
the molybdenum level deviates more than 25%
from the new oil or reference value should a
concern be raised, but the likeliest cause if
mixing or topping-off with a different product.
Element Function
Barium Rust Inhibitor, detergent or dispersant additive
Boron Anti-wear additive
Calcium Detergent or dispersant additive, corrosion inhibitor
Copper Anti-wear additive
Magnesium Detergent or dispersant additive, corrosion inhibitor
Molybdenum Friction modifier
Phosphorus EP additive, anti-wear additive, corrosion inhibitor
Silicon Defoamant additive
Sodium Detergent or dispersant additive, corrosion inhibitor
Zinc Anti-wear or anti-oxidant additive, rust inhibitor, EP additive
Element Function
Aluminum Airborne dirt (correlation ~3:1 Silicon/Aluminum), grease thickener
Barium Grease additive
Boron Coolant additive, detergent additive, oil drum cleansing agent
Calcium Fuller’s earth, dust, gypsum, hard water
Lithium Grease thickener
Magnesium Fuller’s earth, hard water
Potassium Coolant additive, fly ash
Silicon Airborne dust or dirt (as above), defoamant additive, sealant
Sodium Coolant additive, detergent or dispersant additive, airborne salt
Titanium Machinist layout paint, aerosol paint
Vanadium Residual fuel contamination (Bunker C)