You are on page 1of 15

A Guide To Understanding

ELEMENTAL SPECTROSCOPY RESULTS


Getting the most out of an oil
analysis program begins with
understanding the results.
Having detailed knowledge of the analysis report helps pinpoint
problem areas. As experience in interpreting the reports is
gained, one becomes an expert in determining the corrective
actions that lead to increased reliability. Many times, catching
lubricant issues can save time and money in equipment repairs and downtime.

Elemental Spectroscopy is one the most fundamental oil analysis tests. It is used to determine the
concentrations of elements ranging from wear metals and contaminants to oil additives. The method
used to perform the measurement is properly termed Inductively Coupled Plasma Atomic Emission
Spectroscopy (ICP-AES) and the results are commonly referred to as ICP or spec results.

A noteworthy limitation to this test is that the sample must


Use Trending Over completely ionize within a very small, measured area of the
Alarm Limits plasma. As such, only particulate within 0-5 microns is
accurately measured, and particles larger than 10 microns
Absolute limits typically only apply to are essentially not measured at all. Wear particles generated
end of drain samples under a specific under normal conditions and airborne contaminants easily
set of variables; trending avoids many fall within this range, however severe wear and/or
of these pitfalls and can easily spot contamination may produce particles too large for detection
abnormal deviations. and would require supplemental testing such as particle
counting or analytical ferrography.
Trending works on both individual
machines and large fleets, trending Though additives are sub-micron and will always be detected
does not require reporting of hours, by this method, a second fundamental aspect of this test
make/model or sump size, and must be considered: this test only measures elements, not
trending works on both mid-interval compounds, alloys or chemicals. Though certain elements
samples and end-of-drain samples.
may appear in the results and be safely assumed to be from
Trending not only works independently, certain types of additives, this test does not confirm the
or in conjunction with, limits, but it functionality of those additives. While additives are slowly
also re-establishes oil analysis as a consumed, so long as they remain present in the fluid, the
truly predictive maintenance tool. results will not decrease significantly.
CONTENTS
WEAR METALS..................................................................................................................................1
Iron................................................................................................................................................1
Copper ...........................................................................................................................................1
Lead...............................................................................................................................................2
Aluminum ......................................................................................................................................2
Tin .................................................................................................................................................3
Chromium ......................................................................................................................................3
Titanium.........................................................................................................................................3
Vanadium.......................................................................................................................................4
Silver..............................................................................................................................................4
Potential Wear Metal Sources .........................................................................................................5
ADDITIVES...........................................................................................................................................7
Calcium ..........................................................................................................................................7
Magnesium ....................................................................................................................................7
Phosphorus ....................................................................................................................................8
Zinc................................................................................................................................................8
Barium ...........................................................................................................................................9
Potential Additive Sources............................................................................................................. 10
CONTAMINANTS ................................................................................................................................. 11
Silicon .......................................................................................................................................... 11
Boron........................................................................................................................................... 11
Lithium......................................................................................................................................... 11
Sodium......................................................................................................................................... 12
Potassium .................................................................................................................................... 12
Potential Contaminant Sources...................................................................................................... 13
WEAR
METALS
Iron
Iron is commonly expected to be found in
samples as a wear metal, as it is the foundation
element in all forms of steel, which is by far the
most prevalent material in lubricated machines. and bronze parts are alloys of copper lead, tin
It will often correlate with other metals like and/or zinc. Being an alloy, the wear metals
chromium, titanium, molybdenum and from these parts will remain proportional as
vanadium; if the correlation remains they increase.
proportional as levels increase it suggests these
metals are alloyed, but if the other metals When copper increases disproportionally from
increase disproportionally then this suggests other wear metals, it suggests a nearly pure
coated steel parts. copper part or copper-coated part. Plain
bearings typically have a copper layer below the
In gear and plain bearing applications, the steel Babbitt layer, therefore any appearance of
parts are expected to wear at a slower rate than copper in these applications may be viewed as
the mating gear or bearing, so it would be actionable.
expected to see a greater increase in copper, tin
and lead than iron. When iron is increasing at a In applications using some form of oil cooler,
faster rate than other metals the culprit may be whether a radiator-styled air cooler or a shell
corrosion, which can be confirmed by elevated and tube cooler, the tubes or commonly made
water content and/or a corresponding increase from copper. When a tube or entire cooler is
in Acid Number. replaced, the new copper parts will oxidize
slowly for weeks and leach dissolved copper
Iron can also appear as a contaminant; when oxide into the oil, but this increase in copper
granular clay oil absorbent (kitty litter) is used will plateau and should not be viewed as
near a machine, the dust it creates can be abnormal or damaging.
breathed into the system and will appear as an Another form of a harmless increase in copper
increase in iron, calcium and magnesium. This may be seen due to the use of a copper-based
dust is very abrasive and may lead to increased anti-seize compound during reassembly, as any
wear. excess will dissolve into the oil as well.

Copper Perhaps the most concerning increase in copper


Copper usually appears in fluid samples as a can be found in conjunction with the use of EP
wear metal, most often arising from brass or oils, as some, but not all, EP oils may employ an
bronze components. Whether gears, bearing active sulfur extreme pressure (EP) additive that
cages, guides, bushings or piston shoes, brass will chemically attack copper and copper alloys

© 2017 Insight Services, Inc. All Rights Reserved 1


WEAR METALS
(a.k.a. yellow metals). The only remedy to this engine compared to a steel block engine. The
situation is a fluid change to a fluid using either block itself may be a source of wear metals
a non-active sulfur EP additive chemistry, or an when the sleeves for the pistons are machined
anti-wear (AW) additive chemistry, as directly into the block, as is the case in steel
recommended by the OEM. engine blocks. With aluminum blocks, the
aluminum would be too soft to withstand much
wear, so steel sleeves/cylinder liners are
Lead installed; therefore, the primary source of wear
Lead is an expected wear metal in any machine metals in an engine produces similar wear
using plain bearings, as lead and tin are the metals, regardless of block material.
most predominant metals used in Babbitt
overlay, with lesser amounts of copper, In fact, there are very few aluminum parts in
antimony and/or arsenic. Typically, increasing machines that are wearing and oil-wetted, and
levels of lead from this layer are not considered would therefore appear on an oil analysis
actionable, not until metals like copper or nickel report. Reciprocating pistons, whether from
from a lower layer begin appearing. and engine or compressor, are commonly made
from aluminum, but the wearing component of
pistons are the rings, which usually sheds
metals like chromium or molybdenum. Thrust
washers and bushings are legitimate sources of
aluminum as a wear metal.
Another example of aluminum not being a wear
metal is in the differentiation between dust and
dirt on an oil analysis report. Dust is in the form
Lead and tin may also appear due to leaching of silicon dioxide, and is typically small enough
from the solder used to attach cooler tubes, to remain airborne and enter systems through
often in conjunction with an increase in Acid most breathers; dirt, on the other hand, is
Number, however the common action is to aluminum silicate and is a relatively larger
simply change the fluid. particle that is less commonly expected to be
Another form of a harmless increase in lead airborne or able to enter protected systems.
may be seen due to the use of a lead-based Aluminum silicate appears on oil analysis
anti-seize compound during reassembly, as any reports as silicon and aluminum is an
excess will dissolve into the oil as well. approximately 3:1 to 4:1 ration
In engine oil samples, lead may appear from the (silicon:aluminum), and frequently correlates to
use of aftermarket fuel additives like octane an increase in particle count.
boosters, but this should not be viewed as an
increase due to mechanical wear. Users of activated alumina acid scavenging
systems may see aluminum appear as well,
typically in conjunction with sodium, especially
Aluminum in the first sample after a new set of cartridges
While lead is commonly thought to be wear is installed. A correlation with an increase in
metal, that is not always the case. One example particle count will likely be observed.
would be an oil sample from an aluminum block

© 2017 Insight Services, Inc. All Rights Reserved 2


WEAR METALS
Tin Chromium
Tin is another wear metal expected in any Chromium is a wear metal found in the coating
machine using plain bearings, as lead and tin of parts like valves, rods, rings and bearings.
are the most predominant metals used in Typically, increasing levels of chromium, and
Babbitt overlay, with lesser amounts of copper, possibly nickel, disproportional with iron,
antimony and/or arsenic. Typically, increasing indicate coating wear, whereas proportional
levels of tin from this layer are not considered increases suggests steel alloy wear.
actionable, not until metals like copper or nickel
from a lower layer begin appearing. One form of proportional chromium and iron
increase may arise from non-wearing parts
Tin may also appear in newer engines or rebuilt made from stainless steel. Some lube oil piping
engines from the piston overlay that is used, or and/or coolers can be manufactured from
from bushings used in reciprocating stainless steel which may corrode due to
applications. elevated acidity, or erode due to particulate.
Lead and tin may also appear due to leaching When the ratio of chromium to iron is 1:10 to
from the solder used to attach cooler tubes, 1:4, this is highly suggestive of stainless steel
often in conjunction with an increase in Acid wear; when seen with an increase in Acid
Number, however the common action is to Number it is likely corrosion, and when seen
simply change the fluid. with an increase in particle count it is likely
erosion.
Nickel
Nickel is a wear metal found in some machines
using plain bearings, as lead and tin are the
most predominant metals used in Babbitt
overlay, with lesser amounts of copper,
antimony and/or arsenic. Typically, increasing
levels of nickel are from an intermediate layer
and therefore considered actionable.

Nickel can also increase as wear from some


steel parts. It will correlate with iron and other
metals like chromium, titanium, molybdenum
and vanadium; if the correlation remains
proportional as levels increase it suggests these
metals are alloyed, but if the other metals Titanium
increase disproportionally then this suggests Titanium is a wear metal commonly found
coated steel parts. alloyed with other metals. Proportional
increases in titanium and iron are indicative of
One form of a harmless increase in nickel may ferrotitanium, which is typically used the
be seen due to the use of a nickel-based anti- manufacture of shafts. Lightweight titanium
seize compound during reassembly, as any parts like connecting rods are alloys of titanium,
excess will dissolve into the oil as well. aluminum and vanadium; wear from these parts
is often disproportional with iron levels.

© 2017 Insight Services, Inc. All Rights Reserved 3


WEAR METALS
One form of a harmless increase in titanium Vanadium
may be seen from to the use of paints, whether Vanadium is another wear metal commonly
machinist layout fluid to confirm gear mesh, or found alloyed with other metals. Vanadium
recent repainting of a casing exterior using may also be found in the coating of parts like
aerosols. Most bright or reflective paints valves, rods, rings and bearings. Typically,
contain titanium dioxide as a brightener, increasing levels of vanadium, and possibly
however the titanium from worn or dissolved chromium, disproportional with iron, indicate
paint is typically not near clearance size and coating wear, whereas proportional increases
therefore not likely to lead to wear. suggests hard steel alloy wear.

A common misconception about titanium is One form of a harmless increase in vanadium


attribution of wear from titanium parts that are may be seen from to the use of Bunker C fuel in
not oil-wetted, such as turbo manifolds or engines. Crude oil, typically from the Caribbean
turbine blades. While these parts made be area or Mexico, contains vanadium, and much
made from titanium, they are not in contact of it remains in some lesser-refined products.
with the lubricant, nor is their wear debris Unburnt fuel will carry vanadium into engine oil,
expected to migrate to the lubricant. appearing if heat drives of the fuel. This will
manifest as reasonably stable vanadium values,
that may correlate with nickel, iron, potassium,
sodium, aluminum, copper and/or silicon.

Silver
Silver is a wear metal used as on overlay on
some bearings, such as journal bearing for gas
turbines or wrist pin bearings on EMD
locomotive engines. Silver from these parts will
increase disproportionately with iron. Zinc
additized oils will accelerate the corrosion of
silver in these applications, therefore the use of
tricresyl phosphate (TCP) additives is
warranted.

Silver can also be found in some solders,


therefore silver, lead and tin may also appear
due to leaching from the solder used to attach
cooler tubes, often in conjunction with an
increase in Acid Number.

© 2017 Insight Services, Inc. All Rights Reserved 4


WEAR METALS
Potential Wear Metal Sources

TYPE OF EQUIPMENT
Element Hydraulic Transmission Turbine
Airborne dirt Airborne dirt Airborne dirt
Cylinder gland Bushings Alumina media
Aluminum Pump housing Clutch/Friction disc contamination
Pumps Bearings
Thrust washers Oil cooler
Rods Roller/Taper bearings Bearings
Chromium Roller/Taper bearings Shaft coating
Spools
Bushings Bearings Bearings
Cylinder glands Bushings Oil cooler
Guides Clutch/Friction disc
Copper
Oil cooler Oil cooler
Pump pistons Steering discs
Pump thrust plates Thrust washers
Bearings Bearings Bearings
Cylinder bores Brake bands Reduction gear
Gears Clutch/Friction disc Shafts
Pistons Gears
Iron
Pump housing Housings
Pump vanes Power Take-Off (PTO)
Rods Pumps
Valves Shift spools
Bearings Bearings Bearings
Lead
Clutch/Friction disc
Pumps Bearings Bearings
Nickel
Gear plating
Bearing cage Bearing cage Roller bearings
Silver
Solder from coolers Solder from coolers Thrust bearings
Bearings Bearings Bearings
Polyol ester catalyst Clutch Solder from coolers
Tin Pump thrust plates Solder from coolers
Solder from coolers Thrust washers

© 2017 Insight Services, Inc. All Rights Reserved 5


WEAR METALS
TYPE OF EQUIPMENT
Element Compressor Engine Gearbox
Airborne dirt Airborne dirt Airborne dirt
Bearings Bearings Bushings
Block (corrosion) Block (corrosion) Grease contamination
Cylinder guides Blowers Oil Pump
Oil cooler Bushings Thrust washers
Aluminum
Oil pump Oil cooler
Pistons Oil pump
Rotors Pistons
Thrust washers Thrust bearings
Wear plates
Cylinder guides Bearings Roller/Taper bearings
Rings Exhaust valves Shaft coating
Chromium Roller/Taper bearings Liners
Thrust washers Rings
Wear plates Roller/Taper bearings
Bearings (Recips) Bearings (near failure) Bushings
Rings Cam bushings Oil cooler
Roller/Taper bearings Connecting rod bearings Thrust washers
Thrust washers Governor
Wear plates Oil additive
Copper
Oil cooler
Oil pump
Thrust washers
Valvetrain bushings
Wrist pin bushings
Bearings Oil pump Block Liners Bearings
Block Rings Camshaft Oil pump Gears
Iron Camshaft Screws Crankshaft Rings (cast) Pinions
Cylinder Shafts Cylinder Valvetrain Shaft
Lobes Gears Wrist pins Thrust washers
Bearings Bearings Bearings
Lead
Thrust washers Thrust washers
Bearings Bearings Bearings
Nickel
Gear plating
Bearings Bearing cage Bearing cage
Silver Solder from coolers Solder from coolers
Wrist pin bushings
Bearings Bearings Bushings
Bushings Bushings
Piston overlay Con-rod bearings
Tin Governor
Piston overlay
Solder from coolers
Thrust washers

© 2017 Insight Services, Inc. All Rights Reserved 6


ADDITIVES
Calcium and magnesium may also appear
proportionally due to hard water
contamination, which may lead to rust or
Calcium corrosion, correlating with an increase in iron
Calcium is an additive metal commonly used in and possibly water content, if it has not been
detergent additives. Only when the calcium drive off by heat.
level deviates more than 25% from the new oil
or reference value should a concern be raised, In mobile applications, calcium may also be
but the likeliest cause if mixing or topping-off found in road dust, and will increase
with a different product. proportionally with magnesium and particle
count, and possibly silicon and/or aluminum.
With normal and expected additive depletion
Magnesium
due to usage, the additives are still present in
Magnesium is an additive metal commonly used
the fluid, and will still be measured at their
in detergent additives. Only when the
normal levels. Once they do not appear in the
magnesium level deviates more than 25% from
fluid, they have dropped out completely, which
the new oil or reference value should a concern
indicates a more severe degradation
be raised, but the likeliest cause if mixing or
mechanism or additive drop-out.
topping-off with a different product.
Calcium may also appear from the use of
With normal and expected additive depletion
granular oil absorbent products like kitty litter.
due to usage, the additives are still present in
These products are made from Fuller’s Earth,
the fluid, and will still be measured at their
which is a magnesium- and calcium-based clay,
normal levels. Once they do not appear in the
that has an iron contaminant. Proportional
fluid, they have dropped out completely, which
increase in calcium, magnesium and iron, as
indicates a more severe degradation
well as particle count, often indicate ingression
mechanism or additive drop-out.
of this abrasive particulate.

© 2017 Insight Services, Inc. All Rights Reserved 7


ADDITIVES

With normal and expected additive depletion


due to usage, the additives are still present in
the fluid, and will still be measured at their
normal levels. Once they do not appear in the
fluid, they have dropped out completely, which
indicates a more severe degradation
mechanism or additive drop-out.

Phosphorus may appear due to grease


contamination, as general-purpose greases also
Magnesium may also appear from the use of contain AW or EP additive packages. Machines
granular oil absorbent products like kitty litter. with greased seals or those having undergone
These products are made from Fuller’s Earth, recent maintenance may exhibit small increases
which is a magnesium- and calcium-based clay, in phosphorus, depending on the rate of
that has an iron contaminant. Proportional leakage or overage in use.
increase in calcium, magnesium and iron, as
well as particle count, often indicate ingression Another form of maintenance that may lead to
of this abrasive particulate. an increase in phosphorus levels is through the
Calcium and magnesium may also appear use of degreasing chemicals, either from
proportionally due to hard water equipment or parts washing. Some degreasers
contamination, which may lead to rust or are phosphate-based, and may enter a machine
corrosion, correlating with an increase in iron during high-pressure wash-downs, or be
and possibly water content, if it has not been residual contamination from aqueous
drive off by heat. degreasers used in parts washers.

In mobile applications, magnesium may also be


found in road dust, and will increase
Zinc
proportionally with calcium and particle count, Zinc is an additive metal found in all anti-wear
and possibly silicon and/or aluminum. (AW) additive packages. Only when the zinc
level deviates more than 25% from the new oil
or reference value should a concern be raised,
Phosphorus but the likeliest cause if mixing or topping-off
Phosphorus is an additive metal found in all with a different product. The zinc level in AW
anti-wear (AW) and extreme pressure (EP) oils is always comparable to the level of
additive packages. Only when the phosphorus phosphorus.
level deviates more than 25% from the new oil
or reference value should a concern be raised, With normal and expected additive depletion
but the likeliest cause if mixing or topping-off due to usage, the additives are still present in
with a different product. AW oils can be the fluid, and will still be measured at their
differentiated from EP oils, as AW oils contain normal levels. Once they do not appear in the
zinc, at comparable levels, whereas EP typically fluid, they have dropped out completely, which
contain no or low levels of zinc.

© 2017 Insight Services, Inc. All Rights Reserved 8


ADDITIVES
indicates a more severe degradation This type of friction modifier is found in many
mechanism or additive drop-out. engine oils, and some transmission fluids.

Zinc may appear due as a wear, but generally With normal and expected additive depletion
any application where it may exist as a wear due to usage, the additives are still present in
metal will employ an AW oil, therefore the zinc the fluid, and will still be measured at their
content would be masked by the presence of normal levels. Once they do not appear in the
the additive. Brass wear can be differentiated fluid, they have dropped out completely, which
from bronze wear, as only brass contains zinc, indicates a more severe degradation
and both contain copper, lead and tin. Solders mechanism or additive drop-out.
contain zinc, as well as lead and tin; galvanized
steel (from piping or tanks) contains iron and Molybdenum may appear as a wear, as some
zinc; and some coating contain zinc, as well as piston rings and certain alloys of steel use
chromium and nickel. molybdenum. Molybdenum will increase
disproportionally with iron in a reciprocating
application, but will remain proportional with
Barium iron with wear of an alloyed part.
Barium was a detergent additive metal found in
natural gas engine oils, but is no longer allowed
in products manufactured in North America due
to toxicity concerns

Greases, though, continue to use barium in the


form of a thickener system. Machines with
greased seals or those having undergone recent
maintenance may exhibit small increases in
barium, depending on the rate of leakage or
overage in use.

Barium is often ignored, since it appears to


rarely, but this also serves as the justification to
investigate appearance of any level of barium,
as it indicates an abnormal condition.

Molybdenum
Molybdenum is an additive metal commonly
used in friction modifier additives. Only when
the molybdenum level deviates more than 25%
from the new oil or reference value should a
concern be raised, but the likeliest cause if
mixing or topping-off with a different product.

© 2017 Insight Services, Inc. All Rights Reserved 9


ADDITIVES

Potential Additive Sources

Element Function
Barium Rust Inhibitor, detergent or dispersant additive
Boron Anti-wear additive
Calcium Detergent or dispersant additive, corrosion inhibitor
Copper Anti-wear additive
Magnesium Detergent or dispersant additive, corrosion inhibitor
Molybdenum Friction modifier
Phosphorus EP additive, anti-wear additive, corrosion inhibitor
Silicon Defoamant additive
Sodium Detergent or dispersant additive, corrosion inhibitor
Zinc Anti-wear or anti-oxidant additive, rust inhibitor, EP additive

© 2017 Insight Services, Inc. All Rights Reserved 10


CONTAMINANTS
Boron
Boron is an additive metal commonly used in
detergent additives, and occurs in some EP or
AW additive chemistries. Only when the boron
level deviates more than 25% from the new oil
Silicon or reference value should a concern be raised,
Silicon is commonly identified as a contaminant, but the likeliest cause if mixing or topping-off
either from dust or dirt, which must be with a different product.
understood to be completely different types of
contaminants. With normal and expected additive depletion
due to usage, the additives are still present in
Dirt has a different chemical composition than the fluid, and will still be measured at their
dust, though they both are silicon-based. Dirt is normal levels. Once they do not appear in the
also made up of aluminum, with a ratio of fluid, they have dropped out completely, which
around 3-4 times more silicon than aluminum. indicates a more severe degradation
The presence of silicon should always be mechanism or additive drop-out.
compared to the aluminum levels, and only
when the ratio exists can the contamination be Boron may also due to a coolant leak, often in
described as dirt rather than dust. conjunction with sodium and/or potassium;
these elements are present due to the additives
The distinction is important because dust is a used in many coolant formulations. The
much smaller particle and is always present in presence of these elements alongside detected
the atmosphere, and therefore is more readily glycol and water often indicate a severe or
breathed into a system than dirt. Dust particles bottom-end leak, but the absence of glycol and
may be present even in new oil, hence the water typically represent a top-end leak where
persistent suggestion to pre-filter oils. the liquid portion of the coolant is being
combusted or boiled out of the system.
Silicon may also appear as a non-harmful
contaminant, especially after recent On rare occasions, sodium may be present in
maintenance, in the form of silicon gasket the form of an oil additive, which can be
maker or silicon-based grease. Both of these verified with a sample of new oil for reference.
sources may become dissolved in the lubricant,
but neither pose any significant risk for wear.

Lastly, while it may be relatively well-known


Lithium
that anti-foam additives are commonly silicon- Lithium is used in the most common form of
based, i.e. polydimethylsiloxane, their typical thickener system for greases. Generally, traces
concentrations in new oils are at very low levels of grease migrating into a lubrication
levels. Expect 2-3 ppm silicon as an additive, system are not harmful, however the additives
but once levels approach 10 ppm, even in new from the grease may create a negative synergy
oil, this likely represents dust contamination. with the additives in the lubricant.

© 2017 Insight Services, Inc. All Rights Reserved 11


CONTAMINANTS
On rare occasions, boron may be due to
Sodium residual cleaner from drum/tote recycling, as
Sodium is an indicator of a coolant leak, often in the cleaners that are used may be borate-
conjunction with potassium and/or boron; based.
these elements are present due to the additives
used in many coolant formulations. The Potassium
presence of these elements alongside detected Potassium is an indicator of a coolant leak,
glycol and water often indicate a severe or often in conjunction with sodium and/or boron;
bottom-end leak, but the absence of glycol and these elements are present due to the additives
water typically represent a top-end leak where used in many coolant formulations. The
the liquid portion of the coolant is being presence of these elements alongside detected
combusted or boiled out of the system. glycol and water often indicate a severe or
bottom-end leak, but the absence of glycol and
Sodium is also an indicator of contamination water typically represent a top-end leak where
with salt, whether it is from moisture ingression the liquid portion of the coolant is being
from a nearby source of salt water, or airborne combusted or boiled out of the system
particulate ingression from nearby roads that
are salted in the wintertime. Potassium is also an indicator of airborne
particulate ingression from fly ash or smoke.
Users of activated alumina acid scavenging The fly ash or smoke need not be visible, nor
systems may see sodium appear as well, nearby, the only criteria is that the asset be
typically in conjunction with aluminum, located within the fallout zone. Forest fire
especially in the first sample after a new set of smoke frequently migrates hundreds and
cartridges is installed. A correlation with an hundreds of miles, and will last for nearly as
increase in particle count will likely be long as the original fire burned. This form of
observed. particulate is small enough to pass through
even high-quality particulate breathers.

© 2017 Insight Services, Inc. All Rights Reserved 12


CONTAMINANTS

Potential Contaminant Sources

Element Function
Aluminum Airborne dirt (correlation ~3:1 Silicon/Aluminum), grease thickener
Barium Grease additive
Boron Coolant additive, detergent additive, oil drum cleansing agent
Calcium Fuller’s earth, dust, gypsum, hard water
Lithium Grease thickener
Magnesium Fuller’s earth, hard water
Potassium Coolant additive, fly ash
Silicon Airborne dust or dirt (as above), defoamant additive, sealant
Sodium Coolant additive, detergent or dispersant additive, airborne salt
Titanium Machinist layout paint, aerosol paint
Vanadium Residual fuel contamination (Bunker C)

© 2017 Insight Services, Inc. All Rights Reserved 13

You might also like