1) phenol is more readily soluble in

a) dilute HCl. b) both NaOHand HCl.

c)NaOH solution. d) sodium bicarbonate solution.

2) when -OH group is linked with benzene, the compound formed is

a) phenol. b) benzaldehyde. C) benzyl alcohol. D) acetophenone.

3)Ether on hydrolysis give

a) carboxylic acid

b) alcohol

c)Ethers

d) ketone

4) in cannizzaro reaction

a) acid is converted into amine

b) aldehyde is converted into alcohol

c) alcohol is converted into aldehyde

d)primary amine is converted into cyanide.

5) aldehyde and ketone are separated by

a) phenylhydrazine

b) tollens reagent

c) sulfuric acid

d) None

6) which of the following alcohol give ketone on oxidation

a) primary

b) secondary

c) tertiary

d) all

7) which decolourises the colour of acidic KMnO4

a) acetic acid

b)oxalic acid

c)formic acid
 d)propionic acid.

8)an aqueous solution of urea is

a)basic

b)acidic

c)neutral

d)both a and b

9) silver nitrate does not give precipitate with chloroform because

a)CHCl3 is insoluble in water

b) CHCl3 does not ionize in water

c) CHCL3 is an organic compound

d) silver nitrate is insoluble in chloroform

10) chloroform is used for the test of......... amines.

a) primary

b) secondary

c) tertiary

d) all

2 marks question

1)which alkyl halide from the following pair would you expect to react more rapidly by SN2
reaction mechanism.

CH3 CH2 CH2CH2Br. CH3CH2CH(Br)CH3

2) write short notes about cross aldol condensation reaction

3) para dichlorobenzene has higher melting point and lower solubility than those of o- and p-
isomers. Discuss.
4) Write the structure of the following compound

3 -hydroxybutanal

2- hydroxycyclopentane karbaldehyde

3 marks question

By1)arrange the following compound in increasing order of their reactivity in nucleophilic addition
reaction
Ethanal, propanal, propanone

2) how will you convert acetic acid into

a) methane

b) chloromethane

c) propanamide

3 write the equation of the following reaction

a) federal craft reaction

b) Nitration of anisole
c) Federal craft acylation reaction

4) illustrate with example limitations of Williamson synthesis for the preparation of certain type of
ether.

5 marks questios

1) an organic compound with the molecular formula C9H10O forms 2 4 DNP derivative, reduce
tollens reagent and undergo cannizzaro reaction. On vigorous oxidation gives 1,2
benzenedicarboxylic acid. Identify the compound.
2) Give simple chemical test to distinguish between the following pair of compound.
a) propanal and propanone
b) Acetophenon and benzophenon
c) Benzoic acid and ethylbenzoate
d) Ethanal and propanal
e) Pentan 2 one and pent 3 one

3) write structural formulas and names of four possible aldol condensation products from propanal
and butanal. In each case, indicates which act as nucleophile and which as an electrophile.